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By Rodney Trevor Jones, Arthur Robert Barnes

Anglovaal Minerals acquired the Nkana slag dump from Zambia Consolidated Copper mines (ZCCM) in 1998 and embarked on an ambitious project to pioneer the recovery of cobalt from slag using DC smelting technology. Anglovaal Research Laboratories performed initial pioneering smelting tests in a 250 kW DC furnace over a 3-year period before engaging Mintek for three piloting campaigns at the 1.5 MW level. Mintek had previously developed a reductive smelting process, patented in 1995, using a DC arc furnace for the recovery of cobalt from slags. The results of the pilot-plant test campaigns were used as the basis for engineering the commercial 40 MW operation installed at Chambishi Metals plc in Zambia in 2001. This paper traces the development of understanding of the metallurgical fundamentals ultimately used to predict furnace performance, reviews some of the extreme technical challenges faced, how solutions were identified and highlights some of the critical issues identified during piloting and how these impacted both positively and negatively on the final commercial operation.

Jan 1, 2011

By P. R. A. Andrews

"Areas of bubble contact were delineated for cassiterite in the presence of chloride, fluoride, sulphate, phosphate, oxalate and citrate ions using dodecylamine hydrochloride collector. The limits of pH, and the minimum collector concentration were established using the bubble pick-up technique.Bubble contact did not occur below the p.z.c. (point of zero charge), estimated to be 4.7, in the presence of chloride ion, and fluoride ion showed only a weak response in the same pH range. These anions are considered to act as indifferent electrolytes. Activation at pH values below the p.z.c. was obtained with sulphate, phosphate, oxalate and citrate ions; the greatest response was by oxalate and phosphate ions extending pick-up to between pH 2.0 and 2.5.Activation appeared to be strongest when anionic protonated species were in maximum concentration. Strong activation also corresponded to the formation of very stable metal ion species, thought to be formed on the surface of cassiterite, between exposed stannic ions and modifying anions; dodecylammonium ions being absorbed on the surface so modified."

Jan 1, 1991

By N. Afrin

The microstructure and tensile properties of AZ31B-H24 magnesium (Mg) alloy after friction stir welding (FSW) were evaluated. The grain size was observed to increase from approximately 5 µm to about 9 µm after FSW. The obtained Hall-Petch type relationship showed a strong grain size dependence of the hardness values. While the FSW led to about half of the yield strength of the base magnesium alloy, the ultimate tensile strength after FSW could reach about two thirds of that of the base alloy. The hardening capacity of the FSWed samples was about twice of that of the base alloy. The strain hardening exponent of the base alloy was found to be about 0.1 whereas it became larger than 0.3 for the FSWed samples. After yielding the base alloy showed a high initial and almost constant work hardening rate, corresponding to linear hardening stage II, followed by stage III with a decreasing hardening rate. Stage II linear hardening was observed to be absent in the FSWed samples.

Jan 1, 2007

By H. J. White

Haynes International, a world leader in the manufacture and production of nickel, and cobalt base alloys has invented and developed a low cost high temperature material, with a unique combination of superior oxidation resistance and weldability/ fabricability. HAYNES® HR-224TM (Ni ? 27.5Fe ? 20Cr ?3.8A1 ? 0.3Si ? 0.3Ti) forms a planar/ continuous/ adherent aluminum oxide film at high temperatures which has been shown to effectively limit chromium poisoning in solid oxide fuel, cell, systems. A 20,000 pound vacuum induction melted (VIM) + electroslag remelted (ESR) heat has been melted and converted into various product forms: sheet, plate, bar, welded tubing, wire, etc. The alloy was designed for service in severely oxidizing environments recuperators, automotive catalytic converters, wire strand annealing furnace tubes, etc. and has been of great interest to solid oxide fuel, cell, manufacturers as a materials of construction in balance of plant (BOP) design. This manuscript presents the physical, properties, mechanica, properties, and oxidation resistance of the alloy compared to other materials being considered for solid oxide fuel, cell, design

Jan 1, 2010

By Ahmad Ghahremaninezhad, Rebecca Radzinski

Arsenic is a highly toxic compound that is naturally found in the environment and is released through the processing of sulphide minerals. Arsenate (As5+) is less toxic than arsenite (As3+) and is soluble in water but can form insoluble precipitates when metal ions are present. The arsenic removal processes used in industry assume that arsenic is in its pentavalent state. Hydrogen peroxide can be employed to oxidize arsenite; however, it is expensive. It has been shown that activated carbon can be used to catalyze the oxidation of arsenite with oxygen as the only consumed reagent at ambient conditions with an efficiency of 99% in less than 24 hours. The mechanism which oxidizes arsenite is not yet understood; however, this study shows that a strong oxidizing agent is formed in-situ. The species and amount of oxidant formed were determined via iodimetric titration and electrochemical methods. The production of oxidant was optimized by comparing the amount of oxidant formed in-situ to the relative amount of arsenite oxidized.

