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By K. J. Richards

The converting of copper mattes to blister copper has seen few technical advances since the introduction of batch furnaces using submerged tuyeres over a hundred years ago. The first side-blown converting vessel, operated by P. Manhes in 1882, was an offshoot of the 'Bessemer steelmaking process, and subsequent improvements in the conversion of molten mattes resulted In the Peirce-Smith converter, still the Industry standard today. While Peirce-Smith' converting has served the industry well since the early 1900!s, increasingly stringent environmental regulations, burgeoning energy costs, and a trend toward continuous processing have set the stage for a major improvement in this area of copper production. In contrast to a growing number of approaches for continuous converting using molten copper mattes, Kennecott is developing a process for treatment of solidified matte which allows improved' control, higher oxygen enrichment and a separation or decoupling of smelting and converting operations not possible with the other converting technologies. The new process known as Solid Matte Oxygen Converting, or SMOC, eliminates the need for molten matte transfers, minimizes fugitive emissions, and produces high strength SO2 off gases which substantially reduce offgas handling requirements. The SMOC process, despite additional matte solidification and size reduction steps, offers both capital and operating cost advantages for new smelters and the upgrading of existing plants, when compared with conventional converting technologies. Capital cost reductions of up to 35% in converting, gas handling, and sulfur fixation are indicated. Kennecott has successfully tested the new process concept and continued' development work is now under way to commercialize the technology. This paper reviews the limitations of batch copper converting with emphasis on the need for a continuous process, previous industry approaches to continuous converting of molten mattes, and the new Kennecott development.

Jan 1, 1983

By A. Korbel

The progress in understanding the nature of strain localization in metallic materials and in particular the understanding of the role of external (deformation conditions) and internal (material substructure) factors in the development of the tendency toward concentration of plastic flow within transgranular shear bands was the background of the concept given in the title. Following this idea, the practical possibility of replacing the homogeneous in a micro scale mode of deformation by transgrasnular shear bands gives a chance to change the arrangement of the dislocation substructure in the material from that typical for homogeneous deformation into long wavelength (transgranular), pseudo-periodic dislocation walls. The presence or formation of such a substructure in a thermodynamically unstable matrix may result in the formation of the products of phase transformation along shear bands, giving rise to a composite-like structure. This work is aimed to provide a coherent justification to the concept of Natural-Metal-Matrix Composite and summarizes the results of experimental works in this area.

Jan 1, 1997

By D. J. Chaiko

Aqueous biphasic extraction (ABE) processes offer the potential for low-cost, highly selective separations. This countercurrent extraction technique involves selective partitioning of either dissolved solutes or ultrafine particulates between two immiscible aqueous phases. The extraction systems that we have studied are generated by combining an aqueous salt solution with an aqueous polymer solution. We have examined a wide range of applications for ABE, including the treatment of solid and liquid nuclear wastes, decontamination of soils, and processing of mineral ores. We have also conducted fundamental studies of solution microstructure using small angle neutron scattering (SANS): In this chapter we review the physicochemical fundamentals of aqueous biphase formation and discuss the development and scaleup of ABE processes for environmental remediation.

Jan 1, 1996

By Serge Lavoie

Alcan's Guillaume-Tremblay plant, located in Jonquiere, Quebec, has been in operation since 1990. This was the first plasma dross processing plant ever built. In addition to the use of the plasma heating technology, Guillaume-Tremblay has other unique features making it a modern and efficient dross processing facility. This paper presents a general overview of the practical experience at the Guillaume-Tremblay plant. In particular, the utilization of plasma heating in industrial conditions, the metallurgical performance, the unique dross handling system, the control and information management system and the reclaiming of the by-products will be discussed. Finally, the use of the plasma process for salty dross will be addressed' briefly.

Jan 1, 1995

By May Nyman

Due to the vast diversity of chemical media in which metal separations are executed, a wide range of ion separation materials are employed, This ,results in an ongoing effort to discover new phases with novel ion exchange properties. We present here the synthesis of a novel class at, thermally and chemically stable microporous, niobate-based materials. Ion exchange studies show these new phases are highly selective for Sr2+ and other bivalent metals.

