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By S. Mohanty, K. Sarangi, S. Dash, P. P. Patra

Industrial effluent from various industries contains heavy metals that are a serious threat to humans, flora and fauna in water bodies, and the environment. The heavy metals are dumped after precipitation, which has serious environmental consequences. In this paper, a 2D axi-symmetry CFD model has been developed to study the extraction of chromium ion from industrial effluent, in a hollow fibre membrane, using Alamine 336 as the carrier and kerosene as the diluent. The Navier Stokes equation was used to predict the velocity profile of the aqueous and organic phases, and species transport equation, which considers both convective and diffusive mass transfer, was used to predict the concentration profile of the chromium ion in the computational domain. The distribution coefficient was experimentally determined at a pH 4, which was found to be the optimum pH. Numerical simulations were performed considering 11.11 mol/m3 of initial feed concentration for chromium ions and extractant concentration of 0.2 M. Simulations were carried out with various aqueous and organic flow rates, and validated with experimental data. Keywords: CFD, metal extraction, hollow fibre membrane, heavy metals

Jan 1, 2020

By L. Naude, J. Cloete, S. Engelbrecht

The results of an investigation evaluating whether an industrial plant, currently operating using sodium isobutyl xanthate (SIBX) as primary collector for sulphide minerals (mainly chalocopyrite), could adapt to operate using an alternate primary thiol collector without compromising plant and metallurgical performance. Initial laboratory scale flotation tests identified commercial dithiophosphate (DTP)-based and thionocarbamate (TC)-based collectors, that when blended, showed potential to replace the incumbent SIBX primary PGM collector. Industrial plant trail results show that there was no deterioration in recovery of 4E PGMs, even at a lower concentrate grade when operating the plant on the identified (DTP + TC)-based collector blend compared to SIBX. The effect on Cr2O3 content in the final concentrate was also found to be negligible. The (DTP + DTC)-based collector blend also showed promise in terms of plant adaptability in accommodating a new primary specialty collector blend. These observations highlighted the potential of replacing xanthate primary collectors with alternate thiol collector blends for PGM flotation. Keywords: PGM, xanthate replacement, specialty collector, sodium iso-butyl xanthate (SIBX), dithiophosphates (DTP), dithiocarbamates (DTC)

Jan 1, 2020

By S. Ling, T. Liu, Y. Shang

A new copper-molybdenum flotation technology developed for a certain coppermolybdenum ore is introduced. We achieved copper-molybdenum bulk flotation in lowalkali conditions. Locked-circuit test results showed that the bulk concentrate contained 21.05% Cu and 1.10% Mo, with copper recovery of 87.37% and molybdenum recovery of 77.07%. For the copper–molybdenum separation process of the bulk concentrate, we use a new depressant, BK511, to replace the traditional sodium hydrosulfide. We achieved copper–molybdenum separation through one rougher, nine cleaner, and two scavenger processes. The results of locked-circuit tests showed that the molybdenum concentrate contained 46.19% Mo and 0.75% Cu, with molybdenum recovery of 93.80%; the copper concentrate contained 21.50% Cu and 0.069% Mo, with copper recovery of 99.92%. This new technology overcomes disadvantages of using large amounts of lime, sodium hydrosulfide, and other reagents in traditional copper–molybdenum flotation.

Jan 1, 2023

By N. Mutemeri, T. -L. Field, M. Chuma

The categorization of artisanal and small-scale mining has a significant impact on perception and understanding of the sector, particularly from a livelihood perspective. Several developing countries classify different types of artisanal and small-scale mining based on legal status. Given the nature such activities, the tragedy of the commons theory has been applied to understand the inevitable environmental, economic, sociocultural, safety, and health negative externalities – which are products of informality and illegality. Consequently, formalization is a panacea to sustainability. This article aims to offer a conceptual organization and foundational knowledge for characterization of artisanal and small-scale mining. It seeks to identify existing literature on the subject to avoid replication and acknowledge other scholars. Moreover, the article aims to place the study within the context of existing literature, establishing relationships with other studies and why the research is necessary. This paper pinpoints gaps left from other studies in so far as the characterization of artisanal and small-scale mining is concerned. Thus, reviewing literature abetted in finding similarities and differences on how artisanal and small-scale mining is defined from a scholarly and legal basis. The paper ascertains major claims made by earlier research on this topic, such as environmental impacts, the lack of adequate regulatory framework, and presents querying and probing questions lacking from other studies.

