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By W. S. Dyer

Introduction In northern Ontario, refractory clay is found on four rivers of the James Bay watershed: the Abitibi, the Mattagami, the Missinaibi, and the Moose. The clay all belongs to the same geological formation ( the Mattagami of Lower Cretaceous age) , and occurs within a structural depression or 'basin', the boundaries of which have never been defined but which appears to cover at least 1,500 square miles of territory. The recently constructed James Bay extension of the Temiskaming and Northern Ontario railway crosses the northeast end of the basin at the Onakawana lignite field, which by rail is 126 miles north of Cochrane, 605 miles north of Toronto, and 60 miles southwest of Moose Factory. Smoky Falls, the northern terminus of the railway owned by the Spruce Falls Power & Paper Company, Limited, is 7 miles south of one other point in the basin, i.e., the outcrops of refractory clay, sand, and kaolin at the foot of Long rapids on the Mattagami river. Smoky Falls is 50 miles north of Kapuskasing. In a very early report(l) , Dr. Robert Bell, of the Geological Survey of Canada, described '"light coloured marl in horizontal beds" from the Missinaibi river, and noted that the lignite also occurring in the river was probably :associated with the marls. This was undoubtedly the Cretaceous refractory day. Other early writers noted the occurrence of fire-clays, but it was not until Joseph Keele(2), of the Geological Survey, visited thee region in 1919 and studied the clays that their real significance was known.

Jan 1, 1933

By D. Maddocks

"IntroductionThe greater part of the iron ore industry in Canada is located along the Labrador-Quebec border on a geological formation known as the Labrador trough. The Labrador trough is a 700 · mile long geosynclinal segment composed of folded and faulted Proterozoic sediments, volcanics and intrusives, extending from Gagnon, Quebec, to the north west tip of Ungava Bay. This geosyncline can be divided into three parts (Fig. 1).The northern unmined part, extending from southern to northern Ungava Bay, is a low grade metamorphosed iron formation.The iron deposits of the central region, represented by Schefferville, are hematite-limonite ores formed by oxidation and leaching of an unmetamorphosed taconite formation. Average iron content of the ore is greater than 540Jo for direct shipping and 50% for plant feed.The deposits of the southern section (Carol Lake, Wabush, Mt. Wright, Gagnon) extend from just north of Carol Lake to Gagnon and is a metamorphosed silica-iron oxide (specular hematite and magnetite) formation averaging plus 30% iron.The mineral wealth of this area was first observed by Father Louis Babel about 1870 and again by Dr. A.P. Low of the Geological Survey of Canada in 1894. However, the remote location hindered development until after 1945. First production of direct shipping ore from Schefferville was in 1954. Production at Carol Lake commenced in 1962.This area now accounts for sixty million long tons (61 Mt) per year of processed iron ore products as follows:This chapter will concentrate on pelletizing and agglomeration as experienced at the Iron Ore Company's Carol Lake operation. However, whenever possible, reference will be made to alternate methods, procedures, equipment, etc."

Jan 1, 1989

By V. Songmene, A. Tahan, J. P. Michaud

The machining of thin wall parts, often used in the aeronautical industry still creates a number of problems, including panel deformation. Quality and productivity are often affected. This study seeks to determine the optimal conditions for cutting in order to guarantee a competitive fabrication of parts while still maintaining quality and delivery deadlines. The studied model (Spar) is a typical structural part used in the assembly of airplane wings. The main objective of this study was to improve two performance aspects: surface quality finish (quality criteria) and the rate of cutting by stock removal (economic criteria). To achieve this objective, we used an evaluation process of the geometrical error issuing from the machine-tool. We also determined the stability zones of the machine-tool's dynamic system. Finally, a series of high-speed machining tests (finishing cuts) were conducted using an experimental structured approach (16 000 - 24 000 rpm). Profile measures of surface roughness and cycle times registered during trials allowed us to establish optimal cutting conditions. Surface roughness improved as well as cutting by stock removal. Four parameters were taken into consideration: axial depth of cut, chip load, spindle speed, and cutting fluid. Finally, the influence of the type of cutting fluid was evaluated to show that it did not significantly affect machining results.

