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By A. Romero

"Most underground mines require heating or cooling systems to meet health and safety standards in the working areas. In regions where daily or seasonal fluctuations of environmental conditions exist, these systems tend to be over-sized and operate at low average load factors, which increase both investment and operating costs. One possible approach to reduce the temperature variations of the fresh air supplied to the mine, and so reducing the investment in large heating or cooling systems, is to use rock as a thermal regenerator or thermal storage system. Packed rock beds act as thermal inertial units, damping the atmospheric temperature oscillations to provide a more constant fresh air temperature. However, although regenerators exist in some mines, and packed bed rocks have been studied in detail in solar thermal power applications, there is a lack of tools to design new and sufficiently large storage systems of this kind. This work fills the existing gap by presenting a methodology to design and evaluate the impact on the ventilation systems of these regenerators. The method is validated using existing rock bed systems found in the literature and illustrates possible designs for small and large size regenerators in both hot and cold climates.1 INTRODUCTION “ It is quite amazing how often answers to extremely complicated problems can be obtained in this way, by using greatly simplified models of the real situation for the purpose of calculation.” Whiller, A. in private communication to J. S. Stachulak (1989). Motivation Most underground mines located in regions with extreme climatic conditions require the thermal pre-treatment of the fresh ventilation airflows, whether for heating or cooling. Heating commonly is needed in sites with sub-zero temperatures and is usually effected by direct or indirect burning of natural gas or propane. Alternatively, cooling is required in areas with hot temperatures, or in mines with high underground thermal loads where the fresh air at ambient temperature cannot provide enough refrigeration. Thus, when the ambient air conditions cannot provide by itself enough thermal power to ensure safe underground working conditions, a heating or cooling plant is required, which involves a considerable equipment and operation cost."

Jan 1, 2019

By Ahmad Ghahreman, James McNeice

"Cerium is the most abundant rare earth metal and is often found in deposits along with small amounts of more valuable metals such as neodymium and gadolinium1. As a result, the production of cerium oxide often exceeds market demands, thus in some cases it would make more sense to remove the cerium from the process solutions before further purification. A common method of cerium removal is to precipitate CeO2 from the acidic leach liquors by raising the pH to oxidize cerium(III) to cerium(IV). This study investigates the oxidation kinetics using three oxidants; hydrogen peroxide, sodium hypochlorite, and potassium permanganate. The effect of oxidant, pH, cerium concentration and temperature on the oxidation kinetics will be discussed. Cerium oxidation in solutions with pH ranging from 1.0 to 4.0 was investigated at cerium concentrations ranging from 2.0 g/L to 16.0 g/L. A cerium recovery of 40% can be achieved at different conditions with each oxidant at room temperature, with higher recovery at 60°C.INTRODUCTION Over the last 70 years, the rare earth elements (REE) have become crucial components of modern technology. These metals are categorized as light rare earths (LREE) or heavy rare earths (HREE) by governments and miners based on weight, abundance, and therefore value. The minerals bastnaesite, monazite, and xenotime compose the majority of the world?s exploitable sources of these metals (Binnemans, 2013; Parker and Baroch, 1971). Geologists classify the LREE ores as „cerium group? minerals, approximately 50% cerium oxide by weight. The cerium group minerals monazite and bastnaesite compose the majority of world production, leading to an overproduction of cerium relative to world demand. This ratio of light to heavy REE in deposits has led to a phenomenon referred to as the balance problem (Binnemans et al., 2013). As an example, to produce 1 tonne of europium oxide from a bastnaesite deposit 450 tonnes of cerium oxide must be processed. This means that any push to increase production and access the value of the HREE metals will drive down the value of the LREE metals leading to diminishing returns (Zepf, 2016). These ores also contain measurable levels of thorium, subjecting them to complex radioactive waste regulations. During the 20th century, the USA was the largest producer of rare earth metals (REMs), primarily sourced from the Mountain Pass mine in California. However, due to a combination of market dynamics and regulations, China has dominated the market for the last two decades. The largest Chinese REE mine, Bayan Obo, produces rare earth (RE) concentrate as a byproduct of iron mining, decreasing their relative production costs (Gupta and Krishnamurthy, 2005). This mine alone represents about half of world bastnaesite production (Zhi and Yang, 2014). Rising demand for high-tech products has forced Chinese producers to commission other large mines, climbing to 90% of world production in the early years of the new millennium (Mancheri, 2016). This presents the west with a looming supply risk of these critical metals in the future."

