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By Gary L. Hundley

The Bureau of Mines has devised and demonstrated an ammoniacal sulfate leach process for recovering nickel and cobalt from low-grade domestic laterites. Solvent extraction of cobalt, one of the process steps, requires the reduction of hexammine complexes of C03+ to C02+ in an ammo-niacal leach solution. Previously, reduction was accomplished using cobalt metal shot in a column. This report presents experimental results and an economic evaluation comparing two alternate techniques with the shot column: (1) an electrolytic reduction cell with an extended surface area cathode and (2) direct electrowinning from purified leach solution using a cell with a fluid bed cathode. The second alternative eliminates the conventional solvent extraction-electrowinning steps. The costs of the three methods, based on the requirements of a pro-posed commercial-sized plant, including all unit operations, were deter-mined by the Bureau's process evaluation group. The operating costs for the shot column, $1.19/kg Co, and for electrolytic reduction, $1.20/kg, are essentially the same, but the cost of direct electrowinning, $3.77/ kg Co, would eliminate this method as a practical alternative. The cap-ital cost of approximately $14.4 million for reduction in a shot column is much higher than the approximately $4.4 million for electroreduction.

Jan 1, 1985

By A. M. Evans

"INTRODUCTION Exploration of the Iron Mountain and Bader iron-ore deposits in Llano County and the Gamble deposit in Mason County, Texas, was begun by the Bureau of Mines in January and completed in May 1944. The deposits had been examined by A. B. Needham, district engineer of the Bureau, in November 1942. Detailed geophysical studies by the gravity method as well as with a dip needle were made by the Bureau of Economic Geology 3/ of the University of Texas and the Federal Geological Survey. 4/ACKNOWLEDGMENTSIn the program of exploration of mineral deposits, the Bureau of Mines has as its primary objective the more effective utilization of our mineral resources to the end that they make the greatest possible contribution to national security and economy., It is the policy of the Bureau to publish the facts developed by each exploration project as soon as practicable after its completion. The Mining Branch, Lowell B. Moon, chief, conducts preliminary examinations, performs the actual exploratory work, and prepares the final report. The Metallurgical Branch, R. G. Knickerbocker, chief, analyzes samples and performs beneficiation tests."

Apr 1, 1947

By Raymond B. Ladoo

The uses for which ground talcs are suited closely depend upon their physical and chemical properties , but , in spite of this fact , little scientific investigation has been made in order to devise quick and accurate tests for the determination of these properties . The chemical properties of talc are inherent and may not be altered or modified except by selective mining or by chemical processes not practical in the present status of the industry . However , the determination of chemical properties is not so important , for most uses , as of physical properties , although sometimes certain chemical characteristics are perhaps unduly insisted upon by chemists in some industries . Physical properties are dependent both upon mineralogical characteristics and upon methods of grinding and sizing and may thus be partly changed or modified by changes in practice . There is so little known of the chemistry and physics of the various processes in which talc is used that the purchase and sale of talc is governed more by rule- of- thumb methods dependent upon individual opinion and often , prejudice , than by accurate , standard tests . This not only causes unwarranted price fluctuations , but injures both the producing and consuming industries by creating false ideas of the suitability of talc for various uses . It thus seems important that present tests be standardized and made uniform for the whole industry , and that new tests devised to fill the existing gaps .

Jul 1, 1920

By Lewis A. Smith

This circular presents a summary of the domestic chromium industry, and discusses the salient features of the world situation , reflecting the literature of the subject . The United States Bureau of Mines has in its files additional detailed information on many subjects briefly discussed in this paper and desires to assist the industries and the public by giving further data in response to individual inquiries . It will welcome comment and criticism and any contributions that would assist in making future editions of this circular more accurate . Unlike most common metals , chromium is rarely marketed as a pure metal . The chromium industry deals mainly with chromite , the principal ore of chromium , and with ferrochromium , the basic alloy in which chromium enters the metallurgical industry.