Jan 1, 2006

By M. Barati

A collaborative research between University of Toronto and Hatch was conducted to understand and optimize the process conditions pertaining to a novel steelmaking technology. In this technology, known as CRISP, direct reduced iron is continuously melted and refined in a stationary electric arc furnace. The major challenge against continuous operation of the electric furnace was identified to be minimizing the corrosion of the refractory in order to achieve uninterrupted operation for a minimum of one year. Theoretical analysis and bench scale experiments together with two pilot runs resulted in defining an operating window for slag chemistry that would minimize chemical attack to the refractory while satisfying the oxidizing conditions required for sufficient decarburization. An analysis of the process in terms of energy consumption and emission of greenhouse gases revealed that it is superior to the current batch DRI-based steelmaking technologies.

Jan 1, 2011

By Matt Manson

Diamonds in Canada: Recent Advances in Exploration Methodology and Advanced Stage Assessment 1. Exploration Methodologies ? Prospectivity Mapping ? Surficial Geochemistry ? Geophysics 2. Advanced Stage Assessment ? Petrology and Diamond Paragenesis ? Micro/Macro ratios and Macro grades ? Value Sampling and Modeling

Apr 1, 2005

By R. Noorani, M. Cai

"Excavation of deep underground openings in highly stressed grounds can generate new fractures near the openings. As a result, rock mass bulking may occur, leading to large wall deformation. A better understanding of brittle rock failure and the associated fracturing process at the laboratory scale is an essential step towards evaluating dilation behavior of rocks. A grain-based model that can capture dilation behavior of rocks under various loading conditions at the laboratory scale can be a useful approach to study rock mass bulking at the field scale. The aim of the paper is to study the dilation behavior of rocks at the laboratory scale employing numerical simulation. A modified grain-based model is used to simulate the macroscopic response of crystalline rocks by considering micro-fractures at the grain scale. Grains generated with the Voronoi tessellation are allowed to fail in tension or in shear using a strain-softening model. Damage is represented by either grain boundary fracture or grain failure, or the combination of the two. As stress increases, the process of damage, fracture initiation and coalescence in rocks can be captured.The grain-based model was calibrated using test data of the Lac du Bonnet granite and a parametric study was conducted. Numerical simulation results showed that the proposed modeling approach is able to capture most of the mechanical properties, fracture pattern, and dilation behavior in both unconfined and confined loading conditions. In an unconfined compression test, interactions of microscopic fractures may lead to macroscopic shear or axial splitting failure depending on the chosen micromechanical parameters. Numerical experimental results show that the dilation behavior of the model is strongly related to the failure mechanism of rocks. Tensile-failure-dominated failure mode generates large dilation due to the formation of new cracks that are sub-parallel to the loading direction. On the other hand, shear-failure-dominated failure mode produces small volume increase. One significant finding from this study is that in order to capture large dilation using grain-based UDEC models, intragranular grain failure should be considered."

Jan 1, 2015

By Xiang-dong and Zhu, Xia-jie Hao, Yi-lin Fan, Quan Jiang, Lian-xing Hu, Xia-Ting Feng, Shao-jun Li

