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By P. M. Solozhenkin

On the territory Sakha (Yakutia) are located largest in Russian Federation reserves of antimony ores, Sarylakhsk and Sentochansk deposits, amaunt 10% of world stocks of antimony. A processing gold antimony ores Sarylakhsk deposit is carried out on gravitation-flotation circuit to receive gold gravitation concentrate and gold-antimony flotation concentrate with the contents of antimony over 60%. The gold-bearing concentrate is treated on place hydrometallurgicaly to a high-standard product, accepted by gold bank cash department. At the ore dressing plant reached the highest recovery in world in a concentrate of antimony 90%~91.6%, and gold 85.7%~86.0% as a result of scientific research works. Studied the mechanism of interaction cations of metals Pb2+, Cu2+, Cd2+, Hg2+, Ag+ with a surface antimonite presented on the basis of modern physical-chemical methods: nuclear quadrupol resonance, x-ray electron spectroscopy, electron spin resonance. The industrial tests of sodium dimethyldithiocarbate were carried out which confirmed high recovery of Sb and As. The leaching Sb2S3 by bacteria Desulfovibro desulfuricans and transformation antimonite in antimony trioxide by Tiobacillus Ferrooxidans improved following cyanidation . The extraction of antimony in a solution 96.0%~98.0% under optimal conditions. The common total extraction in the appropriate commodity products for gold reached 98%, for Sb 96.5%. At a combination of bioprocessing and cyanidation 85.5% of extraction Au was achieved. The new solvents for antimonite were found. Now by the Close Joint-Stock Co ?Sarylach-Antimony? industrial plant is constructed for processing Au-Sb concentrates to receive antimony trioxide and gold from various antimony deposits of Sakha (Yakutia).

Jan 1, 2014

By Ali Dehghani Ahmadabadi

Gravity separation technique is widely used in mineral beneficiation practices for its low cost, ease of operation, and eco-friendly nature. The most commonly used gravity methods for beneficiation of iron ores are shaking table, jig and spiral methods which aren't very effective for iron mineral fines. Multi-Gravity Separator (MGS) is suitable for the treatment of fines with a maximum particle size of approximately 500 µm. This study was performed on a low-grade haematite iron ore from Chadormalutailing dams. Detailed mineralogical, physical and chemical characteristics of a goethiticlateritic iron ore showed that the sample contained porous and friable oxides and hydroxides of iron. The ore sample had a feed grade of 35% Fe, 1.1% FeO, 15.5% SiO2 and 8.5% Al2O3. Haematite and goethite are the main iron-bearing minerals while quartzite and kaolinite are the major gangue mineral constituents. In this paper, the statistical evaluation and optimization of grade and recovery using a factorial design of experiment (DOE) method has been carried out for Chadormalulow grade ultra-fine haematite tailings with MGS. The input process parameters considered are drum speed, tilt angle, wash water flow rate and pulp density. The results show considerable improvements in both the quality characteristics such as grade and recovery with statistical evaluation and optimization, compared to the initial value of grade and recovery. Keywords: multi-gravity separator, mgs, statistical evaluation, optimization, haematite

Sep 1, 2012

By Rogerio de Oliveira Baldoino

The sedimentary phosphate deposit of Bayovar is located in a very dry area of Peru (desert of Sechura) which is close to the Pacific coast. It consists of seven superposed layers (beds) which call for different strategy of concentration. The ore is composed predominantly by apatite (84% in weight basis) plus silicates (16%). In order to treat the ore from beds 1-5, a suitable standard mineral processing circuit (composed of scrubbing, screening, attrition and desliming) started its operation in 2010, yielding 3.9 Mt/y of concentrate assaying 30% of P2O5. To concentrate phosphate from beds 6-7, however, it is necessary to carry out further cationic reverse flotation of silicates, at neutral pH, to yield a concentrate, which meets market specification. The new process was developed in laboratory scale by a collaborative program conducted between Vale S.A. and the University of Sao Paulo-Brazil. A pilot plant has currently been running in order to confirm the very good results yielded in laboratory scale. The successful accomplishment of flotation in the current beneficiation flow sheet will enable a capacity expansion of 1.9 Mt/y of concentrate assaying 30% of P2O5. As water resources are very limited at Bayovar region, all the steps of concentration, including flotation, must be performed with seawater, which must be continuously recycled. This work addresses some relevant topics related to the use of seawater in the reverse cationic flotation of silicates: influence of temperature, water quality (ageing and chemical composition) and collector type (ether amine versus condensate). The results indicate that condensate amine works better than ether amine. If flotation is conducted with the former collector, the separation process is able to tolerate changes in temperature (25-40oC) and water quality caused by either evaporation or ageing. Keywords: phosphate, flotation, seawater, temperature, ageing, concentration, salt

