Search Documents

By G. A. Peebles

"This paper describes the various types of radiometric instruments and the techniques of their operation for grade control, sampling, assaying and probing drill holes at Eldorado Nuclear's uranium mine in northern Saskatchewan. Modifications that have been made to these instruments are discussed, and suggestions are made for the development of more refined and specialized radiometric equipment."

Jan 1, 1969

By A. R. Khodabandeh, T. Nematkhah

Correct selection of forging parameters is very important to produce sound superalloy parts. In this investigation nickel-iron base superalloy IN901 successfully forged and seal spacer, which is a part of airplane with about 11 kg weight has been produced. Forging has been performed on the basis of hot compression results, which show deformation above 1100°C associated with dynamic recrystallization (DRX) which can increase the workability of material. On the other hand annealing at 1100°C decreases the flow stress during hot compression, and then increases the material formability. Then billets annealed at 1100°C in electrical furnace for 24 hours and reheated again to 1100°C before forging. Initial square cross section billet with 128mm side and 202mm length forged immediately after reheating by 80MN mechanical press. Specimens forged in five steps: upsetting, three steps molding and finishing. Preformed and molded specimens reheated in electrical furnace before later step of forming. Finally specimens trimmed by 1 OMn mechanical press and hot set by hydraulic press and then cooled in air to room temperature. Results show that reheating temperatures has been selected correctly because there isn't any surface crack and die cavities filled completely by forging material. Material flow has been carried out properly and there isn't any defect in critical points especially in extradoses and intradoses. Microstructural examinations show that grain boundaries contain Ti-rich globular particles that formed during cooling.

Jan 1, 2006

By Robert Dickson

Princess colliery is operated by Old Sydney Collieries, Limited, a direct descendant of the General Mining Association of London, England, which, in the first quarter of the nineteenth century, pioneered in coal mining in Nova Scotia. The coal worked is a 5 ft. 6 in. seam known generally through the Sydney coalfield as the Harbour seam but referred to locally as the Sydney Main. Entry is made by shafts, 680 feet deep, sunk in 1871 on a headland forming the northern entrance to Sydney harbour. From them extend the main roadways of the colliery, a distance of 700 feet to the shore line and a further distance of 14,700 feet in submarine areas to a total length of 15,400 feet. It was the first colliery in Nova Scotia designed to work submarine areas. Lateral development extends across a frontage of 16,000 feet and the submarine area from which the coal has been extracted is slightly over 6 square miles. There yet remains sufficient territory ahead of the workings to assure a future life to this colliery estimated at over 80 years at the current rate of production. In this area the seam dips at 6 to 7 per cent and face workings have reached a depth of 1,690 feet below the sea level. Until 1923 extraction of the coal was by room-and-pillar, followed by the drawing of the pillars. At that date the superincumbent strata had reached a thickness of 1,400 feet, resulting in heavy weighting on the roof and severe side pressure on the coal ribs. In combination with a soft, heaving pavement this created a set of conditions involving great difficulties and expense in keeping open places driven in the solid sufficiently long to permit recovery of the coal in the pillars by methods and equipment then available. The operator was forced to resort to extraction by longwall as the only economical method of winning the coal.

Jan 1, 1948

By C. Blawert

In previous studies of various HPDC magnesium alloys we found that the corrosion properties of the skin are inferior in comparison to the bulk, However, this is surprising as one would expect better corrosion properties for the finer microstructure of the skin, In a more detailed study using 2 and 6 mm thick sections from HPDC AZ91 step plates, the corrosion results of the original skin, the slightly removed skin and the bulk were compared, Indeed, the corrosion measurements including potentiodynamic polarization, long term polarization resistance measurements and electrochemical impedance spectroscopy (EIS) revealed a lower corrosion resistance of the original as-cast skin. An explanation for this corrosion behavior was found, on the one hand, in the microstructure concerning especially the amount and distribution of the 13-phase and, on the other hand, in the composition, including the distribution of the most important alloying element Al and of some impurities such as Fe.

