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By L. Weitkämper

The big challenge at present and in the future is the economization of resources. This is applied for the whole industry but particularly in fields of mineral processing. The most important resources are energy and water. The shortage and price advance of energy is worldwide noticeable whereas the shortage of water is regionally limited at present. However due to the increasing world population, associated with a rising standard of living, water will become more and more important. Studies of the Unesco from 2001 indicate that the total water consumption raised seven times since the last 100 years at a growth of population of just three times. (UNESCO-Currier, 10/2001). This trend is going to be increased. While today more than 90 % of the humanity has access to clean water, in 2050 just about 50 % will be in the same situation. These figures indicate the importance of a gentle handling with the resource water. Further more the disposal of fine products, containing most of the water, is an environmental concern and in the future the mining and processing of raw materials will become important and necessary in desert, arid or permafrost areas. In these areas just efficient dry cleaning technologies will allow an economical beneficiation or better enable the processing at all. Most of the separation technologies with high throughput rates in mineral processing are based on wet processes. This applies especially for the separation of fines. Though there are some dry technologies available for the separation of coarse materials, like pneumatic gravity separation [air jigs and air tables], magnetic separation and not least sensor based sorters. Dry separation of fines is bounded mostly on cost intensive and low throughput technologies. The pneumatic separation undergoes at present a renaissance, mainly due to the development of the all air jig by the German supplier Allmineral. This newly developed sorting device yields good results in the separation of coarse to medium size material. All these facts and figures show the potential and motivation for developing an efficient dry separation device for fines. The following article delineates the development, performance and chance of a new dry separation technology for fines.

Jan 1, 2014

By Seher Ata

This paper is concerned with the coalescence behaviour of two bubbles in dilute solutions of cetyltrimethylammonium bromide, methyl isobutyl carbonil and triton x-100. Two bubbles were produced at the tips of adjacent capillaries and the time elapsed between the first contact of the bubbles and film rupture was determined by means of a high speed camera. It was found that the amount of surfactant required to stabilise the bubbles increased in order of CTAB>TX-100>MIBC. The probability of coalescence decreased sharply with increasing surfactant concentration in CTAB and TX-100 solutions while with MIBC each bubble pairs resulted in coalescence, giving hundred per-cent coalescence probability.

Jan 1, 2014

By K. C. Corin, M. S. Manono, J. G. Wiese

"It has been suggested that hydroxo species, particularly those of calcium, selectively adsorb onto gangue minerals. Such species enhance the depressive action of carboxymethyl cellulose (CMC) onto gangue via an acid-base interaction between the positively charged mineral surface and the negatively charged CMC molecule. Thus, the hydrophilicity of gangue minerals is enhanced, preventing the dilution of the concentrate. However, as there is little evidence to support these claims it is important to investigate. Adsorption data and mineral surface charge analyses will allow a fundamental understanding into how electrolytes and their ionic strengths affect gangue-depressant adsorption. It is strongly anticipated that decoupling these effects will allow process operators to tailor their process water quality needs towards best flotation operating regimes and in the long run effect closed water circuits. Thus, using talc and pyrrhotite as proxies, this work investigates the influence of the ionic strength of process water on the adsorption of CMC onto minerals in sulphide flotation.INTRODUCTIONThe phenomenon of gangue depression in mineral flotation is of critical importance as regards the attainment of a required concentrate grade. This thus suggests that the depressant of choice has to have a highly selective affinity for the targeted gangue minerals. This would ensure the necessary prevention of gangue from reporting to the concentrate without inadvertently depressing the value bearing mineral. The chemistry of the environment regulates the manner in which gangue depression occurs. In sulphide flotation, polysaccharides are used as depressants of choice to depress naturally floatable gangue which may in the case of Merensky ores exist as talc. The two widely used polysaccharides in the South African context are carboxymethyl cellulose (CMC) and modified guar gum. It is suggested that polysaccharides depress gangue by rendering the surface of gangue hydrophilic or by preventing the formation of hydrophobic layers on gangue mineral surface, forming large gangue aggregates and thereby increasing their heterocoagulative nature (Shortridge et al., 1999)."