Apr 1, 1932

By R. V. Higgins

The, large volumes of low A. P. I. gravity oil that will remain in many shallow fields of California when such oils no longer can be recovered profitably by pumping are important potential sources of oil when ways and means are found to remove them from the reservoir sands. Estimated ultimate oil recoveries in many of the "low-gravity fields" of the San Joaquin Valley in California indicate that less than 25 percent (on the average) of the original oil will be recovered. These oils have viscosities of 1,000 or more centipoises at reservoir temperatures and, because of their high viscosity and low intensity of the reservoir pressure, the quantities that will be retained in the sands ultimately are so large and their recovery is such a challenge to petroleum engineers that the Bureau of Mines has made the study of their possible recovery one of its major projects. The fact that a slight increase of temperature materially reduces the viscosity of low A. P. I. gravity oils has 'prompted the use of various means for increasing the temperature of the oil in the reservoir sands and hence the rate of flow and Completeness of recovery of the oil. Hot oil, hot water, heated air, and natural gas, steam, super-heated steam, and the products of combustion have been circulated in wells to raise the temperature of the oil it the sands; electric heaters have been installed in wells, and butane and air have been intermittently exploded and the flames propagated through the tubing to the "pay" zones. None of the methods, however, have been entirely satisfactory for the recovery of large quantities of oil.

Jan 1, 1949

By A. J. Barry

This report presents observations made by Bureau engineers regarding hydraulic-powered roof supports that are currently being used or have been used on nearly all operating longwalls in the United States, A comparative summary of specifications for various types of powered supports with a brief description of the mine conditions has been compiled to enable mining engineers and mine operators to readily evaluate the differences in design data. Some of the support data furnished in the field may vary from those listed in manufacturers' brochures because of the trend to customize various support components to meet specific mine conditions. A method of estimating support requirements for different assumed operating conditions is presented. Similar computations for specific mine conditions may be used to make preliminary estimates of support requirements.

Jan 1, 1969

By E. G. Baglin

The Bureau of Mines devised a procedure for selectively extracting platinum-group metals (PGM) and gold from Stillwater Complex flotation concentrate. The Stillwater Complex is the only major U.S. PGM resource. Development of a suitable extraction technique will contribute to its exploitation. The concentrate was roasted at 1,050° C to convert host base-metal sulfides to oxides and the PGM from sulfide minerals to their elemental states. The roasted concentrate was preleached with dilute sulfuric acid to remove easily soluble gangue minerals. After pre-leaching, the concentrate was slurried with 6M HCI and leached at ambient temperature and pressure with a strong-oxidizing agent. Hydrogen peroxide, chlorine, sodium hypochlorite, nitric acid, and a persulfate salt were the oxidants investigated. The two-stage leaching scheme ex-tracted up to 97 pct of the platinum, 92 pct of the palladium, and 99 pct of the gold from the roasted concentrate. The base metals were not solubilized and reported to the residue. No attempt was made to devise a procedure to recover the copper and nickel because they comprise less than 5 pct of the value of the concentrate. Viable techniques for recovering the precious metals from the pregnant solution were sulfide precipitation, cementation with nickel, or adsorption on activated carbon.

Jan 1, 1985

By V. T. Dow

In April 1957 the Bureau of Mines instituted a reconnaissance of titanium-and zirconium-bearing heavy sandstone deposits in the Four-State area of Utah, Wyoming, New Mexico, and Colorado. This report summarizes the study. Eighty-two deposits or groups of deposits, containing an estimated 27,920,000 tons of titaniferous sandstone, were examined in the Four-State area; 16 in southern Utah, 19 in Wyoming, 33 in New Mexico, and 14 in southwestern Colorado. The 16 deposits examined in Utah contain an estimated 1,043,000 tons with an average grade of 17.98 percent TiO2, 5.67 percent ZrO2, 20.98 percent Fe, and 0.09 percent equivalent Th02. The 19 deposits investigated in Wyoming are estimated to contain 21,873,000 tons of titaniferous sandstone having a weighted grade of 5.22 percent 702, 0.55 percent ZrO2, 24.8 percent Fe, and 0.01 percent equivalent Th02.

Jan 1, 1961

By Lee M. Manna

This report summarizes the program to design, fabricate, install and preliminary test a pneumatic braking system for 10-ton mine haulage cars. Major arrangement drawings are reproduced, pneumatic schematics, parts list and actual developed costs. Recommendations as to system improvements are made.

