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By G. M. Ritcey, B. H. Lucas

In the conventional alkaline leaching of concentrate containing nickel, copper and cobalt, copper is usually removed from the system, prior to nickel reduction, by sulphide precipitation. A new process is described for the selective extraction of copper and separation from cobalt and nickel, using liquid-liquid extraction. General Mills LIX-63 dissolved in a kerosene diluent is the extractant. Trace amounts of co-extracted cobalt and nickel are easily removed by a scrub treatment, and copper is recovered from the extract by sulphuric acid stripping, thus providing a solution amenable to the oroduction of electrolytic copper. Estimated processing costs are included together with a proposed flowsheet.

Jan 1, 1972

By X. -P. Zhang, L. N. Y. Wong

Shale gas exploitation initiated in North America has rapidly extended worldwide. Hydraulic fracturing is an emerging field technique for stimulating the gas reservoir. The study of cracking processes, particularly crack coalescence, is vital for a successful hydraulic fracturing to enhance the gas exploitation. Experimental studies have observed that the size effects of the constituent particles are significant on the cracking behavior of the rock specimens. To further investigate the size effects, the bonded-particle model (BPM), which is based on the discrete element method (DEM), is adopted in the present research. In flaw-containing specimens, by varying the crack resolution (?= a/2R), which is the ratio of half flaw length (a) to particle size (2R), the size effects on cracking behavior under compressive loading are studied. By keeping the flaw length constant, the particle size is varied independently in the BPM analysis. Decreasing the crack resolution increases the first crack initiation stress, but it has no obvious effects on the uniaxial compressive strength. The trajectories of the first cracks and secondary cracks hence generated have a higher resolution and are well-defined in those specimens possessing a higher crack resolution. On the contrary, in lower crack resolution specimens, the macroscopic first cracks appear to be wider and less continuous. These findings from numerical simulation clearly demonstrate particle size effects on cracking behavior. Special attention should be paid to these effects in future numerical study using the bonded particle model.

Jan 1, 2015

By \/eena Sahajwalla, Alexander Blagus

This paper reports the effect of using High Density Poly-Ethylene (HDPE)/coke blends on the reduction behaviour of Mn3O4 to MnO at 1000°C. The results suggest that CH4 release increases with increasing HDPE addition. The results show that the rapid release of methane, over only the initial five minutes, limited the interaction of Mn3O4/MnO with CH4. With the devolatilisation of HDPE there was increased porosity in samples containing HDPE, assumed to be the major factor in differences of reduction rates.

Jan 1, 2011

By Karl J. C. Harries

"2.1. INTRODUCTIONNo agreement can be perfect in the sense that it contemplates and provides for all eventualities. Mineral acquisition agreements are usually negotiated and drafted at a time when an orebody is no more than a gleam in a geologist’s eye, so it is hardly possible to provide for development and operation in other than the most general terms. However, an agreement that stops short of contemplating the possibility of an orebody and production is ill-advised. Accordingly, it is important to provide procedures to make decisions that will let the project proceed, even in the face of a fallingout between parties. Whether the parties are shareholders in a corporation or venturers in a contractual common undertaking like a joint venture, differences of opinion and disputes will occur. Unfortunately, more and more are ending up before the courts. Besides greed and the growing tendency in society to fight rather than talk, there are other factors that contribute to the increase of litigation. In some jurisdictions, agreements have tended to become complicated, often defying interpretation, even by a lawyer, and explorationists want their budgets to go into the ground as constructive work rather than into a lawyer’s pocket. All this has led to a growing tendency for corporations to take the attitude that the chances of finding a mine are, at best, marginal and there are lots of earlier agreements in the files to draw from, so why not prepare their own agreements? As discussed in the preceding chapter, this can be folly. All these factors can quickly have parties facing each other in court while a project sits idle. Added to this is the problem that, in some jurisdictions, lawyers may take cases on a contingency-fee basis, sometimes promoting the pursuit of a nebulous claim.When an orebody is discovered, someone will always want some, or more, for himself. There is a breed of “prospectors” who prospect for legal actions, on the somewhat sound grounds that a major corporation will buy off nuisance litigation, rather than incurring the cost and effort of attacking even a poorly founded claim in the courts. They may even find a winner. Besides, it is far more comfortable and relaxing to prospect for problems and legal niceties than to prospect for an orebody.1 In short, it is appropriate to consider briefly some of the factors relating to lawsuits and judgments. Although many of the comments are made in the context of the common law and the Canadian legal system, most of the concepts and suggestions are applicable to any legal system."

