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Silica and limestone fluxing levels in copper smelting slags were studied. Copper concentrates with flux additions were smelted to matte (55.5 per cent Cu) and slag in a pilot scale submerged combustion furnace.Results indicated that oxidic and sulphidic copper levels in slags were minimised with a slag Si02 level of 36 per cent and a SiO2/CaO ratio of 5.5. Total copper losses in slags were 0.6 per cent under these conditions.To produce the desired slag chemistry, additions of bulk silica and limestone to copper concentrates of fluctuating grades were predicted numerically. The method employed the solution of two simultaneous equations, each respectively for silica and limestone calculations.The predicted flux additions were applied in a further series of tests and the resultant stages were found to be satisfactory. The method is applicable to smelting 'operations which employ two flux bins, with weigh feeders, so that slag chemistry may be controlled with the flux/concentrate feed mix.

Jan 1, 1985

By D P. Obeng, L Reemeyer, R Holmes

The Zinifex Century Mine employs a large number of Detritor mills for fine and ultra-fine grinding to liberate silica and sphalerite at 80 per cent passing 7.5 microns before final zinc flotation. A joint project between CSIRO Minerals and the Zinifex Century Mine was carried out to evaluate the Detritor mill performance. Plant surveys were conducted around the Detritors in conjunction with laboratory tests. The survey data showed that the Detritors in the ultra-fine milling circuit performed well. They reduced a feed F80 sizing of 46 microns to a product P80 sizing of 7.5 microns at a gross energy consumption of 37.2 kWh/t. Scale-up of ultra-fine milling Detritors was studied using a 0.55 kW laboratory batch unit and a 355 kW full-scale Detritor by processing Century zinc concentrate with 1 mm sand media. The results indicated that the 0.55 kW laboratory mill underestimated the energy consumption of the full-scale Detritor by about 20 per cent for a product P80 of seven microns. The performances of a horizontal IsaMill and a vertical Detritor were compared as ultra-fine milling devices for processing Century zinc concentrate. The experimental data demonstrated that, when using the same grinding media, the energy efficiency of the two mills is similar despite the difference in mill designs. The Detritors used for regrind duty at the Century Mine performed poorly when processing feed at 80 per cent passing 88 micron. The energy consumption was high and the product size distribution was broad with particles above 100 microns in the feed unbroken and particles below ten microns overground. A coarser ceramic media of 3 mm was therefore tested in a laboratory Detritor to process the regrind Detritor feed as an alternative to the 1 mm Colorado sand used at the Century Mine. The ceramic media reduced the energy consumption significantly and produced a narrower product size distribution, which is more desirable for the downstream flotation process.

Jan 1, 2007

lbis new concept in geology is introduced by a reinteipretation of the Archaean stratigraphy of the greenstone belts of the Yilgarn Craton of Western Australia. Evidence is presented to show that the recorded Archaean succession of the Eastern Goldfields Province is composed of two distinct groups of mafic/ultrarnafic and felsic igneous rocks which, together with sediments, form alternating sequences represented by Cycles 1 to 4; Cycle 5 consists entirely of sediments. Recorded stratigraphy for the Murchison and corre1atives of the Southern Cross Subprovinces conform to this pattern. The five basic components are referred to as Unit 1 to Unit 5. A major erosional unconformity between Units 3 and 4 extending across the Craton is identified as a locus of potential major gold occurrence, including fossil placers, where suitable structural situations exist; Units 1 and 3 are identified as potential hosts of gold and nickel deposits; Units 2 and 4 for gold and base metals.

Jan 1, 1994

A novel fracture-plane control blasting technique with particular application in wall-control blasts in mines employing medium to large diameter boreholes is described. It consists of a string of nested holes, each nest consisting of a large diameter charge-hole flanked on either side by a small diameter satellite hole. Each nest is shown to be an analog of a pressurized hole with diametral notches along its length. This 'equivalent-notched' hole concept for generating controlled fractures along preferred directions has been successfully investigated in the laboratory and in the field. The technique has been used to generate controlled fractures on a quarry bench in highly jointed limestone. The resulting blasts with a 250 mm diameter central charge-hole and 50-75 mm satellite holes show that two nests of such holes almost 5 m apart could be joined by a single co-linear fracture. The design range of diameter ratio between charge-hole and satellite hole is 3 to 6 and spacing is 3 to 5 charge-hole radii. With careful matching of explosives and decoupling, and combination of diameter ratio and spacing, it would be possible to connect two nests of such holes more than 20 charge diameters apart by a single controlled fracture plane. The relative merits of the technique against existing wall-control blasts are discussed, and guidelines for practical fracture-plane control blast designs are discussed.

