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By C. E. Rodgers

WHEN I was asked to prepare, for presentation at the 1938 Annual Meeting of the Institute, some data concerning low-discharge grinding at the Sylvanite mill, it seemed entirely reasonable to expect to have at my disposal the results of at least four full months' operation after the last unit, as then proposed, was installed. Delays in delivery of equipment, nevertheless, shortened the interval, as will be shown herein. In submitting the data contained in this discussion, I wish distinctly to state that the intention is not to claim that final conclusions can be reached at this time concerning our operation. Test periods, in certain instances at least, have been too short for this purpose, although some, where so stated, have been extended through March and April. It is hoped, however, that an advantageous trend in practice can be shown and that the experience related may be of interest to others who are now operating, or who are considering the operation of, low-discharge grinding mills. In the plant under review, four mills are in use: one primary and three secondary. Present mill capacity (grinding, as shown by screen test, about 99 per cent through-200-mesh and approximately 88 to 89 per cent minus-325-mesh with infrasizer giving about 90 per cent of the latter) averages about 525 tons per day. A brief description of each unit will be given and comments will also be made relating to operation. This will be followed by certain test data from which, in conclusion, operating results are summarized.

Jan 1, 1938

By L. Bichler

Utilizing thermal analysis techniques, pioneering research into the solidification mechanism of a popular magnesium alloy AZ91E cast by the Lost Foam Casting (LFC) process was carried out, Foam characteristics, section thickness and application of vacuum were seen to have profound effect on the cooling rate, thermal gradients and casting temperature profiles.

Jan 1, 2005

By Michel Rodrigue, Sylvain Duchesne, Louis Racine

"LocationThe Louvicourt mine is located 20 km east of Val d'Or in Abitibi, in the northwest part of the province of Quebec. The mine is located on Highway 117 connecting Val d'Or to Montreal and very close to the main railway networkHistoryFive successive exploration attempts by Aur Resources resulted in the discovery of the large Louvicourt orebody in June 1989. Construction of the surface and underground infrastructures commenced in the spring of 1991. Milling operations commenced in July 1994. The entire project cost CDN$290 million, almost CDN$20 million less than initially estimated. The concentrator infrastructure cost CDN$64 million.Louvicourt mine is owned in partnership by Novicourt Inc. (45%), Teck Corporation (25%), and Aur Resources Inc., the administrator (30%).Brief DescriptionLouvicourt mine is the largest producer of base metals (Cu and Zn) in Abitibi-Temiscamingue. Its average daily production is nearly 4300 t of ore, for an annual production of 200 000 t of copper concentrate (28% Cu) and 33 000 t of zinc concentrate (57% Zn). After only a few weeks of operation, it had attained its objectives for the most part, and operations continue to be improved."

Jan 1, 2000

By K. Ghyselbrecht, R. Swennen, Y. W. Chiang, V. Cappuyns, R. M. Santos, T. Van Gerven, B. Meesschaert

Heavy metal contamination from mining and metallurgical activities of aquatic systems poses significant risk to the environment and human populations. The investigation of the distribution and immobilization mechanisms of heavy metals in sediments and soils has recently attained high priority. Different remediation methods can be employed to suppress or eliminate these contaminants. A tailored approach using both commercially available and in-house made adsorbents to rem ediate a heavy metal contamination site due to historical metallurgical activities in north Belgium is studied in this paper.

Jan 1, 2011

By M. H. Colebrook

Nickel laterites contain about 70% of all continental or terrestrial nickel resources; therefore the recovery of nickel from lateritic ores has large economic significance. The processing of lateritic ores involves the preparation and movement of concentrated aqueous suspensions. However due to complex characteristics and non-Newtonian properties, ranging from shear-thinning to shear-thickening and from thixotropic to rheopectic, a basic understanding of the flow behaviour must be developed. This understanding will assist in the development of new plants and the operation of existing plants. The work in this paper involves the characterization of three ore types from the Vermelho ore deposit to categorize them as rheologically simple to complex. Rheological testing was also conducted on pure mineral samples that represent the main minerals in these samples. The results show that the rheological properties of the ore types can be related to the surface properties and physical characteristics of the main mineral constituents.

