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By N. A. Gokcen, S. Fujishiro

The dissociation pressure of Cr3C2 has been measured in the range of 1908" to 2237°K by means of graphite Knudsen effusion cells. It has been found that Cr3C2 vaporizes according to the following reaction: 1/3 Cr3C2 (s or 1) = 2/3 C (graph.) + Cr (g). The equilibrizcm pressure, P, of Cr (g) is found to be log Ps=- - (21,194/T) + 6.525 over solid Cr3C2 and estimated as log P, = - (19,535/T) + 5.76 over liquid Cr3C2. CARBIDES of chromium are of great importance in alloy steels and cemented carbides. The published data on their therm odynamic properties at high temperatures, however, are meager. The heat capacity and change in entropy of Cr3C2 were determined calorimetrically by Kelley and Moore1 in the range of approximately 50" to 300°K, and by Oriani and Murphy2 from 297" to 1188°K. The standard entropy of Cr3C2at 298.15°K, obtained by Kelley.7 was later confirmed by DeSorbo.4 Equilibrium in the reaction was investigated by Boericke.5 A recent tabular summary

Jan 1, 1962

By Larry D. Olson

Research, hardware development, and field testing have been conducted on systems to allow easy and accurate determination of both foundation tip depth as well as the properties of the soils at and above the foundation tip. The nondestructive testing method used for tip depth determination is the Parallel Seismic (PS) method, while the soil properties are determined by a Cone Penetrometer Test (CPT). The research and development effort reported herein uses a novel combination of the two methods to allow a single piece of portable field equipment to perform both tests. A system has been developed and tested that includes a triaxial geophone and a hydrophone in the cone probe tip to allow collection of the PS data by a CPT rig without requiring a drill rig with hollow stem augers. Using the instrumented tip along with a standard instrumented CPT cone allows for the simultaneous determination of both the depth of unknown foundations and the measurement of soil properties along the length of the unknown foundation. The combined system allows for a more complete and accurate analysis of foundation capacity and scour susceptibility.

Jan 1, 2007

By Claudio Toro, Alex Moyano, Jonkion Font, Carlos Caballero, Pedro Morales

"Codelco-Chile in the last decade has carried out industrially-oriented research as an alternative to the traditional batch-type converting process. In a first stage carried out preliminary evaluations in a rearranged Peirce Smith (PS) converter, and then an exploratory test in a “Convertidor Teniente” (Teniente converter, TC) for the Codelco-Chile Continuous Converting Process. However, the validation test for this process in the TC was delayed up to the second quarter of 2007 where the validation studies were done satisfactorily.Thus, the objective of this paper is to present the results of the campaign tests validating the Codelco-Chile Continuous Converting Process in the TC1 of the Codelco Norte smelter.The results of charging the solid or liquid matte or high grade matte (“white metal”) by Garrgun, or by mouth of the 22 m x 5 m TC1 are presented. Some features of the industrially validated process are discussed, and the pilot test results of the matte injection are also presented."

Jan 1, 2009

By K. Fagerlund, L. Rosenback, T. Mäkinen, Y. Anjala

This paper deals with the nickel smelter and refinery concepts Outokumpu has applied at Harjavalta and several other plants. Also other process routes and modifications developed and tested by Outokumpu during the recent years are highlighted. Outokumpu started nickel production in Harjavalta in 1959. Until 1995 the Flash Smelting - Peirce-Smith (PS) converting route was applied. High grade nickel matte from the converting step was further refined by means of leaching and electrowinning to produce cathode nickel. In 1995 the nickel production capacity was increased from 17 000 t/a to 52 000 t/a based on the Direct Outokumpu Nickel Smelting Process (DON). In the DON process PS converting is eliminated and high grade nickel matte with low Fe-content is directly produced in the flash smelting furnace (FSF). Metal values from the smelting slag are recovered in the electric furnace (EF) as iron containing Ni-matte. The DON process can be operated with either two matte concept, where high grade FSF matte and EF matte are produced, or a single matte concept, where EF matte is recycled to the smelting furnace and thus only one type of high grade matte is obtained. The additional refinery capacity at Harjavalta is based on hydrogen reduction producing.

