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The floatability of a bituminous coal in NaG solutions was evaluated using a modified Hallimond tube to delineate the role of the electrostatic interaction between bubbles and particles in determining the coal hydrophobicity. Zeta potential measurements showed that bubbles are negatively charged in the entire pH range tested, while coal particles are positively charged below pH 6.0 and negatively charged above it. Also, both sodium and chloride ions were confirmed to act as indifferent ions without any specific effects for both coal particles and bubbles. Flotation as a function of pH exhibited a maximum and minimum at low salt concentrations which is shown to be determined mainly by the coal hydrophobicity as measured by a new hydrophobic levitation technique. At high salt concentrations (above 0.1 mole/dm3), the flotation without such maximum or minimum is controlled by the electrostatic interaction between the bubble and the particle.

Jan 1, 1992

By D. R. Nagaraj

There are few organic ligands that can adsorb effectively on noble metals, especially gold, in aqueous media. Ligands containing sulfur and nitrogen donors are known to be the most effective. Dithiophosphorous acids, for example, are known to adsorb on gold under certain conditions and these, along with xanthates, are used traditionally to recover gold values by flotation from ores. These compounds, however, are not necessarily selective for gold since most of the associated sulfide minerals are also floated. Monothiophosphorous acids, on the other hand, were recently discovered to float gold values selectively from sulfide-containing ores in a mildly alkaline medium; thus the dicresyl monothiophosphate is now used commercially in a gold flotation operation in the U.S.

Jan 1, 1991

By D. A. Fenton

The reliability of large diameter, high horsepower ball mill is paramount when large production and minimum downtime is required. The 17 ft. x 56 ft. double compartment ball mill at St. Lawrence Cement Company has the first gearless drive built in North America and has the world's largest hydrodynamic bearings currently built and running. The machine has seen three years operation and has met its specifications. The mill was designed by Aerofall Mills Limited and the gearless drive built and designed by the Canadian General Electric Company. This paper discusses the operation of the first North American installation of a gearless drive ball mill from the mechanical, electrical and process aspects.

Jan 1, 1977

By Andrew J. Neale, Chelvan Veloo

P.T. Freeport Indonesia currently operate a 600,000 t/d mining and 125,000 t/d milling operation in the remote highlands of Irian Jaya, Indonesia. The isolated location and generally difficult working conditions make for challenges not encountered in most North American operations. In spite of this, the mill technical groups have been able to develop and maintain a highly effective level of plant wide automation. This has been achieved through the appropriate selection of available technologies and the implementation of innovative management practices. This paper provides an overview of the control systems currently installed and focuses on those practices which have resulted in the long term success of process control at Freeport.

Jan 1, 1997

By Richard Klimpel

A common problem in mineral processing and chemical engineering is the need to estimate flow rates and/or weight ratios involved with engineering operations for which it is inherently difficult to directly measure stream weights. Simple examples of this situation include stream separators (a classifier operating on a particle flow) and stream mixers (the mixing of new feed and circulating load in a ball mill circuit). Often in these types of operations, it is possible to sample the streams involved to get approximate component analyses (e.g. size distributions of solid streams, chemical composition of chemical streams). In this paper various formulae are developed which can be used to estimate stream flow rates or weight ratios given information on the stream components. The type and level of experimental error present in the stream component analyses does have an important bearing on the numerical values (and reliability) of the weight ratios calculated by the various formulae. A simple but theoretically sound method is shown for selecting appropriate estimation formulae for any given engineering operation. The derived formulae are applied to sets of experimental classification data for illustration purposes.

Jan 1, 1979

By M. B. Mooiman

It has recently been discovered that the pH at which gold can be extracted from cyanide solution with primary, secondary, and tertiary amines can be increased 2 to 5 pH units by the addition of modifiers. Under these circumstances gold can be extracted at pH values from 9 to 11, commensurate with the pH range found in cyanide leach liquors. The selectivity of the amines and amine/modifier combinations for AU (CN)[-2] over other metal -cyanide complexes is presented and discussed. In addition, potential applications for the solvent extraction of gold from cyanide solutions are discussed.

