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By B Washington, A Campbell, R Taylor

A sampling and measurement program was undertaken on the reaction shaft of the Olympic Dam copper flash smelting furnace. The object of the work was to provide information to validate a mathematical model of the burner and reaction shaft. Samples and measurements were undertaken through the burner inspection ports and the South East (SE) shaft sampling port about half way down the reaction shaft. Samples were collected to enable the calculation of particle loading of shaft gases, or sizing and chemical analysis of the partly-combusted feed, and the preparation of polished sections. Measurements were made of the temperature and sulfur dioxide content of the atmosphere, as well as plume velocity.To implement the program it was necessary to design and construct the following specialised items of equipment. For use at the burner inspection ports: a cup sampler for obtaining samples below the burners (temperature, solids loading and samples for characterisation).For use at the SE shaft sampling port and also at the settler level: trough sampler (plume definition and samples), isokinetic sampler (used as a velocity probe in this work), temperature probe (temperature traverses across the shaft), and sulfur dioxide probe (SO2 measurements across the shaft).The design of the sampling and measuring equipment is described, and examples are cited of the types of information obtained. The problems arising from working in a hot environment with molten or sticky particles are discussed.

Jan 1, 2005

By N Maistry, A Singh

It is estimated that in less than a decade, high-grade iron ore reserves in South Africa will be depleted, leaving only low-grade ores with a dominant lithology of banded iron formation (BIF) hematite. BIF is a complex ore reserve as it is typically liberated below 1 mm, resulting in high energy costs. However, due to its abundance, its beneficiation potential should be evaluated to maximise recovery at an acceptable product grade. To develop a beneficiation program for BIF hematite, the first step is to determine the effect of two laboratory crushing techniques on mineralogical characteristics, specifically liberation and shape. For this study, the cone crusher and high pressure grinding rolls (HPGR) were used. The Electron MicroProbe Analysis (EMPA) and Mineral Liberation Analyser (MLA) were used to compare the mineralogical characteristics. The liberation characteristics for hematite are similar for both crushing techniques; however, HPGR preferentially liberates quartz. HPGR achieved 8– 12 per cent additional quartz liberation in the greater than 80 per cent and 100 per cent liberation classes respectively and specifically in +75 μm size range. Improved quartz liberation is associated with lower energy requirements for downstream milling and improved separation efficiencies for beneficiation units that operate in this size range. Both samples displayed similar shape characteristics; most particles were elongated smooth and the rest were elongated angular. Good hematite liberation is expected at grinds of 212 μm to 150 μm. Further consideration should be given to throughputs, energy efficiency and downstream equipment selection prior to selecting a crushing technique.

Sep 18, 2023

By W D. Ortlepp

Seismicity associated with deep block cave mining operations in hard rock can give rise to dynamic loading of the mining openings. A description is given of the source and damage mechanisms associated with such seismic events, and the possible demands placed on the rock support by the resulting dynamic loading. In addition, production level drifts are often subjected to large static deformations during mining. Appropriate support, able to sustain large static deformations, and capable of absorbing the energy released during dynamic loading, is described. The performance of these support types has been determined by means of large-scale dynamic loading tests, and large deformation static laboratory tests. Finally, a support system which is considered to be appropriate for extraction drifts in block cave layouts subjected to dynamic loading is described.

Jan 1, 2000

By Y Peng, D Liu, S Vink, B Wang

There have been strong industrial observations that clay minerals have a deleterious effect on mineral flotation grade and recovery. However, rigorous explanation on the role of clay minerals in flotation and effective ways to reduce their negative effects are not available. In this study, the flotation behaviour of low quality and high quality coal samples were examined at the Xstrata Oaky Creek Coal plant, and laboratory in fresh and recycled water with high ionic strength. Anionic and non-ionic dispersants including lignosulfonates and triblock copolymers were also tested with an objective of improving coal flotation in recycled water. It was found that overly stable froth was produced in the flotation of both low quality and high quality coal samples in saline water. Speciation modelling indicated precipitation of hydrophilic components which may adversely affect the flotation. Despite the overly stable froth, saline water produced much higher combustible recovery than fresh water without significantly losing the product quality. Lignosulfonate dispersants displayed a potential to improve the flotation in fresh water, but not in saline water. Significant flotation improvement was achieved with the triblock copolymer examined in both fresh and saline water.CITATION:Liu, D, Wang, B, Peng, Y and Vink, S, 2012. Determining the effect of clay minerals on coal flotation using saline water, in Proceedings 11th AusIMM Mill OperatorsÆ Conference, pp 151-158 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Oct 29, 2012