Jan 1, 2005

By D. T. Pritchard

"Introduction""No accounting system is very good, and all of them are infinitely variable*.”The purpose of this chapter is to discuss those facets of a typical accounting system which are most commonly encountered by operating managers in mineral processing plants. However, before concentrating in any detail on these it is important to understand the broad purposes and basic techniques of any accounting system in any major business.The three broad purposes of an Accounting System are:- Administering, controlling, and recording the flow of cash in and out of the business. Cash is, of course, converted into other assets (or stores of value) such as inventory, plant and equipment, etc. These assets also have to be administered, controlled and recorded.- Internal reporting to Management for information, for control, and for use in making business plans and decisions. - External reporting to stockholders, government, lenders and other outside parties.In this chapter we shall organize our discussion of accounting practice in mineral processing plants around these three purposes of accounting and focus in some detail on specific practices and techniques with which operating personnel will be routinely involved. This chapter is divided into the following: Accounting Basics; Administration, Control and Recording of Cash Flows; Internal Reporting; Planning and Budgeting; Cost Control; and External Reporting."

Jan 1, 1989

By Lawrence D. Hoy, Armand Savoie, Pierre Trudel, Ghislaln Tourigny, Robert Crépeau, Lao Kheang

"Recent fluid inclusion and stable isotopic studies in the Bousquet mining district have identified spatial and temporal trends in mineralization temperatures and isotopic compositions of vein forming fluids. These studies indicate that mineralizing temperatures were lower during sterile vein formation (T=200-300°C) than during auriferous vein formation (T = 300-400°C), and that 8 80 values of minerals in sterile veins are lower by 1-3 %o than in associated auriferous veins. In addition to these small differences in 8 80 within individual mineralized zones, a trend of increasing 8 80 values of vein minerals is identified from west to east across the district, with 8 80 of vein minerals increasing by4-6%o. Quantitative evaluation of potential causes of the observed oxygen isotopic shifts suggests that the best explanation for these trends is the derivation of the mineralizing fluids from an isotopically inhomogeneous terrain in which the fluid isotopic compositions are controlled by the isotopic compositions of the host lithologies due to high rock/water ratios in these source terrains. This inhomogeneous source terrain is interpreted as consisting of the Blake River Group volcanics (low 8 80 component) and the adjoining Kewagama and Cadillac Group sediments (high 8 80 component).The genesis of the hydrothermal fluids is attributed to crustal heating during metamorphism, with the fluids representing metamorphic dewatering products and/or fluids incorporated during deposition and burial of the host lithologies. Ductile deformation of the fluid source regions impeded fluid migration during metamorphism; the ultimate release of the mineralizing fluids is attributed to the penetration to depth of vertical structures (fault and shear zones) during brittle deformation of the crust under waning metamorphic conditions. Release of fluids caused by this puncturing of the closed hydrologic source regime produced a localized zone of lowered pressure, drawing fluids from adjacent lithologies toward the fault zones, feeding further hydrothermal fluid upwelling. Au mineralization resulted from chemical processes related to cooling of the hydrothermal fluids and/or interaction with lithologies encountered during fluid migration; the level of crust at which Au deposition occurred likely migrated upward with the thermal anomaly caused by hydrothermal fluid upwelling, eventually reaching the level of current exploitation. Cessation of fluid flow along the vertical structures is attributed to inadequate recharge of the hydrothermal systems as fluid contents were depleted in the lithologies proximal to the vertical structures and/or sealing of the structures by mineral deposition."

