Search Documents

By Y. Wang

Phosphates and fluorides are used as regulators for the removal of silicates from diasporic-bauxite both in direct and reverse flotation. While using dodecylamine chloride as a collector, micro-flotation studies showed that sodium hexametaphosphate has stronger depressing power on diaspore than on silicate minerals with increasing sodium hexametaphosphate concentration at pH 6.5, but sodium fluorosilicate shows poor depression on diaspore with increasing sodium fluorosilicate concentration at the same pH. Zeta potentials of diaspore and silicate minerals become more negative both in the presence of sodium hexametaphosphate and sodium fluorosilicate. Adsorption density studies indicated that the adsorption density of sodium hexametaphosphate on diaspore is much higher than that on silicate minerals at the concentration of 75 mg/L. FTIR spectroscopy studies show that sodium hexametaphosphate interacted with the Al atoms exposed on the diaspore and silicate minerals surfaces to form P?O?Al bonds through the P02 groups. It is possible that sodium fluorosilicate interacted through F- or [SiF6]2- with silicate minerals surfaces based on the analysis by AES.

Jan 1, 2006

By R. P. van Hille, A. W. van Zyl

The BIOX® culture, aiding liberation of arsenopyrite/pyrite occluded gold, is inhibited by thiocyanate (SCN > 1 mg/L); precluding the recycling of tailings water up-stream of the bioleaching circuit. The activated sludge tailings effluent remediation (ASTERTM) process is a biological process that was developed to facilitate water recovery and treat waste water on-site (to achieve a SCN concentration < 1 mg/L) to be recycled or disposed of. The aim of this study was to investigate the effects of changing temperature and SCN loading on the SCN degradation ability of the mixed microbial population clue to seasonal temperature changes and fluctuations of SCN concentration in the waste water.

Jan 1, 2011

By L. S. Trenholme

"Belleterre Quebec Mines, Limited, is a subsidiary of Mcintyre Porcupine Mines, Limited. The property is in Guillet township, Quebec, 45 miles due east of Haileybury, Ontario. It is accessible by 72 miles of gravelled road from New Liskeard, Ontario (Fig. 1).Gold production at the property commenced in 1936 and to March 31st, 1945, had exceeded $9,000,000. For the past 3 years the milling rate has averaged 325 tons a day and the gold recovery about $14 a ton.GENERAL GEOLOGYThe rocks of the district consist of Keewatin-like volcanics conformably overlain by Timiskaming-like sediments. Together they form the remnant of an easterly plunging anticline engulfed by granite (Fig. 2). The pregranite intrusives consist of diorite, gabbro, and ultrabasic rocks, occurring as dykes, sills, and irregular stocks. Dykes of porphyry and lamprophyre presumably related to the batholithic intrusive are common in this area. The veins of quartz are also probably derived from the batholithic intrusives. A few dykes of Keweenawan-type diabase have been observed."

Jan 1, 1954

By G Anders

The effectiveness of two types of powder used in long-wall slashing was compared. The evaluation of the results can serve as a good example of how the application of statistical methods to underground test data can help to minimize the number of tests to be carried out. The conclusions are stated concisely, including a definite assessment of the reliability of the tests. Introduction AN assignment at the Algom Nordic mine called for a performance comparison between 70 per cent Cilgel B and 75 per cent Dygel in longwall stope slashing, particularly taking into account, in both cases, the build-up of bootlegs as dependent on hole deviation. Stopes were usually 8 to 10 ft. high and inclined at about 17 degrees. Starting from a raise, they were widened by consecutive longwall slashes to 60 ft., and, al-lowing for drift pillars, were approximately 300 ft. in length along the incline.

Jan 1, 1964

By Masatsugu Morimitsu

This paper introduces new technology of oxygen evolution anodes which can be applied to produce copper, zinc, cobalt, and other metals by electrowinning. The anode consists of nano iridium oxide particles dispersed in amorphous tantalum oxide matrix as a catalytic layer formed on a titanium substrate. The anode can reduce oxygen evolution potential by 0.25 to 0.55 V compared to commercially available lead alloy anodes and can suppress unwanted side reactions such as manganese oxyhydroxide, lead oxide, cobalt oxyhydroxide which occur during oxygen evolution in the electrowinning solutions. This technology is effective for environmentally friendly electrowinning processes with low energy consumption and less anodic deposition.