Jan 1, 2017

By Mike Dry, Mani Manimaran, Mykolas Gladkovas, Mariam Melashvili, Chris Fleming

Development of a new hydrometallurgical flowsheet requires quantitative description and optimisation of all chemical processes in each step in the process, as well as mass and energy balances across a fully integrated circuit incorporating all the unit operations. This paper covers steps leading to early modelling of a gold processing plant based on a bromine/bromide lixiviant. Research conducted at SGS Lakefield in collaboration with Albemarle provided the data that were used in the development of this model. A previous investigation in this series described the leaching behaviour of various mineral types in Stabilized Bromine reagent. This paper is concerned with the gold recovery operations associated with a conceptual bromine leaching process. The recovery of gold by different types of resin and activated carbon was studied, along with various methods of stripping the gold from the extractant. The circuit is closed by electrolysing the spent leach liquor to oxidize some of the contained bromide back to bromine that would allow recycling the regenerated leach solution back to the leach step in the process.

Jan 1, 2015

By B. Tonn, F. Kröger

"The continued development in engine technology is leading to an augmentation in power density which steadily elevates the requirements for thermally and thermo-mechanically highly loaded components such as cylinder heads and pistons. Due to these high performance requirements conventionally applied Al-Si alloys have reached their application limits, since their mechanical properties deteriorate quickly under the influence of heat. Improved applicability is given by Al-Cu-based casting alloys which have a superior high-temperature strength than Al-Si alloys. Since Al-Cu alloys exhibit insufficient casting characteristics, especially regarding hot tearing susceptibility and increased tendency for porosity, it is currently not possible to cast geometrically complex components in robust permanent mold casting processes. The further development of Al-Cu alloys is aimed at finding an optimum between improved castability while high-temperature strength and thermal conductivity are not deteriorated. It is known that a high amount of eutectic reduces the hot tearing susceptibility of an alloy, but it reduces thermal conductivity at the same time. In this paper it will be presented how the conflicting objectives – improved high-temperature strength, good thermal conductivity and reduced hot tearing susceptibility – can be brought together to develop an optimized Al-Cu alloy for application in permanent mold casting.INTRODUCTION At the beginning of the 21st century car, engine blocks were primarily made of gray cast iron (GJL). Less than half a decade later, the choice of material had shifted towards lightweight materials. Ever since, the car engine manufacturing is dominated by aluminum-based alloys. The weight of car engine blocks could thus be reduced by around 50% due to the lower specific weight of aluminum alloys compared to gray cast iron. Furthermore, the high thermal conductivity of aluminum alloys allowed a reduction of complex cooling channel systems and thereby promoted the advancement of this material group. The further development in engine technology leads to an augmentation in power density which elevates the requirements for thermally and thermo-mechanically highly loaded components. For example, in diesel-powered car engines the upper required limits can reach an ignition pressure as high as 230 bar and gas temperatures of up to 1000°C. Thereby, thermal loads can cause high alternating thermal stresses (Grzincic, 2003) which can effectively be reduced by providing high thermal conductivity."

Jan 1, 2017

By John J. Jonas, Hong Qin

Cylindrical samples of pure titanium were subjected to uniaxial compression at room temperature, leading to the formation of three generations of twins. Many primary contraction twins were observed as the initial texture was favourable for their formation. Numerous secondary extension twins formed within the primary contraction twins and some tertiary contraction twins within the secondary extension twins. The orientations of these three generations of twins were determined by electron backscatter diffraction techniques and their associated Schmid factors (SFs) were calculated. The formation of the twin variants selected in each generation and the absence of certain potential variants are accounted for by rotating the twinning displacement gradient tensor expressed in the twin system reference frame into the crystallographic reference frame of the relevant neighbouring grain. The presence of the observed primary, secondary and tertiary twins is explained in terms of the ease of imposing the required accommodation strains on the neighbouring grains. By contrast, certain first, second and third generation potential high SF twins were absent because their formation would have required accommodation by the most difficult deformation mode: pyramidal glide.

