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By H. C. Fuller

A method was devised and developed by the Bureau of Mines for decomposing manganese sulfate at significantly lower temperature than that required by the conventional procedure of using heat alone. This technique, called the partial reduction method, effected decomposition at 700° to 800° C, as compared to 900° 1,000° C normally required. The process consisted of heating, in the absence of oxygen, a mixture of manganese sulfate and a controlled quantity of a reducing agent. The suitability of commercial-type equipment was tested in laboratory-size models of an externally heated rotary kiln, a r bbled muffle-hearth furnace, and a fluidized-bed reactor. The rabbled-hearth furnace gave the best results with the least operating difficulty produced a gas containing more than 80 percent SC and eliminated 96 percent of the sulfur when coal was used as the reductant. Sintering of the powdery decomposition product produced an agglomerate containing, in percent, 63.6 Mn and 0.4 S.

Jan 1, 1966

By N. S. Dalal, X. Shi, V. Vallyathan

"Correlated spectroscopic and cytotoxicity measurements were made on newly crushed silica to find whether the fracture-induced, silicon related (Si-0· or Si· type) free radicals play a direct role in the mechanism of hemolysis by silica particles. The free radical content of the silica particles was controlled through the radical decay, thermal annealing, and boiling processes, and was followed with electron spin resonance spectroscopy. Portions of the same sample were evaluated for their hemolytic potential, employing sheep erthyrocyte and optical absorption techniques. The results indicate little, if any, correlation between the amount of the silicon-based radicals and the hemolytic potential of the fresh dusts, but these or related radical sites might be contributors to silica cytoxicity and fibrogenicity via peroxidative pathways .INTRODUCTIONIn an earlier convnunication (1.) from our laboratory it was reported that mechanical crushing of coal and quartz under normal air atmosphere generates free rad;cals on the particle surfaces, and that these radicals decay with time, hence pointing to a higher toxicity of fresh dusts in relationship to pneumoconiosis and silicosis. More recently Fubin; et al.(2) have also reported the detection by electron spin resonance (ESR) of the formation of SiO· and Si·-type of radicals from quartz particles crushed under atmospheric conditions. In agreement with earlier ESR studies on single crystals of quartz crushed under high vacuum (10-10 torr) (3) and subsequent exposure to air (3), and to other gases (4), these radicals were identified (2) as being formed by the hemolytic cleavage of the Si-0-Si bonds and the reactions of the Si· and SiO· ,radical with atmosphere. Fubin; et al. (2) also suggested that these radicals might be involved in the mechanism of the fibrotic action by silica, either by transforming the particle surface into a selective oxidating agent or as an initiator of a sequence of reactions leading to fibrosis. Earlier Gabor and Anea (5) had reported that lipid peroxidation caused by free radicals on the silica surface might be involved in the red blood cell membrane damage. Thus far, however, no parallel cytotoxicity, fibrogenicity, and free radical studies on a given Quartz dust sample have been reported, except for some earlier work from our laboratory (1,6,7). We now present more recent results obtained from parallel cytotoxicity, fibrogenicity, and free radical measurements on a freshly made quartz dust. The dust’s free radical content was measured using ESR spectroscopy while its cytotoxicity poteni1al was estimated via hemolysis. Hemolysis was employed as the tox1c1ty test because it 1s a widely used method for estimating the potential of a dust for disrupting the cell membrane (8). The f1brotic potential was followed.by measuring the dust-induced lipid perox1dat1on. us1ng linole1c ac1d as a model lipid. As discussed below, the results obtained suggest new clues.to the mechanism of the Quartz-related cytotoxicity and fibrogenicity."

