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By N. J. Wagner, D. G. Modiba

There is currently limited knowledge concerning South African coal deposits as hosts for rare earth elements (REE). This project aims to determine the concentration of REE, including yttrium and scandium (REY+Sc) in various coal seams and adjacent sediments in borehole cores from the Ermelo, Witbank, and Waterberg coalfields in South Africa. Coal petrography (maceral count and vitrinite reflectance), XRD, XRF, sequential chemical extraction procedure (SCEP) before ICPMS, and mineral liberation analysis (MLA) were conducted on the coal and associated sediment samples. The coals were inertinite-rich, medium-rank bituminous coal, with moderate to high ash content. The two dominant minerals in all the coalfields are kaolinite and quartz, except for sample ZBS2M, where dolomite was dominant. The dominant major oxides are Al2O3, SiO2, Fe2O3, and CaO, which concur with the XRD results. The ICP-MS results following SCEP indicated that both coal and the associated sediments were light REY+Sc dominant. There was also an elevation of medium REY+Sc in the Witbank coal’s associated sediment samples. Notably, the samples with the highest REY+Sc results were the sediment samples. The Waterberg samples had the lowest REY+Sc from both the coal (less than 2 μg/g to 7 μg/g) and associated sediments (2 μg/g to 15 μg/g). While the highest REY+Sc was yielded from the Witbank-associated sediments (500 μg/g to 2,500 μg/g). The carbonate fraction step proved to be the most successful leaching step, as most REY+Sc was recovered in that step for all coalfields. In addition to the carbonate fraction, the silicates and sulfide fraction in the Witbank samples, and the ion-exchangeable fraction for the Waterbergassociated sediments samples proved successful in leaching out the REY+Sc. MLA determined that monazite and xenotime in all the coal samples were the REY+Sc-bearing minerals.

Nov 6, 2024

By F. Dong, F. Yang, J. Wang, Z. Wang, D. Mingxia

Antimony oxide ores are important antimony resources, but their recovery is still a problem. In this paper, the adsorption behaviour and mechanism of dodecamine and quaternary ammonium salt on the surface of cervantite and quartz were investigated. The flotation behaviour of cervantite and quartz using quaternary ammonium salts and dodecylamine as collectors was studied by single mineral flotation experiments. The adsorbed amount was measured and infrared spectroscopy was used to study the ability of several cationic collectors to float cervantite and quartz. The results show that quaternary ammonium salts can simultaneously float the cervantite and quartz. It is difficult to achieve separation of the two minerals using quaternary ammonium salts as collectors. At pH>10, dodecylamine can float quartz but not cervantite, which can achieve reverse flotation separation of the two minerals. The difference between the abilities of quaternary ammonium salts and dodecylamine to float cervantite and quartz lies in the different ionisation properties of the two reagents. Quaternary ammonium salt is a strong electrolyte that is completely ionised in the pulp and exists mainly in the form of quaternary ammonium ions. Dodecylamine is a weak electrolyte and predominantly forms molecules under alkaline conditions. Keywords: Cervantite, quartz, dodecylamine, quaternary ammonium salts, flotation