Jan 1, 2005

By Edward L. McHugh, Stanley M. Miller, Jeffrey K. Whyatt

The point estimation method can be applied to the safety factor (SF) equation for any specified rock slope failure mode (such as plane shear, step path, or wedge) to obtain reliable estimates of the mean and standard deviation of the SF probability distribution. A gamma probability density function is recommended for modeling this probability distribution, because it allows only for positive values and is flexible enough to provide symmetrical shapes and right-skewed, exponential-type shapes for the SF distribution. The mean and standard deviation define this distribution, which then can be integrated numerically from 0 to 1 to obtain the probability of sliding, PS (portion of the SF distribution where SF < 1.0). The overall probability of failure, PF, for the potential slope failure mass is the joint probability that the rock discontinuities are long enough to allow kinematic failure (PL) and that sliding occurs along the rock discontinuities (PS); that is, PF = PSPL. This method for estimating the probability of sliding is extremely efficient computationally, and thus, expedites slope stability simulation routines used by NIOSH software to stochastically describe rock slope behavior and assist the engineer in designing catch benches for large rock slopes. Enhanced bench design translates into increased operational efficiency and safer working conditions in open pit mines and quarries.

By Victor E. Kral

"INTRODUCTION The Phelps Stokes iron deposit, also known as the Iron Mountain claim, was examined by G. L. Thompson, an engineer of the Bureau of Mines, in January 1943. As a result, the Division of Geophysical Exploration 3/ made a magnetorater survey of the deposit in June 1944, and the Mining Branch included it in a,project to explore Nevada iron deposits.The Bureau explored the deposit from September to November 1944 by means of 643 feet of diamond drilling and 445 feet of trenching holes were drilled, all of which penetrated more than: 100 feet of good-grade magnetite, although nearly all the ore except that found in the first hole contained an excessive amount of sulfur. Trenching was done largely over the first two holes, PS-1 and PS-2, and exposed the full width of the ore.The deposit is in Nye County, Nevada, 7.7 miles east of Gabbs. The property was discovered in 1902 was patented in 1907. There has been no production from the property and except for the Bureau's investigation,,has not been, explored since it was patented.Magnetite is the principal ore mineral; it occurs as fine-grained particles associated with sulfides and cemented with talc and calcite."

Feb 1, 1947

By G. J. W. Kor, F. D. Richardson

The sulfide capacities a1 1500°C of slags in the systern CaO + CaF, +Al2O3 have been measured by bringing samples into equilibrium with gas mixtures made from CO + CO2 + SO, + N2. The capacities are negligzble both JOY CaF, and CaF, + Al2O3 melts but when lime is present even at 20 wt pct capacilies as high as 30 x lom3 can be obtained. The results have yielded information concerning the liquidus at 1500°C and fluoride-oxide melts in general. The slags used in electroslag refining contain substantial amounts of calcium fluoride. Robinson and Grainger&apos; report that good results can be obtained by using slags of the approximate composition 70 wt pct CaF2 + 30 pct Al2O3. It has also been reported2 that a mixture of 50 pct CaF2 + 30 pct A12O3 + 20 pct CaO makes a good slag for general use. In view of the fact that very low sulfur contents are claimed for ingots produced by the electroslag process. studies have been made of the sulfide capacities [c, = wt pct S (PO2/Ps2)1/2 at 1500°C. of slags consisting of pure calcium fluoride, and of its mixtures with lime and/or alumina. These studies have also provided information on the phase diagrams. The slags were brought into equilibrium with gas mixtures prepared from NZ + CO + CO2 + SO2. Because CaFz is volatile and also easily hydrolyzed. measurements were made of its loss in weight in various flowing gas mixtures. EXPERIMENTAL Procedure. The apparatus and procedure were the same as described previously. Both platinum and iridium crucibles were used (height and inner diameter about 1 cm), but those made from iridium were stronger and able to withstand a greater number of experiments. In each experiment two crucibles were set in an alumina support and 1 g of slag mixture was divided between them. The materials from each crucible were analyzed separately after being brought to equilibrium with the gas, and then quenched in the water-cooled end of the reaction tube. Materials. Alumina and lime were prepared as de-scribed previously.4 Calcium fluoride was obtained by igniting Analar calcium fluoride in a platinum boat at about 800°C in a stream of pure dry nitrogen: the product was cooled in a desiccator. The slags were produced from mixtures of the powdered constituents, these being melted together in the course of each equilibrium experiment. The sulfur analyses and the X-ray diffraction meas- urements on the solidified slags were made as described previously.4 From the latter it appears that the CaF2 contained less than 0.5 mol pct CaO. RESULTS Values of (ps2/po2) for the Gas Mixtures. The re-sults have been represented in terms of (ps, /Po,)"? for the various gas mixtures used. The va1;es of this function at 1500°C are listed in Table I: they were calculated from the data cited previously for calculations at 1350°C 4 Weight Losses with CaF, and CaF, + CaO. The re-sults of the weight loss measurements* at 1500°C for

