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By Dale Verran, Jared Orynik, Chad Sorba, David Bronkhorst

Denison Mines Corp. (“Denison”) has a 90% interest in the Wheeler River Uranium Project (“Wheeler River”) located along the eastern edge of the Athabasca Basin in northern Saskatchewan between the Key Lake mill and the McArthur River uranium mine. The project is host to the high-grade Phoenix and Gryphon uranium deposits, discovered by Denison in 2008 and 2014 respectively, which include combined Indicated Mineral Resources of 132.1 million pounds U3O8 (1,809,000 tonnes at an average grade of 3.3% U3O8). The Pre-Feasibility Study (“PFS”), completed in accordance with NI 43-101 in September 2018, is highlighted by the selection of the In-Situ Recovery (“ISR”) mining method for the development of the Phoenix deposit, with an estimated average operating cost of $4.33 (US$3.33) per pound U3O8. Phoenix is the highest-grade undeveloped uranium deposit known globally, including Indicated Mineral Resources of 166,000 tonnes at 19.1% U3O8 for 70.2 million pounds U3O8. The paper aims to provide a summary of Wheeler River and an overview of the proposed development of the Phoenix and Gryphon deposits according to the PFS completed for the Project. Further details regarding the PFS, including additional scientific and technical information are described in greater detail in the NI 43-101 Technical Report titled "Pre-Feasibility Study for the Wheeler River Uranium Project, Saskatchewan, Canada" dated October 30, 2018 with an effective date of September 24, 2018. A copy of this report is available on Denison's website and under its profile on SEDAR at www.sedar.com and on EDGAR at www.sec.gov/edgar.shtml.

Jan 1, 2020

By O. Worku, J. H. Masliyah, Z. A. Zhou

ABSTRACT The viscosity of concentrated kaolinite or illite clay in aqueous suspensions was measured in the presence and absence of a small amount of montmorillonite (<1 wt%). To avoid solids settling and to increase the sensitivity of the suspension viscosity measurements, solids concentrations higher than 38 wt% were used. The pH of the suspensions and the concentration of calcium and bicarbonate ions were found to significantly impact the viscosity of the clay suspensions. The results showed a significant increase in the viscosity of kaolinite suspensions with the addition of as low as 0.25 wt% of montmorillonite on a solids weight basis. In addition to illustrating the role of water chemistry in modifying slurry rheological properties, our study demonstrated that viscosity measurement could be a simple, yet sensitive technique for determining the content of smectite clays, such as montmorillonite, in a complex mix of various types of clay.

Jan 1, 2012

By F. Mohamm

"Recent changes in regulations and scientific advances concerning selenium bioaccumulation have placed greater importance on non-biological treatment systems for selenium control. Mining wastewater contains hexavalent selenium (selenate) as the predominant aqueous species and possibly small amounts of tetravalent selenium (selenite). Non-biological removal of selenite is accomplished readily and cost effectively by ferric co-precipitation and adsorption using ferric oxyhydroxides sourced from ferric salts or iron anodes in electrocoagulation cells. Selenate on the other hand is difficult to remove. It is often incorrectly assumed that electrocoagulation is suitable for removing both selenite and selenate. Selenate removal efficiency by electrocoagulation is low and the amount of waste residue produced high. In contrast, BioteQ’s Selen-IX™ process removes selenate very efficiently and produces a much smaller amount of stable residue. The process combines selective ion exchange with electro-reduction of selenate in electrocells that physically resemble electrocoagulation cells but are designed and operated differently. This paper summarizes four years of pilot scale demonstration on a wide range of mine waters and discusses the key benefits and limitations of Selen-IX™. The pros and cons of combining ion exchange with electro-reduction in comparison to direct electro-reduction of selenate are also reviewed.INTRODUCTION Selenium in Mining and Mineral Processing Effluents Similar to sulphate and metals, selenium presence in mining and mineral processing wastewater originates from minerals contained in the mined deposits. Therefore, no organoselenium species are typically present in these kinds of waters and inorganic species including selenite (SeO32-), selenate (SeO42) and elemental selenium account for the majority, if not all, selenium present in these streams. Elemental selenium is not always present in mine water but is often contained in smelter wastewater. To comply with new environmental regulations, a successful water treatment plant must remove selenium from all these forms effectively and economically without generating by-products that are difficult to dispose of or manage. Elemental selenium can be dealt with using filtration or gravity separation in clarifiers often assisted by flocculants and/or coagulants. Mine impacted waters typically contain other forms of suspended solids which are removed from water in this way. Once the solids are removed, the selenium species that remain untreated are the dissolved forms. In mining waters this is mostly selenate with small fraction of selenite. In smelter wastewater, the majority could be selenite. It is well established that tetravalent selenium is readily removed from water by using ferric iron co-precipitation at pH > 4 (NAMC SWG, 2010). Ferric hydroxide/ferrihydrite solids act as the adsorbent for tetravalent selenium when it is in one of the ionic forms of biselenite or selenite. This treatment for tetravalent selenium is highly efficient. Therefore, tetravalent selenium removal is generally not an issue and is often easily incorporated into lime neutralization or unit operations such as electrocoagulation used for removing other metals present in mine impacted waters. Another option of dealing with tetravalent selenium is sulphide precipitation in acidic pH which produces SeS2 and can separate selenite from other metals and/or sludge produced at neutral to alkali pH."

