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By Baseer Abdul, Edouard Asselin

Hydrometallurgical leaching of sulfide concentrates of copper and nickel at medium temperature (150°C) produces residues that contain sulfur and iron bearing minerals and phases. During leaching, and depending on various process parameters, iron may be precipitated as hematite, goethite, jarosite or other oxyhydroxides, which may be more or less crystalline. Hematite is the favored precipitate because it is the most environmentally stable and does not ad/absorb as much copper, nickel or other solution constituents during precipitation. However, the low solubility of iron during the medium temperature processing of sulfide ores can favour the formation of poorly crystalline, nano-scale iron oxide/oxyhydroxide phases. In some cases these phases have been positively identified as the metastable ferrihydrite, which transforms into iron oxides such as goethite, hematite and magnetite over time. A better understanding of what may help drive this transformation during leaching would ultimately result in lower valuable metal losses and more stable leach residues. Higher acid concentrations result in increased copper extractions and favor the formation of hematite during concentrate leaching, rather than other metastable phases. Furthermore, commercially available water displacement formula “WD40®” and other novel reagent(s) affect Fe precipitation and sulfur chemistry, leading to very different process outcomes such as improved extractions and larger, more easily separated, sulfur particles.

Jan 1, 2017

By N. Schreithofer, M. Aspiala, R. Serna

The novel attachment timer apparatus presented in this paper serves as a diagnostic tool that allows the detection of changes in bubble-particle attachment probability and therefore floatability caused by alterations in the chemical environment and particle properties. The apparatus consists of six identical capillaries where bubbles with defined size are produced simultaneously in a measurement chamber. The bubbles at the capillary tips are placed in contact with the submerged particle bed for specific time periods, controlled with the help of automatic actuators. The advantage of the instrument is that hundreds of bubble-particle contacts can be measured automatically within a short time period. Microscopic pictures of each measured bubble are taken while recording the movement of the bubble before, during and after contact with the solid particles. The recorded pictures can be used to determine the actual bubble size and its corresponding deviation, and to detect the attachment of particles. The attached particles are collected in a detachable chamber for subsequent characterization. Furthermore, the device is portable and can be taken to the mineral processing plants for quick evaluation of particle-bubble attachment efficiency with particles and process water sampled directly from real processes.

Jan 1, 2017

By M. Jarvis, D. B. Dreisinger, T. Hitchins

Mineral carbonation (MC) has been extensively researched all over the world since it was found as a natural exothermic process to permanently and safely sequester CO2. In order to accelerate the natural process, various methods for carbonation of Mg-/Ca-silicate minerals and other industrial wastes have been studied. It has been found that the MC efficiency will increase with an increase of CO2 pressure, retention time, temperature, mass ratio of Mg or Ca to Si in minerals, specific surface area, and the slurry concentration in a specific range, and with the introduction of an effective catalysts, for example, 1M NaCl and 0.64M NaHCO3 or carbonic anhydrase. However, there still is not a successful industrial application because of high economic cost and slow reaction rate. It is not economic to exploit Mg- and Ca-silicate minerals deposits or tailings to sequester CO2 by MC, due to the cost of grinding and heat pre-treatment and in some cases the whole sequestration process may result in more CO2 emissions than the amount of CO2 sequestered, due to the requirements of energy inputs. The process however, may be profitable as a whole (with carbon credits). It is suggested to combine MC with recovery of valuable metals from ore deposits in order to reduce the cost for MC by cost sharing for mineral recovery.

Jan 1, 2017

By T. Newton, G. A. Bezuidenhout, P. J. Tauetsile, F. Trask

The technology to selectively leach gold, silver and base metals from ores, concentrates, and wastes, using an alkaline glycine solution, has initiated significant interest in using the new technology in various environments such as in-situ, in-place, dump, heap, and vat and agitated tank leaching. It has been shown that glycine acts synergistically with a number of other lixiviants to lower the net consumption of the other lixiviants while allowing low cost glycine solution recovery. Glycine is a non-toxic, stable, environmentally benign reagent that is available in bulk industrial quantities. It has the ability to dissolve most copper oxide and sulfide minerals, as well as native copper, whilst not interacting with acid consuming gangue nor dissolving iron and various or ubiquitous gangue elements. It acts synergistically with small amounts of cyanide to leach gold-copper ores at leach rates higher than either glycine or cyanide on their own, while significantly reducing cyanide consumption and eliminating detoxification requirements. The leaching behaviour of various glycine based systems will be reviewed, followed by the evaluation of the adsorption of gold onto activated carbon. Where the economics merit it, copper can be easily recovered using solvent extraction or sulfide precipitation.