Jan 1, 1999

By Don Ibana

Supported by the Minerals Council of Australia (MCA) through the Minerals Tertiary Education Council (MTEC), three Australian universities–Curtin University, Murdoch University and the University of Queensland–have formed the Metallurgical Education Partnership (MEP) to jointly develop and deliver an engineering design capstone unit–Metallurgical Process and Plant Design–in their respective undergraduate programs in extractive metallurgy, in order to enhance the students’ educational experience. A unique feature of the program is the close interaction of the students in all three universities and a significant involvement of industry professionals. Now in its sixth year, it is clear that this unit is achieving its objectives

Jan 1, 2014

By Shuqiang Guo, Xionggang Lu, Yuyang Bian, Weizhong Ding, Lan Jiang, Kai Tang, Changyuan Lu

For recovery of rare earth elements from the NdFeB based permanent magnet scraps, a high temperature process was used. Permanent magnets scraps were firstly oxidized in air. The optimal oxidation conditions under air are at temperature of 700oC holding for 30min. After the oxidation process, the oxides were reduced by graphite crucible at 1500oC under Ar atmosphere. By this way, the rare earth elements were recovered in the form of oxides, and Fe was separated to the metal phase. Boron distributed in both the rare earth oxides (REO) containing slag and the metal phase. In order to reduce the boron contents in the rare earth oxides, the carbon saturated iron bath and NdFeB added carbon saturated iron bath were used to refine the slag. By this process, the rare earth oxides with a comparatively high purity of 98.2% were gotten.

Jan 1, 2015

By I. M. Richardson, M. Janssen, I. J. Bennett, V. A. Popovich

The most critical processing step during the manufacture of screen-printed crystalline solar cells is firing aluminium and silver contacts, which generates residual stresses and solar cell bowing. In this paper, an alternative Ag contact formation mechanism is proposed and aspects related to electrical contact properties, residual stresses and layer delamination are investigated. It is found that there are two main processing parameters affecting the uniformity and delamination of the Ag/Si interface, namely the peak firing temperature and the silicon surface roughness. Silicon surface polishing gives a better wetting of the silicon surface by the glass layer, resulting in a good contact and lower incidence of large voids, compared to the case of highly textured surfaces. The non-uniformity in the glass layer and large voids at the Ag/Si interface (in the case of a textured surface) are expected to have a negative effect on the mechanical strength of the solar cell.

Jan 1, 2015

By N. Verbaan, E. Bourricaudy, M. Dry

"Starfield Resources is developing a novel circuit for the recovery of nickel, copper, cobalt, iron oxide, sulphuric acid and precious metals from the Ferguson Lake deposit in Nunavut, Canada. In this deposit, pentlandite is too finely disseminated in pyrrhotite for the production of a smelter-grade nickel concentrate at an acceptable nickel recovery, so established technology is not applicable and a novel chloride-based circuit is under development. The enabling aspect of this circuit is the hydrolysis of ferric chloride to hematite, releasing gaseous hydrochloric acid that is recycled. Conventional steps are used for separating and recovering the valuable metals from the chloride solution generated. This paper briefly outlines the circuit and presents the results of experimental work on the enabling steps, viz. the oxidation and hydrolysis of iron chloride to hematite and gaseous hydrochloric acid.IntroductionThe Ferguson Lake bulk sulphide ore body in Nunavut, Canada, owned by Starfield Resources Inc., contains significant amounts of base and precious metals but its mineralogy is such that it is not amenable to conventional processing. Pentlandite, for example, is too finely disseminated in pyrhhotite for even modem techniques such as fine grinding and improved flotation reagents to be effective [ 1] and extracting the value requires processing the entire bulk sulphide, including the pyrrhotite. To give the project a total green footprint, in terms of both carbon emissions and acid rock drainage, Starfield imposed the following requirements:• No reactive tailings to generate acid rock drainage.• No gaseous emissions other than normal atmospheric constituents.• No liquid effluents.• No regular consumption of fossil fuel.• High recoveries of all the valuable metals."