Jan 1, 1970

By Jesse L. Duke

Outline ?Understanding the context ?The Business, political, social and legal environment ?Recipes for Success (three Ps) ?Develop effective Partnerships/relationships ?Plan carefully ?Actively Manage the ?Process? Business Environment ?Nunavut?Impressive mineral potential ?Emerging diamond industry ?Dominated by Juniors ?NWT ?Maturing Diamond industry ?Emerging oil and gas industry ?Yukon ?Alaska Highway Pipeline ?Junior-dominated exploration and development ?Growing acknowledgement in Canada of the importance of northern resources ?Shift of thinking: north-south infrastructure (vs. East-west)

May 1, 2006

By S. S. Wang

Dialkyldithiophosphinates are a new class of flotation collectors for base metal sulfide ores. Structurally, they are quite different from the conventional collectors such as mercaptans, xanthates, thionocarbamates and dithiophosphates. Collectors Structures [Mercaptans R-SHS Xanthates R-OCS-M+ Thionocarbamates R-OCNH-R Dithiophosphates 2 R-CCNH-R&apos; Dithiophosphinates (R) 2-PS-M+ ] In the above structural formula, R and R&apos; stand for a hydrocarbon radical, and M+ is an alkali metal or ammonium cation.

Jan 1, 1982

By V. F. Swanson

At the AIME meeting in Tampa in Oct. 1966, an empirically developed equation was presented which allowed the calculation of free settling velocity for any sized particle: 1 [ ] This equation requires the use of two parameters a and p which are coefficients derived from boundary layer theory.2 It was possible to develop values of a and p for several minerals by back calculation of published data. The original equation had one major flaw. When the fluid density exceeds the density of the solids, the solution to the equation becomes imaginary. A flaw was indicated also by the fact that galena and sylvite both having cubic cleavage, did not have similar values for a and b. Galena gave calculated values of a = 1.082 and g = 3.11, while sylvite gave values of a = 1.870 and p = 2.56. These flaws prompted further study of the equation, resulting in the following empirical modification: [ ] It is obvious a real solution of the equation is possible for all values of ps and p. When PL > PS, V is negative, indicating that the particles will rise against the attraction of gravity. The validity of the modification is borne out by the fact that when values of a and p were back calculated for galena and sylvite using the modified equation, both minerals gave values of a = 1.038 and p = 3.01. With the modification shown in Eq. 2, Newton&apos;s friction factor becomes [ ]

Jan 1, 1976

By J. Sjöblom

New copper and nickel processes, flash converting and DON, direct high-grade nickel matte smelting, have been developed in order to replace the conventional and not so environmentally friendly PS-converting process. With a laboratory scale laminar-flow furnace the combustion reactions of sulfidic feed particles can be investigated under simulated flash smelting conditions. In the present study, finely ground and screened feed fractions of a copper matte and a nickel matte were flash oxidized in a laminar-flow furnace. The experiments were carried out using 20, 21 vol% and 75 vol% O2 in nitrogen, at temperatures 1100 and 1300 °C and reaction zone length of 7.5-16 cm. The samples were quenched in a water film after a specified reaction time. The matte particle reactions were stopped after short residence time intervals in order to obtain a better understanding of the reaction mechanisms. Chemical analysis was used to determine oxidation degree, and optical and scanning electron microscope combined with energy dispersive analysis was used for characterization of the reacted particles. On the basis of the experimental results the reactivity of the mattes is discussed and possible reaction and dust formation mechanisms are considered.