Sep 1, 2012

By G. K. Nimal Subasinghe

The establishment of grind size that optimally liberates the valuable mineral for efficient down-stream processing is of great importance for most mineral processing operations. Reasonably accurate comminution models as well as models of downstream separation processes may be found in the literature but their use in optimizing grind size is limited without an associated liberation model. In this work, an attempt has been made to address the above shortcoming by demonstrating how the effective parameters of the downstream flotation process may be predicted from the liberation characteristics based on the ore texture data for a disseminated nickel ore. In this regard, the liberation model based on linear intercept distributions of mineral and gangue proposed by King (1979) and its application to predict the flotation performance of an industrial plant demonstrated by Schaap (1979) may be considered useful contributions. However, while the model proposed by Schaap is simplistic enough, it is based on several assumptions due to the non-availability of intercept length measurements on the parent rock, in particular, on the extent of mineral exposure on the surface of comminuted particles. In this work, the linear mineral and gangue intercepts on polished specimens of a binary ore, comprising darker pentlandite as the valuable mineral and lighter barren host rock were measured using an image analyser. The resulting intercept distributions followed negative exponential distributions. Using the mean sizes of mineral and gangue intercepts, the proportion of liberated, compo-site and mineral occluded particles of a given size, the extent of mineral exposure on the surface of particles and their mean mineral contents were calculated using principles of renewal theory. The rock was then crushed and ground and different size fractions were floated. It has been shown that the parameters of observed recovery data based on 1st order kinetics such as the associated rate constant and ultimate recovery agrees well with those predicted from the quantities calculated above. This work has important practical implications since it can indicate variations in flotation performance arising from changes in mineralization within a large ore body.

Jan 1, 2014

By K. B. Venkatesh

In view of the importance of size reduction operations from the energy consumption point of view, during the past one hundred and fifty years a number of attempts have been made to develop a general energy-size relationship. However, to date it has not been possible to clearly define the scope of application of various laws proposed, though Bond law has been widely used with a moderate degree of success. It was, therefore, decided to carry out a thorough analysis of the batch ball mill grinding data available in the literature on several minerals that were ground under normal range of operating conditions. In particular, relationships proposed by Bond, Kapur, Voller and Morrell were examined in detail. It was found that the relationship proposed by Kapur in terms of the mean particle size provided a more accurate basis for estimation of energy. The value of the exponent of mean particle size in this relationship, a, is same as the exponent of the particle size in the expression for the grinding rate parameter: ki = Axia, provided the particle size distribution range corresponds to the self-similar or self-preserving regime. In this regime, mean particle size is proportional to the 80 percent passing size and size modulus. From the practical application point of view, it was possible to describe the variation of µ1 over limited, but significantly broad size range, using a constant value of a. Thus, by carrying out a few batches, grinding experiments over the size distribution range corresponding to the contents of the production mill, the applicable value of a can be determined. Keywords: energy-size relationship, ball mill, mean particle size, self-similar size distribution regime

Sep 1, 2012

By J. Masinja

The mining industry is known to be a potential major contributor to the industrial development of any economy. Large-scale mining has been going on in Zambia for the last 100 years. The impact of mining in Zambia has been to create a development corridor along the line of rail to the Copperbelt Province, where hitherto, mining was concentrated, and then to develop a large consolidated high-density economic zone covering an area of about 72 km by 60km. This area is home to a number of very large integrated copper/cobalt mining complexes. The mining zone has expanded to the Northwestern Province in the last 10 years, where the largest copper mine in Africa now exists, having produced about 300 000 tonnes of copper in 2011. The total output of the Zambian mining industry is now about 820 000 tonnes per annum with projections of reaching 1.5 million by 2015, due to new Greenfield investments expected to come online by then. These new mining industry developments have come on the back of strong and sustained high base metal prices, in the last 10 years or so, due to demand mainly from China and India. This new lease of life has increased the contribution of the sector to the national treasury. The mining industry in Zambia has undergone a very important ownership restructuring with the sale of the previously Government owned parastatal, Zambia Consolidated Copper Mines (ZCCM) which dominated the sector, to allow for private sector participation. The privatization process lasted from about 1995 to about 2002. The recent growth of the mining sector has unfortunately not been matched by an adequate supply of skilled manpower for various reasons. These include: (i) A lack of strong in-house training strategies by the new mine owners (ii) Decrease in industry support to the training institutions (iii) The demise of and restructuring of ZCCM which has consequently limited the Government human resources planning tools for the mining sector (iv) The cyclic nature for the fortunes of the sector has lead to fluctuating interest of student recruitment into training institutions (v) Limitations, both staff and equipment, in the training institutions (vi) A re-structuring of the training institutions This paper examines the current status, and student output from tertiary training institutions for the mining sector in Zambia. This is then compared to the skilled labour demands of the sector. The various cause and effect issues are considered and a proposal on how this skills gap could be addressed sustainably is proposed. Keywords: skills gap, graduate training, quality of graduates