Jan 1, 2018

By Matthew Thurley

Optimisation and control of comminution, pelletization, and agglomeration processes is a complex task with large potential for gains in productivity, energy efficiency, and particle size distribution quality. One factor in realising these gains is the requirement for fully-automated online particle size distribution measurement. Moreover, online particle size distribution measurement that is based on the particles on the visible surface and can avoid or mitigate substantial errors that result from under-sizing overlapped particles and over-sizing areas of fines particles. Literature review indicates a body of substantially 2D photographic based particle size measurement systems that suffer from a large number of significant errors except in the simplest case of a monolayer of particles under good illumination with limited color variation in the material. In order to measure the visible particles on a pile there are a number of requirements including; avoiding particle delineation errors due to variation in material color and shadows, detect overlapping versus non-overlapping particles, and identify areas of fine particles as fines and not large rocks. Results are presented using a fully-automated online measurement system of crushed rock on conveyor belt using a 3D surface laser profile. The system provides continuous online measurement and results are shown on over four hours of production after the primary crusher. Size distribution results are calculated using volumetric estimation of the particles on the surface of the pile. The results show a strong capability to discriminate size variation especially in the 10% and 20% passing values. Furthermore results show that if areas of fines are misclassified as large rocks, and overlapped particles misclassified as small rocks, then a near complete loss of discrimination occurs for the P10 and P20 values which become largely constant values.

Jan 1, 2014

By S. Castro

Molybdenite flotation is strongly depressed at pH higher than 9.5 in the flotation of Cu-Mo ores in sea water. Chemically sea water contains mainly Na+ and Cl- ions, but also some secondary ions, such as SO42-, Mg2+; Ca2+, HCO3-; etc., which are not necessarily indifferent for the flotation of molybdenite. The natural floatability of molybdenite in sea water and in NaCl solutions containing different secondary ions is investigated by micro-flotation tests. The tests indicate that the floatability of molybdenite in alkaline media in 0.6 M NaCl solutions is not affected by the presence of anions, such as, SO42- and HCO3-, at concentrations similar to those occurring in sea water. However, a strong depression of molybdenite at pH ranging from 9.5-10.0, is produced by the alkaline earth metal cations (Ca2+ and Mg2+ ions), dissolved in distilled water or in 0.6M NaCl solutions. It was found that effect of Mg2+ions is significantly stronger than Ca2+ ions. Effect of both ions is attributed to hydrolysis and adsorption of MOH+ hydroxy-complexes. This is followed by subsequent precipitation of hydrophilic colloidal hydroxides at the molybdenite/solution interface, and in bulk solution.

Sep 1, 2012

By Y. H. Wang

Micro-flotation tests of spodumene, beryl, quartz and feldspar have been carried out by using CaCl2 and FeCl3 as modifiers and a blending collector of oleic acid and hydroximic acid. CaCl2 shows efficient activation for spodumene when pH is above 11.5, and FeCl3 exhibits a markedly activation and good selectivity for spodumene in the range of pH 4 to 10. The main species of CaCl2 are CaOH+ and Ca(OH)2 when pH is above 11.5, and the main species of FeCl3?6H2O are Fe(OH)+2 and Fe(OH)3 during the pH range of 4 to 10. A selective flotation of spodumene and beryl from pegmatic ore had also been completed while using FeCl3?6H2O as activator and the blending collector. A bulk concentrate containing 1.087% BeO and 4.70% Li2O has also been obtained in the flotation of spodumene and beryl from pegmatic ore assaying 0.097% BeO and 0.45% Li2O, and the recoveries of BeO and Li2O in concentrate are 74.38% and 69.50% respectively.

