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By D. G. Hulbert

"Mineral processes are complex operations that have been modelled, controlled and simulated by diverse technologies. A review is given of some models of mineral processes in the literature. A new variation of a dynamic process model of flotation is presented. Process models, describing real and relevant physical variables, give a good understanding and good qualitative simulations, but can sometimes require prohibitively difficult and extensive parameter estimations. Process control is usually best done on operational plants by the fitting of system models, which can home in on the plant?s observability, controllability and optimisation. System models can be of a form amenable for use in appropriate techniques for controller design and implementation. The control of milling circuits is discussed in some detail. While simulators use models to predict dynamic or steady-state information, part of their strength lies in their ease of use and their ability to test different types of specifications. Some results are given for a flotation circuit simulator that can be made to solve virtually any permutation of specifications.INTRODUCTIONThe development and application of appropriate technology can lead to better operation of mineral processing plants in industry, so that substantial benefits can be obtained from improved throughputs, efficiencies and product qualities. This paper addresses some of the principles and methods used in the quest for the development and exploitation of such technology. Although the design of processes is often the motivation for modelling and simulation, this paper also targets the use of modelling and simulation for the control and optimum operation of mineral processes. The two processes given the most attention here are flotation and milling.Technologies used in mineral processing range from simple to very complex. Simple technical principles, such as mass and component balances, can yield some simple and effective strategies for modelling and control. However, minerals in particulate form have such complex physical and chemical properties that there appears no end to the complexity that emerges, as more and more factors are taken into consideration in the pursuit of better results and understanding. The situation is aggravated by the complexity of mineral processing plants, which have spatially variable conditions within process units, and complicated interactions between these units."

Jan 1, 2003

The status of utilization of copper ore resources, and the application and development of biohydrometallury technology in the world is reviewed. Based on the characterization of Zambia?s copper resources, biohydrometallurgy technology is shown to be a practical approach to extract and utilize the enormous low grade copper resource, such as ore tailings and low grade copper ore in this country. Through the cooperation of CSU, China and MMMD, Zambia, ?CNMC-CSU Demonstration Base of Biohydrometallurgy Technology in Zambia? was launched and several biohydrometallurgy plants are being constructed. This indicates that the biohdyrometallurgy technology would be applied soon in Zambia and in the whole Africa. Biohydrometallurgy technology stands as an efficient alternative to the traditional pyrometallurgy process and it can be the key to unlock mineral resources value. Keywords: biohydrometallurgy, low grade copper ore, Zambia, Central South University

Sep 1, 2012

By Q. Shi

An investigation into the hydrophobic aggregation of ultrafine smithsonite in surfactant solution has been undertaken through a combination of hydrophobic flocculation experiments, zeta potential measurements, surface tension measurements, and contact angle measurements. The experimental results have revealed that the behaviors of hydrophobic aggregation were closely correlated with the particle hydrophobicity, but they were not lowered byte change of the particle surface charges due to surfactants adsorption. On the other hand, the liquid (solution) surface tension (?LV) plays an important role in hydrophobic aggregation, and the hydrophobic aggregation could not occur below the critical liquid (solution) surface tension (?c). Meanwhile, this flocculation has been observed to require sufficient stirring strength and magnitudes of kinetic energy input to achieve the maximum aggregation degree. From the microflotation results, it has been found that the flotation kinetics response of smithsonite fines is markedly improved due to sufficient stirring strength, and the stirring strength influenced the floc flotation in a manner quite similar to their influence on the hydrophobic aggregation, suggesting that the formation of hydrophobic flocs is a promising means to recover smithsonite in the fine size range.

Sep 1, 2012

By R. B. Shu

A moderate thermophilic microorganisms, has been isolated (45?) from a typical sulphide mine in the region of Mo Jiang located in the southwest of China. The culture has been used to extract copper from chalcopyrite concentrates obtained from De Xing copper mine. The majority of experiments were carried out in 300mL Erlenmeyer flasks containing 150mL volumes of mineral suspension. Effects of some variable parameters such as solids concentration, pH and the concentrations of inorganic nutrients on the bioleaching of chalcopyrite obtained from De Xing copper mine were investigated. For a given concentrate the most important factor affecting the fractional copper extraction was the size of the mineral particles. The overall rate of leaching was found to be limited by the area of mineral surface. The attack started in cracks and genetic defects and finally reached the whole chalcopyrite surface. As a consequence of this, the ore showed strongly cracks. The additive of ferrous sulfate increases the bacteria activity, but did not improve chalcopyrite bioleaching. The results indicate that the nature and relative proportions of the various minerals present have been shown to be important factors.