Sep 1, 2012

By J. Y. ` Xie

The paper introduced bio-oxidation plants of refractory gold concentrate in China and CCGRI cultures. CCGRI cultures are composed of bacteria and archaea. Archaea Ferroplasma acidiphilum is very thick and fills whole mineral surface. It plays a more dominant role in CCGRI process. Several years of practice has proved that the operating temperature in bioreactors between 38~52?,gold recovery is almost same. Pulp concentration has been increased each year and reached to 25%.

Jan 1, 2014

By Ji Hoe Kwon

Hindered-settling column process has been used for the separation of mineral particles for many years. In this study, a model based on DEM (Discrete Element Method) was used to simulate the movements of particles in a settling column separation process. DEM model is capable of describing the motion of particles and calculating the impact forces between particle and particle, and particle and wall contact under various operating conditions. Drag force, rotation induced Magnus lift force, contact force and the gravitational force acting on individual particles were considered for establishing the mathematic models. The overall motion of the particles in water is satisfactorily simulated by the DEM, and the result shows good agreements with the result of lap-scale experiment.

Jan 1, 2014

By Abhakumari

Effect of applied DC potentials on the bioleaching of a chalcopyrite concentrate in the presence of Acidithiobacillus ferrooxidans is discussed. Copper dissolution was the highest at an applied potential of +600mV (SCE), while all the dissolved copper got cathodically deposited at a negative potential of -600mV (SCE). Electrobioleaching at an applied potential of +600mV (SCE) was established at different pulp densities as a function of time. Effect of the magnitude of electrolytic currents on the activity and growth of bacterial cells was studied. Preadaptation of bacterial cells to the concentrate slurry and electrolytic growth conditions significantly enhanced copper dissolution. Electrochemical and biochemical mechanisms involved in electrobioleaching are illustrated with respect to oxidative dissolution and bio catalysis of anodic oxidation.

Sep 1, 2012

"The first 90 years of the last century generated a considerable volume of technical literature on the subject of grinding mill power and its prediction. It is therefore surprising that during this time there were no published models for predicting grinding mill power draw which were validated using a wide range of comprehensive industrial scale data.Notwithstanding this lack of data, the majority of models placed limited emphasis on the internal dynamics of mills and relied on simple assumptions which considered the charge to take up a fixed position and shape.Laboratory based studies (Liddell, 1986), and industrial data (Morrell, 1993), showed that these assumptions did not hold over a wide range of operating conditions, and brought into doubt the ability of the (then) existing models to accurately predict grinding mill power draw. Furthermore no model treated AG,SAG and ball mills as a single class of devices whose power draw could be predicted with the same equations.Through a detailed investigation of the charge dynamics, coupled with a large data base of industrial mill power draws, this situation was rectified by the end of the century, by which time a model had been developed and validated, which accurately predicted the power draw of all wet tumbling mills. This paper describes this model and reviews some of the earlier attempts at mill power modelling.INTRODUCTIONThe early 1900?s saw the beginnings of published papers which tackled the problem of what influenced the power draw of tumbling mills and what equations (models) were suitable for predicting power draw. This interest continued for the rest of the 20th century and the literature contains many papers that attempted to satisfactorily answer these questions. A common and disappointing theme in the majority of them, however, is the distinct lack of suitable experimentally derived power draw data. This deficiency consequently limited the practical application of many of the attempts at modelling mill power draw. Prior to the early 1990?s some limited data on the power draw of grinding mills in the literature can be found, but as Harris et al (1985) remarked they are ?... too frequently unusable simply because one or more essential variables have been omitted?. The absence of published results, from vigorous experimental testing of the various models, has resulted in a general lack of evaluation of the validity of assumptions and hypotheses that such models contain. Harris et al (1985) however, did make some efforts in attempting to evaluate the performance of various power prediction equations and in so doing further developed a semi-empirical one of their own. However, in using manufacturers? published data, which themselves were undoubtedly generated by proprietary equations of unproven validity, they probably succeeded in generating little more than a consensus of the various errors in these models."

