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By O. Dojcar

Equations for calculating the parameters of controlled blasting (burden and spacing of boreholes and weight of the bottom charge) are derived and analysed on the basis of empirical values and made more precise through incorporation of the properties of the rock being blasted and explosive applied. For the success of controlled blasting the correct choice of the blasthole diameter/charge diameter ratio is critical. This relation is defined as the coefficient of radial decoupling of the charge; it is recommended that it is chosen to be between 3 and 3.5. Analysis of smooth blasting, cushion blasting and presplitting indicates that cushion blasting is a less destructive alternative to smooth blasting, but it has a slightly higher blasthole consumption and limited possibilities of use. There are definite economic advantages to controlled blasting, especially in rock masses of low and medium strength

Dec 1, 1996

By A. J. Beer, A. Wetherelt

Paper presented at the UK minerals industry conference held in Leeds, UK, 3-5 April 1995. Camborne School of Mines has developed a simple, cost-effective light-sectioning method that has been used successfully in tunnels and small stopes. Light sectioning provides an almost visual examination of the stope's excavated profile. An illuminated section of walls, roof and floor is recorded photographically. Overbreak and underbreak can then be easily quantified by reference to the designed shape. The prototype rig is described. Use of a fish-eye lens to capture a greater field of view is discussed. Calibration was achieved by comparison with images made with a conventional wide-angle lens with nominal distortion. The system is reliable under a range of operating conditions including dust, heat and humidity. It is also simple and easy to use, does not require skilled personnel and is low cost

Jun 18, 1905

By P. A. Wright

The note describes the steps involved in the combination of results reported by Shiraishi and Bell in 1968 and 1970 and by Mills and Turkdogan in 1964. Shiraishi and Bell derived from their vapour-pressure measurements an expression for the activity coefficient of tin implying that the miscibility gap in the two-liquid region is symmetrical about the N = 0-5 axis. The limits of the miscibility gap were reported by Shiraishi and Bell and measurements were reported graphically by Mills and Turkdogan. Least-square parabolas are fitted to the transformed results of Shiraishi and Bell and of Mills and Turkdogan for the miscibility gap in the liquid tin-iron system. Back-transformation from these curves gives limits at 1438 K and equations are derived that appear to be a fair average of existing data, although a third term for the activity coefficient equation needs to be investigated

Dec 1, 1971

By A. C. Dunham, Y. D. Drakapoulos, P. W. Scott

The Pt and Pd occur alloyed with copper in small, irregularly-shaped grains, 0.25-5.0 micrometers in maximum dimensions. Grains of unalloyed native copper are also present. The grains are completely surrounded by or marginal to magnetite with inclusions of Ni-Fe-Co sulphides and native Ni-Fe, which is apparently a product of the serpentinisation process. Crystallisation of the Pt-Pd-enriched copper probably occurred at the same time, at low temperature, but the previous form of the Pt and Pd is unknown as no earlier PGE phases have been found. While Pt and Pd minerals are usually important in early-magmatic base-metal sulphides, Pt alloyed with Cu is extremely rare and apparently occurs only very late in the paragenetic sequence. A Cu alloy with Pd dominant over Pt and only minor amounts of other elements appears not to have been reported

Jun 14, 1905

By M. C. Amiri

The plant produces 130 kg slag per tonne of crude steel, to add to the basic oxygen steel-making converter slag stockpile of around 2 500 000 t. The slags contain 1.81% V2O5, which can be rendered water-soluble by salt roasting with NaCl and an alkali such as Na2CO3. Preliminary tests gave less than 3% V recovery from slag under optimum roasting conditions when NaCl, NaCO3 or Na2SO4 was used, but showed that sodium phosphate could make all the V water-soluble when roasted with slag in a ratio of 3:1 at 1 100-1 200 degrees C. Almost complete leaching was obtained within 2 h with water at boiling point. Sodium vanadate was precipitated by acidifying the leach liquor with HCl to a pH of about 2.2

Jun 21, 1905

By D. G. Skinner, M. SC. Griffiths

"The natural difficulties associated with the size evaluation of dusts render absolute measurement difficult, or indeed, impossible. Assuming that the desirability of gravi­ metric sampling be conceded, it appears likely tha,t the most suitable means available for physical evaluation are the method of total turbidity measurement, to give a con­ ventional value for specific surface, together with microscopical examination, the great merit of the latter being that in the hands of an experienced operator, semi-quantitative discrimination between coal and other particles is possible.The pipette method, as modified by Fryer, probably-deserves more attention than it has received up to the present. Whatever method is used, it is recommended that in view of the lack of medical knowledge, as much information as possible should be obtained with reference to the total mass concentration, the surface area of the total dust,' and the mass and area of the particles below 5μ in size."

