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By B. McFadzean, P. E. Ngoepe, P. P. Mkhonto, J. Taguta

The adsorption of heterocyclic collectors such 2-mercaptobenzothiazole (MBT), 2-mercaptobenzoxazole (MBO), 2-mercaptobenzimidazole (MBI) and their derivatives on pyrite form a basis in understanding the flotation reactivity that may be applicable in a wide range of sulphide minerals. This study uses a computational and experimental approach to determine the heat of adsorption of MBT, MBO, MBI and modified MBT collectors onto pyrite surfaces. Computational calculations found that the adsorption energies were in the order: MBO > MBI > MBT. The heterocyclic collectors were adsorbed in their thiolate form on the surface. In the case of the pyrite (100) surface, the MBT adsorbed through the exocyclic sulphur atom, while MBO and MBI adsorbed through the exocyclic sulphur and N atoms onto the 5-coordinated Fe atom. The (111) surface was found to be more reactive and different adsorption mechanisms were predicted, where the MBT exocyclic sulphur atom bridged on the 5- coordinated Fe and surface 2-coordinated sulphur atoms, while the N atom adsorbed on the 5-coordinated Fe atom. In the case of MBO and MBI, dissociation of the exocyclic sulphur atom from the collector occurred with subsequent interaction with the surface 5-cordinated Fe and 2-coordinated S atoms. This resulted in the collector carbon atom adsorbing on the surface 2-coordinated S atom, while the N atom adsorbed on the 5-coordinated Fe atom. The adsorption of the modified MBT was found to be more exothermic than the MBT, which showed that introduction of a –CS2 group on the exocyclic sulphur atom improved the affinity of MBT on the surface, and was thus a better flotation collector. The computational results were supported by experimental enthalpy of adsorption measurements and microflotation tests. The chemistry of the heterocyclic thioamides is complicated by the fact that they can exist in a number of tautomeric and ionic forms at different pH’s. This is discussed in relation to the flotation and calorimetric data.

Jan 1, 2018

By C. S. Gundewar

Indian National Steel Policy envisages ambitious three fold rise in steel production by the year 2020. This paper covers the iron ore industry in India which cater to the need of iron ore requirement of Indian iron and steel sector as well as export commitment in addition to addressing the industry?s key concern to attain the same. The main contents are (i) resources and its exploitation; covering status of exploration, reserves and resources, province wise occurrences, distribution, nature of mineralization and generation of fines, etc ; (ii) use of iron ore in iron and steel making, covering physical and chemical requirements for pig iron and sponge iron production; (iii) ore characteristics and beneficiation practice in vogue; (iv) projected steel demand and requirement of quality iron ore and provision thereof; (v) recovery of iron values from in situ low-grade ores and stacked fine rejects (-10/-6 mm) inclusive of slimes (-0.15 mm) from tailing ponds; (vi) agglomeration of fine concentrates preferably by pelletization; (vii) measures to augment iron ore availability for future requirements.

Sep 1, 2012

By Alireza Javadi Nooshabadi, Kota Hanumantha Rao

Formation of hydrogen peroxide (H2O2), an oxidizing agent stronger than oxygen, by sulphide minerals during grinding was examined. It was found that pyrite (FeS2), chalcopyrite (CuFeS2), sphalerite ((Zn, Fe) S), and galena (PbS) generated H2O2 in pulp liquid during wet grinding and also when the freshly ground solids are placed in water immediately after dry grinding. Pyrite produced more H2O2 than other minerals and the order of H2O2 production by the minerals was found to be pyrite > chalcopyrite > sphalerite > galena. The pH of the water influenced the extent of hydrogen peroxide formation with greater amounts of H2O2 produced at highly acidic pH. Furthermore, the effect of mixed sulphide minerals, i.e., pyrite-chalcopyrite, pyrite-galena, chalcopyrite-galena and sphalerite-pyrite, sphalerite-chalcopyrite and sphalerite-galena on the formation of H2O2 showed increasing H2O2 formation with increasing pyrite fraction. There is clear correlation of the amount of H2O2 production with the rest potential of the sulphide minerals; the greater the rest potential of a mineral the greater the formation of H2O2. This study highlights the necessity of revisiting the electrochemical and/or galvanic interactions between sulphide minerals, and interaction mechanisms between pyrite and other sulphide minerals in terms of their flotation behavior in the context of inevitable H2O2 existence in the pulp liquid.