Jan 1, 2020

By A. Singh, R. D. Govender

The current method employed to quantify the efficiency of separation of ferromagnetic ores by wet low intensity magnetic drum separators (WLIMS) incorporates the use of a conventional benchscale Davis Tube (DT) operating at a magnetic field intensity that is equivalent to that of the drum’s surface. However, empirical research has indicated that the magnetic force, or force index, rather than the magnetic field intensity, is the critical factor in the operation of the magnetic separator (Murariu and Svoboda, 2002). Furthermore, the current aforementioned practice would yield incorrect information as the magnetic field gradients produced by a typical WLIMS unit differs considerably from that of a bench-scale DT. In light of this, research on magnetite focusing primarily on the scale-up of DT results to pilotscale WLIMS were undertaken. The investigation entailed a comparative study between that of a typical WLIMS circuit and a bench-scale DT. The purpose was to practically evaluate the performance of a WLIMS, bench-marked against the traditional laboratory-scale DT unit. Moreover, the secondary objective was to produce a magnetite concentrate graded at 69% Fe, 95% -45μm, as a suitable source of separation media for use in the Dense Medium Separation (DMS) industry. Fundamental findings of previous works provided a framework for the study, however, a realworld approach was explored. Preliminary testwork conducted at Mintek investigated the performance of a DT and a typical multi-stage laboratory-scale WLIMS circuit (operating at 1000 Gauss at the surface). The results attained indicated that a DT operating at high intensities is comparable to a single rougher WLIMS stage. Additionally, it was observed that the three stage laboratory-scale WLIMS circuit performed similarly to the DT operating at 1000 Gauss. Moreover, piloting testwork was undertaken, carried out in larger 380mm drums, and the results attained showed a strong correlation with laboratory-scale findings. Keywords: Davis Tube, wet low intensity magnetic separation, magnetite

Jan 1, 2020

By R. G. Coyle

"In an earlier paper the author explored the consequences of price-stabilizing effects, on an industry-wide basis, of various production strategies. These ideas have now been applied to an illustrative case of an individual mine. It is shown that the turning of production and financial policies can affect financial performance over a five-year period by as much as 22 per cent.No generality is claimed for the results and they would differ from mine to mine. It is, however, asserted that the results show that the proper turning of production, reserves and financial policies are more critical determinants of mine performance than has been realised. It is also asserted that the methods of dynamic analysis are the most appropriate means for studying this policy-design problem."

Jan 1, 2014

By K. C. Sole, M. E. Mitshiabo

Although surfactants have proven to increase metal extraction by improving solution flow in porous media, these reagents have not been widely adopted in heap leaching operations because of potential incompatibilities with downstream processes that are subject to surface properties. The BASF leaching aid, LixTRA 118, was previously found to have no significant effect on post-leach operations. This study evaluated its performance in ores of different particle size distributions and the impact on acid consumption and metal recovery. Column leach studies, carried out on a copper oxide ore and mixed oxide–sulfide ore, showed that the effect of LixTRA 118 was more pronounced in ores with wider particle size distributions than in those with more uniformly sized particles. Solution percolation rates increased by up to 18% in the presence of leaching aid, and increased copper recovery and acid consumption. Improved wetting facilitated the kinetics of acid diffusion at macroand micropore level. There was no significant effect on iron recovery

Jan 1, 2023

By T. Oberthür

The Great Dyke of Zimbabwe constitutes the world&apos;s second largest reserve of platinum group elements (PGE) after the Bushveld Complex in neighbouring South Africa. Within the Great Dyke, economic concentrations of PGE are restricted to sulphide disseminations of the Main Sulphide Zone (MSZ), which are currently mined at the Ngezi, Unki, and Mimosa mines. Near-surface oxidized MSZ ores have a large potential. Their total resources are in the range of 160-250 Mt; however, all previous attempts to extract the PGE from this ore type have proved uneconomic due to low PGE recoveries (<< 50 per cent) achieved by conventional metallurgical methods. Within the ores of pristine, sulphide-bearing MSZ, the PGE are bimodally distributed. Platinum occurs mainly in the form of discrete platinum group mineral (PGM) grains (mainly bismuthotellurides, sulphides, and arsenides), whereas approximately 80 per cent of the Pd (and some Rh) is hosted in pentlandite. Within the oxidized MSZ ores, the PGE are polymodally distributed. Whereas the arsenide- and sulphide-PGMs that make up approximately 25 per cent of the original Pt content of the ore largely remain stable (relict PGMs), the remaining PGMs are disintegrated. The base metal sulphides are destroyed, partly releasing their base metal and PGE contents, and are replaced by iron oxides or hydroxides. Unspecified amounts of the PGE are redistributed and either form secondary PGMs, are found in chemically and mineralogically ill-defined (Pt/Pd) -oxides or hydroxides, or in iron-hydroxides, Mn-Co-hydroxides, and in secondary silicates. The problematic processing of oxidized MSZ ores is attributable to their complex nature and polymodal distribution of the PGE, prohibiting a significant upgrading of the ores by conventional metallurgical methods. Therefore, only bulk leaching methods are viable for ore treatment, and novel metallurgical methods have to be developed for the processing of these ores. Our ongoing work aims at locating the PGE in their mineralogical form in order to understand the mineralogical balance of the PGE in the ores and thereby facilitate the evaluation of metallurgical options for their recovery. A short overview on options and recent advances regarding the recovery of the PGE from oxidized ores is given.