Jan 1, 2014

The ball level and pulp load play a key role in the operation of industrial scale ball mills. These two operating variables have a significant influence on the performance of the ball mill and any attempts to optimize these devices require manipulating either one or both of these variables. There are several models that can be employed to perform simulations to optimize the performance of industrial ball mills. However, most of these models require ball load and pulp load measurements as inputs to calibrate the model. The changes suggested by the simulator also provide operating regimes that involve moving either the ball level or pulp load and sometimes both of these variables. A ball mill model coded in JKSimMet was used in conjunction with the Sensomag to optimize the secondary ball mill at Waterval concentrator in South Africa. The results show that the perfect mixing ball mill model can be used in conjunction with the Sensomag to optimize the performance of the secondary ball mill.

Sep 1, 2012

By H. J. Cao

Valuable elements could be extracted by microorganism ferment fluid from bauxite, which mainly due to bacteria acid namely organic acid. And after leaching, reclaiming the remainder organic acid in leaching solution was an important procedure for bauxite leaching process. the re-searching status about organic acid reclaiming process from bauxite ore bioleaching solution was summarized. Common processes for recycling organic acid from bauxite bioleaching solution in this period and their advantages and disadvantages, research aspects which need being confirmed for the future were Indicated

Jan 1, 2014

By S. K. Chaudhuri

With a growing emphasis on maximizing the value by rapidly deploying it across their assets, mining firms are eager to identify any issues that may hinder such efforts and to refine their approaches to overcome them. As such a CDE vision can be considered realized when the following components are addressed and functioning as intended - People: the right resources working together and efficiently to achieve shared goals, Process: well-defined workflows mapped out for key value processes, Technology: availability of the correct tools and applications to increase efficiency in work execution and Locations: regional locations/ sites that need to be linked for collaboration and information exchange. For the above vision, an approach that considers the degree of interaction between the roles in metallurgy operations, mineral resource planning, mine engineering, plant operations, logistics and infrastructure, and which accounts for the current technology states across these groups to determine sub-processes where the impact of a CDE will be the most is critical. In effect, CDE is more about transforming an organization?s operational philosophy than a technology driven project. This paper examines the definition and components of a CDE in a mining context. Real-time operations co-ordination, maintenance interventions, production analysis and optimization processes are examined along with current state technologies and manual processes as candidates which are likely to result in most benefits from collaborative work processes. Finally, the paper examines technologies that can be used to further enable a collaborative working environment.

Sep 1, 2012

By D. Govender

Theoretical flotation models suggest that there is a positive relationship between bubble-particle collision rates and turbulent kinetic energy dissipation. Fine particle flotation performance is generally enhanced by increased collision frequency and hence higher energy dissipation. Contrarily, increased turbulence in the rotor-stator region is related to higher detachment frequency of the coarser size range. Therefore, the optimal modes of recovery for the ?fine? and ?coarse? size classes are diametrically opposed. Industrial applications have previously confirmed that applying greater power to flotation slurries yields significant improvements in fine particle recovery. However, recovery of the coarser size class favors a different flotation environment. An improvement in the kinetics of the fine and coarse size classes, provided there is no adverse metallurgical influence on the intermediate size ranges, is obviously beneficial to the overall recovery response. Managing the local turbulent kinetic energy dissipation, and hence the power imparted to the slurry, offers the benefit of targeting the particle size ranges exhibiting slower kinetics. FLSmidth recently introduced the practical implementation of this concept. In principle, it decouples flotation regimes where fine and coarse particles exhibit preferential recovery. In the case of naturally aspirated machines (Wemco®), it is referred to as Hybrid Energy Flotation? and incorporates at least three phases: ? Standard flotation machines (standard energy input, rpm, rotor size/type) at the beginning of the row, where flotation is typically froth phase limited and operational, and set-up parameters have a limited influence on the recovery. ? Higher-powered flotation machines (high rpm, high power rotor size/type) at the end of the row to improve fine particle recovery. ? Lower-powered flotation machines (low rpm, low power rotor size/type) to enhance coarse particle recovery. In evaluating the effect of turbulent kinetic energy on flotation performance, the spatial distribution and its effect on size denominated recovery needs to be evaluated. The mean energy dissipation rate is a measure of the bulk energy input, but CFD-based models offer a more introspective view of flotation sub-processes. A CFD-based flotation model is used to highlight the effect of turbulent dissipation energy on attachment and detachment rates. Preferential collection zones for ?fine? and ?coarse? particles are predicted for both forced air and naturally aspirated machines. Keywords: CFD-based model, attachment, detachment, energy dissipation, hybrid energy flotation?, forced air, naturally aspirated