A very wide range of technologies are utilised in the mining and processing of ores and a great deal of effort is expended in the development of ænew technologiesÆ to improve mining performance and economics. Traditionally, technology and people have been treated as separate aspects of an operation, when in fact they are inextricably linked. The successful implementation of new technologies is entirely dependent upon the actions, enthusiasm and skills of people, both as individuals and working in groups. This paper discusses the role of technology in mining and how new technologies are implemented by the industry. The paper argues that existing technologies have not been fully or adequately utilised and that effort should be re-focussed on the implementation of technologies that have been taken for granted for many years. The need for greater emphasis to be placed on the management of the human-technology interface is discussed.

Jan 1, 1998

By K Luthbom, A Lagerkvist

According to the Swedish Environmental Protection Agency, the number of potentially contaminated sites in Sweden is approximately 40 000. The funding for remediation from the Swedish Government alone amounts to $A 60 - 80 M (300 - 400 MSEK) annually for the period 2003 - 2006. Uncertainties will arise when obtaining samples in field, preparing them in laboratories and analysing them. Different procedures give rise to varying errors. Using data for decision-making that does not truly represent the site could be fatal. Misclassification of soil could lead to unnecessary costs or to risks to human health and the environment. The total uncertainty of an environmental sample can be split into analytical uncertainty and sampling uncertainty. The analytical uncertainty is usually known and reported from routine analysis. The size of the sampling uncertainty is less well known. Hence, the question is how big are the sampling uncertainties for contaminated soil and how big is the analytical error compared to the total sampling error? A scrap yard and two landfills within a workshop area were investigated. An excavator dug trial pits and samples were taken with a trowel from the walls of the trial pits. Samples were put into plastic bags and taken off site for preparation and analysis using XRF. Sample preparation included drying and sieving. The samples were homogenised by kneading the sample bags prior to analysis. The sampling and sample handling were performed in an intuitively way without knowledge of sampling theory. However, Pierre GyÆs sampling theory was used for subsequent evaluation of the data from the site investigation. The theory defines seven sampling errors, which can be applied to sampling of soil. Some errors have a variance that can be calculated or at least estimated, while other errors can give some idea whether the bias is positive or negative. The total sampling error varied over three orders of magnitudes from sample to sample. The single largest contributor to the large variation in error was the contaminant level. When comparing the analytical error and the total sampling error the ratio varies more than three orders of magnitude.

Jan 1, 2005

By S Walters

The emerging discipline of ‘geometallurgy’ is not new but is becoming increasingly recognised as a discrete and high-value activity. Geometallurgy involves a quantified and spatially constrained approach to ore characterisation in terms of relationships to critical processing performance behaviours. A key outcome is enhanced economic optimisation of mining and improved risk management tools.Industry recognition of the need for large-scale, integrated research to support this emerging area resulted in commencement of a major ongoing initiative in mid-2005. The AMIRA International P843 ‘GeMIII’ project (Geometallurgical Mapping and Mine Modelling) is a cross-discipline collaboration involving a number of world-class research organisations supported by over 20 industry sponsors.The project is delivering integrated tools and methods which link intrinsic rock characteristics to prediction of mineral processing performance. These indices must be capable of spatial distribution in 3D resource models and incorporation into mine planning and optimisation. A key aspect is provision of new cost-effective tools and methods which can provide the large numbers of measured and estimated data points required to undertake effective modelling and spatial distribution. The integrated methodology and enabling technologies being developed through the ongoing AMIRA GeMIII project are outlined, together with implications for supporting industry best practice.