Jan 1, 2006

By T. Iwasaki

This paper points out two key elements in resource trade in general and the Canada-Japan relationship in particular. The first is that the advanced countries have a more important role than one would expect in the supply of resources in world trade. Canada 's dual role as a major resource supplier in conjunction with an advanced economy will continue to increase. The second point is the heavy reliance on foreign resource supplies in some advanced economies, particularly in Japan. Finally, as regard the future of the Canada-Japan economic relationship, particularly .in resource development, it is suggested that trade could be enhanced by an accelerated exchange of various types of resources between the two countries. These include natural resource commodities as well as the more abstract capital, technological and human resources.

Jan 1, 1978

By G. Graves, J. A. Walker

"Abstract - The Mount Fronsac North volcanogenic massive sulfide deposit is the most recently discovered massive sulfide body in the Bathurst Mining Camp. The deposit occurs within a sequence of intercalated fine-grained felsic tuff and sedimentary rocks (Little Falls member), at the top of the Nepisiguit Falls Formation. Aphyric to sparsely feldspar-phyric rhyolite and related volcanic rocks of the Flat Landing Brook Formation overlie the host sequence. The massive and semimassive parts of the deposit have a north-south strike length of 525 m and a dip of ~45°E; the deposit is continuous downdip for 600 m, and thickness varies from 2 to 20 m. The deposit contains an estimated geologic resource of 14 Mt of low-grade, semimassive (>60%) to locally massive sulfides, and includes a high-grade zone of 1.26 Mt grading 7.65% Zn, 2.18% Pb, 0.14% Cu, 40.3 g/t Ag, and 0.40 g/t Au. The semimassive to massive sulfide intersections occur in an envelope of quartz-sericite±chlorite schist, which is interpreted to be intensely deformed felsic tuff. This sequence has a maximum thickness of 140 m and contains significant (up to 50%) fine- to coarse-grained disseminated pyrite. The pyritic envelope has a strike length of 900 m and extends over 1000 m downdip. Massive sulfides are found throughout this alteration envelope, but more commonly occur at or near the upper contact. The significance of the discovery of this deposit is that it represents a near surface discovery of a large tonnage sulfide body in a mature mining camp, one in which the possibility of discovery of a new shallow deposit had been all but discounted. This opens the possibility for future discoveries in this part of the Bathurst Mining Camp. Sommaire - Le gîte de sulfures massifs volcanogènes du Mont Fronsac Nord est la découverte de sulfures massifs la plus récente dans le Camp Minier de Bathurst. Le gisement est situé dans une séquence de tufs felsiques à grains fins interlités de roches sédimentaires (membre de Little Falls, au sommet de la Formation de Nepisiguit Falls. La partie massive et la semimassive s’étendent du nord au sud sur 525 m et ont un pendage de ~45°E; le gisement est continu sur 600 m en angle de chute et son épaisseur varie de 2 à 20 m. Le gisement contient une ressource géologique évaluée à 14 Mt de sulfures semimassifs (>60%) localement massifs à basse teneur, incluant une zone à haute teneur de 1.26 Mt titrant 7.65% Zn, 2.18% Pb, 0.14% Cu, 40.3 g/t Ag, et 0.40 g/t Au. Les intersections de sulfures semimassifs à massifs se situent dans une enveloppe de schiste à quartz-sericite ± chlorite interprétée comme un tuf felsique intensément déformé. Cette séquence contient une quantité importante (jusqu’à 50%) de pyrite disséminée dont le grain varie de fin à grossier et son épaisseur maximale est de 140 m. L’enveloppe pyriteuse s’étend latéralement sur 900 m et a été tracée jusqu’à 1000 m en angle de chute. Des sulfures massifs sont trouvés partout à l’intérieur de cette enveloppe d’altération, mais ils sont plus fréquents près du contact supérieur. L’importance de cette découverte tient à ce qu’elle est un exemple d’un gisement à fort tonnage nouvellement découvert à une faible profondeur dans un camp minier mature, i.e., un camp ou l’on ne croyait plus qu’il était possible de trouver un gisement près de la surface. Ceci ouvre la porte à la possibilité d’autres découvertes dans cette partie du Camp Minier de Bathurst."