Jan 1, 2017

By K. M. Wild, C. D. Martin, F. Amann

"Argillaceous rock formations, in particular clay shales, are notorious for creating challenges in rock engineering. Due to their generally low hydraulic conductivity and their complete saturation in their natural state at depth, the behavior of clay shales is usually characterized by a strong hydro-mechanical coupling.This paper presents typical pore pressure responses monitored in different underground rock laboratories and explores alternative ways for their interpretation. The underpinning processes and their relevance are identified based on analytical and conceptual numerical models. Pore pressure monitoring data from Opalinus clay at the Mont Terri Underground laboratory, the Boom Clay at the Mol facility and the Callovo-Oxfordian clay in the Meuse/Haute–Marne URL show a similar pore-pressure response associated with stress changes accompanying tunnel construction although the tunnels were built in different rock types, at different locations, and under different in-situ conditions.The numerical analyses in this study shows that the pore pressure response around an excavation in low permeable clay shales may have different explanations. Pore pressure drops observed in the tunnel near field can theoretically be explained by both, a pure elastic response in an isotropic or anisotropic rock mass with an anisotropic stress state, or a inelastic response and related dilatancy. However, a comparison between the numerical models and the in-situ measurements revealed that the latter is more likely. This conclusion is justified by the observation that pore pressure drops occur significantly ahead of the tunnel face which is not the case in elastic numerical simulations. Pore pressure measurements in the far field, where failure processes are unlikely to occur, can only partly be explained by a linear poroelastic models. The introduction of an anisotropic material plays a key role in reproducing the responses, conceptually."

Jan 1, 2015

By S. Banisi, E. Arghavani, A. Akbari, Gh. A. Parsapour, S. Darvish Tafvizi

The new copper processing plant of the Sarcheshmeh copper complex consists of two parallel circuits. After a primary crushing, the ore is sent to a SAG mill and the product is further ground in a ball mill. The overflow of the hydrocyclones is fed to a flotation circuit which contains 8 rougher tank cells (RCS130), 3 cleaner cells (RCS50), 5 scavenger cells (RCS50) and a 4 x 12 m flotation column as recleaner. The circuit was initially designed to process a feed containing 0.8% Cu, but because of the ore type change, the feed grade decreased to 0.6% Cu. This resulted in a reduction of final concentrate grade and recovery from 28 and 85.5% to 24 and 84.4%, respectively. Based on the original design, the copper and silica recovery in the cleaner cells should be 69 and 55%, respectively, but these values increased to 85 and 75% because of a higher retention time. The rather high silica recovery (i.e., 75%) was found to be the main source of the lower final concentrate grade. In order to reduce the retention time of particles in the cleaner cell from 13.7 to 6.9 min, the rougher concentrates of two parallel circuits were fed to only one cleaner-scavenger and regrind circuit. This modification increased the cleaner and final concentrate grade from 15.1 and 24.5% to 17 and 26%, respectively. To prevent a possible reduction in the copper recovery, the froth depth in the scavenger cells was reduced. The overall outcome of the circuit modification was evaluated to be a 10% reduction in the energy consumption without any loss in the overall copper recovery.