Jul 10, 2024

By A. Navarra, A. Quelopana

The mine production scheduling problem (MPSP) has been studied since the 1960s, and remains an active area of computational research. In extending the concepts of the MPSP, the automated mine may now be regarded as a hierarchical intelligent agent in which the bottom layer consists of distributed robotic equipment, while strategic functionality occupies the higher layers. Here we present a disambiguation of artificial intelligence, machine learning, computational optimization, and automation within the mining context. Specifically, the Q-learning algorithm has been adapted to generate the initial solutions for a high-performing strategic mine planning algorithm, originally developed by Lamghari, Dimitrakopoulos and Ferland, based on the variable neighbourhood descent (VND) metaheuristic. The hierarchical intelligent agent is presented as an integrative conceptual platform, defining the interaction between our new Q-learning adaptation and Lamghari’s VND, and potentially other hierarchically controlled components of an artificially intelligent mine, having various degrees of automation. Sample computations involving Q-learning and VND are presented.

Dec 1, 2021

By M. Hopf

Numerous developments and improvements have been made to tap-hole designs. On the other hand, there are very specific designs in operation that have endured for many years without any modification. Nobody likes design changes because of risk - the risk of atypical wear, potential hazards, and costly repairs entailing enormous production losses. So the philosophy ‘never touch a running system’ is maintained, because among other things there is no efficient working monitoring technology for tap-holes. In the past few years a couple of new technical solutions have been investigated and developed. Not all theoretical solutions are possible in practice. However, metallurgists are inventive, and the last word regarding efficient working tap-hole monitoring technologies has not yet been spoken.

Jan 1, 2014

By A. E. Lewis, J. Du Plessis, J. Chivavava

Current metallurgical processes lack selective and efficient REE recovery from aqueous leach liquors. Antisolvent crystallisation is used to selectively recover pure inorganic salts from aqueous solutions without excessive chemical use in ambient conditions. Yttrium sulfate octahydrate (Y2(SO4)3.8H2O) was used as a representative rare earth salt to investigate the effect of antisolvent selection on the crystal morphology and size distribution of the final crystalline product produced through antisolvent crystallisation. The antisolvents of choice were short length alcohols that are water miscible i.e. methanol, ethanol, 2-propanol and t-butanol. All experimental parameters except the type of antisolvent were kept constant under isothermal conditions. The large reduction in solubility of the salt by the antisolvent creates high supersaturations. This leads to high product yields as observed in this study at > 91%. In general, a variety of morphologies were successfully formed in each individual alcohol including; rods, plates, prismatic cubes and starburst clusters. The powder X-ray diffraction (XRD) analysis indicated that Y2(SO4)3.8H2O was the only species present for all final products. There was a change observed from the starburst and rod structures for the shorter alcohols towards prismatic cubes for the longer alcohols due to different strengths in the solute-antisolvent interaction at the crystal growth faces. The crystal sizes increased with an increase in the alcohol chain length because of the lower supersaturation conditions due to a limit in the mass transfer induced by the bulkier alcohol structure. In conclusion, it has been shown that the particle morphology and size can be greatly affected by the selection of antisolvent even under high supersaturation conditions, contributing to understanding the effect of different antisolvents on the final particle characteristics. The engineering of favoured product characteristics can therefore be achieved by antisolvent crystallisation, presenting a viable alternative process for the recovery of REE. Keywords: Antisolvent crystallisation, rare earth elements, morphology, particle size

Jan 1, 2020

By V. E. Cogho

Optimum Coal Mine comprises numerous defunct, active, and future mining sections. The mine is primarily a large opencast coal mine; however, underground mining activities will be increasing steadily over the next five years. Opencast and underground mining activities have a significant impact on surface and groundwater resources. To ensure that the mine will be able to continue with its mining operations in the catchment, the extent of this impact requires that substantial intervention and mitigation measures need to be implemented to ensure the environmental integrity and economic use of the catchment's water resources. In developing a sustainable long-term mine water management strategy, numerous scenarios had to be analysed. The various scenarios are a combination of water and land management activities. The main components of the mine's integrated water management strategy include: ? Management of water recharge by continual and appropriate rehabilitation of disturbed land ? Beneficial re-use of impacted mine water for coal plant process water and mining operations ? Reclamation and desalination of remaining excess impacted mine water to potable standard. From the mine's long-term water balance, it is evident that the continued implementation of numerous water management actions is required to mitigate the water resources impact in a sustainable manner. In addition, the installation of a water reclamation plant at Optimum Coal Mine (15Ml/day) is a key step for the mine to achieve a zero impact target.