Jan 1, 2006

By D. Komljenovic, E. Lafontaine, J. Paraszczak

Availability of the production equipment used in underground mines has a substantial impact on production costs and, thus, on mine profitability. Appropriate collection of pertinent data and information, as well as use of adequate performance measures and their analyses, can help mine operators identify cost-effective opportunities to improve equipment availability. This paper presents study results aimed at reviewing and analyzing means and measures used to quantify equipment availability and its contributing factors (reliability, maintainability and maintenance support) in several Canadian underground mines. It overviews sources, as well as quality and quantity of relevant data and information, and examines performance measures and their definitions, as applied to surveyed mines. Problems concerning data acquisition and meaningfulness of the performance measures are discussed. The paper concludes with some suggestions and recommendations concerning several aspects of equipment availability assessment. Evidence suggests that the latter may become a more useful tool for mine operators in their efforts to reduce production cost.

Jan 1, 2008

By W R. Honeywell

Two series of laboratory flotation tests were carried out to study the treatment of Faraday ore by two-stage flotation. First the acid-consumers and then the uranium minerals were floated. On ore ground in the Faraday mill grinding circuit, and using Faraday mill water in the flotation step, a recovery in the flotation concentrate of from 91 to 93 percent of the uranium was obtained in 45 to 50 per cent of the weight at a grade of 0.24 per cent U30s. The saving of acid in leaching the uranium-bearing flotation concentrate, as compared to leaching the whole ore, ranged from 30 to 46 per cent. The average over-all extraction resulting from flotation and leaching of the flotation concentrate was 88.1 per cent. The best collector for the acid-consumers was sodium oleate. Acintol F A-1 emulsion was the best collector for the uranium minerals, and, in the uranium flotation step, an acid pH in the slurry was found to be necessary. The reagent costs were estimated to be 22 to 26 cents per ton of ore.

Jan 1, 1963

By D. V. Dorling, J. T. Bowker, J. A. Gianetto

Over the last few years, interest in the development and construction of large diameter, high pressure pipelines from the Mackenzie Delta in northern Canada and Alaska's North Slope has steadily increased as a result of the projected decline in recoverable natural gas from existing reserves in western Canada. The success of such enormous pipeline projects, which will require utilization of a strain-based design approach, is largely based on successful application of high strength line pipe steels, such as X80 and X100. To fully realize the economic benefits of high strength steels, welding processes and procedures must be developed to ensure that the requirements for high strength and good low temperature toughness are confidently obtainable in field girth welds used in the construction of such pipelines. This study aims to provide a better understanding of the factors that control weld metal strength and toughness for a series of mechanized X100 girth welds produced using a range of narrow-gap gas-metal arc welding procedures. The attainment of high yield strength (> 810 MPa) is considered to be an important target to ensure overmatching strength relative to the longitudinal property distribution of X100 line pipe steel. Some factors that have been considered in this evaluation include influences of gas-metal arc welding process variants (single and multi-wire) and changes in welding procedure specifications, including joint preparation. Key components of this work relate to the reliable measurement of weld metal strength variation through-thickness and as a function of position around the circumference of a given girth weld.