Jan 1, 2003

By D. H. Xiong

Low grade oxidized iron ores are usually not economic to utilize. However, the development of SLon magnetic separators and other new technologies make the process cost lower and lower. In this paper, several low-grade oxidized iron ore process flowsheets are introduced. The key procedure is that at the early stage, SLon magnetic separators are applied to discharge as more tails as possible with very low cost, only a small portion of rough concentrate going to the cleaning stage, showing the new technologies are profitable for such iron ores.

Jan 1, 2014

By Yuhua Wang, Huilan Yang, Yanqing Jiang, Dongfang Lu

"Generally, the concentration of bauxite flotation tailings is around 10%, a large amount of water in tailings needed to be recycled in the flotation process. Sedimentation and dewatering properties of tailings were investigated under different conditions. Surface high negative charges on mineral particles are the key factor to destroy the settlement of tailings when the pulp pH is around 8.9. Hence, the modification of pulp pH around 7 is necessary to the diminution of the repulsive force between mineral particles and then the acceleration of sedimentation of tailings. Anionic polyacrylamine with molecular weight of 14 million is the best flocculant for the settlement of tailings in all tested polyacrylamines. P-toluene sulfonic acid shows better properties than hydrochloric acid for pulp pH adjustment when anionic polyacrylamine with molecular weight of 14 million is used as flocculant. Although the flotation of diaspore is depressed in the presence of polyacrylamine using sodium oleate as collector, but the recycling water traded by the combination of ployacrylamine and p-touenesulfonic acid does not show the depression effects on the flotation of bauxite ore. The lower residual content of polyacrylamine in recycling water treated by the combination of ployacrylamine and p-touene sulfonic acid plays an important role. INTRODUCTION Generally, the waste water generated from mineral processing plant is usually treated by sedimentation, oxidization, electrodialysis, ions exchange, active carbon adsorption and flotation technology, and the treated water is also used again in the industrial process. Flotation was adopted widely to improve the quality of bauxite from low grade diasporic bauxite in China. For flotation, the grinding fineness of bauxite is over 90% -0.074 mm, sodium carbonate and sodium hexametaphosphate were used as regulators, so the tailings pulp is very difficult to settle and be dewatered (Y. Wang et al., 2004; Y. H. Wang et al., 2007; Wang Yu-hua et al., 2008; Wang Yuhua et al., 2011). The water recycling of bauxite tailings are becoming the highlight for the industrial application of the flotation process for bauxite ore. Researchers in China shift their attentions onto this topic."

Jan 1, 2018

By R. Sakthivel

Blue dust is a high grade soft haematite material containing 96.14% Fe2O3 transformed into magnetite (Fe3O4), when it is subjected to planetary ball milling in the presence of iron powder as reducing reagent. X-ray diffraction (XRD), Field emission scanning electron microscope (FESEM) and Laser particle size analyser have been employed to characterize various samples collected at various milling times to know the phase evolution, particle size distribution and morphology of particles. X-ray diffraction studies reveal the formation of magnetite phase at the optimum milling time of 40 hours. Vibrating sample magnetometry (VSM) study demonstrates, that sample obtained at 40 hours of milling time exhibits saturation magnetisation of 14.757 emu/g whereas the starting material used in this study shows only 1.0425 emu/g. Keywords: Blue dust, reaction milling, magnetite, saturation magnetization

