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By J. R. Levin, E. J. Schelter

"We present some of our recent efforts in the development of predictive, directed oxidation chemistry of cerium(III) complexes under non-aqueous conditions. The electrochemistry of cerium(III)- alkali metal heterobimetallic aryloxide complexes is reported and compared with cerium aryloxide complexes that are kinetically stabilized by hydrogen bonding cations that span between the complexed aryloxide ligands. Comparative electrochemical measurements reveal differences between the heterobimetallic complexes and the hydrogen-bonded complexes.INTRODUCTIONThe rare earth elements comprise the lanthanides, La–Lu, and the element yttrium (Aspinall, 2001). Rare earth ores such as monazite, LnPO4, and bastnäsite, LnFCO3, typically bear mixtures of light rare earths: La–Sm while monazite, LnPO4, contains mixtures of heavy rare earths (Eu–Lu) (Cotton, 2006). Pure rare earth elements typically are isolated using a liquid-liquid separations process.(Bautista, 1995) The hydrometallurgy of these elements is a difficult problem because the separation factors between neighboring rare earths, which are predicated on the small differences in the sizes of the trivalent ions, are quite small (Cox, 1992). The element cerium, with its 4f1 electronic configuration in the trivalent state, is unique among the rare earth elements due to a relatively accessible 4f0 electronic configuration. The accessibility of the 4f0 configuration underlies the chemistry of cerium(IV), the only rare earth ion with molecular chemistry in the tetravalent oxidation state (Cotton, 2006). Cerium is trivially separated from mixtures of light rare earths by making use of its unique oxidation chemistry. In an effort to extend separations chemistry by oxidation reactions to other rare earth elements such as terbium and praseodymium, the solution electrochemistry of well-defined cerium complexes is of interest."

Jan 1, 2012

By S. G. Enns, E. W. Yarrow

"Situated about 200 km southeast of Juneau, Alaska, within the lower Stikine River region of northwestern British Columbia, the Galore Creek porphyry Cu-Au deposits are hosted by Upper Triassic to Lower Jurassic alkaline volcanic rocks and comagmatic syenite intrusions. Early and late breccias are also locally important host rocks for mineralization. Of the twelve identified Cu-Au deposits, the most important are the Central zone, Southwest zone and the Junction deposits with a combined resource of 284 million tonnes at 0.67 % Cu.The composition of the intrusive rocks is predominantly silica-undersaturated, alkaline, and metaluminous. Four intrusive suites are identified from field, petrographic and petrochemical data. Variation within suites or lineages can be explained by alkali feldspar fractionation. An oscillation between porphyritic and equigranular intrusions is suggested by the sequence of different intrusive lineages. The youngest intrusive phase is silica-saturated.A complex succession of intrusive and hydrothermal events is demonstrated at Galore Creek, with the most intense alteration and mineralization developing early in its history. In the Central zone, early Ca-K-silicate alteration, dominated by garnet, biotite, Kfeldspar, and anhydrite grades outward into K-silicate alteration. Both are locally overprinted by retrograde sericite± anhydrite± carbonate (SAC) alteration. The most intense Ca-K-si/icate alteration, a magmatic-hydrothermal breccia, and an early syenite intrusion are all coincident with copper mineralization in the core region of the Central zone. However, higher grade mineralization in the zone, exceeding 1 % Cu with more than 0.5 g/ t Au, is typically associated with intense biotite-rich, K-silicate alteration primarily hosted by altered volcanic rocks. The highest gold grades, commonly exceeding 1 g/t, are associated with bornite-rich mineralization situated in the northern and southern parts of the Central zone.Mineralization in the Southwest zone occurs as disseminated chalcopyrite within a late, diatreme breccia and adjacent K-feldspar porphyry. In the other satellite deposits, disseminated chalcopyrite and bornite occur in volcanic rocks with alteration that is similar to the Central zone."

