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By Alla D. Mah

Heat content and entropy data at high temperatures were obtained for cuprous oxide (Cu2O) and cupric oxide (CuO). Experimental results and smooth values are reported. Equations are given for heat content increments and heat capacities above 2980 K. Low-temperature heat capacity data were obtained for cuprous oxide. Evaluation of the 2980 K entropy gave, S°298.15(Cu2O) = 22.08 ± 0.10 cal/deg mole. Heat of formation values were determined for cuprous and cupric oxides. The values are: AH°298.15(Cu2O) = -40,830 ± 300 cal/mole, and AH°298.15(CuO) = -37,230 ± 150 cal/mole.

Jan 1, 1967

By Oliver Bowles

[Simple systematic accounting that adequately records all transactions has long been regarded as essential to the welfare of any business enterprise. Some of the defects that detract from the prosperity of the slate industry are attributable to a lack of effectiveness in cost keeping. This condition has promoted the United States Bureau of Mines to make a detailed study of accounting methods for the slate industry, and to present for consideration a system of accounts, which it is believe would enable the industry to attain more economical management and operation if accepted by a fair proportion of its important units. The method of accounting presented herein has been worked out with the assistance of leading slate producers and the recommendations are tentative and are submitted in this form as a means of developing constructive criticism. Believing that cooperative effort in this, as in many ether problems will bring the most enduring benefits to the industry as a whole, the writer urges that the cost earnest consideration be given to this vital problem now facing the slate industry.]

Jan 1, 1929

By W. R. Crane

Subsidence and ground movement are phenomena common to and attendant upon practically all large-scale mining operations, and under certain conditions may occur in all workings, large and small. The interpretation of the cause of failure in rock masses involves a study of the nature of plants of weakness common to all rocks. The dominating planes of weakness can readily be determined by observation in any given locality, and in order of importance in the study of subsidence are (1) faulting planes, (2) bedding planes, (3) joint planes, and (4) other prominent planes of weakness such as thrust and shear planes and contacts. This report has mainly to do with the third item, joint planes, and is a preliminary statement which t to be followed by a more complete report in bulletin form.

Jan 1, 1931

By Frank E. Cash, John A. Johnson

"INTRODUCTION During the 6-year period, 1940-45, 481,485,000 gross tons of iron ore was shipped from the Minnesota, Michigan, and Wisconsin mines of the Lake Superior district. Approximately 367,000,000 tons, or 76 percent, of this ore was shipped from open-cut mines. The production of this large tonnage of iron ore from the open-cut mines of the Lake Superior district during the recent war was an outstanding achievement. It is questionable whether this record-breaking tonnage of iron ore, vitally needed for the successful prosecution of the war, could have been produced without the modern equipment and mining methods used in the district, The transportation of iron ore from the open-cut mines of the district is the most important phase of the mining cycle. Although some of the mines still use rail haulage advantageously, this method of haulage has been replaced at most nines with motor-truck haulage or a combination of motor-truck and belt-conveyor haulage.SCOPEThe transportation of iron ore in this report covers (1) power shovels, (2) rail haulage, (3) trucks, (4) belt conveyors, (5) shipping pockets, (6) accident statistics, and (7) safety rules pertaining to open-cut transporta¬tion. The purpose of the report is to discuss briefly and disseminate to the mining industry the modern methods, equipment, and safety practices used in transporting iron ore at the open-cut mines of the district.The 25 open-cut mines covered herein, located in the Marquette, Cuyuna, and Mesabi iron ranges of Michigan and Minnesota, shipped approximately 44,000,000 tons of iron in 1945, which amounted to 72 percent of the open-cut iron ore shipped from the Lake Superior district."

May 1, 1948

By William F. Hahn

The Bureau Of Mines recognized the desireability of illuminating working places in trona mines. This report describes two illumination system designs, their demonstration and evaluation on a Jeffrey 120HR continuous mining machine in an active working trona mine in Wyoming.

