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A Study of Extracting Vanadium from Stone Coal Using Cyclic Oxidation

Sep 13, 2010

By I. A. Mwamba

Titanium aluminide of composition Ti-47.5 at.% Al was prepared by melting titanium and aluminium of commercial purity with additions of precious metals of 0, 0.2, 1, 1.5 and 2 at.% content. The microstructure, hardness and oxidation properties were assessed. It was found that at 47.5 at.% Al, the microstructure of plain TiAl alloys was duplex, consisting of duplex lamellar grains and ? grains. The lamellar grains consisted of alternating lamellae of ? (TiAl) and a2(Ti3Al), with overall aluminium content in the range of 43?47 at.%. The ? grains had a aluminium content above 50 at.%. The addition of precious metals to the TiAl alloy resulted in the formation of a new phase, with a high precious metal content, occurring mostly in the ?phase, without any major change to the microstructure. Increasing the amount of precious metals resulted in an increase of the new phase amount, at the expense of the ? phase. The hardness of the different alloys was around 300HV10. Overall, the research has shown that addition of precious metals to TiAl resulted in a slight increase in hardness and a significant improvement of the oxidation resistance. This shows that alloying TiAl with precious metals, at the addition levels investigated, does not alter the mechanical properties very much, but improves oxidation resistance.

Jan 1, 2012

By Peter Makuvise, Alain M. Bantshi

"The Mazowe Gold Mine is managed by Metallon Gold (Zimbabwe) and is situated in the west-central part of the Harare greenstone belt. Orebodies here generally comprise shear zones which are in-filled with gold-bearing sulphides and quartz. The mineralised zones are up to 1 m in width, have average grades of 4 to 5 g/t, and mostly dip between 10º and 60º to the north.Mazowe Mine is one of the oldest mines in Zimbabwe, and exploration and development in this region dates back to 1890, with over 1.4 million ounces of gold produced to date. Mazowe mine comprises two underground operations, Mazowe and the BSV sections. Ore is processed in a single plant which consists of conventional crushing and milling and carbon-in-leach facility.Baldmin Projects was awarded the contract for the design, construction and commissioning of the 60,000 tonnes per month plant at Mazowe mine in 2014 for the processing of sand and slimes tailings from previous operations at Mazowe mine. The average grade of the tailings is 1.1 g/t. The plant consists of feed preparation, grinding, flotation, thickening of flotation concentrate, and carbon in leach (CIL). A pump station for hydraulic mining of the slimes tailings dam also part of the plant.Key features of the Mazowe sands Plant are described and include:• Hydraulic mining of gold tailings dump.• Feed preparation section that includes a (W x L) 2.4 m wide x 4.8 m trash screen, 250 m3 surge tank, a cluster cyclones with 2 x 500 mm diam. Cyclone.• Comminution circuit designed for a bond work index range of 10-12 kwh/tonne. comminution circuit is constituted with 3 ball mills, 1.83 m diam. X 6.71 m Long, 280 kW.• Flotation circuit comprising rougher bank, scavenger bank and cleaner bank. Rougher Scavenger bank is constituted of 6 x 6m3 flotation cells and 3 x 30 m3 flotation cells and the cleaner is constituted of 3 x 6 m3 flotation cells.• Concentrate Thickening with 6 m diam. Thickener.• Concentrate CIL (carbon in leaching): CIL circuit is comprised of 7 tanks with 2 leach tanks and 5 Carbon in leach."

Jan 1, 2017

By Thomas D. Kelly

In 1900, the average U.S. citizen’s average life span was 47 years. He traveled about 1,900 km (1,200miles) in a lifetime and resided in a home with an ice-box for food storage and oil or gas for lighting. He communicated by mail, telegraph and crude telephones with limited availability and range. By 2000, the average citizen’s life span was 77 years. He traveled an average of 19,000 km/a (12,000 miles/year) by automobile alone. He resided in a home with many electrical appliances, including refrigerators and electric lights. And he communicated almost instantaneously with any other part of the globe by several widely available means, including portable phones and e-mail.

Jan 1, 2002

By Steve Kral

When the price of gold cracked the US$9.60/g(US$300/oz) mark last year, the gold-mining industry began to crank up again. This followed several years of gold prices that had languished in the mid-200s. Existing mines increased production and mines that had lain dormant for many years were getting second looks. The United States still produces a large amount of gold. But not much of the new production is coming from that country. Instead, strict environmental regulations still have companies wary of trying to invest the millions needed to start a new mine or expand existing ones. And after years of studies and negotiations between legislators, environmental interests and the mining industry, the United States still has not crafted a new mining law.