Jan 1, 2013

By F. T. Cawood, C. C. Birc

The South African mineral resource royalty system, initiated in 2010, employs a hybrid ad valorem approach tied to profitability ratios. This rate is then applied to the total revenue from mineral sales. In this article we explore how the profitability ratio in the mineral resource royalty formulae interacts with the gold tax formula as applied to South African gold mines, devising a strategy for cut-off grade optimization. The study focuses on nine narrow, tabular-reef (Witwatersrand) gold mines. The approach involves a mixed-integer cut-off grade optimizer utilizing Excel Solver, incorporating relevant royalty and income tax formulae. Different mineral resource royalty cost scenarios were examined. Ignoring these costs in the break-even analysis lowers the cut-off grade but slightly boosts profits compared to considering expected costs. The developed optimizer model, recognizing the profitability aspect of the mineral resource royalty and income tax formulae, yielded a 6% lower cut-off grade than the base case. This is significant for increasing mine life. While the profit differences are marginal (0.2% compared to the break-even base case), substantial improvements were noted: a 6% increase in stope tons above cut-off grade, and a 4% rise in total revenue. Enhanced resource utilization (3% extra gold kilograms) reduces necessary development and overall costs, allowing for a reduction in the cut-off grade and ultimately, more profit.

Aug 8, 2024

By R. B. Khumalo, M. S. Nyarela, R. C. Nemathithi

Palabora Mining Company is one of the largest low-grade copper mines globally. The mine uses block caving for the extraction of the orebody. This paper enumerates the drawpoint loading strategies for the overall head grade improvements, particularly for a block that is nearing depletion. A comprehensive literature review of various considerations relating to improving productivity in block caving is presented to contextualize the draw control in caving. From this study, an optimized draw control strategy is presented, which focuses on three parameters that include grade distribution, loading compliance, and tonnage splits per sector. An empirical method based on the relational study between various parameters is used to outline the key criteria to be used in the optimization of drawpoint loading in block caving.

Nov 30, 2022

It is a great honour to officiate at the celebration of the centenary of the South African Institute of Mining and Metalurgy. Tonight&apos;s festivities bring back happy memories of my association with South Africa&apos;s mining industry during my tenure of office as Minister of Mineral and Energy Affairs. They also remind me of the illustrious personalities who have preceded me on this podium. The Pioneers They include Sir Percy Fitzpatrick, who spoke in 1909 on the eve of the Union, General Smuts, and, on many occasions during the 1920s and 1930, Jan H. Hofmeyr. The basic issues addressed by them continue to enjoy the Institute&apos;s attention today, namely the optimal and safe exploitation of our country&apos;s mineral resources and cost-effective extraction of minerals from their ores. Translated into the Institute&apos;s key objective it reads: To initiate and give effect to the means whereby the requirements for technology and scientific knowledge if the minerals and metals section if the South African economy is satisfied.