Jan 1, 2014

By Hongchun Lou, Yan Zhang, Xianjun Lu

"The potential of Fe(NO3)3 modified attapulgite was assessed for the adsorption of phosphorous removal from aqueous solutions. Natural attapulgite was modified by Fe(NO3)3, and thus the composite adsorption materials could be obtained. Also phosphorous adsorption characterization on the iron-coated attapulgite was investigated in this research. Taken overall the results suggested that phosphorous adsorption capacity could be improved markedly by adopting ferric modified-attapulgite. The optimum phosphorous adsorption were developed in the experimental conditions of the solid-to-liquid Ratio 1g/L, the initial phosphorous concentration 5 mol•L-1, reaction time 120 min, temperature 25 ? and pH=4.0, the removal efficiency is 92.28% for the modified attapulgite. In comparison of batch experimental results of phosphorous adsorption onto natural and iron-coated attapulgite, it has provided much more likely the same change trend. On the other hand, the outcomes of this analysis indicated that ferric modified adsorbent was notably influenced by adsorption element over natural attapulgite. The Freundlich isotherm adequately described the adsorption course of phosphorous onto ferric modified-attapulgite with the correlation coefficient R2 goodness of fit of 0.9690."

Jan 1, 2014

By J. Kolacz

A new optical sorting system based on a complex image analysis and high definition imaging has been developed by Comex. The image analysis is based on high definition cameras of different types and advanced filtration tools for verification of waste particles. Different mineral properties are used to identify the processed material. The system is further combined with a high speed rejection mechanism based on FPGA technology and operating in real time conditions. This provides a minimal error when removing waste particles from the sorted material.

Jan 1, 2014

By J. B. Yianatos

A practical an interactive model to describe the operation of a flotation bank of mechanical cells was developed based on the hydrodynamic and metallurgical characterization of large industrial flotation cells. Thus, the mineral grade and recovery, as well as the stream properties along the flotation bank can be described in terms of the operating variables. The model was built considering the flotation bank as a distributed system, so the solution for the water and solids mass balances, per size classes, for each single cell, are sequentially solved. Also, each cell was described by two distinct zones, the collection zone characterized by the flotation rate constant and the froth zone characterized by the froth recovery. The mineral feed was described in terms of the mineral species and particle size classes, using a rectangular flotation rate constant distribution. Also, the effect of changing the actual operating variables (air flowrate, pulp level, pulp density, pulp flowrate, etc.) on the mineral collection process, in the collection (pulp) zone, was considered downstream along the bank. The froth recovery of floatable mineral has been estimated by measuring the mass flowrate of particles entering the froth by true flotation together with the concentrate mass flowrate (ton/h). The mass flowrate of collected particles at the pulp/froth interface level was calculated from direct measurement of bubble load (ton/m3) and gas flowrate (m3/h). Flotation recovery is mainly related to the froth depth and air flowrate. All parameters considered in the model have been adjusted from direct measurements in plant site. Also, the effects of other operating variables such as reagents dosage, top of froth grade, or froth discharge velocity are presently under study. This procedure has been tested using data from industrial rougher operations consisting of flotation banks with 5 cells to 9 cells in series, and different cell sizes, such as 45m3, 130m3, 160m3 and 250m3. Thus, it has been shown that the model approach is a powerful tool for flotation cells diagnosis, operation and development of new control strategies, as well as, to evaluate the effect that de-sign and operating variables have upon the collection and froth zones performance in large flotation cells.