Jan 1, 2012

By Allan Jansen, Robin Bissett

[Power-Point Presentation]

Jan 1, 2005

By J. G. M. Mukoya, B. Adebayo

"This work was carried out to determine the influence of rock properties and drilling machine parameters on the penetration rate at the SJ pit of Rössing Uranium Mine, Namibia. Rock properties (uniaxial compressive strength, tensile strength, and modulus of elasticity) of samples collected were determined in the laboratory. Drilling experiments were conducted in which feed pressure, air pressure, rotary speed, weight on the bit, and torque were varied to measure their effect on the penetration rate. The uniaxial compressive strength varied from 90–180 MPa for layered marble-quartzite and banded gneiss. Increases in feed pressure, weight on the bit, and rotary speed beyond the optimum level led to a decrease in penetration rate and caused the drill bit to ‘stall’. Results of the study revealed that penetration rate increases with an increase in the feed pressure and air pressure. After reaching a maximum value, the penetration rate begins to decrease despite increasing feed pressure. A very high torque causes the drill bit to stall, since the feed pressure is too high and the air pressure is not sufficient to remove the cuttings from blast-hole at maxium bailing velocities. The average penetration rate varied from 19 to 45 m/h for phase 2 of the pit, and from 17 to 68 m/h for phase 3. The optimum drilling machine parameters obtained in phase 2 and phase 3 were slightly lower than those currently being used at the mine. The trials of the optimum machine parameters will assist in reducing the cost of drilling, which varied from N$29.48 to N$36.31 per metre for the tricone bit. IntroductionDrilling and blasting contribute most to the operational cost in opencast mining and have the potential to influence the cost of downstream operations (Aipanda, 2011). The drillability of rocks depends not only on the rock properties, but also on the drilling tools and operational variables. In rotary drilling, rotational speed, thrust, and flushing are the operational variables, and are known as the controllable parameters. Rock properties and geological conditions are the uncontrollable parameters. Although, many attempts have been made to correlate drillability with rock properties, the rock characteristics affecting rotary drilling have not been entirely defined (Hartman, 1962; Kahraman, Bilgin, and Feridunoglu, 2003). The drill bit is forced into a rock surface from the rotary power head, hence creating stresses and cracks at the bit-rock interface. The performance of a particular bit in any formation i"

May 1, 2019

Jigging is a process of particle stratification in which the particle rearrangement results from an alternate expansion and compaction of a bed of particles by a pulsating fluid flow. The rearrangement results in layers of particles that are arranged by increasing density from top to bottom of the bed. The particles, in addition to the vertically expanded and compacted bed motion, move continuously, horizontally across the supporting screen and helped and influenced by the feed material that is introduced at one end. Following the particle stratification, the particle bed is physically ?cut? at a desired horizontal particle density plane to separate the desired product from the less dense gangue material. The issue of correct pulse characteristics (shape, amplitude and frequency) for the optimal metallurgical stratification of air pulsating jigs has been the subject of much discussion over the years. The accuracy of the dissymmetric stratification depends on the control parameters and the mechanical condition of specific equipment used. This paper will touch on some of the control and mechanical parameters affecting the separation efficiency.