Jan 1, 1994

By S. J. van Wyk, A. S. H. Haagner, A. Abraha

Opencast coal mining is responsible for the greatest area of land disturbance across all of the commodity types in South Africa. Many thousands of hectares have been rehabilitated to date and, although rehabilitation performance is not always measured or reported, a significant database, spanning 24 years, has now been analysed to identify the main shortcomings holding back rehabilitation sustainability across the industry. Data from 48 different collieries with rehabilitation performance scores measured from 2000-2024 were analysed. A standardised assessment framework was implemented at all 48 collieries, focusing on aspects of land capability, soil fertility, landscape form and drainage, vegetation species composition and basal cover, implementation of maintenance programmes, and prevalence of invasive alien plants. The findings show that, although invasive species management, plant species composition, and plant basal cover are often adequate, the implementation of aftercare and maintenance programmes (influencing soil fertility) and deficiencies in overall landform design and drainage systems are most significant in preventing overall rehabilitation progression and self-sustainability. Integrating these during design and rehabilitation execution, followed by intensive maintenance (especially in the first five years post-topsoiling and seeding) will be key for the overall industry performance to improve to acceptable levels. The database is biased towards collieries that actually do undertake rehabilitation and that do measure it, hence the actual industry performance is likely worse than what is presented. Due to the substantial hectarages involved and the main post-mining land uses being grazing and crop production, the industry cannot afford to keep perpetuating deficiencies in achieving the foundational aspects of rehabilitation that would pave the way for sustained economic future use.

Apr 25, 2025

By V. Ross

"Bench-scale flotation tests play a major role in the geometallurgical process value chain. Despite their apparent simplicity, these tests pose pitfalls in terms of operation, as well as the interpretation and modelling of results. In this paper we highlight key aspects to consider in generating accurate and reproducible experimental results, and critically review some assumptions relating to the estimation of entrainment and froth recovery. We subsequently focus on first-order equations to model kinetics and propose a method that accounts more realistically for the decay in kinetics over the duration of a float, and the contributions of froth stability and hence mass pull. The method was applied to three case studies on platinum group metal (PGM) ores and matched or outperformed first-order, two-component models. Also, it allows for a deeper analysis of the integrity of the bench-scale flotation results. IntroductionGeometallurgy is a structured, multidisciplinary approach that integrates key data from the geological, mining, mineralogical, and metallurgical aspects of the value chain to construct spatial models of an ore deposit such that the overall economic benefit and sustainability of an operation can be optimized. Process geometallurgy is aimed primarily at enhancing metallurgical efficiency and plant throughput by the application of appropriate mining and processing strategies, as well as supporting production planning and operational strategies to reduce the impact of highly variable ores. With flotation being the dominant concentrating process in the mineral value chain, the bench-scale flotation test is an important characterization tool – a relatively cheap, simple, and rapid way to obtain key information about the ore and its amenability to economic extraction of valuable minerals. This includes the evaluation of different ore types and the implications of mineralogical composition and texture for comminution and floatability, the effect of the grinding environment on the liberation of minerals, the electrochemical environment in the pulp (Bradshaw et al., 2006), the screening of reagents to improve floatability (Ekmekci et al., 2003), and the role of hydrodynamics in the recovery of valuables and the entrainment of gangue (Amini et al., 2016; Wang et al., 2016). It is also a critical tool in auditing the performance of a flotation plant by hot floats, paving the way for concept and feasibility studies and providing essential data on kinetics for the purposes of scale-up, optimization, and simulation of flotation circuits."

Mar 1, 2019

By E. Y. Baafi, H. Fan, W. Zeng

We present a discrete event simulator, TSJSim (Truck-Shovel JaamSim Simulator), for evaluating the stochastic and dynamic operational variables in a truck-shovel system. TSJSim offers four truck allocation strategies: Fixed truck assignment (FTA), Minimizing shovel production requirement (MSPR), Minimizing truck waiting time (MTWT), and Minimizing truck semi-cycle time (MTSCT) including the genetic algorithm (GA) optimization and the frozen dispatching algorithm (FDA) optimization rules. Multiple decision points along the haul routes for all the trucks close to the decision points were included in the model. The simulation results indicate that the trends associated with production tons and queuing time utilizing the four truck allocation strategies (MSPR, MTWT, FDA, and GA) all demonstrated similar patterns as the fleet size varied. As the system fleet size increased, the system production tons under these strategies at first increased significantly and then remained relatively constant; the queuing time relating to these strategies showed a positive relationship with the system fleet size. The bunching time decreased when the truck allocation strategies were applied in the model. In the simulated truck-shovel network system with multiple traffic intersections, by assigning the trucks at the intersections, both productivity and fleet utilization increased.

