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By Peter Silveston, Earl Shannon

Process-oriented experiments on the use of coal as an adsorbent for certain soluble components of sewage are described. The capacity of Canadian coals for these components was less than 0.1 per cent by weight for the highest concentration at which these components could be expected to be found in domestic sewage. This is much less than values reported in the past. A pronounced selectivity between components was observed. Experiments on bacteria removal in beds of coal, regeneration of spent coal to restore adsorption capacity and COD contributions of coal are reported in the paper. The simple application of coal as an adsorbent does not seem promising.

Jan 1, 1970

By W. L. Murphy

The Star Lake property, located 115 km northeast of La Ronge, Saskatchewan is underlain by metamorphosed andesitic tuffs and flows which have been intruded by the dioritic to granitic Star Lake Pluton. Gold mineralization on the Star Lake property was first discovered at Ru h Lake by E. Beveridge in 1959 and by M. and E. Hird in 1961. In 1960 E. Partridge discovered Kahn 18 and Kahn 28. In 1982 the SMDC-Starrex joint venture completed geophysical and geochemical urveys including magnetics, VLF, IP/Resistivity, vegetation, bulk till and oil sampling, followed by drill testing of pecific targets. To date the most ignificant depo it is the 21 Zone which contain drill indicated reserves of 230,000 tons grading 0.5 oz/ton Au . The 21 Zone con ists of quartz with 5-10% (locally > 30%) drusy pyrite, minor chalcopyrite and trace amounts of scheelite, chalcocite and arsenopyrite. The 21 Zone is enclosed by a 25-50 m wide band of mylonitized monzonite. The mylonite occurs in the central portion of a 300 m wide northeasterly trending zone of brittle deformation .

Jan 1, 1986

By H. Fujihara, K. Uesugi, H. Toda, A. Takeuchi, K. Shimizu

"Hydrogen is trapped at a variety of microstructures, for example grain boundaries, dislocations and particles. It is thought that hydrogen trapped at trapping sites is redistributed to the other sites under loading and then brittle fracture occurs with hydrogen accumulation. In order to understand hydrogen embrittlement behavior, it is necessary to investigate the time evolution behavior of hydrogen accumulation at each trap site. In the present study, changes in hydrogen distribution are observed under stress using Kelvin force microscopy (KFM) that can visualize hydrogen concentration distribution on material surface at high resolution. Spot-like hydrogen enriched regions are observed on the surface of a material. In addition, hydrogen depleted regions are observed around those enriched regions, and the appearance of hydrogen trap due to particles existing near the material surface is revealed. On the other hand, hydrogen trapped at grain boundary can be visualized. From in this result, it was suggested that crystallographic factors influence hydrogen accumulation. The relationship between initiation and propagation of intergranular crack and hydrogen accumulation under stress will be discussed.INTRODUCTIONHydrogen present in a metal sometimes has significant effects on various properties. Hydrogen in a metal is trapped at a variety of microstructure, for example dislocations and grain boundaries. Grain boundaries, dislocations and micro pores are the major trap sites in aluminum alloys. Some researchers considered that hydrogen redistribution and accumulation between these trap sites in a material with loading plays an important role in the brittle fracture behavior. In general, in intergranular fracture and quasi-cleavage fracture, the hydrogen trapped at grain boundaries and dislocations contributes to fracture behavior, respectively. Recently some researchers have shown that the ductile fracture in aluminum alloys is resulted from growth and coalescence of hydrogen micro pores. Analysis using first principles calculation indicates that intergranular fracture occurs when hydrogen concentration reaches 20 atom H/nm2ongrain boundary. From this report, it is considered that hydrogen redistributed during deformation accumulates locally in order to cause hydrogen brittle fracture. In order to understand hydrogen embrittlement, it is necessary to investigate the time evolution behavior of hydrogen accumulation at each trap site. In the present study, we evaluate the relationship between hydrogen accumulation behavior and fracture behavior in Al-Zn-Mg based alloys. In-situ observation was made by combining the tensile test with Kelvin force microscope (KFM) that can visualize the hydrogen concentration distribution on the material surface with high resolution. We also investigate the relationship between hydrogen distribution behavior and crystal orientation."