Jan 1, 1988

By James H. Russell

Alkalized alumina (an active form of sodium aluminate) has been considered as a sorbent for the removal of sulfur dioxide from industrial flue gases. Four rate equations, each based on a different mechanism, were compared with the results of thin-bed sorption tests. It was found that each equation agreed with the experimental results, within experimental variance, over most of the range of sorption studied. First-order rate equations were generally satisfactory in explaining both sorption and regeneration. It is concluded that the equations developed are adequate for the design of commercial fluidized beds for the sorption of SO2 from industrial flue gases and regeneration of the alkalized alumina.

Jan 1, 1970

Despite modest improvements in the performance of domestic interest rates and gross national product,1 fixed investment in domestic producers' durable equipment continued to weaken during the second quarter of 1982 and declined at a 12.8 percent annual rate compared with the first quarter.2 Large declines occurred during the second quarter in expenditures on many of the major mineral-consuming industries such as aircraft, computers, agricultural and construction machinery and mining and oil field equipment. These data appear to be consistent with the low level of business investment plans for 1982 reported in the DOC's Bureau of Economic Analysis survey of expenditures on new plant and equipment.3 Domestic and foreign industrial production and mineral industry production activities continued to decline in the most recent period because of weak demand conditions (Tables 1 and 2). The U.S. mining production index declined 7.7 percent between April and June as compared with 1.2 percent for total U.S. industrial production (Table 1).

Jan 1, 1982

By M. Carrales

This Bureau of Mines publication presents short-range projections of domestic liquid hydrocarbon production through 1980. Appraisal of future crude oil production was made by evaluating the relationship between primary and enhanced oil recovery and the total crude oil producing trends in each of the oil-producing areas of the United States. Future natural gas liquid production was generally estimated by projecting historical production. Estimates of production were prepared for each of the oil producing areas and summarized for the Petroleum Administration for Defense (PAD) districts and total United States. From 1975 to 1980, crude oil production for the conterminous United States is expected to decline from 7.8 to 6.4 million barrels of oil per day (BOPD), and it is expected to increase from 8.0 to 8.2 million BOPD for the total United States. However, these estimates do not include additional production expected from the Elk Hills field in California and the Yates field in Texas. If included, 1980 production for the conterminous United States would be 6.7 million BOPD and 8.4 million BOPD for the total United States.

Jan 1, 1977

By John E. Pahlman

The U.S. Bureau of Mines has continued its investigation of chemical additive drilling fluids that produce a zero surface charge (ZSC) on a rock to better define the boundary conditions of the phenomenon. Laboratory drilling tests were performed on Minnesota taconite, Tennessee marble, and Sioux Quartzite using diamond-impregnated coring bits or tungsten carbide spade bits. Drilling fluids were made from chemical additives such as inorganic salts, cationic surfactants, cationic polymers, acids, or nonionic polymers in either distilled, deionized water (DDIW), mine pond water, mine well water, or tap water. These additives were tested below, at, and above their respective ZSC concentrations. Penetration and bit life improvements obtained with ZSC concentration solutions ranged from 88 and 56 pct, respectively, to over 650 pct and over 400 pct, respectively, for the additives tested. Polyethylene oxide (PEO) was found to be the best additive for ZSC-controlled drilling because a continuous range of PEO solution concentrations produced the enhanced ZSC-controlled drilling performance.