Jan 1, 2011

By Joël P. T. Kapusta

Back in 1995, Air Liquide and Union Minière presented a joint paper at the Copper 95 – Cobre 95 Conference in Santiago, Chile, describing the first full scale plant trials of shrouded sonic injection in a Hoboken converter at the Hoboken smelter in Belgium. Almost a quarter of a century later, the technology known as ALSI, or Air Liquide Shrouded Injection, has been tested or commercially implemented in several copper and nickel smelters. Despite these successes, the copper industry did not adopt it widely in the same manner the steel industry adopted the Savard-Lee tuyere in the 1970s and beyond, not even in the way the lead industry adopted it with the Queneau-Schuhmann-Lurgi, or QSL, process. The development and implementation of bottom-blowing smelting and converting technologies in China in the last ten years, however, changed the industry’s perception that high- and ultra-high oxygen injection in copper smelting and converting was indeed possible under specific process conditions. In this paper, I retrace the key learnings of my journey with sonic injection over the twenty five years from my humble beginnings in my early years with Air Liquide, through plant trials and technology implementation in the late 1990s and into the first decade of the new millennium, and ultimately, to the most conclusive proof that the sonic injection design methodology I established is valid, and the calculation tools I developed are accurate. I conclude by sharing my thoughts about whether the deployment of the Savard and Lee legacy within the nonferrous industry was just a pipe dream or whether it will become a reality. INTRODUCTION In the context of lower quality ores and changing economic markets, copper smelters need to continuously innovate and improve to remain competitive and respect their corporate social responsibility engagements. One avenue towards this business, social, and environmental goal is to increase process intensity while lowering fossil fuel consumption to lower greenhouse gas emissions and reducing process off-gas volumes to better capture As and SO2–laden emissions. I believe high oxygen sonic injection for submerged tuyere copper bath smelting and converting is one technology that can help smelters achieve that goal of higher business, social, and environmental performance. Twenty five years ago, when I discovered that the Savard-Lee tuyere had revolutionized the steel industry (Savard & Lee, 1966; Knuppel, Brotzmann, Fassbieder, Savard, & Lee, 1972), I had a dream — or was it a vision? — that within the first decade of the new millennium, modern copper smelters operating submerged tuyere bath smelting and converting vessels will have implemented high oxygen sonic injection and will be reaping the financial and environmental benefits that the steel industry enjoyed in the 1970s. As we approach the end of the second decade of the new millennium, I have to admit that my dream has been all but shattered as the majority of copper bath smelting and converting vessels today continue to operate under bubbling regime conditions. This mode of operation is archaic, still requires tuyere punching and blows at inherently low enrichment levels, particularly in converting, producing large volumes of process off-gases. Under such operating conditions, regulations and emission quotas for As, SO2, and particulate matter oblige smelters to use not just primary or secondary hoods, but sometimes even tertiary hoods. I vividly recall being told, fifteen or twenty years ago when visiting smelters to promote the application of the Savard-Lee tuyere in nonferrous processes, that implementing sonic injection was not economically viable due to the high cost of compressing air and oxygen. Some of the smelters I visited back then have since mandated their engineering partners to design and build secondary or even tertiary hoods. I cannot fathom how secondary and particularly tertiary hoods, with all of their auxiliary equipment and added ducting, could be more economically viable than purchasing and installing a few compressors, expanding the pipeline network for compressed air and oxygen, and installing a new control valve train to feed sonic tuyeres. Besides, adding hoods does not address the problem of As and SO2-laden fugitive emissions at its source but merely provides a costly mitigation for it by capturing larger volumes of process off-gases rather than reducing these large volumes in the first place. Moreover, hooding does not reduce energy consumption nor does it increase process intensity, two aspects that I believe are critical for smelters to remain competitive and sustainable in a deeply changing market environment.

Jan 1, 2019

By K. Poorhaydari, B. M. Patchett, D. G. Ivey

In this paper, some applications of carbon extraction replicas, as samples for transmission electron microscopy (TEM), are discussed. Modern high strength microalloyed (HSMA) steels, used as structural or pipeline materials, have very small grains with substructures. Replicas used in TEM can resolve the grain boundaries and can be used for grain size measurements in cases where the small size of the grains pushes the resolution of conventional optical microscopes. The grain size variations obtained from replicas correlated very well with mechanical property variations, indicated by hardness, in the fine-grained heat-affected zone and base metal of some welded HSMA steels. Replicas are also very suitable samples for precipitate examination with analytical TEM. Advantages and limitations of the application of replicas, as well as some corrections for the estimation of the volume fraction of fine precipitates, are discussed.

Jan 1, 2005

By J. D. Jones

The geographic occurrence of economic mineral deposits presents a variety of problems in modern tailings disposal operations. This paper presents case histories in several sectors of the mineral industry as well as the several stages of operations planning required for new designs, system expansion, reactivation of abandoned systems and upgrading to present environmental standards.

