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By Brian Hawkins, David Bradley, Rachel Gooding, Lucas Rodriguez, Patrick Wilson, Kevin Wegman, Dhruv Mittal

To better protect the nation and inform difficult defense and preparedness decisions, the Department of Homeland Security (DHS) is performing a probabilistic risk assessment of explosive terrorism risk to the US homeland. After assessing existing models against requirements, well-developed mathematical descriptions and algorithms associated with explosives hazards were combined with probabilistic modeling techniques used in DHS chemical, biological, radiological, and nuclear (CBRN) terrorism risk assessments to create a suitable interior explosive consequence model for assessing the impact to human health.

Jan 1, 2018

By Joseph Licavoli, Paul Sanders, Yang Yang

"Al-Sc-Zr alloys form thermally stable L12 precipitates which provide high temperature strength. Although the overall fraction of L12 Al3Sc and Al3Zr may be increased by increasing scandium (Sc) and zirconium (Zr) content, such additions may increase primary phase fractions and do not produce desirable secondary phase morphologies. Rapid solidification techniques, such as melt spinning, increase solute atom concentration within the matrix. When the supersaturated matrix is aged, higher precipitate volume fractions at low Sc and Zr levels can be achieved improving high temperature strength. Melt spinning was used to rapidly solidify (107 k/s) a thin ribbon of Al-0.5Sc-0.4Zr at. %. The ribbon was compacted and extruded into 99.8% dense rods, and then aged using multi-step isochronal heat treatment up to 600°C. Precipitation strengthening was evaluated by ambient hardness measurement. The ambient hardness of melt-spun ribbon after precipitation hardening increased by 450 MPa (~67% increment) during isochronal heat treatment.INTRODUCTION Small Sc and Zr additions to aluminum improve strength and creep resistance above 300°C due to tri-aluminide precipitation of Al3(Sc,Zr) in L12 structures similar to ??, Ni3(Al,Ti) in nickel superalloy, but the Al3(Sc,Zr) particles have a Sc-rich core surrounded by Zr-rich shell (Figure 1). The Al3Zr shell limits atomic transport between the Al3Sc core and the matrix and reduces coherency strain. These factors reduce precipitate coarsening rate at elevated temperature (Bergner & Van Chi, 1977; Fujikawa, 1997; Knipling et al., 2011; Clouet et al., 2006).Figure 1. Simplified schematic model of precipitate Al(Sc,Zr) in Al-Sc-Zr alloy. Shell is rich of Al(Zr) intermetallic phase, particle core is rich of Al(Sc) intermetallic phase (after Voorhees, 2006). Numerous Al3(Sc,Zr) particles increase alloy strength and creep resistance as the precipitates impede dislocation glide and to a lesser extent climb. Previous work on ternary Al-Sc-Zr alloys show large strength increases versus binary Al-Sc, and Al-Zr alloys in Table 1."

Jan 1, 2018

By Eugene Mirsky, Eloy Ramos, May ElKhattab, John Wise, Terrence Carroll, Jose Torres

In 2017, Nicholson Construction Company completed a $72.1 million design-build contract for Miami Dade Water and Sewer Department to replace an existing 54-inch diameter pre-stressed concrete force main that runs from the Virginia Key Central District Wastewater Treatment Plant, under the Biscayne Bay at Norris Cut, to Fisher Island. In order to install the new sewer pipe below the bottom of Biscayne Bay, a tunnel boring machine (TBM) was launched from a 42ft diameter and 89ft deep shaft on Virginia Key and a precast segmentally lined tunnel was constructed towards a 28ft diameter and 72ft deep retrieval shaft on Fisher Island. Both shafts were constructed through sand and highly permeable limestone, primarily the Fort Thompson Formation which is part of one of the most permeable aquifers in the United States and two different techniques were used to ensure a water-tight shaft at each end of the tunnel drive. The launch shaft structure was built using the secant pile technique, wet excavation and a tremie plug. For the tunnel break-in a soil freeze block was installed after the ground was treated with low mobility grout. The retrieval shaft was built using the Deep Soil Mixing (DSM) technique and excavated in the dry. Precedence of any other structure built this deep through hard layers (UCS over 3,000 psi) using this technique was not found. This case study addresses the challenges of constructing watertight underground structures in highly porous ground for launching and retrieving a TBM. Design challenges from complex asymmetric loading, selection and comparison of the construction techniques, the installation and excavation of both shafts, and their performance are also discussed herein.