"Columnar jointed basalt (CJB), which typically originates from lava flows, is characterized by a special geological structure. The joint network inside the CJB is self-organized into a rough hexagonal arrangement. The field test and measurement during the unloading excavation showed that the columnar joint sets and other internal joint sets not only are important for determining the mechanical properties of the CJB, but also induced its asymmetric unloading deformation and failure. A constitutive model, which considered mechanical deterioration of both the joint sets and rock blocks, was also developed to simulate the unloading behaviour of the CJB. The crack-confinement supporting method for surrounding CJB was developed to overcome the failure of columnar jointed rock mass in the diversion tunnel. Application to the CJB segments of the diversion tunnels in the Baihetan project indicated that this supporting method was reasonable and efficient. INTRODUCTIONColumnar jointed basalt (CJB) rock mass, which typically originates from lava flow, is characterized by a special joint structure. The joint network of the CJB is self-organized into a roughly hexagonal arrangement and leaves behind an ordered colonnade. The widely accepted current view regarding the formation of columnar jointing involves a thermally induced contraction–cooling mechanism (Peck and Minakami, 1968; Degraff and Aydin, 1987; Budkewitsch and Robin, 1994; Lore et al., 2000; Goehring et al., 2006). Although the columnar basalt formation mechanism is fairly understood, the geotechnical characteristics of such rock mass are not well established. In practice, joint sets always induce the multi- failure modes of surrounding rock in the tunneling space (Ibarra et al., 1996; Waltham and Swift, 2004; Mahendra and Bhawani, 2008).According to conventional wisdom in rock mechanics, structural joints affect the mechanical response of rock mass by introducing strong anisotropic effects (Barton and Bandis, 1980; Hudson and Priest, 1983; Brady and Brown, 1985). The columnar jointed rock mass should be considered an anisotropic material given that the joint sets are distributed with some principal directions and characteristic spacing distributions (Cundall and Fairhurst, 1987; Hoek et al., 1998; Wu and Wang, 2001; Budetta and Nappi, 2011; Fortsakis et al.,2012). Columnar jointed rock mass would result in structurally controlled failure patterns, even serious disasters during underground excavation because of the low shear and tensile strengths of intensely joints (Gencer,1985 ;Ishida and Uchita, 2000; Jia and Tang, 2008). The CJB rock mass in the Baihetan hydropower station has exhibited serious stability issues, including sliding, fracturing and even collapse (Shi et al.,2008). Therefore, the geotechnical and geomechanical characteristics of such rock mass should be assessed through in situ investigation and numerical analysis to minimize future accidents during underground unloading excavation."

Jan 1, 2015

By K. El-Ouassiti, M. Zouadi, C. Bazin, D. Hodouin

Data reconciliation techniques are used to attenuate the effect of measurement errors and estimate unmeasured variables. This paper illustrates the application of data reconciliation to hydrometallurgy processes using measurements from leaching and solvent extraction obtained from laboratory experiments. The application of data reconciliation provides an efficient way to detect gross and systematic errors and produces reliable performance indices for process evaluation.

Jan 1, 2005

By A. L. Mular

Some specific cases of the collection of data from industrial grinding and classifying operations, and the development of models from the data so obtained, will be described. The problems encountered, the effort involved, and the value of the derived models in improving the plant efficiencies will be discussed and documented where possible.

Jan 1, 1971

By A. -M. Lafront

The corrosion resistance of die-cast and freely-solidified and electromagnetically-stirred thixocast AZ91D alloy has been studied using electrochemical noise technique in a 0.05M NaCI solution at pH 6.1 and 25°C. Specimens polished at different depths were immersed for a period of 75 min in order to assess the influence of the microstructure on corrosion kinetics and morphology. At depths between 10 and 50 µm (skin), all specimens showed general non-uniform corrosion with the lowest corrosion resistance. Between 100 and 200 µmn (interior skin), the observed corrosion was accompanied by superficial undefined pits due to metastable pitting. The corrosion form for 100-200 µm gave the best corrosion resistance. Stable pitting corrosion was observed beyond 400 µm deep on the bulk specimens. The skin of all thixocast specimens prepared billets showed a more corroded surface than that of die-cast. The interior skin as well as the bulk specimens showed better performance than that of the die-cast specimens.