Jan 1, 1995

By C. J. Simensen, R. Østhus, H. J. Roven, K. G. Skorpen, H. Kalager

"This work encompasses co-extrusion of alloy Al4.5Mg at the core and rapidly solidified Al4.5Mg1Ag forming the surface layer. The goal is to produce a multi-material by co-extrusion having a relatively hard surface as compared to a softer core. At the same time, work hardening in both alloys is expected to be significant due to Mg in solid solution. Precipitation hardening at 160°C is studied by applying solution heat treatments at 560°C. The hardness increased from 80 to 130 VH in the surface material after 236 h. Surprisingly, the Al4.5Mg alloy also shows pronounced aging at this temperature, i.e. from 70 to 90 VH. The relatively high solution heat treatment temperature introduces grain growth in the core, but this is insignificant for the RS surface alloy. Blisters forms at the surface and cracks follows large portions of the interface. However, the tensile ductility is significant in all conditions due to very pronounced work hardening, i.e. for the as co-extruded, T6, under- and over-aged. The elongation at fracture ranges between 40–45% and the tensile strengths 240–275 MPa. The tensile properties increase linearly with the thickness of the RS alloy, i.e. following the rule of mixtures.INTRODUCTION Al-Mg alloys in 5xxx-series are classified as non-heat treatable wrought alloys (Polmear, StJohn, Nie, & Ma, 2017). The formation of the binary ß-Al8Mg5 does not give a substantial increase in the strength of the alloys (Mondolfo, 1976). When a third element like Ag, Cu or Zn are added, G.P.?zones are formed at low temperatures and intermediate, partial coherent phases are nucleated somewhat higher temperatures and finally a ternary, equilibrium phase is formed (Auld, 1968; Cousland & Tate, 1986; Mondolfo, 1976). Both the formation of G.P.?zones and intermediate phases increase the hardness and strength of the materials. An intermediate, hexagonal T´?phase is formed in Al-5 wt%Mg-1wt%Ag, and finally the equilibrium, cubic phase (Al,Ag)9Mg5 is nucleated (Cousland & Tate, 1986; Mondolfo, 1976)."

Jan 1, 2018

By G. Shore

Radiation grafted structures my be fabricated to contain ion exchange groups selective to an ion complex. Proper choice of substrate and monomer will provide selective ion exchange with differing physico and chemical properties. Grafting a selected monomer to the proper polymer will provide selective ion exchange with assured chemical protection of the substrate. Ion exchange systems utilizing radiation grafted structures have been fabricated to ''capture'' gold, silver and palladium from dilute solutions. Other ion exchange systems can feasibly be produced to remove other precious metals. Rotating Cathode Technology is used to recover the metals from their regenerating solutions are pure metal foil.

Jan 1, 1985

By Washington Luiz Mafra

Every year the conventional direct reduction processes ? Midrex and HYL III ? increased their market share in the world steel production, even though they are only economically feasible in countries where natural gas is available at competitive prices. In this context, the new Midrex projects are based on large reactors (Megamod - 1.5 to 1.8 Mt/y of DRI), reduction temperatures of the metallic burden up to 850oC, with bustle gas temperatures between 960oC e 1050oC. Thus, the requirements of metallic burden performance, as well as the evaluating methods, usually based on ISO standards, need to be reviewed. It is well known that the standards usually applied to quality evaluation do not reflect the performance of metallic burden inside the reactors. This paper describes the different methods of evaluating the disintegration under reduction of DR pellets based on ISO 11257 standard. This is the most important method used by pellet producers and customers for evaluating DR feedstocks. The different methodologies tested to evaluate the disintegration under reduction had varying results, evidencing the relevance of the method and the quality of the pellet. Nevertheless, validating the method in an industrial reactor is still fundamental.