Jan 1, 2015

By H. Somekawa

The fracture toughness and deformation structures an AZ31 magnesium alloy processed by equal-channel-angular extrusion (ECAE) were investigated. The average grain sizes of as-ECAE and annealed-ECAE alloys were 4.0 and 16.3 µm, respectively. The plane-strain fracture toughness, Kip, in as-ECAE and annealed-ECAE were estimated to be 27.3 and 23.5 MPam1/2, respectively, by stretched zone analysis. The fracture toughness indicated higher value with grain refinement. From optical microstructural observations in samples after fracture toughness tests, although deformation twins were observed in annealed-ECAE, no deformation twins were observed in as-ECAE. From TEM observations, the dislocations on basal and non-basal planes were activated in as-ECAE. With grain refinement, the activations of dislocations on both basal and non-basal planes were possibly related to the reduction in formation of deformation twins in as-ECAE. In addition, in comparison with direct extruded process, ECAE process was more effective method to improve the fracture toughness in magnesium alloys.

Jan 1, 2006

By A. C. Hawken, L. M. Strah

"The Report outlines the Conversion to Rubber Mill Liners and steel grinding balls from the old style Cobalt pocket liners and flint pebbles which had been used in 5'x22' Fraser-Chalmers tube mills for over fifty years. An outline of the past history and some of the plant modifications are mentioned as well.The details pertaining to considerations, modifications and repairs carried out on the mills are described. Factors influencing the rubber liner design are outlined along with the description of the rubber liner design.The performance and advantages to date are given and concludes with brief summary.HISTORYThe original amalgamation-cyanidation mill of Dome Mines Limited went into operation in 1912. Milling has been continuous since 1912, except for two periods; one of 17 months commencing in December 1917, and the other of about 12 months, when fire destroyed the plant in November 1929. Initially the capacity of the mill was 350 tons a day. In 1916 it was raised to 750 tons a day, following which there was a gradual expansion to 1,500 tons a day."

Jan 1, 1977

By J M. Anderson

The cable belt conveyor installation at Craigmont Mines Limited, Merritt, B.C., has the greatest one-stage vertical fall of any conveyor installed overland in Canada. Since the late summer of 1961, this conveyor has carried more than 5,000,000 tons of copper ore from open pit to concentrator site. When the conveyor is loaded, the drive motor acts as an induction generator, delivering power to an external circuit. This paper covers the selection, the operation, the performance statistics, and the installation and operating costs of this conveyor system. Introduction T HE Craigmont mine is located in the south-western interior region of the Province of British Columbia, approximately 240 miles northeast of Vancouver. A moderate climate, good roads, service by the Canadian Pacific Railroad, power from the British Columbia Hydro Authority, gas from the nearby main line of the Inland Natural Gas Company and close proximity to the village of Merritt provide a favourable location for this mining operation. The ore occurrences at Craigmont have a vertical extent of 1,500 feet,

Jan 1, 1965

By R. Bonnar, R. J. McH. Clark

"The Cheminis gold mineralization zone is approximately 6.5 km west of the Kerr Addison Mine along the Larder Lake Shear Zone, in the southern part of the Abitibi Greenstone Belt. The zone is very similar in appearance to the flow ore at the Kerr Addison Mine and occurs at the same stratigraphic position. Drilling has demonstrated that the gold mineralization at Cheminis persists to a depth of over 3000 ft .The mineralization is hosted by a pyritic, tuffaceous sediment which occurs within a sequence of volcanics and sediments which have been pervasively carbonatized. The gold is largely enclosed within pyrite grains and the amount of gold in the layers of pyrite increases in the layers closest to a graphitic f ault zone.It is suggested that the gold mineralization may be primarily related to the syngenetic sulphide concentrations formed during fumarolic activity on the seafloor along the Larder Lake Shear Zone. At a later stage a hydrothermal event associated with alkalic volcanism may have resulted in regional carbonatization and further concentration of the gold in the vicinity of fault zones."