Sep 5, 2011

By Skinner W, Netting A. K O

Surface analysis of ore samples collected from corresponding concentrate and tailings process streams is now a widely used tool in many Australian base metal sulphide concentrators, particularly those involved in AMIRA projects. The use of tec

Jan 1, 1997

By G King, Q Shu, W Cao, F Gyakwaa, H Singh, S Wang, M Huttula, T Fabritius

Metallurgical slag, such as refining slag, is essential to enhance or promote steel cleanliness. The CaO–MgO–Al2O3–SiO2 system is the primary source of oxides-based inclusions. It plays a vital role in applications in various pyrometallurgical processes. Numerous thermodynamic databases and physicochemical properties of slag studies mainly focus on quenched samples and measurements at room temperature. Consequently, the present study explored the physicochemical, structural properties and crystallisation evolution for CaO–MgO–Al2O3–SiO2 glassy slags via in situ hightemperature Raman spectroscopy and synchrotron X-ray diffraction. The study was carried out by synthesising CaO–MgO–Al2O3–SiO2 slag with varying Al2O3/SiO2 ratios. The results from the in situ high-temperature measurement demonstrated a pattern showing a transformation of a broad peak from the glassy matrix to crystalline peaks. The study showed crystallisation of dominant phases such as Ca2SiO4, Ca2Al2SiO7 and CaAl2O4 that correspond and are attributable to changes of structural units during in situ high-temperature measurements. The results further showed a correlation between an increase and transformation in crystalline phases observed from the spectra obtained from non-isothermal heating of the samples.

Jun 19, 2024

By I Auranen, J Raatikainen

IMA Engineering (IMA) and Mine On-Line Service (MOLS) companies have used on-line sensors for analysing ore and waste rock in mining for more than 25 years. Today IMA on-line sensors are used in various stages of the mining process including on-line analysis of drill cores, drill chips, ore and waste in loader bucket, ROM ore analysis on belt conveyor belt and in bulk ore sorting and in slurry analysis in concentrators. During years of extensive field experience and testing we have found that the waste rock dilution and ore losses create much larger economic and environmental losses than has been previously recognized. According to our studies the main reason is limited number of analysis already in exploration when drill cores or drill cuttings are used in block modelling. The same happens in production because too few and biased samples from benches are used to estimate the ore grade. Much more than today estimated amount of waste enters the mill and considerable volumes of ore losses happen at the same time. The ore grade on the benches and in muck piles is averaged and “homogenized” with averaged and biased samples. These are the main root causes of waste rock dilution and ore losses. Sensor based preconcentration can be the remedy to waste rock dilution and ore losses. This presentation will show examples of the use of on-line sensors in preconcentration when analysing ore and waste rock in drill cores, drill cuttings, on conveyor belt and in bulk ore sorting. Waste rock removal in preconcentration has direct effect on energy consumption in crushing and grinding and chemicals in concentrator. In concentrator waste is separated and goes to tailings pond, however, preconcentration directly reduces the volume of the tailings. In our presentation we will cover cases in base metals and in gold mines.

Nov 10, 2020

By M Fuchs

Roadheaders were introduced to mining and tunnelling in the early-1960s. Since this period their main field of application has been for roadway drivages in coal mines and for mineral production, for instance in coal, rocksalt, potash and gypsum mines. Their main field of application in tunnelling is in softer and partly friable rock formations, a suitable area for non-blasting excavation. However, in longer tunnel sections excavators with high ripping forces have replaced roadheaders in many situations. The main arguments against roadheaders have been and still are:a sharp increase in excavation cost with increasing rock strength and increasing abrasivity; and greater risks in conditions which have not been, or could not be, investigated to a sufficient extent. These arguments have, to a great extent, restricted practical roadheader application in production mining and in a lot of æstandardÆ tunnel projects. To address these limitations, factors which could make roadheaders attractive for such conditions and could overcome existing technological difficulties have been investigated. Extension of the economic field of application in hard rock was found to be the most important and the most effective step forward.