Jan 1, 2014

By Sirish L. Shah

It is now common to have archival history of thousands of sensors sampled every second over long time. Yet we frequently have process engineers complain:??.We are drowning in data but starving for information??. How can these rich data sets be put to use? This paper addresses the issue of information and knowledge extraction from data with emphasis on process and performance monitoring including fault detection and isolation. Most of the major plant, factory, process, equipment and tool disruptions are avoidable, and yet preventable fault detection and diagnosis strategies are not the norm in most industries. It is not uncommon to see simple and preventable faults disrupt the operation of an entire integrated manufacturing facility. For example, faults such as malfunctioning sensors or actuators, inoperative alarm systems, poor controller tuning or configuration can render the most sophisticated control systems useless. Such disruptions can cost in the excess of $1 million per day and on the average they rob the plant of 7% of its annual capacity. Over the last decade the fields of multivariate statistics and data visualization and analysis methods have merged to develop powerful sensing and condition-based monitoring systems for predictive fault detection and diagnosis.These methods rely on the notion of sensor fusion whereby data from many sensors or units are combined with process information, such as physical connectivity of process units, to give a holistic picture of health of an integrated plant. Such methods are at a stage where these strategies are being implemented for off-line and on-line deployment. This article attempts to outline the field of sensor fusion - the application of signal processing methods, in the temporal as well as spectral domains, on a multitude and NOT singular sensor signals to detect incipient process abnormality before a catastrophic breakdown is likely to occur Keywords: Process analytics, process and performance monitoring, multivariate statistical analysis, sensor-fusion

Sep 1, 2012

By G. I. Voiloshnikov, V. E. Dementyev

"One of the most important advances in the world gold metallurgy is the introduction of adsorption technologies for processing of ores and concentrates. «Adsorbent-In-Pulp» process allows to eliminate pulp filtration that is especially important during processing of clay and slime bearing ores. “Adsorbent-In-Leach” process is one of the ways for processing of preg-robbing (carbonaceous) products. High efficiency, increased metals recovery, decrease in capital and operational costs, possibility of easy control and adjustment are the advantages of adsorption processes. Anion-exchange resins and activated carbons are used as adsorbents. This paper presents Irgiredmet experience on gold adsorption technology using both adsorbents (RIP, RIL, CIP, CIL processes). It includes results of long-term studies of different theoretical and practical issues of adsorption processes. Irgiredmet started development of ion exchange technology (RIP, RIL) in 1964. Laboratory and pilot plant tests were conducted to develop process design criteria for 15 RIP plants of the former USSR. During this test work a great number of newly synthesized resins including strong- and medium-base resins was studied, different types of adsorption feed (ores and concentrates) were tested; some theoretical regularities of adsorption process were investigated; the technology of two stage adsorption for silver gold ore, improved flowsheet for gold elution and resin regeneration, designs of technological equipment for adsorption, elution, electrowinning processes including pulsation columns, electrowinning cells etc. were developed. Irgiredmet took part in commissioning of practically all RIP plants in the former USSR. Due to its efforts RIP process became to be the standard technology. Last Irgiredmet RIP projects include the development of adsorption technology using medium-base resin for the three mines owned by GC Petropavlovsk (Amur region, Russia). The complex of the testworks on activated carbon gold adsorption technology including the search of prospective activated carbons; study on gold adsorption mechanism; development, testing and introduction of process flowsheets and the equipment for their realization was conducted. The original gold elution process was developed. The developed CIP technology was firstly introduced at Lebedinsky gold plant (Yakutia). Now carbon adsorption technology is widely used at Russian gold mines as CIP, CIL, CIC processes. The most relevant example of CIP introduction is Svetlinsky gold plant (Ural, Russia) with capacity 8 Mt of ore/ year."

Jan 1, 2018

By Teemu Väyrynen, Matti Vilkko, Antti Jaatinen, Pekka Itävuo

"This paper shows that smooth and accurate feed-hopper level control is essential for consistent cone crusher operation. The objective of the paper is to define the best practices for tight control of cone crusher feed-hopper level. The paper discusses the challenges involved in a delay-dominant level control problem (specifically, dead-time-induced performance and stability issues, mass flow disturbances, process and actuator non-linearity) and proposes five corresponding control structures. The performance of the proposed control structure candidates is evaluated in a simulation study and, finally, a full-scale experiment is conducted for the best-performing candidate. The results of this study emphasize the importance of control structure selection. While the most obvious control structures failed to deliver the desired performance, the best result was achieved by using control structures that eliminate the conveyor transport delay (dead-time) from the control loop. In practice, the control loop dead-time can be eliminated by either using an actuator (variable-speed feed conveyor) that is connected directly to the feed-hopper, or by redefining the process boundaries closer to the used actuator (regulate the circuit mass balance instead of feed-hopper level). The presented control structures provide means to achieve a consistent cone crusher performance and size reduction. This facilitates efforts to improve the plant’s performance and increases the plant’s overall stability."