Jan 1, 1990

By D. M. Ziebarth

"Normal sequence of operations to develop a new underground mine is: construct and outfit headframe for shaft sinking, sink shaft, construct and outfit shaft sump, develop shaft station and shaft bottom steel. In an effort to reduce the overall project schedule, an innovative plan was developed to install service shaft steel below station level, prior to the completion of the shaft sinking effort. To better evaluate the construction of this substantial steel tower, a preliminary constructability evaluation was conducted, including the best method of supporting the main tower; from the bottom, middle or top of the tower. The design criteria and plan involved: •,Develop access from existing service shaft, 25 km underground •,Use of materials to maximize strength while minimizing corrosion exposure •,Estimating the location of the shaft centerline •,Over excavating the station and shaft below station to allow future shaft steel repositioning •,Designing the tower steel for modular installation •,Incorporate commissioning considerations, such as suspension of the cheese weights during steel installation •,Provision for covered stair access to shaft bottom •,Enclosed shaft envelope with open panels to allow visibility and ventilation The design approach was innovative and this paper will describe the design principles and challenges encountered while providing insight into the solutions developed and implemented; especially the modular construction and installation methodology. INTRODUCTION In an effort to expand the mining operations, a plan was developed to construct a new service shaft closer to the new mine workings and convert the existing service shaft to a production shaft at the Potash Corporation of Saskatchewan Inc. (PCS now Nutrien) Rocanville Potash mine in southeast Saskatchewan. The new service shaft required a multi roped friction hoist operating a cage / counterweight, rope guided conveyances to support the operational requirements. The service shaft is an integral part of the mining infrastructure as it provides access to the underground workings, transport personnel and materials underground for operation and maintenance of the mine. The shaft also allows for services required for safe operation of the underground mine, power supply, controls, communication, dewatering and fresh water supply."

Jan 1, 2019

By T. R. Carter, A. C. Colvine

"Rocks of the Grenville Province in southeastern Ontario are currently largely dismissed by many geologists as having little or no potential for discovery of significant deposits of metallic minerals. The present study demonstrates that the area contains numerous deposit types which elsewhere are major metal producers. Therefore, there is significant unrealized potential, especially for gold, zinc, uranium, and possibly copper.The variety of deposits of metallic mineralization include stratiform zinc in marbles; stratabound base metal sulphides in volcanic and sedimentary hosts; gold-quartz veins; quartzmagnetite iron formation; copper-nickel and iron-titanium in intrusive rocks; magnetite skarns; molybdenum in skarns and pegmatites; uranium and thorium in pegmatites, veins, and calc-silicate gneisses; hematite veins; dolomite marbles (magnesium); and barite-jluorite-celestite-galena-calcite veins. There has been significant production of iron, lead, zinc, magnesium, gold, silver, and uranium.The vast majority of the metallic mineral deposits are confined to late Precambrian supracrustal and related intrusive rocks of the Grenville Supergroup. Many of the deposits are stratiform and/or stratabound and occur within units toward the top of major volcanic successions and in the lower portions of younger carbonate-clastic sedimentary successions.Processes responsible for mineral concentration in the area include: (I) syngenetic hydrothermal activity related to both volcanism and sedimentation; (2) epigenetic processes related to diagenesis, regional metamorphism, and igneous intrusive activity; (3) magmatic processes related to igneous intrusions; and (4) supergene concentration and enrichment. The genetic classification of the mineral deposits presented is based on observed geological relationships and these interpreted geneses. The deposit types have counterparts in volcanogenic and sedimentary exhalative, Mississippi Valley type, magmatic, contact metasomatic, and lode gold deposits. Many of the exploration criteria for deposits of these types may be applicable in the Grenville Province, despite the generally high metamorphic grades and complex deformation."

Jan 1, 1985

By J. W. Matousek

The heat content of the waste slag from a typical smelting operation methods for estimating the thermodynamic properties of smelting slags, to include: -- heats of formation -- heat capacities (specific heats) -- heat contents -- melting temperatures -- heats of fusion The techniques are illustrated with the analyses of a nickel reverberatory furnace slag from Copper Cliff, an iron-making blast furnace slag, and a "lateritic" slag from a ferronickel operation in Colombia.