Jan 1, 2005

By D. W. Zandee

"IntroductionHaving mined an economic mineral bearing rock which is of insufficient grade to warrant direct smelting, upgrading or beneficiation is required to make it an economically viable ore. The first step in effecting the concentration process is comminution or sequential breaking of the rock to allow liberation and subsequent recovery of the desired mineral particles. Desirably the ore could be broken down to the point where the valuable mineral is completely liberated to maximize the chance of recovering as much of it and in as pure a form as possible. The number of energy intensive stages of breakage required to attain this goal depends on many physical characteristics of the ore such as hardness, friability, toughness, grain size, existing fracture planes and particle shapes.Commonly the distinct stages are primary, secondary and often tertiary crushing and finally grinding. To increase the efficiency of each stage of size reduction, pre-treatment sizing is common.Crusher feed is commonly scalped of large pieces or screened for reduction crushers and classified for secondary grindingcircuits.Although crushing and screening is employed for many different products, this chapter reviews current practice in larger tonnage metalliferous ore treatment plants.Current practice is to use large gyratory or jaw crushers for primary crushing and some sort of gyrating or cone crushers for additional stages of reduction. For autogenous or semiautogenous grinding circuits only the primary crushing stage is necessary, the balance of the work being performed in the grinding stage. For conventional grinding circuits using ball mills or combinations of rod and ball mills, secondary, tertiary and even quaternary crushing stages are normally required.Older type crushers such as stamp mills, double rolls, sledging mills and hammermills are no longer common but are used for small tonnage special processes.Important to efficient crushing are a variety of sizing devices such as grizzlies and vibrating screens. Products at different stages must be stored to give surge capacity and allow controlled feeding rates through mechanical and gravity feeders. These storage piles, bins and feeders as well as crushers and screens are commonly integrated into a total facility by means of conveyor systems. Most often these are endless rubber belts driven by simple or multiple drive mechanisms usually consisting of electric motors and speed reducers."

