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By W. L. Cornell

The Missouri Pb ores are the only domestic Co resource being mined and processed for other metals; therefore, they present a viable short-term opportunity for Co production. Lead, zinc, and copper concentrates are produced from the ore. The Cu concentrate can contain up to 30 pct Co and the Pb concentrate up to 15 pct Co. Since Co is detrimental to the processing of the Zn concentrate; the remainder of the Co is rejected to the tailings. The tailings can contain as much as 50 pet Co originally present in the mined ore. Researchers at the U.S. Bureau of Mines have successfully tested on a continuous basis a process that recovers a bulk sulfide concentrate from mill tailings. The concentrate contains up to one-half of the Co and from 50 to 90 pct of the Pb, Zn, and Cu. Concentrate weight represents 10 pet or less of the total tailings.

Jan 1, 1989

By H. C. Ko

Calorimetric determinations of low-temperature heat capacities and the standard enthalpy of formation were made by the Bureau of Mines for aluminum sulfide, A12S3. The standard entropy (S°), enthalpy of formation (?Hf°), and calculated Gibbs energy of formation (?Gf°) at 298.15 K are 27.93±0.05 call deg-mole, -155.6±0.9 kcal/mole, and -153.0±1.0 kcal/mole, respectively.

Jan 1, 1976

By Wilbur I. Duvall

This paper presents arguments which show that a velocity seismograph should be used to measure building and ground vibrations produced by blasting . However , portable velocity seismographs suitable for this type of measurement are not commercially available . The paper describes how a velocity seismograph can be assembled from commercially available velocity gages , amplifiers , and recorders . Also , specifications are given which could be used in the design and manufacture of a portable velocity seismograph suitable for measuring vibrations from blasting .

Jan 1, 1964

By Timothy M. Barton

The U.S. Bureau of Mines is conducting research to assess the effectiveness of different chain pillar designs in maintaining gate entry stability. A particular concern is ground control for deep-cover 1ongwalls located at depths in excess of 1,000 ft. The study described in this report was performed in two experimental sections in one longwall headgate section which contained three different pillar designs. Two of the designs used conventional abutment pillars, while the third was a total-yielding pillar system. Both of the test areas were located under 1,800 ft of cover. The purpose of this study was to evaluate the effectiveness of these three pillar designs for gate road stability. As the longwall mined passed the test areas, Bureau engineers monitored entry convergence, roof sag, and changes in roof quality. The study indicated that the all-yield system performed nearly as well as the better of the two abutment pillar systems; but all of the three designs would have failed to provide acceptable stability for second panel mining without considerable artificial support.

Jan 1, 1989

By David L. Veith

This report summarizes a Bureau of Mines review of selected literature on the effects of subsidence due to high-extraction underground coal mining on farmland areas. The data are presented for consideration in evaluating the subsidence effects due to similar mining techniques on the prime farmland areas of Illinois. In Illinois the ground water level in the glacial drift is only 2 to 15 ft below the nearly flat to gently rolling ground surface. The main subsidence concern is flooding, as caused by the lowering of the ground surface, and the subsequent effects on crop production. Positive drainage must be maintained in the farmlands, and the need exists for extensive regional planning by the mining and agricultural industries to maximize short- and long-term production from both efforts. The Bureau is cooperating with the State of Illinois to develop basic information necessary for such planning.

Jan 1, 1987

By Charles L. Kimbell

In overview, the world's mineral industry in 1989 registered gains over its 1988 performance, but these gains were by no means as pronounced as had been those of 1988. The traditional statistical measures of mineral industry performance, namely production, trade, and consumption levels, reflected significant growth in most industry sectors from crude material extraction through the gamut of down- stream processing. Growth in market economy countries generally exceeded growth in the centrally planned economy countries as a result of a variety of causes that will be covered subsequently, but even among the centrally planned countries there were some upturns. In contrast to these measures of the soundness of the industry, the situation for nonfuel mineral and metal prices was less satisfactory than in 1988, and low crude oil prices continued as a problem for the all-important petroleum sector, despite some gains during the year. The oil price situation mitigated against price increases for competitive fuels. Although this was unfavorable for fuel producers, it remained advantageous to consumers, including nonfuel mineral producers, processors, and transporters. Thus it cannot be viewed as a negative factor for the whole of the global mineral industry. Global crude mineral output value was estimated at nearly $1,420 billion in current dollars, an increase of 9% over the 1988 level, and an increase in current dollar terms for the seventh consecutive year. Measured in terms of constant dollars, however, adjusting for inflation, the increase was only 4.7% compared with the 1988 level. Despite the prolonged growth trend, the 1989 crude mineral output value level was still 3.2% below the record high set in 1980, which was $1,467 billion in terms of 1989 dollars.