Jan 1, 1990

By Rath M. C, Das R. P

Studies were carried out on dissolution and oxidation of iron powder in ammonia-ammonium carbonate solution using oxygen over pressures. Cobalt and nickel losses during iron oxidation under different conditions were investigated. Regression equations were derived for percent cobalt loss and percent iron oxidation using ammonia, ammonium carbonate and oxygen partial pressure as the variables. The equations were tested for adequacy using Fisher's test. Cobalt losses increased with the increase of initial cobalt concentration and about 400 mg/l of cobalt was lost from a solution containing 500 mg/l cobalt. A maximum of about 80 mg/l nickel was lost from 1 g/l nickel containing solution, and this loss remained the same even when the nickel concentration was increased to 7.5 g/l.

Jan 1, 1992

The granulites and related "dry" igneous rocks tend to be passed over during exploration for metals. Preliminary data show that high trace concentrations of Cu, Ni and other metals of economic interest are common in orthopyroxene and some of the other granulite minerals. During retrograde metamorphism of granulites, pyroxenes are converted to amphiboles or phyllosilicates, and significant quantities of metals are released and become available for incorporat- ion into new mineral phases, or may be transported elsewhere. S--rich scapolite is the normal scapolite of granulites. Its retrogression to secondary plagioclase provides much S which scavenges Cu, Ni, etc., from pyroxenes undergoing retrogression, thus producing ore-fluids. A full analysis of a scapolite with 5.10 per cent S03 is given. Beryl is unstable in granulites but the rare Be mineral taaffeite (Al4Pf (Be,Fe)O3) with 5,50 per cent BeO occurs in central Australia as a pale green Tabular mineral easily confused for chloritoid in hand-specimen. Metamorphic differentiation and mobilization of primary ore concentrations are major factors controlling their post-granulite attitude and grade.

Jan 1, 1969

By Restarick C. J & Stewart P S B, Kelsall D. P

Over a four-hour period of steady plant operation samples were taken at regular intervals from points within the grinding and flotation circuits. Size fractions of each composite sample were analysed for lead and zinc values and a comparison made of the behaviour of the lead, zinc and gangue minerals, size by size throughout the whole circuit. Analysis of the breakage behaviour using dynamic mathematical models gave the rates of breakage of each size fraction of each main component. Simulated grinding experiments showed that the main grinding circuit had sane reserve capacity. In the lead flotation circuit all lead values between 150 mesh (Tyler) and 5 microns had excellent flotation characteristics, and a major proportion had a high rate of flotation which was practically the same for all sizes. Increase in overall lead recovery would require improvement of the flotation behaviour of ultra-fine lead minerals. These were slow floating and were responsible for approximately half the lead losses in the final zinc concentrate and one third of the lead losses in the final tails.

Jan 1, 1980

By Motyka J, Adamczyk AF, Witczak S

A case study of migration of a paper factory fluid wastes, on the distance of 5 km from an underground disposal site to an ore mine is presented. The ore mine in question, situated in SW Poland is pumping 3.5 m3/s (ca 300 000 m3/day) of groundwater, producing a cone of depression about 150 m deep and several kilometers wide. The migration of wastes (pollutant) occurs within the carbonate karstic aquifer of Triassic age. The aquifer is about 100m thick and is characterized by the coefficient of hydraulic conductivity equal to 8 m/day on the average. The results of systematic measurements carried out for 13 years enabled to estimate the mean breakthrough curve of the pollutant. On this basis and taking into account the coefficient of hydraulic conductivity as well as the mean hydraulic gradient between the disposal site and the ore mine, the migration parameters of the polluting material, i.e. the real flow velocity, the effective porosity and the longitudinal disper- sivity have been calculated. As the measurements considered a long migration distance of the pollutant, the obtained hydrodynamic dispersion constant (dispersivity), in the authors opinion, is reliable enough to be applied for regional groundwater calculations, regardless of the "scale effect".