Sep 1, 2012

By B. McFadzean, J. Taguta

The enthalpy of immersion is the heat change arising from the replacement of the solid-gas interface with the solid-liquid interface when a solid surface is immersed in a liquid. Although immersion calorimetry has been established as a valuable and reliable means of determining solid surface properties such as wettability, it has seldom been applied in mineral processing research. In this study, precision solution calorimetry was employed to measure the enthalpies of immersion of different minerals in water. The enthalpies of immersion were then related to the first-order flotation rate constant as determined by the microflotation technique. The same measurements were also made on sulphide minerals whose surfaces were modified to different degrees of hydrophobicity using different percentage coverages of amyl xanthate collector. The enthalpy of immersion technique was capable of distinguishing and ranking minerals according to their wettability. All mineral types and collector-treated minerals conformed to the same relationship that was found between the enthalpy of immersion and the flotation rate constant. This conformed, empirically, to a power law equation. As the enthalpy of immersion decreased, there were large increases in flotation response for very small changes in hydrophobicity. In addition, a critical enthalpy of immersion (CEI) was found, above which no flotation could occur. The scatter in the data points could be corrected for by adjusting the rate constant using the density of the minerals to produce a robust relationship between the rate constant and enthalpy of immersion. These results have shown that the enthalpy of immersion is able to indicate both the natural mineral hydrophobicity and the extent to which collectors can render a mineral hydrophobic. This technique has considerable potential to be used as a sensitive and accurate measure of mineral surface wettability in order to predict flotation performance.

Jan 1, 2018

By Jacob Masliyah, Zhenghe Xu, Lujie Yan

"Understanding adsorption mechanism of polymeric organic process modifierssuch as carboxymethyl cellulose (CMC) on talc hasbeen a major challenge due to anisotropic nature of talc basal planes and edge surfaces. The main objective of this study is to investigate the adsorption of CMC on the basal planes and edge surfaces of talc.Smooth basal plane and edge surfaces of talc were prepared successfully by simple cleavage and sophisticated ultramicrotome cutting method, respectively. The prepared surfaces were characterized by atomic force microscope (AFM) imaging to be sufficiently smooth for colloidal probe force measurements using AFM. Anisotropic surface charge characteristics were determined,with the basal planes to carry a permanent negative surface charge and edge surfaces featuring a pH-dependent charge characteristic. The adsorption of CMC on talc basal plane and edge surfaces at pH 9 in KClaqueous solutions of various ionic strengths wasinvestigated by in situ AFM imaging technique. Themorphology of adsorbed CMC on talc basal planes and edge surfaces was found to be significantly different, due to different binding mechanisms involved. Interaction of CMC with the talc basal plane was found to bedominated by hydrophobic interactions while its binding with the talc edge surface was mainly through chemical complexation and hydrogen bond. The amount of CMC adsorbed on both talc basal planes and edge surfaces increased with increasing ionic strengthof solutions. The methodology developed in our study opens the door to probe polymer adsorption on anisotropic phyllosilicate surfaces, which can help us better understand the mechanism of polymer adsorption on specific mineral faces."