Jan 1, 1947

By T. From

The organisation's mission is to promote research and technological development in processes relevant to the minerals industry by providing expertise, developing and managing jointly funded projects, undertaking commissions and education and establishing and maintaining research and development networks. It was responsible for the administration of the Mining Technology 2000 national programme to reduce production costs per metallic unit by 50% over 5-8 years, which involved 120 projects in all. Technical areas included ore characterisation/delineation and mine planning, rock fragmentation, rock mechanics, maintenance, energy and ventilation, automation and information systems, cut and fill, bulk mining methods, drifting and production-face development. Other projects have been the Ore Geology Related to Prospecting (PIM) programme to raise the standard of ore geology research in Sweden and promote exploration for volcanogenic massive sulphides in three key regions, and a joint research project on ventilation control according to requirement, including development of fan and gas monitoring systems and an improved, adjustable and intelligent fan

Jun 17, 1905

By D. Mireku-Gyimah, R. S. Suglo

Ghana contains auriferous belts which cover 51 800 km2 of its small area of 239 400 km2. From 1493 to 1600 35.5% of the world gold production was from the Gold Coast (renamed Ghana in 1957). This dropped to 8.9% from 1701-1800. For the past fifteen years annual production has averaged less than 2% of the world total. By 1985 only four gold mines were operating, compared with 45 in 1934 and 11 in 1945. Since 1987 Ghana has experienced a boom in gold mining activities. By 1991, 83 new companies had acquired prospecting licences. At least five new companies have started large-scale production. About 650 licensed small-scale mining groups are in operation. The economic and technological factors that have contributed to the decline of gold production in Ghana are discussed. A summary is given of the methods used to mine and recover gold. These cover small-scale workings, dredging, open cast operations and underground mining. The advantages and disadvantages of these technologies and the future of gold mining in Ghana are considered.

Jan 4, 1993

By Z. H. Khan, A. K. Saha, D. D. Akerkar

The possibility of extracting nickel from a low-iron, highly siliceous nickel ore of Indian origin using roast reduction followed by an ammonia leaching process has been examined. The ore used in the investigation contained 0.82 wt% Ni, 6.20 wt% Fe3O4, 12.04 wt% MgO and 60 wt% SiO2. Phase changes in the constituent minerals on heating were studied by differential thermal analysis which revealed endothermic peaks at 110 and 695 degrees C and an exothermic peak at 810 degrees C. Significant process variables in studies of roast reduction include the amount of reductant, the temperature of reduction and chemical kinetics. Maximum nickel extraction was achieved by reducing the ore with 10 wt% fuel oil at 750 degrees C. The reduced ore was given a preconditioning treatment in concentrated ammonium hydroxide solution to oxidise most of the metallic iron and was then leached in aqueous ammoniacal solution at ambient temperature to dissolve nickel. This gives 88.5% extraction of nickel as soluble ammine complexes.

Jan 4, 1992

By R. W. Ruddle

The present state of knowledge on this subject may briefly be summarized as follows: (1) The copper content of the slag increases with the grade of the matte in contact with it; on the other hand, the proportion of copper lost decreases as the matte grade increases, because as a general rule a smaller volume of slag is produced when a high-grade matte is made. (2) The presence of CaO and MgO in the slag decreases the copper content of the slag, and the presence of ZnO increases it; the presence of A1203 seems to have little effect. The influence of the silicate degree is not yet clarified, but on theoretical grounds it seems likely that the copper content increases with the silicate degree of the slag. (3) High slag viscosity, high magnetite contents and low density difference between matte and slag all tend to increase the copper loss. The volume of slag is also an important factor. (4) The effect of bath temperature on the copper loss is not clear and further investigation of this point is needed. (5) It appears possible to recover a large part of the copper in the slag by adding FeS, CaS and other sulphides

Jan 1, 1953

By C R. Ferrari

Residual subsidence is generally accepted as being about 5% of the total subsidence occurring within 12 months of all mining finishing. This paper looks at five case studies from different parts of the country, in various mining settings within a depth range of 430m to 760m. From a single seam single panel working to working the eleventh seam, all are within the concealed coalfield, similar to today's mining. The monitoring of subsidence continued for many years once the mining had finished and the results obtained are at considerable variance from the accepted norm. Subsidence has been found to carry on for up to eleven years after mining has ended, within a range of 8% to 45% of total subsidence. A highly significant factor was that subsidence, as a whole, was generally much more than predicted. The residual subsidence aspect has to he viewed in this context and in order to debate the subject at length, the causes of residual subsidence have to be balanced against the apparent inability to accurately predict subsidence. The results from the case studies were similar, even though the mining settings differed considerably. Subsidence of around 10% to 20% continued for several years after mining had ceased.