Jan 1, 1988

By Lawson F

Narrowly sized samples of synthetic chalcocite (Cu2S) and covellite (CuS) were leached in oxygenated acidic sulphate-chloride solutions. Chalcocite leaches via a two-stage process, the first stage being much more rapid than the second. The apparent activation energies are 42.7 kJ/mol and 68.2 kJ/mol respectively, indicating that both stages are controlled by surface chemical reactions. The leaching of covellite is also chemically rate limited with an apparent activation energy of 77.0 kJ/mol. The shrinking core model is able to be used to describe the leaching processes of both copper sulphides. Over 97% of copper present in chalcocite dissolved in 0.5 M H2SO4i0.5 M NaCl solution under one atmosphere pressure of oxygen at 85¦C in three hours from particles 36 pm in diameter while only 85% of the contained copper in covellite particles 13 pm in diameter dissolved in the same solution under the same pressure at 90¦C in six hours. About 99% of the sulphide sulphur in chalcocite was oxidised to elemental sulphur while only 90% of sulphide sulphur was converted to elemental sulphur during covellite leaching. The mechanism proposed for the two-stage leaching of chalcocite particles is as follows: in the first stage, cuprous ions rapidly diffuse to the external reaction surface where they lose electrons and go into solution as a complex cupric chloride ion CuCl'. The second leaching stage begins when covellite is formed at the external surface. Copper again goes into solution as the CuCl* ion. The mechanism for leaching synthetic covellite is similar to the second leaching stage for chalcocite except that the leaching rate of synthetic covellite is substantially lower than that of the newly formed 'covellite'. Elemental sulphur formed on the particle surface retards the dissolution processes during both chalcocite and covellite leaching. The presence of chloride ions is necessary if essentially all of the copper from chalcocite is to go into solution. When no chloride ions were present, the leaching rate of both newly formed and synthetic covellite was almost zero. The main role of chloride ions in both chalcocite and covellite leaching appears to be to disrupt the passivation film of sulphur on the particle surface.

Jan 1, 1989

Methane is present in varying degrees in nearly all underground coal mining operations. At mixtures with air near 5-15% it is explosive and consequently since it is not usual for these levels of contamination to be reached in the general body of a mine ventilation system it is not unusual to experience it in specific places. On longwall faces the most used power loader is the shearer machine and because of its general shape, situation and operation it is likely that all the factors which are required to cause a frictional ignition can be present. This paper makes a general appreciation of the causes of these ignitions and methods which are and have been used to control these situations on and around these machines.

Jan 1, 1981

Mt Todd lies towards the south end of the Pine Creek Geosyncline, sandwiched between the Cullen Batholith and the Edith Falls Basin, in an area of regionally metamorphosed sandstones, siltstones and shales. The Batman deposit, some 3 km west of Mt Todd is a sheeted quartz vein system hosted within greywackes of the Palaeoproterozoic Burrell Creek Formation (Finniss River Group). The gold-bearing quartz veins, trending 010¦-020¦ and dipping 60¦-70¦E, are commonly 0.5 to 5 cm wide and occur at intervals which are from 10 cm to 1 m apart. Gold tends to be restricted to the quartz veinlets and immediately adjacent country rock. Grade Control utilises two 4 m 'collar' samples which are collected from each 8 m production blasthole. The irregular distribution of the quartz veins and erratic gold mineralisation has resulted in a disseminated 'salt and pepper' type of gold occurrence, with only a poorly defined footwall. Delineation of ore and waste blocks for mining uses an approach which combines the smoothing effect of kriging with a pragmatic view of the raw data. Large ore blocks with simple geometry help to minimise mining dilution, reduce block variance and give good reconciliations to interpreted ore tonnes and grade. Daily mine face advance is reported against truck counts and provides continual comparison with budgeted production. All data processing uses Gemcom software, together with Lotus spreadsheets.

Jan 1, 1994

Attempt has been made to determine the nature of charge on activated carbon surface by studying the electro-kinetic properties of the carbon in the presence of cations, anions and aurocyanide solutions. The zeta-potential measurements were made in the presence of individual ions and also in combinations. The cations and anions chosen were those commonly associated with gold bearing ores in Kalgoorlie area. It was found that the iso-electric point of Norit Carbon was at pH 4.45; below this pH the charge was positive, while above, it was negative. In the absence of gold cyanide solutions and in the presence of individual cations the i.e.p. shifted to the alkaline range (pH 7.2-8.5) while in the presence of anions the i.e.p. was shifted to less than pH 3.5. In the presence of aurocyanide solutions, the iso-electric point was still in the acid region irrespective of whether anions or cations were present. The probable mechanism for such a behaviour has been attempted after measuring the specific conductivities of solutions before and after gold adsorption, by studies using the electron- probe-mirco-analyser, and S.E.M. on the carbon surface.