Jan 1, 2003

By F. Khomamizadeh

In this study the effect of solidification rate, T6 and T7 heat treatments on thermal fatigue resistance of A319 aluminum was investigated. Increasing of the solidification rate improved the thermal fatigue resistance of the alloy by refinement of the microstructure. The most sensible areas for thermal fatigue crack growth were the eutectic zones, T6 and T7 heat treatments improved the thermal fatigue resistance of the alloy by enhancing of the matrix resistance against the crack propagation. The slight reduction of the thermal fatigue resistance after T7 heat treatment is attributed to coarsening of the precipitates which reduces the matrix resistance.

Jan 1, 2005

By P. Abachi

Cemented carbides or hard metals that generally consist of hard tungsten carbide and a tough metal binder such as cobalt are important in many segments of the world economy, ranging from automobile related components to machining, cutting, and drilling tools. For metal cutting operations such as turning and milling, replaceable cemented carbide inserts are frequently used. The exposure of inserts to very severe conditions (e.g. temperatures as high as 1000°C) in combination with very high loads, limits their lifetime. When the tools and components are scrapped, they are collected with a view to recovering the tungsten carbide and cobalt due to both their environmental aspects and their strategic importance. In this work, a selective electrolysis process was used for recovery of WC powder particles from cemented carbide scraps. The WC-10Co and WC-10Co-VC up to 3 wt.% VC was produced using powder metallurgy route. The mean particle size of WC, Co and VC were selected as 2.5, l.5 and 2.2 µm respectively. Referring to electrochemical curves of WC-10Co cemented carbides in hydrochloric acid solutions with different concentrations, the recovery rate was enhanced in IN acid. Therefore, this solution was selected for recycling of all samples. The surfaces of as-produced and corroded specimens were investigated using a scanning electron microscopy (SEM). Detection of corrosion products was provided by energy dispersive spectrometry (EDS). According to results, the selective electrolysis process could be useful in the recycling of scrap carbide materials, although more studies should be undertaken on economical aspects of the process and the quality of samples produced using recovered powders.

Jan 1, 2005

By Michael Samis

The real option valuation method is often presented as an alternative to the conventional discounted cash flow (DCF) approach because it is able to recognize additional project value due to the presence of management flexibility. However, these two valuation methods can be separated on a more fundamental level by their differences in risk discounting. Real option valuation applies the risk-adjustment to the source of uncertainty in the cash flow while the DCF method adjusts for risk at the aggregate level of net cash flow. This seemingly small difference is the reason why the real option method is able to differentiate between projects according to each project?s unique risk characteristics while the conventional DCF approach cannot. This paper provides an overview of the real options and DCF valuation frameworks and discusses the differences in risk discounting that exist between the two methods. Using grade-school mathematics, this paper clearly demonstrates how, with real options, a unique project risk discount can be calculated which is directly linked to the project?s unique risk profile. It also highlights why the DCF method fails in this regard and shows why a call to ?increase the Risk-Adjusted Discount Rate? is an incomplete solution at best. Finally, a heap-leach project and satellite reserve development project are valued with both techniques and the difference in investment conclusions is explained in terms of the risk-discounting concepts discussed here.

May 1, 2003

By F. Habashi

Magnesium is the eighth most abundant element in the earth's crust, It occurs in nature in sea water, brines, and a number of minerals, Metallic magnesium was first isolated by Humphry Davy (1778-1829) in England in 1808 via electrolysis of anhydrous magnesium chloride with a mercury cathode, Antoine Bussy (1794-1882) in France extracted the metal in 1828 by reducing fused magnesium chloride with metallic po¬tassium vapour, The first industrial production of magnesium by electrolysis of molten carnallite began in 1886 in Hemelingen in Germany, In 1940 Lloyd M, Pidgeon (1903¬1999) in Canada pioneered the first industrial metallothermic magnesium extraction plant based on the reduction of dolomite with ferrosilicon under vacuum, Since then the magnesium industry developed further and a variety of processes are presently used.