Jan 1, 1977

By Ellis S. Hertzog

The material published in this report is part of a special study of some of the chemical and physical properties of Alabama coals. The complete study included friability and grindability determinations, high and low temperature assay distillation tests, and ash fusion-temperature determinations. Proximate and ultimate analyses and. calorific values of the coal samples also were obtained. This paper is concerned only with grindabilities, although proximate analyses have been included to give a better picture of the problem as a whole. The growing interest in grindabilities of coals is a result of the increase in use of pulverized fuel in REscent years. The tenative ball-mill grindability method D409-35T4/was used in making all the determinations. The method of sampling and the technic of the testing procedure is described in Considerable detail in this report because the procedure was established quite recently. The ball-Mill grindability index is a measure of the ease with which coal may be ground, which may be an important factor in estimating pulverizing costs. Up to the present time few data on the grindability of Alabama coals have been published. The data in this paper show that the Warrior and Cahaba fields exhibit a wide range of grindability in their coals. The mines tested are well distributed throughout the productive areas of these fields, and it is possible to make rough estimates of the grindabilities of coals not listed in this report from the data given for mines situated in the same vicinity. ACKNOWLEDGMENTS This study was conducted at the Southern Experiment Station of the Bureau of Mines in cooperation with the University of Alabama. The Alabama liming Institute was of great assistance in furthering the investigation, and the work was undertaken largely as a result of its request that the Bureau of Mines should make certain studies of Alabama coals. Grateful acknowledgments

Jan 1, 1938

By Lloyd Williams

1. The investigation shows that the Sewanee bed is the only bed of major importance in Marion County, 97 percent of the coal mined in the county having come from this bed. There are coal reserves in minor quantity in the Battle Creek bed, and production from this bed depends on a few small truck mines. The Richland bed, or Lower Sewanee, has been mined in the past, but no coal has been produced from it in late years. There are no production records of any other beds in the county, although same coal has been produced from them. 2. Known measured and indicated reserves in all beds, based on a minimum thickness of 14 inches and on 1,800 tons per acre-foot of coal in place, are estimated to be 61 million short tons as of January 1, 1953. Of this total, 55 million short tons is in beds 28 inches and more thick. Areas in each bed were omitted from the estimate where available data relative to the bed characteristics are too meager to permit making an estimate that conforms with the definitions of measured and indicated coal adopted for this study. Should future drilling or development prove reserves in these areas, such reserves should be added to the total estimated reserves.

Jan 1, 1955

By John W. Kopp

Stemming is used in blasting operations to help contain explosive gases as long as possible. Stemming can reduce airblast, improve fragmentation, and reduce the chances of hot explosive gases igniting methane and dust explosions in underground mines. Stemming is required in underground coal mines but is generally not used in underground metal and nonmetal mines. Some underground metal and nonmetal mines are classified as gassy and can require special blasting procedures such as the use of stemming to minsure the safety of miners. The types and amounts of stemming material that are desirable in underground metal and nonmetal mine blasting to ensure good or improved fragmentation while containing the hot gases are largely unknown. This Bureau of Mines research examined the effectiveness of differing lengths of stemming by measuring stemming ejection times as related to burden movement. With properly stemmed blasts, stemming is contained until some burden movement has occurred. Test blasts at two surface limestone quarries were evaluated using high-speed photography. For the conditions of these tests, a stemming length of at least 26 charge diameters was found to prevent premature stemming ejection. In tests with stemming lengths of 16 charge diameters, the stemming was effective but there was early venting of hot gases through fractures in the rock. Further testing with other rock types, hole diameters, explosive types, and stemming materials as they affect incendivity is recommended.

Jan 1, 1987

By Dennis A. Hansen

As part of a U.S. Bureau of Mines program to develop a more continuous titanium metal extraction process that uses domestic resources, a study was made to determine the extraction of titanium (Ti) and iron (Fe) from New York rock ilmenite using fluosilicic acid (H2SiF6). The effects of leach temperature, acid concentration, and particle size were investigated for the rate at which Ti and Fe are extracted from the ilmenite. Within the leach time studied, the extraction data fit a shrinking-core model; the rate-controlling step was diffusion of H2SiF6 through an ash layer resulting from a heterogeneous leaching reaction. The rate is linearly dependent on the H2SiF6 concentration and is inversely proportional to the square of the particle diameter. Using 2.6M H2SiF6 at 85°C, 49% of the Ti and 53% of the Fe in 44-to 74-µm New York rock ilmenite were extracted in 3 h.