Jan 1, 1989

By N. S. Dalal, X. Shi

"Electron spin resonance (ESR) spectroscopy has been employed to· examine the role of tetraperoxochromate( V) ions (Cro:-) and other Cr(V) species in the generation of hydroxyl (OH) radicals in the reaction of Cr(VI) with H2O 2 in biological media. In contrast to earlier suggestions, the present ESR studies using crystalline K3CrO8 as a source of Cro:- show that decomposition of Cro:- in water or in H2O 2 does not generate significant amounts of OH radicals. Addition of NADH to a solution containing Cro:- yields a Cr(V)-NADH complex, which readily reacts with H2O 2 to generate OH radicals. Similar results obtained from several other biological reductants, including vitamin B2 , indicate that a vacant coordination site on a Cr(V) complex facilitates its reaction with H2O 2 to generate ""OH radicals. We thus suggest that in biological media, reaction [3] instead of [1] or [2] is the major pathway for the OH radical generation: While the carcinogenic potential of Cr(Vl)-based compounds has been well established via epidemiologic and animal studies (1), the underlying biochemical mechanism is still not well understood (2). In a recent development, however, Kawanishi et al. (3) have reported that hydroxyl (OH)2 radicals might be the key species in the mechanism of Cr(VI) toxicity. As to the mechanism of the ""OH radical formation they suggest that Cr(VI) reacts with cellular hydrogen peroxide (H2O 2) to form the tetraperoxochromate(V) (Crog-) ions, which decompose to produce hydroxyl radicals. It was also suggested (3) that the ""OH radicals thus produced cause genotoxicity via DNA base modification and deoxyribose phosphate backbone alterations. More recently Aiyar et al. (4) reported the detection of OH radicals in the reaction of Cr(VI) with H2O 2 in biological media, including the reaction of ""OH radicals with deoxyguanosine to generate 8-hydroxydeoxyguanosine adducts, confirming that ""OH radicals could indeed play a significant role in the mechanism of Cr(VI) toxicity. However, the mechanism for the ""OH generation was not clarified, although the role of Crog- ions as possible precursors was mentioned, somewhat along the lines suggested by Kawanishi et al. (3). The possibility of the participation of Crog- in the ""OH generation has also been indicated by Sugiyama et al. (5), since they mention that vitamin B2 enhances the formation of""OH radicals in the reaction of Cr(VI) with H2O 2 because of the generation of Crog- in the reaction."

Jan 1, 1990

By V. F. Parry, W. S. Landers

"INTRODUCTION The primary object of this investigation was to determine changes in physical and chemical properties of subbituminous lump coal while in storage for 8 months in a typical residence and to demonstrate how this fuel may be stored without degradation or spontaneous combustion. The second object of the study was to determine how the stored coal performed in a hand-fired furnace operated under practical conditions.The investigation revealed that if care is exercised in placing sub-bituminous lump coal in a closed bin, no significant slacking or degrada¬tion occurs, no hazards arise, and over-all indicated efficiencies of about 65 to 69 percent can be obtained under practical,firing conditions that the average home owner can meet.Owing to the war emergency, much attention is being given to the proper storage of coal, and campaigns are being conducted to increase the quantity of coal being stored to relieve transportation and production overloads. Ordinarily, coal dealers do not recommend storage of subbituminous coal in homes owing to deterioration of the coal and to possible hazards from spontaneous combustion. This practice has grown from some troubles that have been experienced, which can be traced to improper preparation, improper bins, and poor technique in placing coal in a bin. There is no good reason why subbiturninous lump coal cannot be stored safely in homes."

Jun 1, 1944

By Stella Sigler

This publication contains analyses and related source data for 153 natural gas samples from 16 States. Of the total samples, 149 were collected during calendar year 1993. The remainder were collected earlier, but releases granting permission to publish were not received until 1993. None of the analyses have been previously published in annual reports. All samples were obtained and analyzed as part of U.S. Department of the Interior, U.S. Bureau of Mines investigations of the occurrences of helium in natural gases of countries with free market economies. This survey has been conducted since 1917. The analyses published herein were made by mass spectrometer and chromatograph.

Jan 1, 1994

By John B. Goodman

This report summarizes the work done by the Koppers Company, Incorporated, in cooperation with the Bureau of Mines on the commercial evaluation of the primary low-temperature tars produced from Texas lignite in the Rockdale, Tex., plant of the Aluminum Company of America in conjunction with the Texas Power and Light Company. The interest of the Bureau of Mines in this project is twofold. First, through its cooperative agreement with the Texas Power and Light Company the Bureau has assisted in the technical design and practical operation of the prototype, externally heated, entrained-state carbonizer for producing char for electric-power production and for primary low-temperature tar. Second, the first successful operation of the prototype carbonizers employing the Bureau of Mines-Parry process on lignitic coal in 1953-54 led to the production of large quantities of primary lignitic tar, concerning which too little was known or had heretofore been published in this country.