Jan 1, 2010

By J Taguta, B. McFadzean, P. E. Ngoepe, M. G. Mulaudzi

Computational modelling methods and isothermal titration calorimetry (ITC) were employed to investigate the interaction of a pyrite surface with thiol collectors. Modelling work was conducted in the presence and absence of water. Microcalorimetry was employed to investigate the resultant energy of interaction pyrite as a result of mineral-collector interactions. Sodium ethyl xanthate (SEX), diethyldithiocarbamate (DTC) and diethyl dithiophosphate (DTP) were investigated in this study. The results showed that the calculated surface energies and morphologies for FeS2 showed that (100) and (111) are the most stable surfaces. The morphology also indicated the appearance of the (100) and (111) surface facets and no presence of others. The calculated adsorption energies between thiol collectors and the pyrite surface were always more exothermic than the experimentally determined ones. When comparing different ligand types with the same alkyl chain length, the heat of adsorption of diethyl-DTC was greater than that of ethyl xanthate and diethyl-DTP for pyrite. Experimentally, the diethyl DTP barely adsorbed onto the pyrite surface and this may be due to a different mechanism of action. In computational calculations, water adsorption was found to reduce the reactivity of the Fe atom for the interaction with thiol collectors, and bring the adsorption energies closer to the magnitude of the experimental values. Keywords: Computational modelling, microcalorimetry, experimental and thiol collectors, adsorption energies

Jan 1, 2020

By F. K. Crundwell

The rate of dissolution of sulphide minerals is frequently interpreted in terms of the passivating behaviour of a layer of material on the surface. This interpretation has driven research to identify and possibly remove this layer from the surface, and thus yield higher rates of dissolution. The identification of such layers has proved difficult, with different researchers claiming different compositions for possible layers. An alternative framework has been pursued by the author and co-workers, who have argued that the rate of dissolution is governed by the electronic structure of the minerals which give rise to their semiconducting properties. Researchers sceptical of this approach have argued that semiconducting properties are only important in highly pure substances. In this paper, we review the electronic and semiconducting properties and discuss how they impact dissolution behaviour. These properties affect their colour and dissolution properties even though the minerals are not high purity substances. Keywords: Dissolution, leaching, passivation, semiconductor, chalcopyrite

Jan 1, 2020

By M. Rudolph, J. Sygusch

Froth flotation is well-established and efficient in the selective separation of valuable particles from unwanted material with sizes ranging from 10 μm to 200 μm. However, when it comes to the separation of ultrafine particles (< 10 μm) there are still some challenges, or rather opportunities. This research aims at developing a method for the separation of ultrafine particles based on multiple particle properties. Amongst such properties are wettability, morphology (shape or roughness) and size with applications not only in mineral processing but in general chemical engineering. In this study, three differently shaped fractions are used as valuables for testing: spherical particles, elongated particles and irregularly shaped particle fragments; together with ultrafine magnetite as the gangue material, in order to investigate the effect of particle morphology on ultrafine particle flotation, as well as wettability, which is varied by esterification using alcohols. Flotation tests are carried out using a novel flotation device that was designed especially for the flotation of ultrafine particles, combining advantages from machine-type froth flotation and column flotation. The results showed that, in contrast to previous studies, recoveries for ultrafine spheres were higher than for ultrafine fragments for all wettability conditions, and hydrophobisation generally increased particle recoveries for said morphologies. Tests using fibres showed different behaviour as hydrophobisation had negative effects on their recovery, despite increased selectivities and kinetics. These findings suggest that apart from influences of particle properties within the suspension zone, their effects on the froth characteristics should be studied in more depth. Keywords: Ultrafine particles, Flotation, Particle shape, Wettability, Esterification of glass, Hydrophobisation

Jan 1, 2020

By P. Kitobo, T. Nduba, D. Mbay, J. B. Vangu, R. Ciband

The flotation plant tailings at Kamoa Copper Mine concentrator were found to contain a high proportion of extremely fine particles. The potential issues with settling these fine solids were resolved by the use of a poly-di-allyl-di-methyl ammonium chloride (DADMAC) coagulant, Flobead DB 45 VHM, in conjunction with a standard anionic polyacrylamide flocculant. This paper outlines some of the issues encountered and how they were resolved at the Kamoa concentrator. The potential to use this process and technology at other sites is also considered