Jan 1, 1978

Agenda ? Introduction ? Inmet?s Operations and Closed Properties ? Inmet?s SECA Philosophy ? Inmet?s SECA Framework ? The Business Case for TSM ? Inmet?s TSM Reporting ? Inmet?s 2004 TSM Performance ? Opportunities for Improvement ? What Have We Learned From The TSM Process So Far? ? Summary Introduction ? Inmet has evolved into a strong TSM supporter ? Inmet is confident that TSM can be successfully and cost effectively implemented by smaller companies ? Inmet?s reporting on economic, environmental and social performance was raised significantly in our 2003 Annual Report ? a signal our commitment to good performance and improvement in these areas ? Our 2004 Annual Report has been further enhanced with the inclusion of our TSM performance

Apr 1, 2005

By J. Dubinski

Passive tomographic imaging is a technique that can be used for assessing seismic hazard in mines with high seismic activity induced by mining. The basic idea behind such an interpretation is the assumption that there is a relationship between high values of seismic velocity and high values of stresses in the rock mass. This relationship was confirmed both in laboratory an in situ measurements and constitutes the basis for rock-burst and seismic hazard evaluation. In the paper seismic tomographic images of seismic P wave velocity and seismic P wave velocity gradient have been presented to determine rock-burst hazard and locate high seismic activity zones in the area of coal panel 306 in Zabrze Bielszowice mine. The zones of high values of P-wave seismic velocity gradient have been found to correlate with the distribution of high energetic seismic events. Passive tomographic images were obtained using modern bent ray tracing tomography algorithm with regularization. Recent study give rise to observation that not only high values of P-wave seismic velocity is important in seismic hazard assessment as many strong seismic events are located in the areas of high values of velocity gradient. This recent observation permits to increase quality of passive tomographic imaging for detection of seismogenic zones and is presented in the paper. The advantage of passive tomography comparing to active tomography is that sources of seismic waves are generated by rock mass itself and costly controlled explosions are not necessary. Another practical limitation of active tomography is the size of study area which usually do not exceed 200 m by 200 m. This restriction does not appear in passive tomography where area of study is usually 2000 m by 2000 m and the tomographic images delineate velocity structure in locations where mining induced seismicity take place. Passive tomography method utilized in analysis of rock mass state in underground mines encounter some difficulties concerned with the numerical stability of optimization algorithms. In the presented approach to passive tomography problem numerical stability is obtained by special regularization method and by application of very stable numerical seismic ray-tracing algorithm.

Aug 1, 2013

By Gordon L. Kidd

The object of this paper is to show the relations of the East Coulee coal area to the near-by Willow Creek, Wayne, Rosedale, and Drumheller areas, all being parts of the Drumheller field. The word ?area? is here used in a more local sense than that employed by Dr. J. A. Allan, whose. &apos;area&apos; is rather comparable with the &apos;mining division&apos; in British Columbia. I have drawn freely from the published information, particularly from Dr. Allan&apos;s report on the "Geology of Drumheller Coat Field, Alberta", and from Dr. E. Stansfield&apos;s paper on " A Chemical Survey of Alberta Coals", to whom thanks are due. The Drumheller field is served by branch lines of the two principal Canadian railways. The C.N.R. traverses the district by its Goose Lake line from Calgary to Saskatoon; and the C.P.R. by a line from Calgary to Acme and then southeasterly to Drumheller, where it effects a junction with the C.N.R., over which the C.P.R. has running rights as far as Rosedale. From Rosedale, a joint line built during the summer of 1928 extends about forty miles down the Red Deer river to the mouth of Bull Pond creek. From that point the C.P .R. turns more southerly to connect with the Bassano-Empress line. The C.N.R., it is expected, will eventually proceed eastward to connect with a transcontinental line. The joint line from Rosedale down the Red Deer river opened up the Willow Creek and East Coulee areas.

Jan 1, 1929

By K. M. Ed

AN explosive is a solid or liquid substance which, when fired by some means, changes into a gaseous product occupying a volume very much greater than its original volume. The great speed at which this change takes place causes the explosive to exert a sudden blow on adjacent material. It is this action which is effective in blasting operations when the explosive, confined in a shot-hole, is fired. All explosives are similar in one respect, in that the change into the gaseous state is accompanied by the production of hot gases or flame. This results from the rapid combustion of the solid or liquid ingredients. Ex-plosives differ greatly, however, in the speed at which the reaction takes place. Black blasting powder, for instance, reacts comparatively slowly, hence the flame persists for an appreciable length of time. High explosives, on the other hand, react much more quickly; consequently, the flame is of much shorter duration. In &apos;closed-light&apos; or &apos;gaseous&apos; coal mines, the use of ordinary explosives is generally prohibited, due to their inherent ability to ignite gas or coal-dust by reason of the flame which they produce when fired. For instance, black blasting powder, which produces a flame of long duration, is not ordinarily considered safe to use in such mines; neither are ordinary dynamites, as their flames, while shorter than that of black blasting powder are, nevertheless, of sufficient temperature and duration to cause ignition of fire-damp or coal-dust. For this reason, specially formulated high explosives, called &apos;permitted&apos; explosives, should invariably be used in such mines.