Jan 7, 1997

By D. J. Wall, T. D. Johnson, M. T. Parry, G. R. Heath

In coal-fired power stations coal is ground to a fine powder and then transported pneumatically at 25-30 m/s velocity to remote burners. Wear of the conveying pipework is a well recognised problem and traditional lining materials are Nihard and basalt. In many cases these are being replaced by alumina tiles in order to improve life and reduce the frequency of replacement. A programme of laboratory testing of candidate aluminas with AIO, contents between 85% and 99-5% has been undertaken and the results compared with field experience. This gives confidence in the erosion tests, which were designed to replicate most of the field conditions. However, it has not proved possible to draw correlations between the laboratory erosion rates and any of the materials’ bulk properties. SEM, TEM and microanalysis studies have therefore been made in order to look for microstructural aspects that could be influencing erosion rates and it has been shown that intercrystalline cohesion, the matrix phase and porosity appear to have most influence on wear performance. It is necessary to quantify these microstructural parameters if reliable erosion performance is to be obtained. This paper was read at the Institute of Ceramics Annual Convention at the University of Durham, April 1988.

Jun 12, 1905

By A. Z. Lang, D. A. Hall

After a brief description of the causes of spontaneous heating and of general preventative methods, a detailed account is given of occurrences of spontaneous heating in the Main Seam (locally known as the 5/4 Seam) at Westoe Colliery. This seam is about 12 feet thick consisting of hands of coal and shale, but only 4 feet 6 inches is worked because of the thickness os strata in water-bearing rocks and the worked section is selected on quality considerations. An advancing longwall face in this seam (2nd South) began to heat after working for six months and ultimately had to be abandoned. By adopting retreating methods and mining narrow panels it has been possible to extract this coal at an excellent rate of productivity. The system of goaf ventilation is important, because the use of a bleed road would have given rise to dangerous conditions in a goaf which of necessity would have contained fallen coal. Preparatory seals were prepared at selected sites so that, if necessary, a panel could be sealed off quickly; these seals are completed as soon as possible (within three weeks) of finishing a panel. A gas sampling system has been instituted which includes daily sampling on the face and in the goaf, and weekly sampling at the stoppings of all completed panels. The coal has now been extracted from this seam for three years without any further difficulties from spontaneous heating.

May 23, 1905

By A. H. G. Mitchell

Gold-poor and gold-rich porphyry and epithermal gold-silver deposits of Caenozoic and Cretaceous age in the western Pacific and central and eastern Europe are confined to predominantly andesitic continental margins and island arcs. The arc volcanic rocks overlie a complex non-oceanic basement of stacked nappes, the uppermost of which is often ophiolitic. The emplacement of ophiolite triggered a reversal of tectonic polarity, subduction and arc magmatism. Andesitic volcanism and the formation of a strato-volcano were followed by the ascent of magma and porphyry copper mineralisation. Regional propylitic alteration came from convecting, predominantly meteoric fluids. Magmatic degassing caused advanced argillic alteration. This is commonly unmineralised in perched water tables, but may sometimes host high sulphidation gold or enargite gold at deeper levels within the propylitic zone. The onset of extensional stress after the andesitic volcanism allowed meteoric water to circulate to depths of 5 km or more, with consequent cooling of an ascending magma body at depth and the development of low sulphidation epithermal gold mineralisation near and immediately above the sub-volcanic basement surface. All andesitic arcs are mineralised. Regional controls on their ore potential include the level of erosion and geological features in the basement that focus the ascent of fluids. Differences between the mineralisation of the European and the western Pacific arcs may reflect the presence of older, more granitic basements in many of the European arcs.

