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By Fathi Habashi, Ernesto Bourricaudy, Fouad Kamaleddine

Ilmenite occurs in black sand at the mouth of great rivers as in India, or as massive deposits like in Quebec Province in Canada. It is unsuitable for processing into pigment or for metal production because of its high iron content and its low grade. Pyrometallurgical and hydrometallurgical methods have been developed to cope with this problem which resulted in the production of two commercial products that became known as synthetic rutile and Sorelslag. Attempts are also underway to produce TiO2 pigment directly from ilmenite. This report presents a newly developed process called the Magpie process, which enables the production of high-grade synthetic rutile (over 95% TiO2) from low grade ilmenite (10-12% TiO2). Naturally, if such process is applied for low-grade ore it can be applied with advantage to high grade material as well.

Jan 1, 2014

By X. J. Luo, F. Zhang

"Metallurgical slag (MS) such as steel slag, copper slag is a renewable resource and its compressive strength exceeds 200MPa in general. Because pure metal slug can easily be mixed into MS, complex recycle system is necessary in order to realize MS’s recycling. Meanwhile, there is high equipment failure rate in conventional crushing system. New crushing systems with inertial cone crusher could solve this problem very well. Recovery rate of MS tailings requires that crushing product can’t contain too much oversize product, so the essential equipment include two crushers and one sieve in the traditional crushing system. The new crushing system which only includes two crushers can meet the requirement and simplify the crush process. Investment of crushing equipment and infrastructure can be cut down. Operating and maintenance costs can be obviously reduced due to the simple process, which also could achieve high energy saving and excellent economic efficiency.INTRODUCTIONMetallurgical Slag (MS) such as steel slag, copper slag is a typical industrial solid waste and it threatens our environment’s safe. Metallurgical enterprises must take action to settle these wastes in order to protect our environment. Because pure metal slug can easily be mixed into MS, its uniaxial compressive strength (UCS) will exceed 200Mpa. If crushing station employs traditional crushing equipment, equipment failure will be easily caused because of these pure metal slugs. Coarse crushing equipment usually adapts jaw crusher in traditional Crushing technology and rod mill will be utilized to finish the secondary and fine crushing works. And the same time screening machinery should be used to ensure the suitable particle size (Figure 1)."

Jan 1, 2016

By Karl Houseley, Dr. Robert J. Chapman

"A gravity concentration process has been applied to ores from the Clogau Mine, north Wales, the Tyndrum deposit, central Scotland and an alluvial ore from Leadhills area of Scotland. In the case of the Welsh ore and the alluvial deposit the gold grains in the concentrate and tailings streams have been characterised in terms of their three dimensions.In the case of Welsh ore, the thickness of a gold grain has been shown to be the single most important factor in determining behaviour in a gravity concentration operation. Six indices were used to quantify the overall geometry of the gold grains and those which incorporate a thickness term have proven to be effective in predicting the destination of gold particles within the concentration circuit. It is proposed that the most simple of these, the Heywoods flakiness ratio, has potential for the control of milling operations as an alternative to the established practice of characterising the size of the mill discharge.The effect of grain geometry on the recovery of fine gold has been studied using Tyndrum ore. The recovery of gold by gravity concentration increased from 20% to 70% when the criteria used to design the milling operation was the prevention of over grinding of gold grains.The destination of alluvial grains in the concentration circuit did not show such dependence on shape, and this has been attributed to the effective classification of all the gold grains in the sample by fluvial action producing a population of similar geometric characteristics."