Dec 13, 2022

By R. K. W. Merkle, F. A. S. Reyneke, Z. Harris, P. W. J. Delport

The technological advancements in computing power in the last 30 years have enabled the practical visualization of complex geological environments in three-dimensional (3D) space. 3D models and their application in the mining industry are becoming increasingly important, for example, to identify future exploration areas and targets, for mineral assessment and evaluation, and prediction and planning of future drill-holes. However, acquiring borehole data is an expensive practice, with drilling programmes costing mining companies up to billions of dollars each year. Tighter financial constraints on exploration budgets result in more pressure being put on three-dimensional models to accurately identify future target areas. This article aims to evaluate the potential drilling success of simulated greenfield and brownfield exploration using a 3D geological model created of Leeuwpoort tin mine. These simulations investigate the probability of intersecting a mineralized zone of economic interest and evaluate how the probability is affected when the number of drill-holes and distance from a known intersection changes. Furthermore, these simulations attempt to obtain an indication for the minimum number of drill-holes required for a successful exploration campaign at the mine. The investigation also aims to establish a first-pass attempt towards developing a ‘favoured procedure’ for identifying potential exploration targets for tin deposits with geological and geochemical characteristics similar to Leeuwpoort. The results for the ‘favoured procedure’ established are statistically tested using the ‘bootstrapping’ method. By simulating various exploration scenarios, the study also emphasises the importance of predicting successful drilling, which aids in budgeting for drilling programmes as the minimum number of drillholes needed for a specific exploration project can be determined.

Feb 2, 2022

By V. van der Merwe, C. W. Siyasiya

"A petrochemical company experiences premature thermal fatigue failure of the casting moulds used in catalyst production. The aim of the project was to find an alternative alloy that would outperform the current low-alloy cast steel used for the moulds. Based on their thermo-fatigue properties, 3CR12 ferritic stainless steel and H11 tool steel were chosen for testing and comparison with the currently used BS3100 B7 cast steel. Samples of each material were subjected to temperature cycling in a Gleeble 1500TM thermo-mechanical processing simulator, followed by surface analyses. The main parameters derived from the test work were the total true strain, the hot strength of the materials, and the number of cycles to failure. Additionally, the coefficient of thermal expansion for each material was measured using a Bähr dilatometer. H11 tool steel yielded the best performance by way of having the fewest surface cracks, the lowest total true strain per cycle, the most cycles to failure, the highest hot strength, and the lowest coefficient of thermal expansion.IntroductionThe Catalyst Manufacturing Plant (CMP) is a dusty environment with temperatures higher than ambient. Molten mill scale (magnetite, Fe3O4) is tapped from the electric arc furnace into the casting moulds at temperatures close to 1600°C. After 10 seconds the magnetite is quenched with a water spray for 50 seconds to a minimum temperature of 400°C. Sometimes there is residual water in the pans from the cooling fog process (water sprays) in the empty mould. In a typical plant, the factory produces 40–44 batches a day containing between 150–300 moulds, depending on the time required for the specific batch (Buchholz, 2014). The typical batch in the CMP usually weighs about 6 t. The thickness of the tap, speed of the casting belt, and tilting angle all affect the number of moulds per batch.One of the main problems faced during the molten mill scale casting is the premature failure of the casting moulds. Cracks initiate on the surface of the mould, which is in contact with the hot catalyst, and propagate into the interior of the mould. Cracks are generally concentrated in the middle area of the mould where the catalyst makes first contact with the mould, and which experiences the highest temperature fluctuations. This suggests that the cracks are caused by thermal fatigue during the casting process."