Jan 1, 2002

By J-P Franzidis

A technique for determining the recovery of attached particles across the froth phase in flotation that relies on measuring the rate at which bubble-particle aggregates enter the froth is used to investigate the selectivity of attached particles across the froth phase. Combining these measurements with those of other techniques for determining the froth recovery of attached particles provides an insight into the different subprocesses of particle rejection in the froth phase. The results of experiments conducted in a 3 m3 Outokumpu tank cell show that the detachment of particles from aggregates in the froth phase occurs largely at the pulp-froth interface. In particular it is shown that the pulp-froth interface selectively detaches particles from aggregates according to their physical attributes.

Jan 1, 2005

By M Grigorescu, J H. Hodgkinson, M Khanal

The mining industry often needs to operate in remote or climatically harsh locations. The industry has recently been forced to deal with extreme conditions including floods, heatwaves and droughts. As these are becoming progressively frequent occurrences, mines typically build ‘downtime’ into production schedules and expect to incur costs to manage the various risks arising from climate extremes. Importantly, many environmental conditions are becoming more extreme and consequently, risk management based on past data can become increasingly ineffective. Market and shareholder demand for fewer interruptions are another pressure on mines to avoid prolonged or frequent downtime. Hence, adaptation to climate is becoming an important strategic move for many companies, many of whom are using future climate scenarios and alternative risk evaluations.We present here a method that uses commonly available mine site data to assist decision-making for reducing vulnerability to sudden flood. The method, ‘climate-related adaptation from terrain evaluation results’ (CRATER), identifies a mine’s flood ‘hot-spots’ and presents them as a ‘traffic lights’ warning map. The process then requires a failure analysis process such as fault-tree analysis to identify both the cause of possible failures and a range of possible failure-avoidance adaptations. In the final stage, management can assess the most suitable option for the mine, based on the availability of capital such as time, facilities, labour and money in addition to social acceptability of the options. CRATER has been tested in an open cut mine environment and is now being further developed to identify how subsidence over underground mines may impact on flooding and ponding over the mining life cycle (CRATER II). Further work is continuing to test larger and more complex mine landscapes to deliver a method to extract more knowledge from existing data.CITATION:Hodgkinson, J H, Grigorescu, M and Khanal, M, 2016. Reducing mine site extreme rainfall vulnerability using climate-related adaptation from terrain evaluation results, in Proceedings International Mine Management Conference, pp 187-200 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jun 22, 2016

By C E. Loo

The cohesive zone has a significant influence on blast furnace operation and performance. The high-temperature behaviour of the reducing ferrous burden determines the properties of the cohesive zone and is studied in a laboratory using a softening and melting test. This paper summarises recent work aimed at better understanding the physico-chemical changes in a ferrous bed during softening and melting. Using a combination of standard, non-standard and quenched tests supported by optical image analysis, this work has highlighted some important differences in behaviour between lump, pellets and sinter as well as between the two lump ores and two acid pellets. As with the two lump ores, one pellet is denser than the other and the denser ore/pellet is also higher in silica.Within the cohesive zone, densification of the ferrous layer leads to reduced permeability and greater pressure drop. From the work presented in this paper, two key mechanisms of ferrous layer densification were identified. Firstly, the formation of fayalite, which melts at low temperatures, can act as a lubricant between particles and lead to densification of the ferrous layer under load. Secondly, reduction to metallic iron is topochemical and fayalite in the outer shell of the particle restricts gas flow to the centre and results in the formation of a wustite core. As temperatures rise, the wustite melts and eventually exudes out of the shell, occupying void spaces between particles and further reducing layer voidage and permeability.This work has shown that density and silica content are two key factors that result in increased densification of the ferrous layer. For porous Australian lump ore, the higher porosity and lower silica reduces the formation of fayalite and limits the formation of the wustite core, ultimately leading to a more permeable bed. The difference between the porous and dense ores was more pronounced with the introduction of prereduction to better simulate blast furnace conditions. This suggests that a porous ore gives significantly better cohesive zone permeability and blast furnace operations than a dense ore.The behaviour of fluxed sinter particles is different in that the silica reacts with lime to form dicalcium silicate. Minimal wustite core forms because relict hematite particles in sinter are only small and reduction occurs uniformly throughout the particle. Even with significant loss of material through prereduction, beds formed from sinter remained comparatively rigid. Studies using a typical blast furnace burden mix of 80 per cent fluxed sinter and 20 per cent porous ore showed that the structures of these beds at softening and melting temperatures are very similar to the sinter-only test. Measurements of bed contraction and pressure drop also confirmed that the introduction of 20 per cent porous ore into a sinter bed did not alter its properties. This is an indication that 20 per cent ore can be easily accommodated by blast furnace burdens.CITATION:Loo, C E, 2015. Important acid ferrous burden properties in the cohesive zone of a blast furnace, in Proceedings Iron Ore 2015, pp 367–376 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015