Jan 1, 1996

By Janos de Warga

"After a short introduction to the history of the semi-conductor theory, the paper describes the principles of electron and hole flow in the semiconducting materials, the operation of the PN junction, and the rectification process in multi-layer devices (diodes and SCR's). The various methods of purification and zone-refining of the silicon are illustrated prior to the discussion on the most commonly used junction-forming processes (alloying, diffusing, etc.). Modern device fabrication and packaging operations are illustrated. Factory testing, evaluation, electrical parameters and guaranteed rating characteristics are listed. It is explained in this paper how the various device parameters affect the electrical performance of the finished unit and how the finished unit characteristics (turn-on, turn-off time, etc.) will influence the equipment rating. In concluding, some typical items of equipment are highlighted, and the applications of these semiconductor rectifiers in the chemical, mining, pulp and paper, and steel industries, etc., are dealt with."

Jan 1, 1967

By H. Jung

The microstructures and grain sizes of nanocrystalline Co and Co-1.1 wt % P alloys were characterized by X-ray diffraction. The corrosion properties of as-deposited and annealed Co-l.l wt % P alloys and pure nanocrystalline Co were studied in a deaerated 0.1M H2SO4 solution using electrochemical measurements and XPS surface analysis. Potentiodynamic polarization testing and impedance measurements revealed that an addition of P to pure nanocrystalline Co improved the anodic-corrosion resistance, however, this enhanced corrosion resistance was compromised by the heat treatment process at 350 and 800°C. The corroded surface of annealed nanocrystalline Co-1.1 wt % P at 350°C exhibited a more porous P-enriched layer compared with the as-deposited case. A sample annealed at 800°C corroded uniformly showing second-phase precipitates. The enhanced corrosion resistance of as-deposited nanocrystalline Co-1.1 wt % P was attributed to the elemental P on the surface that acted to hinder the anodic dissolution kinetics of surface Co following an initial selective dissolution of Co. However, at a higher anodic overpotential region, the superior corrosion resistance of Co-l.l wt% P alloys did not last because of the formation of a non-protective surface film consisting of mainly hypophosphite and phosphate as well as elemental P.

Jan 1, 2005

By Richard P. Taylor, Rod Henham

Abstract - Newly discovered pegmatites distributed throughout the sub-surface environs of the Musselwhite Archean gold deposit occur as narrow dikes that intrude most of the major lithological units. The mineralogy and textures of the pegmatite dikes are characteristic of granitic pegmatites of the "Rare-Element Class"; more specifically, they closely resemble varieties of the "Complex-type" granitic pegmatites that are commonly associated with zones of tantalum mineralization. The essential minerals in the dikes comprise albite, quartz, and K-feldspar, together with lesser amounts of mica (including lepidolite), spessartine, tourmaline, and locally, spodumene. Fine-grained (30 µm to 300 µm), tantalum-bearing minerals occur in the quartzo-feldspathic matrix of the dikes as disseminations, in interstices, and in small vugs. The nature of the tantalum-bearing mineral assemblage present in individual pegmatite dikes varies from a simple mineral assemblage composed of ferrocolumbite (with around 39 wt% Ta2O5) in the most northerly dike, to more complex assemblages comprised of manganotantalite (with up to 75 wt% Ta2O5), ferrotapiolite (with up to 79 wt% Ta2O5), and microlite (with up to 76 wt% Ta2O5) that are present in dikes located several kilometers to the south and southwest. The compositional characteristics and textural relationships of the tantalum-bearing minerals in the dikes provide evidence of igneous fractionation trends that are typical of rare-element granitic pegmatites. Such trends suggest that the newly discovered pegmatites represent part of a more extensive group of cogenetic, tantalum-mineralized dikes.

Jan 1, 2001

By C. Bourgoin

"The limited development and application of new technologies to narrow-vein mining is currently impeding progress in the industry to a point where productivity, working conditions and operating costs have reached a critical stage in many Canadian mines.In an effort to foster the emergence and application of new technologies, Université Laval, together with other organizations, has carried out a R&D project focussed on the need of identifying new development pos5ibilities and of facilitating the transfer of technology in matters related to underground mining methods and machinery.The first phase of the study consisted of an in-depth assessment of current practices and problems in narrow-vein mining. The second phase was a state-of-the-art survey of mining methods and equipment, together with proposed modifications and innovations. The third phase of the project concerns the experimental development as well as the principal application of various proposed technologies.This paper presents an overview of the organizational, technical and strategic considerations which guided the University group and it serves as well to introduce a newly-published brochure, entitled ""Underground Mining Techniques of Vein Deposits"", which summarizes such work to date. More specifically, a perspective of technological developments applicable to narrow-vein mining is presented."