Jan 1, 2016

By Sydney H. Ball

It is a peculiar anomaly that while the world uses the term "rich as a gold mine" as the superlative figure of speech descriptive of wealth, the shares of gold mines are not as popular investments in America as certain of them should be. One of the most able of Manhattan&apos;s bankers is a director in an investment trust with a portfolio the value of which has gone the way of other such portfolios. Luckily a couple of years ago a few hundred shares of Homestake were purchased, and since then the trust has not only received therefrom satisfactory dividends but has benefitted from a large appreciation in their value. At each directors&apos; meeting, however, the banker in question, Cato-like, suggests the sale of these shares, gold shares being, in his opinion, too speculative to be included in the portfolio of any trust. A short time ago the financial pages of one of our great metropolitan papers featured an article listing the corporations still paying dividends at the 1929 rate. Gold-mining shares were, the article stated, excluded, although in reality every gold mine on the New York Stock Exchange paid higher dividends in 1932 than in 1929. This &apos;Alice in Wonderland&apos; treatment of the gold-mining shares is admittedly a bit confusing to those of us who believe that the shares of certain gold-mining companies have a rightful place in any well diversified portfolio. It should, however, here be recorded that whereas, fifty years ago, in America, gold-mining shares were considered by the public as instruments of nefarious gambling, now shares of the better gold mines are sought by astute investors. In England for well over a generation their value as sound investments has been widely recognized.

Jan 1, 1933

By H. Brodie Hicks

"THE REVIVAL of the Mayo mining camp, with particular reference to the activities of United Keno Hill Mines, Limited, has been one •of the more spectacular and also one of the most important of the post-war developments in the Canadian mining field. The geological location of the camp, coupled with other natural disadvantages, have in the past limited the mining area to small-scale, highgrading operations, but the post-war improvement in metal prices has now broadened the possibilities and has led to the considerable success achieved by United Keno Hill Mines, Limited, and the present boom-type development by a whole host of newcomers to the field.LocationYukon which has an area of 207,000 square miles, is showing ever increasing possibilities as a mineral source of great value and more and more attention is being focussed on the Territory. The accompanying generalized map (Figure 1) shows the main transportation routes and mining districts.The Mayo Mining District comprises roughly the eastern two thirds of Yukon Territory lying north of McMillan river and south of the Peel. The district was one of the first in the Territory in which placer gold was discovered, but the occurrences proved of minor importance. Other minerals reported include ores of tungsten, tin, antimony, and several other metals, but of primary importance have been the ores containing silver-lead-zinc-cadmium now being developed and mined in the Keno area. Similar ores have been found over a very considerable area, extending some 50 miles north, 15 miles east, 30 miles west, and 10 miles south of the townsite of Keno Hills, Keno City, a total area of 2,700 square miles."

Jan 1, 1952

Discovery of an economic diamond deposit produces considerable wealth in terms of jobs, royalties, mining investment, and economic spinoffs for residents, including Aboriginal peoples. Diamond mines contribute to the GDP, increased personal income per person and reduced unemployment rates. Is it possible in Alberta?