Jan 1, 2015

By J. Basi, D. F. Rucker

"A review of historic operating practices of the heap leach pads at the Los Filos Mine, Mexico, revealed periods of restricted cyanide addition, reduced leach time, and insufficient irrigation flow. These issues all led to the buildup of partially leached recoverable gold inventory within the leach pads. Drawing down this inventory represented an opportunity to bring value forward. This paper outlines the strategic initiatives which were implemented as efforts to accelerate the inventory drawdown, including geophysical mapping and pressure injection.INTRODUCTION Los Filos is a heap-leach operation located in the Guerrero gold belt in southern Mexico. Operational and hydraulic challenges at the Los Filos Mine have led to a buildup of gold in inventory within the leach pads. Operationally, periods of restricted reagent addition, reduced leach time, and insufficient irrigation flow have compounded over the last eight years, and resulted in significant inventory growth. Hydraulically, the leach pad has issues with low permeability and solution channeling due to the fines and clay content of the ore. The leach pad is storing high-grade pregnant leach solution (PLS) as perched aquifers above areas that are compacted and difficult to drain. These operational and hydraulic challenges made it particularly difficult to spatially predict the precise locations of the inventory build-up. Fortunately, the challenges at Los Filos are not unique to the mine, and others have taken steps elsewhere to reduce metal inventory through a program that targets areas for inventory drawdown. For example, Ghorbani et al. (2016) noted that a method of injecting barren reagent solutions, applied directly to specific areas of a leach pad to reduce inventory, was presented by Wan and Brierley (1997) and Wan (1997). Seal (2004; 2007), Seal and Jung (2005), and Seal et al. (2012) have put the injection methodology into practice in Nevada and Colorado gold mines with a technology called Hydro-Jex®. The goal of Hydro-Jex has been to supply reagents at a high pressure over a short duration, followed by periodical low pressure rinse periods to remove leached metal and resupply fresh reagent to the ore."

Jan 1, 2017

By J. Budac, J. Dennett, D. Mayne, P. Nawrocki

"The Nickel/Cobalt operation in Fort Saskatchewan, Alberta has successfully used an oxidative ammonia leach process to refine a variety of feeds into high quality nickel and cobalt products for over 60 years. Fundamental changes to the refining process were made when the major feed was converted from nickel concentrate to cobalt rich mixed sulphides in the early 1990s. Since the early 1990s, the production capacity of the refinery has expanded to match increases in both mixed sulphides and other feeds. In addition to increasing the production capacity of the refinery, other changes have been required in order to improve the operability and reliability of the refinery as well as to deal with increasingly stringent safety and environmental requirements. This paper describes recent changes at the refinery including changes to the flow sheet, improvements in unit operations, incorporation of new feeds, management of byproducts, and control of impurities.INTRODUCTION The Cobalt Refinery Company (Corefco) plant in Fort Saskatchewan processes nickel-cobalt mixed sulphide intermediate produced at the lateritic nickel mine and high-pressure acid leach (HPAL) facility in Moa Bay, Cuba. Both operations are jointly owned and operated by Sherritt International and General Niquel of Cuba. The mixed sulphide, along with other feed materials, is processed at the Fort Saskatchewan refinery using a pressure ammonia leach-hydrogen reduction process to produce nickel and cobalt metal. This refinery was originally constructed in 1954 to treat nickel concentrate from Sherritt’s Lynn Lake mine in Manitoba. (Benson and Colvin, 1964; Boldt and Queneau, 1967; Forward, 1953; Forward and Mackiw, 1955; Kerfoot, 1989) From the mid-1970s until the early-1990s, the facility operated as an independent refinery, treating nickel-bearing feeds from around the world. The flowsheet was changed in 1992 to address the increased cobalt content of the feed. (Cordingley and Krentz, 2005; Kerfoot and Cordingley, 1997) The flowsheet was adapted further in 2009 to improve cobalt speciation in the leach process, which allows better cobalt-nickel separation. The 2009 iteration is shown in Figure 1. Three ammonia leach stages were used to ensure high recoveries of nickel and cobalt. Underflow solids from the final leach stage contained mainly iron oxides. One of the features of the leach process is the innovative recycling of ammonia. Ammonia vented from the leach process in tail gas and from atmospheric tanks is recovered and recycled into the refinery using water based scrubbers and a high pressure distillation process. Indeed, roughly 250 t NH3/d is recovered as distillate and recycled back into the process. Also, air enriched with ammonia which is vented from the later first stage autoclaves is recycled to the lead first stage autoclaves to maximize oxygen and ammonia utilization."