May 1, 2007

By K. Reinharter, J. Schmidl, D. Gregurek, A. Spanring

Copper smelting furnaces are typically lined with magnesia-chromite refractories, which are exposed to multiple and complex stresses. The selection of the processing route, furnace type and slag system will be dictated by the specific ore type available, this will determine the individual refractory wear. This paper evaluates the common refractory wear mechanisms as observed in the copper Peirce-Smith converter and in the copper anode furnace. The chemical factors include corrosion caused by fayalite type slag and sulfur supply, as well as, by Cu-oxide attack. Changes in the temperature during the furnace operation (thermal-shock) create stresses in the brick lining which can only be absorbed in limited extent. Mechanical factors include erosion, caused primarily by the movement of the metal bath, slag and charging material, as well as, stresses in the brickwork due to punching. Finally improper lining procedures can also effect the service life. All these wear parameters lead to severe degeneration of the brick microstructure and a decreased lining life. Therefore, a detailed investigation and understanding of the wear mechanisms through “post mortem studies” together with thermochemical calculations by FactSageTM software is an important prerequisite for the refractory producer. Based on these research results, combined with specific process knowledge, appropriate brick lining solutions for copper processing furnaces can be recommended. INTRODUCTION The refining of copper includes converting of matte or black copper into blister copper for final fire refining process in the anode section. Typically Peirce-Smith (PS) converters are in use. Other technologies include Hoboken Converter, TBRC but also Flash Converting Furnace and bath smelting furnaces (ISA, Ausmelt) (Davenport et al., 2002). For fire refining two types of furnaces are used – the rotary furnace type is dominantly used in the primary production route while secondary smelters tend to use hearth refining furnaces which are more suitable for scrap melting. Installed working linings are based on magnesia-chromite bricks but especially in the anode refining section the application of alumina-chromia bricks have become more popular in the recent years. It comes without saying that, to some extent, large variations in the slag composition can be observed from the data provided to RHI Magnesita during post-mortem studies of used refractory samples and this needs to be addressed properly during the selection process of refractory linings.77

Jan 1, 2019

By R. Q. Honaker

A significant problem in ultrafine particle classification is the significant amount of submicron particle by-pass to the coarse particle stream. In classifying cyclones, submicron particle by-pass to the underflow stream can be reduced by decreasing water recovery. Past studies have shown that a reduction can be realized when the feed solids concentration is increased or the apex diameter is reduced. However, both adjustments tend to increase the particle size cut point and negatively affect classification efficiency due to the impact on slurry rheology. The addition of a viscosity modifier to the feed stream of a classifying cyclone improved the classification performance and decreased the particle size cut point over a range of feed solids concentrations. The detailed test program investigated the use of the modifier in conjunction with varying apex diameters to identify conditions that minimize ultrafine by-pass. With small apex sizes, roping conditions were readily eliminated by the addition of viscosity modifiers. The addition of the modifier had no deleterious effect on froth flotation performance, which commonly serves as a downstream separation process. The fundamental and practical benefits of viscosity modifiers in classification processes are discussed in this publication.

Jan 1, 2006

By Hermann A. Derbuch

Twin Mining made a conscious decision when it changed from gold mine explorer and developer to become a diamond explorer in Canada?s Arctic. It was a decision of survival in an environment that saw junior gold companies either disappear or turn into dot com companies. Twin Mining learned fast and staked within weeks of that decision the first 50 sq. km of claims on, what became, its TORNGAT property at 59½° latitude on the east coast of the Ungava Bay in northern Quebec. This land position, 724 diamonds later (including 322 macro diamonds of gem quality, white and transparent) grew to 507 sq. km today. The 74° latitude called when Twin Mining exercised the option to acquire 3 claims owned by Helix Resources Inc. which revealed exceptional diamond potential. A gem quality 5.4 mm (0.768 carat white and transparent) diamond and the discovery of 16 pipes on 15.2 ha convinced Twin Mining?s board to sanction the deal. Both properties have outstanding features. Kimberlite Dykes and Pipes are in outcrop. The property locations have deep-sea access near existing infrastructure. Their locations are in an environment that is stable and development friendly and has a positive track record with successfully operating mines near-by.

May 1, 2001

By K. Soldenhoff, M. Fainerman-Melnikova

The use of strong base resins for uranium recovery is severely affected by the presence of chloride ions in solution. In areas where high-quality process water is not readily available, the use of saline water would extend the potential application for ion exchange in uranium processing. This study presents measurements of uranium uptake, using a wide range of commercially available weak base anionic exchangers, from solutions with chloride concentrations ranging from 2.5 to 22 g/L Cl. Out of 14 weak base anionic resins tested, 3 were identified that were not severely impacted by the presence of chloride and significantly outperformed a gel strong base resin typically used for uranium recovery in high-chloride environments. The uranium loading was sufficiently high for the consideration of development of the application of uranium recovery from uranium ores leached with seawater.