May 1, 2008

"7.1. Glossary of the Platinum-Group Minerals7.1.1. IntroductionA glossary of the platinum-group minerals (POM) serves as a useful introduction to a chapter on their mineralogy. Earlier glossaries (Cabri, 1972, 1976) were prepared for different purposes and composed in a different manner. As for most mineralogical textbooks, from Dana's System of Mineralogy, 3rd Edition (1850) , to Fleischer's Glossary of Mineral Species (1980), this glossary is primarily a chemical classification, arranged here in two tables. Table 7.1 groups the mineralforming compounds of the six platinum-group elements (POE) according to their essential anion(s) or according to the nonPOE element in intermetallic compounds. Table 7.2 is a similar listing for the native metals and alloys of the POE. Both tables include unidentified POM considered to be bona fide new minerals requiring additional study for complete characterization and recognition (see Chapter 9*). Some information on the chemistry of the POM is given in the sections on X-ray data (7 .2) and ore microscopy (7 .3). Because the overwhelming majority of POM have been characterized by the electron microprobe, a more detailed account of representative analyses is given in Chapter 8**. The total POM listed in Tables 7.1 and 7.2 is about 100, after deleting some which would not qualify as discrete species if found today, but which are still recognized on historical grounds; e.g. iridosmine, osmiridium, platiniridium. Tables 7.1 and 7.2 also include 28 unnamed POM; included because they are considered to be probably new species (Cabri 1981 b). The referral scheme for unnamed minerals is the same as in Chapter 9. There are considerably more palladium minerals known than other POM; the proportion of total species (listed in Tables 7.1 and 7 .2) for the POE is: Pd 48%, Pt 21 o/o , Ru and Ir 9% each, Rh 8% and Os 5%. These proportions are in marked contrast to the estimated cosmic abundance, as compiled for average type C1 chondrite by Naldrett and Duke (1980): Pt 29%, Ru 20%, Pd, Ir and Os 15% each, and Rh 6%."

Jan 1, 1979

By Robert B. Parsons

"The last edition of Tax Notes expressed concern about two proposed tax changes in Finance Minister Paul Martin&apos;s 1995 budget that could have detrimental effects on Canada&apos;s mining industry. This month, Tax Notes expands on these concerns. This article is based on a paper that the author presented at ClM &apos;95 in HalifaxIntroductionOn a global basis, there are more investment opportunities in the mining industry today than at any other time in history. Countries in Central and South America, Eastern Europe, the CIS, Central Asia, and Asia are competing aggressively to attract investment to all sectors of their domestic mining industries. Today, the demand for investment dollars exceeds the amount of dollars that are available for investment in mining. It is not surprising, then, that the established mineral producing nations are witnessing a decline in spending on exploration and development on their home turf, and an increase in spending in developing countries. In the context of a developed country such as Canada, there are two manifestations of the problem of declining investment: (I) Foreign investors are allocating more of their capital budgets to new opportunities in developing countries; and (2) Canadian juniors and seniors are spending proportionately more abroad. This shift in global spending patterns is the source of some concern for the future of Canada&apos;s mining industry, particularly because it is widely believed that the current rate of discovery of ore reserves in this country is too low to replenish depleting reserves.""Government bashing"" has always been a popular pastime in Canada. Invariably, this pastime has focussed, at !east in part, on taxation. In view of the intense competition that Canada faces on the global mining scene, it is important that the role of taxation in the decision-making process be kept in perspective. This paper seeks to put the role of taxation into perspective."

Jan 1, 1995

By S. K. Schwartz

"This paper describes the general layout of the environmental monitoring scheme at Devco &apos;s No. 26 Colliery, including wall face ventilation, fan performance and methane drainage, and then goes on to discuss the sensors, the outstation layout, the surf ace control room and the protection of the system.IntroductionCape Breton coal mines have been pioneers in the use of the latest technology in mining coal on this continent. To mention just one example, continuous methane monitoring at the coal face was started in 1976 and the idea of automatically stopping the face conveyor during high gas levels using the face signalling system was conceived and developed by CBDC engineers.With the introduction of remote environmental monitoring, No. 26 Colliery will be the first underground coal mine in Canada and possibly in North America to have computer-based comprehensive environmental monitoring.Traditionally, surveillance of the mine environment has been based mainly on periodic checks by portable or hand-held monitors. Although this method proved adequate, it has some limitations, namely:1) restricted &apos;number of observations and samples;2) relatively long time between taking measurements and availability of results for assessment.With remote monitoring, the above limitations are overcome because (a) monitoring is continuous and (b) monitored data are updated quickly (typically 5-7 sec.). Remote monitoring also provides a centralized &apos;information center&apos; at the surface from where the entire mine environment can be monitored. Details of modes in which data can be displayed and features available at the location will be discussed later in the paper."