Jan 1, 2007

By D. A. Jacobson

Mining operations, whether new or existing, are constantly looking for ways to maximize production and improve energy efficiency, while keeping the footprint required to a minimum. The Nordberg MP1250 cone crusher was designed with these three goals in mind. A series of side-by-side evaluations comparing an MP1250 to an MP1000 were completed at two Freeport-McMoRan operations. The first evaluation began October 2009 in a tertiary position and the second began March 2010 in a secondary position, where it remains in full production today. Utilizing 25% higher power capacity than the existing MP1000 tertiary crushers, the MP1250 had 29% higher capacity and 17% lower specific energy, adjusted for differences in feed and product size. The MP1250 compared to the existing MP1000 secondary crushers achieved 30% higher capacity at a slightly reduced specific energy, while achieving a finer product. The MP1250?s higher capacity and energy efficiency may have application in many crushing plants. Depending on site specific economic factors, greenfield projects may benefit from a smaller footprint and less ancillary equipment, whereas brownfield projects may benefit from higher capacity or a finer product within the same footprint.

Jan 1, 2012

By N. Dobrin, R. Sheinman, Y. V. Kokotov, L. N. Braginsky

Increasing the production of a Mixer-Settler unit requires either increasing flow rates or increasing extractant concentration. The mixers still have to ensure complete emulsification and to maintain high values of specific interface surface area in order to provide a high rate of mass transfer. Theoretically, an increase in mixing intensity can support increased flow rates without reducing extraction efficiency. Unfortunately, conventional pump mixers and mixing systems create small droplets that do not separate easily. As pumping action and mixing intensities are increased, the quantity of small droplets increases. We describe the development and industrial application of a novel mixing system for efficient mass transfer without forming significant quantities of small droplets, targeting both high mass transfer rate and low entrainment values.

Jan 1, 2014

By Š. Šachlová, T. Lokajícek, M. Petružálek, T. Svitek, A. Štastná

During the past 20 years, alkali silicate reaction (ASR) as a cause of concrete deterioration has been studied by a wide range of experimental methods such as microstructural and macrostructural analysis, bulk chemical analysis, X-ray and neutron diffraction analysis, etc. All of these data are compared with expansion values of mortar bars (following ASTM standard C 1260). Recent studies indicate the useful application of non-destructive methods with the aim of better reflecting mechanical properties and the degree of deterioration of real concrete. Ultrasonic testing methods (including ultrasonic pulse velocity UPV) are widely used to determine material mechanical properties and the changes induced by a variety of mechanical or chemical processes. However, only a few laboratory studies of ASR focused on ultrasonic testing of mortar bars. Due to this fact, a heating chamber was designed and constructed to enable ultrasonic sounding of mortar bar specimens while stored in accelerating solution. Regular ultrasonic sounding of mortar bars reveals significant dependence of ultrasonic data such as longitudinal P-wave velocity, signal energy, signal amplitude and signal frequency on mortar bar storage time. Ultrasonic data were subjected to time domain as well as frequency domain analysis. Different storage conditions were used to determine the effect of ASR on ultrasonic parameters. Mortar bars, prepared in the same manner with one type of aggregate, were stored in cold or warm water or in an accelerating warm medium. Ultrasonic data accurately reflects the differences in hardening and deterioration of tested mortar bars due to different storage conditions. Ultrasonic results showed very good correlation with the results of ASTM standard expansion tests and much higher sensitivity to ASR-induced concrete deterioration. Expansion tests showed 1% measured length differences in comparison with up to 80% resolution of ultrasonic data. The ultrasonic testing proved to be a suitable laboratory method for investigating ASR-related processes and could lead to an improvement of standard testing procedures.