Jan 1, 2012

By Yi-xin Zhoa

The characteristics of coal bumps are analyzed based on the microseismic data from No.8935 workface in Xinzhouyao coal mine, Datong Mining Group. The geology of this workface is characterized by the thick sandstone roof and coal seam, both with relative higher stiffness and strength. In order to investigate the mechanism and precursors of coal bumps occurred in No.8935 workface, the locations of microseismic, the relationship of microseismic energy and frequency and the spectrum of microseismic signals are analyzed. The result shows that the coal bumps in No.8935 workface were mainly induced by the seismic caused by roof failure. The coal pillar near the goaf is more easily to bump. The statistics results indicate that the coal bumps were mainly occurred in the gate road near the pillar, less than 50m ahead of mining face and located in the hard roof adjacent with coal seam. Moreover, the frequency, energy, b-value and frequency spectrogram of microseismic events were found to decrease before coal bumps. It was found that the frequencies of the microseismic events before coal bumps mainly concentrate upon 5~60Hz. The sudden decreasing of frequency and increasing of amplitude of microseismic events can be regarded as a precursor of coal bumps.

Aug 1, 2013

By M. Mahfoud

The effect of grain refinement on the tensile and fatigue crack propagation behavior of sand cast magnesium alloy AM60B has been investigated in the present study, C2Cl6 in the amount of 0,3% was used to grain refine the melt, The fracture toughness tests were conducted in laboratory air at room temperature (25°C) using a sine-wave cyclic frequency of 20Hz and a load ratio of R = 0,1, The response in the Paris's regime and the critical stress range were determined, Preliminary findings have shown that C2Cl6 has a significant effect on both the tensile properties and fatigue crack propagation of the alloy tested, Grain refinement increased both the yield and ultimate tensile strength by more than 46%, and decreased the crack growth rate from 2,7 to 1,4 MPa Vm , However, the grain size seems to have a smaller effect on threshold stress intensity factor range. The fracture surfaces of specimens were examined optically and under the scanning electron microscope (SEM) to determine the relationship between grain size and fatigue properties.

Jan 1, 2005

By Jeff Smith

Agenda About NORTHPARKES The NEED The INITIATIVE The SEARCH The PRODUCTS The SOLUTION The RESULTS The Northparkes copper-gold mine in Central Western NSW commenced operations in 1994. Copper concentrate is produced and shipped to smelters in Japan, China & India under long term contracts with spot sales to other Asian countries.

May 1, 2006

By Corinne Boone

CO2e.com, LLC - launched in November 2000 - aims to be ?the global hub for carbon commerce.? CO2e.com is a subsidiary of the Cantor Fitzgerald Group, one of the world?s leading brokerage firms Recent Investor in CO2e ? Mitsui & Co. Alliance with Cantor Fitzgerald Environmental Brokerage Services Group (CFEBS) Offices in London, Toronto, Tokyo, New York, San Francisco, Los Angeles, Connecticut, Houston Primary Goals/Benefits of ET § Goals of Emissions Trading: ? Permit Industrial Growth/Expansion ? Promote Economic Efficiency and Flexibility in Meeting Air Pollution Standards § Benefits of Emissions Trading: ? Enhance Air Quality w/o Economic Stagnation ? Encourage Development of New Technology ? Foster Most Efficient Use of a Limited Resource -- Clean Air § Contributes to Sustainable Development and objectives of UNFCCC, Kyoto Protocol?.

Nov 1, 2002

By John Hughes

1. De Beers, Diamonds and Canada 1.1. De Beers was founded long ago (1888, the same time that Canada became a country) in a rural mining village in South Africa. Today, we employ 22,000 people across 19 countries and have 14 mines including open pits, shafts, beach-sands and seabed. 1.2. Last year our sales were US$5.7 billion and our total production amounted to 47 million carats which means a 40% global market share. For the Kyoto buffs in the audience, the company consumes 66 million cubic metres of water per annum, 210 million litres of hydrocarbon fuel and 1,600 GWh of electricity. Stats are good, but aren?t as expressive as a movie. This one is 2 minutes long, which is quicker than I could elaborate. (Video 1 - 2 minutes) 2. De Beers in Botswana is the leading source of diamonds 2.1 Today Botswana is the Jewell in the Crown. There are three big open pits that enjoy economies of scale that make them the lowest cost producers. Last year 60 million tonnes of overburden and 30 million tonnes of ore were moved in Botswana alone. Botswana produced 31 million carats, compared to 14 million carats in South Africa and 2 million very high quality carats inn Namibia. 3. Diamond Mines provide feedstock? ?.to jewellery stores