Jan 1, 2014

By S. Jeon, N. Hiroyoshi, N. Kitajima, S. Tanaka, M. Ito, R. Pongsumrankul, C. B. Tabelin

"Gold (Au) extraction is inefficient when crushed waste mobile phones (WMPs) are directly leached by ammonium thiosulfate likely because of the cementation/precipitation of dissolved Au in the presence of base metals like copper (Cu), iron (Fe) and/or aluminum (Al). This study applied physical separation techniques to remove base metals as well as plastics and concentrate the Au containing fractions from WMPs prior to leaching. Coarse fraction of crushed WMP (+2-5.6 mm) was pretreated by jig and magnetic separation to remove plastics and base metals like Fe, Cu, and Al, while the fine fraction (-2 mm) was pretreated by flotation, and float and sink separation. The leaching results showed that Au extraction increased in both of the size fractions. In the coarse fraction, Au extraction increased by as much as 2-fold after pretreated (from 4 to 7%). Improvement of Au extraction in the fine fractions after pretreatments were even more dramatic. Au extraction increased from 4 to 61%. These results indicate that physical pretreatment to remove co-existing common metals and plastics is effective to improve Au extraction from WMPs. INTRODUCTION Global sales of mobile phones are expected to increase steadily in the foreseeable future because a lot of people buy newer phones with upgraded and more advanced functions almost every two years, which leads to the higher generation of waste mobile phones (WMPs). WMPs contain a wide variety of materials including plastics, glasses, base metals and precious metals such as gold (Au). Among all the valuable materials in WMPs, Au accounts for over 80% of its total metal price (Park et al., 2017), so recovery of Au from WMPs is needed."

Jan 1, 2018

By A. Boehm

Mineral selective flash roasting (Steiner process) in oxidizing atmosphere was tested successfully for the efficient low intensity magnetic separation of siderite from ankerite and other gangue minerals within the ore of the Steirische Erzberg, Austria. The calcium, magnesium and manganese containing siderite turns selectively into a ferromagnetic oxide phase while ankerite remains paramagnetic. The expulsion of CO2 increases the volume specific surface depending on the selected temperature. Unlike pure iron oxides absorbing SO2 below 530°C, the calcined siderite (enriched in the magnetic product of the Steiner process) acts as a sorbent for SO2 between 500 and 820°C. The effect was studied by thermogravimetric analysis and particle bed tests complemented with neutron thermo diffractometry (D20/ ILL). The energy input was simulated with the help of a tube furnace. The composition of the artificial combustion gas permeating the bed was close to that measured in pilot scale tests (6 % CO2, 12 % O2, 700 vpm SO2). The evaluation of data relating the SO2 variation in the off gas monitored by electrochemical cells to the actual phase composition revealed an intermediate ferrite phase as absorber. During the rapid decomposition in oxidizing atmosphere starting at 500°C the occurring siderite alters to a (CaO, MgO, MnO)Fe2O3 ferrite as an intermediate phase accompanied with sudden SO2 absorption. SO2 disintegrates the ferrite structure forming MgSO4 and MnSO4, taking Fe2O3 as a catalyst. Ankerite (enriched in the non magnetics of the Steiner process) starts to absorb at temperatures above 1000°C forming gypsum. The findings support the SO2 controlled operation of the Steiner process by ?autodesulfurisation?. It explains aspects of the SO2 implementation reactions within off gas recycling in Austrian sinterstrands. Keywords: magnetising flash roasting, neutron thermo diffractometry, SO2 absorption, siderite, ankerite

Sep 1, 2012

By Gabriel Barrios, Juan Pérez-Prim, Marcelo Tavares

"The application of High Pressure grinding Rolls (HPGR) has been growing in the mining industry for the last 10 to 15 years. The major benefits generally supporting this trend are better energy efficiency, improved grinding capacity, less sensitivity to ore grindability variations and higher metal recovery in downstream processes such as heap leaching and flotation. The HPGR machine comprises a pair of counter-rotating rolls mounted in a sturdy frame. One roll is fixed in the frame, while the other is allowed to float on rails and is positioned using pneumohydraulic springs. The feed material is introduced in the gap between the rolls and is crushed by the mechanism of interparticle breakage. Comminution performance is largely determined by the pressure exerted on the bed of particles by the floating roll hydraulic system. The operating bed pressure depends on the hydraulic system start-up parameters and the loading response of the feed material. The work describes how the coupling of the multi-body dynamic simulation with Discrete Element Method in which particle breakage is described using the particle replacement method, can be effectively used to predict the performance of the HPGR. The model considers important variables as the HPGR rolls geometry and design, the hydraulic spring system start-up parameters and the material loading response, to describe operational key outputs as material throughput, operating gap and roller pressure distribution. The preliminary version of the model has been used to predict the effect of material properties on the operating gap and the load distribution on the surface of the rolls, demonstrating that it can describe qualitatively the HPGR operation, indicating that the model will be a power full tool for the simulation and selection of industrial HPGR units."