Jan 1, 1980

By Rogers F. Davis

This publication has been prepared to supply manufacturers and industrial users a listing of mobile diesel-powered transportation equipment approved or certified by the Bureau of Mines f r use in gassy noncoal mines and tunnels. Testing of diesel-powered equipment is one phase of the Bureau's health and safety program of approval of electrical and diesel equipment designed to prevent explosions, fires, shocks, and toxic hazards in underground mines. In mines such equipment must be used and maintained properly. Manufacturers submit machinery and component parts to the Bureau for study f their design and safety features. Equipment must pass exacting tests and meet strict requirements established through research, development, and experience before the Bureau approves it as permissible for safe use in mines.

Jan 1, 1967

By Arnold B. Hubbard

This report presents a hydrogenolysis study undertaken to obtain information on the constitution of the kerogen or organic material in Colorado oil shale and to determine some of the properties of the hydrogenolysis products. The high yield of hydrogenolysis products was separated, so far as possible, into type compounds; a number were identified. The results thus obtained were used as a basis for proposing the possible existence of certain structures in kerogen. To the authors' knowledge, few or no hydrogenolysis studies have been made of Colorado oil-shale kerogen by others. However, this method has been used in studying the constitution of coal. In general, the coal studies involved treating pulverized coal at different temperatures and hydrogen pressures with different catalysts. In some instances different solvents were used during the treatments.

Jan 1, 1959

By W. J. McConnell, C. P. Yaglaglou

"IntroductionThis paper on the kata thermometer is issued by the Bureau of Mines on account of the general interest in this instrument and the fact that it is frequently used in studies of mine ventilation conditions with regard to comfort and health of miners. It has been used in the studies being conducted along this line by the Bureau of Mines on the effects of high temperatures and humidities of air in mine working on the comfort conditions, as well as in studies of atmospheric conditions in mine, railway and vehicular tunnels.The study of the various physiological responses of the human body to different degrees of temperature combined with different percentages of relative humility in still and in moving air, now being conducted at the Pittsburgh experiment station of the bureau in the research laboratory of the American Society of Heating and Ventilating Engineers, cooperating with the Bureau of and the U. S. Public Health Service, presents an added opportunity of investigating the instruments that have been devised to measure atmospheric conditions as they affect the comfort and health of human beings.The ordinary mercury thermometer, as pointed out by Heberden3 almost hundred years ago is a very inadequate instrument for measuring the physiological effects of atmospheric conditions. It merely accounts for that part of the body heat lost by raliation and convection, while as a matter of fact greater part of the body heat resulting from the metabolic process within the body is eliminated by means of evaporation from the surface of the body."

Jan 1, 1924

By A. J. Kraemer

Few important improvements other than the development of cracking processes were made in technical petroleum refining from 1914 to 1919. Refiners were concerned mainly with enlarging their plants and erecting new plants to meet the growing demand for petroleum products. Shell stills operated as a unit or arranged in series for progressive or continuous distillation were the prevailing distillation equipment. Some improvement was made in condensers, but in most refineries of the period coils of pipe immersed in tanks of water were used to condense vapors and cool liquid products of the stills. Heat exchangers to conserve heat and reduce costs were more highly developed at California topping plants than at other plants. In this connection Wadsworth3/states: It is regretted that information concerning the operation of topping plants with eastern and Middle West oils is not available. The writer carefully canvassed the Middle West, but did not find a plant where operation had progressed beyond the early experimental stages and reliable figures could be furnished.

Jan 1, 1941

By Edward L. McHugh

The appraisal of mineral resources of the Challis National Forest, Idaho, by the U.S. Bureau of Mines, was made so that the mineral resources of the forest could be appropriately considered in land use planning. Information from this study is intended to help the U.S. Forest Service to incorporate mineral resource data into forest plans. The study was done in conjunction with the U.S. Geological Survey, which released a companion report on the geology and mineral potential of the Challis National Forest in 1989. Mineral development activity in and under the Challis National Forest has been of great economic significance to Idaho and the United States. Since the 1960's, mines within the forest have produced mineral commodities worth more than $590 million A current (1989) commodity prices. Identified mineral resources have a gross value of about $2 billion at current prices, including 8 strategic or critical minerals. The U.S. Bureau of Mines study identified and described 723 active and inactive mineral properties within the forest. Mineral properties with identified resources were evaluated to determine their economic significance, and an assessment was made of the feasibility of mineral development. Of the 2,516,191 acres in the Challis National Forest, about 390,000 acres were classified as having mining development interest commercially important mineral production, mainly of molybdenum, gold, and silver from the Challis National Forest is likely for the foreseeable future.

