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By Ryokichi Shimpo, Akio Fuwa

"The process-measurements of copper smelters in Japan were investigated for the summary of the latest technique and for the fundamental study of process control. The smelters investigated are those employing flash smelting furnace and P.S. converter, one reverberatory furnace and P.S. converter, and one continuous smelting converting furnace (M.I. process). Respective process is then considered, consisted of several reactors of different functions. The measurement methods were summarized in each reactor, including the measurement points. The methods of chemical analyses of the samples in each reactor were also investigated.IntroductionAn investigation on the process measurements, chemical analyses, and system control in copper smelters in Japan were carried out for understanding and summarizing the technique of the pyrometallurgical copper smelting operations. The typical seven processes in six copper smelters were investigated in the period from 1985 to 1987. The smelters investigated were Touyo Smelter of Sumitomo Metal Mining Co., Ltd., Kosaka Smelter of Dowa Mining Co., Ltd., Saganoseki Smelter of Nippon Mining Co., Ltd., Tamano Smelter of Hibi Kyodo Smelting Co., Ltd., Ashio Smelter of Furukawa Co., Ltd. and Naoshima Smelter of Mitsubishi Metal Co., Ltd. They include five flash smelting furnace and P.S. converter systems, one Mitsubishi continuous smelting and converting process (M.I. process), and one reverberatory furnace and P.S. converter system.The investigation was performed by making inquiries about the measurements, chemical analyses, system control, and their future prospects to the engineers in each smelter and by summarizing up in each item. The system control and future prospects were summarized in another paper titled ""Process Control Scheme of Copper Smelting Processes in Japan and Future View."

Jan 1, 1989

By M. Rodgers

Dow Water & Process Solutions (DW&PS) was approached by ASARCO Inc. to attempt to recover cobalt and copper from their copper solvent extraction (SX) raffinate. Cobalt is added to many copper electrowinning tankhouses to help to prevent lead electrode corrosion. With cobalt?s high price this can be a large expense. ASARCO has ore that contains a small amount of naturally occurring cobalt. Currently they have no way of capturing this high value metal from their leach or raffinate streams. DW&PS has some chelating resin technologies that should be able to help solve this problem.

Jan 1, 2010

By Antonio de Lucas, Juan Francisco Rodríguez, Ignacio Gracia, Mª Teresa García

"The amount of waste of Polystyrene (PS) foams is increasing in last years due to their use in insulation, protecting and, storing many different food products. Conventional methods of recycling such as crushing and shrinking by heated air or frictional heat have the disadvantages of molecular degradation, resulting in a reduction of the quality of the recycled polymer. Dissolution and shrinking with suitable solvents is one of the cheapest and more efficient ways of polystyrene recycling but in the process of the solvent recovery by distillation a certain degree of molecular degradation is produced. In this way, CO2 supercritical technology appears as an interesting alternative for the elimination of solvent. This work proposes a global process to polystyrene recycling in two steps: a polystyrene dissolution with a suitable “green” solvent followed by its elimination by supercritical tecnologhy. In order to develop a “green process” the constituents of essential oils, limonene, terpinene, cymene, and phellandrene, are selected as the most appropriated solvents. Introduction In the last years, disposal of the non-biodegradable plastic wastes has been recognized as a serious environmental problem. Recycling these wastes has great interest in order to prevent the environmental pollution and to preserve natural sources (1, 2, 3). Since the Polystyrene foams (PS) is one of the most used foam in isolation, protecting and food storage most of recycling work is concerned with this polyolefin (4). The two main alternatives for treating polymer wastes are energy recycling, where wastes are incinerated, and mechanical recycling (5). Environmental argumentations such as toxic emissions are building up a public resistance against incineration process (6). Mechanical recycling is a popular recovery path for manufacturers and is carried out on single-polymer waste streams. Any way, the market for recycled products can only be found if the quality is close to that of the original. Unfortunately the process of classification and further recovery of these wastes makes them often more expensive than virgin plastic (7, 8). Solvent extraction is one of the cheapest and more efficient ways for PS recycling. If it is done in house of waste producers the separation between plastics could be easy and effective and the transport costs would be eliminated."

Jan 1, 2008

By Pengfu Tan

Xstrata Copper at Mount Isa in Australia has operated one copper Isasmelt furnace and four P-S converters. The phenomena of foaming occur in above 10% of converter operations. A thermodynamic model of copper P-S converter and a viscosity model of converter slag have been developed to simulate the slag blow and copper blow. The model predicts the chemistry and viscosity of copper skims during copper blow. The effects of oxygen potential, charge of dirty materials, slag carry-over, under-blowing, over-blowing, and temperature on the foaming and viscosity of copper skims have been discussed. Some improvements of the industrial operations have been presented.