Jan 1, 2018

By Frank W. Cole, Sharanjit S. Dhillonn

A new method has been developed for calculating flowing bottom hole pressure in a gas well, using as a basis the general energy equation. Fundamentally, the method shows that a plot of flowing pressure versus depth for a gas well can be represented as a series of incremental .straight lines, with the accuracy in-creasing as the number of increments increase. It is shown mathematically that for most cases the slope of the flowing pressure versus depth curve is essentially constant, in which case a single calculation based on surface conditions will yield acceptable results. In all cases studied no more than two iterations were required for very good accuracy, and in most cases only one iteration was necessary. Several example calculations are shown and the results are compared to other commonly used methods of calculating bottom hole pressures These examples show that the method provides answers which are at least as accurate as other methods usually used, and results in a considerable reduction in computation time.

Jan 1, 1960

By J. W. Craig

THERE are, broadly speaking, three classes of refractories: acid, basic, and neutral. Fireclay, diaspore, silica, and the sillimanite group of minerals are included in the acid class, which for the most part are not very resistant to basic slags. The neutra! class includes chrome, graphite, and silicon carbide, while most important in the basic class are magnesite and dolomite. Although chrome is a neutral refractory, it has no sharp distinction from magnesitic refractoriness. The two are mineralogically (1) and chemically related, and there is available on the market a complete range of brick from straight chrome to straight magnesite. In many indus trial applications, one. type may be replaced by another. The present paper is confined entirely to such refractories. The following types of basic and neutra! brick, each sold under sorne special trade name, are available for use in Canada: (1) Burned chrome from crude ores (2) Burned chrome from treated ores (3) Chemically bonded (unburned) chrome-magnesite ( 4) Burned chrome-magnesite (5) Chemically bonded ( unburned) magnesite-chrome (6) Chemically bonded (unburned) high-iron magnesite (7) Burned high-iron magnesite (Regular) (8) Burned low-iron magnesite (9) Burned olivine-magnesite (10) Burned magnesitic dolomite-chrome (Magnecon) (11) Chemically bonded magnesitic dolomite-chrome (Magmecom) (12) Dolomitic brick

Jan 1, 1936

By F. E. Senftle

Introduction The usual laboratory methods of uranium analysis are either tedious, time-consuming chemical procedures or elaborate physical methods requiring sensitive equipment. There is thus an urgent need for a method of estimating the uranium content of ore samples by approximate analysis in the field. When a new property is being developed, it is desirable to know, with the least possible delay, the uranium content of channel samples in order to guide the diamond drilling and digging operations. Prospectors, too, require approximate analyses of their hand specimens to evaluate their discoveries. To satisfy the demand for these types of analyses, several field procedures have been tried. Two general plans can be followed. One is fast but will yield only a rough estimate. The other is slightly longer but, if done carefully, will give an assay probably within 10 per cent of the true value. For field operation it is necessary to strip the more accurate laboratory methods of analysis of all refinements because of the limited equipment and skilled techniques at hand. Most of the corrections normally applied, with the exception of that for equilibrium, will not alter the gross analysis to any appreciable extent. When uranium atoms in pitchblende disintegrate, they break down into other radioactive elements, and eventually the number of elements being formed is equal to the number breaking down. The ore is then said to be in equilibrium. Certain geological processes, however, such as leaching, may selectively remove some of these elements and hence reduce the radioactivity of the ore sample. The ore is then said to be out of equilibrium. The field analysis may then be in error by as much as 50 per cent since the apparatus is calibrated with standards that are in equilibrium. However, such a large error due to loss of equilibrium is the exception, and in most cases uncorrected field types of analyr.is are justified.