Jan 1, 1992

By M. S. Seehra, R. S. Pandurangi

"INTRODUCTION Silica and kaolin (a layer aluminosilicate) are among the major constituents of most coal mine dusts.' Whereas kaolin is cytotoxic in vitro but nonfibrogenic in vivo in humans and experimental animals,2-4 the cytotoxic and fibrogenic potential of silica is rather well established.5 Wallace and co-workers 6-8 have studied the cytotoxic potentials of both native and surface-modified silica and kaolin and inferred that retoxification is slow in the case of occluded silica vis-à-vis native silica. Recent epide¬miological studies indicate that silica concentration alone in a mine dust, as determined by transmission IR spec¬troscopy (TIRS), does not correlate well with the pro¬gression of coal workers' pneumoconiosis. 9 This obser¬vation has led to the suggestions that silica particles occluded by clays such as kaolin may not be fibrogenic. This proposal requires accurate estimations of kaolin, silica, and occluded silica. The current method of silica analysis in a mine dust sample employs TIRS of the 797- cm -1 band of silica, although its accuracy, as well as that of x-ray diffraction studies, is no better than 25 % , even in a laboratory-generated dust.° In this paper we have employed the techniques of diffuse reflectance spectros¬copy (DRS) and photoacoustic spectroscopy (PAS), in conjunction with an FT-IR spectrometer, for the quan¬titative determination of silica in laboratory-generated silica-kaolin mixtures.One of the main advantages of DRS and PAS is that, in these techniques, problems arising from sample prep¬aration of the KBr-based disks used in TIRS are avoided. There are, however, several other considerations (e.g., particle size effects and saturation phenomenon) which complicate the use of DRS and PAS for quantitative work. 10-25 In this paper, we have carried out a systematic comparison of the quantitative abilities of the two tech¬niques, as applied to the silica-kaolin mixtures, with par¬ticular attention to the saturation behavior of several bands with different absorption coefficients. In particular, we show that a weaker band for silica at 1875 cm-1 is suitable for quantitative purposes, and that quantitative accuracy is higher in DRS than in PAS. Details of this work are given below."

Mar 1, 1992

By L. C. IlsLey, E. J. Gleim, F. CRAVEN

Electrical apparatus and circuits began to be used in mines about 50 years ago. A search of the literature on mining reveals that in 1882, umping was being done by electricity in some aines of England. One account tells of a small electric locomotive being used in 1882 "to drive eight corves loaded with coal" in a mine near Dresden. In an account of his visit to some English mines, en American in 1892 mentions that he saw underground electric signals, lights, pumps, hoists, and one revolving- cutter-bar 19wall mining machine,. Among the carl electrical installa- tions in the United States was an electric locomotive in the Lykens Valley Coal Co. mine at Lykens Valley, Pa., in 1887. In 1889 the Sperry electric coal digger was being tried out. Tarce mining machines were placed in the Prospect mine, East Palestine, Ohio, in 1890. An electrical pumping plant was put in oneration during 1892 in the Woodward mine of the Delaware, Lacka- rahma & Western Railroad Co. Thus we Almost coincident with the proposed use of this new servant in under- ground workings, came the thought of making it safe in gassy mines. find an account of a design for a protected stationary electric mine lamp proposed by Edison in 1831. Enclosed-type motors rere developed in the United States and shiped to English collieries about 1903. From those early beginnings there has been continuous progress until to-day one finds hundreds of pieces of specially designed electrical apparatus distributed in American coal mines and in mines of nearly all important coal-producing countries. Along with introduction of this equipment grew the idea of the necessi- ty of government aid, in standardization. In most coal-mining countries to- day the governments either directly or indirectly have a considerable in- fluence in guiding the design of electrical equipment intended for use in Pasay mine

Jan 1, 1933

By Foster Fraas

The Bureau of Mines investigated a method for calculating values of adsorption energy; the goal was to devise an equation consistent with experimental data accumulated in the investigation of adsorption as related to ore separation processes. Numerical identification of the constants of a previously formulated equation provided an equation by which values of adsorption energy could be calculated. Values thus calculated checked with those obtained by calorimetric measurement.