Jan 1, 2006

By R. Lasmanis

"Washington State's diverse geological setting is reflected by its several types of porphyry Cu-Mo deposits. All are associated with calc-alkaline intrusions, and they range in age from Jurassic to Miocene.The largest is the Mount Tolman Mo-Cu deposit located in the Omineca Belt. It contains 2.18 billion tonnes of material averaging 0.093% MoS2 and 0.09% Cu. There are intermediate-size Mesozoic deposits in the Intermontane Belt. The Cascade volcanic arc hosts small- to medium-Tertiary deposits. Among these, of particular interest is the Sunrise breccia pipe, which has been explored over a vertical distance of 1000 m. It contains reserves of 64.6 million tonnes averaging 0.319% Cu and 0.071% MoS2 with significant tungsten values. The Glacier Peak deposits have potential resources of 1.7 billion tonnes averaging 0.334% Cu and more than 0.015% MoS2 and also contain tungsten. The Margaret deposit can be classified as a porphyry Cu-Au type; it has reserves of 200 million tonnes averaging 0.434% Cu, 0.0175% MoS2> 0.27 g!t Au and 1.92 g!t Ag. Drill intercepts of the North Fork deposit also show significant gold values.Mineralization and hydrothermal alteration of these deposits are typical of porphyry deposits, although some differences can be noted. The Mount Tolman molybdenum deposit contains topaz alteration zones and is transitional between a plutonic type and a Climax-type molybdenum system. Other deposits, such as the Kelsey, Mazama, North Fork, and Margaret, are low-sulphide systems that contain significant amounts of magnetite."

Jan 1, 1995

By L. Veleva, Garcia. A., G. Perez

Aluminum is a metal used for the transmission of electricity of high voltage, in the construction industry and other areas. In atmospheric conditions aluminum forms an oxide layer (Alz03'H20) as a result of its corrosion, entering the passive state. The oxide layer can be destroyed by the presence of ions (Cr, SOx-n) developing localized (non uniform) corrosion attack by pitting, difficult for evaluation. The concepts of fractals and self-similarity were used in this study for the characterization of the development of localized corrosion. Images obtained with a scanning electron microscope (SEM) of samples of electrolytic aluminum wire that have been exposed during one year in ruralurban and marine-coastal environments of the humid tropical climate of Mexico, have been processed. The development of pitting has been studied as a function of time, making a statistics of the frequency of appearance of pits versus the area occupied by them. The data show that the distribution of the pits follows a power law. Therefore, the concept of self-similarity can be applied for the study of the phenomenon of localized corrosion, describing their development with time.

Jan 1, 2006

By V. P. Mehrotra, D. W. Fuerstenau, A. -Z. M. Abouzeid

The use of pulverized coal for electric power generation results in the production of vast amounts of fly ash. One potential use for waste fly ash is the production of pellets for lightweight aggregates. This paper is concerned with the role of the physical and chemical characteristics of two different fly ashes in governing their agglomeration or pelletization behavior and their strength characteristics. In batch balling experiments, fly ash pellet growth was found to be extremely sensitive to the amount of moisture added. One ash (Mohave) exhibits marked pozzolanic activity whereas the other (Jim Bridger) does not. The pozzolanic activity has a very pronounced effect on pellet growth kinetics, moisture requirements, and the effect of various additives on growth kinetics. Slow drying under ambient conditions produces strong pellets from Mohave ash whereas Jim Bridger ash pellets lacking in pozzolanic activity are weak. Rapid drying at high temperatures results in weak pellets because water necessary for hardening is driven out of the pellet. Steam curing enhances pellet strength. Locked-cycle pelletizing experiments exhibit expected oscillation in pellet production rates and attendant fluctuations in pellet green strength.

Jan 1, 2004

By F. Tanaka

Copper losses to discard slag have long impacted on the profitability of copper smelters. Businesses based on the treatment of secondary materials have also revealed that copper losses are indices of precious-metals losses. Many custom smelters are thus required to obtain more reliable controls for reducing copper losses than ever before. Mitsubishi Materials Corp. has cooperated with academic research institutes in conducting research projects on the pyrometallurgical fundamentals of copper smelting systems, including mutual evaluation of magnetite behavior between synthetic and industrial slags. The state-of-the-art pyrometallurgy has subsequently been introduced to Naoshima smelter for controlling the Mitsubishi process. The revised controls function successfully and the operational results demonstrate that avoiding the discharge of solid magnetite from the S-furnace is quite effective to reduce copper losses. Magnetite behavior has been controlled over the Mitsubishi process so as to reduce copper losses while satisfying the needs of recycling businesses growing in Japan. In-situ estimation of magnetite behavior using the absorbed heat from the melts to cooling water will also be discussed.