Jan 1, 1982

By Jena, Anand S, Das R. P

Leaching studies were carried out on Indian Ocean manganese nodules using sulphuric acid as the lixiviant. By leaching the nodules with 8 per cent sulphuric acid for 12h at 100°C, copper and nickel could be completely extracted along with 50 per cent cobalt and 6.2 per cent manganese.94.2 per cent of the iron was also dissolved. To increase manganese and cobalt extraction, charcoal was used as a reductant. The role of charcoal was to reduce the manganese dioxide and render it soluble as manganese sulphate as well as to facilitate solution of the cobalt minerals associated with the manganese dioxide. Various leaching parameters were studied including acid concentration, amount of reductant, leach time, pulp density and leach temperature. It was found that by leaching the nodules with 10 per cent sulphuric acid at 100°C for 4h using 5 wt/wt per cent charcoal (0.05g of charcoal per g of nodule) almost complete extraction of copper, nickel, cobalt and manganese could be achieved. However, under these conditions all the iron present in the nodules was also leached.

Jan 1, 1989

Five types of mineral resource were known in the sedimentary cover of the oceans and seas floors prior to the 1980's :1) hydrocarbon fields including some very large zones of oil and gas accumulation; 2) "Red Sea" type thermal oozes with increased concentrations of noble metals; 3) ferromanganese nodules; 4) concentrations of metallic sulphides ("Black Smokers"); and 5) cobalt-bearing ferromanganese crusts on the summits and slopes of seamounts. Since then, the so called "White Smokers", containing sulphides of copper and zinc, have been discovered. The ore horizons (manganese, copper, nickel and other metals) of the sedimentary cover of deep-sea basins comprise a sixth type of mineral resource in the oceans. These horizons have not only a theoretical, but also a principal economic significance

Jan 1, 1995

By McNabb KE, Ward B, Dyer G

Roof conditions at Southern Colliery, the second longwall mine to be established at German Creek, were found to be much stronger and more massive than at the earlier longwall mine on the lease. Investigations were made to ascertain the level of face support required for longwall extraction under the changed geological conditions. Geotechnical information was provided from drillholes and highwall exposures. Downhole geophysical logs, notably the sonic velocity log, were used to obtain a distribution of the major lithological units over the mine area. A representative type section of the strata and geomechanical properties was compiled to form the basis for numerical modelling. Two-dimensional finite element methods were used to predict strata movements and chock loads under cantilevered roof conditions. The model incorporated a 6.3 in thick roof beam either bonded or detached, with either a 2 in or 5 in overhang. The solid rib, immediate roof, chock support and goaf were modelled as distinct parts, in addition a front abutment stress profile, derived from three-dimensional displacement-discontinuity analysis, was superimposed on the model.

Jan 1, 1992

By Koppe J. C, Costa J. F C L

This paper compares different results for overburden volume estimation assisted by geoestatistics, particularly using kriging methods. The main goal is to obtain the most reliable digital terrain model for the calculation of the overburden volume. The data was collected on an irregularly spaced grid and interpolated values were calculated to provide a denser, more regular data set before volume estimation. The field work was developed at the Butia-Leste Coal Mine, southern most Brazil, where an accurate survey was done using a total station theodolite with electronic data collector. The study was developed in five main steps: data acquisition, exploratory data analysis, spatial continuity measurements, point and block kriging estimation and verification of the results. Data acquisition was carried out on a 5 x 5 in grid. This dense grid provides an exhaustive data set of the real terrain against which data subsets can be compared for the various interpolation procedures and volume calculation. This provides an interesting insight into the influence of the number of data on the estimation error. Univariate statistics were used to compare each data subset and the exhaustive dataset. Ordinary kriging on the data subsets followed by contouring was carried out using Geoeas and Surfer software respectively. A subroutine written in C provided the link between the files generated in Geoeas and subsequent contouring routines embedded into the Surfer package. Omnidirectional and directional variograms were modelled defining the parameters for kriging estimation using Geoeas. Different variogram models were checked through cross validation prior to kriging. A comparison between the magnitude of the differences in volumes calculated with the different DTMs was attained. These final result indicates the sensitivity of the volume obtained to the number of data points. As the number of data points increases the estimation error decreases, but at some point there is no significant decrease in the final volume with the collection of additional data.