Jan 1, 2003

Characterisation of Computer Printed Circuit Boards for Hazardous Properties and Beneficiation Studies

Sep 13, 2010

By G C. Bolton

Experiments were conducted to access the feasibility of removing zinc from lead slag by sulfation or chlorination or both. Gaseous sulfation with sulfur dioxide and oxygen released only 50 per cent of zinc even under the most severe conditions. Sulfation with concentrated sulfuric acid by a fast-leach process released 95 per cent of zinc while pug-roasting released a maximum of 78 per cent of zinc. Chloridization with NaCl in the presence of sulfating gas released 50 per cent of zinc, while direct chlorination with chlorine gas and oxygen released 85 per cent of zinc and 100 per cent of lead in a chloride condensate containing little impurities.

Jan 1, 1980

By J. C. Kerkering, S. M. Miller, P. C. McWilliams

Researchers at the U.S. Bureau of Mines investigated the use of close-range photogrammetry and subsequent stereo digitizing to obtain data from rock fracture roughness profiles. The photogrammetric process yielded results that were acceptable but somewhat inferior to those obtained by a mechanical profilometer. On the basis of this study, further pursuit of photogrammetry as a data collection method in mining is proposed. Fractal geometry was investigated as a means of measuring the roughness of rock fracture profiles. Four fractal algorithms were used: divider method, modified divider method, box method, and spectral method. A comparison of the methods gave ambiguous results. Brown's modified divider method provided the best means of obtaining the fractal dimension. Shear strength estimates were obtained using the parameters of the modified divider method and Myers' Z, measure. Because of differences in results when comparing the different ways of obtaining the fractal dimension, future users of fractals in studies of rock fractures are advised to cross-check their results carefully.

Jan 1, 1993

By A. D. Thomas, V. N. Rampton, S. Paradis, C. F. Gleeson

"A shallow till sampling program was completed on a 1 km grid over the St . George Batholith in southern New Brunswick. The ""B"" soil horizon was analyzed for Cu, Pb, Zn, Ag, Co, Mo, U and Sb and the heavy minerals from the ""C"" soil horizon were analyzed for W, Sn and A u. The results delineated four of five recorded W occurrences, three of four recorded Mo occurrences, all recorded Cu occurrences and one recorded Au occurrence. The results indicate that shallow till sampling in conjunction with bedrock and Quaternary mapping can inexpensively define exploration targets in terrain similar to that underlain by the St. George Batholith.A similar program was carried out in eastern Ontario involving the analysis of four separates from the till, the ""8"" soil horizon, the -50 mesh fraction, the -250 mesh and the heavy mineral fraction of the ""C"" soil horizon and humus. Also sampling was carried out near known gold occurrences at closer spacings. Regionally, anomalous results from all sample media clearly defined a large auriferous shear zone and associated splays. Over one known showing all media clearly defined the showing and a secondary zone. On the regional scale the heavy mineral fraction gave the best anomaly definition and contrast, but the -250 mesh fraction was found to be the most cost effective for defining exploration targets. For detailed surveys, humus was found to be cost-effective."

Jan 1, 1986

By V. R. Shea-Albin

This U.S. Bureau of Mines report discusses elastic wave velocity and attenuation behavior as an indicator for changes in load and structural integrity of coal samples. Measuring changes in compressional (P)-wave and shear (S)-wave attenuation and velocity under uniaxial and triaxial compression tests revealed their effectiveness for distinguishing changes in applied load and structural failure of samples. The velocity and attenuation values were used in further calculations such as ratios of P-wave to S-wave values, dynamic elastic constants, normalized velocities, and attenuation coefficients to reveal trends for loading and failure. The behavior of both P-wave and S-wave attenuation and velocity together define distinct and consistent phases of load change and failure for uniaxial and triaxial tests. The S-wave velocity and attenuation illustrate changing axial load and initial development of microfractures within the sample preceding structural failure more clearly than those of the P-wave. The attenuation and velocity ratios and dynamic elastic constants (except the bulk modulus) respond to closure of small preexisting fractures within the coal sample with initial loading to failure of coal samples. The attenuation coefficients and normalized velocities reveal trends similar to those shown by velocity and attenuation.