Jan 1, 2006

By Bruce Macdonald

Operational monitoring of slope stability can be achieved by space based InSAR monitoring platforms. Natural and man-made rock slopes are monitored using a novel stack-based InSAR method that exploits both persistent point scatterers (PS) as well as coherent distributed scatterers (DS) such as areas of pavement and sparsely vegetated surfaces. The new method, Homogenous Distributed Scatterer (HDS)-InSAR identifies InSAR targets by using adaptive multilooking of statistically homogenous pixel neighbourhoods combined with thresholding the differential temporal coherence of each target candidate with respect to its surroundings. HDS-InSAR preserves PS and therefore forms a direct generalization to our proven DualScale-PSI method. The density of HDS exceeds that of PS by more than an order of magnitude often providing essentially continuous coverage over urban and industrial landscapes featuring a mix of infrastructure with mostly bare soils or rock surfaces. The improved coverage enables better definition of surface motion and underlying geology, which will lead to superior interpretation of the geophysical mechanisms causing the surface deformation, e.g. through improved integration with 3D deformation modeling. We illustrate the performance of our new HDS-InSAR method compared to DualScale-PSI using displacement results from Vancouver, Canada; Bingham mine, USA; and the Palabora mine, South Africa.

Jun 1, 2012

By Kimio Ilagaki

The distribution ratios of Ag, Pb, As, Sb and Bi for the Cu2S-FeS or Ni3S2-FeS matte I FeOx-SiOl, FeOx-Si02-CaO or FeOx-CaO slag equilibration in a MgO crucible were determined experimentally at 1523 ~1573K under controlled partial pressures of S2 and 02 at given PS02 of 10.1,50.7 and 101.3 kPa(O.I, 0.5 and I atm), and the observed dependency of distribution ratio on the matte grade, S02 pressure and slag basicity were analyzed on the basis of thermodynamics.

Jan 1, 2003

By Jussi Vaamol

A commercial CFD-code was used to solve isothermal flow fields of gas and liquid in a Peirce-Smith converter. The model was validated with a 1/4 scale water model, and parametric study. Limits of the modeling technique used were recognized, but calculated results indicate that the present model predicts the general flow field with reasonable accuracy. The model was used to examine general flow conditions in an industrial scale PS-converter. Typical scaling factors of physical models were also evaluated with the aid of predicted bubble distribution, patterns of the flow fields and magnitude of flow velocities. The numerical simulations were found to open new viewpoints to the fluid dynamic related phenomena in the PS-process.

Jan 1, 1998

By I. Ueda, S. Ishikawa, T. Nagata

“O-SR process” in which the S-Furnace of the Mitsubishi process is followed by existing reverberatory furnaces (RFs) and Peirce Smith (PS) converters has been operated since December 2007. The S-Furnace smelts copper concentrates to produce molten matte containing 58-62%Cu which is then settled in the RFs and converted to blister copper in the PS converters. The SO2 gas generated from the S-Furnace and PS converters is converted to sulfuric acid in the acid plants. In addition to the smelting copper concentrates, the O-SR process has advantages in terms of recycling various waste/secondary materials. Automotive Shredder Residue (ASR) has been treated in the RF to reduce fossil-fuel consumption in RFs, and to recover various metals included in ASR as well, since 1993. Electronic circuit boards (E-scrap) has also been processed in order to recover not only copper but also rare resources such as gold, silver and PGMs since 2013. Strategic modifications have enabled expansion of the processing volume of E-scrap. Enhancing recycling of wastes and scraps from urban mines while reducing the consumption of natural resources in the “O-SR” process will be demonstrated and discussed in the present paper. INTRODUCTION Onahama smelter and refinery has been operating as a custom smelter since 1965. Smelting facilities were subsequently expanded to two green-charged RF furnaces and five PS converters in 1973. Since RF is a conventional old-fashioned smelting furnace that necessarily consumes a huge amount of fuel to smelt copper concentrates, saving fuel cost has been an important objective. In early 1980’s the fuel was changed from bunker oil to pulverized coal, while utilizing the combustion heat of waste tires. Furthermore, treatment of combustible waste such as shredder residue (SR) was initiated in order to save fossil fuel for smelting concentrates in the RFs. Since enhancing of the treatment of SR requires a reduction in concentrate smelted in the RFs, most concentrates were dried and injected through tuyeres into the PS.converters. These modifications enabled to reduce the amount of the pulverized coal combustion and to increase SR treatment in the RFs. SR treatment capacity has increased to 12,000mt/month because the SR market has grown after the enforcement of the Vehicles Recycling Law. Such business environment has been attributed to establish the thermal-materials recycling system of SR in which the RFs have changed their role from copper concentrates smelting furnaces to waste materials combustion furnaces.