Jan 1, 2014

By A. Y. Senchenko, Y. V. Kulikov

"The most common technique for selection of grinding equipment is the Bond method implying determination of a ball mill work index (BWi). The method is perfect for greenfield projects where a ball mill must be sized to grind an ore to 80% passing 75-100 µm. Finer grinding will require application of specific correction factors to a standard equation since initially the method was not designated for sizing of fine (minus 75 µm) grinding mills. Significant issues are related to selection of grinding equipment for treatment of originally fine materials when the standard procedure is not applicable. In 1984, Levin published his special technique titled as “A proposed test for the determination of the grindability of fine materials”, where he offered to use the standard Bond ball mill for determination of a specific grinding energy. However, this method did not meet with wide recognition. In 2017, Institute TOMS under guidance of JKMRC’s specialists performed a testwork aimed at verification of a new universal technique for determination of grindability of initially fine materials. An object was to test three aged tailings samples for the subsequent modelling of comminution circuit and evaluation of potential throughput of the existing ball mills with final grind size of ?80 passing 53 µm. In parallel with development of the universal approach, TOMS’ specialists carried out tests according to the Levin method in order to compare the data resulted from two methods. The results from lab ball mill testing on three products following the alternative test methods are presented in this paper along with the testing methodology and results analysis. Specific energy was calculated for regrinding of the materials to the required size. Difference of the examined methods and assessment of their applicability for sizing of full-scale equipment are explored."

Jan 1, 2018

By H. M. Yang

Structural alteration of pyrophyllite during mechanical activation in a planetary mill was investigated by X-ray Diffraction (XRD) and Fourier Transform Infrared Spectroscopy (FTIR) techniques. Mechanochemical effect markedly promotes the decrease in reflection intensities with increasing the grinding time. Prolonged grinding causes the pyrophyllite to become the amorphous structure. It can be indicated that pyrophyllite is very susceptible to alteration by grinding. Crystal size (d006) of pyrophyllite appears to be a limit after 2h grinding. IR spectroscopy analysis shows a little alteration in the bands of pyrophyllite after mechanical activation. The results indicate that the ordered structure of pyrophyllite is destroyed and lattice deformation occurs. Porous silica was then successfully prepared via leaching the mechanically activated pyrophyllite. Pyrophyllite was first ground for 6 h. Ground samples were subsequently leached with 4 M hy-drochloric acid at 80 °C for 2 h to produce porous silica with specific surface area of 188.1 m2/g, total pore volume of 0.18 mL/g and average pore size of 3.9 nm from N2 adsorption analysis. Otherwise, the porous silica obtained from direct leaching of the original pyrophyllite only has a specific surface area of 4.3 m adsorption analysis. 2/g and total pore volume of 0.03 mL/g. It is inferred that grinding is favorable for the formation of microstructure pores. It offers a simple and convenient route for the preparation of porous materials from natural minerals.

Jan 1, 2014

By H. Gallardo, J. Yianatos

Flotation is a separation process in which mineral recovery depends on the particle surface properties. The selective collection of particles by air bubbles requires hydrophobic mineral surfaces. Hydrophobicity can be selectively induced on a valuable mineral surface by means of reagents. For this purpose, it is required that mineral grains in the ore become physically liberated or exposed in the particle surface after grinding. The grinding process generates three types of particles according their exposed surface in the floatable mineral: locked particles (0-10%), associated particles (10-90%) and liberated particles (90-100%). Locked particles have low floatability, and they typically show low recovery (<20%), while liberated particles have a high floatability and can be easily recovered (98-100%) at different particle sizes (10-150 µm). The main challenge in the flotation process is the recovery of associated particles. These particles typically have recoveries of 20-80%, but strongly depend on the particle size, particle surface liberation and collector dosage. Recent studies on particle floatability by size-liberation have significantly contributed to improving the characterization of flotation processes. In this work, a study of flotation recovery of associated particles of 10-90% liberation is presented for particle sizes (10-150 µm) and collector dosages (5-40 g/ton). In this work historical data on galena recovery based on particle cross-section composition of galena was used, assuming they represent an acceptable estimate of particle surface composition, as shown by some previous researchers. The results showed that galena recovery can be well represented by a model consisting of the interaction of a linear function and a Gamma distribution function to account for the liberation and the particle size effects. Consequently, an alternative approach for modelling the recovery of associated mineral (10-90% liberation), with a reduced number of parameters, was developed and validated.