Jan 1, 2007

By Andrzej Luszczkiewicz, Magdalena Duchnowska, KGHM Polska Miedz S. A., Witold Pawlos, Jan Drzymala, Alicja Bakalarz, Przemyslaw B. Kowalczuk

Numerous data in the literature confirm that the chemical composition and consumption of grinding media influence electrochemical properties of flotation suspension as well as effectiveness and selectivity of upgrading processes. During a milling process, attrition of grinding media is observed. Depending on the susceptibility to abrasion, the grinding media influence, to a different extent, the redox potential, pH as well as flotation efficiency. As a result, different upgradeability of sulfide minerals is observed. The paper presents laboratory scale flotation results, obtained for the copper sulfide ore from Polkowice Region of KGHM Polska Miedz S.A. in Poland ground in the presence of forged steel, highchrome iron and stainless steel as the grinding media. The investigated flotation feed contained 36 g/t (ppm) of silver and 1.86 % of copper. Several flotation tests were conducted using fixed amount of frother and a mixture of sodium ethyl and isobutyl xanthates as the collector at three different doses of 75, 100 and 125 g/t. A comparison of the obtained results confirmed that the application of grinding media with different chemical compositions influenced the electrochemical properties of the suspension and recovery of silver and copper in the final concentrate. The highest values of redox potential were observed for the stainless steel as the grinding medium. Moreover, in the presence of this type of grinding media, regardless of the collector dosage, the best silver upgrading was observed. For the forged and high-chrome iron media, the recovery of silver depended on the collector dosage. It is indicated that higher levels of the redox potential, together with smaller amount of iron released from the grinding medium, improve the flotation of the silver-bearing mineral compounds from the copper sulfide ore.

Jan 1, 2016

By J. Gebhardt, D. McBride, C. R. Bennett, Croft. N., M. Cross

A comprehensive model of solution flow through heap leach systems requires a numerical solution with the ability to predict variably saturated-unsaturated flow through porous media domains that contain materials with spatially variable properties. The types of flow associated with stockpile leach processes lead to flow problems, such as infiltration into dry soil, drainage, perched water tables and flow through heterogeneous materials. Computational methods for modelling this class of flow behaviour are conventionally based on the classical Richards' equation. However, the governing equations are highly non-linear, difficult to solve, and require iterative numerical solution methods. The pressure-based form of the Richards' equation suffers from poor mass balance, while the mixed form can possess convergence difficulties. An adaptive transformed mixed algorithm is described, which reduces the non-linearity of the problem, optimizes the time step size, and provides a fast, numerically robust scheme that significantly reduces computation (or CPU) time. This method is shown to give fast, accurate solutions on a number of complex flow problems. The utility of this algorithm is illustrated through its implementation within the PHYSICA computational modelling software, which incidentally, provides a framework for a comprehensive heap leach model.

Jan 1, 2005

By J. N. Van der Merwe, M. Mathey

"We present an analysis of the mechanical properties of coal specimens from various coalfields and seams in South Africa. Our database comprises of 1800 test results from uniaxial and triaxial compression tests, as well as indirect tensile strength tests, which we collected from the various mining houses and research agencies in the country. We inspected the database for possible errors and present a brief description of the verification procedure in the paper.In the analysis, we reveal that the collected samples of strength and elastic properties of South African coals can be represented by single lognormal or normal distributions with only few outliers. This finding indicates that the samples realistically approximate the population of mechanical coal properties in the country and may suggest that the properties are randomly distributed. Significant coalfield- or seamspecific trends for the mechanical properties of coal are not clearly discernible from our data.Typical coefficients of variation for the individual mechanical properties range between 25-50 % on a country-wide and seam-specific level of analysis. Average uniaxial compressive strength values, however, are closely clustered for all seams. A comparison with data available from international coal strength studies show the distinct difference between South African coals and seams in countries of the Northern Hemisphere, where differences in the average coal seam strength are more pronounced.We observe that the number of specimens whose failure mode is influenced by the presence of natural discontinuities reduces drastically with the application of very small confining pressures to the specimens. Further, the strength-reducing influence of discontinuities diminishes with increasing confining pressures."

