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By Chuanyao Sun, Longli Liu, Fayu He, Guiye Wu

Utilizing thioglycolic acid (TGA) as a template and using structure-guided design, a molecular modelling approach has been used to design and screen appropriate dispersant for chalcopyrite. A series of organic dispersants based on a TGA substitution with hydroxyl and amino and sulfonic functional groups have been examined on chalcopyrite surface. 20 organic depressors of chalcopyrite have been investigated to study the quantitative structure-activity relationship (QSAR) of chalcopyrite depressors. For the chalcopyrite surface, depressor containing carboxyl and sulfonic group is generally stronger than the depressor containing hydroxyl group. Increasing the number of hydrophilic group can effectively enhance the inhibition. Increasing the number of Solidophilic group does not necessarily lead to enhanced inhibition ability; steric factor is one of the important factors to affect the interaction. Extension alkyl carbon chain length cannot enhance the interaction of depressors. Isomers principle as well as applies to the chalcopyrite depressor molecular design. Flotation verification tests further confirmes the accuracy of the molecular simulation. Through the Computer Aided Molecular Design (CAMD) technology, we can save enormous time and resources to design novel surfactants. This research and application will play a great significance role in sulfide flotation.

Jan 1, 2014

By V. I. Ryaboy, V. P. Kretov, S. E. Levkovets, I. V. Ryaboy

"Using the flotation of a gold-containing ore from a deposit in Kazakhstan as an example, we have conducted a study designing dialkyldithiophosphate collectors, in addition to xanthates, for the flotation of hard-toenrich gold-containing ores to increase gold recovery.The increased flotational ability of the dialkyldithiophosphates was determined by their surface activity at the liquid-gas interface and their hydrophobic ability, the changing of which allowed us to control the collecting power and selective ability of the dialkyldithiophosphates. The studying of the surface activity of aqueous solutions was done using the stalagmometric method and the evaluation of the hydrophobic ability was done in percentage of the relative value of the zinc ion binding in the solution in standard conditions.Studying the influence of surface activity in our designed dialkyldithiophosphate collectors, with their close hydrophobic ability, showed that even with a small increase in surface activity in their aqueous solutions, gold recovery increased by 2-3% in laboratory conditions. Using this enabled us first to apply the dialkyldithiophosphate collector BTF-161 at a plant in Kazakhstan, and then to introduce the specially designed dialkyldithiophosphate collector BTF-163, which has been in use since. Further study of dialkyldithiophosphate activity based on this concept showed us that for the range of short-chain dialkyldithiophosphate collectors with a chain length of up to ?5, the effectiveness of ore processing became lower the higher their surface activity got, with relatively small differences in their hydrophobic ability. For long-chain dialkyldithiophosphates with a chain length of over ?5, ore processing effectiveness increased with the increase of their hydrophobic ability.Based on these studies, a new effective dialkyldithiophosphate collector, BTF-1517, was designed. Using this reagent in continuous gold recovery tests allowed us to reach an 84.21% recovery with a concentrate quality of 15.66 g/t, while using the applied collector BTF-163 in similar conditions led to the recovery of 82.87% with a concentrate quality of 15.65%. As a result, the Kazakhstan processing plant decided to conduct industrial tests with the BTF-1517 collector."

Jan 1, 2018

By Nikkam Suresh

Dense medium cyclones have been in use for washing coarse and small coals for more than 50 years. There have been modifications in its design and today these units have become indispensable for washing of Indian coals possessing difficult washing characteristics. About 53 percent of the Indian coals (coking and non-coking) are being washed in jigs, about 38 per cent are washed in dense medium cyclones while the remaining 9 per cent is treated in other units like Barrel Washers, Heavy Media Baths and Drum Separators etc. The present paper deals with the attempts made for design of industrial Dense Medium Cyclones for enhanced coal recovery. Two industrial units of 500 mm diameter and 650 mm diameter were designed with their washing capacities being 200 m3/hr and 350 m3/hr, respectively. The results of the pilot tests conducted on 500 mm cyclone treating very high Near Gravity Material coals crushed to -3.0+0.5 mm gave an ash reduction of up to 19.5 percent with the new design i.e., from a feed ash of 34.5 percent to 15.06 percent in clean coal with an appreciable yield of 45 percent in one stage.