Jan 1, 2017

By M. A. Bérubé, M. Choquette, P. W. Godbehere

"RESUMELa scorie produite par le procédé pyrométallurgique d'extraction Noranda contient environ5% de cuivre. Elle est traitée comme un minerai conventionnel de cuivre au concentrateur de Mines Noranda et les rejets de flottation présentent encore des teneurs souvent supérieures à 0.3% en cuivre. La scorie est principalement constituée de magnétite, de fayalite et d'un verre siliceux. Bien sûr, Ie cuivre y est majoritairement sous forme de sulfures et d'un peu de cuivre métallique. Le verre contient toutefois un peu de cuivre en solution, de 0.14 à 0.33% en moyenne, selon l’echantillon examine, ce qui représente à peine 1% de tout Ie cuivre de la scorie. Dans les rejets de flottation, cela justifie par contre de 15 à 25% des pertes totales en cuivre, Ie reste se retrouvant sous forme de tres petits globules de sulfures de cuivre ou de cuivre métallique, en moyenne de 2 à 3 micromètres de diamètre et bien emprisonnes dans Ie verre.SUMMARYThe slag produced by the Noranda continuous smelting process usually contains about 5% copper. It is processed as a conventional copper ore at the concentrator of Noranda Mines. The flotation tailings still often contain more than 0.3% Cu. The slag is mainly constituted by magnetite, fayalite and a siliceous glass. Evidently, the copper occurs mostly as sulphides and, to a lesser extent, as metallic copper. However the glass contains a small amount of this metal in solution, between 0.14 and 0.33% on an average, depending upon the investigated sample. This represents scarcely 1% of the total copper in the crude slag, but as much as 15 to 25% of this metal in the flotation tailings, in which the major part of the copper occurs as very small globules of copper sulphides or metallic copper with an average diameter of about 2 to 3 um and well-locked in the glass."