Jan 1, 2015

By B. Kenney

For SOFCs, composite cathodes comprising an electronically conducting electro¬catalyst (e.g. LSM) and an conically conducting electrolyte material (e.g. YSZ) are considered to improve the electrochemical performance by extending the active reaction zone to regions beyond the electrolyte-electrode interface, as in the case of conventional cathodes. Interpretation of experimental data for composite cathodes, however, is complicated by the mixed conducting behaviour which results in local overpotential distributions throughout the composite cathode. These local overpotentials depend on many factors, such as the composition, particle size, porosity and thickness of the cathode. Reliable experimental data obtained from composite cathodes requires carefully crafted microstructural parameters in order to minimize the overpotential variations. A mathematical model of a composite cathode was developed using coupled differential equations describing transport and consumption of chemical species, oxygen ion and electrons. Simulations under various oxygen concentrations were used to obtain the reaction order of the oxygen reduction reaction. An apparent po2 dependency was then extracted from the predicted Rp vs P02 data. It was found that this p02 dependency can be significantly influenced by the micro-structural parameters of a composite cathode, primarily due to local overpotential distributions.

Jan 1, 2005

By Bennett McLaughlin

AGNICO-EAGLE started sinking the Penna Shaft in 1995 with a hoisting plant capable of hoisting 1,800 tonnes per day from a 2,240 metre deep shaft. Exploration success lead to the installation of a hoisting plant capable of extracting 4,500 tonnes of ore and 1,800 tonnes of waste per day from a depth of 2,210 metres. The introduction of a new rope selection factor, permitting a safety factor of 4.0, represented the breakthrough required for a cost-effective project. This paper describes the process taken to introduce the new rope selection factor and its impact on the original plant.

May 1, 2001

By J. W. Craig

CHROME ore, which is used in Canada in the production of ferro-alloys, in a variety of refractories, and indirectly in many chemical industries, is both commercially important and scientifically interesting. The sight of chromium metal is familiar to all of us in the home, the office, the automobile. Chromium is synonymous with armaments: it is understood to be one of several essential metals in tanks, which played an important role in the defeat of France in the spring of 1940. Chromium, in other forms, comes into our daily lives by way of paint and leather, of the familiar green ginger-ale and beer bottles, and more indirectly in every pound of steel produced in the .Dominion. Necessary to our civilization in peace and war, the ores of chromium occur in many corners of the earth. This paper attempts to describe the chemical constitution of chrome ores, their world distribution, and the various chrome products and their industrial applications in Canada.

Jan 1, 1940

By P. -Q. Wu

A modified electrochemical noise (EN) technique has been applied to monitor corrosion wear of TiN-coated ASP23 steel and TiN-coated AISI 316 stainless steel sliding against corundum in 0.5 M H2SO4. Experimental results show that the EN technique can sensitively detect potential and current variations during a corrosion-wear process. Corrosion-wear mechanisms of TiN coatings depend on their substrate properties. If the substrate is passive, such as AISI 316 stainless steel, the potential and current variations reflect the properties of the coating. Depassivation and repassivation alternately take place on the tribo-activated wear area during the steady-state phase. If the substrate is active, such as ASP23 tool steel, the electrochemical noise is dominated by dissolution of the substrate at the pinholes and the hydrogen evolution all over the exposed surface.

Jan 1, 2005

By Chr. Krause

Within the scope the collaborative research centre 599 (Medical University of Hanover, University of Veterinary Medicine Hanover, University of Hanover) the behaviour of the degradation of magnesium materials as implants are investigated by using animal experiments (rabbits). Thus extruded cylindrical pins from the magnesium alloys MgCa0.8%, WE43 and LAE 442 were implanted intramedullary in the tibiadiaphyses. The implantation duration was 3 and 6 month. After the explantation 3 point bending tests were carried out to investigate the possible changes of the mechanical properties. Clearly changes in dependence of the implantation duration could be determined. The three magnesium alloys show a decrease of the mechanical resistance with an increasing implantation time. To evaluate the degradation process, wich is the reason for the changes, micrographs and element analyses (EDX) have been accomplished after the 3 point bending tests. The micrographs show for all used magnesium alloys corroded surfaces but no preferred corrosion on the grain boundarys. The element analyses show beside a layer which is rich in calcium and phosphorus an agglomeration of rare earth elements in this layer. With these results a using of magnesium alloys as a material for implants can be announced.

Jan 1, 2006