Jan 1, 2007

By M. Krasowska, K. Malysa, M. Krzan

The paper presents fascinating, in our opinion, observations on mechanism and course of processes occurring during bubble collision with hydrophobic and hydrophilic solid surface. Hydrophobicity of particle surface is a necessary condition for the particle attachment to bubble. We have observed that even in the case of such hydrophobic solid surface as Teflon, the bubble attachment didn't occur at first collision. In distilled water the bubble bounced a few times without attachment. Influence of a-terpineol and n¬pentanol on bubble local and terminal velocity and the phenomena occurring during bubble collisions with hydrophobic and hydrophilic solid surfaces was studied. Bubble collisions with the solid surfaces were monitored and recorded using the high-speed (1182 frames per second) camera. It was found that in distilled water the velocity variations of the "approach-bounce" cycles were identical for Teflon and glass. Four distinct "approach-bounce" cycles were detected both at Teflon and glass surfaces. Moreover, the amplitude and frequency of the velocity variations were identical on collisions with the hydrophobic (polished) and hydrophilic surface. There was no immediate three phase contact formation, with the hydrophobic Teflon surface, what we found really astonishing. Roughness of Teflon surface seems to be important parameter, which affects probability of the bubble attachment as a result of a presence of micro-and/or nano-bubbles at the surface. It was detected that the presence of the micro-bubble affected attachment of the colliding bubble even in distilled water. Presence of a small amount of a-terpineol or n-pentanol affects dramatically the bubble velocity, but their role in mechanism of the bubble attachment needs further study.

Jan 1, 2004

By François Robert, Rex Brommecker, Don S. Bubar

"The Orenada Zone 4 deposit is a small vein-type gold deposit occurring directly within the Cadillac Break southeast of Val d' Or in southeastern Abitibi Sub province. Mineralization is hosted by the Piche Group which, on the Orenada property, consists of talcchlorite- carbonate, chlorite-carbonate, and sericite-chlorite schists, derived from ultramafic volcanic, mafic igneous, and intermediate to felsic volcaniclastic rocks, respectively. All these rocks have been carbonatized.Rocks of the Pichi Group display a strong east-west, subvertical S1foliation, which is superimposed by asymmetric, intrafolial F2folds with shallow to moderate plunge to the east and to the west. F2folds are accompanied by an S2, subvertical axial planar cleavage, and are interpreted to result from dextral transcurrent shearing along sr.The Zone 4 deposit occurs within a large F2 fold, 60 m wide and plunging at 45 to the east, down to a depth of at least 300m. The auriferous zones consist essentially of zones of closely spaced, parallel quartz-tourmaline-albite-carbonate-arsenopyrite veins concordant to Sr these veins have been folded by the large F2fold and may pre-date the folding. A few discordant quartz-tourmaline-arsenopyrite veins, post- dating the F2 folding, also contain gold. Wallrocks adjacent to concordant veins have been carbonatized, albitized and contain significant amounts of tourmaline and arsenopyrite, with which gold is intimately associated.The Orenada Zone 4 deposit is a unique example of a deformed vein- type gold deposit, and exemplifies one of several types of association of lode gold deposits with folds."

Jan 1, 1990

By W. A. Lang

"IntroductionCARBONIZATION, gasification, and chemical utilization of coal are interrelated topics, which makes it difficult to review one without indicating its connection with the others. Hence, in Progress in Coal Technology, Series No. 5: Carbonization, reference was made to gaseous products recovered in the carbonization of coal, and .to a number of chemicals made from the tars, light oils, and ammoniacal liquors which are by-products of coal carbonization.In this, the sixth paper in the review series, prime consideration will be given to the complete gasification of coal to give a fuel for domestic industrial, or power purposes and a synthesis gas suitable for the manufacture of gasoline, Diesel oil, and chemicals. The hydrogenation of coal, an alternative source of liquid fuels and of chemicals, will be reviewed, as will be a number of processes for •the recovery of chemical products from coal by extraction and chemical treatment."