Jan 1, 2016

By P. K. Jain

A spiral concentrator is a density separation device used for the beneficiation of coal and various minerals such as iron ore, chromite ore, gold, beach sand minerals etc. The flow pattern developed in the equipment is complex and unique, yet the operation is very simple, with low capital and operating expenditure. Spirals are applied for beneficiation of material in the size range finer than 2 mm and are capable of recovering heavy minerals as fine as .01 mm. The understanding of the unique flow pattern has kept researchers engaged over the last few decades and attempts are being made to explain such flow patterns so that they can be controlled and modified to improve the operating efficiency, Ep (Ecart Probable Error, also known as probable error in separation) and acceptability of spiral concentrators for processing of fines and slimes - currently being discarded and dumped in the tailing ponds. An attempt has been made in this paper to explain the generation of complex flow patterns with application to classical solid mechanics in the fluid and slurry system. The same has been used to explain the selective separation of particles in different zones in a cross-section on the spiral trough. The paper also discusses the application of a force balance model to explain the generation of secondary circulation. Due to the presence of laminar and turbulent flow regimes in the spiral concentrator, varieties of equations have been proposed in the literature, consisting of different equations for different zones. An attempt has been made to present a unified flow equation for calculation of flow velocity at different positions on the spiral trough. Keywords: Secondary circulation, spiral concentrator, density separation, fine particle processing

Jan 1, 2020

By J. R. Bredell, J. Branehog, C. Coetzee, J. J. van Tonder

A nutating grinding mill, exemplified by the commercial HICOM mill, achieves efficient particle size reduction through the accelerated motion of the material charge within the nutating chamber. This design, characterised by high particle velocities and rapid charge circulation, offers a compact solution compared to tumbling mills. There have been concerns regarding the mechanical reliability of kinetic joints for certain specialised mining applications. Recognising the need to model internal forces in such systems, this study focuses on the uncoupled simulation using multibody dynamics and the discrete element method. The investigation employed a small-scale experimental test mill, referred to as the NuMILL, featuring a cylindrical chamber (140 mm internal diameter, 245 mm height, 6° nutation angle). Instrumented with an array of sensors, the NuMILL provided internal load data for validating the simulations. Experiments were conducted with an empty chamber or filled with charge material. Charge materials included coarse sand or steel pellets with a charge-to-chamber mass ratio of 0.25. The mill speed ranged between 100 to 700 RPM. Multibody dynamics modelled resultant inertial and frictional loads within 5%, while the discrete element method simulated the internal material contact loads with accuracies ranging from 1% to 19%. The combined simulation approach predicted the resultant forces in the critical kinetic joint within a 20% margin. Representing the charge using rigid lumped mass elements was also studied. The presented simulation techniques, validated against experimental data, offer a robust foundation for analysing larger systems, including the industrial-scale HICOM.

Mar 5, 2025

By H. Dudycz, A. Skoczylas, P. Stefaniak, P. Pyda

In the era of Industry 4.0, technologies such as Big Data (BD) and the Internet of Things (IoT) play a key role, especially for multi-site manufacturing companies. In such companies, the challenge is to collect and process massive amounts of data from industrial devices and extract key information from this data in real-time for ad hoc decision-making. The ability to analyse data from industrial devices translates directly into streamlined production processes, cost optimisation, prevention of unplanned events, and safety during operation. In this context, particular attention should be paid to Big Data Analytics (BDA), whose main source is the Industrial Internet of Things (IIoT). The purpose of this paper is to propose an IT system architecture incorporating BD and the IoT for a mining company. The paper presents results from a literature review focusing on available BD and the IoT solutions for industry (mining in particular) for the purposes of the acquisition, integration, and advanced analysis of data. The advantages and disadvantages of the different solutions were indicated and gaps in the accessibility to dedicated functionality are identified. Based on the analysis of a multi-site mining company, the main challenges faced by such companies planning to implement BD and IoT solutions are identified. Also, a proposal for an IT system architecture incorporating BD and IoT for a mining company is described in the paper. The contribution of the article consists of the identification of the challenges faced by mining companies planning to implement BD and the IoT solutions, and the proposal of an IT system architecture that allows BDA whose main source is the IIoT.