Jan 1, 2010

By C. M. Davidson, D. J. Drexler

"Sulphuric acid treated with hydrogen peroxide to destroy organic contaminants could conceivably show increased corrosivity toward carbon steel shipping and storage vessels, caused by the persistence of a peroxide residual. This paper describes work performed to determine the effect of 0-200ppm hydrogen peroxide on the corrosion of carbon steel by 93% and 98% sulphuric acid at room temperature (23ºC) and 50ºC.Steel electrodes were exposed to acid containing several peroxide levels (0. 45, iOO and 200 ppm) for up to two weeks. Specimens were removed at intervals and weight loss, open circuit potential, depth of metal loss and residual peroxide concentration recorded.Hydrogen peroxide decomposes considerably over two weeks in iron-contaminated sulphuric acid. initial peroxide concentrations > l00 ppm suppress corrosion, but the effect is lost when concentration decays below about 60 ppm. Sustained peroxide levels in the range below 60 ppm may increase corrosion rates. These phenomena are interpreted by analogy with anodic passivation."

Jan 1, 1987

To optimise the haulage of the large tonnages produced from stopes in this high production gold mine, an ore pass and feeder system was introduced. This ore pass was designed and developed in 2006 and the plate feeder installed and commissioned soon after. Cavity Monitoring Surveys (CMS) have been undertaken of the ore pass since it was commissioned. The original thickness that was surveyed of the pillar between the ore pass and decline in 2006 was approximated to be 19 m. Throughout its use large blocks of rock were reporting at the plate feeder. This was the first indication that the ore pass was failing somewhere between the tipping level of the 9410 level and the plate feeder at the 9330. Even so CMS surveys were not taken systematically to firstly identify the area of failure or for monitoring. In August 2008 after implementing management systems, large blocks were still reporting to the plate feeder. The decision was made to empty the pass enough to carry out a CMS survey of the area. Subsequently it was discovered that the area of failure was between the decline and ore pass and that since the first survey the pillar thickness had been reduced to approximately 9.7 m. Further management controls were put in place to slow movement of the material and to limit the use of the 9410 tipping level, but this did not alleviate the rate of failure entirely. The results of an initial inelastic numerical model indicated that most of the pillar was damaged and that failure into the decline likely if no changes were made. The numerical modelling predicted that even if material was no longer passing through the ore pass interaction between the voids was unavoidable and would most likely result in instability. The ore pass and plate feeder are an integral part of the haulage system for the remaining life-of-mnie. Two solutions were sought to firstly reinforce and stabilise the pillar between the ore pass and decline and secondly to rehabilitate the ore pass or find an alternate design that could still utilise the plate feeder. This paper summarises the analysis and resulting rehabilitation that was used to accomplish this.

Nov 25, 2010

By Joseph M. Kurtak

The Bureau of Mines is currently conducting a four year mineral assessment of the 5.7 million acre Valdez Creek Mining District in Southcentral Alaska, as part of its ongoing statewide mining district evaluation program. This report is a summary of the 1987 field work, which included the examination of mines, prospects, and mineral occurrences in the study area. Placer gold has been the most important metal produced in the area, and production totaled 161,131 oz, with the majority of the production coming from the Valdez Creek Mine. Lode gold and silver production totaled 1,581 oz and 8,617 oz, respectively and came mainly from the Golden Zone Mine. Varying amounts of other metals, including copper, lead, zinc, molybdenum, antimony, chrome, nickel, cobalt, tin, tungsten and platinum exist in the study area. Occurrences of industrial limestone and coal are also located in the area.

Jan 1, 2011

By D Craw, P Upton

"An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation. The Otago Schist belt of southern New Zealand hosts widespread orogenic gold deposits. Erosion of these orogenic gold deposits has led to the formation of numerous placer deposits distributed across and beyond the host schist belt. Numerical modelling of crustal scale deformation and geomorphic evolution has defined the key tectonic features that have controlled the severance of detrital gold deposits from their sources. Tectonic activity over the past 20 million years, during development of the modern Pacific-Australian plate boundary, has severed links between some placers and their sources. Detrital gold was transported south from the Otago Schist source region in two different river systems in the Miocene. Mesozoic orogenic gold deposits shed gold into rivers that flowed to the south. These rivers were terminated by the rise of north-west-trending basement ridges at the boundary between weak schist crust and strong greywacke crust, and the ridges were controlled by pre-existing faults at that rheological boundary. In contrast, rising mountains close to the developing plate boundary in the Miocene were the locus of new orogenic gold deposits hosted in extensional faults. These gold deposits were rapidly exhumed and contributed detrital gold to orogen-parallel Miocene rivers that flowed to the south-west. Pleistocene deformation on mainly north-west and north-east orientations, and associated river capture, has severed the links between these Miocene orogenic deposits and downstream detrital gold.CITATION:Craw, D and Upton, P, 2015. Tectonic severance of links between placer gold and its sources, southern New Zealand , in Proceedings PACRIM 2015 Congress, pp 541–544 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 18, 2015