Sep 1, 2012

With rapid development of Chinese iron & steel industry, it is of significance to intensify the utilization of domestic complex iron ore resources. The tin, zinc-bearing complex iron ores are typical polymetallic and intractable ones because of the complicated intergrowth relations among the multi-elements, and they have not been efficiently utilized, presently. Based on the thermodynamic analysis of iron, tin and zinc oxides reduction by CO, the technological conditions of tin and zinc recovery and pellets preparation from tin, zinc-containing iron concentrates by selective reduction roasting are studied and a new comprehensive utilization process is developed in this investigation. Under the optimum conditions, the tin and zinc volatilization is respectively in excess of 80% and 70%, and the compression strength of roasted pellet is more than 2500 N/P. Moreover, the residual tin and zinc in the finished pellets is below 0.06%. The finished pellets can be used as high quality iron-making burdens for large-scale blast furnace.

Jan 1, 2014

By Sun Chuanyao, Cao Fei, Sun Desi, Zhou Dezhi

"The research applies the density functional theory and molecule design technology to design and synthesize the novel flotation collectors for copper-sulphur separation. Density functional theory (DFT) was applied to investigate the electronic properties of O-isopropyl-N-benzyl thionocarbamate (IP-BIAN) and O-isopropyl-N-ethyl thionocarbamate (Z-200). The calculation results show that both the energy of highest occupied molecular orbital (EHOMO) and the lowest unoccupied molecular orbital (ELUMO) of IP-BIAN are smaller than that of Z-200, electronegativity of IP-BIAN is higher than that of Z-200. According to the Klopman’s generalized perturbation theory, the collecting power of the two compounds is predicted to be Z-200 > IP-BIAN, the selectivity of IP-BIAN is better than that of Z-200. Then the thionocarbamate molecular is synthesized, and the compounds are characterized by nuclear magnetic resonance (NMR). It turns out that the test result identifies the prediction after the flotation verified test of pure mineral and actual mineral. The results demonstrate that the EHOMO and ELUMO are smaller in the thionocarbamate after a nitrogen atom is bound to benzyl, the thionocarbamate has strong selectivity and low collecting power. The lower the LUMO energy of thionocarbamate is, the stronger the back donation covalent p-bond between collectors and chalcopyrite is, thus improving flotation power for chalcopyrite and selectivity against pyrite. The result proves the feasibility of design and synthesis of the novel thionocarbamate through the frontier orbital properties of the collectors.1. INTRODUCTION Thiocarbamate is a kind of nonionic polar collector and is now widely used as flotation collector for copper-sulphur separation. The flotation power of thiocarbamate to chalcopyrite is stronger than pyrite, so it has high selectivity against pyrite. The frontier orbital theory and density functional theory (DFT) has been widely applied to study the structure-activity relationship of flotation collectors [1-6]. The flotation test results can be interpreted by using the reaction energy criteria and quantum-chemical parameters, such as the energy of the highest occupied molecular orbital (EHOMO) and the energy of the lowest unoccupied molecular orbital (ELUMO) of collector [7-11]. In turn, there are rarely reports about screening the novel flotation collector, by the frontier orbital properties such as HOMO and LUMO of flotation collectors. In this thesis, we apply the density functional theory and molecule design technology to design and synthesize the novel flotation collectors for copper-sulphur separation. Based on the previous findings of the structure-activity relationship of xanthogen formats [12], it has stronger collecting ability to chalcopyrite while the xanthogen formats after a nitrogen atom is bound to benzyl. Thus, in this study, a novel thionocarbamate molecule O-isopropyl-N-benzyl thionocarbamate (IP-BIAN) will be constructed, when the group structure connected with N atom in the known collector O-isopropyl-N-ethyl thionocarbamate (Z-200) is replaced with ethyl by propyl. The collectors (IP-BIAN and Z-200) have been calculated by DFT methods in quantum chemistry. By analyzing the reaction energy criteria and the frontier orbital properties (HOMO and LUMO), this research predicts flotation performance of novel collectors (IP-BIAN), then the synthetic experiments and flotation verified tests are conducted. The research provides a new theory reference for screening out the high-effective flotation collectors of copper-sulphur separation. This technology adoption will contribute to the sustainable development of mineral resources as it shortens the research cycle of new collector molecules and reduces the investment."