Jan 1, 2018

By P. Condori

In spite of the importance of the slurry transport and discharge in autogenous and semiautogen-ous (AG/SAG) mills, it is evident that a more comprehensive and useful model is still required. Semi-empirical models used up to now have many limitations and cannot be used beyond the ranges in which they were developed. The breakage of particles as they are transported along a mill com-plicates the experimental analysis and the modelling of the transport process within the mill. The interaction of the grate discharge and the pulp lifters, with the added issue of backflow from the pulp chamber into the mill, makes the discharge modelling process difficult. In order to overcome these difficulties, a mechanistic approach has been applied. The general transport and discharge model was subdivided into four independent models: Flow through the charge, flow through the grate, flow in the pulp lifter, and flow-back. This paper gives an overall description of the modelling approach and discusses in particular the modelling of transport of fluids through the charge. In order to evaluate and calibrate the model, experimental work was carried out. To evaluate the gradient pressure under different conditions of charge packing and flow rate, a specialised experimental rig with a highly sensitive pressure gauge was used. Preliminary results identify the differences of the charge and grate on the restriction of flow. The existence of a dynamic voidage in our particular system was more evident and as a result, a semi-empirical correlation for the voidage was developed. In general, results show that the me-chanistic model derived from Ergun?s equation for flow through a packed bed can be satisfactorily adapted.

Jan 1, 2014

By Y. F. Guo

Laboratory scale experiments were conducted to produce titanium-rich material from Panzhihua ilmenite. The results showed preoxidation with sodium salt additive especially for Na2B4O7 signif- icantly advance the reduction of iron in Panzhihua ilmenite. Acceleration mechanism of preoxidation with Na2B4O7 has been studied here. The maximum metallization of iron 92% can be obtained under conditions of preoxidation at 850? for 30 min and subsequent reduction at 1100? for 150 min. The rusting separation technique to reduced ilmenite has been further studied, obtaining titanium-rich product with TiO2 over 82% and the recovery of TiO2 above 97%.

Jan 1, 2014

By T. C. Alex

Mechanical activation of gibbsite [?-Al(OH)3] is the theme of this paper. Industrially prepared gibbsite used in the study has a mono modal size distribution with a median size, d50=110 µm. Mechanical activation of this gibbsite has been carried out in a planetary mill at ambient conditions. Mechanical activated gibbsite samples are characterised in terms of particulate characteristics, structural characteristics and reactivity. As a result, of milling, mono modal size distribution of the unmilled gibbsite changes to a broad multimodal distribution. Size reduction has been sharp in the initial stages of milling; median size reduces to ~7 µm during 15 min of milling. Thereafter no decrease in median size is observed; rather it is found to increase gradually with further increase in milling time, indicating particle aggregation. Morphological studies of milled gibbsite have shown that the platelets forming the agglomerate are separated first; the separated platelets then undergo breakage. Aggregation of particles sets in the later stages of milling as a result of increased surface area and surface energy. X-ray diffraction (XRD) and transmission electron microscopy (TEM) studies have clearly revealed the changes in gibbsite structure during milling. Analyses of XRD data show that the crystallite size of gibbsite decreases as the milling time progresses whereas its microstrain is found to increase. Accumulation of energy in the structure is the result in both cases. TEM micrographs with signs of defects leading to disordering of gibbsite structure complement the XRD results. Reactivity of milled gibbsite, decrease in its deydroxylation temperature and increase in alkali dissolution, is found to increase with mechanical activation. Increased reactivity of milled gibbsite is found to have a strong correlation with the BET specific surface area. Keywords: mechanical activation, gibbsite, alkali dissolution, thermal dehydroxylation, reactivity

Sep 1, 2012

By Q. Zhang

This paper, by studying the surface properties of pure dolomite minerals separated from representative marine sedimentary rare earth-bearing phosphate ores in Zhijin, Guizhou, aims to study the effect of different anions on the ? potential of dolomite. The research findings showed that the dolomite mineral had a point of zero charge (PZC) at pH 6.5, and the PZC shifted towards lower pH values with addition of anion SiO32- and PO43-. However, addition of anion CO32- and F- resulted in higher PZC values. Keywords: dolomite, ? potential, PZC, anion