Jan 1, 1991

By W. D. Mcmillan

"Magnetic surveys made by the Missouri Bureau of Geology and Mines in 931 and 1932 disclosed a large positive anomaly about a mile south of Bourbon, Mo. 3/ Electrical resistivity measurements made by the Division of Geophysical Exploration of the Bureau of Mines in the winter of 1942-43 indicated that the source of this anomaly was in the pre-Cambrian rhyolite at a depth of more than 1,400 feet. 4/In order to determine the character of the material that caused the magnetic anomaly, which might be either a body of magnetite or a large intrusive of basic rock, the Bureau of Mines drilled four holes to depths of 1,800 to 2,300 feet. Magnetite in rhyolite porphyry was encountered at 1,600 to 2,000 feet, and this is doubtless the main source of the magnetic anomaly, although it is possible that additional iron ore exists at greater depth.Hole 1 was apparently located southeast of the source of the anomaly and encountered only small stringers of magnetite. Hole 2 penetrated four mineralized zones having a total thickness of 125.7 feet and an average weighted content of 43.52 percent iron and 31.62 percent silica. These zones were tested again by a deflection hole, 2A, which gave nearly identical indications. Hole 3, 500 feet north of hole 2, penetrated 58 foot of mineralized rhyolito containing an average 43.4 percent iron.Metallurgical tests showed that the silica in the ore is tightly locked with the magnetite. After grinding to minus 100 mesh, a 66 percent iron con¬centrate with 7 percent silica was obtained by flotation."

Oct 1, 1946

By Douglas W. Fuerstenau

This report presents the results of an investigation of comminution in tumbling mills. Five different topics involved with ball mill and rod mill grinding kinetics were studied and the results analyzed in terms of phenomenological size reduction and transport models. Continuous rod mill grinding was found to be characterized by high Peclet numbers which permit simulation to be carried out by several methods. The dry batch ball mill grinding of mineral mixtures showed that the breakage rates of the components were composition-dependent but time-independent and were normalizable with specific energy. Locked-cycle tests on mineral mixtures showed that a grinding circuit may take a long time to attain steady-state, during which time the composition of the mill holdings, and hence the breakage rates of the components, continuously changed. This study revealed that under plant conditions, grinding circuits can be in transience perpetually. The transport of mineral mixtures through drums was found to exhibit complex size and/or density-dependent segregation. However, the grinding media in a ball mill can eliminate such segregation, thereby simplifying the modeling of the continuous grinding of complex feeds. Wet batch rod mill grinding on single minerals divulged that the normalizability of breakage kinetics is valid for slurries of constant pulp density at different hold-ups but cannot be extended to slurries varying in pulp density.

Jan 1, 1983

By John T. Dieckmann

This report documents the work performed and the results obtained in a 2-year development of a Mobile Inert Gas Generator for use in the Bureau of Mines Remote Sealing System for fighting underground coal mine fires. The performance requirements of an inert gas generating system for the Remote Sealing System were clearly established. A thorough review of seven possible system designs meeting these requirements was conducted. An air cooled, distillate oil fired combustion type inert gas generator was selected for further detailed design, hardware fabrication, and performance testing. The Inert Gas Generator constructed under this program has been thoroughly performance tested and has been operated in the field for approximately 200 hours. The system has met or exceeded all important performance requirements. The system was used in the fire fighting efforts at the Bethlehem Mines Corporation Cambria Division Mine 33 fire and contributed to the successful containment of the fire. The system was also employed in the demonstration of entire Remote Mine Sealing System at the Jenney Mine in the fall of 1978. The system is currently avail-able for fighting any future underground coal mine fires.