Jan 1, 2018

By T. C. Alex

Mechanical activation of gibbsite [?-Al(OH)3] is the theme of this paper. Industrially prepared gibbsite used in the study has a mono modal size distribution with a median size, d50=110 µm. Mechanical activation of this gibbsite has been carried out in a planetary mill at ambient conditions. Mechanical activated gibbsite samples are characterised in terms of particulate characteristics, structural characteristics and reactivity. As a result, of milling, mono modal size distribution of the unmilled gibbsite changes to a broad multimodal distribution. Size reduction has been sharp in the initial stages of milling; median size reduces to ~7 µm during 15 min of milling. Thereafter no decrease in median size is observed; rather it is found to increase gradually with further increase in milling time, indicating particle aggregation. Morphological studies of milled gibbsite have shown that the platelets forming the agglomerate are separated first; the separated platelets then undergo breakage. Aggregation of particles sets in the later stages of milling as a result of increased surface area and surface energy. X-ray diffraction (XRD) and transmission electron microscopy (TEM) studies have clearly revealed the changes in gibbsite structure during milling. Analyses of XRD data show that the crystallite size of gibbsite decreases as the milling time progresses whereas its microstrain is found to increase. Accumulation of energy in the structure is the result in both cases. TEM micrographs with signs of defects leading to disordering of gibbsite structure complement the XRD results. Reactivity of milled gibbsite, decrease in its deydroxylation temperature and increase in alkali dissolution, is found to increase with mechanical activation. Increased reactivity of milled gibbsite is found to have a strong correlation with the BET specific surface area. Keywords: mechanical activation, gibbsite, alkali dissolution, thermal dehydroxylation, reactivity

Sep 1, 2012

By H. X. Yan, J. X. Zhang, F. S. Niu

"The analysis on influencing factors of hydraulic conditions in fine hematite flocculation, such as stirring speed, stirring time and axial distance of particle size and fractal dimension of floc was investigated. Furthermore, response surface methodology(RSM) has been applied according to the Box-Benhnken center-united experimental design principle to optimize parameters of hydraulic conditions as a response index to indicate the fractal dimension of floc. The results show that when the agitation speed is 900r/min, the axial distance is 2.0cm, and the stirring time is 3.0min, the particle size reaches the maximum value of 35.44µm and the fractal dimension is 1.6594. The interaction between the axial distance and the stirring speed is highly significant, but the interaction with the stirring time is not obvious. The experimental data and model predications match well, which indicates that the established model has high accuracy and practicability. INTRODUCTION With the exhaustion of iron ore resources that are easy to be mined and the vigorous demand for iron and steel, the exploitation and utilization of fine-grained embedded iron ore resources have drawn attention from the industry and the government [1~2]. Flocculation flotation is one of the effective methods for separation and recovery of fine granular minerals. In 1975, the method was first applied and succeeded in Tilden Concentrator, USA. Flocculation and desliming became the key technology of the Tilden to raise its annual treatment capacity from 4 million tons to 8 million tons at that time [3 ~ 4]. In 2008, the selective flocculation and desliming-reverse flotation technology was successfully used to treat 2.8 million tons of Qidong iron ore. Under the conditions of 28.36% raw iron grade and 98% grinding fineness -0.038 mm, the ideal index of 62.5% iron concentrate grade and 68% recovery was obtained [5]. Dr Kitchenner of the Royal College of Mining and the Ore Processing Research Group of Wallenstein Laboratory first proposed the use of flocculation to separate minerals. After that, many scholars conducted a great deal of theoretical and practical researches, but mostly they focused on chemical theories, mathematical models and selectivity differences in the flocculation process, while the research on the influence of the pulp flow state on the separation effect in the flocculation process started later [6~9]. The results show that the motion of the agitated flow field has a significant influence on the formation of flocs. The fluid morphology will change with the change of hydraulic conditions. The change of fluid morphology will not only affect the movement behavior of particles, but also change the action of chemical agents on the surface of mineral particles[10~12]."

Jan 1, 2018

By K. C. Corin, M. S. Manono, R. M. Manenzhe, J. G. Wiese

"Environmental concerns necessitate the recycling of process water within mining operations. Given that recycled water is chemically different from fresh water, and collectors are added such that they adsorb at the liquid-particle interface, changes in the aqueous phase are expected to affect collector adsorption. A Finnish nickel-copper ore was floated in synthetic plant waters of varying ionic strengths and plant waters obtained at Boliden Kevitsa Mine, with aerophine and sodium isopropyl xanthate as collectors. Of the tested waters, the copper thickener overflow was the least conducive to xanthate adsorption and valuable mineral recovery. The nickel thickener overflow, standard process water, and raw water were the most conducive to xanthate adsorption. For the raw water and nickel thickener overflow, increased adsorption correlated with increased valuable mineral recovery. Further, recycling xanthate retained in water affected the selectivity of the collector and hence the concentrate grades.INTRODUCTIONFlotation is a separation process that exploits the differences in the surface properties of the particles being separated. The efficiency of separation is dependent on the degree of hydrophobicity achieved by the particles meant to be floated, which are, in most cases, valuable minerals. The hydrophobicity is in turn dependent on the adsorption of the chosen collector onto the surfaces of the floated particles (Fuerstenau, 1984; Taggart and Hassialis, 1946). Empirical findings suggest that species dissolved in solution strongly influence collector adsorption and overall flotation response (Fuerstenau and Chander, 1986). Due to environmental concerns, it is becoming more pertinent for mining plants to recycle process water and hence limit the usage of potable water. There is an interest to ensure minimal discharge of plant water into the environment, as this water is typically polluted with process reagents that may render it toxic (Levay et al., 2001)."