Jan 1, 1994

By Stephen Hardcastle

Personnel Heat Exposure Issues In Canada?s Deep Mechanized Mines ?Project developed in 2004 ?Base/precious metal industry identified heat stress/management as a major challenge affecting productivity and operating costs ?Project started in 2005 ?Current research nearing completion ?Guidelines, further data analysis and ?Communicating the Science? will continue into 2011 Managing Heat Exposure Control?. The cost implications ?Controlling the environment ?Ventilation already a major expenses/energy user ?Large Canadian mines are currently delivering massive volumes of air 15-20 tons of air/ton ore ?Large investments in ventilation upgrades, mechanical cooling

May 1, 2010

By Stephen Hardcastle

Personnel Heat Exposure Issues In Canada?s Deep Mechanized Mines ?Project developed in 2004 ?Base/precious metal industry identified heat stress/management as a major challenge affecting productivity and operating costs ?Project started in 2005 ?Current research nearing completion ?Guidelines, further data analysis and ?Communicating the Science? will continue into 2011

Oct 1, 2010

By Marko Lampi, Ross Andrews, Jouni Pihlasalo, Robert Matusewicz

With widespread discussion on reducing carbon, sulphur and other emissions, use of sustainable energy sources and the pivotal circular economy theme, consideration needs to be given to pyrometallurgical operations broadly and more specifically, non-ferrous metallurgy. These themes present a number of challenges in terms of current operations and the view of processing the metals which are largely taken for granted in day to day living. This paper considers how these themes will impact pyrometallurgical flowsheets using the non-ferrous base metals as an example. It will examine the flowsheet chain to offer views on the boundaries of flowsheet optimization and the application of available tools to meet these future goals and challenges. INTRODUCTION The themes of reducing footprint through lowered CO2, S and other emissions, together with process sustainability (e.g. lowered energy) and links to the circular economy are well known to everyone in the metals industries. Whether it is reducing greenhouse gas emissions or analysing the importance of metals recycling in the circular economy, all these themes carry with them the fundamental premise of any change being considered; how can you best optimize a system to meet your aims? Of course, this depends on the available tools and the approach used for optimisation.

Jan 1, 2019

By Mitchell Gordon

"In almost all thickener applications the highest possible solid/liquid separation efficiency is what is desired by the user. There is a trend in the industry due to monetary restraints and environmental pressures to look at ways to extract this maximum performance by either retrofitting existing thickeners or installing the most cost effective new thickener. This paper looks at some of the common problem areas and presents a range of solutions developed by Outokumpu Mintec in North America and outokumpu's subsidiary Supaflo Technologies Pty. Ltd.The Emerging PictureAfter many hours of discussions with a large number of plant personnel over the last two years a picture began to emerge regarding current thickening operations in the industry. Initially, it seemed that everybody had their own unique process problems and therefore needed a correspondingly unique solution. Looking more closely at all the cases and the ideas that we had either implemented or suggested, it gradually became apparent that the majority of operators all had one and the same process need ....""Better Separation Efficiency""The range of operational problems that were uncovered in the survey were much more varied than expected and often were not even considered initially to be thickener problems. Often, it was only after the rejection of many solutions to the problem, generally due to capital cost, that the actual cause of the problem was looked at and found to be a thick-ener.A summary of the problems that have so far been identified is presented in Table 1. They are subdivided under three major categories of environmental, process and paste fill to highlight the wide range of mining activities that can be affected by poor thickener performance. These seem to be the major areas where the need for better separation efficiency is rooted."