Jan 1, 2014

By Behzad Vaziri Hassas, Firat Karakas, Mehmet Celik, Onur Guven

Since dewatering is a costly process, removal of moisture from relatively fine size lignites is an important industrial problem. As the lignite gets finer, the presence of micropores and relatively low hydrophobic nature of lignite lead to trapping of large quantities of water in the coal matrix. Lignites used in power stations need to be dried to a certain degree of humidity before it is transferred to the combustion chamber. It is generally wise to dewater coal as much as possible by physical means before it is dried. However, dewatering cost in some cases may be prohibitive. Thus, sometimes removal of even little percent moisture may be of great help in such operations. Surfactants have been used to increase the efficiency of coal dewatering. It is crucial to select appropriate type and amount of surfactants in order to get higher efficiency. Since the hydrophobic characteristic of coals increases with increasing the coal rank, dewatering of bituminous and anthracite can be accomplished using low HLB surfactants (Oily), however, these surfactants are not efficient in the case of low rank coals like lignites and brown coals. It is suggested that adsorption of low HLB surfactants on high rank coals is governed by Acid-Base interactions rather than electrostatic and van der Waals forces. Since this characteristic in lignites is not strong enough, low HLB surfactants could not be effectively adsorbed on low rank coals to make surface more hydrophobic. In this paper, a special set-up has been designed to study the effect of high HLB surfactants on dewatering of fine lignite particles. It is shown that high HLB surfactants function more efficiently on low rank coals than low HLB ones.

Jan 1, 2014

By Vladimir F. Skorokhodov, Nikolay N. Melnikov, Svetlana P. Mesyats

"Among the problems of the civilization development, a problem of interaction between man and natural environment can be highlighted. In the twentieth century the human transforming activity had got scales of geological processes and defined the contradiction between the goal to increase the quality of human life and possibilities of the natural environment. Last twenty-five years after the World Summit on the Environment (1992) indicate that the development of civilization is still based on receiving super profits from the natural resources exploitation. This statement is confirmed by economy globalization rates, growing contradictions between consumption and production, depletion and degradation natural environment. A new technological order is formed at the time of growing world population, technological capacities, organizational complexity, from one side, and global scales of geo-resources consumption, on the other side. Sciences, determining the further civilization development, should take on the task to change the social worldview, since the preservation of human population consists in remediating and maintenance of biosphere functions as a regulator of ecological balance. The new worldview in the geo-resources exploitation is based on the Ecological strategy of mining development, which consists in reducing mining-induced loading on natural environment while increasing efficient mineral production and processing, and providing for a comprehensive solution of tasks on mineral deposit development. One of strategic trend of mining development is to increase complexity and completeness of useful component extraction from ore and mining deposits while reducing wastes and decreasing their stockpiled volumes. The implementation of the ecological strategy has shown that the future is determined by reduction of the environmental impact while improving the efficiency of mineral mining and processing.INTRODUCTION The global nature of environmental problems caused by the scale of consumption of natural resources, huge amounts of waste, and intensive man-made impact on the environment requires a revision of the strategy for the natural resources development. Many existing technologies are ineffective in achieving the ultimate goal. Direct output in the raw materials - the end product technological chain rarely exceeds 10%, which implies a huge amount of work to move the soil. In addition, the feature of scientific and technological progress at the present stage is the growth of power-to-weight ratio."