Jan 1, 2018

By R. Perlo

"INTRODUCTION Peoples’ and operators’ safety in construction are tightly linked to the engineering choices, as much as the necessity of reducing time and costs of realization. Therefore, it is of paramount importance to address them properly from the earliest stage of the design, identifying the risks connected to the work and the variability of such during the different phases of the project. Risk is often measured as the expected value of an undesirable outcome. Regarding to occupational safety and health, the risk is the likelihood that a person may be harmed of suffers adverse health effects if exposed to a hazard. This combines the probabilities of various possible events and the assessment of the corresponding harm into a single value. However, the actual occurrences are often more complex than a single binary possibility case. In a real case scenario, with several possible accidents, the total risk is the sum of the risks for each different accident, provided that the outcomes are comparable. The semi-automatic tunnel support system along with its erector machine proved to be a solution with improved structural performance, able to reduce the time and yet to deliver an enhanced, quality-aware and safer working environment for the operators. The implementation of the system provides the engineers, the contractors and the owners with an effective alternative option shortlisted in 2015 for the ITA Award for the Safety Innovation of the Year. In a market industry driven by safety and time constrains the efficiency shall be the ultimate goal, in order to provide solutions able to negotiate with the most challenging ground conditions. In this paper, the authors describe the recent developments on regard of this whole new tunnel support system, including design approach and presenting related case histories OFFSETTING THE RISKS Considering the above factors, from the manufacturers’ point of view, an effective way to limit the construction risks is to focus on the material and technological characteristics, their application and the risks related to them including any residual risks. Finally addressing the construction needs also involves time and cost-effective solutions. The path to follow is an integrated approach where the efficient management of the risk is supported by a flexible, user-friendly, and time effective product that is able to provide a safe, reliable and viable solution to address the construction requirements. Therefore, in a market sector driven by safety and time constraints, the efficiency is a key goal, in order to avoid redundancy and yet to deliver a safe working environment able to meet the construction schedule. The safety of all the parties involved is given by stable working conditions, either for the workers, or the operators and eventually the public. Therefore, the solutions provided should ‘strengthen’ the overall condition and such “to limit or to reduce the deformations within acceptable designed limits and to prevent [the tunnel] to collapse” [1: Clause 207.1.4]."

Jan 1, 2018

By T. Bauerle, G. Poplin, Z. Dugdale

"The issue of mine worker fatigue is as complex as it is understudied. Generally, worker fatigue lies somewhere on a continuum between psychology and physiology, which makes the measurement and management of it difficult with no easy solutions for operators or workers. Answers to even basic questions remain elusive—such as what is fatigue, how is it measured, and how can organizational resources reduce fatigue—and answers seem to present no single, clear path to action for the health and safety of the worker. This manuscript supplements the growing body of interest in the problems of fatigue in the mining industry by reviewing some of what is known about worker fatigue in general and in the mining industry in particular. The material covered here includes basic topics of the hows and whys of worker fatigue; an overview of fatigue models, findings, and evidence-based solutions with a focus on mining; and potential future directions aimed at mitigating miner fatigue. INTRODUCTION “It is recommended that the whole fatigue test problem be stated in a form the nature of which may be indicated by the following suggestions: that the term fatigue be absolutely banished from precise scientific discussion, and consequently that attempts to obtain a fatigue test be abandoned [emphasis added].” – Bernard Muscio, Pioneer Australian Philosopher and Industrial Psychologist, in a 1921 Report to the Cambridge Industrial Fatigue Research Board Fatigue presents several challenges for the mining industry. Depending on the specific occupation, daily work, or operational setup on any given mine site, mining jobs can have a fair amount of labor-intensive tasks mixed with monotonous and repetative duties. Combined with the long working hours and shift-work schedules of mining work, the prevalence of fatigue in mine workers may seem rather unsurprising. On the one hand, mining is certainly not alone in facing the challenge of addressing worker fatigue. Indeed, many of the characteristics above mirror the similarities of fatigue in other industries, such as health care, aviation, and security. To the extent that fatigue in mining acts like fatigue in any other industry, then any fatigue management applications, trainings, or interventions in existence can be borrowed from other industries and applied to mining in a “cookie-cutter” approach. On the other hand, some have argued that mining in particular is especially susceptible to increases in the prevalence of fatigue beyond the characteristics listed above due to the multifaceted combination of factors in mining environments associated with fatigue: dim lighting; limited visual acuity; hot temperatures; loud noise; highly repetitive, sustained, and monotonous tasks; shiftwork; long work hours; early morning awakenings; and generally poor sleep habits (Canadian Centre for Occupational Health and Safety, 2012; Legault, 2011). Legault (2011) in particular argues that it is the combination of these factors simultaneously that can make mineworkers particularly susceptible to sleep deprivation and fatigue in comparison to other industries where these factors are often not present alltogether. If fatigue looks and acts different in mining, as others have argued, more research is needed to determine if, how, and why worker fatigue might need to be managed differently in mining."