Jan 1, 1995

By A. J. Hyett, N. Hedrick, J. Blackall

The Garford bulb anchor is a modified cable geometry developed and patented by Garford Ply Ltd. of Australia, and which has recently become widely available in Canada. It is produced by deforming the seven wires (including the central kingwire) of a standard cable into a bulb" (Fig. 1). Laboratory cable pull tests indicate that the bond capacity of the 25 mm Garford bulb anchor is comparable to the nutcase cable, in excess of the birdcage cable, and significantly higher than standard 7-wire strand. Its comparative advantage over the latter is most significant for tests at low radial confinement and high water:cement ratio grout, which corresponds to operational conditions of low quality rock (i.e. weak, highly fractured rock masses, foliated hanging walls, failed ground, etc.) and poor installation quality control (perhaps the most common explanation for cable bolt failures). It is under such conditions that cable bolting is often ineffective. The most impressive result is that for a reduction of the effective rock mass modulus by a factor of five, the Garford bulb cable capacity remains virtually unchanged.

Jan 1, 1995

By Wouter Bleeker, Isabelle Cadieux

"Abstracts of theses related to mineral deposit studies and exploration, completed at geology or earth science departments of Canadian universities, have been compiled for the period 1991 to mid-I993. Part I, presented in the June, 1994 issue of the ClM Bulletin, gave a listing of thesis titles. Part II, which consists of edited abstracts of theses considered to be of direct application to mineral deposit studies and exploration, is presented under various themes as follows:A. Kimberlites, Other Alkaline Intrusions and Related Studies;B. Volcanogenic Massive Sulphide Deposits and Related Studies;C. Mineral Economics;D. Mesothermal Gold Deposits, Other Gold Deposits and Related Studies;E. Magmatic Nickel-Copper, Platinum Group Element, and Chromite Deposits and Miscellaneous Platinum Group-related Studies;F. Granite and Pegmatite-related Deposits and Porphyry Deposits;G. Diverse Hydrothermal Deposits. Sediment-hosted CopperDeposits and Mississippi Valley Type Lead-Zinc Deposits; andH. UranitnlHeiated studies, Evaporites and Exploration Geophysics.Abstracts related to themes A to D were presented in previous issues of the ClM Bulletin, abstracts related to themes E and F are presented in this issue. The remaining abstracts will be presented in a future issue."

Jan 1, 1994

By R. Prioul, J. Kear, D. Chuprakov, A. P. Bunger

"Hydraulic fracture (HF) growth through naturally fractured rocks challenges the development of accurate predictive HF models. The authors present laboratory experiments differentiating behaviours associated with orthogonal and oblique intersections between HFs and natural fractures (NFs). HFs were created in sandstone and crystalline (gabbro) rock specimens, impinging orthogonally or obliquely on an unbonded machined frictional interface. Ultrasound monitoring was used to observe the rate of propagation through the interface. A contrast was observed between direct and offset crossing for orthogonal and oblique intersection, respectively. The stresses required to promote crossing depended on the intersection angle between HFs and NFs.RÉSUMÉ La propagation des fractures hydrauliques (FH) dans les roches naturellement fracturées pose un défi pour le développement de modèles prédictifs. Nous présentons des essais en laboratoire qui différencient les comportements associés aux intersections orthogonales et obliques entre les FH et les fractures naturelles. Des FH ont été créées dans des spécimens de grès et de roches cristallines (gabbro), heurtés de manière orthogonale ou oblique sur une interface machinée, non liée, de frottement. Un suivi par ultrasons a servi à observer le taux de propagation à travers l’interface. Un contraste a été observé entre un croisement direct et un croisement indirect des intersections respectivement orthogonales et obliques. Les contraintes requises pour promouvoir le croisement variaient selon l’angle d’intersection entre les FH et les fractures naturelles."