Jan 12, 1992

By K. C. Dunham, M. Solomon, T. A. Rafter

Sulphur isotope ratios have been determined for 81 sulphides and S and O isotope ratios for 26 barites from the Alston Block in the northern Pennine ore field. In addition, both isotope ratios have been determined for 29 evaporitic anhydrites of various ages from European and Australian localities. The consistency of the sulphate isotope ratios over a wide area of the northern Pennines, and their similarity to values for Lower Carboniferous evaporites, suggests that the sulphate originated from Lower Carboniferous connate waters. It is suggested that these mingled with warm brines rising through granitic plutons beneath Tynehead and Upper Weardale, the aqueous sulphide ion in these brines having a delta34S value of approximately +10 per mille. The delta34S values for the sulphides range from +15.0 to -5.9 per mille and show an outward zoning with higher values in the central fluorite zones and mainly negative values in the outer barite zones. The wide range of delta34S values for the sulphide S is not characteristic of magmatic S and there is no adequate local source in the Carboniferous sediments. It is suggested that formation waters, probably mainly of connate origin, sank down sufficiently deep to become heated above 200°C before rising through Caledonian granite plutons into the Carboniferous sediments, where they spread laterally to mingle with cooler sulphatic connate water. The rising fluids were hypersaline brines carrying F, Ba, Pb, Zn, Cu and S. Temperatures of deposition calculated from galena-sphalerite isotope fractionation are similar to temperatures previously determined from fluid inclusion studies.

Dec 1, 1971

By T. Piirainen, T. Alapieti

"The Koillismaa layered igneous complex is the result of igneous activity that occurred 2436±5 m.y. ago. Its crystallization took place in three separate but connected magma chambers, the total volume of which is estimated at more than 2000 km'. These chambers were located partly in a feeder system within Archaean granitoids and partly in an unconformity between these grani­ toids and Early Proterozoic supracrustal rocks. The composition of the parental magma that initially filled the chambers is thought to have been that of a relatively MgO-rich tholeiite. Sulphides and platinum-group minerals are mainly concentrated in the marginal series of the western part, where they are encountered over a distance of 25 km. This marginal series is an originally nearly horizontal series of rock types that displays a reversed differentiation trend, grading inwards from gabbroic to ultramafic rocks, followed bv rocks of the layered series. The chilled margin is not encountered anywhere in its original position at the contact, probably as a consequence of magmatic erosion, but remnants are to be found in the form of elongated xenoliths. Partly melted siliceous fragments from gneissic country rock typical of the lower part of the marginal series indicate pronounced contamination.Chalcopyrite, pentlandite and pyrrhotite±pyrite are the predominant sulphides. The accessory sulphide minerals include covellite, violarite, marcasite, mackinawite, sphalerite and argentian pentlandite. Platinum-group minerals are represented by froodite, michenerite, merenskyite and sperrylite. Other accessories that have been identified are electrum and native copper and gold. The mean of the Cu/(Cu+Ni) ratio in the mineralizations is 0.67 and Pt/(Pt+Pd) 0.31.It is suggested that the sulphide phase was formed in the marginal series as the solubility of sulphur in the basic magma was lowered by contamination, possibly assisted by some other factors. The sulphur isotope data support the juvenile origin of the sulphur."

Jan 1, 1984

By H. L. Paterson, R. R. Keays, M. J. Donaldson, D. J. Boyack, M. F. Smith, J. J. Gresham

