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By R C, K L. Rees, J S. J van Deventer

In contrast with previously published models for the carbon-in-pulp (CIP) process, the model proposed in this paper incorporates film transfer, intraparticle diffusion, simultaneous leaching, preg-robbing, the loading of multicomponent species, and the effects of fouling and changing cyanide levels. The rationale behind this comprehensive model is that changes in fouling and competitive adsorption along a CIP cascade affect the profiles of gold loading. As it is impossible to quantify all these non-ideal factors, a method is proposed whereby an imaginary species is postulated so as to combine all the competitive effects. A plant survey at the Telfer mine has shown that the mass loss due to a gravimetric analysis of the fouled carbon could be used directly to quantify this competitive effect. The degradation and consumption of cyanide along the Telfer CIP cascade enhance the loading of copper on to the carbon, which should be taken into account when modelling the gold profiles. It appeared that the effect of cyanide itself on the loading of gold was negligible compared with its effect on the copper. Evidently much more research is required on this topic in order to optimise CIP operations exposed to constantly changing conditions.

Jan 1, 1998

By I F. Wood

Planning for flooding and assessment of flood impacts are important requirements for mining projects, as they are also for other types of development. With more intense development and concern from the community, supported by government regulatory requirements, assessment of flood concerns and impacts has become of increasing importance. To ensure that flooding issues are fully understood and results presented in an appropriate format, advanced hydraulic analysis procedures have been developed and are beginning to be applied. These procedures must be rigorous in an engineering context but the results must also be readily understood by the community and government agencies. Advanced two-dimensional hydraulic modelling is becoming accepted as an important means of assessing flooding issues for mining projects. With presentation of results from hydraulic models with Geographic Information Systems (GIS), flood impacts can be analysed rigorously and presented clearly. This paper discusses the application of advanced hydraulic modelling in the planning and impact assessment of a major mining project located on a floodplain where there is extensive inundation. The analysis provides for both input to the planning of the project and for detailed assessment of potential impacts. This case study illustrates some important aspects of the application of hydraulic modelling using a two-dimensional modelling to a critical flood design.

Jan 1, 2003

By Neill T. J, Howarth D. F, Malcolm J. McPhersqn

For many years Isa Mine has seen the need for a continuous mining machine which will economically cut hard rock. Tunnel borers are unsuitable due to the size and inflexibility of the machine and the shape of excavation mined. The design of roadheader type machines will not permit the use of the necessary cutting technology. in 1983 a joint project was undertaken by The Robbins Company and Mount Isa Mines Limited to develop and to trial a machine suitable for cutting hard rock in an operating mine. The project was based on the proven technology of raiseboring applied to horizontal development. The Mobile Miner was fabricated and trialled in a disused quarry in the U.S.A. during early 1984. Following these trials, the machine was transported to Mount Isa and commenced mining in September that year. The initial duty was to continue the development of a decline commenced by conventional mining for a conveyor system to serve the deeper southern areas of the 1100 copper orebody. This system will permit direct tipping of copper ore to a new crusher complex and conveying of the - crushed ore approximately 2 kilometres to the central hoisting shaft facilities. The Robbins Mobile Miner MM120-3001 uses a vertical rotating cutting wheel mounted on a horizontal swinging boom to excavate a nominally rectangular shaped heading. The cuttings are collected on an apron and conveyed back through the machine. The resulting excavation is smooth-walled with no blasting damage to the surrounding rock. This provides a safer working environment than does conventional drill and blast development mining. Ground support requirements are considerably reduced.

Jan 1, 1986

By N Maistry, A Singh

It is estimated that in less than a decade, high-grade iron ore reserves in South Africa will be depleted, leaving only low-grade ores with a dominant lithology of banded iron formation (BIF) hematite. BIF is a complex ore reserve as it is typically liberated below 1 mm, resulting in high energy costs. However, due to its abundance, its beneficiation potential should be evaluated to maximise recovery at an acceptable product grade. To develop a beneficiation program for BIF hematite, the first step is to determine the effect of two laboratory crushing techniques on mineralogical characteristics, specifically liberation and shape. For this study, the cone crusher and high pressure grinding rolls (HPGR) were used. The Electron MicroProbe Analysis (EMPA) and Mineral Liberation Analyser (MLA) were used to compare the mineralogical characteristics. The liberation characteristics for hematite are similar for both crushing techniques; however, HPGR preferentially liberates quartz. HPGR achieved 8– 12 per cent additional quartz liberation in the greater than 80 per cent and 100 per cent liberation classes respectively and specifically in +75 μm size range. Improved quartz liberation is associated with lower energy requirements for downstream milling and improved separation efficiencies for beneficiation units that operate in this size range. Both samples displayed similar shape characteristics; most particles were elongated smooth and the rest were elongated angular. Good hematite liberation is expected at grinds of 212 μm to 150 μm. Further consideration should be given to throughputs, energy efficiency and downstream equipment selection prior to selecting a crushing technique.