Jan 1, 2017

By C. Feng, D. W. M. Arrigan

Arsenic is often associated with gold mining operations and poses a significant health and environmental hazard. While a number of technologies are available for removing arsenic, none of them is effective under all conditions. Although adsorption is a promising approach, most methods focus on the purification of water under neutral or acidic conditions and tend to be less effective in gold mining process waters, operating under alkaline conditions. In this study, the removal of As (III) and As (V) from both arsenic-only solutions and simulated process waters using composite magnetic nanoparticles was investigated. The nanoparticles consisted of magnetite (Fe3O4) or maghemite (?-Fe2O3) cores covered by various metal oxides with Langmuir adsorption capacities of As (III) and As (V) ranging from 31.4 to 79.1 mg/g and 10.2 to 25.5 mg/g, respectively, in arsenic-only solutions at pH 9. Their adsorption capacities were further recognised by the adsorption tests conducted in simulated process waters. The ability to remove As (III) is of particular importance as it is harder to remove it from alkaline solutions. The magnetic cores allow simple and efficient magnetic recovery of the As-loaded nanoparticles.

Jan 1, 2017

"THE OTTAWA BRANCH, CIM, each year holds a symposium on a subject of topical interest. The symposium this year was on Canada's Offshore Mineral Resources, at which papers were presented by: Dr. Donald G. Crosby, chief, Resource Administration Di-vision, Department of Energy, Mines and Resources, Ottawa; John A. Beesley, head, Legal Division, Department of External Affairs, Ottawa; and David W. Smith, man-ager, offshore exploration and production, Shell Canada Limited, Calgary. Because of the interest which this topic holds for our members, and because of the wealth and significance of information presented, the three papers -representing the first comprehensive review of our offshore resources -are reproduced herewith. The opening remarks of the Chairman, Dr. F. K. North, Professor of Geology, Carleton University, are also recorded, together with a few of the questions asked by the large attending audience. The symposium was held February 13th, and was organized by Dr. W. M. Tupper, chairman of the Branch Program Commit-tee. Differences in the extent of the continental shelf will be noted in the papers. These differences are related to slightly different definitions of the continental shelf by the authors."

Jan 1, 1969

By Erik Richer La Fleche

LEGAL RISKS LEGAL RISKS ARE COUNTRY RATHER THAN PROJECT RISKS OTHER COUNTRY RISKS ARE POLITICAL AND MACRO-ECONOMIC RISKS COUNTRY RISKS ARE EXAMINED AFTER PROJECT RISKS COUNTRY RISKS COUNTRY RISKS INCLUDE: WAR AND ARMED CONFLICT TERRORISM AND SABOTAGE CURRENCY INCONVERTIBILTY AND TRANSFER NATIONALIZATION AND CREEPING EXPROPRIATION GOVERNMENTAL BREACH AND REPUDIATION OF CONTRACT CHANGE OF GOVERNMENT CORRUPTION COUNTRY RISKS FIRST NATIONS AND LANDOWNER CLAIMS LABOUR UNREST SINGLE CAUSE ACTIVISTS REGULATORY AND BUREAUCRATIC DELAYS CONFLICT BETWEEN GOVERNMENT LEVELS ETHIC AND RELIGIOUS TENSIONS INTERNATIONAL SANCTIONS TAXATION CHANGES CHANGES IN LAW