Jan 1, 1959

By John F. Papp

Based on a review of historical domestic and international chromium metal production capacity, production, consumption, trade, and trade literature, world annual chromium metal production capacity in 1995 was estimated to have been 38,300 metric tons, a drop from 43,500 tons in 1994. World chromium metal production and consumption were estimated, on average from 1984 through 1992, to have been 21,000 tons per year. U.S. consumption was estimated, on average over the same time period, to have been 6,200 tons per year. The major world chromium metal producers between 1984 and 1995 were China, France, Germany, Japan, Russia, United Kingdom, and United States. From 1984 through 1992, world trade averaged 8,400 tons per year. Germany and the United States accounted for over 75 percent of imports on average during the same time period. U.S. chromium metal import value rose from under $1 per kg before 1964 to over $6 per kg in 1993. Over the same time period, prices rose from about $4 per kg to about $10 per kg. Chemical specifications have become more stringent. Detailed chromium metal trade, prices, value, chromium metal chemical specification, and production capacity by country are reported. A shift in trade patterns was anticipated as Japan exits production and displaces Germany as the second largest importer and as Russia increases its role in world trade.

Jan 1, 1995

By R. J. Kuczynski

The U.S. Bureau of Mines operated a 2,000-g (4.4-lb) batch process development unit for recovering platinum-group metals (PGM) from automobile catalysts. Virgin monolith, used pellet, and used monolith catalyst samples were tested. Leaching twice with 1-pct sodium cyanide (NaCN) solution at 1600 C for 1 h dissolved more than 95 pct of the PGM from virgin catalysts and more than 90 pct from used pellet catalysts. More than 85 pct of the PGM was dissolved from used monolith catalysts when a third autoclave step was added. Solid PGM concentrates containing more than 99.8 pct of the dissolved PGM and analyzing greater than 70 pct PGM were recovered by heating the pregnant leach solutions from virgin catalysts to 2500 C and used catalyst to 2750 C for 1 h. The solution after heating contained less than 0.2 ppm. total cyanide. The virgin residues passed the EPA Extraction Procedure Toxicity Test (EP Tox Test), the EPA Toxicity Characteristic Leaching Procedure (TCLP), and the California Waste Extraction Test (WET) for all elements except Ba. Adding sodium sulfate (Na2S04) to the virgin leach residues reduced the amount of Ba dissolved to an acceptable level. The used leach residues passed the EP Tox Test for all elements but failed the WET and TCLP for Pb.

Jan 1, 2010

By Jaan Kiusalaas

This report is a self-contained User Manual for a computer program called SPASID -- Subsidence Prediction and System Identification. The program has two primary functions: (i) Precalculation of ground movements due to underground mining operations using the influence function method; (ii) Computation of influence function and site parameters from measured displacements. SPASID is written in FORTRAN and consists of four modules: (i) Preprocessor Module that prepares and maintains surface and mine data bases; (ii) Subsidence Computation Module that predicts movements of the surface; (iii) System Identification Module which is used to calculate the optimal influence function parameters, and (iv) Postprocessor Module for generating graphic displays of subsidence data. The last module is somewhat machine dependent but has internal documentation to indicate potential changes. All of the modules may be run in either batch or interactive mode. The manual does not assume previous knowledge of the influence function method or programming competence.