Sep 18, 2023

By J Hadjigeorgiou

The stability of open stopes in underground hard rock mines is influenced by several factors including the shape and size of the excavation, surrounding stresses as well as the degree of jointing. This paper presents a design methodology for stope analysis in jointed rock masses. The proposed approach relies on geological structural data to construct realistic three-dimensional joint network models. The stability of an open stope is determined based on a limit equilibrium analysis.

Jan 1, 2000

By M Grigorescu, J H. Hodgkinson, M Khanal

The mining industry often needs to operate in remote or climatically harsh locations. The industry has recently been forced to deal with extreme conditions including floods, heatwaves and droughts. As these are becoming progressively frequent occurrences, mines typically build ‘downtime’ into production schedules and expect to incur costs to manage the various risks arising from climate extremes. Importantly, many environmental conditions are becoming more extreme and consequently, risk management based on past data can become increasingly ineffective. Market and shareholder demand for fewer interruptions are another pressure on mines to avoid prolonged or frequent downtime. Hence, adaptation to climate is becoming an important strategic move for many companies, many of whom are using future climate scenarios and alternative risk evaluations.We present here a method that uses commonly available mine site data to assist decision-making for reducing vulnerability to sudden flood. The method, ‘climate-related adaptation from terrain evaluation results’ (CRATER), identifies a mine’s flood ‘hot-spots’ and presents them as a ‘traffic lights’ warning map. The process then requires a failure analysis process such as fault-tree analysis to identify both the cause of possible failures and a range of possible failure-avoidance adaptations. In the final stage, management can assess the most suitable option for the mine, based on the availability of capital such as time, facilities, labour and money in addition to social acceptability of the options. CRATER has been tested in an open cut mine environment and is now being further developed to identify how subsidence over underground mines may impact on flooding and ponding over the mining life cycle (CRATER II). Further work is continuing to test larger and more complex mine landscapes to deliver a method to extract more knowledge from existing data.CITATION:Hodgkinson, J H, Grigorescu, M and Khanal, M, 2016. Reducing mine site extreme rainfall vulnerability using climate-related adaptation from terrain evaluation results, in Proceedings International Mine Management Conference, pp 187-200 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jun 22, 2016

By B Beamish

"All underground coal mines in Australia are required to develop a Spontaneous CombustionManagement Plan (SCMP). The New South Wales Government has developed a guideline (MDG1006) to assist operations to comply with this requirement. A reference document is alsosupplied with the guideline that describes the type of information that is needed for input to theplan, including identifying possible tests that can be used for propensity assessment. However,there is no clear indication of what program of sampling and testing is suffi cient to provide adefi nitive assessment of spontaneous combustion propensity prior to and during mining. This paper reviews the existing methods available for quantifying spontaneous combustion propensity and discusses the sampling requirements that are needed from exploration to mining. A new, more defi nitive method of spontaneous combustion testing is also presented that benchmarks coal self-heating performance from mine ambient temperature to thermal runaway. Examples of the eff ectiveness of this new test method for identifying and quantifying reactive pyrite in coal as well as quantifying the diff erence between dry and wet season conditions are provided in the paper."