Jan 1, 1952

By Sylvie Lévesque, Cory Hennessey, Daniel Amariei

"In the iron ore industry, fine particles recovery is an important concern in terms of process performance and production costs. Continuous efforts are thus devoted to increase the efficiency in handling these fines.The Reflux Classifier (RC) is a relatively new technology that is mainly used in the coal and industrial minerals industries. The operating principle of this system is based on three mechanisms: hindered settling, autogenous dense medium and lamella settling. A preliminary evaluation of the Reflux Classifier technology for the beneficiation of iron ore fines was formerly done at the pilot scale using a RCTM300 unit. The good results obtained, using iron ore fines from screened spiral stream, made this technology very attractive for the iron industry. However, the high capacity of the RCTM300 unit (1–3 t/h), makes it unsuitable for R&D purposes. Thus, a smaller unit, the RCTM100, was assessed to validate the performances obtained with the RCTM300.This paper summarizes the performances obtained with the RCTM100. The challenges of the scale-down related to the adaptability of this technology to the iron ore industry are also presented. The results are compared to the RCTM300 performances, as well as benchmarked against sink-float tests. The metallurgical results on feed and products issued after the test work with the RCTM100 unit are supported by mineralogical characterization using a Mineral Liberation Analyzer.INTRODUCTIONFine particles recovery by physical separation means is a historical concern (Holland-Batt, 1992; Peukert and Wadenpohl, 2001; Srivastavaa et al., 2001; Majumder et al., 2003). Attempts to improve fine particle recovery at the laboratory, pilot and industrial scales adopting different strategies with traditional equipment or assessing new promising devices such as the MGS (multi-gravity separator), the Kelsey jig, the Yang jig, etc. (Kim, 2002; Goudreau, 2008; Kerr, 2012) have yielded variable success."

Jan 1, 2016

By Orlando Rojas, Javier Pizarro, Romke Kuyvenhoven, Francisco Soto

"The concept of geometallurgy has been extensively mentioned and used in the mining industry in the past years. However, each mining firm has a different understanding of what geometallurgy means, and its actual value varies significantly from site to site. Even in the case of properly constructed geometallurgical models, it is fairly common to observe a sub-utilization of the model in the actual operation, because of its low production forecasting capability on the short term. This disconnect between the geometallurgical model and operations is typically caused by a lack of tuning between the original model and the actual plant operation. Also, the absence of procedures and other standards for reconciliation, affects the confidence and the predictive quality of the model. The geometallurgical model should consist of three different levels: (I) adequate capture of information, (II) data analysis and modelling, and (III) development of the block model. Once the geometallurgical in-situ model is finalized, a process model should be developed of the plant at industrial scale, in order to scale up the in-situ geometallurgical parameters from their base or standard condition, to the actual operating reality of the plant. Finally, the stage of reconciliation will close this process, assuring that any deviation between the geometallurgical model and the actual plant operation is not due to lack of tuning, but due to operational issues such as unattended maintenance requirements or poor process control in the operation. The methodology as described in this paper has been applied at several large mining sites in Chile. The paper presents the characteristics of the proposed methodology, and quantitatively describes its benefits with examples from actual operations.INTRODUCTIONIt probably is fair to say that geometallurgy became widely used in greenfield projects in the Andes region during the mining boom of the 90’s, when massive orebodies were studied and developed, and upfront metallurgical characterisation proved its use for accurate economic evaluation including estimates of plant throughput, energy consumption, final product quality and overall recovery. A few examples of such greenfield studies for concentrator plants in the 90’s are Minera Los Pelambres (Antofagasta Minerals, Chile), Minera Escondida, Laguna Seca (BHP Billiton, Chile), and Rio Blanco (then Montterrico Metals, Peru). Large size hydrometallurgical operations such as Cerro Colorado, Quebrada Blanca and Lomas Bayas (all in Chile), also recognised early on the importance and value of relating ore mineralogy, geological characterisation and metallurgical behaviour."