Jan 1, 2018

By Ghislain Bournival, Seher Ata, Graeme J. Jameson

A common method to prevent bubbles from coalescing in a flotation cell is by the addition of surfactants, called frothers. The gas dispersion properties in a column were tested for solutions of 1-pentanol, tri(propylene glycol) methyl ether, and poly(propylene glycol) in the presence of sodium chloride. The dependency of surfactant on the gas holdup can be divided into regions. It seemed that for a sufficiently low concentration of surfactant, even a stronger surfactant could show a transition in gas holdup from constant/decreasing to increasing with concentration. This region, however, was not marked by a decrease in the average bubble size. In addition, PPG gave higher gas holdup values while averaging larger bubbles. On the other hand, sodium chloride mostly affected the gas holdup when the concentration was high enough to prevent bubble coalescence. Another parameter affecting the gas holdup was the superficial gas velocity. A linear dependency was found between the two under a bubbly flow regime. The current study showed that both surfactants and salt could slightly affect the influence of the superficial gas velocity on the gas holdup.

Jan 1, 2014

By R. D. van der Weijden, W. F. C. van Wageningen

"Copper(II) can be recovered or removed from acidic copper sulfate solutions as cuprite or metallic copper powder by reduction with carbohydrates (van der Weijden et al., 2001, 2002). In order to make this process suitable for a commercial scale pipe reactor, process conditions and reactor configuration need to guarantee proper throughput of the dilute suspension. This is where crystal engineering also comes into view. Copper powder characteristics, such as size and shape of particles, influence the tendency to adhere to reactor walls and to agglomerate, which in turn influence the throughput. Furthermore, separation, drying, packaging and product quality, are dependent on the powder characteristics.In this paper the effect of both chemical and physical parameters on the shape and size of particles were systematically studied in a number of autoclave experiments. These parameters include mixing, Cu(II) concentration, pH, temperature, seeding, use of additives and reactor materials. Additionally, Monte Carlo simulations of copper growth inside a Kenics static mixer were made. Results show that the use of additives, and the use of static mixers influence particle characteristics the most."

Jan 1, 2003

By Sergio Castro, Janusz Laskowski

In the flotation in highly concentrated electrolyte solutions not only ionic strength but also chemical composition, flotation pH and mineral properties play an important role. As a result an improvement or depression may be observed. A strong improvement in the floatability of hydrophobic bituminous coals and other inherently hydrophobic minerals is characteristic for the "salt flotation process", which is carried out in concentrated electrolyte solutions at natural pH and without addition of any flotation reagents. However, pH is a key factor when saline and hipersaline waters with hydrolyzing metallic ions are used as process water. In the case of flotation of Cu-Mo sulfide ores in seawater, molybdenite is strongly depressed by the Mg2+ hydrolysis products when pH is raised to depress pyrite. Process water with a high content of Mg2+ and Ca2+ ions, and this also includes seawater, have deleterious effect on the anionic flotation of industrial minerals with fatty acids. The flotation of potash ores is carried out in NaCl-KCl saturated brine (6-7 mole/L of NaCl and KCl) with the use of long-chain amines. Such a high electrolyte concentration changes dramatically the amine Krafft point making the collector insoluble in brine; its mode of action entirely differs from that in conventional flotation processes.

Jan 1, 2014

By G. Mucsi

This paper deals with the laboratory investigation of cathode ray tube (CRT) glass based glass foam, a relatively new product so called ?Geofil bubbles?. The main process engineering material properties of raw materials, such as particle size distribution, moisture content, density and specific surface area are shown. Then the preparation of raw cathode ray tube glass waste is presented including the following steps: crushing in impact crusher, grinding in laboratory scale ball mill, mixing, pelleting and sintering. We found that it was possible to produce foam glass (with proper mechanical stability and particle density) from the investigated waste CRT glass. The material characteristics of the final product strongly depend on the sintering conditions. Optimum conditions were determined particle size fraction was found to be 4-6 mm, temperature 800 0C, residence time 7.5 min. Keywords: waste CRT glass, grinding, pelleting, sintering, glass foam