Jun 1, 2012

By P Crorkan

Within the framework in which future exploitations for Codelco-Chile Divisi=n El Teniente are situated, regarding the deepening of its reserves and the geotechnical problems that affect their recovery, it becomes strategic to evolve with new variants, which make deep mining possible. Codelco ChileÆs Divisi=n El Teniente is progressing within its long-term planning the exploitation of a sector called Esmeralda, which includes its removal through the gravitational caving method (panel caving). It is planned to use pre-caving, which basically consists of developing and undermining the undercut level, without having developed the infrastructure of the production and transport levels. This is carried out in order to achieve a better redistribution of the stresses, thus obtaining higher quality in the infrastructure development of these levels as well as less risk. The extraction reserves for this area, estimated through the opportunity cost selection criteria, were determined at 348 million tons with an average grade of 1.014 per cent Cu. The project carried out geological and geotechnical studies in order to prevent the geomechanical risks of the sector to be exploited, which is a site conformed totally by primary ore. Lithologically, it occurs mainly in Andesite, located at the western limit by Brecha Braden Pipe. There are also varieties of porphyries and hydrothermal breaches of anhydrite. The Esmeralda Mine production program will increase from 4000 tpd (average) in 1998 to its 45 000 tpd rate of production estimated for the year 2005. The approved investment for the period 1995 to 1999 is $US 150 million, out of a total $US 213 million for the project. At feasibility study level and before the project, it showed a Net Present Value of $US 342 million, an Internal Rate of Return of 37 per cent and an IVAN indicator of 2.3 for a ten per cent discount rate and a copper price of 100 US cents/lb.

Jan 1, 2000

By B BussiFre, J Molson, M Aubertin, G W. Wils

Waste rock piles containing reactive sulfide minerals can serve as long-term sources of acid mine drainage (AMD). Within these piles, many physical, geochemical and biological processes can contribute to the production of AMD. The flow of water, for example, depends on internal pile structure, which depends on the dumping methods used to construct the pile. In this paper, the internal structure and grain size distribution of typical waste rock piles are first reviewed with respect to their effect on internal water flow. A numerical model is then applied to simulate unsaturated flow within a waste pile assuming two primary waste materials, different atmospheric conditions and several geometric configurations. The simulations suggest that water movement can be controlled by introducing fine-grained material layers within the coarser host material. However, these layers should not be horizontal because they can lead to localised high-saturation regions as well as preferential flow favouring the production of AMD. A shallow slope towards the pile boundary may be introduced to force drainage to the outside while maintaining low saturation within the interior, thus reducing the production of AMD.

Jan 1, 2003

By J J. McNee and, J Crusius, T F. Pedersen

The use of water covers is a globally-applied method for minimising acid rock drainage (ARD) and metal leaching. Although the subaqueous disposal of potentially acid-generating materials has been shown to effectively limit ARD, under certain scenarios, metal remobilisation can occur at circum-neutral pH. The following paper presents data from four case studies in which metal mobility from submerged mine waste resulted in degradation to water quality in the overlying water cover. Subcentimetre resolution profiling of dissolved constituents across the tailings-water interface (dialysis arrays), in conjunction with mineralogical information, were used to elucidate the controls governing metal mobility. The data illustrate four pathways of metal remobilisation, including: the release of zinc via the oxidative remineralisation of metal-rich organics at the tailings-water interface; enhanced remobilisation of arsenic as a result of anthropogenic eutrophication; the release of copper resulting from the pH-driven dissolution of treatment sludges; and the release of radium from uranium mill tailings due to the dissolution of radiobarite [(Ra,Ba)SO4] by sulfate-reducing bacteria. The results highlight the conclusion that the chemical stability of submerged tailings reflects both: the solid-phase characteristics of the tailings material; and the physical, chemical and biological characteristics of the depositional environment. In particular, the data illustrate that rigorous characterisation of both the waste solids and receiving environment must be performed in order to assess their compatibility. The results have relevance to the management of tailings repositories including constructed impoundments, pit lakes and natural lakes.

Jan 1, 2003

By G Billing a, D Gribble, E Hall, D Varga

The theoretical benefits of electronic detonators have been reasonably well documented. To support this, a practical comparison was made between the performance of the standard shock tube system, NONEL, and a high precision electronic system, HotShotÖ, at the Sunrise Dam Gold Mine. The expected benefits from electronic detonators to Sunrise Dam were identified prior to the trial. Based on these, a number of objectives were set to demonstrate the value of the HotShot system. These are an improvement in fragmentation leading to an increase in productivity, less oversize rehandling, increased throughput and more uniformity in muck pile movement. To maintain the integrity of the trial, the nominal timing of the shots was kept exactly the same, thereby restricting any performance improvements to the precision of the electronics. Accordingly, adjacent shots were chosen with consistent geology. Video footage was taken of the blasts and vibration monitoring was carried out by fixed geophones throughout the mine. Spot heights of the muck pile swell were taken immediately after the blast and heave profile graphs were generated for comparison. Video footage was taken for a period of three hours for both shots to analyse cycle times of the excavator and trucks. PITRAM data was also collected for analysis. As far as practicable, the ore was taken to the same finger on the run-of-mine (ROM) pad to assist in single sourcing for the crusher and to allow oversize to be separated out. From specific metrics taken during the trials, it was shown that the expected improvements due to the high precision timing of electronics were realised in all areas.