Jan 1, 1983

By G. St. J. Perrott, G. W. Jones

"In cooperation with The Edison Electric Illuminating Co. of Boston, Mass., a survey was conducted in 1929 and 1930 by the United States Bureau of Mines to determine the general hazards of combustible gases and vapors in manholes and other underground openings owned by this company. The territory served approximates 650 square miles and includes 46 cities and towns. The transmission and distribution systems are on overhead construction and underground wires and cables run in underground conduits and manholes. There are 17,000 manholes on the system, and also an area in Boston proper served by the Edison tube system. These conduits and manholes are laid in various types of streets from the most modern type of cement roadbed to the older type of loose macadam. The conditions as found could be considered as typical of any public utility in the electric-light and power field. The survey extended over a period of about a year beginning in June, 1929, and ending in July, 1930, and during this time 1,765 different manholes were tested and a total of 4,068 tests were made.Previous to starting the actual survey, one of the writers, G. W. Jones, spent considerable time in Boston determining the best methods of practical· test procedure. In this work cooperation was given by John Campbell, superintendent, special service department, who for a number of years has been making a study of explosions in underground street areas and preventive measures in Boston and various cities.After this preliminary investigation the tests were continued by employees of the Edisun Company. Copies of all records of tests were forwarded to the United States Bureau of Mines Pittsburgh Experiment Station so that the writers were in close touch with the progress of the survey, and changes could be made in the test procedure whenever deemed necessary."

May 1, 1931

By J. P. Walsted

The lack of an iron-smelting industry in the Pacific Northwest places the ferrous metals industries under an economic handicap. No iron-smelting enterprises, now dormant, had been operated successfully. Iron made at both of hoes installations proved to be satisfactory for normal pig-iron uses. Electric power and reductants acre available in the area. Power from the dames now completed and. those being constructed insures present and future needs for basic industries. Subbituminous coal, close to the main supply of iron ore, insures ample reluctant for all smelting requirements.

Jan 1, 1954

By H. D. Pallister

A review of? reports and literature on the pyrite deposits at Pyriton, Ala., indicated that a large tonnage of pyrite, some of which contained a small amount of copper, had been mined and shipped to fertilizer plants throughout the South. The information contained in this literature tended to demonstrate that the ore occurred in separate lenses of greater or less extent and of varying thickness and richness in pyrite as well as in copper. The outcrop being parallel with the Atlantic Coastline Railroad and just south of it makes the deposits readily accessible for shipment. Slopes could be sunk as they were in the past in the ore body if it were of sufficient grade and thickness, and the ore could be hoisted up the slope and milled close to the slope mouth with an ample supply of water from Talladega Creek, which follows the outcrop closely.

Jan 1, 1949

By John C. Machisak

The Nation's mining and quarrying industries have again met the annual challenge to their ingenuity--that of reducing disabling work injuries among their employees. The effectiveness of management in facing this problem and in meeting this responsibility is evident from the results of the 1961 National Safety Competition. Three hundred ninety-three or 45.3 percent of the mines and quarries participating in the competition established a new record number of participants operating throughout the competition year without a disabling work injury. Another record established in the 1961 contest was the number of participants (868) enrolled in the competition. This annual safety competition was begun in 1925 and is conducted by the Bureau of Mines, U.S. Department of the Interior. It provides for six bronze Sentinels of safety trophies which are awarded each year to the winning participant in each group. Since its inception, the competition has exerted a strong influence in the field of safety promotion. The statistical record of its accomplishments over the years gives strong support to the theory that well-organized and well- administered safety programs are effective tools to be used to reduce the number of disabling work injuries. It stimulates and holds the interest of employees and management in accident prevention. Because of this, mines and quarries participating in the contest have a more favorable safety record than those operations not enrolled.