Jan 1, 2015

By G. K. Livingstone

"This paper describes mining conditions in the Kaiser surface and underground coal mines in the Sparwood area of southeastern British Columbia. Mining methods are explained, major mining equipment is listed and production rates are given. Reclamation methods and results are described. Data are given on safety organization, safety practices, accident statistics, safety inspections and absenteeism. IntroductionThe coal mines of Kaiser Resources Ltd. are located in the southeast corner of British Columbia. All present mining is in the Sparwood area, where operations began in 1900 with the opening of the Michel underground mines. Production increased rapidly at first, then went through successive periods of depression and prosperity. Following are the highlights. Quantities are in clean, short tons. 1900 1910-Rapid rise in production to a peak of 512,000 tons in 1910.1911-1924-Reduced rate of production, averaging 238,000 tons per year, due to strikes, manpower shortage during World War 1 and post-war depression.1925-1929-Second prosperous era, with production climbing to 383,000 in 1929.1930-1933-Second depression-production falling to 231,000 in 1933.1934-1942-Third era of prosperity-production recovered and new production peak of 908,000 tons reached in 1942 during World War II.1943-1956-Corttinued prosperity, with production averaging 720,000 tons per year.1957-1959-Loss of markets to oil and gas; production dropping to 517,000 tons in 1959.1959-1969-Recovery due to new coal market in Japan; production climbing back to the 900,000-ton level.197D-Present-Jump in production reaching 6.6 million tons in 1975. This was the result of the purchase of the property by Kaiser Steel, who negotiated a large-volume, long-term contract with Japan, built the coal port of Westshore, reduced shipping costs by instituting unit trains, and reduced production costs by investing in large-scale mining machinery and a new preparation plant."

Jan 1, 1980

By Robert E. Loftus

"The author discusses the growth in the use of ocean-going bulk carriers for the transportation of mineral commodities, and predicts future trends. The various types of tonnage carriers are described, along with the special discharging gear used, the costs involved and the duties of some of the personnel.THE FIRST CONSIDERATION in planning the ocean transportation of minerals is the type of vessel to be utilized. The modern 'Bulk Carrier' bas proved to be the most successful vehicle for the purpose. I would there-fore like to describe this fleet in some detail and at-tempt to show the impact that the bulk carrier bas bad on the movement of bulk materials."

Jan 1, 1968

Traditionally within the mining industry, single models for both grade and geology of orebodies are created upon which all mine development decisions are based. These models provide a single interpretation of the extent and continuity of the mineralization envelope based on solids and sections interpreted from relatively wide spaced drilling i.e. the models infer behaviour of grade and geology at smaller/local scales based on data available at wider scales. The variable behaviour of grade and geology cannot be derived from single kriged resource models. In recognition of this, Newmont Mining Corporation typically uses Sequential Gaussian Simulation (SGS) to quantify grade variability and to determine its effect on some of these mine development decisions. In most of these studies the mineralized envelope remains fixed and grade simulations are generated within a fixed volume. To account for uncertainty in the geology/ mineralization envelope Newmont Mining Corporation has been experimenting with Multiple Point Statistics (MPS). Multiple-Point Statistics is an emerging technique, which can be used to generate multiple, geologically realistic, realizations of data that displays complex non-linear features. MPS uses a conceptual model of the geology, called a Training Image (TI), to infer these high-order spatial relationships. The multiple realizations allow for an assessment of the geologic uncertainty, which can be further combined with grade simulations to generate a more complete picture of the true uncertainty of a mineral deposit.

Jan 1, 2011

By A. E. Wraith, R. Harris, J. Qiu, R. Parra

Small pilot scale experiments have shown that it is possible to almost fully eliminate the minor elements (ME), namely As, Sb, Bi and Pb contained in smelter dusts by vacuum calcination of mixtures of the dust with sulphidizing agents such as dirty copper concentrate or elemental sulphur at 900 °C and 80 +/- 30 Pa for 90 minutes. The products of this calcination are a residue comprising a purified mixture of copper containing compounds along with the gangue constituents and a high sulphur condensate comprising a mixture of the minor element compounds. In particular, the Cu:ME ratios of the concentrate and dust were increased from 250 and 50, from 28 and 12 and from 36 and 8 to roughly 3000, 3000 and 100 for the calcine, for Bi, As and Sb, respectively. It has also been calculated that (i) the copper content of the vacuum calcine may be recovered by feeding it into a Peirce-Smith converter during its slag blow, and (ii) the resulting recycling could increase the minor element treatment capacity of a smelter by 100 % while also reducing the blister As content by a factor of three. The experimental results are briefly discussed and a treated dust recycling option is examined. Example operating conditions are presented and available commercial technology for the vacuum calcination of the mixtures is reviewed.