Sep 1, 2012

By Vinay Jain

Beneficiation of alumina rich iron ore slimes is a major challenge for the Indian iron ore industry. One of the methods by which this problem might be addressed is by design/screening of suitable reagents (flocculants/depressants/collectors) which act selectively towards either aluminum containing minerals (gibbsite and kaolinite) or iron bearing minerals (hematite and goethite) in order to separate them. Our earlier work indicates that separation of iron oxide minerals from gibbsite is relatively more difficult than from kaolinite. Accordingly, our research work has been focused on finding selective reagents for iron oxide ? gibbsite separation. We have performed density functional theory (DFT) computations to evaluate the interaction energies of seven different reagent groups - carboxylic acid, flotol, hydroxamic acid, phosphonic acid, iminobismethyl phosphoric acid, xanthate and starch with hematite and gibbsite surfaces. The objective was to identify if any of these groups show selective adsorption towards one of the mineral surfaces. Among all these reagents, starch exhibits the highest selectivity towards the hematite surface with a difference in interaction energy of ~63 kcal/mol between hematite and gibbsite surfaces. This is consistent with experimental findings at our laboratories on slime samples from Noamundi mines wherein it is being observed that usage of starch as a flocculant does lead to an improvement in the final grade of the ore with significant reduction in the Al-content. A binuclear complexation mechanism based on affinity between Fe and Ostarch atoms combined with a geometrical templating effect, arising out of a close correspondence between Fe-Fe distance on the hematite surface and O-O distance in starch, is proposed to explain the strong adsorption of starch on hematite surface. Keywords: slimes, iron ore, alumina, hematite, gibbsite, DFT, adsorption, flocculants

Sep 1, 2012

By E. Barsky

The composition of multi-component materials is proved to be unambiguously determined by the composition uncertainty parameter (composition entropy). At the same time, every component, depending on its content, introduces a certain value into this parameter. Quality criterion of multi-component separation is determined by the total change of this parameter for all products obtained as a result of the separation process. This parameter can unambiguously estimate both multi-product separation and complicated schemes of modern beneficiation plants. It can be used to estimate binary mixtures separation, too. During the optimization of multi-product separation, another problem arises, which is not peculiar to binary mixtures. In this case, the total efficacy depends on the order of separation boundaries, as well. In the present paper, a specific example of initial product separation into seven products by six boundaries is investigated. It is clear that with respect to a single boundary, two products only can be obtained. In this case, the separation optimum is shown to correspond to the separation of boundary-class particles equally into both products. We have also established that from the point of view of entropy, the maximal possible separation efficacy corresponds to equiprobable composition of the initial mixture, i.e., the fine product quantity in the material to be separated is equal to that of the coarse product. Three groups of experiments were carried out. In the first group, the boundaries were consecutively specified from the finest to the coarsest one. In the second group, the boundaries were set vice-versa, i.e., consecutively from the coarsest to the finest one. In the third group, no sequence was observed. At every separation stage, a boundary was specified in such a way that the separated material composition was as close as possible to equiprobable one relative to this boundary. Total efficacy was different in all the three cases. In third group of experiments, its value is the highest, which confirms the advanced supposition. The obtained results are phenomenological, ? they can be applied to any processes of solid, liquid and gaseous materials separation.

Jan 1, 2014

By V. A. Chanturiya

There is an obvious disproportion in Russia gold-mining industry between the structure of gold reserves and the gold-mining techniques. The bulk of gold (over 70%) is extracted from alluvial deposit, 20%~25% from bedrock occurrences and 5%~7% from complex copper-zinc and polymetallic ores. The proved gold-bearing reserves are distributed as follows: alluvial ?19%, bedrock ?80%, the latter being sufficient to supply gold at the current production level for 100 years to come. In Russia, like elsewhere in the world, development of primary gold deposits is considered a first-priority line of development for gold-mining industry. Most of the gold-containing ores characteristic of Russian gold deposits are resistant ores with gold content varying between 3 ppm and 5 ppm usually showing quite low gold and silver recovery by cyanidation. Processing resistance of gold-containing mineral complexes is related to the presence of gold particles of submicrometric (<1.0 µm) and nanometric (10~100 nm) size, mostly asso-ciated with pyrite and arsenopyrite. Therefore switching over to processing bedrock entails a num-ber of technological problems that stem from chemical and physical resistivity of ores. The chemical resistivity can be overcome through flotation, oxidation roasting, autoclave leaching (biohydro-metallurgical oxidation), etc. The physical resistivity can be dealt with by resorting to traditional power-intensive methods,e.g. grinding to a ?40µm size, thermal treatments of sulphide concentrates and non-traditional high-energy methods of liberating the sulphides by means of power attack, e.g. electro-chemical oxidation, exposure to electron beam radiation and other methods. The modern non-traditional processes for treatment of rebellious noble metal-bearing ore, aimed at improving disintegration efficiency for finely dispersed mineral complexes are analysed. Advantages and perspectives of a new high-efficient, energy-saving and ecologically safe process of the nanosecond high-power electromagnetic pulses (HPEMP) effect are proved. The said process provides a stable increase in the valuable component recovery at lower energy consumption and production costs of the finite product at the stage of dressing rebellious gold-bearing ores and concentrated products. The experimental data prove high efficiency of the preliminary impulse treatment, thus, the increase in the gold recovery at the cyanidation stage amounted to 4%~12% from rebel-lious ores, 10%~30% from gravity concentrates, 5%~45% from flotation concentrates, 30%~80% from oil flotation tailings.