Jan 1, 2019

By Elvin R. Beach, Jaroslaw Drelich

Pull-off forces were measured for 8-9 pm diameter polystyrene (PSI particles on smooth spin- coated polystyrene films and hexadecanethiol (HDT) self-assemble monolayer surfaces using atomic force microscopy (AFM). Three parameters were controlled during experimentation: (i) the maximum applied load pressing the particle onto the substrate was varied from 50 to 4,000 nN, (ii) loading/unloading rate for the particle to attach and separate from the substrate varied from 0.01 to 9.3 Hz, and (iii) contact time for particle to reside on the substrate surface before retracting the particle to separate it from the surface changed from I µsecond to 200 seconds. the pull-off forces increased with increasing applied loading, increasing loading/unloading rate, and increasing contact time for the PS particle on PS film and on HDT monolayer. The PS particles experience elastic and plastic deformations duringpull-08 force measurements. Plastic deformation is primarily associated with flattening of surface irregularities. The results obtained in this research suggest that the particle-substrate contact areas of the magnitude comparable to those predicted by the JKR contact mechanical model can be reached in the AFM experiments by using high applied loads and long particle-substrate contact times. This result re-opens the prospect of' using AFM for studying surface energies of deformable micro-particles, even if the micro-particles have small irregularities on the surface.

Jan 1, 2003

By F. Hashiuchi

In 1996, the Saganoseki custom smelter & refinery successfully shifted to a single flash smelting furnace operation and increased the copper production capacity to 450,000mtpy in 1998. As the next step, Saganoseki planned to further increase the productivity, especially in the area of P.S. converters and acid plant. As the results of modifications and operational improvements, the gas washing & cooling sections of the Saganoseki acid plant were consolidated from 3 to 2 lines, and increased the gas treatment capacity. The S02 converters in the acid plant were also modified to increase the acid production. By increasing the matte grade from 65 to 68%, six PS converters have been successfully integrated into four, while maintaining the production capacity and reducing the environmental burden in 2005. This paper discusses recent operational conditions and the results of implementation of technological improvements.

Jan 1, 2007

By Bin Feng, Xiang Fang, Tao Guo, Fandong Lu

Abstract: Rough set theory (RS) can find useful information from a large number of data and generate decision rules without prior knowledge. Support vector machines (SVM) have good classification performances and good capabilities of fault-tolerance and generalization. To effectively control blasting vibration effect, prediction model of blasting vibration parameters based on rough sets and support vector machines are established. Particle swarm algorithm (PS) is used to dynamically discretize attributes. Then, according to the optimal particle calculated by the PS algorithm, the decision table is established. After eliminating less importance attributes and data, then SVM is trained and established for prediction. The model can deal with both quantitative and qualitative factors such as aperture and cast direction, and analyze their importance to peak vibration acceleration value. The improvement of prediction accuracy is verified by testing data.

Jan 1, 2014

By Harumasa Kurokawa

Since the initial start-up, the Toyo Smelter & Refinery has been operating in harmony with the ambient environment, and improvements have been implemented with technologies specifically developed for further protecting the environment. Toyo Smelter & Refinery is now planning to increase the copper production capacity from 280,000 tpy to 450,000 tpy, over a period of several years. In 2003, the first step of this smelter expansion and modernization plan was implemented. The production capacity of the P-S converter was increased dramatically, as it became possible to operate under a ?2 hot-2 blowing? schedule. In 2005, an additional converter will be installed, in order to allow operation under a ?3 hot-2 blowing? schedule. This report will describe the technical improvements on the P-S converters, as well as describe the Toyo expansion program and discuss the technologies applied to the fugitive gas collecting system.