Sep 1, 2012

By R. Mukherjee

Consistency of Run-Off-Mine (ROM) quality plays an important role in mineral processing which is not very often talked about. The major impediment is limitation of sampling ROM ore, which makes processing plants to run without any realtime feedback on ore quality that comes in. The process of direct determination of Run-Off-Mine (ROM) ore quality is expensive and time consuming as drawing and preparing representative samples from blasted muckpiles are constrained by large sample size and inherent heterogeneity in terms of size and chemistry. In absence of techniques for direct measurement of quality, monitoring and control of ROM, feed to the processing plant at Joda East Mine, like all other iron ore beneficiation plants worldwide, is largely based on blasthole sampling and subsequent chemical analyses of blastcone chips. While such indirect methods proves to be more accurate for representing whole of a mining block or blasted muckpile (~30-50KT/blast), it is indeed a challenge to ascertain and predict day to day input quality for a part there off. This eventually leads to a gap between predicted and actual ROM quality, resulting in difficulties in process control, in turn, and leading to wide swings in product quality. Hence, it is imperative to bridge the gap between predicted and actual ROM quality by arriving at means, which ensure consistent plant feed grade to deliver consistent output. The paper discusses an efficient and affordable alternative for effective prediction of ROM alumina which has been developed by integrating blasthole quality database in GPS based Truck Dispatch System (GPS-TDS) at Joda East Mine. Initially, GPS-TDS has been installed for optimizing production parameters only, but this development has helped in further utilization of GPS-TDS for real time quality monitoring by improving ROM grade prediction and scheduling from several ore blocks in active mining areas. Keywords:run-off-mine (ROM), blast hole, feed grade, GPS-TDS

Sep 1, 2012

By Gus Van Weert, Samuel A. Bolorunduro, David B. Dreisingerm

"As deposits of high-grade base metal sulphides become depleted, attention must be focused on the treatment of complex sulphides, which contain significant fractions of precious metals such as gold and silver. Acid pressure oxidation is a promising process for these materials and the recovery of silver and gold will improve the economy of the process. Gold can be recovered from the oxidised residues, however, silver is incorporated into the jarosite specie and the cyanidation of the resulting residue yields very low recovery.Pressure oxidation of various complex sulphides was carried out at 110-150°C in sulphate media with additions of potassium iodide under conditions similar to industrial autoclaving. The resulting residues were subjected to cyanidation. High recovery of silver, up to 98%, was achieved because its incorporation into lead-hydronium jarosite during the pressure oxidation was minimised, while its deportment into the cyanide-soluble silver iodide was favoured. Silver recovery decreased slightly at high temperatures (140° and 150°C) because of the enhanced stability and kinetics of lead-hydronium jarosite, but this could be overcome by increasing acidity and iodide concentration of the autoclave slurry."

Jan 1, 2003

The value creation with kaolin clays depends on removing the colored impurities which manifests in to higher brightnessone of the most sought after properties on applications such as paper coating, paint and others. The processes for removing impurities include magnetic separation, froth flotation and selective flocculation. While the flotation and selective flocculation processes exploit the physico-chemical differences between the surface properties, the magnetic separation uses the bulk magnetic susceptibility differences between the diamagnetic clay and ferro- and para-magnetic nature of the impurities. The major advantage with magnetic separation remains high yield and no or low reagent usage. However, the magnetic separation technology suffers from low separation efficacy when finer colored impurities (<1 µm) are encountered in the feed. Use of stronger magnetic intensities during magnetic separation showed limited success; nonetheless the adverse effect due to finer size range remains a dominant effect even at 5 Tesla magnetic field. Furthermore, the presence of diamagnetic colored impurities irrespective of their sizes can not be removed. Cytec Industries has recently developed a ?bolt-on? chemical enhancement technology for magnetic separation that essentially embraces the best product performance attributes of flotation and selective flocculation while keeping the chemical usage to a minimum level and using the readily available magnetic separation equipment. The paper will outline the technology and illustrate optimization work at pilot plant magnet on a wide variety of crude accommodating the process needs and plant limitations. The major advantages of chemical enhancement technology to magnetic separation include: 1) simple extension to existing magnetic separation technology, 2) ability to produce comparable product in quality with cost effectiveness compared to flotation and selective flocculation, 3) removal of impurity minerals over wide size range, 4) removing non-magnetic impurities, 5) providing robust process with high process yield and 6) operation-friendly nature. Furthermore, chemical enhancement technology for magnetic separation has also emerged as a platform for re-moving impurities at low levels in other mineral systems as well.

Jan 1, 2014