Jan 1, 1989

By S. R. McCutcheon, D. R. Lentz, W. S. Downey

"Abstract - The Little Falls member of the Nepisiguit Falls Formation is situated in the northern part of the Brunswick Belt of the Bathurst Mining Camp and has been interpreted as the distal equivalent of proximal tuffaceous rocks that host the stratiform Brunswick No. 12 and No. 6 Pb-Zn massive sulfide deposits. It comprises fine-grained, greenish-gray tuffaceous sandstone in the lower part, and coarse-grained, crystal-rich tuffaceous sandstone in the upper part. Petrographic evidence suggests that these rocks have a turbiditic origin. The Little Falls member is underlain by the Vallée Lourdes member, mainly composed of relatively shallow-water calcareous rocks, and is conformably overlain by Mn-rich sedimentary rocks, mainly red argillites that host the Tetagouche Falls Mn-(Fe) deposit. All these rocks are considered to belong to the Nepisiguit Falls Formation, part of the Ordovician Tetagouche Group. Whole-rock geochemical data from the fine-grained tuffaceous sandstone and coarse-grained tuffaceous sandstone indicate that the two units of the Little Falls member are distinct. Zr and TiO2 contents, and total rare earth element (REE) values are higher in the coarse-grained unit (average Zr/TiO2 = 0.040, average SREE = 247 ppm, n = 6) than in the fine-grained unit (average Zr/TiO2 = 0.048, average SREE = 158 ppm, n = 17), which can be attributed to the variation in crystal content between the two units. Both units are HREE-enriched and have elevated La/Yb relative to the typical Nepisiguit Falls Formation. Overall, the geochemical data combined with evidence from the bounding units suggest that the Little Falls member was deposited in relatively shallow water, possibly in a near-arc environment. The relationship of volcanic facies within the Nepisiguit Falls Formation and the geochemistry of these facies indicate strongly that fine grained, reworked tuffaceous rocks, regardless of whether they are the distal equivalents of proximal tuffaceous rocks, are not associated with the major ore-bearing horizons of the Bathurst Mining Camp. Sommaire - Le Membre de Little Falls de la Formation de Nepisiguit Falls se retrouve dans la partie nord de la Ceinture Brunswick du Camp Minier de Bathurst ou elle a été interprétée comme l’équivalent distal des roches tuffacées proximales hôtes des gisements de sulfures massifs de Pb-Zn stratiformes Brunswick No.12 et No.6. Il consiste en grès tuffacé à grains fins gris verdâtre dans sa partie inférieure et en grès tuffacé à grains grossiers riche en cristaux dans sa partie supérieure. Les données pétrographiques suggèrent que ces roches ont été déposées par des courants de turbidité. Le Membre de Little Falls repose sur le Membre de Vallée Lourdes, lequel consiste principalement en roches calcareuses déposées en eau relativement peu profonde; il est de plus recouvert en concordance par des roches sédimentaires manganifères, lesquelles consistent principalement en argilites rouges hôtes du gisement de Mn-(Fe) de Tetagouche Falls. Toutes ces roches appartiennent à la Formation de Nepisiguit Falls, laquelle fait partie du Groupe de Tetagouche, d’âge Ordovicien. Les données lithogéochimiques des grès tuffacés à grains fins et à grains grossiers indiquent que ces deux unités du Membre de Little Falls sont distinctes. Les teneurs en Zr et en TiO2, ainsi que la teneur totale en Éléments des Terres Rares (ÉTR) sont plus élevées dans l’unité à grains grossiers (Zr/TiO2 moyen = 0.040, SREE moyen = 247 ppm, n = 6) que dans l’unité à grains fins (Zr/TiO2 moyen = 0.048, SREE moyen = 158 ppm, n = 17), ce qui pourrait s’expliquer par la variation de la quantité de cristaux dans chacune de ces deux unités. Chacune de ces deux unités présente un enrichissement en ÉTRL ainsi qu’un rapport La/Yb relativement plus grand que ce qui est typiquement observé dans la Formation de Nepisiguit Falls. Les données géochimiques considérées conjointement à l’information provenant des unités adjacentes suggèrent que le Me"

Jan 1, 2006

The Challenges in Mining _Large expensive assets that are not being utilised as well as they should _?Silo? operations plan, schedule and execute in isolation?poor visibility across the Value Chain _Disruptions or unforeseen events have serious upstream and downstream impacts _Exacerbated by multiple information systems, mostly spreadsheets _Strategic simulation (supply and demand) is often poorly Handled

Nov 1, 2011

By R. S. Fitzpatrick, P. Hegarty

"Gravity separation is a key technology in the recovery of a range of mineral ores including coal, tin, tungsten and tantalum. One of the problems associated with gravity concentration is that recovery is traditionally lower than for other separation techniques such as the flotation of base metals. Any improvements in recovery will, therefore, have a significant effect on the economics of operations of this type. More accurate, robust modelling of gravity separators is one means of achieving greater recoveries. Furthermore, better modelling can lead to more informed equipment selection and process design for potential economic deposits.Previous models for gravity separation equipment have typically relied on simple metal mass balances from samples of the separated products. However, with advances in technology there is a ready availability of analytical instruments for the automated quantitative determination of mineralogy. Instruments such as the Mineral Liberation Analyser and QEMSCAN make it possible to estimate particle size and density (related to mineral liberation and association) which are the primary factors in gravity separation. Models produced using quantitative mineralogy of feed streams will be potentially superior to those produced historically.This paper describes test work undertaken on a wet shaking table using a synthetic ore. The objective of this test work was to develop a model to predict the effect of changes in feed ore characteristics on shaking table performance by measuring quantitatively the mineralogy of the feed material. Particles were divided into size/density classes based on the results of QEMSCAN analyses.It was found that it was possible to use data from QEMSCAN to predict the recovery of size/density classes and to predict the effect of changes in the relative abundances of these classes on the separation. This model can potentially be used to adjust operating variables to maximise grade and recovery by monitoring the input feed. Care was needed when utilising QEMSCAN data to ensure representivity."