Sep 1, 2021

By J. van der Walt, W. Spiteri

Flyrock remains a significant threat to the health and safety of mine employees and integrity of infrastructure, as well as to the safety of the neighbouring communities and their property. This investigation was motivated by the general lack of fundamental research and mathematically quantifiable data in the literature regarding the relationship between blast design parameters and their impact on flyrock. The focus was to develop a concept that can be used to mathematically quantify the trajectory of flyrock resulting from a blast, which can be used for future research. The ultimate goal for this technique, once it has been fully developed, is to: ➤ Enable mining operations to generate a database with accurate historical flyrock measurements resulting from their blasting operations ➤ Allow research teams to conduct scientific investigations into flyrock and the impact of various blast design parameters ➤ Generate point-cloud data to visualize blasts and flyrock in a virtual reality environment for training and education purposes. This paper summarizes a conceptual technique and preliminary fieldwork that was carried out to determine the technique’s feasibility and motivate further development. The results show conclusively that a modified photogrammetric technique is capable of capturing flyrock data for further processing and analysis. The data acquisition procedure can, at this point, be used to meet the first aim of the project, namely to gather a field database of historical flyrock generation. Further development of the technique is ongoing and it is envisioned that the scientific-based technique will provide a method whereby future flyrock studies will be comparable and that assumptions will be limited.

Apr 5, 2023

By X. Zhang, E. Li, Y. Xiao, Z. Yu, H. Han, J. Xie, J. Tian, W. Sun, K. Hong

In a pulp environment, the surface properties of magnesite and dolomite tend to be similar, due to the re-adsorption of dissolved calcium species, which makes the flotation separation difficult. In this paper, the chelating reagent EDTA is introduced to eliminate the adverse influence of the calcium species and to restore the selectivity of magnesite-dolomite separation using sodium hexametaphosphate (SHMP) as a depressant. Flotation experiments confirm that the recovery of magnesite improves significantly in the presence of EDTA. Zeta potential experiments confirm that the negatively charged EDTA4+ and HEDTA3+ species can form soluble and stable chelates with positively charged Ca2+ and Ca(OH)+ species preventing their adsorption on the magnesite surface. Adsorption measurements prove the addition of EDTA can decrease the adsorption of depressant SHMP on the magnesite surface. X-ray photoelectron spectroscopy (XPS) measurements further confirm the transformation from the surface of magnesite to dolomite in the presence of calcium ions, and the possible adsorption mechanism of EDTA and SHMP on the magnesite and dolomite surface. Key words: Magnesite; Dolomite; Surface dissolution; Flotation separation

Jan 1, 2020

By B. A. Obadele, R. Machaka, M. L. Raganya, M. E. Makhatha, N. A. Moshokoa

The influence of solution treatment on the phase evolution and tensile properties of Ti-Mo alloys was investigated to assess their potential use in biomedical applications. Phase formation and microstructural evolution were studied using X-ray diffraction (XRD), optical microscopy (OM), scanning electron microscopy (SEM), and electron backscatter diffraction (EBSD). The mechanical properties were characterized by means of tensile tests and bending strength. XRD analysis showed that solution treatment increased the volume fraction of β phase and supressed the α" phase. The microstructures of the as-cast alloys consisted of β equiaxed grains with sub-grain structures of different sizes, while the solution treated alloys comprised β equiaxed grains only except for Ti- 10.02Mo, which comprised needle-like α" structures. EBSD showed an increase in the volume fraction of the ω and α" phases in all the alloys after solution treatment. The elastic modulus and UTS of all the alloy significantly decreased after solution treatment, except for Ti-15.05Mo,whereas the elongation significantly increased. The fracture surfaces of all the alloys after solution treatment indicated more ductile behaviour than brittle

Jun 10, 2024