Jan 1, 1983

By S. L. Manske

The Mesquite gold deposit is a recent discovery of Gold Fields Mining Corporation lying 65 kilo- meters northeast of El Centro in Imperial County, California (Figure 1). The deposit is located on the southwestern flank of the Chocolate Mountains and is a bulk-minable, low grade "disseminated" orebody. Although the host rocks of the deposit are part of a regional high-grade metamorphic terrane, abundant brittle fractures, brecciation, and open-space vein fillings indicate that Mesquite mineralization is epithermal. Faulting which postdates the hydrothermal activity has complicated the original geometry of the orebody. Alluvium effectively hides most surface expression of the mineralization, but open-pit mining is now revealing the details of Mesquite geology.

Jan 1, 1987

By Charles B. Escapule

The first successful heap leach of silver ores in the State of Arizona has been under continuous operation since early 1976 at the State of Maine Mine, two miles southwest of Tombstone, Arizona. The silver produced from leaching old mine dumps at this property vas the first in the Tombstone mining district to achieve a 999+ purity. While cyanide leaching of silver and gold ores is a time-proven accepted practice, a relatively new method of treatment called "heap" leaching was employed. Heap leaching is a comparatively inexpensive fast way to recover precious metals from low grade material.

Jan 1, 1981

By John S. Burton

Mineral policy in Canada has been in a state of transition and change over the past several years. 1976 has witnessed some settling of troubled waters and the pattern of the currents of change is becoming more clear. The provinces play a key role in this process and have provided much of the thrust for new initiatives. On the other hand, the federal government in Canada in recent years has taken a much more active interest in mineral affairs than previously and has asserted its powers on a number of key policy questions. Some of the initiatives from the two levels of government in Canada have come into conflict with each other and, thus, contributed materially to a state of affairs that includes change, uncertainty and conflict.

Jan 1, 1976

By W. W. Wen

The objective of this investigation was to study the electrokinetic behavior of oxidized coals to indicate the feasibility of separating oxidized coals from ash materials and pyrite by an mine flotation process. The effects of soluble inorganic electrolyte products from coal oxidation were also examined. The electrokinetic behavior of coals of different rank and degree of oxidation were studied by an electrophoreses technique. Generally, increasing the oxidation increases the negative value of the zeta-potential and decreases the isoelectric point (IEP). Flotation results indicate that the flotation recovery increases with decreasing pH values, and that with ferrous sulfate at pH 6.5 the flotation recovery is optimum while the pyrite was depressed. Comparing the flotation results with the electrokinetic results verified that in the presence of ferrous sulfate, the maximum hydrophobicity of oxidized coal with dodecylamine and frother is near its IEP which is around pH 6.5 to 7.0.

Jan 1, 1976

By A. J. Neale

Much has been published lately about the application of advanced control strategies in the automatic control of autogenous and semi-autogenous grinding circuits. The application of adaptive control algorithms, self-tuning controllers, state estimation, and expert systems has been well documented. While these approaches can be very effective; experience has shown that quite often simply "fixing the fundamentals" can have a significant positive impact on overall grinding circuit performance. This paper will highlight the results of process optimization and process control work by the authors at a variety of autogenous and semi-autogenous installations. A review of one approach for quantifying the mill load/bearing pressure/power relationship is provided. Accurate monitoring of key mill process variables is a necessary prerequisite for both effective process analysis and process control. This paper discusses some of the concerns related to defining steady state operating conditions and the issues related to signal conditioning. The paper concludes with a discussion of an effective application of algorithmic constraint control which incorporates many of these considerations.