Jan 1, 2016

By J. M. Hong, H. K. Zheng, R. Hu, C. B. Zhou

The Jinping-I double curvature arch dam, located in the middle reach of the Yalong River and with a maximum height of 305 m, is the world highest dam of the same type that has been completed. Since the second and third periods of the reservoir impounding, after which the reservoir water level was raised by about 200 m, a significant amount of leakage was observed out of the drainage holes deployed in the lowest drainage tunnel at the left-bank abutment at EL. 1595 m, with a pressure of 0.3 MPa at one typical hole when it was blocked. In this study, a number of analyses including water quality analysis, digital borehole imaging, tunnel geological mapping and in-situ groundwater monitoring were performed to investigate the source of leaking, the leakage passages and the performance of the grouting curtains. An inverse modeling procedure combining the orthogonal design, finite element forward modeling of the transient seepage flow, artificial neural network and genetic algorithm was invoked to further evaluate the permeability of the foundation rocks whose permeability was underestimated in design, using the in-situ measurements of flow rate and piezometric head. The geological structures that lead to the leakage were identified and the seepage flow behaviors in the dam foundation and the left bank abutment were assessed. Given the connectivity nature of the sub-vertically oriented fractures that induce the leakage event, it is found that some of the drainage holes with relative larger amount of discharge could be closed or blocked for reducing the amount of leakage without remarkably increasing the pore water pressure in the foundation rocks.

Jan 1, 2015

By Anton Gronningsater

AS we know, Sir Henry Bessemer introduced Bessemer converting in the steel industry about 1855. It was not until twenty years later that the principles were adopted by non-ferrous metallurgists. In 1880, Manés first produced blister copper from matte in a converter, a very important forward step in copper metallurgy. For thirty years, up to about 1910, bessemerizing of copper matte was carried out in the acid-lined converter. It is not necessary here to enumerate all the shortcomings of that operation, one of which was that it strictly limited the grade of matte that could be treated; a 35 per cent matte was low in those days. From the early days of copper converting, many and repeated attempts were made to use a basic converter lining, and the older metallurgists will remember the numerous reports and discussions in connection with such experiments. These make interesting reading. I quote from a book published in 1900: ?'The siliceous lining is as much a part of the process of copper converting as magnesia lining is in the basic bessemer treatment of phosphoric iron, and it is suicidal to attempt any other kind of lining, either water-jacketed or basic.' "Even if the silica could be introduced in this way (through the tuyeres), it would still produce another trouble in the converter. The small particles of silica, being cold, would combine very imperfectly with the iron oxide and produce granulated and pasty slags, which could not be skimmed or poured out of the vessel".

Jan 1, 1942

By K. H. J. Clarke

SINCE the beginning of this century the non-ferrous mineral industry has contributed $17,809,-000,000 to the economic growth of Canada. To contemplate the vast amount of investment capital required and the resultant beneficial distribution of these billions of dollars for labour, transportation, supplies, taxes and dividends, challenges the imagination. It is the purpose of this paper, (a) to trace the development of the industry since its formative period to the present; (b) to discuss the current situation and problems; and ( c) to attempt to peer into the hazy future. Although there are 21 metals currently being produced in Canada which are classified as non-ferrous, or as alloying metals, copper, lead, zinc, nickel-the metals which will be discussed in this paper-constitute almost 60 per cent of their total value. ;The story