Jan 1, 1949

By A M. Goodwin

Detailed stratigraphic studies in the Birch-Uchi Lakes area have shown that the volcanic components are arranged in superimposed sequences, or cycles. Each cycle displays a progression from predominantly mafic effusives below to predominantly felsic extrusives above. Sedimentary rocks are preferentially associated with the felsic extrusives. Two volcanic cycles are represented. The average stratigraphic thickness of the volcanic rocks present is 31,000 feet. The original volcanic pile was probably in the order of 40,000 feet thick. The present lithologic composition is estimated to be: mafic volcanic rocks, 60 per cent; felsic volcanic rocks, 27 per cent; sedimentary rocks, 10 per cent; and others, 3 per cent. Gold occurrences are preferentially distributed with respect to the volcanic succession. Of fifty recorded occurrences, thirty-nine are located in the upper felsic division of the lower volcanic cycle; forty are associated with closely interbanded daciterhyolite pyroclastic rocks, andesitic lavas and siliceous sediments. The gold-bearing quartz veins either lie at the contacts of enclosing lithologic units or occupy cross-cutting fractures in one or more adjacent units.

Jan 1, 1965

By H. W. Manley

SULPHUR, like the minerals of coal, iron and petroleum, is one of the essential materials in our modern expanding industrial civilization. Before discussing the salient features of the production of sulphur from the Canadian sour gas, it seems appropriate to outline the historical past and probable future utilization of sulphur. The ancient Greek writer Homer spoke of its "pest-averting sulphur" and the "divine purifying fumigation". Ancient alchemists found sulphur to be a fascinating and baffling material. The discovery of gun powder in the year of 1250, and its application to the art of war a, century later, made sulphur an important commodity in the progress of mankind. The initial manufacture of sulphuric acid in the year of 1736 by the Englishman Joshua Ward, established the basis of a chemical industry that today utilizes 80 per cent of the consumption of elemental sulphur. Commercial production of the chemical soda ash ( N a2C03) discovered in 1787 by the famous Leblanc Process, in-creased international demand for the element sulphur and marks the birthday of the Sicilian sulphur industry.

Jan 1, 1961

By Thom Mambe, Angelo Fernando

The objective of this work was to identify key parameters related to the reduction of the sulphur content in ammonium diuranate (ADU), and the identification of solid products being formed under various operating conditions. A laboratory-scale, continuous ADU precipitation circuit was assembled using a glass reactor vessel immersed in a temperature-controlled water bath. A pre-prepared uranium feed solution was fed continuously using a peristaltic pump. Anhydrous ammonia mixed with compressed air was metered and pumped using a double-headed peristaltic pump. An over-head mixer was used to keep the solids in suspension. The precipitated ADU slurry was removed from the reactor at the same flow rate as the feed solution. The slurry was sampled to generate ADU solids for chemical and physical analysis after four hours of continuous operation to ensure steady-state conditions. The following variables were studied to determine their influence on the sulphur content in the resulting ADU. (a) sulphate:uranium molar ratio in the reactor (1:1, 1:5, 1:10 and 1:20) (b) precipitation pH ( pH 6, 6.5, 6.9, 7.5 and 9) and (c) precipitation temperature (40C and 60C) A total of 18 tests covering the above parameters were conducted, and the results indicated that the sulphur content in the resulting solids was highly dependent on the reaction pH. Out of the pH levels tested, tests completed at pH 6.9 and 7.5 generated solids containing the lowest sulphur contents, between 0.5 to 1.5% S uranium basis (UB). The sulphur content in solids was found to vary linearly with the sulphate:uranium ratio in the feed solution, showing a statistically valid correlation. The impact of temperature was minor between 40°C and 60°C, with a slight advantage at higher temperatures. Tests at a sulphate:uranium ratio of 1:1 produced solids with the lowest sulphur contents. The influence of pH or temperature on sulphur content in solids was almost non-existent at this sulphate:uranium ratio. Precipitation pH is the major factor influencing ADU sulphur content, followed by the uranium to sulphate ratio.

Jan 1, 2020

By Gilles Bonin

Structures and serpentinization patterns in the Thetford Mines peridotites are important characteristics indicating the necessary geological conditions which led to the development of chrysotile orebodies in Early Ordovician limes. These structures and serpentinization patterns are reviewed in this paper using the geology of LAB Chrysotile orebodies as a model. Structural aspects include parallel and transverse faults, parallel and transverse granite slabs, and orebodies, some of which trend clearly north-westward parallel to the accretionarymovement. Serpentinization patterns in the peridotite belt, particularly in the harzburgite, include primary pervasive mass serpentinization and secondary complete serpentinization. Listwaenites layers appeared along some faults and along some granite slabs as a result of hydrothermal alteration of the serpentine, following the emplacement of the devonian plutons to the south. These plutons as we/1 as other important lineaments, align with the structural pattern of Thetford Mines ophiolites. It is believed that these plutons are part of a heavy magma tic corridor resembling the Pilote-Mont-Louis corridor in the Gaspe (Doyon and Berger, 1997), and the Buchans' structure in Newfoundland (Hutchinson, 1984), both intersecting the Brompton-Baie Verte line.