"Albite-rich sedimentary rocks that contain abundant Fe sulphides occur in the lower portion of the ultramafic sequence at Kambalda and their broadly antipathetic relationship to most of the nickel orebodies is well documented. These sediments generally contain less than 0.1% Ni, but nickeliferous equivalents with 0.3 to >6% Ni occur locally in close spatial association with more typical volcanic peridotite-associated massive, matrix and disseminated ores. Nickeliferous sediments have been mined at several locations at Kambalda but, collectively, they constitute less than 2% of the total Kambalda nickel reserve. The nickeliferous sediments occur both on the ultramafic-footwall basalt contact and within the lower part of the ultramafic sequence, and are usually less than 5 m thick. They are commonly finely laminated rocks with a cherty appearance, composed essentially of layers of albite+quartz±amphibole, alternating with pyrrhotite+pentlandite±pyrite layers. Some contain a minor amount of carbon. The sediments are only of ore grade (> 1% Ni) immediately adjacent to massive Fe-Ni-Cu sulphides, which are interpreted as normal magmatic ores on the basis of geochemistry and the presence of distinctive ferrochromites. The nickel content of the sediments decreases to background levels (<0.1%) within about 20 m of the massive sulphides. In most locations the massive sulphides clearly have been emplaced tectonically within or adjacent to the sediments, which are commonly highly deformed. Typical nickeliferous sediments contain about 1% Ni, 0.1% Cu, 0.1% Zn, 400 ppb Pd, <0.2 ppb Ir and 10-200 ppb Au. They have lower Ni/Cu (average 10), higher S/Ni (average 6) and higher S/Se (average 11 200) than associated massive sulphides (average 40, 4.8 and 7400, respectively). The Pd/Ir ratio of the nickeliferous sediments (typically > 1000) contrasts markedly with that of associated massive sulphides (average ca 16).The high Pd/Ir values are similar to those which have been reported for hydrothermal Fe-Ni sulphides and barren sulphidic sediments of probable volcanic exhalative origin. They preclude a direct magmatic origin for the sulphides in the nickeliferous sediments, though S/Se and S isotope data indicate a magmatic source for the sulphur. The restriction of nickeliferous sediments to within about 20 m of normal magmatic sulphides and the lack of a widespread Ni dispersion halo suggest local redistribution of originally magmatic Ni. This probably occurred by diffusion and hydrothermal mobilization during deformation and amphibolite-facies metamorphism. Although not totally ruled out, a volcanic exhalative origin for the Ni seems unlikely."

Jan 1, 1984

By J. Plant

Stream-sediment sampling undertaken to define the regional geochemistry of northern Scotland is described with particular reference to the errors involved. The region is underlain essentially by Moine schists, Caledonian granites and Old Red Sandstone sediments, which are generally characterized by low geochemical relief. Factors in the secondary environment obscure the relationship between trace-metal concentrations in stream sediments and bedrock geology. Investigation of sampling and sample preparation methods indicates that the -100-mesh material is the optimum size fraction for the regional survey of this area: it provides adequate geochemical contrast: it reduced the incidence of spurious high values in the samples investigated and it is available in amounts which are adequate for all the analyses required. Grinding samples improves precision and reduces the preferential volatilisation of metals coprecipitated with hydrous manganese and iron oxides for the optical emission spectroscopic method used initially. A study of the dispersion of metals in the drainage system of an area of Pb-Ba-Mo mineralisation and an area of U-Pb mineralisation, respectively, indicates that a sampling interval of 1 per 2 km2 based on second- or third-order streams is adequate to define anomalous metal concentrations. Regional variation can also be represented on the same interval. Modifications to the sampling procedure to reduce the effects of the secondary environment are complicated by the primary association of Mn and Fe with mineralisation in the area. The ratio of analytical and sampling error to regional variance shows that procedural precision is adequate to prepare regional geochemical maps of northern Scotland, with the exception of Cr, Cu at low concentrations and Pb.

Dec 1, 1971

By Winmill T. F.

The previous papers have been concerned only with the atmospheric oxidation of coals from the Barnsley Seam, for which it has been shown that an adequate explanation of the origin and nature of gob-fires can be based on the reaction between the coal itself and the oxygen of the air without the intervention of any other substance. It becomes of importance, therefore, to ascertain how far a similar explanation will hold good for spontaneous heating in other seams, and with this object in view samples including anthracite and lignite have been taken from a considerable number of pits in different parts of the UK (south Wales, Northumberland and Durham, north Staffordshire, Portrush and Ayrshire), some liable to fire, others not. There is abundant evidence to support the commonly-accepted view that spontaneous heating is due to the heat evolved during the absorption of oxygen from the air by coal or pyrites. The quantity of heat produced by the reaction has been measured and it has been shown that the observed rate of heating of a sample of coal agrees with the rate calculated from the heat of reaction and the rate of absorption of oxygen

Dec 1, 1916

By J. H. E. Jeffes, K. T. Jacob

Solid oxide galvanic cells, of the type: Pt,Ni-NiO | Solid electrolyte | O(metal),Cermet,Pt, were used to measure the activity coefficient of oxygen in liquid Cu at 1 100 and 1 300°C and in Pb at 1 100°C. Similar cells were used to study the activity coefficient of oxygen in the whole range of Cu + Pb alloys at 1 100°C and in Pb-rich alloys at 900 and 750°C. The results obtained are discussed in terms of proposed solution models. An equation based on the formation of 'species' of the form M(2)O in solutions of oxygen in binary alloys is shown to fit the experimental data

Dec 1, 1971