Jan 1, 1994

By James A. Commins

Accurate engineering predictions of energy needs for pollution control equipment used in surface mining operations is critically important to sound management selection of control alternatives. This paper will describe a procedure for evaluating two control alternatives with different energy needs. Three steps are involved: an analysis of the pertinent regulations, a determination of the size distribution of the particles being emitted, a calculation of the energy needs and costs of the candidate control systems as a function of these regulations and emission characteristics. The principal air pollutant to be controlled in surface mining operations is particulates, or dust, some of which is already on the material introduced into the primary crusher and other dust which is generated by the various steps in the subsequent processes. The requirement for control stems both from regulations concerning workers at the operating site, and the community surrounding the operations. In order to speak quantitatively about the need for control we will use regulations that pertain in Pennsylvania although it must be borne in mind that such regulations vary according to juristiction.

Jan 1, 1975

By A. Heriba

Cyanide is highly toxic to humans and other organisms. Concentrations of RCN as low as 0.05 ppm can be lethal to fish (Scott and Ingle', 1981). In wet climates and in colder climates where natural degradation is slow, it is becoming mandatory to destroy cyanides in effluents before they can be discharged. The disposal of spent gold ore as tailings from cyanide heap leach processing facilities is a matter of concern to the public, the mining industry, and regulatory agencies. South Dakota mining laws and regulations require that spent ore be neutralized to a suitable level with respect to cyanide before disposal (Durkin, 1990). To safeguard the environment and protect ground-water and surface-water supplies adequately, a reliable test is needed to determine the amount of cyanide in the solid spent ore.

Jan 1, 1993

By D. Kang

The adsorption behavior of silver in ammoniacal solutions on to activated carbon has been studied. The parameters affecting the adsorption of silver on to activated carbon included temperature, agitation speed, concentration of cations and anions as well as that of ammonia. It was found that the adsorption of silver from ammoniacal solutions was dependent upon the initial silver concentration in the solution and other factors. The recovery of silver from ammoniacal solutions was found to be not so effective as the case with gold reported earlier. The adsorption rate was relatively slow overall, despite a rather fast initial adsorption. The apparent activation energy for the adsorption was measured to be 30.2 kJ/mol. It was believed that the kinetics of the silver adsorption on activated carbon was limited by a mixed control mechanism.

Jan 1, 1998

By Dean E. Albon

In the late 1940's and early 50's in southern Illinois, the usual open pit blasting in the coal field consisted of one or two rows of churn drilled vertical holes being shot with instant electric blasting caps. The entire shot detonated at one rime. In southern Indiana and Ohio most mines were drilling horizontal holes and they too were primed with instant EB caps. During the ten years from 1355 through 1965 many changes occurred in drilling and blasting methods. The churn drill in southern Illinois and the horizontal drill in Indiana and Ohio were replaced by the rotary vertical drill. The ammonia dynamites and liquid oxygen explosives were replaced by ANFO. The elctric blasting cap in the hole was replaced by a detonating cord down line and detonating cord trunk lines made the connections between holes and rows of holes. Host open pit mining was in areas far enough from town that the noise and vibration from blasting was, if not ignored, at least tolerated. During the 1960's open pit mining expanded to account for nearly 50% of the coal produced. Mines came closer to town and towns expanded along the highways with suburban homes and mobile homes. The mines began receiving complaints about the noise and vibrations from blasting operations.

Jan 1, 1976

By Y. Luo

Surface subsidence monitoring is the most effective means for investigating the nature of, and developing the techniques for predicting, the surface movement and deformation process. However, because of imperfection in survey equipment and field practices, the surface movement data collected from field survey are not error-free. Also due to lack of proper numerical techniques for computing surface deformation from the measured surface movement data, a relatively large portion of the subsidence data collected could not provide more information other than surface movement. In this paper, the sources and magnitude of errors in the measured surface movements and calculated surface deformation are discussed. Techniques for improving the accuracy of the calculated deformation indices (i.e., slope, strain, and curvature) are developed. The proposed techniques include: (1) proper selection of monument spacing for subsidence monitoring; (2) a data smoothing technique for data pre-processing; and (3) a number of numerical methods and/or procedures for calculating surface deformation indices from the measured surface movement data.