Jan 1, 2005

By Germán Richter a

To comply with the chilean air quality regulation requirements, the Hernan Videla Lira Smelter which is a custom smelter having to cope with a wide variety of concentrates, has developed a two-step modernization plan. The main steps are: - A second acid plant of 80,000 Nm3/hr to be operating at the end of 1996. This will increase the sulphur capture from 43% to 701/o in association with the replacement of the Hoboken converter by a second PS-converter to reduce the operation problems resulting from the treating of high garde matte. - Oxygen enrichment, is going to be incorporated in 1998 in the Teniente Converter and PS-converters in association with tuyere injection of dry concentrates, increasing the sulphur capture to 90 - 93% of sulphur inputs. By this program, sulphur emissions will be decreased from 40,000 tpy today to less than 8,000 tpy and in this way to carry out the environmental regulations.

Jan 1, 1996

By W. Persson

The first installation at a copper smelter of a Semtech OPC System for continuous, on-line production control of copper converting in PS converters took place in 1994. At present OPC systems are installed at 19 PS converters. The technology presents to the operator real-time information on the progress of the process he is controlling in the form of optical process parameters, thus facilitating dynamic process control. The optical process parameters are based on time- and wavelength resolved registrations of the light emitted by the off-gas flames and identification of correlation between these parameters and characteristic metallurgical process data. The present paper provides a description of the technology as seen by the furnace operators and a summary of operating experiences made during five years of full-scale, operation at various smelters, reviews influences from the technology on smelter operational practises and comments on recent developments as regards new applications of the technology.

Jan 1, 1999

By Jared Ball, Benjamin Hogg

There are over 100 process parameters that can be monitored during a single Peirce-Smith (PS) converter batch operation. To support a consistent operation it is important to select the correct Key Performance Indicators (KPI’s) to monitor. They should be strategically chosen to drive the desired behaviour with enough flexibility to endure process variations. At the Xstrata Copper Smelter in Mount Isa most of the PS converter operators have very little experience and are often lacking in the appropriate education or training to properly understand the process. For this reason 10 simple KPI’s were chosen that could be easily comprehended and monitored by all smelter personnel. KPI compliance has been supported by relevant project work in the converter area. Charge sequence trials have been performed in an effort to reduce splash and optimise activity time. The online measurement of full and empty ladle weights has enabled an immediate indication of skull size, skim/slag carryover, and metal loss.

Jan 1, 2009

By Michael Lane

With the success of their existing casino operation on the Ohio River in Lawrenceburg, Indiana, the Indiana Gaming Co., LP planned a major expansion of the current facilities. This expansion includes a second 1400+/- car parking garage, a new surface parking lot, elevated walkways, and a new floating casino that will double their present square footage and consolidate all of the gaming activity to one floor. In March of 2006 Richard Goettle, Inc. was awarded the general contract to construct a 260? x 520? boat slip for the new Argosy VII floating casino. An Open Cell® bulkhead system was specified as the means for constructing the new slip. Our contract included the purchase and installation of 300,000 square feet of PS27.5 sheet pile, excavation of 230,000 cubic yards of soil, and a 3300 square foot Mechanically Stabilized Earth wall.

Jan 1, 2008

By Paul Juárez, Eduardo Albuquerque, Elves Matiolo

Este trabajo tiene por objetivo evaluar el efecto del reactivo Tiourea (TU) como depresor de calcopirita en la separación selectiva de la molibdenita por flotación diferencial empleando potencial zeta, medidas de ángulo de contacto y pruebas de flotación en celda Partridge Smith (PS).

Sep 1, 2017

By C. M. Díaz, P. J. Mackey, P. Coursol

In a recent paper [1], the present authors discussed calculated energy consumption numbers in copper sulphide concentrate smelting for four different smelting technologies. For the present study, from among these technologies, they selected the Noranda/Teniente continuous bath smelting followed by Peirce Smith (PS) converting route to investigate the impact on total energy requirement of some key process variations, such as tuyere injection of dry concentrate vs. slingering of wet concentrate over the molten bath, continuous converting vs. conventional batch PS converting and commercially proven slag cleaning alternatives. In their calculations, the authors used the same thermochemical model and methodology used in their earlier paper. This approach to explore plant design options provides an interesting basis for evaluating flowsheet modifications that could lead to significant copper smelting energy savings. The METSIM software was used in the present paper to carry out heat and mass balance computations for 8 different flowsheet configurations. The results are presented and discussed in the paper with respect to copper recoveries, energy requirements and CO2 emissions.