Jan 1, 1979

By Daniel Harrington

On the night of June 8, 1917, the flame of a carbide lamp accidentally set fire to the uncovered and frayed insulation of an armored power cable near the 2,400-foot level of the North Butte Mining CO.'s Granite Mountain shaft. How this, insulation accidentally became exposed is explained on page 15. The highly flammable oiled fabric set fire to the shaft timbers, and as this is a downcast shaft the fire spread with great rapidity, soon filling the mine workings with smoke and gas. At the time 410 men were working underground, 247 of whom escaped by various means, but most of the 163 remaining were probably overcome soon after the fire started, and perished. Only two men were actually burned. The cause of the disaster was purely accidental. The immediate effect was the unexpected reversal of normal conditions; the ultimate effect was great loss of life and the destruction of the main hoisting shaft, putting it temporarily out of service. The work of rescue and fire fighting continued eight days. The following pages present an attempt to draw some practical conclusions and suggestions from this disaster. The property of the North Butte Mining Co. consists of about 220 acres in the northeastern part of the Butte district, Montana. Next to the Anaconda Copper Mining Co. it is the largest producer of the district. In 1916, the year before the disaster, there were 1,160 men employed. The output was 560,947 tons of ore, which yielded 24,498,181 pounds of copper, 1,047,063 ounces of silver, 1,712 ounces of gold, and 412,953 pounds of zinc. The profit was $2,479,595. The total development work for that year was 21,694 feet. During the first half of 1917, the year of the accident, the daily tonnage of ore averaged 2,000, an increase of 400 tons over that of the year 1916.

Jan 1, 1922

By Alice M. Chieruzzi

This Country Documentation Report presents the development of economic indices for Zambia for the period from 1970 through 1981. The work done through the Bureau of' Mines, Minerals Availability Program, under Contract number J0225001. This contract calls for the development of twelve index time series describing factor input costs in the mining sector of 95 countries. The twelve index time series describe the costs of: 1) mining wages, 2) construction wages, 3) equipment and repair parts, 4) bits and related steel, 5) timber and lumber, 6) fuel, 7) powder and blasting agents, 8) tires, 9) construction materials, 10) industrial materials, 11) transportation, and 12) electrical power. These indices combined with weight factors being developed by the personnel of the Minerals Availability Field Office (MAFO) of the Bureau of Mines in Denver, Colorado, will be used to perform instantaneous updates of all costs relating to the mining industry. The indices were developed primarily for use in the Bureau's Minerals Availability Program in assessing the worldwide availability of nonfuel minerals.

Jan 1, 1983

This publication summarizes the Bureau's activities as part of a study of the Juneau Mining District (JMD) during the period 1984-1988. The objectives of the program were to identify the type, amount, and distribution of mineral deposits in the district, determine ore reserves, study beneficiation technologies for the ore, make feasibility studies, and address economic and legislative effects on mineral development. The JMD study was a cooperative study involving the Bureau and the Alaska Division of Geological and Geophysical Surveys (ADGGS). Over 30 employee-years were spent by the Bureau on this project. Bureau investigations in the JMD consisted of a district-wide investigation of industrial materials in addition to site-specific investigations of precious and base metals in five subareas. During the 4 years of the JMD study, more than 300 areas, mines, prospects, and occurrences were visited, which contain gold, silver, copper, zinc, lead, nickel, cobalt, tungsten, molybdenum, chromium, and platinum group metals (PGM). More than 59,000 feet of underground workings were mapped and sampled. More than 5,500 samples were taken; one diamond drilling program and three geophysical surveys were completed. An up-to-date and complete mineral data base for the JMD did not exist prior to this study. The JMD study, which coincided with a tremendous increase in mineral interest and activity in the district, has proven to be valuable to both the minerals industry and land management agencies. The discovery of two new mineral occurrences and compilation of data on known mines, prospects, and occurrences have aided industry activity in the region. The study enabled timely data to be available to land management agencies at the Federal, State, and municipal levels.