Jan 1, 2007

Reliable predictions of the long-term water quality and water level fluctuations in a final void are vital if mine operators propose to decommission final voids in open cut mining operations. The catchments feeding final voids typically comprise a large proportion of coal placed or re-shaped spoil piles. Spoil piles from open cut coal mining operations have distinctive hydrological characteristics, which result in unique run-off behaviour. There is a need to understand the nature of spoil hydrology processes in order to predict the long-term hydrological behaviour and water quality responses of such systems. Preliminary estimates indicate that it may take 20 or more years for a void to flood. It is impractical for mine owners and operators to wait until long-term hydrological and water quality conditions have been established in a void, before reaching agreement with regulators about mine closure conditions. Reliable simulation of the long-term water quality and water level fluctuations in a void are therefore. The adoption of an agreed modelling approach and sharing of results from field data programs could result in the establishment of a database that could be used, with regulatory approval, for assigning parameter values, without the need for a specific data collection program for every individual void. Industry and regulators should agree on the model adopted for predicting post-closure behaviour of spoil/void systems. This will require reliable, robust methods for field data collection. This paper describes the field monitoring, data collection, model preparation and simulations undertaken over a three year period for Australian Coal Association Research Projects (ACARP) Project C7007. It presents the findings of that research, and provides comment on aspects of the project that were undertaken well and on aspects that could have been done better. Limited data is presented in this paper due to confidentiality arrangements with the relevant mine sites.

Jan 1, 2003

By Iley J. D, Siviour N. g, Moffatt R. J

The process of desilverising by fractional crystallisation with reflux was investigated through laboratory batch tests and continuous laboratory bench scale tests at CSIRO Clayton, to a 300 kg/hr pilot plant at Port Pine. The pilot plant built at BHAS comprised a vertical cylindrical refining column with internal diameter 250 mm and height 3.2 m, attached at the top to an off-set cylindrical stirred crystalliser tank. Crystals were made in the crystalliser by intermittent immersion of steel cold fingers, which were water cooled between immersions. Gas heat was used for melting the crystals at the base of the column and for side compensation heating. A computerised in strumentation system was employed for data logging and for controlling some critical plant operations. A mechanical device was first employed to promote counter-current plug flow of crystals down the column against the rising stream of reflux liquid, but this was found to be unsatisfactory owing to excess noise, frequent mechanical failure, and excessive accumulation of dross. Plug flow was finally promoted by pulsing the column. Low silver levels, less than 1 gitonne, were achieved with both methods of crystal transport under total reflux conditions. The pulsed column gave results for silver and bismuth which agreed with the theoretical predictions of a computer model, but there was some selective drossing of antimony. In the mechanically agitated column, excessive drossing promoted selective removal of most of the antimony and some of the bismuth, and the results after extended operation were well removed from the theoretical predictions. Plant failures and operating problems prevented the achievement of satisfactory product quality with the necessary reliability under production conditions. Other priorities necessitated the termination of the project before the process could be optimised.

Jan 1, 1989

By Parker C. J, Mikula P. A

The excavation for the Sydney Opera House Parking Station comprises a large donut shaped underground cavern with a central sandstone pillar. The maximum effective roof span is about 19 m and the rock cover is between 7 m and 8 m. Permanent support for the roof and the various services tunnels consists of a combination of tensioned anchors, and untensioned dowels, and mesh with shortcrete and fibrecrete as the final lining. Steel sets were installed at main intersections.Fundamental to the design philosophy for excavation of these spans at such shallow rock cover was the use of monitoring to check on the adequacy of the installed support. Prior to excavation, extensometers, inclinometers, piezometers and surface settlement survey stations were installed. Underground survey stations, anchor load cells and shotcrete pressure cells were installed as excavation proceeded. Excavation commenced at the crown using an initial heading and three widening stages. Geological mapping during excavation confirmed borehole expectations, namely sandstone beds 1 to 4 m thick interbedded with thin shale units. Bedding plane contacts varied over short distances from tight partings to thick brecciated seams. Jointing was subvertical and joints tended to be bed-limited.