Jan 1, 1982

By P. J. Sylvester, D. H. C. Wilton, R. I. Wheeler, M. A. E. Huminick, D. Evans-Lamswood

"Abstract — Systematic characterization of the mineralogy of massive sulfide ore deposits can provide valuable insights into ore genesis and metallurgical processing that would not be apparent otherwise. We describe a method wherein (1) normative mineral abundances are calculated from whole-rock chemical assays using an algorithm, (2) the results are cast in block models, (3) the results are then verified with automated image analysis of a subset of samples prepared as grain mounts by backscattered electron imaging and X-ray mapping on a scanning electron microscope, and (4) those verified results are integrated with textural data determined by optical microscopy.The technique is applied to the magmatic Ni-Cu-Co sulfides of the Ovoid orebody, based on geochemical assays of 3175 whole-rock samples. Three principal ore zones are defined in the Ovoid. Type I ore occurs in the center of the deposit; it is magnetite-rich and pyrrhotite-poor with intermediate contents of pentlandite and chalcopyrite. Type II ore surrounds Type I ore and is pentlanditechalcopyrite- rich with intermediate contents of pyrrhotite and magnetite. Type III ore occurs at the base and along the outer periphery of the northern part of the orebody; it is pyrrhotite-rich and chalcopyrite- poor with an intermediate content of pentlandite, and a low-to-intermediate content of magnetite."

Jan 1, 2012

By L. W. Vollmer

Introduction During the past three years at least fifty strings of 9% nickel steel tubing have exhibited excellent resistance .to the variably severe corrosive conditions typical of many of the sweet condensate wells in Mississippi, Louisiana, and Texas. This experience, and the characteristically outstanding performance of other ?nickel alloy steels under hydrogen sulphide corrosive conditions, dictated the selection of 9% nickel steel tubing for the second well drilled in the sour condensate Pincher Creek field of southwestern Alberta. The damaging effects of the Pincher Creek reservoir fluids on well equipment had been manifested in the discovery well by the rapid and not yet fully understood failure of API Grade N-80 tubing, stainless steel wire lines, and alloy steel fishing tools. Two very unexpected failures in the 9% nickel steel tubing, after only six days of service in production tests, instigated an extensive and continuing investigation to ascertain the probable cause of failure. This discussion presents some of the results obtained thus far which cast a little light on the perplexing behaviour of steels in hydrogen sulphide environments in general, and in sour condensate wells in particular. History of Tubing Failures Walter Marr well No. 1, in which the 9% nickel steel tubing failures occurred, produces from the Madison lime at the depth interval approximately 12,200 to 12,750 feet. The gas-oil ratio is about 26,000 and the gas contains 10.2 per cent hydrogen sulphide and 6.3 per cent carbon dioxide by volume.

Jan 1, 1952

By Linda Hodgson

1. Introduction ?Northgate Minerals Corporation is a mid-tier gold and copper producer with mining operations, development projects and exploration properties in Canada and Australia. ?Kemess Mine is Northgate?s principal operation. Where in the world is Kemess? ?Kemess is located in north-central British Columbia,430 kilometres northwest of Prince George. ?The Kemess South complex consists of an open-pit mine, a 52,000 tonnes per day mill and various ancillary support facilities including maintenance shops and housing for Kemess&apos; 340 full-time employees.

May 1, 2010

By K. Spence

"The notion of “value” has always been a subjective and contentious issue. Indeed, value is in the eye of the beholder. There are as varied methods and practices for valuing property, as there are industries in which they are applied. For example, there is replacement value, insurance value, salvage value, appraised value, book value, and fair market value, to name a few, although in the mining industry, valuations usually refer to fair market value.In the Canadian mining industry, at present, there are no comprehensive regulations or guidelines that specify which approaches or methods are appropriate for use in the valuation of mineral projects. In January 1999, The Mining Standards Task Force of the Toronto Stock Exchange and the Ontario Securities Commission recommended that the Canadian Institute of Mining, Metallurgy and Petroleum (CIM) establish a committee to review and advise on approaches and methodologies for the valuation of mineral properties. Among the approaches to be considered are included the following: the discounted cash flow approach, the cost approach, the option pricing approach and the market comparables approach. In addition, methodologies differ depending on whether the project is at the exploration stage or the producing stage.The CIM Special Committee on the Valuation of Mineral Properties (CIMVal) expects that its final report will form the basis for a Canadian code or standard for the valuation of mineral properties."