Jan 1, 2014

By B. Gorain, O. A. Bascur

"The advent of digital revolution has now enabled us with numerous tools that could be leveraged to transform our operational data into actionable insights. Key opportunities with digitization include better visualization, transparency, integrated planning and execution for value-chain optimization, that results in smarter production, intelligent response to changes in ore, process and equipment conditions, reduce energy and waste along with prevention of asset breakdown, safety and environmental issues. It is important to realize that these digital tools have limited value, from a metallurgical operational context, if we cannot bring-in the appropriate domain expertise along with getting the basics right. The focus within Barrick is to ensure that there is adequate depth of different disciplines built into our platforms along with breadth to integrate other disciplines such as geology and mining for an effective Mine-to-Mill integration. A gold recovery improvement strategy based on optimal Gaudin size distribution, leaching performance monitoring and guidance via feed grade maps is discussed. Simultaneous identification of process and equipment constraints enable finding the best overall conditions for Gold recovery. This paper discusses the methodology, findings, and challenges in the ongoing journey of implementing a Metallurgy Analytics platform that evolves from being retrospectively descriptive to anticipatively prescriptive.INTRODUCTION The last few decades have seen some remarkable advancement in information technology, but recently various digital technologies have resulted in several synergies to deliver innovation in diverse applications. The mining industry has been relatively slow in adopting these technologies compared to the other industries, but this scenario is changing fast. Mining companies globally are going through a series of challenges such as declining ore grades with complex metallurgy, increasing depth of ore bodies, high capital and operating costs, lower productivity, shortage of technical resources, significant pressure from stakeholders to deliver, along with growing environmental and corporate social responsibility issues. Improvement in profitability would need significant improvements in operational performance."

Jan 1, 2018

Goethite ore are the third most abundant source of iron. The overwhelming part of these ore is represented by low-grade varieties which cannot be used in iron and steel industry without preliminary beneficiation. Biomass is a renewable solid fuel, which is feasible for the substitution of coke and coal in the manufacturing due to its lower contents of harmful elements and abundant raw material sources. Utilization of biomass in iron ore sintering process as heating agent and reducing agent contributes to energy conservation and emission reduction. The biomass was mixed together with goethite ore for roasting process to investigate the effects of reduction roasting. The results show that the goethite ore is dramatically reduced and magnetized into maghemite by biomass with the biomass dosage less than 20% and the roasting temperature below 650 oC. When the goethite ore roasted with biomass, the magnetization values could be enhanced more than two orders of magnitude, meets the standard of magnetic separation, which could significantly reduce the iron beneficiation cost. Keywords: biomass, goethite, reduction, magnetization, roasting

Sep 1, 2012

By V. F. Petrov, E. P. Olberg, S. V. Petrov

"The study was carried out using process solutions produced during cyanidation of gold-bearing concentrates from a gold-processing plant. It was found that the water contained a significant portion of thiocyanate (7910.0 mg/L), cyanide was virtually not present. The metals occurred primarily as iron (355.0 mg/L) in the form of ferrocyanide. Cyanide recovery was conducted using an ozone treatment process with reactors developed by the Environmental Department of Irgiredmet. The process design ensured complete utilization (100%) of O3, thus equipment operation safety increased.The recovery of free cyanide from thiocyanate was 76.6%, which corresponded to 5.12 kg of NaCN (100%) per 1 m3 of solution. Recovered NaCN can be used for recycling in hydrometallurgical processes.The operating costs estimation showed that the production cost of a tonne of recovered cyanide was US$1288.7, considering the prices of energy and commercial sodium cyanide in Russia in 2017, i.e. recovered cyanide is cheaper than commercial cyanide by 55.8%.INTRODUCTION Depletion of oxidized gold-bearing ores readily amenable to cyanidation has shifted focus to large-scale processing of primary ores with high sulphide content. Primary ores processing flow sheets involve gravitational and/or flotation concentration with subsequent treatment of produced gold-bearing concentrates. Typically, concentrates reporting to cyanidation contain considerable amounts of sulphur that can interact with CN- and further formation of SCN-. The use of refractory gold liberation methods (bacterial liberation, ultra-fine grinding) provides activation of this side reaction up to complete consumption of free cyanide in a short period. This makes water recycling unviable and impractical.The interaction of the sulphur content in concentrates and cyanide contributes substantially to consumption of NaCN required for efficient gold recovery. Inappropriate consumption of the main reagent achieves dozens of kilogram per tonne of material to cyanidation, and reaches approximately 100% when gold is recovered from activated sulphide-containing products (e.g. by ultra-fine grinding)."