Apr 1, 2005

By D. M. Maijer, S. L. Cockcroft, A. B. Phillion, P. Fan, C. Reilly, H. Khadivinassab

A combined experimental / numerical approach is proposed to investigate the bulk transfer of solute due to liquid metal feeding during shape casting of aluminum alloy A356 (Al-7Si-0.3Mg). A dumbbell-shaped experimental casting geometry has been developed, which promotes solute redistribution due to liquid metal feeding. The redistribution of solute in trial castings is evaluated based on the area fraction of eutectic phases. In the numerical model, silicon species segregation during solidification are calculated assuming the Scheil approximation, and are coupled with macro-scale solute transport due to Darcy flow in the mushy zone and feeding flow. The model has been implemented within the commercial CFD software, FLUENT, which simultaneously solves the thermal, fluid flow fields and species segregation on the macro-scale. The experimental and numerical results are compared and contrasted to examine the effects of liquid metal feeding in this casting.

Jan 1, 2014

By Franz Simon

Conventional fine gold electrolytes for barrel applications working electrolytically actually permit significant precious metal savings by corresponding optimizations but the most gold is still deposited on areas of the components where it is not absolutely essential for the desired bonding and soldering applications, i.e. in high current density areas. Therefore an electrolyte working electrolessly has been developed which inevitably leads to a much more uniform thickness distribution since in an electroless process there are no areas favoured by metal deposition and current distribution. The new electrolyte will be presented and its performance will be compared with conventional electrolytes as regards thickness distribution. The potential gold savings will be discussed.

Oct 1, 2003

Bahuerachi Project Characteristics Why it?s nicer at Bahuerachi Mexico is a mining country Low political, regulatory and trade risk Low social/permitting risk Proximity to infrastructure Road Power grid (8 km) Rail line (25 km) High grade zones (skarns), CRD and near surface oxide component are sweet spots to the overall system. Size of low grade system points to potential long mine life?and numerous new targets developing. Timelines-2006? 90 to 100 combined RC and core holes to go! MAIN ZONE Drilling ? Goat ?Finish Mid April ? Main Zone, going North, depth of testing dependent, estimated for May ? North Lobe-May ? Commission independent resource estimate by May 06 for results of first pass drilling to date ?tonnesand grades ?Main Zone Milestone. ? Continue infill or expanded drilling to July (minimum) ? 1stpass RC scheduled until September OTHER Targets ? Begin drill testing North Skarn target Mid-April, minimum 5 drill holes, 1,000 meters. Ongoing expansion of target with surface work (mapping) ? Road to Colome(Skarnin north of Main Zone) as part of porphyry program ? Tule(southern) porphyry and skarn system-soils and mapping OUTSTANDING events Metallurgical report on floating and leaching tests (Sulphide/oxides).