By A McKay

The Great Artesian Basin (the Basin) is a large aquifer system underlying more than 20 per cent of continental Australia and most of Queensland. The aquifers of the Basin are an important water source for many industries, including the mining sector. The Queensland Great Artesian Basin Water Resource Plan (the Plan) was released in March 2006. The Plan provides a framework for the long- term holistic management of the aquifers in the Queensland Section of the Basin, in a manner that is consistent with the strategic management plan for the Basin as a whole. The paper describes the Basin and summarises trends in the demand for water in the Queensland section of the Basin. It describes the broad framework for management of the Basin by the individual Australian states, as well as the planning entitlement framework for water resource management in Queensland. The paper discusses the content of the Plan. This includes: the division of the aquifers into management areas and management units for management purposes, provision for protection of the flow of water to springs, limits on further allocating water, provision for a competitive process for access to new water and provision for water trading. Under the Queensland planning and entitlement system a resource operations plan is prepared to specify operational arrangements to implement a water resource plan. A resource operation plan for the basin is expected to be finalised before the end of 2006. The paper summarises the likely content of the plan.

Jan 1, 2006

By T Blyth, D Holden, N Archibald, S Huffadi

The Morning Star mine is owned by Hill 50 Gold NL. Gold is hosted in quartz-carbonate ¦stibnite ¦molybdenite veins that occur in a series of deformed, altered and metamorphosed mafic volcanics with subordinate sediments and felsic intrusive rocks. The irregular gold distribution and its relationship to structure and alteration intensity makes the definition of stoping limits difficult. Understanding the structural evolution of the orebodies and the contemporaneous and later structures that affect the orebodies has been very useful in this context. This paper reports on a detailed mapping exercise (as part of a more extensive and on-going investigation) and the integration of this mapping with other geological and grade control data in a 3D modelling environment to provide an expanded basis for stope design. Three types of mineralised zones can be discriminated based on the morphology of the veins within. They are:those associated with strongly folded, thick veins (approximately 1 m thick eg 05 orebody); those comprising planar, boudinaged and some folded veins which consolidate to form tabular, steeply dipping bodies (eg 010 orebody); and zones containing the above vein types and thin, highly deformed veins within zones of intensely foliated country rock that result in localised, irregularly distributed high-grade gold zones (eg 02 orebody). The mineralised zones associated with thick folded veins are typically predictable over many tens of vertical metres. The second and third types of ore zone is generally less predictable. Detailed mapping and structural kinematic studies indicate all ore zone types are affected by progressive deformation involving strong strain partitioning. It is interpreted that high strain zones, recognisable by intense foliation development and highly deformed veins, are the latest stage of a progressive deformation which approximates bulk flattening. Structural controls on mineralisation can be defined at two different scales.Regional scale folding has deformed a sequence of mafic volcanics with interlayered sediments and felsic intrusives. Initial geometry of felsic bodies relative to orientation of the primary lithological layering and the bulk shortening direction is interpreted to be critical for initiation and development of strongly dilatant zones within this package of rocks, and Local scale dilation is evidenced by development of several vein sets whose range in orientations and opposed vergence relationships suggest a pre-folding origin comprising both extensional and hybrid shear-extensional types. Continued deformation resulted in folding of these veins with strong strain partitioning. Major vein packages are closely spatially associated with the felsic/mafic contact and an interpreted early structure which appears to have partitioned early dilation. This structure is now obscured by strong deformation but is currently represented by a zone of planar veins.