Jan 1, 2018

By L. S. Zhou

HermesTM metal magnetic liner (MML) has been invented and manufactured by China Metallurgy and Mining General Co. (CMMC). This paper describes its mechanism, structure, magnetic field distribution, application, economic benefit and safety performance. The 10 years? service life in Benxi Steel?s Waitoushan Mine, along with 6 years? technological analysis on its application in 5500mm×8800mm (diameter × length) ball mill in Anshan Steel?s Diaojuntai mineral processing plant, has proved its advantages such as super reliability, long service life, light weight, thin thickness, low noise and short payback period. It has also demonstrated its positive effects on the grinding process such as high productivity, energy-effective performance and low consumption of grinding media. It reduces labour intensity and improves working conditions, due to its easy installation, free maintenance and the fact that it doesn?t require fastening bolts or cause slurry leakage. It is de-signed scientifically in accordance with the varieties of processing lines, mill specification, ore type and grinding media, and has been applied in different grinding processes for magnetite, hematite, gold ores, nonferrous ores and other materials. HermesTM MML has three types of products: General, Composite and Heavy-duty. They are designed to meet the requirements from customers in China and abroad. So far, more than 400 sets of MML have been applied in ball mills with diameter rang-ing from 1500mm to 5500mm. It has become highly popular in American market recently due to its safe and effective performance.

Jan 1, 2014

By N. Tsoni

The separation and recovery of fine and ultra-fine particles during the processing of mineral commodities by conventional separation methods is difficult and inefficient. This is due to the problems posed by the very small size of the mineral particles. The fine and ultra-fine mineral particles are either generated during size reduction processes or are necessitated by liberation size. This problem is expected to deteriorate, as deposits of even lower grade are processed. The inefficiency of the conventional separation methods with regards to the processing of very fine particles leads to the loss of considerable quantities of mineral commodities to the tailings. Novel methods and techniques as well combinations of known methods have been tested over the years. Among them, selective aggregation, along or in combination with flotation, has been given much attention. This study deals with the application of hydrophobic agglomeration as a separation method for very fine particles. The selected mineral system is magnesite/quartz, due to its sensitivity to physi-cochemical separation methods. The aim was the selective agglomeration of magnesite using sodium oleate. Tests on single minerals revealed that separation seems feasible and efficient. The parameters examined were: pH, quantity of sodium oleate, conditioning time, and, finally, settling time. Tests carried out on artificial mixtures of the two minerals, under various proportions, confirmed the results obtained from single mineral tests but they were slightly inferior. Finally, hydrophobic ag-glomeration tests were carried out on single and artificial mixtures of minerals using sodium oleate and petroleum as reagents. The results show that the addition of petroleum improves the results. In conclusion, hydrophobic agglomeration can be applied successfully even for fine particles of difficult-to-be-separated systems such as magnesite and quartz.

Jan 1, 2014

By Jerzy A. Mielczarski

The separation of albites from quartz by flotation applying the conventional HF-methods is no longer acceptable from an environmental and health point of view. Therefore, the search for a new reagent scheme without using HF depressor for separation of albite from quartz is under consideration. The flotation behaviour of ore mineral components depends on the produced hydrophobic or hydrophilic surface coverage (chemical functionalization). Currently we have excellent possibility of monitoring surface composition and structure at molecular and atomic levels at surfaces of natural minerals contacted with aqueous solutions of collectors, activators, depressants which is vitally important for the understanding of the surface chemistry that govern selective and efficient flotation. Detailed surface characterization of minerals before and after their exposition to different solution conditions was performed by the most modern spectroscopic techniques such as developed by us the infrared external reflection technique combined with spectral simulation and X-ray photoelectron spectroscopy (XPS). It is possible to monitor surface reactions which facilitate the separation process and those which bring disadvantage to selective flotation. At first we found that a small amount of ?mineral impurity? presented in natural ore could play important role in selective hydrophobization process. It was found that the pH of solution (parameter possible to control) and natural mineral impurities present in mineral samples (parameter related to ore origin) play a very important role in the separation process. Another important parameter is interaction between minerals, quartz and albite, present in aqueous solution. The limitation of flotation separation resulting from chemistry will be discussed. Moreover, the most promising scheme for separation of albites from quartz will be examined.

