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By A. A. Berk

The Bureau of Mines devised a test nipple for the field study of corrosion in the condensate-return lines of Federal heating plants. Corrosion surveys, made with this device, showed that the deterioration of the piping was caused principally by carbonic acid in the steam condensate. Corrosion problems were brought under control when the carbonic acid concentration in the condensate was decreased. In many instances, this was effected by decreasing the total carbon dioxide content of the feedwater; in others, the condensate acidity was neutralized with volatile, alkaline chemicals. Filming treatment with octadecylamine, reported successful in controlling return-line corrosion in industry, was much less effective in Federal area-heating plants. Laboratory study by the Bureau disclosed that octadecylamine is unstable in heating systems. Analytical methods were developed for this chemical and its degradation products in heating-plant condensate. Field surveys, in using these methods, confirmed the instability of the filming material. Laboratory tests showed that the degradation products are not useful film formers. Since filming treatment has little effect on condensate corrosivity, the piping was corroded where it was not coated by the treatment chemical.

Jan 1, 1962

By Richard J. Bielicki

This Bureau of Mines study estimates the number of major pieces of coal- mining equipment that will be required to produce 950 million tons of marketable coal in 1980 and 1.2 billion tons in 1985. The coal tonnages were projected in the intermediate coal supply scenario of Project Independence Blueprint (PIB). The equipment projections were determined by consideration of historical trends and by evaluation of information from equipment manufacturers and mining companies. The ability of the manufacturers to meet the projected equipment demands was also determined. It was concluded that equipment supply offers no presently discernible constraint to mining 1.2 billion tons of coal in 1985. A shortfall in projected production for the intervening years, however, is probable owing to anticipated shortages of draglines.

Jan 1, 1976

By P. M. Gruzensky

Several experiments have been carried out in efforts to evaluate qualitatively a variety of electrolytes for refining bismuth. Most extensive work was done with the basic tartrate, hydrochloric acid, and hydrofluosilicic acid electrolytes. Deposits that are smooth and adherent can be obtained from these three electrolytes if low cathode current densities are employed. All three electrolytes were effective in purifying crude bismuth considerably, with additional purification indicated in each instance by a reelectrolysis step. With the basic tartrate electrolyte best results were obtained when the electrolyte was at 40° C, and contained at least 100 grams of bismuth per liter, An apparent disadvantage was depletion of bismuth from this electrolyte, causing the deposits to become spongy and nonadherent.

Jan 1, 1956

By William S. Roberts

As part of the Bureau of Mines critical and strategic minerals program in Alaska, 34 high-purity chromian spinel samples were analyzed for trace and major element geochemistry and mineralogy. The samples were analyzed by X-ray diffraction, X-ray fluorescence, and chemical techniques. Systematic differences in chemistry are evident when samples collected from the Chugach Mountains and their related extension are compared with chromian spinel samples collected from interior Alaska. Compared with the Chugach samples, the interior Alaska samples have higher average amounts of A1203, Fe203, Ti02, and NiO, have lower average amounts of FeO and Cr203, and exhibit greater dispersion in values. Considerable mineralogical variability of chromian spinel exists between and within individual Alaskan chromite-bearing ultramafic complexes. Of 34 samples analyzed, 25 samples are magnesiochromite, 5 are chromite, 3 are spinel, and 1 is hercynite. As a group the interior Alaska samples have a smaller average unit cell dimension than the Chugach group of samples. The chemical and mineralogical differences between the two groups of samples can be attributed to different genetic histories and may have implications for locating chromian spinel deposits amenable to standard beneficiating techniques.

Jan 1, 1985

By A. S. Swanson

The Babb fault vein in Crittenden and Livingston Counties, Ky. (fig. 1), is one of an extensive series of such veins in the Western Kentucky and Southern Illinois fluorspar district. First operated in 1904, the production to May 1, 1944, was estimated at 143,000 tons of fluorite ore. There are five mines (fig. 2) on the Babb fault zone - Guill ,Kentucky Babb, Delhi-Babb, Eagle-Babb and Howard-Barnes. The Bureau of Mines developed four of these properties by core drilling from July 9, 1943, to May 1, 1944. During that period a total of 8,177.8 feet of diamond drilling was completed in 28 holes.