Jan 1, 2016

By 000-900-009-492

The flotation has been and is still the most widely used mineral concentration method. Because of its complexity, the flotation process required the development of robust control strategies which was facilitated by the introduction of on-line sensing instruments such as x-ray fluorescence (XRF) on stream analyzer (OSA), gamma density gauges and electromagnetic flowmeters. The interest in developing control strategies has persisted because the benefits to be gained in terms of improved metallurgical performance are substantial. As the flotation control becomes more and more difficult due to the emergence of low grade and complex ore cases, other control strategies have to be introduced. Froth based control is one of the emerging useful control strategy This paper will focus on the state of the art in the on-line froth characterization as obtained by numerical image analysis. The technology of machine vision provides a novel solution to several of the problems encountered in conventional flotation systems for monitoring and control, and constitutes a powerful tool for the investigation and interpretation of the effect of various flotation parameters as driven for the froth phases. Copyright @2001CIM

May 1, 2001

By R. G. Achter, E. Wilson

"This paper describes the work undertaken to renovate the Pipe Open Pit drainage system, incorporating measures to improve effluent quality. It describes the technical feat of drilling an l l-inch-diameter hole from the bottom of the open pit for a distance of 1100feet to intersect an underground drift. An innovative method of checking the inclination of this hole is also described. The paper outlines the construction required on the 1500-foot level of the underground mine to facilitate water impoundment and slime settling, as well as the instrumentation for control of water flows. IntroductionThe Manitoba Division of Inco Metals Company operates two mines-an underground mine at Thompson and an open pit at Pipe. The Pipe Open Pit is located 20 miles southwest of the City of Thompson, approximately 400 miles due north of Win nipeg(Fig. 1).Surface diamond drilling of the Pipe ore body was sta rted in 1959. In 1961, a shaft was sunk to a depth o f 1,570 feet to carry out further exploration work and obtain bulk ore samples for metallurgical testing. Site preparation to mine the upper portion of the orebody as an open pit was initiated in 1966 and by late 1967, the removal of silt and clay overburden was in progress. The contractor completed the dredging in the fall of 1969. Over 12 million cubic yards of muskeg, clay and silt was removed, which in some places was 150 feet deep over the orebody. Production began in early 1971, by which time the top three benches of rock had been excavated and the orebody exposed.The Pipe No. 2 Mine main shaft was started in 1970 and completed in 1973 at a depth of 3,160 feet. Development for exploration purposes was carried out on the 1500 and 2460 levels, and permanent pumping facilities were installed.The surface dimensions of the open pit are 2,200 by 1,600 feet, with the long axis striking northeast. The walls are designed with a 45- to 50-degree slope and the ultimate design depth is 720 feet. The present depth of the pit is 520 feet and production capacity is 6,800 tons of ore per mine day."

Jan 1, 1980

By J. A. Morgan, P. M. Dimmell

Abstract - The Aubry pegmatites are located on the Seymour Lake property, 15 km north of Lake Nipigon in northwestern Ontario. The property lies within the Caribou Lake-Marshall Lake greenstone belt along the English River-Wabigoon subprovince boundary of the Superior province of the Canadian Shield. The property was optioned in March 2001 by Linear Resources (now Linear Gold Corp.), who carried out gridding, prospecting, geological mapping, soil and lithogeochemical sampling, trenching, channel sampling, and a total of 1,866 m of diamond drilling in 32 holes. The Aubry pegmatites are classified by Breaks et al. (2003) as complex type, spodumene-subtype, lithium-cesium-tantalum pegmatites (Cerný, 1989). These pegmatites generally form under high-pressure-low-temperature conditions, display complex internal zoning, have relatively low Nb/Ta ratios in the ore-forming assemblages, and contain significantly elevated tantalum values (Cerný, 1989). Other examples of spodumene-subtype pegmatites include the formerly producing Hugo pegmatite in South Dakota, and the currently producing Greenbushes pegmatite in Australia. The Aubry pegmatites occur as an undulating system of stacked sheets that dip moderately to steeply eastward over a 1-km strike length. The main portion of the North Aubry pegmatite ranges in true thickness from 10 to 28 m over a strike length of 125 m, whereas the thickest portion of the South Aubry has an estimated true thickness of 15 to 16 m over a minimum strike length of 95 m. The North Aubry pegmatite remains open downdip and along strike to the north, whereas the South Aubry pegmatite remains open downdip and along strike in both directions. The Aubry pegmatites are among the most highly evolved in Ontario, with the southern end of the North Aubry (trench 5/6 area) being the most highly fractionated (Breaks et al., 2002). Channel samples from the trench NA-5 area of the North Aubry pegmatite produced values up to 2.49 wt.% Ta2O5 over 4 m. Coarse manganotantalite crystals, up to 5 cm in diameter, from this trench contain up to 84.9 wt.% Ta2O5 (Breaks et al., 2002). Drill hole SL02-31 in the trench NA-6 area gave values of 0.046 wt.% Ta2O5 over 17.7 m, including 1 m @ 0.464 wt.% Ta2O5. Further exploration will focus on defining the grade of the North Aubry zone, extending and defining both known pegmatites, and identifying additional Ta-rich zones within them. Lithogeochemical and enzyme leach soil geochemical data suggest the presence of multiple undiscovered pegmatites on the property.