May 1, 2013

By Z. D. Hora

Air hough diatomite is known in many parrs of British Columbia, deposirs of mineable size have only been found in the area between Kam/oops and Quesnel in the sourh-cenrral parr of rhe province. Ar Quesnel, commercial producrion has continued since 1950 from diatomite lenses up ro 35m rhick. OCCURRENCES of diatomite are reported from many parts of British Columbia, but deposits of mineable size are known only from the area between Kamloops and Quesnel. Only Quesnel deposits have yet reached the production stage. Commercial production dates back to 1950, and up until 1979 approximately 22,700 tonnes of diatomite had been produced. Most extracted diatomite was processed until 1980 by Crownite Industrial Minerals Limited in Quesnel to produce an oil absorbent and animal bedding. Smaller shipments are used to make insulating bricks on the lower mainland. Deposits near Quesnel extend 40 km along the western bank of the Fraser River from Quesnel to Alexandria; most production has come from Lots o. 6132 and 906. Di atomite is present as discontinuous lenses up to 35 m thick. Diatomite beds Industrial Minerals in Canada are of Upper Miocene age and are overlain by plateau basalts. Diatomite consists almost exclusively of Melosira granulara diatoms that are usually very small and mixed with variable amounts of clay, ilt and volcanic ash. In recent years, extensive beds of diatomite were identified near the confluence of the Chilcotin and Fraser rivers. Diatomite in this locale is a part o f the Upper Miocene to Pliocene Chilcotin Group of sedimentary rocks that are overlain by olivine basalt and related luffs. A deposit near Red Lake is situated 50 km northwest of Kamloops. Diatomite beds occur in the Tranquille Series of Eocene age and are similar in composition to those in the Quesnel area. The Red Lake deposit is abo ut 4 m thick but its areal extent is only a few tens of hectares.

Jan 1, 1984

By D. M. Ward

"The uranium deposits upon which the Rabbit Lake project story is based are located at the eastern margin of the Athabasca Basin just west of Wollaston Lake in northern Saskatchewan. This paper provides a general review of the exploration history for the major deposits and the influence of an expanding geological data base, which served to guide the continuing exploration programs.A brief description of each of the deposits is provided in order of their discovery and with emphasis upon their relative geological and mineralogical characteristics.The Rabbit Lake and Eagle Point orebodies are monometallic uranium deposits localized by thrust faults within the Aphebian Wollaston Group. The Cof/ins Bay A-zone, B-zone, and D-zone are polymetaflic U, Ni, As, Co (Au , Ag) deposits located within the Helikian Athabasca Group at its unconformable contact with the underlying Wollaston Group. INTRODUCTIONThis paper demonstrates the importance of applying the accumulated geological knowledge, gained through the exploration, mining, and development process, to the ongoing success of exploration programs. To emphasize this point, the basic geology of each of the major Rabbit Lake area deposits will be presented in chronological order of their discovery and subsequent development. These depos its include Rabbit Lake, Collins Bay A-zone, B-zone, D-zone and Eagle Point. The geological descriptions are based primarily upon the detailed observations of many current and former geologist s employed by both Gulf Minerals Canada Limited and Eldorado Resources Limited. Much of the early historical data was obtained from Dr. E.E.N. Smith, formerly with Eldorado Resources Limited. Regional GeologyThe Rabbit Lake area which includes the Rabbit Lake, Collins Bay A-zone, B-zone, D-zone and Eagle Point deposit s, is located on the eastern edge of the Athabasca Basin close to the western shores of Wollaston Lake (Fig. I). The area is in the Churchill Province of the Canadian Shield within the Wollaston lithostructural domain, at the eastern edge of the Athabasca Group. The uranium deposits occur within both the Wollaston Group metasedimentary assemblage of probable early Aphebian age, and the diagenetic ally altered quartz sandstones and conglomerates of the Athabasca Group of Paleohelikian age. Both units unconformably overlie granitoid gneisses interlayered with metasediments and a graphitic iron formation all believed to be of Archean age. All uranium depo sits in the Rabbit Lake area occur in close proximity to the Paleohelikian - Aphebian or Paleohelikian - Archean unconformity."