Jan 1, 2000

By T Raynlyn, A Edenton, M Adam, R J. Holmes, J R. Manuel, N Ware, R Smyth

Due to ongoing demand and increasing depletion of high-grade iron ore resources from large deposits, Australian iron ore producers are developing smaller size deposits to maintain current export levels. The iron grade, mineralogy, chemical and physical characteristics of iron ore fines being mined from different deposits vary considerably. It is therefore imperative to develop long-term strategies to maintain the quality and consistency of iron ore fines while moving to a larger diversity of smaller deposits. Blending is a common practice in sinter plants as it is almost impossible to produce a high performance sinter mixture displaying the required characteristics from one single ore. Blending is also one of the most effective options being used by iron ore producers to ensure the long-term stability of their products while increasing production. When designing a blend, the blend components are selected to support each other to achieve the required overall balanced metallurgical performance of the final product at a relatively low cost. To do so, a fundamental understanding of the key characteristics of iron ore fines and their potential impacts on the iron ore sintering process and sinter quality are required. In this paper, the sintering process and sinter structure have been analysed and the key factors affecting the sintering performance of iron ore fines, including productivity and quality, identified. Under fixed sintering conditions, the granulation efficiency, nuclei stability and the volume and properties of the primary sinter melt are believed to have important impacts on both sintering productivity and sinter quality. Discussion is then focused on the effects of ore chemical, physical and mineralogical characteristics on the key factors identified and in turn the consequences for sintering productivity and sinter quality.

Jan 1, 2009

By J Zhang, O Ostrovski, C Zhang D Cai, Q Wang

The conventional CaO-SiO2-based mould fluxes are not suitable for high-Al steel casting because of the strong reaction between silica in the flux and aluminium in the steel strand. In the process of casting of high-Al steel, flux composition changes; with the decrease of the silica concentration and increase of alumina. Knowledge and understanding of the effect of the Al2O3/SiO2 ratio on flux structure and properties are useful for flux design for the high Al-steel continuous casting. This paper investigated the effect of the Al2O3/SiO2 ratio on structure, viscosity, phase composition of fluxes quenched at different temperatures and heat transfer of CaO-Al2O3-SiO2-B2O3-Na2O-Li2OMgO- F fluxes. It was found that flux melting temperature increased with the increase in Al2O3/SiO2 ratio. Viscosity of the flux melts increased significantly with the increase of the Al2O3/SiO2 ratio from 0.7 to 1.2, reaching the maximum value, and then decreased with further increase of the Al2O3/SiO2 ratio. Raman spectroscopy analysis revealed that the change of the Al2O3/SiO2 ratio led to the change of aluminate and silicate structural units. The turning point for viscosity was attributed to the change in the degree of flux polymerisation. X-ray diffraction (XRD) analysis showed that increasing Al2O3/SiO2 ratio increased crystallisation tendency of the fluxes. Heat transfer measurement by infrared emitter technique (IET) revealed that increasing Al2O3/SiO2 ratio led to the decrease in heat flux which is correlated well with the increased crystallinity of the flux. The results suggested that the flux with Al2O3/SiO2 ratio 4.3 is the best candidate among the studied CaO-Al2O3-based mould fluxes for casting of high-Al steel.