Jan 1, 2014

By Robert Snow, Shibo Zheng, Wenyi Song, Xiaoqing Ma, Patrick Zhang

Numerous phosphate mineral depressants have been reported in the literature for use during anionic flotation of dolomite from carbonate fluorapatite in slightly acid circuits. In one part of this research, laboratory flotation experiments were conducted to compare the effectiveness of phosphate depressants to process ground, deslimed high-MgO Florida phosphate pebbles. Ten potential phosphate depressants were evaluated during laboratory anionic flotation of dolomite from phosphate in a slightly acid circuit using a sulfonated oleic acid soap plus oil as the dolomite collector. Eight of the depressants have been used by various investigators with foreign and domestic carbonate-phosphate ores. Four of the depressants were found to be reasonably effective during the current flotation study, namely: sodium tripolyphosphate (STPP), sodium hexametaphosphate (SHMP), tetrasodium pyrophosphate (TSPP) and diphosphonic acid (DPA). Without depressants, the sulfonate collector required to produce cell underflow phosphate products containing <0.80% MgO and MgO/ P2O5 ratio <.033 was 1.13 kg/ton of flotation feed at a flotation pH range = 5.5-6.0. Using this collector level with 0.91 - 1.36 kg/ton of feed of STPP, SHMP or TSPP yielded phosphate products analyzing 0.73-0.92% MgO and MgO/ P2O5 ratios = .027-.034 at 90.0-96.8% P2O5 recovery. Similar grade phosphate products were obtained using DPA as the phosphate depressant at 84.1-87.5% P2O5 recovery. When no depressant was used, a similar grade phosphate product was obtained at only 65.9% P2O5 recovery. Another part of the research aimed at reducing MgO content in the final concentrate from Florida phosphate plants by conducting dolomite flotation on the final concentrate. Numerous phosphate depressants were tested for this purpose, including acidic, neutral and alkaline reagents. The most effective phosphate depressant was found to be phosphoric acid, giving both high grade and recovery.

Jan 1, 2014

By H. Kasaini

Batch wise adsorption tests for platinum (Pt) on the surface of activated carbon pellets (Norit RO 0.8 BET surface area 1100 mg/g) were carried out in mixed chloride solution. The purpose of this study was to assess and compare the adsorption performance of amine-treated activated carbons (AACs) and native activated carbons (NACs) in terms of adsorption capacity and selectivity. The effect of pH and temperature on adsorption capacity and selectivity was established. The amine- treated ACs were prepared by anchoring the amino groups (butyl amines) on the surface of AC pellets in aqueous media and the UV-Vis was used to determine the amount of amine sequestered from solution by ACs. The dosage of butyl amine on the surface of ACs averaged 0.15 g/g, carbon. The adsorption mechanism was described by the ionization and complexation model whereby interaction between the protonated AAC surface and the anionic chlorocomplex ions (PtCl5 [H2O]-, PtCl62-) proceeded by either electrostatic attraction or/and by covalent bonding [(NH3)2PtCl6 or (CH2COO)2PtCl6]. By comparison, the adsorption capacities of Pt on amine-treated ACs and native ACs were 53.8 mg/g and 33.03 mg/g, respectively which highlight the benefits of anchoring functional molecules on ACs. The selectivity of AACs was influenced by solution pH. Pt adsorbed selectively on the surface of amine-treated ACs at pH<1.5. The highest separation factor that was recoded pertained to Pt and Fe species (ßPt/Fe = 90) then followed by Pt and Ni species (ßPt/Ni = 30) or Pt and Cu species (ßPt/Cu = 15). The lowest separation factor was recorded for Pt and Cr ions (ßPt/N= 5). Adsorption kinetics of Pt on amine-treated AC surfaces, according to the first and second order reactions, were investigated and results showed that rates were in the order 10= 5). -4 min-1 and 102 g?min/mg, respectively. The pseudo 1st order kinetics predicted the adsorption capacity of 51.81 mg/g which was almost similar to the experimental value (53.8 mg/g) while the second order rate equation predicted Pt adsorption capacity of 40.1 mg/g. Both The Langmuir and Toth isotherm fitted the Pt adsorption at pH < 1.0. The Freundlich isotherm tended to underestimate the adsorption capacity of AACs.