Jan 1, 2018

By Hermann Wotruba, Lars Weitkämper

"Dry coal dressing was popular during the 1950.s and 60.s in many parts of the world. The devices mainly used were air jigs and air tables.The increase in ash and moisture content of run-of-mine coals due to the wide advanced mechanisation of mining mechanisation during and after this period led to that pneumatic devices being unable to treat run-of-mine coals with the desired efficiency. Since the 1960.s almost all new coal preparation plants have been based on wet processes that are highly efficient in terms of coal recovery and their ability to handle damp and sticky run-of-mine coals. (Frankland, 1995)However, water is becoming increasingly costly and the disposal of fine products, containing most of the water, is an environmental concern. There would be significant cost savings and a lower total energy consumption if coal could be cleaned dry. Efficient dry coal treatment would be an interesting solution in desert, arid or cold areas.In Germany one dry coal dressing plant is in operation. The process and the advantages and disadvantages are presented below.Further on new developments in the field of dry density separation of coal are reviewed and analysed. Test results of new dry coal separation methods e.g. new developed air jig and magnetic separator are reported."

Jan 1, 2003

By T. Ueda, T. Oki, S. Koyanaka

"Accurate assessment of the liberation state of crushed ore particles is important for efficient mineral processing. In general, the liberation state is assessed by two-dimensional (2D) measurement of polished ore sample sections. However, this 2D measurement inevitably suffers from overestimation of the degree of liberation, known as stereological bias. This arises from the fact that biphase particle sections of which only one phase happens to have been cut are indistinguishable from liberated particles. To date, several stereological correction methods have been proposed, but their applicability for various types of particles has not yet been sufficiently examined, and this tends to undermine their practicality. We have addressed this problem using a numerical-analytical approach in which various types of biphase particles are modeled, and the 2D sectional information is compared with actual three-dimensional (3D) information. Through simulations, we revealed a general relationship between the internal mineral structure of particles and the stereological bias. Finally, we have developed a unique stereological correction method in which the texture (a 2D pattern characteristic) of particle sections is used to estimate the internal structure of particles, and thereby the stereological bias. KEYWORDS Mineral liberation, stereological bias, texture analysis INTRODUCTION Mineral liberation assessment of 2D particle sections inevitably suffers from stereological bias; that is, overestimation of the degree of liberation. Stereological bias is caused by the fact that a composite particle can be misidentified as a liberated particle when only one phase happens to have been cut in sectional measurement. Stereological bias has attracted attention since Gaudin pointed out its importance in 1939 (Gaudin, 1939). Several attempts have been made to measure the 3D liberation state directly, avoiding the bias, using X-ray computed tomography (Gay and Morrison, 2006; Lin and Miller, 1996; Miller et al., 2003; Miller et al., 2009; Reyes et al., 2017; Videla et al., 2007). These have provided useful information through laboratory testing, but further technical refinement is necessary for practical usage, to overcome the technique’s limitations in terms of resolution, assessment of minerals of similar density, and speed. Therefore, for practical purposes, detailed information regarding mineral phase geometry is obtained by sectional analysis, using automated scanning electron microscopy/energy-dispersive X-ray spectroscopy (SEM/EDX)-based analysis (e.g., with a mineral liberation analyzer (MLA) (Fandrich et al., 2007; Sandmann, 2015)); and the development of an effective method of stereological correction, which predicts the relevant bias and transforms the measurable 2D degree of liberation into its 3D counterpart, is an important research aim."