Jan 1, 2018

By S. Carsten, S. Subramanian, R. Vasant Kumar, S. Vimalnath

"The effect of EPS components namely protein, polysaccharide and biosurfactant purified from Pseudomonas fluorescens was investigated for the bioremediation of Pb(II) ions in aqueous solution. Two parameters, namely the amount of EPS component and the concentration of Pb(II) ions were optimized for maximum Pb(II) ions uptake. The EPS components interacted with Pb(II) ions were characterized using energy dispersive X-ray analysis (EDAX) to ascertain the presence of Pb and by attenuated total reflection-Fourier transform infrared spectroscopy (ATR–FTIR) to reveal the functional groups involved in Pb(II) binding. The maximum Pb(II) binding capacities of protein, polysaccharide and biosurfactant were found to be 11.4, 0.55 and 0.11 mg mg-1 respectively. The biosorption processes followed the Langmuir model. The Gibbs free energy (?G0) values of -23.6, -20.9 and -23.2 kJ mol-1 for Pb(II) biosorption by protein, polysaccharide and biosurfactant respectively, attested to spontaneous, chemisorption processes. The ATR–FTIR results revealed the presence and involvement of amino, hydroxyl, carboxyl, phosphate, and methyl functional groups in Pb(II) binding and EDAX analysis confirmed the interaction of Pb with EPS components. The Pb(II) binding mechanisms of EPS have been discussed. The results demonstrate the potential of the purified EPS components of P. fluorescens for removal of Pb(II) ions from aqueous solution INTRODUCTION Waste water containing toxic metals from various industries pose a serious threat to human health and ecosystem. For treating such waste water, conventional methods like chemical precipitation, coagulation, evaporative recovery, electrodialysis, floatation, flocculation, ion exchange, reverse osmosis, nanofiltration, ultrafiltration are used (Lakherwal et al., 2014). These methods have some disadvantages like toxic sludge generation, incomplete metal removal and high cost (Singh and Gadi, 2012), necessitating the search for cheaper and efficient alternative methods. Bioremediation is one of the emerging alternatives where bacteria, fungi, yeast, algae and other biological substances are used as sorbents to remove toxic heavy metals (Vijayaraghavan, et al., 2015). Recently, the bioremediation potential of extracellular polymeric substances (EPS) of microbial origin has attracted attention. However, for Pb(II) removal, there is a paucity of literature focusing on EPS."

Jan 1, 2018

By I. Govender, M. C. Richter, N. Mangadoddy

"We present an analysis of trajectory and time averaged data of near gravitational material (NGM) representative coal tracer particles within a magnetite medium passing through a 100mm diameter hydrocyclone imaged with PEPT (positron emission particle tracking) at iThemba labs, Cape Town. The tracking of neutrally buoyant tracers as well as the other NGM allows an empirical study of the approximate dynamical behaviours of both the dense medium as well as the range (size and density) of particles around the separator’s cut size within a partially imaged volume of the cyclone body lying within the field of view of the detector. The study was commissioned as part of a CFD validation study using empirical data from a real-world lab-appropriate system in order to shed light on the inner workings of hydrocyclones and their separation mechanisms. We employ various optimisation and noise reduction techniques within the analysis and follow a detailed investigation of the velocity fields derived from the raw spatial positions with an emphasis on the velocity profile within the forced and free vortex zones. Challenges encountered with this high velocity particle tracking experiment within a highly attenuating environment are also discussed. Various important velocity distributions are shown and compared to theoretical predictions. The power law decay profile of the free vortex and radial velocity scaling with regards to the Froude number are reproduced in line with the static particle approach. INTRODUCTION Cyclones have long been a vital industrial tool for the separation of different classes of particles. These cyclonic separators (with either gas or liquid medium) operate by forcing the solids-bearing fluid at high pressure into a cylindrical vessel causing high tangential velocity fluid rotation as well as, in the case of an “open” (with exit channels open to the atmosphere) cyclone, a central vortex air column spanning from underflow to overflow exit. The fluid is forced to exit the cyclone at two locations, the spigot and the vortex finder, generating the underflow and overflow respectively. The body of the cyclone usually terminates in a conical shape to focus the underflow stream. This geometry and large incident fluid velocity force high density materials toward the wall of the vessel where they are most likely to move along and down the inside wall away from the inlet to exit via the underflow while lower density materials traverse the cyclone body closer to the central vortex and are buffeted by the upward-moving column towards the overflow exit. This separation mechanism is selective of density and size in an interplay between the centrifugal force due to the rotation of the fluid and a drag force acting on the particles."