By M. Tadayonsaidi

The effect of alloying elements on the mechanical properties and thermal expansion of 336 casting alloy usually used as piston alloy which has low thermal expansion and very good high-temperature mechanical properties and good wear resistance was investigated. The mechanical properties and thermal expansion characteristic of samples with different combination of alloying elements, which enhance to reduce the cost of products, have been studies, The results show remarkable increase in the mechanical properties with increasing the amount of Cu and Mg, while are reduced with increasing amount of Ni, On the other hand, the use of eutectic aluminum alloy as 336 alloy with higher percent of Cu and Mg and lower percent of Ni are recommended for industry, due to economical viewpoint and satisfactory properties.

Jan 1, 2005

By Joseph M. Kuchta

The limits of flammability and minimum autoignition temperature of a fuel are important elements in assessing fire and explosion hazards that may exist when using or handling the fuel. The limits of flammability define the range of compositions of the fuel gas or vapor mixed with an oxidant through which a flame, initiated by an outside energy source such as an electrical spark, can propagate. The minimum autoignition temperature (M.A.I.T.) is the lowest temperature at which the fuel vapors ignite spontaneously in a specified medium; in this case the ignition energy is supplied by the heat content of tae environment. This temperature is also referred to as S.I.T. value by some authors. Because the autoignition of a fuel also depends on the time interval during which the fuel is subjected to heat, ignition delays are significant. Ignition delay is defined here as the total time elapsed between the introduction of the liquid fuel into the oxidizing atmosphere and the appearance of a flame. This time interval includes both the physical and chemical processes leading to ignition. The ignition delay is usually maximum at the M.A.I.T, and decreases as the temperature of the system is increased. The flash point and the fire point are also useful in assessing the fire and explosion hazards of a fuel. The flash point is the lowest temperature at which saturated, flammable fuel vapor-air mixtures are formed at atmospheric pressure and, therefore, it is essentially the lower limit of flammability

Jan 1, 1962

By J. Geertsma, F. de Klerk

During the hydraulic fracturing treatment of an oil or gas well the liquid pressure in the borehole is increased until tensile stress in the surrounding rock exceeds tensile strength. Once a tensile fracture is initiated, it is penetrated by liquid from the borehole and fracture propagation under continuous hydraulic action takes place. The fracturing liquid carries a propping agent to ensure a highly permeable flow channel after pressure release. Field results range from failure to obtain increased production to outstanding success. In all cases, however, it unfortunately remains uncertain whether the values chosen for the operational parameters, such as injection rate, pumping time and fluid viscosity, were in fact the ideal ones. Though experience provides a lead, a more satisfactory way to predict results would seem to be to subject the fracture propagation process to a theoretical analysis that (1) makes the maximum use of the relevant physical information and (2) so simplifies the resulting calculations that the field engineer gets practical data that he can handle comfortably. We are attempting here to do this in connection with the prediction of fracture width and areal extent before pressure release. What remains of the fracture afterwards depends on the distribution of the propping agent between the fracture walls, and that is a separate story. Idealization of the Problem To keep the problem tractable, a number of simplify- ing assumptions have had to be made: 1. The formation is homogeneous and isotropic as regards those of its properties that influence the fracture-propagation process. 2. The deformations of the formation during fracture propagation can be derived from linear elastic stress-strain relations. 3. The fracturing fluid behaves like a purely viscous liquid; i.e., any peculiar flow behavior due to the addition of gelling agents or other additives is neglected. Moreover, the effect of the propping agent distribution on the distribution of fluid viscosity in the fracture is not taken into account. 4. Fluid flow in the fracture is everywhere laminar. 5. Simple geometric fracture-extension patterns are assumed — either radially symmetrical propagation from a point source (Fig. 1A) or rectilinear propagation originating from a line source (Fig. 1B). In the first case the periphery of the fracture is circular, in the second case it is rectangular. 6. A rectilinear propagation mode can be accomplished only by injection over a large perforated interval, thus forming a line source. Such a rectilinear fracture must therefore be located in the vertical plane. A circular propagation mode might be expected from injection through a narrow band of perforations. This forms a point source. Because gravity effects are excluded from our considerations, the fracture propagation plane may in this case assume any angle with respect to the wellbore as far as the