Jan 1, 1989

Presentation Overview Corporate Overview Kutcho Project History Exploration Development Permitting Capstone -Pursuit of Value Building a mid-tier copper producer focused in the Americas Two operating copper mines; Cozamin& Mintomines High grade and low cost 2010 forecast: 80-85 million pounds of copper in concentrates Total Cash Costs* of ~US$1.10/lb to US$1.20/lb of payable copper produced Significant by-products of gold, silver, lead & zinc Growth potential Further expansions at existing Cozamin& Mintomines High grade copper development: Kutcho project, BC Investments in Nevada Copper & Silver Wheaton 100% North American assets Low risk ?Canada & Mexico ?Conventional operations

Oct 1, 2010

By M. J. Michaud, M. J. Lavigne

"Abstract - North American Palladium Ltd. operates its Lac des Iles open pit palladium mine 85 km north of the city of Thunder Bay, Ontario. The Roby Zone deposit occurs within the mafic/ultramafic Lac des Iles Intrusive Complex (LDI-IC), which was created by multiple pulses of magma of varying composition within several closely spaced chambers. Chaotic lithological distribution, the presence of magmatic breccias, and the rarity of rhythmic layering suggest a dynamic intrusive environment with disruptive magma pulses. As of December 31, 2001, measured and indicated resources for the 950 m long by 815 m wide Roby Zone deposit totalled 159 Mt grading 1.55 g/t Pd, 0.17 g/t Pt, 0.12 g/t Au, 0.05% Cu, and 0.05% Ni at a palladium cut-off grade of 0.7 g/t. The Roby Zone contains an additional 73 Mt of inferred resources at similar grades.The Roby Zone is dominated by varitextured gabbro containing pipes and pods of breccia, and large blocks (~60 m across) of varying lithology. Mineralization at Lac des Iles occurs as: (1) a PGEand base metal-rich magmatic matrix of breccia (breccia ore); (2) mineralized dikes or sills (gabbronorite in North Roby ore); (3) lower-grade mineralization in varitextured units that are host to the distinctive breccia ore and envelope the North Roby ore; and (4) high-grade mineralization associated with strong silicate alteration exemplified by high-grade ore.The close spatial association of the mineralized breccias with both varitextured units and silicate alteration leads to an interpretation that the energetic magma that created breccia was charged with a dissolved fluid, and that this deuteric fluid exsolved at high temperatures to migrate through crystal mush, enhancing crystallization along its pathways, resulting in variable grain size. This transformation occurred at high temperature and produced sulfide-poor, varitextured gabbro-hosted mineralization exemplified by some of the mineralization in the North Roby Zone, and also found throughout the Roby Zone. The association of hydrous silicate alteration with mineralization can be explained by continuing fluid migration during cooling and continued metal transport. Résumé - North American Palladium Ltd. opère la mine à ciel ouvert de Lac des Iles située à 85 km au nord de Thunder Bay, Ontario. Le gisement Roby Zone est encaissé dans le complexe mafique/ultramafique de Lac des Iles (LDI-IC), lequel représente une intrusion polyphasée créée par plusieurs pulses magmatiques de différente composition à l’intérieur de chambres magmatiques fermés. La distribution chaotique des lithologies, la présence de brèches magmatiques, et la quasi-absence de litage rythmique suggèrent un environnement magmatique dynamique perturbé par l’introduction de nouveau magma. Au 31 décembre 2001, les ressources mesurées et indiquées s’élevaient à 159 millions de tonnes titrant 1,55 g/t Pd, 0,17 g/t Pt, 0,12 g/t Au, 0,05% Cu, et 0,05% Ni, pour une teneur de coupure de 0,7 g/t Pd. De plus, la Roby Zone contient 73 millions de tonnes de ressources inférées à une teneur similaire.La Roby Zone est principalement encaissée dans un gabbro de texture hétérogène (varitextured) caractérisé par des cheminées et des lentilles de brèches et des énormes blocs (environ 60 m de diamètre) de plusieurs lithologies. Au Lac des Iles, la minéralisation en EGP et en métaux de base se retrouve dans la matrice magmatique de brèches (breccia ore), dans des dykes ou des sills minéralisés (gabbronorite dans la zone North Roby ore), comme minerai de basse teneur encaissant le minerai de brèche (breccia ore) et enveloppant la zone North Roby. Du minerai de haute teneur est également associé avec une forte altération en silicates dans la zone high-grade ore.L’étroite association spatiale entre les brèches minéralisées et les unités de texture variée (varitextured) et l’altération en silicate suggère que le magma énergique qui a causé la bréchification était chargé de fluides. Ces fluides deutérique"