Jan 1, 2014

By X. L. Wang

Hydrothermal method was applied in the preparation of calcium sulfate whiskers in airtight re-actor using gypsum as primary materials. The optimum conditions of preparation are as follows: pH value 9.8~10.1, concentration 5%, material size 18.1µm, which were determined by the analysis of the diameter of CaSO4 whiskers through SEM. On these conditions a product of ultrafine CaSO4 whiskers with diameter of 0.19µm and aspect ratio of 98 is obtained. Ultrafine CaSO4 whiskers with different concentrations, modified by titanate NDZ-401, were added into polypropylene as intensifier and composites of Ultrafine CaSO4 whiskers/ polypropylene were prepared by melting-extruding method. Mechanical performance of the composites was tested and surface morphology of the composites was observed by SEM. The results indicated that impact notched izod of the composites was enhanced by 49.5% compared with pure polypropylene when 10.0% Ultrafine CaSO4 whiskers were added into polypropylene and toughening effect was very remarkable. Dispersion behaviour and interface phenomenon of Ultrafine CaSO4 whiskers in polypropylene matrix were investigated by SEM. The results indicated that Dispersion performance of Ultrafine CaSO4 whiskers modified by titanate NDZ-401 in polypropylene matrix is good, which improved mechanical performance of composites to some extent.

Jan 1, 2014

By G. V. Kalabin

"The paper supports applicability of satellite imagery at regional and local level for rapid quantitative assessment of natural environment in zones of activity of mining complex enterprises. Exacerbation of environmental problems during mineral mining and processing associated with their scale and geography of field distribution through the vast territory of our country requires constant monitoring of natural environment status, which necessitates engagement of space surveillance nowadays. It is proposed to use the monitoring of land cover and land use at regional and local level for the environmental assessment of a particular production or complex productions. You must establish the dependence of NDVI change trend with the magnitude of anthropogenic impact on the source or multiple sources of environmental pollution a particular area.. We present the results of studies of vegetation remote sensing methods in a number of territories placing mining enterprises. INTRODUCTION Ensuring a healthy environment is necessary both in untouched areas and disturbed. The condition of the developed territories should be monitored with particular attention, since the restoration of the disturbed territories requires great efforts and financial costs. More narrowly, the health of the environment (Zakharov V.M. and etc.,2001) means its quality ensuring the health of man and other species of living organisms, which includes two aspects (Zakharov V.M. and etc, 2000): - ensuring an environment conducive to human health as a biological species: - maintaining the health of the natural environment, i.e. its constituent species of living organisms and plants. The consequence is the disturbance of natural ecosystems, which determines the quality of the environment, favorable for human habitation and the state of health of the population in total determine the status of the territories where enterprises for the development of georesources are located and allow them to be ranked according to the degree of environmental danger. Without knowledge of the trajectory of ecosystem successions, it is impossible to offer adequate requirements for the technologies used to ensure the implementation of the preserved natural potential after the removal or reduction of man-made stress."