Jan 1, 2002

By S. Kwon, J. W. Wilson

"In salt and potash mines, the time-dependent deformation mechanism should be clearly understood based on in situ measurements to predict the performance of a mining design. In this study, in situ deformation measurements from the Waste Isolation Pilot Plant (WIPP) and other salt and potash mines were used to determine the transition time from the primary to the secondary creep stage and to investigate the influence of adjacent excavations such as a nearby tunnel excavation, panel excavation and/or pillar extraction on rock deformation. IntroductionThe deformational behaviour of underground excavations in salt and potash mines is complex due to the time-dependency of the rocks. When the material properties are determined from laboratory tests, they should be carefully applied to in situ conditions, because in situ conditions are completely different from laboratory conditions. For instance, in situ deformation measurements show that the deformation rate decreases with time similar to those observed in the laboratory during the early stages. However, the rapid decrease of deformation rate does not come from the microscopic strain hardening effect observed in laboratory tests, but mainly from stress relief around the opening after its excavation (Baar, 1977). It is, therefore, recommended to undertake in situ measurements and use them to understand the deformation mechanism.Even though in situ measurements are widely accepted as important information for understanding the deformation mechanism of salt and potash (Barr, 1971; Kovari and Amstad, 1993), not many publications have focused on the fundamentals of data measurement, the application of the measured data, and the development of data analysis techniques. Recently, several new techniques for better understanding the deformation mechanism of rock salt have been developed that are based on in situ measurements. Kwon and Miller (1995) developed a new technique for describing the actual deformational behaviour of an underground excavation in rock salt. The migration of “zero strain boundary,” which represents a no movement boundary around an underground excavation, could be calculated by the technique developed by Kwon and Miller (1996). Kwon and Wilson (1997, 1998) applied neural network techniques to in situ deformation measurements to predict the deformational behaviour of the underground excavations at the Waste Isolation Pilot Plant (WIPP) located in the United States.In this study, in situ deformation measurementsfrom the WIPP site and other salt and potash mines in the United States were extensively analyzed to understand the deformation mechanism of the underground excavations in the rock mass."

Jan 1, 2002

By A. G. Spencer, A. D. Taylor

This paper discusses some of the advantages and problems associated with the selection of large unit equipment for a metallurgical plant. A given flowsheet and material balance for an iron ore concentrator is assumed. Then two plant designs are developed, one utilizing a number of smaller-size equipment units and one utilizing the largest available equipment units. The mechanical and electrical problems are discussed and a comparison of capital costs is made. Finally, brief consideration is given to a plant de-sign using units larger than those which are currently available.

Jan 1, 1968

By P. E. Cavanagh

Introduction A comprehensive study of the economics of processes for smelting iron ores has been made by the Ontario Research Foundation on behalf of the Ontario Research Commission. This survey has included investigations of all processes in commercial use, and proposed processes which are still in the experimental stage. The two main objects of this work were to discover (l) whether any known processes would be particularly suited to present and future Canadian conditions, and (2) whether any new process would be of assistance in solving the present scrap shortage in Canada. The future prospects of the Canadian iron smelting industry have changed radically in the past ten years. For nearly twenty years before 1939 no iron ore was mined in Canada. The ore used was imported, mainly from the United States and Newfoundland. The economics of iron blast-furnace smelting always force the location of blast furnaces near the source of coal for making high-grade metallurgical coke, and near the market for iron and steel, rather than near the iron ore. Blast-furnace installations in Canada are confined to the north shores of the Great Lakes with ready access to United States coal and ore and the major Canadian markets, and to Nova Scotia near the coalfields of that Province. This distribution of primary smelting capacity naturally results in relatively high prices for iron and steel in the West, the North, and in Quebec.