Jan 1, 1995

By Lunt D

Arsenic is classified chemically as a metalloid. That is, it has properties intermediate between those of metals and non-metals. Like non-metals, it combines with many metals to form arsenides (eg arsenopyrite FeAsS, niccolite NiAs, sperrylite PtAs2), but like metals it forms sulphides and oxides (eg realgar AsS, arsenolite As203). Arsenic is distributed widely in the Earth's crust at an average concentration of 1.5 mg/kg and is present in more than 150 minerals.

Jan 1, 1991

By Waladan M, Elliot B, Rankin W. J

A survey was undertaken on the Kalgoorlie Nickel Smelter in which samples of slag and matte were taken along the length of the integrated flash smelting furnace and analysed to determine the variation of nickel and iron concentration. At the same time the oxygen potential of the slag and matte was measured using disposable tip solid-state oxygen probes. The results show that the oxygen potential of the slag is higher than that of the matte and that both decrease from the reaction shaft end to the slag tap hole end of the furnace. The slag and matte are not at equilibrium except towards the tap hole end. Reduction of nickel and magnetite from the slag occurs before the slag enters the slag-cleaning appendage by reaction with iron in the matte. Thermodynamic modelling and laboratory experiments showed that the equilibrium nickel and magnetite contents of the slag in the absence of a carbonaceous reducing agent are about 0.4 per cent and 7.5 per cent, respectively. A carbonaceous reductant is required to obtain a lower nickel content in the slag.

Jan 1, 1991

The problem of instantaneous outbursts remains unsolved after over a century of events and the investigation of the mechanism of the phenomenon and means of treating it. Outbursts have occurred of up to 5,000 tonnes with perhaps up to 500,000 m3 of accompanying gas, either methane (CH4) or carbon dioxide (C02) or mixtures. The low density of CH4 and the high density of CO2 give particular problems. Australia with both gases has experienced outbursts for 85 years with fatalities as recent as 1978. The Bulli Seam of the Illawarra area of the Sydney Basin is affected and outbursts with both CH4 and CO2 occur. The Northern and Central Bowen Basin also experiences outbursts with both gases. Proneness of affected mines is related to the high rank of the'coal and the proneness of the seams-is localised according to depth, gassiness, structure and development geometry. Proneness may be reduced by appropriate choice of mining methods. In addition to outbursting mines other mines have symptomatic phenomena. Traditional preventive methods have been used and control by induce- ment has been practised. A method of local prediction for widespread use has not been achieved although locally successful prediction 1Superintendent Rock Mechanics and Strata Control, The Broken Hill Proprietary Company Limited, Steel Division Collieries, Wollongong, N_RW

Jan 1, 1980

By D Feng, G C. Lukey, J S. J, R R. Dagastine

An ongoing challenge in the coal industry is pyrite removal using the flotation method for fine particles. The use of a æseparation in frothÆ (SIF) technique to recover coarse particles of up to a few millimetres in size has presented a potential solution. However the commercial success of SIF is still limited due to the poor understanding of the separation mechanism. The particle floatability in SIF is determined by the constructive or destructive stresses resulting from the forces exerted by the particle on the bubble films. Hence, the surfactant properties and the mineral characteristics (eg hydrophobicity, shape, etc) are the key factors that control the interaction between the particle and froth. In the present work, the interaction forces between different particles (ie crushed glass, pyrite and coal) and a single air bubble are measured in a non-ionic surfactant solution (pentaethylene glycol mono n-dodecyl ether, C12E5) using an atomic force microscope (AFM). Experimental results show that the interaction is primarily dependent on the contact angle (ie the degree of hydrophobicity of the minerals). For crushed glass, the transition from repulsion to attraction was observed as the contact angle increased. As the concentration of C12E5 increased, the adhesion force was suppressed due to wrapping effect. For coal and pyrite with much higher hydrophobicity, long-range attraction was observed. The effect of shape factor was only visible at high surfactant coverage where sign of destabilisation became noticeable on the retracting force curve. These results provide a fundamental understanding of the direct interaction forces of a complex real system between an irregular particle of either crushed glass, pyrite or coal and a single air bubble. Theories developed for interpretation and modelling are thus far based upon the study of ideal systems of glass or polystyrene spheres and an air bubble and were incapable of explaining the interactions in complex real systems. The presented measurements were a first approach to the problem of real mineral-bubble interaction in flotation systems. Thus, the results can only best be interpreted semi-quantitatively.

Jan 1, 2005