Jan 1, 2010

By T. E. Swigart, C. E. Beecher

The Federal Government, as the largest lessor of oil and gas lands in the United States, is vitally interested in the conservation of those resources. This manual has been prepared at the direction of the Secretary of the Interior to call the attention of lessees of public oil and gas lands to the most common oil and gas field wastes and the best methods of preventing them; to outline the policies of the Interior Department on field operations; and to give information as to how the "Operating Regulations" of the department will be interpreted by the Bureau of Mines. The oil industry has progressed steadily. Present operating methods are much more efficient-and less wasteful-than those of a few years ago; moreover, the art of producing oil and gas is continually advancing. Public interest requires that improved methods, which will result in obtaining the greatest possible amounts of oil and gas from the natural deposits, shall be developed and used. Part I of this manual points out types of oil and gas wastes and suggests, in detail or by reference, the most practical and effective methods in current practice for stopping these wastes. Throughout Part I the department's operating policy is given, with interpretations of the "Operating Regulations" for enforcing every practical measure of conservation. Part II comprises the revised "Operating Regula-tions" which supersede all previous regulations and will govern future operations on public lands; it will be found in the pocket in the back cover of this bulletin.

Jan 1, 1923

By C. F. Winquist

The Bureau of Mines is engaged in research to evaluate the effects of cutter bit wear at coal mine faces. This paper addresses one element of conical bit wear, bit rotation. A discussion on mounting configura-tion and bit forces and their effects on rotation is presented. The effects on rotation and bit forces of bit attack angle, cutting depth, and skew are determined for two types of conical bits during linear cutting of sandstone-inclusive rock. The results indicate that a 10° negative skew angle and 35° attack angle produce the maximum rotation of 17.5° for each foot of cutting. Data on bit rotation and bit forces are presented in an appendix.

Jan 1, 1985

By C. P. Mabie

This report summarizes studies by the Bureau of Mines in developing a simple method for estimating the phosphorus pentoxide (P205) content of finely ground sedimentary phosphate ores and beneficiated products. The method used involved leaching, filtration, and precipitation. The Bureau found that measurement of the volume of ammonium phosphomolybdate precipitate obtained from samples containing 16.8 to 37.7 percent P205 and the use of an appropriate calibration curve permitted estimates of percentage of P205 content accurate within ± 1.1 to ± 2.6 percent, respectively, at the 95-percent confidence limits. Incidental to mineral dressing and petrographic investigations of western phosphate ores in 1959, the Bureau of Mines undertook development of a simple process-control method for rapid on-the-spot evaluation of phosphate-mineral recovery. Because of the fine-grained and obscure character of western phosphate ores, chemical, rather than microscopic or petrographic, techniques were investigated. The described method involves acid decomposition of the ore or product, filtration, addition of ammonium molybdate reagent to the filtrate, and centrifuging and measuring the volume of yellow ammonium phosphomolybdate precipitate produced.

Jan 1, 1961

By H. B. Brunot

On April 26, 1949, the Bureau first approved a machine designed to replace the cycle of cutting, blasting, and loading coal by a single operation. This machine took the coal directly from the solid face and delivered it to transportation equipment. By January 1, 1955, 30 approvals for designs of machines of this type had been granted by the Bureau. In the main, this paper describes briefly the action of the various designs approved as permissible. In addition, the approval number, the date of approval, the voltage of the power supply, the number and character of the explosion-proof accessory parts, the size of the trailing cable, and the overcurrent protection at the outby end of the trailing cable are given for each design. Since no similar information has been published by the Bureau, it is hoped the material in this paper will be valuable in giving the mining public an organized look at the various machines of this nature that have been approved as permissible by the Bureau.