Jan 1, 1987

By F. Calizaya, S. Bhattacharyya

"This study presents the results of a set of sound level measurements carried out in three underground mines where auxiliary fans are used regularly. Sound levels as high as 100 dB(A) by the workings and 115 dB(A) by the fans were measured in these mines. These levels are quite high even for intermittent noise. Ventilation layouts and best practices used to overcome potential problems related to overexposure to fan noise in underground hard-rock mines are presented here. Factors such as fan type, rotational speed, and silencer-duct arrangements and their effects on noise attenuation are discussed. INTRODUCTION Auxiliary fans are used in hard-rock mines extensively. They are used to ventilate development headings, crusher rooms, conveyor transfer points, and underground shops. They are also used in developing long tunnels and ramps. Depending on the flow requirements and space restrictions, single or double stage axial fans with rigid or flexible ducts are used. Usually, they are high pressure (3.75 kPa) fans with flow rates ranging from 7.1 m3/s to 30 m3/s. The input power varies from 15 kW to 113 kW (Mutama, 2004; O’Connor, 2008). Typically, a 113 kW fan can produce sound levels as high a 113 dB(A) (Howes, 2005). Silencers are often omitted for cost reduction purposes or when used, they are not well maintained. Furthermore, silencers provide limited attenuation depending on their length and type. Typically, the sound attenuation ranges from 10 dB(A) for a 1 × D silencer to 14 dB(A) for a 2 × D silencer, where D is the fan diameter. In a mine, the silencer is subject to wear and tear, especially when the silencer is used in harsh environments. The interior lining can get clogged and the acoustic fill can get covered by dust and diesel soot, thus reducing the silencer performance. Periodic cleaning of the interior casing can increase the attenuation capacity of a silencer by 6 to 9 dB(A) (Dabson & Acuña, 2017). However, this requires a special silencer design in which the inner cartridge can be removed, the sound absorbing material replaced, the inner casing cleaned and the whole set retrofitted. A number of techniques can be used to reduce auxiliary fan noise in underground mines. These range from selecting the right fan for the job to installing adequate silencers. The choice depends on the air quantity requirement at the working place, cross-sectional area of the opening, duct diameter, fan type (axial or centrifugal) and local restrictions. Auxiliary ventilation layouts and best practices used to overcome potential problems related to overexposure to fan noise in underground hard rock mines are presented here. Factors such as fan type, rotational speed, duct diameter, and silencer-duct arrangements and their effects on noise attenuation are discussed."

Jan 1, 2019

By Z. Z. Öztürk, N. Sarica, A. H. Üçisik, C. Bindal

"Titanium oxide films were fabricated on commercially pure titanium surfaces via anodization procedure. Anodization parameters, anodization time and voltage were altered, whereas temperature and chemical composition of anodization bath were kept constant. The main idea in this study is to obtain rough titanium-oxide surfaces. The type and feature of titanium oxide formed were observed via SEM and EDX analyses. What was revealed from SEM and EDX analyses were combined with Ti-O phase diagram in order to make judgment on the type of phases obtained, e.g. solid solution and/or compounds. Studies on the different regions of each sample showed that surfaces consist of different titanium oxide compounds with various O/Ti ratios in nano level and solid solutions varying in terms of chemistry on the same sample. Thus together rough surfaces and inhomogeneous distribution of "titanium oxides" were obtained. It was also found that when anodization time and voltage were increased, more granular surface with higher O/Ti atomic ratio was obtained."

Jan 1, 2015

By Han Xing, Cui Jianzhong, Qin Ke, Shao Bo, Zhang Haitao

In this paper, a new approach that uses hot-top DC casting process to producing multi-alloy ingots is present. The different type and size of composite and coated ingots (4045/3004/4045 three-layer composite ingots with section 630mm by 1500mm and 4045/3003 coasted ingot with F140mm/F110mm in diameter) are cast by this approach. The macro-morphologies and microstructures of the composite ingots, the temperature distribution and the element distribution in the interface zone were investigated, also and the interface bonding strength was measured. Results show that the solid supporting layer formed on the cooling plates plays a key role in the casting process of composite ingots. The solid supporting layer can prevent the blending of two melts by resisting the impact of alloy melt, which ensures the stable casting process and casting high quality composite ingots, because the contact height is increased using hot-top DC casting. In addition, fabrication and properties of 4045/3004/4045 three-layer composite ingots with section 630mm by 1500mm are reported in detail.