Jan 1, 1950

By E. A. Clarke

The vapor-phase section of the Coal Hydrogenation Demonstration Plant at Louisiana, Mo., was operated for the first time in April 1949. The run lasted only 10 days because of time limitation (pending plant dedication in May) and the small amount of charging stock available. The primary purpose of the operation was to break in and determine the operability of the equipment and to supplement the operators' classroom training with actual practice by operating the plant under mild conditions. A secondary aim was to obtain data on the hydrogenation of petroleum oil and lignite tar distillate at approximately 10,000 p.s.i. while making gasoline and Diesel fuel oil. Although the operations were carried out under conditions considerably below those used in the plant design, a great deal of experience and data was obtained. As it is not feasible at this time to conduct further vapor-phase operations on similar stocks, this report has been prepared to present and summarize the data obtained through this operation.

Jan 1, 1950

By V. A. Danielson

The Bureau of Mines studied waste disposal methods a1 a coal mine in Kentucky and another in Alabama to develop cost estimates, to provide better knowledge of current practices, and to guide consideration of alternate disposal methods. Costs of the existing waste disposal systems at each mine were estimated using present-day costs of equipment and labor. Costs of waste disposal systems using alternate equipment were also estimated. Although total disposal costs were essentially the same for both operations, reclamation costs will differ because of different reclamation practices.

Jan 1, 1969

By Alice V. Peter

The rare-earth group are among the least familiar of the 92 known elements. Moreover, the relatively few people who have even heard of the rare earths ordinarily regard them merely as very rare elements having unusual names but doubtful commercial application. This typical attitude can be attributed partly to the fact that no commercial uses have been developed for most of the members of the group and partly to the fact that those which do enter into useful articles do so anonymously. Most people speak with a degree of familiarity of the "chromium" plating on their automobiles or household appliances; "antimony" ash trays and cigarette boxes are on sale in many department stores; and "tungsten" lamps and even "molybdenum" steels are advertised in popular magazines. However, the average user of a pocket cigarette lighter is not conscious that the important sparking element is a "flint" made from ferrocerium, and if he does chap on to inquire about the composition he is likely to be told that it is "sparking alloy", "misch metal", or 'pyrophoric alloy." Similarly, the wearer of spectacles made of "Crookes" or other tinted glass probably is not aware that the light softening effects are due to the presence of rare-earth oxides, or that the arc light on his street may owe its brilliance to cerium fluoride in the carbon electrode. Despite a variety of practical applications, however, most of the rare-earth metals still must be listed as scientific curiosities. In fact, little is known as to the properties which may make them useful products at some future date. Meanwhile it is important to note that Nature has been relatively generous in her distribution of the rare earths and that adequate supplies of most of them will be forthcoming when these elements have proved their worth as commercial products.

Jan 1, 1935

By M. L. Skow

Large tonnages of the manganese ores found in Aroostook County, Maine, are refractory to conventional mineral-dressing techniques and to the common chemical- extraction procedures. The Maple Mountain-Hovey Mountain ores are typical of this type. Because the most promising method of recovering the manganese from these ores has been a chloridizing roast in which the ground ore is in contact with gaseous hydrogen chloride, preliminary batch tests were made with a fluidized bed. On the basis of these tests, it was concluded that fluidization, with careful control of operating conditions, could be employed for this cloridization and warrants further study. Selective volatilization of the iron at 600° C. was unsuccessful. An operating temperature of approximately 950° C. was necessary for a practicable rate of volatilization of manganese chloride. Hydrogen chloride contents of 10 to 100 percent of the fluidized gas gave essentially equivalent manganese recoveries with an 80- minute retention time, For shorter periods reaction was more complete with the higher hydrogen chloride concentrations. At the 80-minute retention period the lower hydrogen chloride concentrations volatilized somewhat less iron and also improved the physical operation of the process. Fluidization gave results superior to comparable tests on chloridization in a fixed bed.

Jan 1, 1956

By James D. Brown

The Bureau of Mines has written a computer program in FORTRAN to facilitate the calculation of concentrations from X-ray intensities in electron probe microanalysis. Philibert's absorption and Castaing's secondary fluorescence corrections are used; no atomic number correction is included. Background and dead time corrections are applied to the data before calculating the relative intensities. Data from any type of electron probe microanalyzer can be used with the program.