Jan 1, 2001

By H. L. Noblitt, Pauline Moyd, Louis Moyd

The deposit, which forms a ridge -adjacent to the York river, in Mont-eagle township, is held by Monteagle Minerals Limited, of Toronto. The ore is in a Precambrian gneiss which is composed of nepheline, scapolite, andesine and microcline feldspars, muscovite and biotite micas, and -corundum. The major orebody is tabular and is exposed for 1,200 feet along the crest of the ridge. It aver-ages about 90 feet in thickness, dips at about 70°, and was intersected by drilling at a vertical depth of 600 feet. The deposit was prospected for corundum in the early 1900's. Recent exploration was undertaken to deter-mine its potential as a source of high-alumina ceramic material, with by-product corundum and white mica. The program included prospecting, mapping, trenching, diamond drilling, bulk sampling, beneficiation research, a large-scale beneficiation test, product evaluation, market investigations, and plant design. Reserves, to a depth of about 300 feet, are estimated at about 3 million tons.

Jan 1, 1962

Slurry flow, including flow through the charge, through the discharge grates, along the pulp lifters and its discharge from the mill is an important contributor to the efficiency of the grinding process within a SAG mill. Poor transport of finer ground material can adversely affect grinding leading to excess energy consumption and over-grinding of fine material. This paper extends a 1-way coupled DEM-SPH method to three dimensions and applies it to a 1.8 m diameter by 0.6 m long AG/SAG pilot mill. This provides detailed information on the internal flow of slurry within a SAG mill, including the prediction of dry regions and of slurry pooling. Full 3D analysis also allows the pulp flow patterns into and out of the mill via pulp lifter chamber to be investigated.

Jan 1, 2012

By L. R. Hougen

The Falconbridge Matte Leach Process yields high-purity nickel chloride by selectively dissolving nickel from copper-nickel converter matte with hydrochloric acid , purifying the solution by solvent extraction and crystallizing NiCl2 4H2O by further acidifying the purified leach liquor. In the Kristiansand Matte Leach Plant, a granular oxide is produced by high-temperature hydrolysis of the nickel chloride for subsequent reduction to a high-purity granular metal product, designated NICKEL 98. This paper describes the investigation of on alternate route to processing nickel chloride in which high-quality cathode nickel is produced by electrowinning from all- chloride electrolyte. The investigation was made in a pilot circuit containing two production-size electrowinning tanks operated in conjunction with the commercial-scale leach plant.

Jan 1, 1977

By Freislich. M., Y. Gordon

"In the changing global market scenario for raw materials for the steel industry, a number of novel iron- and steelmaking process technologies are being developed to provide the steel companies with economically-sustainable alternatives for iron- and steel-making. In addition, the steel industry is also focusing on reduction of energy consumption as well as green-house gas (GHG) emissions to address the crucial subject of climate change. In this context, it is important to assess these critical issues for the alternate iron- and steelmaking technologies that have been developed. This paper presents a comparative evaluation of energy-efficiency and GHG emissions for some selected iron- and steelmaking technologies that are being considered for implementation. In this work, Hatch’s G-CAP™ and En-MAP™ tools that were developed with the main objective of quantifying and qualifying the potential energy savings and CO2 abatement within the iron and steel industry, were employed in the evaluation conducted. INTRODUCTIONThe iron and steel industry continues to transform itself and evolve in the ever-changing global market place – the raw material scenario is constantly changing with respect to quality and quantity (availability), there is stiff competition in both global and local markets, and there is increasing pressure to address global climate change issues, especially since the steel industry is highly energy- and carbonintensive. There is growing importance of steel production in developing countries such as China and India – this means that the steel industry in these countries will play an important role in defining and shaping the future of the industry.Climate change is expected to present new risks to the steel industry with respect to ensuring a sustainable business. Legislators are proposing to limit GHG emission by placing an implicit price on CO2 emission - market-based “cap and trade”, carbon tax etc.. In this scenario, it is important for the steel companies to reduce exposure to climate-related risks and at the same time, find business opportunities within these risks. Thus, there is a need to strategically manage the climate change risks; the key steps to strategically manage climate change risks are presented in Table 1[1]."