Jan 1, 2015

By T. R. C. Aston, C. M. K. Yuen, J. L. Gilby

"The access tunnels for the Donkin-Morien Mine in Cape Breton, Nova Scotia, comprise two parallel tunnels driven through a sedimentary sequence of sandstone, siltstone and mudstone to intersect the Harbour Coal Seam under the Atlantic Ocean, approximately 3.5 km offshore (Fig. 1). The No. 2 tunnel was driven a total distance of 3579 m using a 7.6 m diameter Loyat full-face tunnel boring machine (TBM) and was supported by steel sets. The No. 3 tunnel was initially driven a distance of 1027 m using drill and blast methods (dimensions 7.6 m wide by 5.3 m high) supported by rock bolts and shotcrete. This tunnel was then completed (front March 1986 to February 1987) using the tunnel boring machine to a distance of 3573 m.During the period May 1983 to December 1984, a major geotechnical research program was undertaken in the Donkin-Morien tunnels by Golder Associates in conjunction w,ith CANMET and the Cape Breton Development Corporation (Yuen et al., 1985). The research program included the monitoring of the performance of the TBM and drill and blast drivages, and the study of the thrusting characteristics and rock-interaction of the TBM excavation. The main emphasis of the research program was on the collection of field data which was to be made available in the form of a comprehensive report for the future use of others who might wish to carry out a detailed interpretation and analysis. The information gained from the program was also used during the tunnel"

Jan 1, 1988

By R. Holmwood, M. Faris, P. Holloway, M. Collins

Sulphuric acid addition is a major driver of the economics in the processing of nickel laterite ores by high pressure acid leaching (HPAL). Understanding the optimal acid addition rate is essential for the success of any HPAL operation, and this is especially true at Ambatovy, where the composition of the feed tends to vary significantly on a day-to-day basis. Most studies on the effect of acid on nickel extraction in HPAL have used laboratory testwork as their basis. Although these studies are invaluable in assessing the economics of a new project, they are limited by the range of ore composition that can be tested and the differences between the operation of the laboratory equipment and the commercial plant. To enable optimization of the acid addition at Ambatovy, operating data from the HPAL operation were obtained using OSISoft’s PI system and the data from several periods were examined to develop relationships between acid addition and nickel extraction. The initial relationships from 2014 focused on the acid required to achieve a target nickel extraction of 95%, with aluminum and magnesium in ore and feed slurry solids content as the major variables. As Ambatovy ramped up through 2015 and 2016, the calculated acid requirement was further refined to address the effects of HPAL temperature and retention time, and the oxidizing/reducing characteristics of the ore, and to generate acid requirement relationships as a function of ranges of nickel extraction. These relationships supported raising the target nickel extraction to 96% and enabled the development of an economic model between acid addition and nickel extraction.

Jan 1, 2017

By C. Samuelsson, H. Ahmed, B Björkman, A. Andersson

The cost of raw material and energy is a continuing driving force towards working with increasing the recycling of ore based steelmaking residues. In Sweden no on-site sinter plants are operated at the integrated steelworks. Instead, selected residues from the plant are incorporated in a cold bonded briquette product which is recycled to the process via the blast furnace (BF). Since the BF sludge is the major bleed of zinc out of the furnace it is required to be de-zinced prior to recycling in the briquette product. In the present work landfilled BF sludge has been characterized with respect to chemical composition, particle size distribution, X-ray diffraction (XRD), and scanning electron microscopy (SEM). The sludge was also subjected to laboratory scale hydrocyclone trials aiming at reducing the zinc content making the sludge viable for recycling. The results suggested that the sludge had been agglomerated prior to the characterization and hydrocyclone treatment. The zinc removal using the hydrocyclone was discussed.

Jan 1, 2015

Safety Leadership The management and leadership of a mining operation is a challenge at all times. The pressure to make production, safety, and environmental goals is intense. At some point mining cycles will put every operator into periods of time where economic issues seem to over-ride all other concerns. This is when leadership is most needed.