Jan 1, 2018

By I. Dymov

"The extractive metallurgy of precious metal ores involves gravity concentration, flotation and cyanide leaching. Pre-oxidation, such as roasting, autoclaving, bacterial oxidation and other techniques, is required for processing refractory ores. Selection of the process is mainly driven by the grade, reserve and mineralogy of the target elements. The concentrations of precious metals in the crust are extremely low and highly variable, resulting in ore variability in many gold, silver and PGE deposits. More importantly, precious metals in an ore may occur in two or three forms (i.e. microscopic, submicroscopic and surface-bound), making ore processing of precious metals extremely challenging. The objective of geometallurgy and process mineralogy is to reduce and minimize the technical risk in project evaluation, process selection, mine planning and production forecasting through geometallurgical modelling, representative sampling and subsequent systematic mineralogical characterization and metallurgical testwork. Geometallurgy is a technique to document variability within an orebody and quantify and evaluate the impact of many factors including geology and mineralogy on grinding, flotation, leaching and metal recovery processes, while mineralogy is one of the major predictive and trouble-shooting tools for many new mineral projects and operating mines. This paper presents an overview of fundamentals, methodologies and techniques applied in geometallurgy and process mineralogy and highlights the importance of both disciplines in process selection and plant optimization with applicable case studies. INTRODUCTION Precious metals, including gold, silver and platinum group elements (PGE) occur in various geological settings and ore types. The concentrations of these metals in the crust are extremely low and highly variable, resulting in ore variability in many gold, silver and PGE deposits. More importantly, precious metals in an ore may occur in two or three forms (i.e. microscopic, submicroscopic and surface-bound), making ore processing of precious metals extremely challenging. Process selection is most important in any precious metals project and is mainly driven by the grade, reserve and mineralogy of the target elements. Free-milling ores, such as Kupol in Russia, Hemlo in Canada, Grasburg in Indonesia, UG-2 in South Africa, Lac des Iles in Canada, and Noril’sk in Russia, can be processed using flotation or cyanidation with or without gravity. B2Gold Corp, a Canadian gold company, just started a number of new and under construction free-milling gold operations such as Fekola mill in Mali, Mastbati mine in Philippins and Otjikoto mine in Nambia. However, refractory ores (particularly gold ores), such as the Carlin and Goldstrike mines in the USA, Giant in Canada, Pueblo Viejo in Dominican Republic, Porgera and Lihire in PNG, Kittilla in Finland, Fairview in South Africa and Shuiyindong in China, must be processed using pre-oxidation prior to cyanide leaching. In some mildly refractory gold ores, such as Kumtor mine in Kyrgyzstan and KCGM in Australia, ultrafine grinding is required to liberate fine-grained gold particles. For some gold ores containing both free-milling and refractory components (such as Cripple Creek mine in Colorado, USA), two or more recovery processes may be required. The variability of grade, metal deportment, ore hardness and other parameters is one of the risks that encountered in development and operation of many precious metals projects. To minimize and reduce the technical risk caused by ore variability, geometallurgy and process mineralogy have been used by mining companies in the last two decades to measure and quantify the spatial variability of the deposits that are being developed. This paper presents an overview of fundamentals, methodologies and techniques applied in geometallurgy and process mineralogy, it highlights the importance of both disciplines in process selection and plant optimizat"

Jan 1, 2018

By V. Panayotov, M. Panayotova

"Wastewater from ores processing is often polluted by molybdate and sulfate (SO42-) ions. Sorption is one of suitable methods for removing those pollutants when presenting in low concentrations. This work reports results on adsorption of sulfate and molybdate ions on metal modified (with barium - Ba and lead - Pb) and organic reagent modified (with Hexadecyl-trimethyl-ammonium bromide - HDTMA) clinoptilolite. Zeolite’s modification with Pb, Ba and HDTMA increases its uptake capacity with respect to Mo(VI) at pH 3, with the uptake capacity decreasing in the order CL-Pb > CL-HDTMA > CL-Ba. Lead-modified clinoptilolite shows high uptake with respect to Mo(VI) in acidic, neutral and slightly alkaline conditions. The presence of SO42- in concentrations twice higher than the amount of Mo(VI) do not interfere with the Mo(VI) removal by CL-Pb. Zeolite’s modification with Ba and Pb renders it able to immobilize SO42- from water in the pH range 3-9. Kinetics of the uptake process is best described by the pseudo-first order kinetic equation. Increasing the initial concentrations of Mo(VI) and SO42- increases the removed amount of pollutants. INTRODUCTION Wastewater from copper-molybdenum ores processing is often polluted by molybdate and sulfate ions. Molybdenum (Mo) migrates easily in water and consequently the Mo polluted areas could extend for hundreds and thousands of meters (Ryzhenko, 2010). Molybdate anion is the only Mo(VI) species in natural water, i.e. at pH > 6.0. Its median freshwater hazardous concentration affecting 5% of the species (HC 5.50%) is 38.2 mg Mo/L (De-Schamphelaere et al., 2010). The marine water chronic toxicity (HC 5.50%) is assessed at 5.74 mg Mo/L (Heijerick et al., 2012). The predicted no-effect concentrations (PNEC) are 12.7 mg Mo/L and 1.92 mg Mo/L correspondingly for freshwater and marine water (Heijerick et al., 2012a). When sulfates present in drinking water in excess of 250 mg/L they cause a cathartic action (especially in children) in the presence of sodium and magnesium, and when the concentration exceeds 600 mg/L, diarrhea. When sulfate-rich effluents are discharged into the environment, they may increase the acidity of water bodies and soils (Guimarães and Leão, 2014). Because of the adverse effects to human health and the environment, limits are set for SO42- concentrations in waters and wastewaters in the range of 250 / 500 mg/L."