May 1, 2006

By Golaleh Riahi

An original method is used to obtain stable nanoparticles of gold-based mono- and bimetallic systems supported on an acidic zeolite. This approach has been applied to PtHY (1wt% Pt) and to bimetallic Pt-AuHY containing 1% of platinum to which is added the amount of gold required to give Au/Pt molar ratios of 20,40,60 and 80%. Metal clusters of Au or Pt-AuHY are formed inside the supercages of the zeolite framework by the thermal reduction of cations by the ligands (en = H2N-CH2-CH2-NH2) under inert gas flow at a temperature depending on the metal. The use of acidic zeolites favours the dispersion of the metal and the thermal stability of the particles. This stability is explained by chemical anchoring of metal clusters by the Brønsted sites of the support. Several techniques have proved that for a molar ratio of 20% metal particles of Pt-AuHY are bimetallic. The segregation of Pt and Au starts for molar ratio =?40%. The catalysts tested on the methylcyclopentane hydroconversion reaction reveal that the addition of gold to platinum leads to an increase in the activity and an improvement in the selectivity for isomerization of the skeleton (cyclohexane and benzene) to the detriment of hydrogenolysis. Similar results were obtained for the dodecane isomerisation to isododecane. These catalysts were also tested in CO, propene and propane oxidation. The activity of fresh catalysts is rather low. It increases after their pretreatment in oxygen or hydrogen atmosphere. In propene oxidation in the reaction mixture O2 ? H2, beside total oxidation of propene to CO2, also propene hydrogenation was observed, particularly at low temperatures. The presence of Au enhances the hydrogenation properties: high selectivities (> 90%) to propane and high propane yields on PtAu HY are observed up to ~150oC, whereas for Pt HY catalyst the selectivity and yield to C3H8 decreases rapidly with the temperature beginning from ~100oC.

Oct 1, 2003

By Larry G. Twidwell, Corby G. Anderson, Camille M. Fleuriault

"The selective precipitation of iron as ammonium jarosite is a well-established industrial technology in base metals hydrometallurgy. It is a key technology in minimizing iron tenors which would be disruptive to downstream processing. It also provides a more readily filterable iron solid to better facilitate materials handling. This paper elucidates the fundamentals behind industrial iron precipitation. Then, the details of the successful optimization of an industrial ammonium jarosite circuit are presented.HYDROMETALLURGICAL IRON REMOVAL FUNDAMENTALS Iron is the fourth most abundant element in the Earth’s crust (5% by weight) and is often found in complex ores such as sulphide-bearing formations. Iron represents an issue though during leaching, a technology which is widely used for the treatment of this type of ore: •,Iron has the particularity of forming hydroxides when leached under certain conditions. Iron hydroxides form a viscous gel, which is difficult to filter and traps valuable elements such as silver. •,Iron is solubilized along with other metals and interferes with the subsequent extraction steps. As a result, purification of the pregnant leach solutions is required to achieve economical extraction of base metals. In the 1960s, metallurgists developed iron precipitation processes for solution purification (Habashi, 1999). Nowadays, precipitation of iron bearing species, such as goethite, hematite or jarosite, has become one of the most common methods used in the industry to purify leach liquors. To be suitable, the precipitate has to be readily filterable and thus must not be too fine of particle size. Precipitation can take place in autoclaves at medium to high temperatures, under an oxygen or air overpressure (Tourre, 1984, Fleuriault 2016, Fleuriault Anderson Shuey, 2016))."

Jan 1, 2016

By Leslie B. English

"HistoricalWHILE DIGGING caves and underground passages for living quarters, primitive man must have had some means of illumination. Most likely he used pieces of wood or slim bundles of reeds or grasses as torches, perhaps steeped in animal fats to give more light. If this is so, we may accept these as the first means of underground illumination. Very little was clone to improve lighting devices for many generations, but slowly there was developed a fount holding fatty oils, with a spout in which was inserted a form of wick.Actual mining. for metals first of all, was started about 3,000 B.C. Some of the old Greek and Roman records refer to the use of torches underground, and some evidence of clay lamps has been found. Candies came into use some time during the first century A.D. When coal mining began about the 14th Century in England, candles were used for illumination because of the ease of manufacturing and handling them. Open oil-lamps came into use early in the 16th century -Agricola, in his De Re .Metallica, written about 1540. pictures a miner with such a lamp. However, the expense of these was so great that candies still continued as the general means of underground lighting.Unfortunately, as miners went deeper underground, they encountered a mysterious gas which. upon coming in contact with open lights, flamed violently, resulting in explosions and accompanying loss of life. The first reference to the results of these gas explosions appeared in 1621. No help seemed to be available. The gas was given off when the coal was mined and the miners could not see without lamps. Attempts were made to use the phosphorescent glow from partly decayed fish, fish skins, and fungus, also to bring daylight clown into the workings by means of a series of • mirrors; •but these means of illumination proved to be impracticable."

Jan 1, 1955