Jan 1, 1940

By A. F. Robertson

FOR several years, the rock-burst question has been given serious consideration by the operating staff at Wright-Hargreaves mine and, as a result of observations and experiences, several different methods of mining have been developed which are now in use in various parts of the mine. These are described in the following pages. It should be emphasized, how-ever, that these methods, and the views expressed in this paper, are based solely on conditions at Wright-Hargreaves mine. Such conditions may or may not be similar to those obtaining in other mines in the Kirkland Lake area, where ore occurrences, veins, wall-rock, faulting, intrusives, etc., may be entirely different. Size and shape of ore-bodies, composition of the ore-bodies and their surrounding rocks, locations of intrusives and sedimentary rocks, and direction, dip, and strength of faults, all introduce problems that are peculiar to each individual mine. Ground failure&apos; in coal and metal mines is not at all unusual. A variety of systems of mining have been developed to delay movement of large or small blocks of ground, or, in some instances, to take advantage of the fact that ground movement, due to mining operations, is unavoidable. Ground failure may be either slow collapse or it may take place with explosive violence. It is principally with the latter condition that we are concerned in the mines of the Kirkland Lake district.

Jan 1, 1939

By M. Fujikawa

The Kamioka Zinc Smelter was converted from the jarosite process to the goethite process in the year 2000. The reasons for the conversion of the process were that the silica content of the raw material increased and the iron content decreased. The silica easily turns to a gel in sulfuric acid solutions and this causes the solid-liquid separation characteristics to deteriorate. The basic behavior of silica in sulfuric acid solution was investigated and it was found that the goethite process is the most suitable to effectively separate and remove silica from solution. Furthermore, Fe has the capability to remove elements such as Ge that have an adverse effect on zinc electrolysis. This means that, when the Fe content of the raw material decreased, the impurity removal capability also decreased and there was a risk of a build-up of impurities in the process. Iron precipitates in many forms in sulfuric acid solutions. The capability to remove elements such as Ge differs depending on the compound precipitated. Goethite has a higher capability than jarosite to remove elements such as Ge. In this report, the results of applying the process established by investigations of the basic behavior of Fe, silica and Ge in the zinc refining plant are presented.

Jan 1, 2006

By G. P. Gu

The in-service 90/10 cupro-nickel tubes in a water-chiller system suffered from severe corrosion damage during their relatively short service life causing unexpected down time. In addition to downtime, the environmental risk associated with losing refrigerant was also a concern that initiated this investigation, Microstructural investigation using SEM and electron microprobe indicated that pitting corrosion had resulted in local nickel depletion, During the corrosion process, copper appeared to have re-deposited around the corrosion pits accelerating the local corrosion.

Jan 1, 2005

By T. C. WEBB

In New Brunswick, significant potash deposits are intimately associated with rocks of the Lower Carboniferous Windsor Group. To date, two deposits high in sylvinite, up to 20 m thick, have been confirmed at depths between 490 and 1,035 m below surface near Plumweseep and Salt Springs. These areas are currently under development by the Potash Company of America and the Denison-Potacan Potash Company respectively. A third area, near Lower Millstream, is also known to contain potash-bearing evaporites and is now being explored by BP Exploration Canada Ltd. All three areas are situated in the western half of the Moncion Subbasin and are within 25 km of Sussex. Numerous similarities in stratigraphy, thickness, mineralogy and structure suggest that deposition of evaporites throughout much of southern New Brunswick was contemporaneous and extended over a considerable area. Future opportunities for potash exploration in the province thus seem excellent. A number of large unexplored areas remain in the Moncion and Cumberland Subbasins and in parts