Jan 1, 1965

By M. J. Ferrante

The standard enthalpy of formation, low-temperature heat capacities, and enthalpy increments above 298 K were determined by the Federal Bureau of Mines for synthetic dawsonite [NaA1C03(OH)21. The enthalpy of formation was determined by hydrochloric acid solution calorimetry, with the result ?Hf°298 = -469.4±0.7 kcal/mole. The low-temperature heat capacities were determined from 6 to 307 K by adiabatic calorimetry. Tabulated are low-temperature values of Cp°, S°, and H.-Ho° from 3 to 298 K. The derived entropy at 298 K is S298 = 31.55±0.3 cal/deg mole. Enthalpy increments above 298 K were obtained by copper-block drop calorimetry. Tabular data of Cp°, S°, H°-H°298, -(G°-H°298)/T, ?Hf°, ?Gf°, and log Kf are given from 298 to 477 K. Enthalpies and Gibbs energies of decomposition are also reported.

Jan 1, 1976

By S. P. Howell

"Technical statistical study has been made of accidents in the anthracite region of Pennsylvania in which explosives were involved. The data have been taken from the accident reports in the files of the department of mines of Pennsylvania, supplemented by inquiries in the field.This study has disclosed a wealth of information regarding the nature and the cause of accidents that occurred where different means of firing shots of explosives were employed. In the anthracite region shots are fired with fuse, with squibs, and with electricity,Many of the salient features of this accident experience are illustrated in this report of investigations, and a number of recommendations are made to reduce the hazards of each of these three methods of shot firing.Experience seems to demonstrate that, under conditions in the anthracite region, electric firing of shots is substantially the safest method; that accidents wherein fuse is employed are more frequent than accidents in which electric firing is employed; and that the number of accidents when squibs are employed far exceeds those in which either fuse or electric firing is used."

Mar 1, 1930

By J. M. West

Expanded war in Viet-Nam overshadowed activities in the Far East in 1965, diverting capital and materials from potential regional development projects. Japan with-stood a period of business recession that was particularly felt by its coal mining and iron and steel industries. Toward yearend signs of improvement began to show. Despite the recession with attendant credit restrictions and forced cutbacks in areas of overproduction, Japan's overall industrial output rose nearly 5 percent during the year. Foreign trade, liberalized in 1964, was a strong point in the Japanese economy and took the place of lagging domestic demand. Japan maintained its third place in world production of iron and steel ahead of West Germany and in 1965 was the world's fore-most exporter of iron and steel in primary and semimanufactured forms. Economic setbacks in mainland China caused by its "Great Leap" failures and subsequent withdrawal of Soviet technical assistance were difficulties relegated to the past. However, a newly formed "Red Guard" political group, part of a so-called cultural revolution, was due to cause new disruptions in 1966. Nevertheless, significant gains were claimed in Chinese industry, and the country approached self-sufficiency in petroleum in 1965 by virtue of its Tach'ing oilfield. Restoration of friendly relations was achieved between South Korea and Japan accompanied by Japanese offers of industrial aid and increased trade. Indonesia's economy was deteriorating; the country withdrew from regional development organizations and continued its stubborn confrontation policy against Malaysia throughout 1965. Late in the year after a Communist uprising had been quelled, there was a period of political retrenchme t and it was hoped that economic improvements would follow. Petroleum remained a strong area in Indonesia's varied resources, and its production was increasing. Tin output declined, however, because of operating difficulties.

Jan 1, 1967

In 2004, a total of 4,401 stone mining operations reported employment to the Mine Safety and Health Administration (MSHA). Stone mines comprised 30.4% of all mining operations.