Jan 1, 1993

By H G. Poulos

Prediction of ground deformation caused by soft ground tunnelling is an important problem facing design engineers. The ground deformations are caused by the closure of the gap formed around the tunnel due to the tunnelling procedure and soil intrusion via the tunnel face into the tunnel. There are three different approaches that are commonly used in practice to estimate the ground deformations due to tunnelling, namely, empirical methods, analytical methods and finite element methods. One of the important issues of tunnelling in urban areas is the assessment of the likely impact on adjacent pile foundations of ground movements arising from tunnel construction. The main objectives of this paper are two-fold: first, to assess the available methods to estimate the tunnelling-induced ground deformations, and second, to examine the effect of such ground deformations on adjacent piles. Analytical solutions to predict the tunnelling-induced ground deformation developed by the authors are used in this study. These estimated ground deformations are imposed on the pile in simplified boundary element analyses to compute pile responses. The influence of various factors such as tunnel geometry, ground loss ratio, pile diameter and ratio of pile length to tunnel depth are examined in this study.

Jan 1, 1999

By R W. Wilson, A R. Branch, T S. Pooe

The original bulk air cooling system at this particular mine made use of two water chilling refrigeration machines to produce peak cooling of approximately 12 MWR with a downcast air temperature of about 7°C; however, as the shaft is not used for transporting personnel, the opportunity existed to supply more cooling to the mine by lowering the downcast air temperature. An ice storage facility has been constructed and provides a range of opportunities in operating the system: colder air temperature sent to the shaft, enabled by using near-zero degree water produced by melting ice to cool the air; electricity time-of-use management, by shifting electricity usage out of peak tariff periods; and increased peak cooling capacity, by melting ice while chilling water. Ice is created in the storage facility at night while the ambient air temperature is low and then melted to produce cold water when required by the cooling process. An ice dam was constructed and serpentine stainless steel coils installed where the ice is produced; one of the refrigeration machines was converted to chill a glycol solution to subzero temperatures to create the ice on the coils; a plate heat exchanger was installed to allow the glycol chiller to act as a water chiller as well; and a third spray stage was added to the bulk air cooler to utilise the near-zero water. This paper describes the thermodynamic design, construction and performance assessment of the new system, which is unique, novel and represents the state-of-the-art of this type of cooling system and energy management.CITATION:Branch, A R, Wilson, R W and Pooe, T S, 2015. Novel use of ice thermal storage for energy management on a mine refrigeration plant, in Proceedings The Australian Mine Ventilation Conference, pp 185–192 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 31, 2015

By S N. Nyoni, K C. Corin, C T. O’Connor

Considering future water scenarios, as influenced by the increasing scarcity of water and the move towards sustainable process engineering etc, the closed water circuit becomes an important point of study in metallurgical operations, such as in milling and flotation. However, a deterrent in the use of recycled process water is often a lack of understanding of the effects of the accumulation of dissolved ions and other process chemicals. Recovery of the valuable minerals may be impacted by the concomitant complex mineral-pulp chemistry interactions. Literature indicates that these interactions are not necessarily antagonistic to process outcomes. Wet milling using steel media results in the dissolution of Fe from the media, the rate of which is dependent, inter alia, on the type of media and the chemical conditions of the aqueous environment in the mill. The pulp-phase interactions of dissolved ions with sulfide minerals may result in significant changes to the chemical conditions in the mill, which may subsequently impact negatively on the flotation recoveries. To understand the effect of these interactions in the context of the processing of sulfide minerals, this study seeks to consider the effect of three factors, viz mineral type – pyrite (Py) and galena (Gn) -, milling media of different compositions – forged steel (FS), 21 per cent high chrome and ceramic media -, and water chemistry, viz, deionised water (DI) and synthetic plant water (SPW). Ceramic media and galena are used for the respective control cases where the milling media and sulfide mineral contribute no Fe species. Using DI as a control case, a high ionic strength case is used to mimic the changes in water chemistry for a closed water circuit. Batch flotation tests are used as a diagnostic tool to determine the effects of these media-water-mineral interactions to investigate correlations between the chemical reactions occurring and chemical species present during the milling process and the ultimate flotation performance.