Jan 1, 1999

By Pengfu Tan

The control of converter slag chemistry and slag viscosity has played an important role in optimizing converter operations. A thermodynamic model of copper P-S converter and a viscosity model of converter slag have been used to predict the chemistry and viscosity of converter slag. The effect of oxygen potential, SiO2/Fe in slag, detection of slag blow endpoint, and temperature on slag viscosity, liquidus temperature of converter slag and skimming operation has been discussed. Some applications of the industrial operations have been presented.

Jan 1, 2006

By Jonkion M. Font

As a comprehensive contribution to the understanding of oxygen-blowing of matte smelting, the copper and nickel solubilities between the FeOx SiO2-MgO slag with saturated SiO2 and the Cu2S-Ni3S2 FeS matte with the NCu/(NcU+NNi) of 1, 0.75, 0.5, 0.25 and 0, in a MgO crucible were investigated at 1573 K under controlled partial pressures of SO2 at 0.1, 0.5 and 1 atm. The partial pressures of SO2, S2 and O2 were controlled by using an Ar-SO2-S2 gas mixture after passing through a sulfur reservoir. It was clarified that, at a given matte grade, the solubility of copper in the slag was independent of pso2 while that of nickel increased with increasing pso2. This notable difference was considered to be ascribable to the chemical formulas of the mono-metallic sulfides in which one copper atom combines with ½ sulfur atom while one nickel atom combines with 2/3 sulfur atom. It was also clarified that, at a given iron content in the matte, the pot and ps2 were independent of the matte species. This was ascribable to aFeS in the matte, which was independent of the matte composition, Ncu/(Ncu+NNi), at a given iron content in the matte.

Jan 1, 1999

By Pengfu Tan

Converter slag chemistry control has played an important role in optimizing converter operations. A thermodynamic model of copper P-S converter has been developed to predict the behavior of magnetite in the converter slag. Predictions of bath temperature, slag and matte compositions, and magnetite content in the slag have been validated by industrial data. The effects of fluxing strategy, returns and skim charges, oxygen enrichment, and temperature on the magnetite formation in the slag have been predicted and discussed. Some improvements of the industrial operations have been presented.

Jan 1, 2005

By M. L. Sorokin

The thermodynamic of nickel production from laterite ore and from sulfide concentrate can be analyzed using PO2 - PS2 diagram of the Ni-Fe-S-0-SiO2 system. The procedure of the diagram computation is suggested and the diagrams for various temperature and Fe/Ni ratio are calculated. Three-suffix Margules equations are used for the calculation of the thermodynamic properties of three solutions: liquid matte, liquid slag and solid Fe-Ni alloy. The diagrams are used for the considerations about direct one-stage metallic nickel production.

Jan 1, 1994

Council for 1998/99 President R.P. Mohring President Elect J.R. Dixon Vice Presidents Senior M.H. Rogers Junior Dr L.A. Cramer Immediate Past President Dr N.A. Barcza Honorary Treasure J.A. Cruise Members of Council J.P.W. Bennie E.G. de Villiers A.A.B. Douglas F.M.G. Egerton R. Graham Dr R.G. Gürtunca Dr R.V.R. Handfield-Jones P.J. Knottenbelt R.G.B. Pickering* P.S. Piper Prof. R.F. Sandenbergh Dr T.R. Stacey D.J. van Niekerk P.J. Venter J.C. Viljoen

Jan 1, 1998

By C. Caballero, A. Warczok, K. Itagaki, A. Moyano, J. Font

The Codelco Norte Smelter process 2,500 tpd of arsenic-bearing concentrates with an arsenic content of up to 1.5% in one of its two main smelting units, the Teniente Converter. The product, 1,100 tpd high-grade matte or white metal, is traditionally fed to the PS converters, while the 1,700 tpd of slag is fed to the slag cleaning electric furnace for copper recovery. This is achieved in a very reductive environment which reduces the viscosity of the slag and enhances the sedimentation of the high-grade matte droplets. The behavior of arsenic in this non-oxidative environment was studied at lab-scale and fundamental thermodynamic data were obtained. Based on these data a thermodynamicbase model to assess the arsenic behavior in reductive environment was developed. It is based on a mass balance for the reduction and sedimentation stages performed in an electric furnace which allows the recovery of high-grade matte droplets after decreasing the viscosity of the slag. This model can be a very suitable tool for predicting fractional distribution of arsenic in the slag cleaning electric furnace, when the distribution ratio, vapor saturation degree, temperature, y As and pO2 are given.