Jan 1, 2014

By Alexander V. Epiforov, Stanislav V. Balikov

This paper describes of processing tests of 8 flotation concentrates containing precious and base metals by pressure oxidation (POX) method. Concentrates 1 and 2 were gold-copper concentrates. Zinc and silver were by-products in these concentrates. These concentrates were processed by POX with following cyanidation of POX solid residues, copper solvent extraction and zinc carbonate precipitation. The recoveries of gold, copper, silver and zinc from these concentrate were 98, 99, 30 and 99%, respectively. Concentrates 3 and 4 were lead-zinc concentrates. Silver was by-product in concentrate 3. Gold, silver and copper were by-products in concentrate 4. Concentrate 3 was processed by POX with following reduction smelting of POX cakes for primary lead recovery and zinc carbonate precipitation from POX solution. The recoveries of lead and silver into ingot were 96 and 98%, respectively. The recovery of zinc was 99%. Concentrate 4 was processed by POX with following zinc carbonate precipitation and reduction smelting of POX cakes. Copper was precipitated from the POX solution using sodium sulphide prior zinc precipitation. The recovery of zinc into carbonate concentrate was 99%. The recoveries of lead, gold and silver into lead bullion were 95, 99 and 98% respectively. The recovery of copper into sulphide concentrate was 99%. Concentrate 5 was gold-pyrite concentrate, and concentrates 6-8 were double refractory gold-arsenopyrite concentrates. Silver was by-product in these concentrates. These concentrates processed by POX and CIL. The recovery of gold from concentrate 5 was 98%, and from concentrates 6-8 was 85-90. Low gold recovery from concentrates 6-8 was associated with preg-robbing factor. The recovery of silver from gold-sulphide concentrates did not exceed 10-20%. The low silver recovery was associated with argentojarosite formation that is resistant to cyanidation. The flowsheets for complex processing of precious and base metals sulphide flotation concentrates based on this test work results were proposed.

Jan 1, 2018

The molybdenum ores currently utilized in China are mostly molybdenum sulfide ores whereas oxidized molybdenum ores, being finely disseminated and difficult to process, have not been exploited and utilized effectively. In this article the beneficiation process of a molybdenum ore occurred in an oxidized ore zone was investigated in order to provide a new way for the development and utilization of the oxidized molybdenum ores in China. The molybdenum mineral in the ore was mainly wulfenite and the associated minerals included barite, limonite, quartz and small amount of cerusite. Limonite in the ore occurred in a crust and honeycomb-like colloidal state and composed the framework for the formation of the other minerals in the ore, which filled the pores in the framework. Wulfenite was mainly fine-grained and occurred in the fine porous crust and honeycomb-like framework. The finely disseminated ore structure made the separation and recovery of the molybdenum mineral in the ore very difficult. On the basis of the mineralogical study of the ore, experiments were conducted to compare the various mineral processing methods for the beneficiation of the ore, including single gravity concentration, single magnetic separation, single flotation, and a combination of high intensity magnetic separation and gravity concentration. The results indicated that with single gravity concentration a molybdenum concentrate containing 5.85 % Mo with a yield of 11.76 % and a Mo recovery of 43.5 % was produced. With single high intensity magnetic separation it was very hard to obtain a molybdenum concentrate product. With single flotation process a molybdenum concentrate containing 7.06 % Mo with a yield of 15.14 % and a Mo recovery of 62.63 % was produced. With a combination of high intensity magnetic separation and gravity concentration a molybdenum concentrate containing 6.46 % Mo with a yield of 11.81 % and a Mo recovery of 42.11 % was produced. In conclusion, compared to the other methods the flotation process can produce more reasonable technological and economical results and is the best process for the exploitation and utilization of the finely disseminated oxidized molybdenum ore.

Jan 1, 2014