Jan 1, 2018

Geopolymers are novel engineering materials with the potential to play a highly significant role in the transformation of the construction materials and building products industry in the push to-wards sustainable development. These materials are formed by activation of industrial aluminosilicate waste materials such as coal ash or blast furnace slag with alkaline solutions. Some mineral waste can also be used, either as fillers or as reactive components. The use of waste-based geopolymers results in significant (up to 90%) reduction in carbon dioxide emissions when used in cement replacement applications. In addition to the formation of conventional pre-cast products, these high performance mineral binders are ideally suited to use in the conversion or encapsulation of toxic waste, including radioactive waste, due to their chemical stability and resistance to acid attack. It is the aim of this paper to review recent developments on the science underpinning this ?green? technology, and to discuss the technical and commercial drivers governing the large-scale adoption of the technology. Some of the recent fundamental breakthroughs in the study of geopolymer technology at the University of Melbourne will be presented. Despite the complexity of this reactive sol-id-gel system, progress has been made in the development of a thermochemical reaction kinetic model that has been validated using both calorimetric data and synchrotron kinetic data. Geopolymerization is potentially a disruptive technology, so that it is normal to expect strong resistance from established companies in the construction materials industry. It is increasingly necessary that waste generating industries such as mining collaborate with industries such as construction that could utilize this waste. The world?s first full scale geopolymer plant utilizing waste and re-cycled material has been commissioned recently in Melbourne, Australia, so progress on commercialization will also be presented. The authors frequently present keynote lectures on geopolymer science and technology at materials science, ceramics and construction materials conferences. However, this interdisciplinary technology that is still in its infancy, deserves more attention in the mineral processing and mining industry in view of its potential use in the mining industry, and also in view of the importance of mineral processing techniques in recent advances in geopolymers.

Jan 1, 2014

By B. Csoke

To improve the efficiency of the crushing/screening plant of Bazalt-Középko Kobányák Ltd. (Hungary), the implementation of computer aided quality control is planned. In the current phase, the R & D work aims at the solution of high-priority tasks: 1) Developing the process models, validation of the models by means of industrial measurements. 2) Developing the algorithm for the process control of the crushing/sizing plant. 3) Developing the suitable computer program. To develop the mathematical models of crushing (breakage and probability functions) and to determine the model parameters, the experimental industrial trials were carried out on hydrocone crushers of types Svedala H 4800 EF and H 4800 F, changing the gap size and crushing relatively narrow grain size fractions. Additionally, the parameters of the separation function for the screens operating in the system were determined. It was established that the crushing probability depends on the grain size of the feed (Y) and the gap size (s), so the breakage probability S, for each cone crusher, can be well characterised by the function formed using the ratio of these two parameters: SfYsf==. The distribution of the broken grains can be described reliably using the relative grain size distribution function B(? = x/Y) (usually Schuhmann-Gaudin- or Rosin-Rammler-shaped function). For the screens, the probability function ()2()111/NTx = xd ???---???? is suitable for cha-racterising the separation (where x? grain size, ?-open-area ratio, d ? rectangular screen aperture size, N ? number of appearance of the particle on a screen surface). Using these functions, the comminution circuits were described by means of vector/matrix equations. The calculations and measurements verified the reliability of the developed models and algorithms.

Jan 1, 2014

By P. C. Beuria

Iron ore concentrate contains different mineral phases viz. hematite, magnetite, goethite, kaolinite, and gibbsite. Presence of some of these phases like goethite, kaolinite, and gibbsite contribute to the loss on ignition (LOI) content of the sample. Iron ore fines (pellet feed) are pelletized for utilization in DRI & BF processes. In the present pelletization technology i.e., straight grate and grate kiln processes, the LOI in the ore should be within the range of 2.0-2.5%. LOI content in the iron ore concentrate is found to be more than 4% after beneficiation of low-grade iron ore. It is therefore difficult to produce good quality pellet because of high LOI content. The LOI content of the sample is a detrimental factor in the pellet making. For effective pelletization, the LOI content in iron ore fines needs to be reduced before pelletization. It can be reduced by fluidized bed roasting. The objective of present work is to understand the kinetics of removal of LOI from iron ore fines. The effects of bed depth, temperature, and residence time on reduction of LOI content in iron ore fines were studied using muffle furnace. The process of roasting was carried out at four different temperatures varying from 400 to 950 °C with a variable residence time of 30, 45, 60 & 75 minutes and at bed depths of 16, 32, 48 & 64 mm. In all instance of experiments carried out, one of the parameters was kept constant. It was observed that at 850 °C and 30 minutes of residence time, there was sufficient removal of LOI in static bed condition even at a high bed depth of 64 mm. Keywords: LOI, pellet feed, fluidized bed roasting, goethite