May 1, 2009

By W. D. Robson

THE prevention of silicosis by metallic aluminium has been reported by Denny, Robson, and Irwin in two papers. The first (1) was published in 1937; the second (2), in 1939. The results definitely established that silicosis was prevented in animals by the inhalation of small quantities of aluminium. The present communication records subsequent progress in this field of research. HARMLESSNESS OF ALUMINIUM Animal experiments having served their purpose, it became necessary to consider means to test the discovery on humans. A question for immediate consideration was: Is aluminium harmful to man when inhaled as a fine powder? While the animal experiments were reassuring, since they conclusively showed the powder to be innocuous when breathed by animals, it was, nevertheless, desirable to have additional reassurance with regard to its effect upon human beings. Through the courtesy of the Aluminum Company of America and especially the valued interest in this problem displayed by that Company's Director of Research, Dr. Francis C. Frary, a study was made of the records pertaining to the health of a group of 125 employees who had for many years been engaged in the manufacture of finely powdered, metallic aluminium for the paint and ink industries. The conditions were such that these employees had inhaled varying and oft-times very dense concentrations of this powder daily over periods ranging from 6 to 23 years, the average for the group being 12 years. X-ray pictures of their chests showed no abnormalities attributable to aluminium. Their general health seemed better than that of the 3,000 workers in other sections of the plant. In fact, the early films of three employees in this group of 125 showed shadows suggestive of minimal tuberculosis, which shadows were not discernible in films taken after considerable periods of exposure to aluminium powder. The harmlessness of aluminium was, by this study, reasonably well established at the outset, a finding subsequently verified by Ontario research on humans.

Jan 1, 1944

By M. R. Hudec, M. A. Nikolinakou, P. B. Flemings

"We model the shale response to the large deformations associated with salt bodies, and we identify the implications of the stress changes for hydrocarbon exploration. We employ both the static and evolutionary approach, and show that while the static one can model actual geologic geometries, only the evolutionary approach can provide a detailed description of the stress history of shales, which is essential for predicting stress, porosity, and pore pressure and, more generally, for understanding Earth processes related to salt-hydrocarbon systems.INTRODUCTIONDuring the last two decades, understanding the stress, material behavior, and pore pressure in shales around salt bodies has become increasingly important. The energy industry routinely drills near salt (Beltrão, Sombra, Lage, Fagundes Netto, & Henriques, 2009; Meyer, Zarra, Rains, Meltz, & Hall, 2005; Seymour, Rae, Peden, & Ormston, 1993), because a significant number of hydrocarbon reservoirs around the world are found in layers dipping away from salt diapirs.Salt is a viscous material that cannot sustain deviatoric stresses. Under differential loading it flows, changes shape, and eventually relaxes to an isostatic stress state (Urai & Spiers, 2007). Therefore, emplacement of a salt body and its viscous relaxation process may cause significant deformation of the surrounding sediments, perturb their state of stress and create local overpressures (Dusseault, Maury, Sanfilippo, & Santarelli, 2004; Seymour et al., 1993). As a result, drilling near salt is particularly challenging, and problems leading to additional expense or even abandonment are common (Bradley, 1978; Dusseault et al., 2004; Meyer et al., 2005; Seymour et al., 1993; Willson et al., 2003).Historically, salt and the evolution of its cross section to the present day geometry have been studied using kinematic restorations (Rowan & Ratliff, 2012). This approach aims to explain the present geologic section through a sequence of plausible past sections; however, it does not model the constitutive response of the wall rocks, hence it cannot provide any prediction on their state of stress. Similarly, largestrain numerical studies (Albertz & Beaumont, 2010; Chemia, Schmeling, & Koyi, 2009; Goteti, Ings, & Beaumont, 2012; Gradmann, Beaumont, & Albertz, 2009) have focused on the rheological evolution of salt systems without modeling the geomechanical response of the sediments."

Jan 1, 2015

By M. J. Latva-Kokko

This paper describes the behaviour of iron and the methods used for iron control in the nickel matte leaching process. OMG Harjavalta Nickel Oy processes approximately 10 000 t/y of iron, which enters the process with the nickel matte raw material. Iron dissolves and precipitates in several different stages of the leaching process. Compounds like ferric hydroxide, parabutlerite, goethite, hematite and jarosite are found. Iron removal is done within the leaching process, and this means that the dissolution of nickel sets the limiting conditions for iron precipitation. A leach residue consisting mainly of the iron precipitates is neutralized and stacked in the waste pond. When iron is precipitated from concentrated nickel sulphate solution, some nickel is lost by co-precipitation. Recent studies have shown that Ni-Fe ratios less than 1%, attributed to co-precipitation, can be obtained with jarosite precipitates, compared to 2-3% ratios typically found with hematite precipitates. Iron can be precipitated as jarosite under the optimal nickel leaching conditions by adding ammonium sulphate to the feed slurry of the autoclave.