Jan 1, 1970

By Russell J. Gartrell

This report describes the engineering feasibility and economic advantages of using a steep angle conveyance (SAC) system in conjunction with medium and large draglines to transport spoil in a typical Western Coal Mine. The SAC system, including a receiving hopper, a steep angle conveyor and a sticker/spreader, is capable of processing overburden material at the rate of 7,000 tons/hr. The unique feature of this system is the steep angle conveyor which transports the overburden material from the pit bottom to the top of the spoil at angles to 45 degrees. Compared to other means of cross-pit conveyance considered during this study, the SAC system offers the advantage of easier operation, lower conveyance cost and greater mobility. The results of this study have shown that integration of the SAC system into both established and planned new mines would improve the overall mining operation, expand the operating capability of existing equipment and reduce mining end reclamation cost.

Jan 1, 1977

By Frank B. Fulkerson

A study was made of scrap iron and steel in the South Central States in order to determine trends in processing, shipment, and consumption of this important commodity. These data were derived in part from statistical sources and in part by visits to scrap yards and steel mills. Trends in the industry were reviewed. Dealers in 1963 supplied 1.8 million tons of iron and steel scrap to steel mills and foundries in the south-central area, compared with 2.1 million tons in 1955. Most of the scrap was processed and shipped within 200 to 300 miles of consuming centers. Exports provide a principal outlet for dealers along the gulf coast. Most of the scrap that fills these orders is loaded onto freight cars at yards in Texas and Louisiana and -is shipped to ports for direct transfer from railroad car to ship. The tonnage exported varies greatly from year to year. The largest scrap operations are in or near large cities which are heavy scrap generating areas, steel mill sites, or port cities for export of scrap. A tentative analysis indicates that the short-run supply of prepared scrap is inelastic to price changes; therefore, buyers probably arc in a strong bargaining position at times of declining demand. One technological development in the iron and steel scrap industry is the use of large presses which can take complete automobiles with frames, wheels, springs, and other heavy parts still intact and reduce them to bundles. At Houston, Tex., and Kansas City, Mo., shredding plants are in operation that reduce car bodies and other light scrap into flat pieces 4 to 6 inches in size.

Jan 1, 1966

By Maryam Sadeghi, Jonathan Roy, Claude Bazin

"The operation of mineral processing equipments is intimately related to the mineral composition of the ore. However unit performances are usually characterized in terms of metal contents or recoveries as this data is easier to obtain than the mineral contents. This paper describes a method that combines the operations of material balancing and estimation of the mineral contents of the ore. The estimated mineral contents can be used for process analysis and diagnosis of operating problems.IntroductionThe ore that is feeding a concentrator is made of minerals that condition the energy requirements for the ore comminution and the performances of the subsequent separation circuit. Indeed a change in the mineral composition of the ore may lead to lower grinding mill throughput as well as lower recovery or grade of the economical products. Despite this relationship is recognized the mineral composition of the ore is seldom measured or estimated to provide regular information for the diagnosis of operating problems. Some methods such as the QEM-SCAN (Whiten, 2008; Lamberg and Vianna, 2006) are available to measure the concentration of the minerals in ore samples but the method is time demanding and plant operators usually base their evaluation of the plant performances on chemical assays of metals or elements since this data is easier to obtain from ore samples.Usually samples of the streams of mineral processing plants are collected on a daily basis to be assayed for strategic elements. The obtained concentrations are balanced to produce coherent data with the material conservation constraint and then used to characterize the day to day operation of the plant in terms of recovery of valuable metals and grades of the marketable concentrates. The behavior of contaminant elements can also be monitored from this data allowing the operators to explain for instance a lower zinc concentrate grade by a more important contamination of iron. However such diagnosis is only partial as the contaminant element can be transported by different minerals. Indeed the iron contamination of a zinc sulfide concentrate may be caused by an inadequate depression of pyrite or due to another iron carrying mineral. A possible way to answer the question is to determine the concentrations of the various minerals in the ore and produced sealable concentrates. Since measuring the mineral contents of the ore could be a demanding task one should consider to estimate this data from the daily chemical assays of the sample collected on the main streams of the circuit. Some authors have already investigated the problem. Whiten(2008) described a method to estimate the mineral contents of an ore sample. Lamberg and Vianna(2006) proposed a method to do a sequential mineral reconstruction followed by a material balance. Few of these methods account for the mass conservation of the reconstructed mineral contents."

Jan 1, 2016