Sep 1, 2012

By B. McFadzean, P. E. Ngoepe, P. P. Mkhonto

"The theoretical technique of computational modeling and the experimental determination of the enthalpy of adsorption of a ligand molecule onto a mineral surface deliver the same output parameters and, therefore, complement each other in investigating the affinity of different ligand types for mineral surfaces.This study ran parallel experimental tests and computational calculations to determine the enthalpy of adsorption of a series of increasing chain length xanthates onto a pyrite surface. The outcomes showed that, while the absolute energy values were different, the trends were similar. Both computational and experimental approaches showed that the extent of the interaction of the xanthate molecule increases with increasing carbon chain length. The computational values were larger than the experimental values, which could be explained, in part, by the addition of water to the computational system, which resulted in a decrease in the heat of adsorption on the (100) surface, compared to the adsorption of the collector in a vacuum. The computational method showed that, in the case of the pyrite (100) surface, the most exothermic reaction was obtained when the two xanthate sulfur atoms bridged two pyrite 5-coordinated iron atoms. The (111) surface was found to be more reactive and different adsorption mechanisms were predicted for each of the C2, C3, C4 and C5 chain length xanthates.The experimentally determined exothermic increase in heat of adsorption for the addition of each CH2 group was found to be -8.17 kJ/mol. The contribution of the thiol head group was -34.9 kJ/mol. Previous studies on self-assembled monolayers have shown that these values are compatible with lateral interactions between CH2 groups and the exclusion of water. This study provides a rigorous experimental and computational approach which is intended to afford confidence in modelled data for the screening of new ligands for flotation processes.INTRODUCTIONComputational modelling is a fast and cost-effective method of screening collector molecules for the efficacy of their adsorption onto mineral surfaces. However, it is desirable to measure the computational outputs against experimental outputs to check for congruency. Computational modelling and experimental microcalorimetry both deliver the same output parameter: the energy of adsorption of the molecule onto the solid surface. These techniques are therefore ideally suited to complement one another in investigating the affinity of the interaction between collector molecules and mineral surfaces."

Jan 1, 2018

By Gus Van Weert, Samuel A. Bolorunduro, David B. Dreisinger

"Silver is currently lost as jarosite during the pressure oxidation of sulphides and cyanidation of the residues yields 5-10% of silver. Efforts to recover silver from complex sulphides, which contain economic fractions of silver require an understanding of the behaviour of acanthite during pressure oxidation. However, previous studies of acanthite (Ag2S) reaction have been complicated by the formation of argento-jarosite and uncertainties arise on the interpretation of the results.In this work, the acid pressure oxidation of high-grade natural silver sulphide mineral (acanthite) was carried out at 110-150°C and under the conditions similar to that of pressure oxidation of complex sulphide. The predominant product of reaction is elemental sulphur. The rate of reaction increases with increasing temperature and with the presence of ferric ions. The kinetics is controlled by chemical reaction with activation energy of 72.6 kJ/mol. The rate of reaction decreases with the presence of silver sulphate in the initial slurry. The proposed overall reaction is close to: []"

Jan 1, 2003

"Wet low intensity magnetic separation has been used for the recovery of magnetite for decades. As high-grade reserves continue to decline, low grade magnetite ores are being targeted for iron production. Low grade magnetite mineralisation is typically fine grained and requires fine to ultrafine grinding (P80 40 - 30 µm) to liberate it from, predominantly, silica/silicate gangue matrices. Grinding to such particle sizes requires high power consumption and produces excessive fines which impact negatively on wet magnetic separation and tailings dewatering. In addition, the dearth of fresh water for mineral processing in arid areas impacts negatively on the economic viability of low grade magnetite projects. These challenges have motivated innovation in dry magnetic separation technologies for the beneficiation of magnetite that can be economically applied on a large-scale. Such technology has been developed in the Cyclomag Planar magnetic separator (PMS) invented by South Australia-based Christopher Kelsey of IMPTEC P/L. The significant gangue mineralisation associated with magnetite ores in South Australia is quartz. In this study, the performance of the Cyclomag PMS on the recovery of magnetite mineral from magnetite-quartz blends was investigated. Magnetite-quartz blend were subjected to the PMS at varying control parameters - magnet discs rotation speed, inlet airflow and feeder speed. The study showed a successful dry separation of magnetic mineral from non-magnetics using the Cyclomag PMS. The PMS has potential to effectively recover magnetite mineral."