Jan 1, 2011

By Tangstadm Merete, Eli Ringdalen

"This paper presents an overview of results from The Norwegian Research Institution SINTEF and the Norwegian University of Science and Technology, NTNU regarding new and ongoing research in silicon production. The main studies are related to condensation of SiO gas and cavity formation. If SiO gas condensation is increased at the top of the furnace resulting in SiO content in the off-gas closer to equilibrium, the Si yield will be increased significantly. Experimental work, simulating a cavity under industrial conditions, has shown that the cavity grows downwards from one layer. Physical appearance of zones in industrial furnaces, and selected reactions in these, are discussed based on results from excavation of industrial furnaces and results from laboratory experiments. Experimental studies of reaction rates for the formation of SiO are presented. Quartz properties are demonstrated to vary between differing quartz types and the effect of this is discussed.Introduction Both the theoretical and industrial issues associated with the production of silicon are described in detail in the textbook written by Schei et al [1]. This book covers the knowledge of silicon production process up to 1998. Together with the work by Myrhaug [1] and by Aasly[2], this is the main basis for this paper. Recent and ongoing research at SINTEF and NTNU focusing on production of Si and SiO in the high temperature zone, dissociation of SiO and condensate and cavity formation will be discussed."

Jan 1, 2012

By Zviad Kovziridze

Structure of celsian ceramics in BaO-Al2O3-SiO2system is studied with electron microscope in the entire temperature region of baking interval. The process of the pores filling and the full consolidation of material growth at comparatively high temperatures of baking intervals are described.

Jan 1, 2006

By I. Iwasaki

Flotation characteristics of pyrrhotite by itself and in complex sulfide ores are reviewed with respect to the effects of oxidation, grinding media and other electroactive minerals.

Jan 1, 1988

By Yasumasa Hattori

An extensive study including fluid dynamic calculations, cold model tests, pilot plant tests as well as measurements in a commercial flash furnace was carried out in order to develop a new Sumitomo flash smelting concentrate burner. The pressure measurements in the commercial burner indicated that the premixing of the concentrate and reaction air in a burner was insufficient. Pilot plant tests showed that enhancement of the premixing of the concentrate and reaction air is very effective for improving the burner performance. Using the additional pressure drop of the reaction air as an indicator of the premixing, a new type Sumitomo premixed concentrate burner was developed.

Jan 1, 2003

By T. Plikas, L. H. Gunnewiek, L. Oshinowo

"Electric furnace smelting is one of the principal unit operations for ferroalloy production, and increased process intensity, improved availability, minimal maintenance and a longer campaign life are common objectives for electric furnace operation in order to obtain favourable economics of production. Furnace designers have continued to develop innovative solutions, e.g., furnace cooling systems, that have allowed these objectives to be realised and CFD modelling plays a key role in the design process. Enhanced understanding of the energy transfer process in the furnace and the ability to develop, evaluate and optimize components of the crucible design to match process requirements are the key motivators for modelling.This paper provides an overview of recent applications of CFD to the design of electric furnaces. The aim is to illustrate what can be done, and identify areas where further work is needed in this field. Examples include furnace bath simulation, crucible cooling system design, taphole design, baking of Soderberg electrodes, off-gas systems, and fume control and building ventilation. It is argued that the trend is for numerical models to become more encompassing while at the same time more accessible, and therefore further improvements in furnace design will be realised with continued and well validated modelling efforts.IntroductionOne of the main processing steps in ferroalloy production is the smelting of ore in electric furnaces. The three-electrode, AC submerged arc furnace is most prevalent method for smelting in the industry, with shielded-arc and DC plasma arc furnaces achieving limited application (1,2). Commercial furnaces range in size from a few megawatts to more than eighty megawatts of supplied power, and operate with the objective of maximising the return on capital invested. Maximising productivity and energy efficiency are two pathways to achieving this objective, through process intensification, increased availability, minimal maintenance, and increased campaign life for the furnace and associated equipment. Concurrently, the need to reduce the environmental impact of metal production by controlling the emission of particulate emissions, greenhouse gases, and other harmful by-products must also be met."

Jan 1, 2004

By Mike Trovant, Stavros A. Argyropoulos

"A fixed grid numerical model for phase change problems is proposed. The model solves for heat transfer and fluid flow, via the coupled solution of the energy, continuity and momentum equations. In addition, the numerical scheme accounts for temperature varying thermophysical properties and determines the shrinkage profile resulting from phase and density change. Simulations are run to determine the effect of varying model parameters and wall cooling rates on the location and shape of the shrinkage void formation in cylindrical casts. Results are shown for both aluminum and magnesium.IntroductionThe mathematical modeling of phase change processes (be they solidification or melting problems) entails solving for many interrelated phenomena. A comprehensive numerical simulation of the casting of a metal, for example, would have to account for: (a) heat transfer in both the solid and liquid portions of the metal and in the mold, (b) the release of latent heat during phase change, (c) fluid flow behavior in the liquid portion of the metal, (d) temperature induced shrinkage caused by liquid contraction and solidification contraction, and (e) the development of thermal stresses with accompanying shrinkage in the solid portion of the cast and mold. A schematic of the relationships that exist between the coupled equations which govern solidification is shown in Figure 1."