Jan 1, 2023

By R. Jacobs, R. E. L. Pobe

The Moab Khotsong Metallurgical Complex comprises a gold recovery circuit (Noligwa Gold Plant) and a uranium recovery circuit (South Uranium Plant). The metallurgical complex employs the reverse leach technology for the recovery of uranium; specifically, uranium extraction prior to gold using acid leaching processing. The inherent uranium species in the ore are uraninite, coffinite and brannerite. The slurry that has been subjected to the uranium leach is further subjected to solid-liquid separation to separate the uranium in a solution through counter-current decantation and the solids (solids carrying all the gold), which are repulped and returned to the gold plant for gold processing. The uranium leaching process is critical to the uranium playing a pivotal role as a value adding by-product to the gold operation. The benefit of adopting this reverse leach process, for improved gold recovery, is that it exposes gold particles occluded within the uranium matrices and avails them for cyanidation. However, the drive for operational efficiency in uranium extraction must be weighed against the incremental operating cost against the backdrop of depressed spot uranium market prices. Over the years, efforts were directed at maintaining the benefit of extracting uranium to enhance gold recovery and simultaneously, optimising the operating cost model for the uranium operation to remain relevant to the gold operation. The aim of this paper and the corresponding presentation is to give an account of the uranium processing optimisation journey embarked on over the years; namely, the operational tradeoffs made in the process of ensuring that uranium continues to add value to the gold operation. These challenges were faced while striking a fine balance between processing cost and operational efficiencies against the prevailing depressed uranium spot market prices. Mineralogical- and laboratory tests conducted form the support basis for the results and observations articulated in the paper. Keywords: By-products, gold extraction, reverse leach benefit, uranium extraction

Jan 1, 2020

By M. Rudolph, R. Tolosana-Delgado, G. van den Boogaart, M. Reuter, U. Peuker

This paper addresses the challenge to define a concept of entropy (state of order) for a textured particle system. Both the particle texture, the intergrowth respectively, and the particle size influence the order of a particle system. The smaller the particles become, the more particles form the solid system and the more permutations of the structure of the particle bed are possible. The texture within a particle is fixed, as long as it is not subjected to changes due to comminution, flocculation or agglomeration. The paper will present a definition of entropy, which is able to reflect qualitatively and quantitatively the intergrowth and the size (distribution) of the particles. Theoretical examples will show how different breakage mechanisms can be identified using the entropy definition. Furthermore, we will define the specifications for data sets to calculate the entropy of a particle system. Keywords: Milling, mineral liberation, intergrowth, statistical entropy, modelling

Jan 1, 2020

By Q. G. Reynolds

The dual-electrode DC arc furnace, an alternative design using an anode and cathode electrode instead of a hearth anode, was studied at small scale using computational modelling methods. Particular attention was paid to the effect of two key design variables, the arc length and the electrode separation, on the furnace behaviour. It was found that reducing the arc length to brush arc conditions was a valid means of overcoming several of the limitations of the dual-electrode design, namely high voltages and arc deflection.

Jan 1, 2012

By J H. Sullivan

Contents Background information Locality of Kumba?s Iron Ore Mines Sishen?s Product Specifications Geological Description of boreholes Sample Preperation Block delineations Production Geology Process Laboratory information Turnover times reached Inter Laboratory Comparisons Quality control activities in lab Purpose of laboratory Results attained Standard samples Monitoring of processes with QA/QC standards Mean paired difference of duplicates Duplicate samples Conclusion

Jan 1, 2005

By A. J. Barrett

Backfilling at Vaal Reefs during the experimental phase has been carried out using cyclone-separated tailings which are transported underground hydraulically by means of a borehole. The selected tailings are piped from the borehole to the stope and then, after the addition of a flocculant, deposited in place via single or multiple nozzles. The successful performance of the backfill/stope system relies not only on the actual quality of the placed material, but also on the effective operation of stope filling. The success of stope filling relates to the complex, time- dependent interaction of backfill, stope and barricade materials, and the transport and placement procedures used. A comprehensive laboratory testing programme was carried out on backfill materials at Vaal Reefs in conjunction with the experimental stope- filling operation. The range of testing techniques corresponds to the requirements of each stage of the backfilling process. Where necessary, new or alternative techniques were sought during the course of the experiment to satisfy and facilitate better understanding of the different processes. These techniques comprise both routine quality control testing and research-oriented testing. The laboratory testing techniques appropriate to each stage of the backfill process are briefly discussed. This paper presents the main conclusions of the study and identifies areas for further research.

Jan 1, 1988