Jan 1, 2016

SOFCs with thin electrolyte of two types: SDC (15um) single-layer and YSZ (5um) + SDC (15um) bi-layer were fabricated by screen printing and co-firing on Ni¬YSZ cermet substrates. Using in-situ sintered Sm0.5Sr0.5CoO3 cathode the SDC-cell shows high performance at low temperature, 1180mW/cm2 peak power density around 650°C, while the YSZ+SDC bi-layer cell generates about 340mW/cm2 at 650°C, and good performance at 700-800°C with almost theoretical OCV value. Many Zr-content micro-islands were found on the SDC electrolyte surface. The influence of co-firing temperature and thin film preparation methods on the Zr-islands' appearance was investigated.

Jan 1, 2005

By F. Vasilikou

Commercial deployment of Carbon Capture Utilization and Storage (CCUS) requires field testing of a scale that can stress the geologic reservoirs. One such reservoir of interest consists of unminable coal seams that exhibit favorable characteristics and depositional environments and lower pressure and temperature than other, deeper, reservoirs. Such conditions can reduce compression costs while utilizing the action of adsorption that offers a more effective carbon dioxide (CO2) bonding than free storage or solution. To ensure the success of such tests, a number of parameters should be accurately determined, such as the seam geometry and stratigraphy, coal porosity and permeability parameters as well as optimum injection conditions. In essence the CO2 injection model should be calibrated for the reservoir characteristics using all available data. History matching calibrations are based on gas and water production from existing wells prior to injection. This paper will present reservoir models that were developed for a pilot--scale 907 tonnes (1000 tons) CO2 injection test that was performed in 2009 through one legacy coalbed methane production well in Russell County, Virginia, USA. The model incorporates a number of individual coal seams about 0.3 m (1ft) in thickness located at depths ranging from 300 to 700 m (1,000 to 2,200 feet). Model calibration was performed through history matching to prior production data, and subsequently the model was utilized to develop different injection scenarios. The developed model was used after injection to calculate CO2 plume distribution patterns that were monitored at the injection test. The paper will present model data and assumptions with a special emphasis on the effect of hydraulic fractures and the skin factor to the coalbed methane (CBM) production model.

Aug 1, 2013

By Hong Zhong, Shuai Wang, Fangxu Li, Guangyi Liu

"The flotation performances and adsorption mechanisms of a-hydroxyoctyl phosphinic acid (HPA) to malachite, cassiterite and wolframite were investigated by micro-flotation tests and X-ray photoelectron spectroscopy (XPS) analyses. The micro-flotation results indicated that compared with styrene phosphonic acid (SPA), diphosphonic acid (DPA), benzohydroxamic acid (BHA) and salicylhydroxamic acid (SHA), HPA exhibited excellent collecting power to the three oxide ores. In addition, HPA showed superior selectivity against hematite, tourmaline, feldspar and quartz. The results of XPS analysis demonstrated that HPA reacts with active species (M) on metal oxide by formation of P-O-M or P-M bonds.INTRODUCTIONIn mineral processing, flotation has been the main process for separation and recovery of valuable minerals from complex ores (Mei, 2013; Zhou, 2014). One of the key requirements in flotation process is to increase selectively the surface hydrophobicity of the targeted minerals by surfactant (known as collector in flotation) adsorption so that these mineral particles can preferably attach air bubbles in a slurry or pulp (Bai, 2004; Hankins, 2004). To anchor a solid surface selectively, special functional group are designed to adjust the interaction between the surfactant and the active sites of solid surfaces (Wu, 2006; Huang, 2014).Organic phosphorous compounds have strong affinity toward metals or metal oxides because they form more stable metal complexes than metal carboxylates (Pazik, 2001; Zheng, 1998). In mineral engineering, phosphorous compounds have been exploited as metal extractants and flotation collectors (Alguacil, 2002; Sun, 2008). Ni (2012) and Zhang (1998) introduced diphosphonic acid (DPA) as an effective collector for flotation of fersmite and niobite. Liu (1999) found styryl phosphonic acid (SPA) was a superior collector for flotation recovery of finely disseminated rutile ores. Gruner and Bilsing (1992) thought SPA was one of the best collectors for flotation recovery of cassiterite which could obtain a high-grade concentrates of more than 40% with high recovery values. Bulatovic (1999) investigated the flotation performances of phosphoric acid ester (PAE) to perovskite, ilmenite and rutile and found that PAE was an impactful collector for selective flotation of titanium minerals from complex ores in the presence of petroleum sulfate. However, a-hydroxyoctyl phosphinic acid (HPA) as a flotation collector for recovery of titanium ores were hardly reported in the previous literatures."