Jan 1, 1956

By R. V. Ramani, W. Miola

"A relationship exists between the quartz contents in the underground coal nine airborne dust samples and those in the coal and host rocks that are mined [17, 18, 19] The prescribed method for quartz analysis in respirable airborne coal dust samples is the MSHA P-7 method. Accurate quartz analysis procedures are needed for bulk samples in order to predict the potential quartz content in airborne nine dust, which in turn will aid the design of quartz dust control procedures during mining. thereby reducing the airborne quartz dust in underground atmospheres. The requirements of this method are that the amount of quartz is the sample be less than 250ug, and the total sample weight less than 2,500 ug. Unlike with airborne dust samples, there are no limitations to the available mass of bulk samples. However, these are no standard procedures for the preparation of bulk samples for scanning or prescribed methods for quartz analysis. The NIOSH and MSHA methods are certified for roped* dust and the acceptance of these methods for bulk samples assumes that the bulk samples will be reduced to the conditions specified for respirable dust samples. An alternative method is X-ray diffraction, which provides higher average quartz values than those obtained from P-7 method for the same samples.An investigation was carried out to determine the optimal procedure for preparing the bulk samples for the IR and XRD analyses. In this paper, the investigations on the effects of calibration, particle sizes, matrix composition, interferrous, and behavior of the filter substances on IR, XRD and FTIR results are presented. The error introduced by the presence of kaolinite and a new sample asking procedure to reduce it are discussed. The problems experienced with conventional sample holders for scanning were eliminated with the design and development of a new hollow sample holder. Quantitative comparison of quartz determinations by IR, XRD and MR methods on coal, roof and floor rocks, and airborne dust samples are presented. The important factors affecting the results of quartz analysis methods are: 1) bulk sample preparation for obtaining representative and homogeneous analysis samples: 2) particle size distributions of the analysis samples and calibration standards; 3) qualitative matrix composition of the analysis sample; 4) matching calibration standards to analysis sample; 5) substrates for sample deposition during analysis sample preparation; 6) procedures for analysis sample mounting; 7) selection of proper portions of she response profile for insanity measurement; and 8) interferences of spurious phases with the critical analyses. The recommendations of this study are important to enable comparisons and interpretations of analysis and research results."

Nov 1, 1995

By J. W. Thompson

ORES PROCESS OF ORE CONCENTRATION-PATENTABILITY. The patent issued to Sulman, Pickard, and Ballot, November 6, 1905, and assigned to Minerals Separation and Minerals Separation American Syndicate, for new and useful improvements in ore concen- tration, its object being to separate metalliferous matter from gangue by means of oils and fatty acids that have a preferential affinity for such metalliferous matter, the principal feature of which is "agitat- ing the mixture to cause the oil-coated mineral to form a froth," was clearly anticipated by other patents, and each step in the process described in the Sulman, Pickard, and Ballot patent is fully described in more than one of the prior patents, with the single exception of the reduced quantity of oil used; but the discovery that the small fraction of oil is sufficient to produce flotation of the metalliferous matter can not be made by itself or in combination, the subject of a patent. Hyde v. Minerals Separation, 214 Fed., 100, p. 109, May, 1914. ACTION FOR CONVERSION OF MINERALS. In an action by the grantor of a certain mine and mining property against his grantee to recover damages for the conversion of a quantity of ore that the grantor before the conveyance had mined and extracted from the mine and placed on the dump near the mine, the plaintiff is not entitled to recover where it appears that at the time the ore was placed on the dump the mine was owned and operated by a mining company and that at the time the ore was taken out of the mine the company had no intention of doing anything with it but simply deposited it on the dump as waste and to give an opportunity to develop the mine and get better ore to send to the smelter, and that

Jan 1, 1915

By Noel N. Moebs

This report summarizes a Bureau of Mines study on the use of geotechnology to identify and reduce ground control hazards at slate quarry operations in eastern Pennsylvania. The major ground control hazard is falling rock, attributed to weathered bedding plane faults, which weaken quarry highwalls. It was demonstrated that these faults can be detected outside of the quarry perimeter using surface resistivity measurements. Falls of ice from quarry highwalls constitute a second major hazard, which requires water diversion as a basic control method. In situ stresses seemingly cause only minor problems in slate extraction although they could interact with developed stresses and lead to failure of barriers between quarries. Pull tests showed that rockbolts anchor firmly in slate and should prove effective in securing loose rock.

Jan 1, 1986