Jan 1, 2001

By A. M. L. Cushing, S. Kelebek, A. Ghahreman

Iron sulfides are part of many ore deposits affecting flotation separation of non-ferrous base metals from them. Open-circuit potential (OCP), potentiodynamic polarization, and electrochemical impedance spectroscopy (EIS) measurements were carried out with pyrite and pyrrhotite electrodes to investigate their reactivity under various flotation conditions, which involved the use of TETA, SMBS, and their combination. TETA was found to adsorb on the electrode surfaces causing a significant increase in charge transfer resistance of the product formed, which was most significant at OCP. This effect is much less with SMBS, indicating its greater surface reactivity compared to TETA. The combined use of these reagents decreases charge transfer resistance to a greater degree than that experienced with their individual uses. Addition of Cu2+ as a potential activator to this system nearly eliminates the action of TETA on the electrode surface, which can be attributed to sequestration/chelate formation in liquid phase. The relative effects of these reagents on pyrrhotite electrode are similar to that of pyrite. The main difference between the pyrite and pyrrhotite electrodes is that the observed charge transfer resistance on the pyrrhotite surface with each reagent case is significantly lower by 3 to 4 fold. This is compatible with its anodic nature and ease of oxidation since the OCP value of pyrrhotite is lower than that of pyrite. Results are discussed in relation to flotation/depression behavior of these iron sulfide minerals in mineral separation processes.

Jan 1, 2017

By Z. D. Hora

Traditionally, industrial minerals in British Columbia comprise about 10 per cent of the combined value of mineral, coal, petroleum and natural gas production. Over the years a wide variety of industrial minerals have been produced in British Columbia, often with a different level of marketing success. For some products such as building stone, common brick or expanded shale, once strong demand gradually disappeared; for others such as asbestos and barite, new discoveries or new industrial activities created demand and new markets. For yet other minerals such as fluorite, talc and perlite, wider use has been prevented by the small size, poor quality or remote locations of the deposits. Bentonite (1926 to 1944-as a by-product from coal mines) Building stone (intermittently since the mid-1800s) Chromite (1918 and 1929) Over the past years, the list of industrial minerals produced has been expanded to include several new commodities: glassgrade silica sand, magnesite, pumice and silica for ferrosilicon and silicon carbide manufacture.

Jan 1, 1984

By Osvaldo A. Bascur

Business Challenges ? Many Versions of the Truth ? Lack of Enterprise Visibility (Transparency) ? Limited Communication & Collaboration ? Complex Implementation & Maintenance of software ? End user ease of use of information applications ? Responsive to change ? Access to timely information ? Secure computing ? Maturing Workforce Real time Portal - First of All ? Why Move to a Portal - Portals Recaptures the Business User - Broader Scope - Easy Navigation, World Standard - Features of a Portal - User Profile - Delegation (Secure Delegation of Admin Authority e.g. portal\pat) - Single Sign-On ? HUGE

May 1, 2004

By L. Voisin, E. Díaz, V. Montenegro, W. Kracht

Grinding media is of great concern in the mining industry mainly because its consumption represents an important part of the costs during mineral processing and consequently, of the total mining business OPEX. In addition, grinding media consumption impacts directly on flotation performance through negative contamination by corrosion, affecting the pulp chemical potential, complicating the understanding and control of the process, as galvanic interactions between mineral species also occur. In addition, during the process there is also a physical consumption of the grinding media through erosion and impact. In both cases, mineralogy has an important role because pulp abrasion power, chemical reactivity, rheology, hardness and other variables depend on the minerals contained in the pulp and their interactions. In the present study, a geometallurgical and phenomenological model, which describes the grinding media consumption and its relationship with mineral hardness expressed by Bond Work Index, was obtained based on advanced mineral characterization techniques such as Hylogger3TM, X-ray diffraction, X-ray fluorescence and experimental grinding tests using a laboratory mill applied on Chilean copper pulps. The results obtained show that pH has an important effect on grinding media consumption, because corrosion varies with hydrogen ions availability. Also, mineral hardness depends on mineralogical composition, but textural analysis must be performed to have a better description of this property. Finally, minerals present in a sample define the grinding media consumption mechanism, because a sample with harder minerals and a greater value of Bond Work index is capable of protecting grinding media from impact wear, while a sample with lower hardness but with a big sulfide minerals content would be more aggressive with grinding media because corrosion is more important in this case. The geometallurgical model obtained is capable to relate the grinding time, mineral hardness, content of sulfide minerals and grinding pH to estimate the grinding media consumption.