Jan 1, 1984

By M. J. Nicol

The leaching of gold with thiosulfate solutions in the absence of ammonia and copper ions was investigated using electrochemical and kinetic methods. In sodium thiosulfate solutions, the electrochemical oxidation of gold was hindered and the leaching rate using pure oxygen as the oxidant was very slow. It was found that the addition of a small amount of thiourea or formamidine disulfide to the thiosulfate solution greatly enhanced the oxidation of gold. However, the enhancement to the overall dissolution of gold using dissolved oxygen as the oxidant was limited. This was attributed to the fact that the oxygen reduction process was unaffected by the additives and remained slow, which limited further improvement to the overall kinetics. An alternative oxidant, the ferric EDTA complex having a reduction potential of approximately 0.12 V, was found to be promising. The cathodic reduction of ferric EDTA was fast and reversible at neutral pH. While the ferric EDTA complex was effective in oxidizing gold, it did not appear to significantly oxidize thiosulfate. A thiosulfate solution containing thiourea and ferric EDTA has been shown to quickly dissolve gold in the form of a powder as well as from gold ores. In the leaching with the ores high gold recoveries of above 90% was achieved with the best performance obtained in neutral solutions (pH 6-7).

Jan 1, 2005

By E. C. Keeley

Some Safety Measures at Ontario Mines The following safety precautions have of late been taken by several of the Ontario mines: installation of water crossovers; washing clown of faces to show-up missed holes; insistence on gloves being worn as a protection to men&apos;s hands; wearing of safety boots and hats by underground men; and wearing of goggles by all men using hammers, starting holes, etc. In the summer of 1924 the Mclntyre mine began experimenting with means of removing powder smoke from headings by installing fans and pipe-lines of various designs, also with different means of introducing water into the air-blast when blowing smoke. By October of that year they had devised a scheme of water connection between the water and the air line, at a distance of about one hundred and fifty feet back from the face, using two valves and a short hose. By this means a limited amount of water could be introduced into the air which blew into the face, resulting in a fine spray of air and water combined. This spray not only helped to eliminate fumes but also introduced fine particles of water into the air, raising it above the dew point, with the result that when these fine particles of water settled they had attached to them fine dust particles, thus eliminating, to a great extent, the injurious dust caused by blasting. The combined air and water is turned on immediately after blasting and allowed to blow continuously for from four to five hours, until the muckers come on shift.

Jan 1, 1931

By G. S. Hume

Introduction O WING to the mineral discoveries which have recently been made in the Great Bear Lake region and the possibility of the need for fuel for transportation and development, it seems.timely ro review available information regarding the oil prospects in the vicinity of Great Slave lake and Mackenzie river, where a vast area is underlain by Palreozoic and younger sediments that undoubtedly are petroliferous. Exploratory surveys were carried out in this area by the Geological Survey and others in the latter part of the 19th century, but it was not until 1920, when drilling for oil actually began, that any serious attention was paid to the oil prospects. This is readily accounted for by the remoteness of the region, the lack of quick transportation facilities, and the shore summer season. Numerous and copious oil seepages had been reported, however, from widely separated localities, and interest was stimulated by the knowledge that these occurred in Devonian strata which had given a remarkable record of sustained production of high-grade oil in the oil-fields of southwestern Ontario. . Accordingly, during the four years 1920 to 1923, inclusive, several parties sent out by the Geological Survey made as thorough an investigation of various parts of the area as seemed warranted at that time, and from these surveys most of our information regarding the details of the stratigraphy is derived. In such a large area, it is inevitable that the lithology and thickness of rocks of the same age would show wide variations, and hence it should be recognized that conditions as regards oil prospects in the vicinity of the west end of Great Slave lake are quite distinct from those that occur near Fort Norman, 400 miles farther to the northwest, and these again are in all probability quite different from those in the less well known Arctic Red River area, 250 to 300 miles still farther north.

Jan 1, 1932

By W. F. James

Introduction The season of 1927, from the point of view of mining development in the area west of Rouyn, was quite satisfactory. Serious prospecting and development&apos; were undertaken over quite a large area, though the results in the matter of discovering new deposits of economic importance were rather disappointing. A large amount of systematic prospecting and geological mapping was carried out in the course of the work, and a considerable body of information collected. A widespread occurrence of sulphide mineralization was noted, chiefly near bodies of older gabbro. The frequent occurrence of pyrrhotite in or near which local concentrations of chalcopyrite were localized, lends support to the idea that such older sulphides as pyrite and pyrrhotite are relatively easy of replacement by chalcopyrite. From the prospector&apos;s viewpoint, areas near the contacts of masses of older gabbro are favourable prospecting ground, and pyrite and pyrrhotite mineralization are favourable indications that massive chalcopyrite may be found where it has completely replaced such sulphides. Pyrrhotite being magnetic is easily located, even where drift covered, by the use of such convenient instruments as the dip-needle and the magnetometer. It is suggested that pyrrhotite bodies, when located, be thoroughly prospected because of the fairly strong probability that they may show replacement by the more valuable chalcopyrite.

Jan 1, 1928