Jan 1, 2018

By M. Bergerman

Sossego was the first Vale SAG mill operation to process copper-gold ore. It is located in Para state, south east of Amazon region in Brazil. The comminution circuit was designed to treat 41 000 metric tons per day comprising primary crushing, one 11.6 m SAG mill operating in closed configuration with cone crushers, followed by two 6.7 ball mills. In the first three years of continuous operation Vale investigated alternatives for obtained improved performance of the circuit by investigating operating conditions, mainly focusing on SAG mill. A number of actions were then implemented, which resulted in significant increase in overall production. Vale then decided to further assess the performance of the comminution circuit as a function of ore characteristics. A comprehensive ore characterization program was then conducted, together with the calibration of mathematical models on the basis of surveys carried out at the industrial circuit. The simulator was then used to predict the production level associated to each ore type, as well as to establish the optimized circuit configuration and tailored operating conditions. The ongoing validation program is planned to consolidate the selected strategy, as well as showing the benefits in adopting such indices in mine planning, as opposed to rather simplistic approaches. This paper describes in detail the main aspects of optimizing the industrial circuit performance, as well as the successful method for predicting the production as a function of ore characteristics.

Jan 1, 2014

By C. A. Acuña

Extensive literature exists on the motion of single bubbles and the behaviour of swarms of bubbles. This contribution describes work to track and reveal the motion of individual bubbles in a swarm. The technique is based on high speed cinematography and tracking of multiple moving objects. Image processing algorithms were implemented in Matlab to isolate and measure geometric proper-ties of the bubbles in image sequences recorded at 2 ms interval; and these properties were compiled into a data structure. To track a bubble, the geometric properties and a matching criterion were applied on consecutive pictures to identify the bubble. The bubble trajectory was reconstructed from the data structure for the matched objects. The methodology is briefly described. The new technique was tested for bubbles produced at slot-type spargers (i.e., approximately 2-D swarms) in the presence of two frother types ('strong' and 'weak'). Two observations are discussed: a) that bubble motion in a swarm describes a velocity-size relationship dictated by the dominant bubble size class; and b) that surfactant type influences bubble rise velocity for bubbles in the range 0.1 mm to 4 mm. The latter suggests surface viscosity rather than surface immobilization determines bubble rise velocity.

Jan 1, 2014

By V. F. Petrov, O. D. Khmelnitskaya, V. M. Lodeischikov

"The processing of copper gold ores is one of the major issues of gold-mining industry in the beginning of 21st century. In this case, application of ammoniacal cyanidation process for this type of mineral raw materials deserves special attention. Irgiredmet Institute has carried out a wide range of studies on ammoniacal cyanidation process and evaluated the possible commercial use of this process for Russian operating plants. Copper gold-bearing ore from a current Russian deposit was studied. The content of gold and copper in the ore is 9.4 g/t and 0.4%, respectively. Based on the results of preliminary test work, a flow sheet was developed. It included gravity concentration followed by cyanidation of the gravity tailings using CIP. The flow sheet provides sufficient total gold recovery (91.5%). However, this technology has disadvantages, such as high specific consumption of reagents: 4.5 kg/t NaCN and 13.5 kg/t Ca(OCl)2 the ore and the increased gold grade in the liquid phase of the tails slurry (0.2 g/t). In order to improve cyanidation process parameters, test work on gravity tails processing using ammoniacal cyanidation was carried out. After the test work was completed, ammoniacal cyanidation flow sheet for copper gold-bearing ores was developed. Leaching conditions were optimized using recycled process solutions. Recommendations on gold recovery from the solutions and tails detoxification are given. The proposed flow sheet provides 91.5% gold recovery. In this case, compared to the conventional option, the consumption of cyanide decreases by 3-4 times.INTRODUCTION The technology of precious metals recovery from gold-bearing ores is based on cyanidation. This accounts for up to 90% gold recovery and the significant portion of silver (Lodeischikov, 1999). However, there exists the category of so called refractory ores. They are not amenable to direct cyanidation (without using additional expensive processes), or they are characterized by low indices of metals recovery and high consumption of reagents. The latter also include copper gold ores. Their deposits can be found extensively both worldwide and in Russian Federation. A feature of these ores is that they contain not only gold but also copper. It is considered not only as a valuable component but also as a harmful mineral impurity that hinders gold cyanidation, gold precipitation from the solutions by cementation onto zinc dust and adsorption onto activated carbon (CIL, CIP-processes), detoxification of cyanide bearing effluents."