Jan 1, 2005

By J. E. Dutrizac, Alba Sunyer

The factors affecting the precipitation of arsenic-free alunite (KAl3(SO4)2(OH)6) were investigated in a series of laboratory experiments. Although the amount of alunite precipitated increased with increasing retention time, temperature, solution pH and the concentrations of Al(SO4)1.5 or K2SO4, the composition of the products remained nearly constant. The preferred conditions identified for the precipitation of arsenic-free alunite were then used to assess the behaviour As(III) and As(V) during alunite precipitation at 98°C. Increasing additions of As(III), as NaAsO2 or As2O3, resulted in a slight increase in the amount of precipitate formed at pH 2.80. However, X-ray diffraction analysis showed all the precipitates to be alunite, and <0.2% As(III) was detected in the products. In contrast, increasing additions of As(V), as KH2AsO4 or As2O5, resulted in significant increases in the amount of precipitate formed at pH 2.80 or 3.00. Furthermore, the arsenate (AsO43-) contents of the precipitates increased up to 15%, and the sulphate contents decreased, as the As(V) concentration of the synthesis solution increased from 0 to 9 g/L. X-ray diffraction analysis of the products detected only alunite, but there was a progressive expansion of the alunite cell with increasing arsenate content. The implication is that arsenate substitutes for sulphate in the alunite structure. Preliminary observations on the environmental stability of the arsenate-bearing alunite using the TCLP protocol gave solubilities <0.4 mg/L from a precipitate containing 8.5% AsO4 and 7.8 mg/L from a product containing 19.5% AsO4. Thus, it appears that alunites containing less than -10% AsO4 would be an acceptable vehicle for the disposal of arsenic from hydrometallurgical processing solutions.

Jan 1, 2011

By M. J. Merwin

Heat treated seamless tubular products are processed in a fashion that can be easily modified to produce dual phase microstructures, through the implementation of intercritical soaking prior to quenching. Dual phase steels are known to possess low yield strength compared to tensile strength. The steel line pipe market is interested in low yield-tensile ratio materials for application in reel barge pipe laying operations. In the current work compositions of commercially produced material already in use for the line pipe market were examined and dual phase microstructures were successfully developed. The microstructure and properties of the materials were found to be stable over the range of intercritical temperatures employed. Tempering temperature and, somewhat unexpectedly, small chemistry differences were found to have the largest influence on properties. Excellent toughness performance was observed in samples tempered at temperatures in excess of 550°C. Tempering in this temperature regime produced materials with strength suitable for application as API X60 line pipe. A difference in tensile strength between steels of similar chemistry was observed, and is not fully understood at this time. Welding performance was considered through simulation of three regions of the heat-affected zone. Neither intercritical temperature, nor tempering temperature, were found to have a significant influence on the heat-affected zone properties. The peak temperature achieved in the thermal cycle was the only significant factor. The hardness of the heat-affected zone was found to increase continuously with increasing peak temperature. While toughness was found to be low for both partially-transformed and coarse-grain heat-affected zones, the toughness of the fine-grained heat-affected zone was substantially better. Based on the results found in this laboratory study, a limited production trial is expected.

Jan 1, 2005