Sep 1, 2012

By Carin Laubscher, Francis W. Petersen, Jaap P. Smit

Waste streams, such as acid mine drainage, are often characterised by low pH values and high concentrations of heavy metals, dissolved solids, calcium and sulphates. Although lime remediation effectively removes most of the heavy metals as hydroxides, it is less effective at lowering levels of sulphates. Various methods of removing sulphates from effluents exist, such as precipitation with lime, precipitation with barium salts, co-precipitation with calcium carbonate, reverse osmosis, and ion exchange. Mintek developed a chemical precipitation (SAVMIN) process to treat acid mine drainage, which entails the addition of lime to precipitate the metal hydroxides, and the subsequent formation (precipitation) of calcium sulphoaluminate or ettringite. The key to the viability of the new technology lies in the correct use, regeneration and recycling of Al(OH)3 used to precipitate the ettringite. The water produced by this process is suitable for disposal to watercourses or for agricultural, domestic or industrial consumption. No brines are produced as the salts are converted to solid hydroxides, gypsum and calcium carbonate. The technology has been tested on several different waters in pilot plant campaigns. Results obtained indicate that potable water can be produced (containing less than 200 mg/L sulphate and no heavy metals) as long as the monavalent ions (Na+, Cl-, etc.) are within limits.

Jan 1, 2003

By N. I. Tyushkova

On the basis of detailed studying of mineral structure of ore and treatment products it is established that the given ore refers to oxidized Pb-Zn vein-disseminated ores. Technological special features of the basic ore minerals and the reasons causing their obstinateness that is defined by following features are revealed, presence at dominating quantity difficult to float lead minerals: mimetesite (9.67%), green lead ore(0.48%); non float: bindheimite (2.16%) and plumbojarosite (0.36%) and high assay of oxides and hydrous ferric oxides; also thin, emulsive and submicroscopic segregations of the defined minerals in swamp ore. As a result of researches the scheme of gravitational-flotation treatment was conducted in semi-industrial scale. It allows to receive two concentrates from ore: a lead gravitational concentrate of mark ??-4 with the assay of 55.5 % of Pb and 0.77 % of Zn; and a Pb concentrate of mark ??-7 with assay of Pb of 40.97 % and Zn of 1.39 %. The total assay of Pb in concentrates makes 81 %. The efficiency offered by gravitational-flotation schemes is defined by possibility for recovery of big impregnated lead minerals under gravitation. The use of this method of gravitation has allowed to recover such mineral as beudantide and to exclude irrevocable losses of lead in tails which are connected with this mineral. Scientific value of the presented researches is connected with the fact the problem of extraction of the oxidized minerals of Bb and Zn is rather difficult and insufficiently studied. Keywords: flotation, oxidized forms of Pb and Zn

Sep 1, 2012

By F. Burat

The present research covers the results of experiments carried out with high frequency vibration screen on dewatering of coal fines. In the tests, the addition of surface active reagents was studied employing a high frequency vibrating screen. To increase the efficiency of mechanical dewatering processes, ultrasonic treatment was applied along with surfactants and optimum dewatering conditions were obtained. The moisture content of the feed material was from 82.5% to 41% by the optimization of operation parameters including the angle of the screen, vibration frequency, feed rate and screen opening size. Optimum parameters obtained in dewatering processes carried out with the vibrating screen were kept constant and the effects of surface active reagents and ultrasonic treatment on dewatering were investigated. Finally, the moisture level of the material was further reduced from 41.0% to 37.66%.

Sep 1, 2012