Jan 1, 2018

By Katja Ohenoja

Polymer dispersants, also known as grinding aids, are widely used to reduce the viscosity of mineral particle suspensions and to improve energy efficiency during fine grinding. In this study, the effect of polymer dispersant with different molecular structure on the suspension properties in the wet stirred media milling of limestone was studied. The stability of suspension was studied by combining rheological and zeta potential measurements. The PDI value of polymers corresponds to the width of the molecular weight distribution so that low PDI corresponds to narrow MW distribution and high PDI to the wide one. In this study, two traditionally fractionated polymer dispersants with high PDI (over 2) and one novel polymer dispersant with low PDI (1.2) has been tested. It was noticed that dispersants worked as electrosteric stabilizators and prevented the agglomeration of ground limestone particles. The uses of dispersants could increase solids concentration used in the grinding experiments and at the same time lower the particle size and specific energy consumption. The obtained particle sizes were about 1 µm regardless of which dispersant was used or the amount of it. The novel dispersant with low PDI reduced viscosity most when compared with the traditionally fractionated polymer dispersants. Results indicated that even higher solids concentrations can be used at the same amount of dispersant when the novel low PDI polymer dispersant is used. Alternatively, lower dosage of novel low PDI dispersant can be used compared to traditionally fractionated dispersants.

Sep 1, 2012

By Jia Muxin

The adsorption behaviors of metal ions on a silicate mineral and the flotability of a metalized silicate mineral with sodium oleate as collector are closely related to the structure of the silicate mineral. The adsorption isothermals of the metal ions on different silicate minerals are studied, the parameters of the isothermal give the information how many surface oxygen anions a metal ions is attached to, from this information and the structure of the mineral the site where a metal ion is attached can be guessed (The adsorption isothermals and adsorption behaviors with pH are fitted with Temkin, Frenudlich and Kurbatov equations respectively). Metal ions as Cu2+, Ni2+, Zn2+ are attached to the oxygen anions of surface species –Si-O– on the quartz surface, most of them coordinate to only one surface oxygen, their adsorption ability on quartz is low, but this metal ions on quartz surface protrude out of the surface perfectly, so their ability to combine with oleate acid radical is excellent. Quartz can be activated well by such metal ions. The isothermal of Fe3+ on quartz indicates these cations coordinates with more than two surface oxygen anions. This means the Fe3+ nucleates on quartz surface in the form of Fe(OH)3 colloid particles. The isothermals of Cu2+, Ni2+, Zn2+ Fe3+ on spodumene shows such ions coordinate with more than two surface oxygen anions, it indicate these ions may attach to the position where Li+ is formerly exists, such metal ions stay in a cave on the mineral surface, their adsorption abilities on spodumene are quite well, but they are affect by the oxygen anions of the two Si tetrahedron chains, the can almost not activate this mineral. These cations may attach on the site where Al3+ exists on the muscovite surface, just like spodumene, muscovite can not be activated well by such cations. Pt2+ has a large ion radius, as Pauling’s rules depicts polyhedron can not attach to Si tetrahedron well, the adsorption ability of Pt2+ on quartz is low and quartz is activated badly by Pt2+. On the other Pt2+ can adsorb well on spodumene and muscovite well and activated them well because it is not affected so bad by the tetrahedron oxygen anions of the minerals for their its large radius. The isothermal of Ca2+ on quartz indicates a Ca2+ coordinates with less than one surface oxygen anion, this means Ca2+ attaches on quartz mainly by physical adsorption. The adsorption abilities on mineral surface and the interaction abilities with oleate acid radical of the transition metal ions with the same valence are guessed to be determined by their d electron number, the rules should be d1<d2<d3<d4>d5<d6<d7<d8<d9>d10. Hydrogen bond may play an important rule in the activation of the mineral by HF and the interaction of the HF activated silicate mineral with collectors. The general rule is high bond valence and small metal ion radius surface species –Me-O can be activated well by HF with sodium oleate as collector. For example – SiIV-OH is neutral while –SiIV-FH+ and –SiVI-FH+0.33 are positively charged, the positively charged surface species are more likely to connect oleate acid radical via hydrogen bonds.

Jan 1, 2003