Jan 1, 2012

By James W. Ballard, H. H. Schrenk

"The X-ray method of quantitative determination is advantageous because it permits determination of compounds rather -than ions or elements; for example, the direct determination of quartz in silicates,4/,5/,6/ The method also takes into account the finest particles of a sample, which may be lost in wet chemical methods because of solubility or in petrographic methods because of limitation of the microscope. The sample is usually reduced to a powder and is easily prepared,7/ only a few milligrams of material being necessary. The sample and its chemical composition are not destroyed and may be used for further analysis by X-ray diffraction or by other methods.This paper presents in detail some of the more essential problems that arise in the application of X-ray diffraction to quantitative chemical analysis, Photometric measurements are discussed in connection with line intensities and the choice of X-ray film. The internal standard method, successfully used in spectrographic analysis, is applied.Copper K-alpha X-rays from a demountable research-type X-ray tube were used with a camera of 20 centimeters radius with a cast-lead-slit collimating system. A combination of a tilted wedge and a lead-slit collimating system permitted irradiation of a large amount of sample with X-rays. This tended to minimize errors due to possible inhonogeneity of the sample, to decrease the time of exposure, and to keep the lines on the X-ray film to a minimum width. There was sufficient dispersion of the lines for satisfactory analysis of most samples. Power was furnished the tube by a. source of constant high potential consisting of a synchronous motor generator furnishing 500-cycle power to a 100-kv. transformer, rectifying valves, and a condenser filter circuit. The X-ray tube was operated as a gas-type tube at 35 kv, and 20 ma,, the exposure times varying from 1 to 2 hours. The constant output of X-rays from the tube, indicated bar an exposure meter built for the purpose, was satisfactory.The recording microphotometer8/has been described. It was found preferable to a nonrecording instrument for measuring blackening of lines above a background on X-ray films. This background, which usually occurs, is sometimes complicated by numerous peaks from lines of complex diffraction patterns. is microphotometer record of the pattern, therefore, facilitates the location of the background 'and the measurement of the heights of the peaks and thus contributes to the accuracy of a determination."

Jun 1, 1946

By C. M. McKinney

This report contains Bureau of Mines routine crude-oil analyses of 20 samples from5 areas on the arctic slope of Alaska. Two samples were condensates from the South Barrow gasfield, Barrow Lakes area. The remaining 18 samples were crude oils from the following areas: Barrow Lakes, 1 seepage sample; Umiat, 10 well samples; Cape Simpson, 1 seepage sample and 3 well samples; Fish Creek, 2 well samples; and Wolf Creek, I well sample. Table 1 summarizes information on the origin of the crude-oil samples, and table 2 summarizes characteristics of the samples. Item numbers in both tables correspond to item numbers of the analyses at the end of this report, and the samples are referred to by these numbers throughout the text.

Jan 1, 1959

By Ernest W. Johnson

In most underground iron mines in the Lake Superior district the active workings are at considerable depth. When additional openings into such. nines are needed, operating officials are eager to discover more efficient methods of constructing them. In recent years, openings into two mines in the district were made by the borehole method,-which employs chilled-iron shot as the cutting medium. Others were made by the churn-drill method, in which pilot hole is churn-drilled and subsequently reamed to a desired but relatively small diameter. Both methods are comparatively new and unique, at least in some phases and in their application.

Jan 1, 1946

By N. A. C. Smith, A. C. Fieldner, R. R. Sayers

Gases and vapors given off by petroleum and its products have long been recognized as somewhat injurious, when inhaled in high enough concentrations. The petroleum industry has recognized these effects and has tried to minimize the possibility of employees encountering dangerous concentrations of the vapors. Petroleum gases and vapors have not, however, been considered as actively poisonous, in the sense that hydrocyanic (prussic) acid and phosgene are poisonous; men have been exposed to them repeatedly, and for long periods, without any marked ill effects. Light Mexican crude oil when first introduced into the United States for refining was handled in much the same way as was customary with other apparently similar crudes; but experience soon showed that some toxic substance escaped from the crude during production and transportation and in most of the refinery operations. After a preliminary investigation several of the larger companies decided that the gases from the petroleum were the source of trouble, and therefore took precautions, wherever possible, to protect the men from exposure to these gases. With the increasing use of Mexican crude, this problem has become important. The present report covers the work done on the subject by the Bureau of Mines and the Public Health Service under a cooperative agreement with the American Petroleum Institute.

Jan 1, 1925