Jan 1, 1987

By Marvin E. Lane

Viburnum, located in the foothills of the Ozarks in south-east Missouri, is the site of a modern lead mining and milling operation. Two mines are currently producing a total of 5,000 tons per day and a third mine is in the final development stage, with full production scheduled for late this year (1964). These mines will supply the tonnage required to keep the Viburnum mill operating at a full capacity of 7,000 tons per day for many years. The efficient underground mining operation is completely trackless. Drill jumbos are used to break the ore in a room and pillar method of mining. Transloaders, or St. Joe shovels, and trucks do the loading and hauling. The Viburnum mill has a world-wide reputation as a most efficient operation. This is due to the extensive use of automatic process controls, and labour saving materials handling facilities. Introduction THE St. Joseph Lead Co., has operated lead mines in southeast Missouri for 100 years. These operations have been confined largely to the area called the

Jan 1, 1964

By Paul Girard

"The copper property of Madeleine Mines Ltd. is in Lapotardiere and Boisbuisson townships, Gaspe North. The initial find was made in 1964, and subsequently a copper deposit of 5.3 million tons of ore was outlined. The property lies in Ordovician sedimentary and volcanic rocks near the major granite intrusive of the McGerrigle Range. The host-rock is a 300-foot-thick metamorphosed silty shale unit, close to the contact of the intrusive. The structure itself coµsists of a southerly-dipping monocline or the south limb of an anticline, on which a large dragfold has been imposed.Chalcopyrite, bornite and chalcocite are the principal sulphides present in the ore. Of particular interest is the zoning arrangement of these sulphides. The orebody is chimney-like in shape and appears to be a fracture-filling deposit that is genetically related to the granite intrusive and is confined within a highly fractured zone of very brittle rock. The deposit presents features uncommon to any of the other known copper deposits in the Gaspe Peninsula."

Jan 1, 1969

In April, 1961, a large pillar was removed by blasthole mining methods at Inco's Murray mine. More than half a million pounds of explosives were used to break 2,120,000 tons of ore in a single underground blast. The 5, 10 2-inch boreholes, involving 435,815 feet of drilling, were loaded over a three-week period, using conventional explosives and short-period electric caps. From this blast, more than half a million tons of ore have been removed to date (April, 1962) through slusher trenches situated in the footwall of the ore body. T HE Ontario Division of The International Nickel Company of Canada, Limited, operates six underground mines and two open pits in the Sudbury district in the north-central part of the Province. This paper describes the removal of a large pillar at the Murray mine (Figure 1), where 2,120,000 tons of ore were broken in a single underground blast by the blasthole mining method. This is the largest underground blast achieved to date (April, 1962) at Inco mines.

Jan 1, 1963

By Greg Johnson

Maintenance needs information about assets to optimize availability and production needs information about performance and consumption to maximize output. In considering both these needs together as, ?Asset Optimization?, the information systems that support them are critical. The theory of Asset Optimization derives from the Lean Manufacturing concepts developed by Toyota, but some changes are required to apply this to mining operations. In particular, mining operations require automated systems due to their geographic spread and they need a strong emphasis on capturing under-performance losses as well as delays and stoppages in production. Leading metal miners and coal miners alike have applied these systems to good effect in the last 10 years. The concepts developed initially in minerals processing plants are now being applied to the mines themsleves as well as the mining logistics chain. Production increases of 5?10% are achievable with the right implementation and consideration of the some key lessons learnt in the last 10 years. Putting these lessons into action is one key step in the goal of optimizing asset performance and thus utilizing the resource at lowest cost.

Aug 1, 2013

By R. A. Campbell, R. R. Rogers

"AbstractThe experiments described show that crude bismuth metal containing up to 5 per •cent lead, 0.14 per cent silver, 0.015 per cent copper, 0.02 per cent iron, .and small amounts of antimony, nickel, and tin may be refined to a bismuth content of 99.98 per cent by distillation followed by chlorination. It also is shown that bismuth trichloride of high ,purity may be produced by passing chlorine over hot •crude bismuth metal and allowing the resulting vapours to •condense in a cooler .part of the system.IntroductionBISMUTH is used in the production of alloys and pharmaceuticals. During 1952, the New York price for the refined metal was $2.25 per pound in ton lots.Some months-ago a Canadian producer requested the Mines Branch to investigate methods of refining the bismuth which they had been producing. Their crude product had been selling for $1.50 to $1.70 per pound and it was desired to increase its purity to at least 99.98 per cent so that it could be sold for $2.25 per pound."

Jan 1, 1955

By Engineering Staff

In 1958, the Iron Ore Company of Canada decided to proceed with the Carol Project. The ore deposits in the area are part of the highly metamorphosed southern zone of the Labrador Trough. They lie along the shore of W a bush lake, in the western part of Newfoundland-Labrador, 190 miles north of Sept-Iles. The project is designed to mine, by open-pit methods, 17,200,000 long tons of crude ore, grading 37 per cent iron, per year. This ore will be beneficiated to produce 7,000,000 long tons of concentrate, grading 66 per cent iron, of which 5,500,000 long tons will be pelletized. Production is scheduled to commence this summer. Initially, ore will be taken from 45-foot benches in the Smallwood mine, using jet-piercing production drills and large-scale blasting with "slurry" explosives. Four 13-yard electric shovels will muck the broken ore into 100-ton trailer trucks. The trailers will be hauled to two 2,000-ton loading pockets, which feed the ore into 100-ton railcars. Four ore trains, each comprised