Jan 1, 2012

By L. Shasko

Deliberative mapping is a method of public engagement designed to bring citizens and specialists together to inform policy decisions in conflict-laden areas of science and technology (Stirling and Davies 2004a). Citizens and specialists participate in the process both separately and together. A deliberative mapping study was held in Regina, Saskatchewan in October and November of 2019. Participants in the study assessed options for reducing greenhouse gas emissions in small, remote or off-grid communities, including assessing the role of small modular nuclear reactors (SMRs) in climate change mitigation. Deliberative mapping is designed to facilitate direct, two-way conversations between citizens and specialists through both formal and informal discussions. The relationship building component of this process may increase trust. Public consultation processes that lack two-way dialogue or are seen as obligatory rather than meaningful can worsen public opposition or lead to negative public perceptions. Public education alone is not enough to change public opinion. Providing people with more information on topics they already hold opinions on can work to reaffirm previously held biases, but building relationships can provide new pathways to overcome divisions and turn close-mindedness into open-mindedness.

Jan 1, 2020

By Long Han, Beijing General Research Institute of Mining and Metallurgy, Yu Xie, Yunhai Zhang, Yangge Zhu, University of Science and Technology Beijing, Yanbo Shang, Xingrong Zhang

"The first-principles method was employed to study the adsorption of hydroxyl calcium (CaOH+) and hydroxyl (OH-) on hematite and quartz surfaces. The calculation results suggested that OH- preferred to interact with the active Fe sites on the hematite surface, whereas OH- adsorbed on the quartz surface by weak hydrogen bond. Though CaOH+ could easily adsorb on the hematite and quartz surfaces by the formation of Ca-O bond, the covalence formed on the quartz surface was apparently stronger than that on the hematite surface, meaning a stronger and more stable adsorption. CaOH+ adsorbed on quartz surface was mainly through the interaction of O-2p and Ca-3d states, and this interaction on hematite surface was weaker.INTRODUCTIONIron Increase and Silicon Reduction Technology (Yu & Duan, 2002) of hematite is mainly through the reverse flotation (silica is floated away from the iron concentrate). There are two ways to achieve this (Houot, 1983). One is to collect quartz by cationic collector directly; the other is to activate quartz by lime and then collect it by anionic collector. There are two main different views with respect to the mechanism of quartz activation: mono-hydroxyl compound theory (Fuerstenau, Rice & Somasundaran, 1965; Fuerstenau & Palmer, 1976) and surface hydroxyl precipitation theory (Hu & Wang, 1988; Wang & Hu, 1990). The former indicated the formation of the mono-hydroxyl complex is one of the two criteria of quartz flotation. The later theory, on the other hand, suggested that surface precipitation is the adsorption of active species of metallic ion on quartz surface. However, most of those researches are based on the solution chemistry of flotation and little is done at the microscopic level.In this paper, by the help of first-principles calculations, the adsorption models, bonding conditions, Mulliken charge populations and adsorption energies of hydroxyl and calcium hydroxyl ions (OH- and CaOH+) on hematite (001) and quartz (100) surfaces were investigated to find out the lime activation of quartz at atomic level, which is significant for the researches of quartz activation theoretically and practically."