Sep 1, 2007

By H. H. Schrenk

Much has been written and said concerning tables of permissible or maximum allowable concentrations of various toxic substances in air, but not enough attention has been given to their limitations and how to use them intelligently . There is a tendency to place too much reliance on figures , with little or no consideration of their real meaning . The repeated publication of a figure often adds significance to it far beyond that intended by the original author or publisher . How are these figures referred to as "maximum allowable concentrations " established? What is their real meaning? To answer these questions it is necessary first to define maximum allowable concentration . The usual definition is somewhat as follows : "The average concentration to which an industrial worker can be exposed for 8- hours daily for an indefinite period without injury or occupational disease . This definition is made up of the following items : ( 1 ) Average concentration, ( 2 ) 8 - hour day , ( 3 ) indefinite exposure period , and ( 4 ) lack of injury or occupational disease . There is some controversy regarding item ( 1 ) , items ( 2 ) and ( 3 ) are usually though not invariably accepted , and there is definite disagreement regarding the interpretation of item ( 4 ) . . To reach a more satisfactory interpretation of maximum allowable concentration , attention is directed to ( 1 ) the development of tables of maximum allowable concentrations , ( 2 ) criteria on which limits are based , and (3 ) methods used to obtain data on which limits are based .

May 1, 1948

By John P. McDonnell

This U.S. Bureau of Mines report describes the results from an in-mine investigation of an alternative longwall gate road design. The coal mine operator modified the pillar layout (reversed the location of the big and small pillars) in a portion of a three-entry longwall gate road area. The modified pillar layout was an attempt to reduce stress and, subsequently, stress-related ground control problems (cutter roof and dynamic floor heave events) in the tailgate region during "second-panel" mining. The results from borehole pressure cells installed in the modified gate road area showed that the ground pressures in the panel edge and adjacent small pillar were significantly reduced during second-panel mining compared with ground pressures experienced in the typical pillar layout gate road areas. The reduced stress levels around the tailgate entry adjacent to the second panel, as compared with the tailgate stress levels with the typical pillar arrangement, contributed to improved tailgate ground conditions in the test pillar zone.

Jan 1, 2010

By F. W. Hoertel

Tungsten from the hydrogen reduction of WF was vapor - deposited to coat MERM (Material Evaluation Rocket Motor ) graphite and rhenium- lined graphite nozzles . These nozzles have surface configurations that preclude the conventional fabrication of high- density- tungsten liners . Operation at 550 ° C produced selectively placed uniform coatings of specified thicknesses at near theoretical density . An acceptable coating could not be deposited on a beryllia nozzle because of an undesirable side reaction between the substrate and one or more of the products of the reduction reaction .

Jan 1, 1964

By R. E. Siemens

A process is being developed by the Bureau of Mines to selectively recover nickel and cobalt from low-grade domestic laterites. In laboratory evaluation of the process, the oxides in the laterite were selectively reduced with carbon monoxide at temperatures from 350° to 600° C. For material containing more than about 5 percent magnesia, pyrite additions or post-reduction heat treatments were necessary to achieve satisfactory nickel and cobalt extraction for this range of reduction temperatures. Multistage leaching of the reduced material at ambient temperature and pressure in the presence of oxygen, ammonium sulfate, and ammonium hydroxide extracted up to about 90 and 85 percent of the contained nickel and cobalt, respectively. The nickel was selectively recovered from the leach solution by solvent extraction and was then stripped from the loaded organic with dilute sulfuric acid to provide a nickel-rich electrolyte. Treatment of the raffinate with hydrogen sulfide resulted in the recovery of cobalt as a sulfide. The only contaminant in solution was magnesium which was removed by ion exchange or precipitation. In this process the energy requirements are relatively low and except for minor operation losses, only coke and oxygen are consumed.