Jan 1, 1963

By E. J. Lintner

This paper is one of a series being prepared by the Bureau of Mines describing; gypsum mining and crushing methods and costs at various operations throughout the, United States. These papers are designed to dissemminate technical information regarding methods used. The cost tabulations represent local operating expenditures only and not total production costs. It is recognized that publication of total production costs may in many instances cause embarrassment to the individual operator as well as to the industry as a whole; on the other hand, operating costs are essential to the technical discussion and. study of the methods employed. The attention of the reader is specifically called to this differentiation in order that no misunderstanding of the scope of the cost tabulation shall ensue. The following report deals specifically with the mining and primary crushing methods employed at the plant of the Ebsary Gypsum Co., Inc., Wheatland, Monroe County, N. Y. This company is capable of maintaining a maximum yearly production of 220,000 tons of crushed gypsum, thereby ranking as one of the largest gypsum operators of the State. The methods and practices employed typify the standard methods followed by gypsum producers in western Now York State, The bed of gypsum mined lies only 35 feet beneath the surface and is above average thickness for this vicinity.

Jan 1, 1937

By Kevin Ashley

Because toxicities may differ for Cr(VI) compounds of varying solubility, some countries and organizations have promulgated different occupational exposure limits (OELs) for soluble and insoluble hexavalent chromium (Cr(VI)) compounds, and analytical methods are needed to determine these species in workplace air samples. To address this need, international standard methods ASTM D6832 and ISO 16740 have been published that describe sequential extraction techniques for soluble and insoluble Cr(VI) in samples collected from occupational settings. However, no published performance data were previously available for these Cr(VI) sequential extraction procedures. In this work, the sequential extraction methods outlined in the relevant international standards were investigated. The procedures tested involved the use of either deionized water or an ammonium sulfate/ ammonium hydroxide buffer solution to target soluble Cr(VI) species. This was followed by extraction in a sodium carbonate/sodium hydroxide buffer solution to dissolve insoluble Cr(VI) compounds. Three-step sequential extraction with (1) water, (2) sulfate buffer and (3) carbonate buffer was also investigated. Sequential extractions were carried out on spiked samples of soluble, sparingly soluble and insoluble Cr(VI) compounds, and analyses were then generally carried out by using the diphenylcarbazide method. Similar experiments were performed on paint pigment samples and on airborne particulate ?lter samples collected from stainless steel welding. Potential interferences from soluble and insoluble Cr(III) compounds, as well as from Fe(II), were investigated. Interferences from Cr(III) species were generally absent, while the presence of Fe(II) resulted in low Cr(VI) recoveries. Two-step sequential extraction of spiked samples with (?rst) either water or sulfate buffer, and then carbonate buffer, yielded quantitative recoveries of soluble Cr(VI) and insoluble Cr(VI), respectively. Three-step sequential extraction gave excessively high recoveries of soluble Cr(VI), low recoveries of sparingly soluble Cr(VI), and quantitative recoveries of insoluble Cr(VI). Experiments on paint pigment samples using two-step extraction with water and carbonate buffer yielded varying percentages of relative fractions of soluble and insoluble Cr(VI). Sequential extractions of stainless steel welding fume air ?lter samples demonstrated the predominance of soluble Cr(VI) compounds in such samples. The performance data obtained in this work support the Cr(VI) sequential extraction procedures described in the international standards.

Jan 1, 2009

By Donald P. Schlick

Respirable dust provisions of the Federal Coal Mine Health and Safety Act of 1969 are designed to protect the most important resource of the coal mining industry--its workers. The Act imposes two respirable dust standards of 3.0 milligrams per cubic meter of air after June 30, 1970; and 2.0 milligrams per cubic meter of air after December 30, 1972. Under Federal regulations, each operator is required to carry out a dust sampling program established by the Secretary of the Interior and the Secretary of Health, Education, and Welfare, This program features the sampling of "high risk" face workers to establish that the exposure of each miner is below the dust standard, Mining sect ions, continuously in compliance with the regulations, may sample at less frequent intervals. In addition to requiring the mining company to take respirable dust samples, the Bureau of Mines will perform in-depth dust inspections twice a year, as well as frequent "spot inspections." The Bureau has established a semiautomatic computerized operation capable of processing over 1 million samples per year. This facility will be linked to various Bureau offices by a telecommunications system to provide automatic data printouts within hours after samples have been weighed.

Jan 1, 1970