Jan 1, 2017

By Raj Thamburaj

"Over the last few decades, the emphasis on affordability and reduced cost of ownership has necessitated the development of innovative processes to carry out repairs in aero engine components. Conventional weld and braze repairs have evolved into advanced, sophisticated processes using state of the art knowledge in lasers, robotics and materials technology. This paper illustrates past and present scenarios in an attempt to illustrate progress that has been made in this area. The problems encountered in the past have been detailed along with the solutions that have been developed and commercially implemented to address these issues. Apart from technical progress, this presentation also addresses the progress made in business approaches and in Certification/Regulatory issues surrounding aero engine repair. Progress in Technology Repair technologies have also been the embryo from which new and revolutionary manufacturing technologies have evolved as well. Electron Beam Free Forming and LENS are examples of how a completely new manufacturing concept can evolve what was originally only a process to join metals. The current and future potential of these spin offs is discussed providing examples of application. While several problems have been solved over time with the implementation of advanced repair technologies, the demands of the industry have created new challenges. The paper describes these issues, outlines potential solutions and discusses the future of repair technologies in terms of the far reaching influence it is sure to have in design, manufacturing, maintenance management and life extension. Progress in Business Trends.Business approaches to repair and maintenance have also gone through considerable change with the introduction of ""Power by the Hour"" and other similar arrangements between the companies responsible for engine overhaul and the end-users. Program Based Logistics (PBL) is yet another innovation to provide a win-win situation for the repair service provider and the end user. This paper traces the development of these business initiatives and highlights successful applications. Progress in Repair Certification, Regulatory Issues.Understanding of the issues surrounding certification of repairs has also evolved with time and regulatory issues have been clarified considerably. Procedures for analysis and testing are much clearer and ""Check Lists"" are being drafted for certifying repairs on various engine components. The PMA phenomenon has added yet another dimension to the issues regarding certification and these are discussed as well."

Jan 1, 2010

By S. C. Ells

Introduction An investigation of the bituminous sands of Alberta was begun by the Mines Branch, Department of Mines, in 1913. This investigation was interrupted during the period 1916-19, but was resumed in 1920. Work completed in October 1924 has included detailed topographical surveys of extensive areas, examination and sampling of principal outcrops, the mining of trial shipments, laying of demonstration pavements, and a study of methods adapted to the recovery of hydrocarbons from the crude bituminous sand. Bituminous sand consists, for the most part, of clear quartz grains, cemented together by petroleum residuum or bitumen. In form the quartz grains are most irregular, varying from sharply angular to smooth, waterworn shapes. The bitumen has a specific gravity of 1.018 and has a penetration of 9.00 mm. (77° F. 100 grams 1 sec.). The percentage of bitumen associated with the sand varies from 5 to 25 per cent. A large tonnage is available in which the percentage of bitqmen is 15 per cent or over. Production Up to the present time, production has been restricted to requirements for experimental .and demonstration work. The total quantity shipped for such purposes has not exceeded 750 tons.

Jan 1, 1925

By T. W. Cavers

The Dwight-Lloyd sintering machine was the answer to the flue-dust problem of the copper blast-furnace smelter. Then came concentration by flotation, which threatened to eliminate the blast furnace from the smelting field altogether, and again the sintering process solved the problem. As is well known, the sintering process is dual in its function; it expels sulphur from the charge and it converts a powdery material into nodules or chunks that hold together. The charge is ignited on top just as it passes over the edge of the first suction box, and the oxygen of the air that is drawn downward through the charge breaks up the sulphide and oxidizes about fifty percent of the sulphur. The heat produced by this reaction in the upper stratum of the charge ignites that lying immediately below, and, when the pallett has travelled the full length of the machine, the tire has reached the graces and the fine concentrate has changed its characteristics by being partially fused and has become a more or less solid mass. When the Granby Company was smelting its ore as mined, one small D-L machine was adequate for the treatment of the flue dust, but as soon as the policy of smelting the concentrate was adopted, it became necessary to add two large machines to the sintering plant. The three sintering units, of which two are 42 in. by 396 in. and the other 42 in . by 264 in. in hearth area, have a combined capacity of from 370 to 450 tons (dry) of charge per day. The capacity varies directly as the hearth area. The sinter produced is about 88 per cent of the dry charge, or 325 to 400 tons per day. The sintered fines returned for resintering average between 30 and 35 per cent of the charge, but this is not as great a disadvantage as might appear, since the addition of hot fines improves the burning qualities of the mixture. From 50 to 54 per cent of the sulphur is eliminated in the sintering operation.