Jan 1, 1965

By Nan C. Jensen

Modern high-temperature metallurgical processes have created a demand for raw material for furnace parts and lining that not only will with-stand high temperatures is but will not react with the substance being melted in the furnace. Spark-plug insulators, laboratory ware, tanks for the glassmaking making industry, and saggers and kiln furniture for the chinaware and pottery trades also must be made of materials hat have high melting points. Among the minerals that can be employed for such refractory uses ore those commonly known as the "sillimanite group' -kyanite, andaluste, sillimanite, and dumortierite - and the allied minerals topaz and pinite. Consideration of the occurrence, properties, qualities, uses, and sources of supply of these commodities and the markets for them constitute the subject of this paper. General Features of Kyanite and Related Minerals Kyanite, andalusite, and sillimanite ire composed of three elements - aluminum, silicon, and oxygen ? and are called aluminum silicates. The have

Jan 1, 1943

By B. J. Moore

This publication contains analyses and related source data for 234 natural gas samples from wells and pipelines in 21 States and 1 foreign country. All of the samples were obtained and analyzed during calendar year 1975 as a part of Bureau of Mines investigations of the occurrences of helium in natural gases of countries with free market economies. This survey has been conducted in the United States by the Bureau of Mines since 1917. In late 1965, the survey was expanded to include foreign gasfields. The analyses published herein were made by mass spectrometer and n special helium analysis apparatus, which are described in Bureau of Mines Bulletins 4862 and 576.3 The results of the investigation of the occurrences of helium are published annually to make the information available as soon as possible to the gas industry and the public in general. Seventeen previous publications have presented the results of 10,831 gas analyses prior to 1975. The first 3, Bulletins 486,4 576,5 and 617,6 contain analyses and related source data on 5,218 gas samples collected from 1917 through 1960. The other 14

Jan 1, 1976

By Jos. R. Guiteras

This paper has been written to describe briefly the mining and milling of gold and silver ores in the Black Canyon and neighboring mining districts in Yavapai County, Ariz. The description of present operations is the result of a 10-day visit to the region by the writer in March 1936. Acknowledgments The author is indebted to earlier writers on the geology and mining in this regions and to the mine managers and their staffs, whose courteous cooperation has made possible the assembling' of material for this paper. Individual acknowledgments are made in the text.

Jan 1, 1936

By G. L. Oldright

[This paper is the fifth 4/ of a series of publications on smelting in the load blast furnace. The objects of this investigation are to determine the conditions obtaining within the blast furnace by direct experimentation, and to correlate the behavior of the furnace at various tines with the main factors governing the operation of the blast furnace, and metallurgical losses.]

Jan 1, 1929

By J. D. Warne

The ferberite district of Boulder County, Colo., has been an important producer of tungsten since 1900. During World War I, high prices for tungston concontrates resulted in a brief period of intense activity, and the production in 1917 was 2,707 tons of 60 percent W03 concentrates. Production declined thereafter, and in 19.2 the tungsten produced in Boulder County represented about 4 percent of the Nation's output, being exceeded only by the scheelite production in California, Nevada, and Idaho. Boulder County has boon an important source: of tungsten in the Korean emergency; the present report does not describe this recent activity, as it will be covered by a future publication. Tungsten occurs in small ore shoots of narrow and irregular veins. Most of the ore shoots have been found outcropping on the surface. Core drilling; has been used by the larger operators to explore for new veins and to locate extensions of known veins.

Jan 1, 1953

By R. L. Grant

[p(,ton~to'rs 'ar-IV uscG.. to explode 9crnli .... sible c}:plosivcs, dynamites, or other hiGh uxplosives. This ?,...!xplosion or detr)nation is brought about by th\.:J energy which i liberated as a cOl":"Lb' nation of concusBion and heat wl1en the ? detonator is fired. 'm Ot:18t? I'l(jrds~ liThe detonator is the key VI: ich unlocks the enerGY of a llgh? explosIve""? (8) :1/. Being sensitive nd latently dangerous, detonators ITl.ust lTIeet t\V0 primary requirerDentr: They must be ..;.afe to handle and IT. list? detonate' when (l,esired, the ... eby iIr.parting deton:l.tion to the explo8ivc cJ.1Cire-e.]