Jan 1, 2007

By Xiang Li, Xibing Li

It is paramount that the stability of rock slopes be correctly accounted for under diverse operating and environmental conditions. Owing to different sources of uncertainty entailed in such stability problems, conventional deterministic approach through the calculation of a factor of safety (FOS) cannot reflect quantified uncertainties explicitly and sufficiently. Thus it is highly desirable to invoke the reliability approach to consider uncertainties in a systematic manner. Nowadays, the current design standards have an increasing tendency to ensure rock slope stability by pre-defining a target reliability index (or target probability of failure), viz., the reliability level of a rock slope is pre-set as a target to be satisfied. In such a situation and considering the fact that the FOS used as an indicator of slope performance still has a very wide acceptance, we focus on proposing an inverse-reliability-based methodology which aims at developing a two-fold indicator strategy, i.e., using the FOS and reliability together to deal with slope stability problems. The basic idea behind it is to utilize a so-called inverse first-order reliability method (IFORM) to directly calibrate the FOS provided the target reliability index has been given. In this way, the calibration scheme relating the FOS can be rationally done by not only incorporating uncertainties, but also satisfying a desired level of the prescribed reliability. Based on this, to make the IFORM computationally feasible and also reduce its computational cost, we introduce the response surface method (RSM) to generate a surrogate for the FOS-based limit state function (LSF), considering the lengthy and complicated form of the FOS in some recognized methods (e.g., within the framework of limit equilibrium). Distinguished from the existing RSMs that potential inadequacies may arise, we present an RSM based on a hybrid approach combining support vector machine (SVM; used as a regression technique) and uniform design (UD; pertaining to experimental design). Using a representative example of rock slope stability problem, we demonstrate the feasibility and validity of the developed methodology, during which the associated sensitivity study and further discussion are also performed. By dint of such a methodology, we can establish a link between the conventional deterministic approach and the reliability approach, where a logical and realistic framework is provided, for cases achieving the specified reliability, to assist in selecting the FOS which remains adequate for rock slope stability even in the face of uncertainty.

Jan 1, 2015

By A. Romero

"Most underground mines require heating or cooling systems to meet health and safety standards in the working areas. In regions where daily or seasonal fluctuations of environmental conditions exist, these systems tend to be over-sized and operate at low average load factors, which increase both investment and operating costs. One possible approach to reduce the temperature variations of the fresh air supplied to the mine, and so reducing the investment in large heating or cooling systems, is to use rock as a thermal regenerator or thermal storage system. Packed rock beds act as thermal inertial units, damping the atmospheric temperature oscillations to provide a more constant fresh air temperature. However, although regenerators exist in some mines, and packed bed rocks have been studied in detail in solar thermal power applications, there is a lack of tools to design new and sufficiently large storage systems of this kind. This work fills the existing gap by presenting a methodology to design and evaluate the impact on the ventilation systems of these regenerators. The method is validated using existing rock bed systems found in the literature and illustrates possible designs for small and large size regenerators in both hot and cold climates.1 INTRODUCTION “ It is quite amazing how often answers to extremely complicated problems can be obtained in this way, by using greatly simplified models of the real situation for the purpose of calculation.” Whiller, A. in private communication to J. S. Stachulak (1989). Motivation Most underground mines located in regions with extreme climatic conditions require the thermal pre-treatment of the fresh ventilation airflows, whether for heating or cooling. Heating commonly is needed in sites with sub-zero temperatures and is usually effected by direct or indirect burning of natural gas or propane. Alternatively, cooling is required in areas with hot temperatures, or in mines with high underground thermal loads where the fresh air at ambient temperature cannot provide enough refrigeration. Thus, when the ambient air conditions cannot provide by itself enough thermal power to ensure safe underground working conditions, a heating or cooling plant is required, which involves a considerable equipment and operation cost."