Jan 1, 1948

"4.1. IntroductionThis chapter reviews the geochemistry of the platinum-group elements (POE) in sulphur-poor silicate rocks, and the limited data on POE in silicate, oxide, sulphide, arsenide and sulpharsenide minerals. The earliest geochemical studies of POE in silicate rocks, minerals and meteorites were carried out mainly by Goldschmidt, the Noddacks and their co-workers, and are reviewed in Crocket (1969). These researchers established the siderophile character of the POE, emphasized the common association of the group with sulphides in ultramafic-mafic rocks and suggested that very low concentrations of POE are typical of sulphur-poor silicate rocks and minerals. Much of these data were for Pt and Pd only and are more than 50 years old. Because of the poor sensitivity typical of the available analytical methods, few reliable data were obtained on silicate rocks in these early studies. Surveys of POE geochemistry demonstrate that the data base for sulphur-poor silicate rocks is very restricted, although considerable highquality data for Pd and Ir have been accumulated (Wright and Fleischer 1965, Yushko-Zakharova eta/., 1967, Mertie 1969, Crocket 1969, 1979, Keays 1981).Two recent publications, Vol. 71, No. 7 (1976), of Economic Geology (An Issue Devoted to Platinum-Group Elements) and Vol. 17, Part 2 (1979), of The Canadian Mineralogist (Nickel-Sulphide and Platinum-Group-Element Deposits), are of special interest. These volumes are clear testimony to the impressive progress made in the last decade toward describing the mineralogical and geochemical aspects of POE ore deposits, but at the same time demonstrate the constraints in modelling POE ore genesis due to our meager knowledge of the. POE content and distribution among minerals in the source rocks of ultramafic and mafic magmas. It is clear that the phases hosting POE in mantle source rocks are poorly understood. Nevertheless, Naldrett and Duke (1980) have shown that the absolute and relative concentrations of POE in magmatic sulphide ores are related to the degree of partial melting of mantle peridotites, and subsequent processes of batch equilibration and fractional segregation of sulphides."

Jan 1, 1979

"2.1. General Considerations and Properties2.1.1. IntroductionOur present knowledge of the platinum-group elements (POE) is extensive, the reason being two-fold. The elements have many uses and, moreover, they exhibit extremely varied chemical behaviour, depending on their state of oxidation and chemical environment. The present chapter reviews a selected body of material which is of particular relevance to mineralogy and geochemistry.Comprehensive treatises on the POE include those by Mellor (1956-1957), Gmelin (1938-1957) and Pascal (1958). The inorganic chemistry, particularly coordination chemistry, has been dealt with in works by Griffith (1967), Hartley (1973) and Livingstone (1975), and the analytical chemistry by Walsh and Hausman (1963), Beamish (1966) and Beamish and Van Loon (1972, 1977). Darling (1973) and Savitsky (1978) have reviewed the metallurgical properties and applications of the metals. Goldberg and Helper (1968) have reviewed the thermochemistry and oxidation potentials of POE systems, and Wagman et at. (1969) have also provided selected values of their thermodynamic properties. The geochemistry of the POE has been reviewed by Yushko-Zakharova et at. (1967), Cousins (1973), Cabri (1974), and Naldrett and Duke (1980).Platinum was used briefly as a coinage metal in ImperialRussia. Otherwise, the principal early use for platinum and its alloys was in the fabrication of chemically resistant apparatus. Subsequently, a large part of platinum production was utilized for catalysts in the sulphuric acid and ammonia industries. Platinum has been replaced by vanadium pentoxide in the manufacture of sulphuric acid, but, in recent times, catalytic upgrading of petroleum and emission control systems for automobiles have opened further huge markets for the metal. All of the POE find uses either as reagents or catalysts in the synthesis of organic compounds, e.g., in the Wacker process, which uses palladium chloride to catalyze the production of acetaldehyde from ethylene. There are, of course, a large number of specialized uses for the elements, particularly in alloys, temperature measurement devices, cancer therapy and so on."

Jan 1, 1979