Aug 24, 2022

The difficulty in screening of ores when the moisture contents reach certain critical levels has resulted in mining circuits using wet processes for screening. While this has been acceptable in past years it is no longer acceptable in certain countries and where the mining company is looking to reduce its impact on the surrounding environment.   Various mining companies have been looking at ways to remove the need of using water, with all its inherent drawbacks and to be able to produce its desired products in a dry process.   This would have the benefits of less environmental impact and cost, (due to not requiring wet processing equipment), less power consumption (reduced equipment needed), no corrosion issues, no contaminated waste waters and reduced maintenance activities.   Until recently this has proven elusive or with technical restrictions with current available acceptable technologies for high capacity plants.   One major mining company began seriously exploring ways to overcome this dilemma so that they did not replicate their current ways of operating for their new expansion plans.   They partnered with Metso Minerals to undertake extensive groundbreaking laboratory test work and provide potential solutions as to how to solve this. The laboratory test work proved interesting enough to design, manufacture and test on the actual mining site a prototype screening machine in the circuit.   This break through in screening technology reduces the environmental impact on the area in which the mine is located by: eliminating the storage and use of water, reduction in energy consumption due to having no pumps in the plant, reduction in plant costs and the upstream affects on the environment process used to manufacture and ship the materials the plant structure is built from, and no large tailings dams to take up land space and affect the environment through groundwater/ water table contamination and the negative effects on animals and ecosystems Laboratory test were conducted and a full size machine was installed at the plant site along side conventional machines. The screen size (2.4 m wide x 6.1 long double deck) was determined by the size of screens currently in operation at the mine. The parameters that were explored were: types of screen surface (polyurethane, woven wire etc), types of screen motion (linear, circular or elliptical), angle of motion ( 40,45,55,60 degrees etc), and throw (amplitude), speed and 'g' force.

Jun 1, 2010

By D S. Stewart, K W. Keskimaki

The Henderson Mine has been utilising a continuous panel caving method to extract molybdenum ore since starting operation in 1976. In the past three decades since the mine was designed, many changes have taken place in underground technology as well as the general nature of the mining business. The impacts of larger scale underground equipment and automation are significant at Henderson and continue to reshape the nature of the enterprise. During the first years of operation in the 1970s, Henderson required almost 2000 employees to achieve full production, today only about 400 people are required to fully utilise the plantÆs capacity. The most recent change to the facility is the conversion from a rail haulage system to an underground crushing and conveying system that transports ore 25 km to the Henderson mill site. This change has required the introduction of large, rubber tired haulage trucks underground and the mining methods necessary to develop the large openings demanded by the trucks and underground crusher. The development of the underground crusher is also the first step to mining the final bottom horizon of the orebody. Along with this move comes an opportunity to almost triple the effectiveness of the mining effort, through higher draw columns and wider draw bell spacing. This final advancement to a totally trackless mine has positioned Henderson well for safe and efficient operation as it enters the 21st century.

Jan 1, 2000

By K Luthbom, A Lagerkvist

According to the Swedish Environmental Protection Agency, the number of potentially contaminated sites in Sweden is approximately 40 000. The funding for remediation from the Swedish Government alone amounts to $A 60 - 80 M (300 - 400 MSEK) annually for the period 2003 - 2006. Uncertainties will arise when obtaining samples in field, preparing them in laboratories and analysing them. Different procedures give rise to varying errors. Using data for decision-making that does not truly represent the site could be fatal. Misclassification of soil could lead to unnecessary costs or to risks to human health and the environment. The total uncertainty of an environmental sample can be split into analytical uncertainty and sampling uncertainty. The analytical uncertainty is usually known and reported from routine analysis. The size of the sampling uncertainty is less well known. Hence, the question is how big are the sampling uncertainties for contaminated soil and how big is the analytical error compared to the total sampling error? A scrap yard and two landfills within a workshop area were investigated. An excavator dug trial pits and samples were taken with a trowel from the walls of the trial pits. Samples were put into plastic bags and taken off site for preparation and analysis using XRF. Sample preparation included drying and sieving. The samples were homogenised by kneading the sample bags prior to analysis. The sampling and sample handling were performed in an intuitively way without knowledge of sampling theory. However, Pierre GyÆs sampling theory was used for subsequent evaluation of the data from the site investigation. The theory defines seven sampling errors, which can be applied to sampling of soil. Some errors have a variance that can be calculated or at least estimated, while other errors can give some idea whether the bias is positive or negative. The total sampling error varied over three orders of magnitudes from sample to sample. The single largest contributor to the large variation in error was the contaminant level. When comparing the analytical error and the total sampling error the ratio varies more than three orders of magnitude.

Jan 1, 2005