Aug 21, 2024

By D Giurco

As part of global systems of mineral production and consumption, the Australian minerals sector is facing sustainability challenges across technological, social, ecological, economic and governance domains, as well as between local, national and global scales. To ensure that the Australian minerals sector progresses towards sustainability, it is imperative to understand the possible ways in which AustraliaÆs mineral resources could support sustainable futures. A significant research gap exists between the complex nature of questions concerning minerals sustainability and the reductionist methods available to deal with them. This paper argues the need for broader, more integrated approaches to questions concerning minerals sustainability, which can address multiple human perspectives, complex and æmessyÆ patterns and processes across multiple organisational, temporal and geographical scales and whole systems of mineral production and consumption. To inform the development of a new approach to minerals sustainability, this work reviews the contemporary understanding of the Australian minerals sustainability problematic, from the perspective of the Australian minerals sector (Minerals Council of Australia), the Australian research sector (Mudd 2007a, 2007b; Mudd and Ward 2008) and a multi-scale international project (MMSD 2002). This review shows the focus of current responses to the minerals sustainability problematic, identifies the need for an integrated approach to questions of minerals sustainability and addresses how different approaches are informed by underlying and unarticulated assumptions about the tolerability of tradeoffs between different societal goals, the treatment of uncertainty and the application of different conceptual geographical, organisational, temporal and life cycle scales to define the minerals sustainability problematic. The Mineral Resources Landscape proposed, offers an expanded conceptualisation of minerals sustainability, to link minerals production and consumption in an integrated assessment across the entire minerals supply chain, connecting social, ecological, technological, economic and governance domains across local, national and global scales. The key leverage points governing change in the Mineral Resources Landscape are identified as: the material source, extraction and production technologies, level of service and value, and consumption patterns. Mapping the key challenges facing the minerals sector, as identified in the review herein, indicates that the boundaries defining traditional conceptualisations of minerals sustainability focus on the material source and technology and ignore two very key drivers of the Mineral Resources Landscape û the æservicesÆ minerals offer to society and the æconsumption trendsÆ which assimilate these services into society. Understanding these overlooked aspects of the Mineral Resources Landscape, along with the conventional areas of focus, is essential for identifying the Australian minerals sector as a provider of sustainable mineral services. This insight prompts a reconsideration of the role of minerals services and consumption trends, together with the role of the material source and technology in shaping change and the emergence of sustainable systems of Australian minerals production and consumption, across multiple scales and domains.

Jan 1, 2009

By S Basu, P M. Midhun

Electro-Slag Remelting (ESR) is a process capable of producing ingots with much lower centre-line segregation and better internal soundness than conventional ingot casting processes, as well as lower inclusion and sulfur concentrations. This process is commonly used for alloyed steels intended for critical applications like components of marine turbines, supercritical powerplants and rocket motor casings. It involves melting a metal electrode using electrical resistive heating in a slag pool and re-solidification of the resulting metal droplets beneath the slag layer, forming an ingot. Conventional ESR fluxes consist primarily of CaF2, Al2O3 and CaO, along with minor concentrations of SiO2, MgO etc. The emission of fluoride vapour from the molten slag causes several environmental and health problems, triggering a need to develop and reduce the fluoride content in the ESR flux. The present study aims to develop low-CaF2 alternatives to commercial ESR fluxes without compromising on productivity and the surface quality of the refined ingot. Thus, the modification in chemical composition needs to satisfy properties like electrical resistivity, viscosity and liquidus temperature, essential for efficient ESR operation. Since electrical resistivity and viscosity are highly dependent on the ionic structure of the molten slag, it is important to understand the effect of compositional modification on the structure of the flux. The present study employs Fourier-transform infrared spectroscopy (FT-IR) and Raman spectroscopy to investigate the structural variations in the modified fluxes, especially the effect of changing SiO2 concentration, in comparison with conventional CaF2-rich fluxes. Additionally, thermal analysis (Differential Thermal Analysis (DTA) and Thermogravimetric Analysis (TGA)) has been carried out to characterise the melting behaviour of the fluxes. The findings are compared with simulations carried out using the FactSage™ software, ver 8.3 (GTT Technologies, Aachen, Germany). Simultaneous analysis of liquidus temperature and the structure is expected to help in identifying the practical suitability of modified ESR flux compositions for industrial implementation.

Jun 19, 2024