Jan 1, 2018

By Sergey Dyachenko

"Following the adopted strategy for making the production modern, efficient and environmental friendly the Company completed a stage of the integrated program aimed at reconfiguration of its processing capacity.Upgrade of the Talnakh Concentrator with commissioning of two start-up facilities (SF) allowed an increase of 30% in its ore processing capacity up to 10 mtpa. In addition to a new high-tech equipment installed, a new concentration process was adopted offering the main advantage of 25-30% reduction of sulfides in concentrate. New concentration technology enabled the total amount of produced nickel concentrates (from Norilsk and Talnakh Concentrators) to be processed at upgraded smelting facilities of Nadezhda Metallurgical Plant and allowed decommissioning of smelting capacities of Nickel Plant resulting in emissions reduction by 30%.Nornickel plans to boost the capacity of Talnakh Concentrator to 18 mtpa by 2022, after commissioning of the 3rd SF. This will provide a shorter route for ores transportation from Talnakh mines along with improvement of cost/performance ratio of ore processing through the usage of the modern equipment and optimized concentration flow scheme. Total capacity of Talnakh Concentrator will be sufficient to process ores from Talnakh deposits with planned upstream assets development taken into account. Volume of ore mined from Norilsk deposits to be processed at Norilsk Concentrator will be also increased.Upgrading the crushing section at Kola MMC Concentrator in 2015 provided finer particles of the crushed ore, resulting in 6.6% increase in specific capacity of ore mills as well as 1% higher recovery of non-ferrous metals due to improved liberation of ore minerals.In 2015-2017 the Company was actively engaged in optimization of existing process flow schemes and parameters of Kola MMC, new high-performance reagents were adopted for concentration process, namely, collectors, depressors, flocculants. These measures allowed the Concentrator to reduce its annual operating unit costs and ensure sustainable production of concentrate with the lower grade of the incoming feedstock.Launched in October 2017, Bystrinsky GOK’s Concentrator was 3D designed and received a range of advanced technological solutions.All design process procedures and technologies rolled-out at the Company’s concentrators were developed by Russian R&D institutes, with the key role of Gipronickel Institute, R&D Service of Kola MMC and Polar Division's in-house Engineering Support Centre."

Jan 1, 2018

By L. Ya Agapova

Emissions from pyrometallurgical processing of copper concentrates are usually subjected to wet scrubbing. The washing sulphuric acid so produced contains up to 0.2 g/L of rhenium, which is recovered by solvent extraction in the form of crude ammonia permeate (NH4ReO4). The mother liquor, obtained from the sulfuric acid wash, contains up to 35 g/L of rhenium and significant amounts of impurities. Crude rhenium salt is commonly processed by double recrystallization to produce marketable salt. A ton of high grade NH4ReO4 can be produced using 3.0-3.5 m3 of mother liquor. We propose an efficient technology of mother liquor pre-treatment aimed at removal of water-soluble organics with subsequent electrodialysis. Electrodialysis of mother liquor in a multichamber electrodialyzer resulted in the production of pure rhenium acid, from which a marketable NH4ReO4 is precipitated using ammonia solution. Multiple steps of recycling consisting of dissolution of NH4ReO4 salt, rhenium acid production from NH4ReO4 salt by electrodialysis and precipitation of NH4ReO4 from rhenium acid made it possible to upgrade the purity of obtained rhenium compounds by 1-2 orders of magnitude. A rhenium metal powder of 99.997% purity was produced by high-temperature reduction of high-purity NH4ReO4 with gaseous hydrogen. Rhenium metal powder of high purity can be produced from sulfate solutions of NH4ReO4 by non-platinum anode-based membrane electrolysis processes also. Keywords: rhenium, mother liquors, membranes, electrodialysis, rhenium acid, ammonia perrhenate, reduction, powder, electrolysis

Sep 1, 2012