Jan 1, 1941

By Charles J. Cohen, Donald F. Reed

"INTRODUCTION AND ACKNOWLEDGMENTSThis report supplements a previous report on work done in this same area 4/ but covers only the period from November 1945 to November 1946. The project was established in 1943 to investigate magnetite deposits in the northwestern Adirondacks by geophysical surveying and diamond-drilling for the purpose of increasing iron production in the eastern United States.In its program of investigation of mineral deposits, the primary objective of the Bureau of Mines is the more effective utilization of our mineral resources, that they may make the greatest possible contribution to our national security and economy. The policy of the Bureau is to publish the facts developed by each project as soon as possible after its conclusion. Maps showing the detailed magnetic surveys of the deposits and anomalies discussed in this report are on open file at the offices of the Bureau of Mines, College Park, Md., and at the University of the State of New York in the office of the Director of the State Science Service, Educational Building, Albany, N. Y.The Mining Branch, Lowell B. Moon, chief, conducts preliminary exami¬nations, performs the actual investigations, and prepares the final report. The Metallurgical Branch, Oliver C. Ralston, chief, analyzes samples and performs beneficiation tests.The chemical analyses included in this report were made at the Eastern Experiment Station of the Bureau of Mines at College Park, Md., under, the general supervision of J. B. Zadra, chief, College Park Division, Metallurgical Branch, and the immediate direction of Dr. Alton Gabriel, in charge of the laboratory service unit."

Nov 1, 1947

By R. O. Dannenberg

The Bureau of Mines conducted laboratory investigations with the objective of developing an alternative process for recovering cobalt and copper from complex sulfide concentrates. Processes currently used depend largely upon precipitation techniques to remove impurities and recover cobalt from sulfate liquors prepared by oxidative pressure leaching of the sulfide concentrates. The Bureau conducted bench-scale research on a process for treating cobaltite concentrates, comprising (1) oxidative pressure leaching, (2) jarosite precipitation followed by H202 oxidation and pH control to remove iron and arsenic, (3) copper solvent extraction with a mixed hydroxyoxime-amine extractant, (4) copper electrowinning from recirculating acidic strip liquor, (5) selective cobalt extraction from copper solvent extraction raffinate with a phosphinic acid extractant, and (6) electrowinning of cobalt from a recirculating weak acid strip liquor. Overall cobalt and copper recoveries were 91.7 and 84.1 pct, respectively. Electrowon products assayed 99.8 pct Co and 99.89 pct Cu.

Jan 1, 1987

By G. H. Gronhovd

This report describes the design and initial operation of a slagging gasification pilot plant installed by the Bureau of Mines at the Lignite Research Laboratory, Grand Forks, N. Dak., in 1958-59. The tests covered in this report were conducted over a period of about 2 years, beginning in April 1959. The pilot plant was designed for eventual operation at pressures ranging from 400 to 600 p.s.i.g. (pounds per square inch gage); however, for the preliminary test reported here, the gasifier was fitted with a low-pressure slagging section and operated at atmospheric pressure and at 80 p.s.i.g. The reason for using a low-pressure slagging section for initial operation was to facilitate modifications in design during the development of a reliable slagging procedure.

Jan 1, 1962

By William H. Pomroy

This report describes Bureau of Mines research that led to the design, prototype fabrication, and successful proof-of-concept testing of an improved stench fire-warning system for underground noncoal mines. Stench systems are the most widely used means of warning driers in underground noncoal mines of fires or other emergencies. A stench system alerts miners that an emergency condition exists by injecting an odorant into the mine air. Although stench warning systems have been used successfully for over 60 yr, present systems suffer several serious shortcomings, including odorant toxicity, unreliability of warnings, widely varying stench concentrations, and others. In 1980, the Bureau began a research program to upgrade the stench warning system. The resultant system overcomes the deficiencies of existing systems by substituting tetrahydrothiophene for the commonly used ethyl mercaptan stench odorant, and through the use of a specially designed stench injector. The improved injector reliably meters stench fluid into either ventilation-air or compressed-air streams at a precisely controlled rate. Prototype hardware has been fabricated and proof-of-concept tested under bath laboratory and in-mine conditions.

Jan 1, 1985