Jan 1, 1934

By Pingchao Ke, Zhihong Liu

Fe(III)-As(V) precipitates were synthesized from the Fe(II)-As(V)-SO42--H2O system at 90°C in initial Fe(II)/As(V) molar ratios of 4.0 and 5.0, respectively. The synthesis were carried out by introducing oxygen gas into the system to oxidize Fe(II) ions into Fe (III) ions, and at the same time, adding aqueous sodium carbonate solution into the system to neutralize the acid released by the hydrolysis reactions, with the purpose of keeping the pH constant at 1.5±0.05. The precipitates obtained were characterized by XRD, chemical composition analysis, SEM, XPS, and Raman spectrum. The results indicated that the particles in the precipitates were in the morphology of irregular aggregation with their sizes in the range of about 1–4 µm. The precipitates consisted of scorodite, ferric arsenate and amorphous hydrated ferric oxide, of which amorphous hydrated ferric oxide formulated as Fe(OH)x(SO42-)y. The characteristic XPS peaks of Fe-AsO43- and Fe-O in the precipitates located at 711.8 and 713.3 eV, separately, and the existence of amorphous hydrated ferric oxide led to two series of shake off lines developed over the end of high binding energy of Fe2p XPS. The precipitates were stable in TCLP tests at pH 4.93 for 60 hours with the arsenic concentrations in the leaching solutions being 0.27 mg/L and 0.59 mg/L for the precipitates prepared in the initial Fe(II)/As(V) molar ratios of 4.0 and 5.0, respectively. The tests for the long-term stability of the precipitates were carried out by leaching them for 40 days at 25°C under various media in the pH range from 9.50 to 10.57, and the results showed that the precipitates synthesized in this study were much more stable than those by previous researchers.

Jan 1, 2017

By A. J. Hargraves

"It is difficult to quantify comparatively the gassiness of a property. The most common index to gassiness, cubic feet of gas per ton of coal mined, is very arbitrary and does not take into account the geological setting nor the mining operation. The gassiness of a virgin coal in situ can be assessed, but no method is precise and the most accurate methods involve prolonged field and laboratory experiments. In general, gassiness increases with depth. Whereas 'gas' normally implies methane, other gases such as nitrogen, carbon dioxide, etc. may be present in seam gas also. The inflammability of methane is a problem, particularly the explosibility of a methane-air mixture; also oxygen dilution is involved in high gas concentrations and some gases are poisonous even in low concentrations. Cross measuring into a virgin seam is usually not as troublesome as development in the seam, where narrow openings may require strong ventilation to dilute gases exuding from the face and sides. Total extraction presents problems of gas from the working seam, or from adjacent seams, particularly at the return side, or of gas-laden air from the goaf streaming out or sometimes surging out intermittently, again on the return side. In pillar extraction or longwall retreating special roadways may be required to allow the side-to-side and end-to-end flushing of the goaf which is somewhat inherent in longwall advancing. Layering may occur, particularly where ventilation conditions are not brisk. Outbursts of gas from adjoining seams may be induced by sudden rupture of roof or floor in caving workings. Outbursts of coal and gas from the working seam may occur, mostly in development work, under special environmental circumstances. Gas problems may be reduced or eliminated by predrainage of gas ....:. rarely successful from the working seam - usually undertaken from adjoining seams prior to escape of gas released by caving. The ideal solution - general predrainage of gas to the surface from measures prior to mining - has yet to be accomplished. • In the planning of gassy mines it is possible to make an assessment of gas contained in the seams and to estimate what proportion will be released into the mine air, but emission of gas into mine workings is never steady and at present there is no better planning criterion than experience at the mine next door!"

Jan 1, 1973