Jan 1, 2016

By Maureen A. McGuinness

Kidd Mine, an Xstrata Copper operation in Timmins, Ontario, operates a 400 t/h pastefill plant that provides paste backfill to stopes at the depth of 9000 ft. This paper will cover the operating practices of the pastefill plant both on surface and underground, highlighting tailings excavation, paste mix design and the pipe maintenance program. Kidd Mine, une opération d'Xstrata Copper à Timmins, Ontario, opère une usine de remblai d'une capacité de 400 t/h. Le réseau de distribution permet d'acheminer le remblai en pâte juste qu'à une profondeur de 9000 pi. Cet article couvrira le mode opératoire de l'usine de remblai tant à la surface que sous-terre en mettant l'emphase sur l'extraction des rejets miniers, la recette du remblai en pâte ainsi que le programme d'entretient du réseau de distribution.

Feb 1, 2008

By Masaharu Moteki

At present, the Unmanned Construction System (UCS) is adapted on initial operation against the disaster. For instance, it has been used in Unzen. When the scale of the disaster is big, or the danger to a person is big, the UCS is expected as a quick and safe construction technology. The Remote Controlled UCS is introduced into construction site to repair earth-fill embankment or to remove rock, as urgent measures after the disaster outbreak. For improvement of the operability, shortening of the skill time, reduction of the fatigue, examination of the most suitable system (placement of a monitor and the joy stick) of the remote system is a main theme in the Public Works Research Institute (PWRI). In the report of this year, when the operator controls construction machine directly or he controls it using remote system (he can check the situation of site only via monitor), the degree of achievement, construction efficiency and construction precision were inspected. The remote system which is based on the system used at Unzen was developed at PWRI.

Aug 1, 2013

By Deborah McCombe

"and Bill Roscoe, Consulting Geologist and Principal with Scott Wilson Roscoe Postle AssociatesMineral property valuations are carried out for a variety of reasons, such as mergers and acquisitions, non-arm’s length transactions, initial public offerings of stocks, support of audited financial statements, fairness opinions, determination of vendor considerations, litigation, expropriation, income tax matters and insurance claims.The CIMVal Committee was formed in 1999 to review and advise on approaches to the valuation of mineral properties. CIMVal is a special committee of CIM formed on the recommendation of the Mining Standards Task Force of the Toronto Stock Exchange and the Ontario Securities Commission.After solicitation of views and consultation with various interested parties, the CIMVal Draft Standards and Guidelines for Valuation of Mineral Properties were released for comment in February 2002 and were finalized in February 2003. CIMVal’s objective was for the standards to be used by the mining industry in general and to be adopted by Canadian securities regulators and Canadian stock exchanges. To that end, the standards contain many of the definitions and concepts of National Instrument 43-101, Standards of Disclosure for Mineral Projects, which came into force in February 2001.The intent of the CIMVal Standards and Guidelines is that mineral property valuations be carried out by appropriately qualified individuals and that all relevant information be fully disclosed. It consists of two parts: standards, which are mandatory in the valuation of mineral properties, and guidelines, which elaborate on the standards and provide guidance and recommendations for the valuation process and for reporting."

Jan 1, 2003