Jan 1, 2019

By P. M. Daignault

"Fording Coal Limited is one of Canada's largest producers of metallurgical coal for the export market. Medium- to highvolatile coals are mined at its Fording River operations in southeastern British Columbia. This paper discusses some of the mine design and production related problems encountered, and how they have been resolved. Other aspects of the operation such as geography, geology and standard mining methods employed are also covered.IntroductionFording Coal Limited was formed in 1968 to mine and market metallurgical coal resources held by the company in the East Kootenay region of southeastern British Columbia<1>. The company, at its Fording River operations, holds approximately 19,635 hectares of coal lands, having an estimated resource of 3.5 billion tonnes of metallurgical coal. Total reserves are approximately 520 million tonnes.Fording Coal is owned 600Jo by Canadian Pacific Enterprises Limited and 400Jo by Cominco Limited. Cominco itself is owned approximately 540Jo by Canadian Pacific Enterprises. The company, originally staffed and managed by Cominco, has been independent since January 1978, with its own board of directors, management, staff and employees. The head office is in Calgary, Alberta. The Fording River operations are located in British Columbia, approximately 70 km north of the Crowsnest Pass, near the Alberta/ British Columbia boundary, only 150 km by air and 320 km by road from Calgary.A contract was signed in 1969 with the Japanese steel mills to provide 45. 7 million tonnes of metallurgical coal over fifteen years, commencing in 1972, at an annual rate of 3 .05 million tonnes per year. The mine is presently expanding annual production capacity from the original 3.0 million long tons (3.05 million tonnes) to in excess of 5.0 million tonnes.Concurrent with this production expansion, a vigorous marketing effort has diversified Fording's customers to include additional countries in the Pacific Rim area. Three cleaned coal products are now marketed compared to the single ""standard blend"" product originally shipped to satisfy the Japanese contract. The product specifications are listed in Table I."

Jan 1, 1985

By R. E. Whitehead

"Abstract - Alkali-alumina and MgO-alumina plots are an effective instrument for displaying chemical and mineralogical compositions of altered and unaltered rhyolites and rhyodacites. They reveal that most supposedly unaltered rhyolites, apart from those of Cenozoic age, have undergone losses in Na2O and gains in K2O. The extreme loss of Na2O from highly altered rhyolites immediately adjacent to VMS deposits is strikingly illustrated by alkali-alumina plots. MgO/Al2O3 vs. K2O/Al2O3 diagrams display a strong negative correlation between MgO and K2O that results from the conversion of sericite to chlorite. A similar negative correlation between MgO and whole-rock d18O is apparent on plots of these two parameters. Alkali-alumina plots underscore problems in selecting appropriate precursor compositions required for mass-balance calculations. Molar ratio plots are a viable alternative to such calculations. Sommaire -Les diagrammes alcali-alumine et MgO-alumine constituent un instrument efficace pour la représentation des compositions chimiques et minéralogiques des rhyolites et rhyodacites altérées et fraîches.Ces diagrammes révèlent qu’à l&apos;exception de celles d’âge Cénozoïque, la plupart des rhyolites qualifiées de fraîches ont subi une perte de Na2O et un gain de K2O. L’intense perte en Na2O que l’on note dans les rhyolites fortement altérées associées aux gîtes de type SMV est particulièrement bien mise en évidence par le diagramme alcali-alumine. Le diagramme MgO/Al2O3 vs. K2O/Al2O3 montre une forte corrélation inverse entre le MgO et le K2O due à la conversion de la séricite en chlorite. Une corrélation inverse analogue entre le MgO et le d18O de la roche totale s’observe sur un graphe comparant ces deux paramètres. L’usage du diagramme alcali-alumine fait ressortir combien il peut être difficile de choisir un précurseur de composition appropriée pour des calculs de balance de masse. Les diagrammes de rapport molaire constituent une alternative à de tels calculs."

Jan 1, 2006