Jan 1, 1962

By A. S. Knight

THE breaking and handling of ore is obviously the most important consideration when the layout of a new mine is contemplated. The problem must be attacked with due regard to the claim area of the property, the dip of the orebody, the anticipated percentage of payability, the width of the reef, and the amount of dislocation anticipated by dykes, faults, or sills. Among these, as far as East Geduld is concerned, the three most important items are: Area. 2,640.5 claims. Average dip 12° (from flat to 35°) Average channel width 36 inches. We are fortunate on the Witwatersrand in 'chat there is usually sufficient information available from surrounding properties to determine, within narrow limits, the factors mentioned above. With this information avail-able, the choice of layout is not limited, and it will be found that on the Witwatersrand each group has developed its own technique to suit its individual requirements. On East Geduld, the layout of the property for handling ore is known as the endless-rope haulage system. Following is a brief description of the general principles followed.

Jan 1, 1942

By N Robb

This paper gives an account of the laboratory testing, plant testing and final inclusion of the two-stage sulphuric acid leaching process in the Milliken mill. Operational results for September, 1962, are presented, showing a uranium extraction of 95.5 per cent, with a saving of some 16 lbs. of 100 per cent H~S04 and some 9 lbs. of lime per ton milled. Methods for effecting further improvements in the process are indicated. HISTORY P RIOR to the incorporation of two-stage leaching, the process for the treatment of uranium ores at Milliken consisted of a single-stage sulphuric acid leach, followed by a solution recovery step involving washing in thickeners and two-stage filtration. The thickener overflow solution was subsequently concentrated and purified by ion exchange, and the uranium was recovered, by two-stage precipitation, as ammonium diuranate. Figure I illustrates this flowsheet. For satisfactory extraction of uranium from the. Milliken ore, a high residual acidity, of the order of 40 grams per litre of free acid in the discharge solution, must be

Jan 1, 1963

By O. Hall

STOPING at Noranda" is a sequel to "Mining at Noranda". "Mining at Noranda", presented in 1937 (1), sketches Noranda's history, metallurgical problems, exploration, mining methods, mining details, pillar extraction, and costs. "Stoping at Noranda" deals in greater detail with our stoping, the use of sub-level drifts instead of benches, and the drilling out of the stopes with jointed rock drill steel and diamond drills. Sun-LEVEL DRIFT STOPING: Sub-level drift stoping is almost universal throughout the mine and is the standard sroping method in both sulphide ore and rhyolite flux ore. The features that have led to the adoption of this standard are: (1) Continuous symmetrical drilling in sub-level drifts with no delay for blasting. (2) Large-tonnage blasts Saturday night after the drillers have left. (3) Comparative freedom from gas and smoke during the working days. ( 4) The daily safety achieved by having all stope drilling done in drifts. (5) The safety and security achieved by drilling out stopes, floors, and pillars before there is any weighting or cracking.

Jan 1, 1939

By G. Gagnon

"HistoryMining of the Schefferville iron deposits began in 1954 on completion of the 357 mile railway linking the mines and the St-Lawrence river port of Sept-Iles. Apart from crushing, no treatment of these ores was required before smelting. In the late 1950's, testwork began at schefferville to develop a process for upgrading the extensive lower grade deposits containing 51% iron with 15% silica (natural analysis). Engineering for a six million ton per year beneficiation plant using cationic silica flotation and the A-C grate kiln Began in 1970 and the first pellets were produced in mid-1973.Production requirements and operating difficulties have restricted capacity to approximately 85% of design but on going improvements are being made continuously to attain design capacity.GeologyThe sedimentary ore bodies of the labrador trough occur in a belt 5 to 10 miles wide and 60 miles long and contain 51 individual deposits varying in size from 1 and 60 million tons. The ores are classified into three main color groups."

Jan 1, 1981

By A. Uribe-Salas, J. A. Finch, B. J. Huls

Froth depth or interface level is an important control variable in column flotation which can influence both grade and recovery. A common method of locating the level is based on sensing the hydrostatic pressure at one or more points along the column. The level indicated can be in considerable error, largely because of variations in froth and collection zone bulk densities. A portable conductivity probe has been developed to detect the position of the interface from conductance measurements across the interface. The location of the interface corresponds to the position where a large change in conductance is observed, which is primarily a consequence of the difference in gas holdup between the collection and froth zone. This probe detects the position of the interface to an accuracy of ± 5 cm. The probe can be used while the column is in operation, which allows for on-line recalibration of the level detection system. Results obtained in its application in a pilot-scale column (0.91 m in diameter) are described.

Jan 1, 1990