Jan 1, 1961

By D. H. Pulling

Statistics for copper consumption from various sources show that the importance of production from secondary sources is increasing. This is of particular significance in countries such as the U.K ., which are totally dependent on secondary material for the supply of home-produced copper . A brief survey of the U.K . industry has shown that, in the past, relatively high profit margins have not encouraged high cap ital investment and development of more sophisticated operating techniques, but set against a background of rapidly escalating operating and energy costs , together with an ever-increasing demand for copper , it is anticipated that the industry will see great changes in the near future. With this in mind, an experimental furnace for continuous smelting of copper-bearing scrap has been developed at the University of Birmingham. This furnace has been designed to combine the conventional operations of blast furnace or reverberatory smelting, usually followed by converting, in one unit, and incorporates many of the features of the WORGRA and Noranda processes for continuous primary smelting . It consists of a long, sloping channel, constructed of chrome-magnesite refractory, which: is churned near the top. Smelting is effected lower down the channel, where iron, etc., in the scrap is oxidized and slagged off with silica flux. Provision is made for oil injection to increase oxidation rates. Metal can flow from the bottom of the channel, and slag from the top, so that a counter-current flow is achieved. The approximate molten capacity is 25 kg. Various scrap charges, both synthetically made and as supplied from various industrial smelters, have been successfully smelted. Metal of 83 -95 % Cu has been produced, depending on the original charge composition and the degree of air injection, although air injection was also found to considerably increase the copper loss to slag. Recoveries of other valuable non-ferrous metals in the charge were good.

Jan 1, 1977

By H. O. Lien

Among the known iron deposits in Canada, many are of low grade and require beneficiation to produce an acceptable blast-furnace feed. Some of the deposits have never been considered for commercial exploitation due to the lack of a suitable concentrating process. A number of deposits of this type are located in Northern Ontario. The problem in upgrading these deposits is three fold. Firstly, the iron occurs as a mixture of magnetite and hematite. Secondly, the grain size of the material can be fine to very fine. Thirdly, the complex mixture of gangue minerals, which consists invariably of silica, flaky silicates and carbonates, slimes excessively on fine grinding. Algoma's efforts to concentrate these iron-bearing materials culminated in the development of a "Selective Flocculation and Desliming Process" employing slimes removal as the sole beneficiation technique. The process was applied successfully in the laboratory using two stages of grinding and a total of seven deslimings. Prior to the removal of slimes, the iron-bearing fines were selectively flocculated from a thoroughly dispersed pulp using a modified starch as flocculant, Sodium silicate was employed as dispersant. An attempt was made to optimize some of the process variables using material from one specific iron formation near the town of Geraldton in Northern Ontario. The preparation of the starch proved most critical. This matter, and the method used to evaluate the degree of breakdown of the starch molecule, are therefore discussed in some detail.

Jan 1, 1978

By J. E. Dutrizac, J. M. Zinck

Ferrihydrite is often the initial precipitate resulting from the rapid neutralization of Fe(III) sulphate solutions, and it seems to be a major constituent of zinc plant neutral leach residues. The most important parameters affecting ferrihydrite precipitaton are temperature, solution pH and the neutralization rate. Low temperatures and rapid neutralization rates yield poorly filterable ferrihydrite, whereas higher temperatures and slower neutralization rates produce readily filterable precipitates; in all instances, however, the precipitates are two-line ferrihydrite. Significant amounts of Zn are incorporated in the ferrihydrite precipitates, and the Zn contents increase with increasing Zn concentration, pH or temperature. Generally, the sulphate contents of the precipitates decrease as the Zn contents increase, and this may indicate that the Zn is adsorbed on the ferrihydrite. Discrete Zn phases were not detected. Neither Cd nor Tl is precipitated with ferrihydrite, although thallium jarosite co-precipitates with ferrihydrite at high Tl concentrations and elevated temperatures. Virtually all of the Sn added to the solution precipitates with the ferrihydrite, but the tin is believed to be present as intimately admixed amorphous SnO2.nH2O. Although selenite extensively precipitates with the ferrihydrite, selenate remains mostly in solution, likely because of the close similarity of the SeO4 2- ion to the SO4 2- ion which is present in high concentrations and saturates the available sites for anion adsorption.

Jan 1, 1998