Jan 1, 2016

By Chi Zhang, Junyi Wu

"The use of permanent stainless steel cathodes for electrorefining and electrowinning of cathode copper had been introduced to the market long time ago and now is a well-accepted technology worldwide. During the last decades, the Chinese copper refinery industry had been growing rapidly and many large scaled production plants had been built. In the modern refineries, permanent stainless steel cathodes are introduced and used instead of traditional starter sheets. The most common steel grade used is austenitic stainless steel S31603 (316L/1.4404), while both S30403 (304L/1.4404) and N08904 (904L/1.4539) have been used depending on the actual working conditions, especially with regarding corrosion environment. While 316L permanent cathode functions well in many plants, different kind of problems, such corrosion and deformation, have been reported. There is therefore an increased need for more suitable material. New stainless steels, such as duplex stainless steels, with better properties have been tried and introduced into the application of permanent stainless steel cathode with satisfied results. The article introduces first the Chinese copper refinery industry and properties of duplex stainless steel in general, and then describes the development of using permanent duplex stainless steel cathode, including the actual working conditions, production of cathode sheets as well as the experiences of application in details. After more than one year’s usage, the advantages of permanent duplex stainless steel cathodes are clear seen.INTRODUCTIONChina has become a major player in the international copper market, accounting for around 40 percent of global refined copper demand. Despite the slowdown of the Chinese economy, the consumption of copper products will still increase, but with a medium and/or low growth which will be the new situation for the coming years. The average growth rate is expected to be around 5 percent per annual. In the coming Five-Year plan for National Economic and Social Development a number of initiatives will be finalized which will require massive amounts of copper. In 2015, the expected consumption of copper products will be over 9 million metric tons. The main driver of the consumption is the electric power industry which accounts nearly the half of the total consumption; followed by cooling application with 15% and transportation with nearly 10%, see figure 1."

Jan 1, 2016

By L. Li, K. Jiang

China is the world largest producer and consumer of zinc. Beijing General Research Institute of Mining and Metallurgy (BGRIMM) is one of major research and engineering institutes for nonferrous metallurgy in China. This paper (presentation) introduces the development of China’s zinc smelting industry, key production processes and main producers. The process research and development are reviewed as well as BGRIMM’s R&D activities in the last decade. China's refined zinc production was 4,829kt in 2012, accounting for 38.6% of world production. Primary production was 4,722kt. There are around 150 refined zinc producers in China. The traditional fluid bed roasting - leaching jarosite is still a dominant process for primary production and its production accounts for about 60% of country's total production. However, the direct leaching process is gaining market share. Seven direct leaching plants with 330kt/a capacity, including autoclave leaching and the Outotec direct leaching, have been put into production by June 2013. Five autoclave leaching projects with 590kt/a capacity are in the pipe line and are expected to be commissioned in 2014 and 2015. To cut the production cost and improve smelter economics, process research to optimize the production flow sheet, to improve the iron removal and to enhance the recovery of co-existed rare metals were carried out. The development trends of China’s zinc smelting industry from the view of cutting production cost, improving energy efficiency, increasing comprehensive utilization are discussed accordingly.

Jan 1, 2014

By John B. Hodgeson

AMMONIA is an essential constituent in the production of the ammonium-sulphate and ammonium-phosohate soil fertilizers manufactured by the Consolidated Mining and Smelting Company of Canada, Limited. The fertilizer plant, built in 1930 at Warfield, near Trail, provides a means of utilizing the large amount of sulphuric acid produced from the sulphur dioxide which is removed from the smelter smoke. The plant has an avail-able source of cheap power which makes the production of fertilizer economically possible. The fundamental operations involved in the production of ammonia at the Warfield plant are, first, the manufacture of hydrogen by the electrolytic dissociation of water; next, the recovery of nitrogen by the fractional distillation of liquid air; and finally, the combination of hydrogen and nitrogen in proper proportions and under suitable conditions to form ammonia.

Jan 1, 1938

ABSTRACT It is critical that historical processes and concomitant exposures to specific nickel substances be understood because some diseases linked to inhalation of certain nickel-containing substances have a long latency between first exposure and disease onset, and because nickel substances vary significantly in their toxicological properties. A discussion of the smelting history and related processes at Vale Canada’s (Inco’s) Copper Cliff, Ontario, smelter is integral to the understanding of these processes. The post-1950 processing history, equipment, propensity for aerosol formation, operational procedures, and ventilation controls used by Vale Canada in roasting, smelting, converting, and copper-nickel separation is discussed.

Jan 1, 2013