Jan 1, 2011

By Milton F. Goodrich

The idea of using water-only cyclones to scalp clean coal from the feed to other devices has recently been gaining in popularity. 1,2,6 An indication of this popularity is that water-only cyclone scalping is already employed in a few commercial plants. Water-only cyclones scalp the feed to a heavy media vessel in the Warwick plant,3 to Deister tables in the Rowland plant,4 and to a heavy media cyclone circuit in the Amherst Coal Company's McGregor plant.5 Despite this trend, we found surprisingly little information in the literature on the performance of water-only cyclone scalping. Therefore, we undertook a study of its technical merits, limiting our investigation to a water-only cyclone scalper in conjunction with heavy-media cyclones. We felt this to be a reasonable combination of equipment, since both processes operate well on the same size coal. First, we developed simple mathematical relationships revealing general characteristics of the system. Next, we compared the clean coal yield and quality obtainable by the system on four different coals with that obtainable by heavymedia cyclone circuit alone and water-only cyclones middlings recirculation circuit alone. This was done by using computer program to simulate the operation of the three systems. Finally, we considered the effect that implementation of the system would have on a typical preparation plant circuit. The System The system chosen for study [(shown schematically in Fig. 1)] comprises two stages: a primary stage (PI) consisting of water-only cyclones, and a secondary stage (P2) consisting of heavy media cyclones. The water-only cyclones separate raw coal at a low specific gravity, producing a relatively small amount of high quality clean coal and a refuse containing much good coal. This refuse is then recleaned in the secondary stage, where the sharper separation of heavy media cyclones, operated at a higher specific gravity, reclaims additional clean coal. Finally, the clean coal from both stages is combined as the system's clean coal, while the refuse from the secondary stage becomes the system's refuse output. Theoretical Analysis Two assumptions lie behind the following theoretical analysis. The first assumption is that partition curves can represent not only the performance of each stage but also the performance of the system as a whole. These curves show partition number as a function of specific gravity, where partition number is either the percent or fraction of a raw coal with a given specific gravity reporting to clean coal. The second assumption is that these curves are independent of the raw coal characteristics. At any specific gravity the system's partition number is solely a function of the partition numbers of each stage. For convenience, we use the following variables in describing this relationship: g = specific gravity, PS(g) = the partition number of the system at specific gravity g, P1(g) = the partition number of the primary stage at specific gravity g, P2(g) = the partition number of the secondary stage at a specific gravity g. For this system, we can show algebraically that the relationship is: [Ps (g) = PI (g) + (1- P1(g)) P2 (9)(1)] With this equation the system's partition curve can be determined if the partition curves of each stage are known. By definition, the partition numbers P1(g) and P2(g) must each be less than, or equal to, one. Placing these constraints on Eq. (1), we arrive at the relations: [Ps(g) % P1(g) and Ps(g) % P2(g)(2)] Thus, at any specific gravity the system's partition number is always greater than that of both stages. [Figure 2] shows typical partition curves. Curve I represents the primary stage, which consists of water-only cyclones operating at a separating gravity of 1.3. (The separating gravity or the

Jan 1, 1979

By Huilan Yang, Feng He

This paper intends to introduce the development of copper smelting and converting technologies in China in recent years, with a particular emphasis on the introduction of various continuous converting technologies, and moreover, it analyzes the advantages and disadvantages of those technologies, including their impact on the downstream anode refining from different points of view. INTRODUCTION At present, many converting technologies are used in copper pyro-metallurgical plants in China, including Peirce-Smith (PS) converter, flash converting furnace, multi-lance based top blowing, bottom blowing and so on. These technologies have spanned a wide range of time. PS converter technology has been applied in copper smelters for many years and most of the blister copper have been produced by this technology; flash converting technology has been developed since 1990s and been maturely applied in several plants up until now; top blowing and bottom blowing technologies have been revived in China in the past decade and boast good environmental protection performance, energy efficiency, throughput capacity and short process flow. All of the said technologies have reference operations in treating high-grade matte. As more and more attention is paid to environmental protection globally and copper smelters continuously seek for cost reduction, it is necessary to share those converting technologies, especially those new converting technologies derived in China, with copper smelting practitioners in the world. This paper aims to analyze the advantages and disadvantages of various technologies from a macroscopic view and discuss their actual application effects, current developments and future improvements. BRIEF INTRODUCTION OF VARIOUS CONVERTING TECHNOLOGIES IN CHINA China has seen a rapid development in copper smelting industry in the past 30 years and has become the largest gathering place of copper smelters in the world, most of which are operating with PS converting furnace technology, however, with the increasingly strict environmental requirements of the Chinese government in recent years, the low-level pollution issue and the disadvantage of large gas exhaust amount per unit of copper of converting furnaces are particularly prominent.

Jan 1, 2019