Jan 1, 2007

By María Cristina Ruiz

In the processing of copper concentrates by the conventional smelting-converting technology, complying with the increasingly severity of environmental legislation in some countries has become difficult, mainly due to severe fugitive emissions of gases produced during the batch PS (Peirce-Smith) converting step. In this work, the results of an investigation on the pressure leaching with sulfuric acid and oxygen of white metal (produced in a Teniente Converter reactor) are discussed. The study was carried out at laboratory scale and the main variables studied were temperature, concentration of sulfuric acid and partial pressure of oxygen. The experimental results indicated that most of the sulfur in the white metal was oxidized to sulfate in the whole range of temperature studied (105ºC to 150 ºC). The concentration of sulfuric acid over 0.05 M, and oxygen partial pressure over 6 atm had little effect on the dissolution of copper from the white metal. On the other hand, temperature had the most significant effect on copper dissolution; below 130 ºC copper dissolution was incomplete after 5 hours of leaching while at 150 ºC the dissolution was complete in 90 minutes and 10 atm of partial pressure of oxygen

Jan 1, 2006

By Ling Wu

The development of pyrometallurgical technologies has been focused on new smelting reactors, but the proposal for new converting reactors has been substantially lower. Up to today about 80% of copper matte is treated by the traditional P-S converters which have the weakness of pollutant fugitive emissions. Therefore, the continuously converting processes for treating molten matte have been studied and developed. In July 2017 the "oxygen-rich side blowing smelting + multi-lances top converting & fire refining" continuous copper treating process was commissioned. This process was designed by ENFI and YanTai GuoRun Copper Smelter. In this process, oxygen rich side blow technology is adopted for smelting, which is a new type of side blowing smelting furnace to produce high-grade copper matte. The converting adopts the horizontal multi-lances top-blowing continuously converting process, which eliminates the transportation of molten melt and the SO2 fugitive emission. The intermediate products of this process, copper matte and blister copper is fed into the furnaces respectively through launders. This new process is more advanced, more reliable and more environmentally friendly. Until now, this process in the GuoRun copper smelter is operating smoothly. An increasing number of projects which use this process are under design and construction in China. INTRODUCTION At present, there are many advanced smelting technologies for copper concentrate, such as oxygen bottom blowing smelting, flash smelting, top lance smelting (including ISA and Ausmelt furnaces smelting), side blowing smelting, Mitsubishi smelting, etc. At the same time, there are many copper matte converting technologies such as oxygen bottom blowing continuous converting, flash converting, Ausmelt top lance converting, horizontal multi-lances top blowing converting, Mitsubishi converting, P-S converter converting, etc. The final blister copper fire refining technology mostly adopts rotary anode furnace. Therefore, in the process of processing and extracting the copper from concentrate to produce anodes, there are dozens of technology combinations. Among them, the non-continuous converting technologies for molten or cold matte are often adopted in the converting process. The traditional P-S converting technology had been utilized for over one hundred years, with a mature, reliable and simple operation, also has advantages in the secondary scrap smelting of a wide range of quality. However, due to its batch operation, frequent roll in and out, poor sealing, considerable air infiltration, needs for ladles for molten phases transportation and other characteristics, the technology has a serious pollution problem due to fugitive SO2. At the same time, in the cold matte converting technology, the molten matte needs to be cooled and then processed. The sensible heat of the molten matte cannot be recovered, and the preparation process is needed in the process. Therefore, both energy consumption and investment are relatively higher.

Jan 1, 2019

By S. Tanaka

The Tamano Smelter of Hibi Kyodo Smelting Co. Ltd. was commissioned in 1972. Since start up, the anode production capacity has increased from 101,000 tpy to 290,000 tpy, as a result of the application of continuous improvements at each phase of the expansion projects. The Tamano Smelter had developed several innovations, including the original coke combustion technology for Flash Smelting Furnace operations (T-FSF), and has also been able to extend the operating life of the Peirce-Smith converters. This paper will present several improvements implemented at the Tamano Smelter, and will discuss relevant P-S converter operation.

Jan 1, 2005