Jan 1, 2006

By T. Kerr, C. Mattich, J. Wilson

"In refractory gold concentrates, gold is occluded in sulphide minerals preventing efficient cyanide leaching. Hence, roasting is used to oxidize sulphur and organic carbon, the latter being necessary to minimize recovery loss through the preg-robbing effect. In 2009, Outotec commissioned the circulating fluidized bed roaster at Syama gold mine in Mali. Since 2013 Resolute and Outotec have been implementing improvements to the roaster performance with the capacity increasing from 8000 t/month in 2013 to above 13,000 t/month in 2016, while achieving a residual sulphide sulphur and organic carbon contents of below 0.1 wt.% and 0.4 wt.%, respectively. Thus a gold recovery in the CIL of above 90% is attained. In 2016, Outotec audited the Syama roaster. The analysis resulted in the Low Carbon Roaster (LCR) upgrade concept which (i) allows re-processing of calcine dust from the spray cooler and ESP after pelletization and (ii) allows the roasting of a further fine-organic carbon rich feed, i.e. de-slime circuit tailings. The LCR upgrade aims to reduce organic carbon to <0.2 wt.% and increase roaster-leaching gold recovery by >3%. Project development included extensive testwork. The LCR process is expected to become operational during FY 2019.INTRODUCTION Double refractory sulphide ores exhibit the characteristics of gold locked within pyrite grains, in the presence of preg-robbing natural (organic) carbon. Hence, to achieve high recovery during subsequent processing steps, i.e. cyanide leaching, oxidation of sulphide sulphur is required, producing a porous calcine by way of a roasting step. This allows for the gold contained within the pyrite grains to be accessible during cyanide leaching. Furthermore, it is necessary to oxidize the organic carbon. Oxidizing the organic carbon is essential as gold recovery loss occurs as a result of gold-cyanide complexes being adsorbed on organic carbon, this phenomenon is termed as preg-robbing (Miller et al., 2016). The gold absorbed on the organic carbon is lost, reporting to the tailings stream. Hence, the aforementioned oxidation of sulphide sulphur and organic carbon is the process goal. Nonetheless, the latter must occur at a controlled temperature which is concentrate/ ore specific, since the pores of the produced calcine should not sinter, as this makes the gold contained in the calcine less accessible during leaching, leading to gold recovery loss. The tight temperature control requirement is a decisive factor in the choice of a Circulating Fluidized Bed (CFB) as the roasting reactor, due to the excellent mixing characteristics of the CFB which results in temperature homogeneity of (+/-10°C). Roasting of double refractory ores, as described above, can be included in the flowsheet after comminution and grinding, a process termed as whole ore roasting, or by including a flotation circuit termed as concentrate roasting. Roasting the flotation concentrate results in less solid flow, increased sulphide sulphur grade and organic carbon content resulting in a higher heating value and higher gold content. A typical composition of the Syama ore and concentrate is given in Table 1. Ore average values presented correspond to the period 2015, while concentrate values are typical for the flotation performance throughout the period 2012–2015."

Jan 1, 2017

By J. -F. Blais, M. -O. Simonnot, J. Mocellin, G. Mercier, J. -L. Morel

Large quantities of ferromanganese sludge are generated as waste material by blast furnace during the manufacturing of ferromanganese. These slags are very rich in manganese, zinc and lead (5 to 40 %). These residues have been deposited in a pond in periphery of the steel industry. Considering the market value of the metals, these brownfield sites can now be considered as secondary resources. We have developed a hydrometallurgical process for selectively leaching Zn, Mn and Pb in order to produce compounds of Mn and Zn pure enough to be economically recoverable and a residue rich in Pb. Batch laboratory experiments were carried out to determine appropriate leaching conditions to maximize zinc extraction (100 %) and manganese extraction (90.0 %) with sulfuric acid and to generate a residue containing 15 to 30% of lead. This Pb residue is recyclable by another process.

Jan 1, 2015