Jan 1, 1992

By Sammie D. Guy

This paper discusses the subject of "Improving Contracting Methods" from the owners point of view, particularly the public. An overview is given of the work of the U.S. National Committee on Tunneling Technology and some apparent results of the implementation of these recommendations or lack thereof. Selected recommendations that are not being implemented are discussed as to the the desirability and the possible impact of their implementation. Impediments to acceptance of the recommendations are identified and solutions proposed. The difference in the flexibility, attitudes and approaches of owners, public, quasi-public and private, toward improving contracting methods are discussed. Particular emphasis is given to the fact that the onus to improve is on the owner because they usually develop the contractual language or at least have the final decision on its content and are or should be an equal party to the contract during its administration.

Jan 1, 1983

By Arthur M. Ribe

In my experience, nothing helps me better to get off to a good start in preparing a paper or a talk than a copious consultation with a comprehensive dictionary. I also feel defining the perimeters of a particular subject is helpful to the listener and reader. Sometimes thus precisely defining even the most common of words is helpful. Our general topic this morning as all of you know is "Transportation of Industrial Minerals." The definition of transportation given by the dictionary which I think is appropriate here is: "Systems and modes of conveyance of persons or goods from place to place." Our preceding panelists have outlined for you the state of the art inso¬far as systems and modes of conveyance from place to place are concerned today via rail, water and motor. My assignment is somewhat different as indicated by my topic, "The Traffic Manager in an Industrial Minerals Operation."

Jan 1, 1969

By P. Corser

Operational and geotechnical constraints on mining within steeply dipping deposits and historic landslide areas, which are characteristic of subarctic coal deposits in Alaska, will be discussed. The current plan for mining through these areas will be presented, as well as an alternative plan for minimizing the adverse effects of mining through an historic landslide area.

Jan 1, 1988

By William H. Dresher

A study has been made of the reaction mechanisms occurring during the salt-roast process to form water-soluble sodium vanadate compounds from the vanadium oxide compounds present in vanadium-bearing ores and concentrates. Two reactions have been identified, either of which lead to water-soluble compounds--oxidation of sodium chloride by water vapor and. oxidation of sodium chloride by oxygen. The former reaction has been found to be predominant in the salt-roast process. A kinetic treatment of the data has shown that for the formation of sodium metavanadate the rate-controlling step in the reaction, in which sodium chloride is oxidized by water vapor is the decomposition of a species containing water and sodiumm chloride, on the surface at the gas-solid interface. For the formation of sodium pyrovanadate, the rate-controlling step is the decomposition of a species containing water and sodium metavaradate on the surface. The transportation of water through the system, perhaps as a sodium chloride-water complex or a sodium metavanadate-water complex, and the actual chemical reaction are relatively fast compared to the initial surface decomposition step. A similar treatment on the data for the oxidation, of sodium chloride by oxygen has shown that the rate-controlling step, is the actual transportation of oxygen from the gas-solid interface to the reactive site. This transportation is by a sequence of two diffusion processes. Transportation during the early stages of the reaction is by the diffusion of oxygen through a continuous layer of reaction product. After, the first few minutes of reaction time a second diffusion process begins and is continuous for the remainder of the reaction. This second diffusion process involves the diffusion of oxygen, through a layer of reaction product that has developed voids around which the oxygen must diffuse. The hindering, nature of this latter process causes the rate of transportation of oxygen to the reaction site to be considerably slower than by the simple diffusion mechanism initially followed. A thermodynamic treatment of the data has shown that the energy of activation for the decomposition of the water-sodium chloride species on the surface is -12.1 Kcal. per mole. For the decomposition of the water-sodium metavanadate species on the surface' the energy of activation is -15.1 Kcal. per mole. The results of this study indicate the limiting mechanisms of the basic reactions occurring during the salt-roast process. These results suggest what variables should be examined in applying this information to actual plant operations.

Jan 1, 1961