Jan 1, 1994

By A. Rios

ENAMl's Paipote Smelter commenced operations in 1951. At present, it processes 230,000 tonnes/year of green feed in a conventional smelter, which comprises one reverberatory furnace, two Hoboken, one Peirce-Smith converters and one rotary anode furnace. The feed is composed of 83% copper concentrate and 17% metallic copper precipitates, which results in a feed average grade of 32% of copper content. The final products are 75,000 tonnes/year of copper anodes and 48,000 tonnes/year of sulphuric acid. At present, the plant is undergoing a modernization to expand the smelter capacity to 300,000 tonnes/year of green feed and increase the sulphuric acid production to 100,000 tonnes/year. This will be achieved with the installation of an El Teniente Converter and an expansion in the acid plant. The work began in November 1991 and is scheduled to be in operaton by March 1993. The paper provides an overview of the modernization plans and results achieved to-date.

Jan 1, 1993

By S. S. Chabot, S. E. James

A recent survey of CEOs from major steel companies worldwide revealed the importance of recycling zinc units from EAF dust, mill scale, blast furnace dust, and other zinc containing streams in their plants. Many processes were developed and installed in response to this challenge. The most successful approach involves the production of a crude zinc oxide and selling it to primary zinc producers to recover the metal value. The problem with this process is the high concentration of halides in the crude oxide. This type of material cannot be processed directly in an electrolytic zinc plant because of corrosion problems it will cause in electrolysis. In 1999, BRZ installed a zinc oxide receiving and washing plant to minimize the impact of halides to its circuit. A description of the washing plant and initial operating results are included.

Jan 1, 2000

By Rodney T. Jones

DC arc furnaces were first used industrially for the reductive smelting of chromite fines to produce ferrochromium thirty years ago. Since then, they have been used for a variety of applications, including the smelting of ilmenite to produce titania slag and pig iron, the recovery of cobalt from non-ferrous smelter slags, and the smelting of nickel laterite ores to produce ferronickel. The power of these furnaces has increased from 12 MW to 72 MW for ferrochromium, and to 80 MW for ferronickel. The largest of these furnaces requires two electrodes to carry sufficient current to generate this much power. A review is presented of various DC arc furnaces in use, along with a discussion of the likely ways in which furnace power might be increased further in the future.

Jan 1, 2014

By Courtney A. Young

Cyanide is a critically important chemical to the mining and metallurgical industry. It has a strong affinity for metals making it favorable as an agent for metal finishing and treatment as well as a lixiviant for metal leaching, particularly gold. These technologies are environmentally sound but, because cyanide is very toxic, safeguards are required to prevent accidental spills and treat effluents before being discharged. Various methods of cyanide remediation by separation and destruction for cyanide management purposes are therefore reviewed. The methods have been broadly categorized as physical, -adsorption. complexation and oxidation methods including photolysis and other advanced-oxidation processes. Reaction mechanisms for these methods are presented throughout this paper, Finally, the methods are compared in regards to their effectiveness in treating various cyanide species: free cyanide, thiocyanate, weak-acid dissociables, and strong-acid dissociables.

Jan 1, 1998

By Marco V. Ginatta

Current world production, 60'000 ton/y, is exceedingly too small for titanium's extraordinary combination of favorable properties; it should be 1,000,000 ton/y (7% of stainless-steel). Prices that competitively sustain that sales volume are achievable only with electrolytic production, as it is for all other commercial nonferrous metals. But titanium does not have its commercial electrolytic plants yet, because of producers decisions and strategies, scientists works, industrial problems with chloride process, lack of consumers sponsors. Fluoride high temperature process has the advantages of aluminum electrolysis, plus other favorable characteristics specific to titanium and its feed material. One electrolytic titanium potroom replaces several different plants used for sponge production. Production of titanium ingots with zero defect is achieved. The solidified cathode rectangular slabs are suitable for direct rolling.

Jan 1, 2001