Jan 1, 1975

By Changwoo Lee, Jan M. Mutmansky

"This paper results from the research at The Pennsylvania State University into establishment of standard procedures for characterization of respirable coal dust performed by the Generic Mineral Technology Center for Respirable Dust and supported by the U.S. Bureau of Mines and the Mining and Mineral Resources Research Institute at The Pennsylvania State University. The research performed within this particular project is oriented primarily toward standard methods of sampling and characterizing respirable coal mine dust underground so that the chemical, physical, and morphological characteristics are known and can be related to the incidence of coal workers' pneumoconiosis (CWP) in Pennsylvania.The research was initiated by con¬ducting a search of the literature to determine what coal and geologic variables may be related to CWP. The effects of coal rank, free silica content, the mass of respirable dust, and the level of trace elements were the major variables studied. It seems to be evident that the free silica content, the rank of coal, and the mass of respirable dust are the major concerns in defining the causes of CWP. However, based on the literature survey, the authors have concluded that verification of the causes of CWP is a multivariate problem and must be analyzed in an appropriate statistical manner.The results of a multivariate analysis of ten trace elements recorded on Pennsylvania coals are presented. Five of these trace elements were found to be of use in differentiating one coalfield from the others. Of these five elements, chromium and zirconium showed a strong positive correlation with the rank of coal while strontium showed a negative correlation.The design of the field sampling work and its application in future research is the final topic discussed. The sampling plan is oriented toward continuous miner sections with eight-stage impactors as the collection equipment. All of the field work will be conducted in the coal measures of the Allegheny Formation and above with both dust and channel samples being collected in the same mines.Coal workers' pneumoconiosis has been an important topic of concern to miners, mining engineers, and epidemiologists for decades. The general cause of the dis¬ease, the inhalation of coal mine dust, is well known, but the specific coal and geologic variables that affect the incidence and severity of the disease are still subject to debate and study. The primary objective of this study is to identify those variables of Pennsylvania coals that contribute to the CWP problem. To accomplish this task, a field sampling program is to be conducted to relate the characteristics of the coal dust, the coal seam properties, and the geologic variables to the occurrence of CWP.The first year of this study has been involved with both a literature review and experimental work oriented toward identification of causal variables related to CWP. The results of this work are presented here along with plans for implementation of the findings in future research.The previous studies of CWP causal variables have been conducted by scientists, engineers, and medical personnel. Many different types of studies have been performed with emphasis on interpreting the effects of dust mass concentration, mineralogy of the coal, the rank of the coal, and trace element concentrations upon the incidence of CWP in various coalfields. Most of the research has been conducted during the last two decades, with the British Isles, West Germany, and the United States being the primary countries involved.The review of the literature was conducted to determine which variables are likely to warrant further study in Pennsylvania. Previous research studies have related CWP to free silica and other mineral content, the rank of coal, the mass of dust in the working place, and the trace elements in the coal and lung dust. In the following sections, each of these topics will be discussed and analyzed."

Jan 1, 1988

By Bernard Porter

The rate of the heterogeneous reaction between reactor-grade yttrium and lithium fluoride in lithium fluoride-yttrium fluoride mixtures was measured using a quartz spring balance. At 950° C the magnitude of the rate of reaction is 10-5 grams of yttrium/cm2-sec. The heat of activation for the reaction is 38.3 kilocalories per mole of LiF. A surface-controlled mechanism is proposed in which LiF is adsorbed on the yttrium metal surface. An activated complex is formed when additional LiF reacts with the adsorbed LiF-metal site. The activated complex then decomposes to the products) which are lithium metal and YF3. The importance of the reaction in the electrowinning of yttrium metal from fluoride electrolytes is discussed.

Jan 1, 1967

By R. L. Handy

The objective of this research was to devise and test an apparatus to rapidly evaluate the cohesive and frictional strength of coal in situ, in order to increase the safety and percentage of coal recovery from underground coal mines. During the first year device was designed utilizing the bore-hole shear test principle from soil shear strength testing: Two opposing corrugated plates are forced outward to exert a controlled contact pressure against the sides of a previously bared hole, and then the plates are very slowly pulled along the axis of the hole to cause shearing of coal in contact with the plates. Results with the device are expressed in terms of a friction angle[_] and a cohesion c. The [ ] angles obtained from an Iowa coal arc in close agreement with and fall between results from triaxial and direct shear laboratory tests on the same coal. The measured cohesion was found to be much less than from the comparable laboratory tests. It may be increased by pre-stressing and other techniques to embed the shear plate teeth for the first shear test point.

Jan 1, 1973