Jan 1, 2018

By J. Seifert, L. Hunter, P. W. Conrad, S. Rosenthal

"The goal of the protocol for reclaiming in-pit tailings ponds to exceed federal and state regulations was to develop a series of steps that can be followed to design, operate, and reclaim a tailings disposal pond that will develop into grazing land with a wetland for open pit sand mines in warm dry climates. By incorporating a wetland into the reclamation design, the post mining land use gives back to both the wildlife as a source of water as well as providing for a diverse range of post mining land use including but not limited to livestock grazing and ranch land use. An example design was completed using this protocol to demonstrate how the protocol can result in in a well-designed, reclaimed tailings disposal pond. BACKGROUND In an industry plagued with decaying historic mine sites, the public’s perception of mining appears to be poor. While modern mines are closely monitored and generally managed by ethical professionals, history still influences how the public perceives the mining industry. From collapsing abandoned underground workings to historic tailings dam failures, the failure to account for the environment in the past seems to affect public perspective on mining today. In a 2013 “Opinion Former Survey,” a survey conducted through interviews with a diverse range of stakeholders in various gold companies, it was noted that the most serious challenges facing the mining industry were environmental concerns and the permitting challenges associated with them (Council). In another article, this time focusing on Australian citizens and their perspectives of the mining industry, it was found that the majority of those surveyed had a big concern over the environmental impacts of mining especially when it comes to water quality and quantity (Scan). The statistics portrayed in these articles illustrate that today’s mining engineers needs to make more of an effort to change the public’s perspective of mining by being more environmentally aware. These engineers should be continuously asking themselves what they could be doing better from an environmental perspective to ensure that history is not repeated and that natural resources are used as efficiently as possible."

Jan 1, 2018

By V. A. Masloboev, A. V. Svetlov, D. V. Makarov

"The methods of heap leaching are considered to be the most promising for the low-grade copper-nickel raw materials. The article presents intensification capabilities of the process. Objects of research: the low-grade copper-nickel ores of Moncheplutone deposits (Moroshkovoye Lake, Nyud Terrasa, Nittis-Kumuzh’ya-Travyanaya (NKT), as well as the copper-nickel ore dressing tailings of the “Kola MMC” JSC. The following directions for the intensification of the low-grade copper-nickel raw materials heap leaching have been considered: preliminary electric pulse destruction (EPD) of ore; ore crushing and further sulfuric acid agglomeration. The impact of sulfuric acid concentration (1-3%) on the extraction of non-ferrous metals kinetics from the copper-nickel ore dressing tailings under various conditions of the percolation leaching has been studied. INTRODUCTION The low-grade grade sulfide ores at the abandoned and producing deposits, overburden rocks, mill tailings and non-ferrous slag are thought to be one of the large-scale sources for non-ferrous metals, on the one hand. On the other hand, they are known to be the subjects of emergency environmental danger. For this reason, the use of mine dumps and tailings, as well as the remained ores left in the ground as raw products, and at the same time decreasing the load on environment, are considered to be the pressing ecological and economic issue (Chanturia et al., 2012). Methods of heap hydrometallurgical and bacterial leaching are sure to be potentially productive for processing such low-grade and technogenic raw materials (Petersen, 2016). The early studies of hydrometallurgical method possibility to process copper-nickel ores of the Murmansk region deposits were launched in the seventies of the previous century (Golovko et al., 1978). For referencing purposes, the main types of impregnated ores from the deposits Zhdanovskoye, Kaula, Sopchinsky Plast and Lovnoozerskoye were selected. The metal content varied, as %: 0.46-1.49 of nickel, 0.01-0.62 of copper. In the first experiments, the solution containing 150g/l of H2SO4 and 135g/l of NaCl, was used in the capacity of leaching reagent. The possibility of underground metals leaching from the ores of the Lovnoozerskoye deposit was justified due to the performed laboratory and further large-sized tests."

Jan 1, 2018

By Ifeanyichukwu Nweke

"Aluminium rolling processing from ingots to cold rolled coils comes with a lot of challenges especially in controlling defective products in casting, hot mill and cold mill operations. Hence this study focused on reducing defects at mills and cast-house using six sigma approaches. The use of six sigma approach will help the production experts to determine the gap between its operation and world class process. Practical data from First Aluminium Rolling mills were presented and analysed and mini improvement projects were proposed based on organisation need to achieve excellence. This study encourages aluminium alloy industries to pursue process improvement projects on the basis of analysis on data obtained from their shop floor, hence ensuring that through this, recovery is improved and cost of poor quality is reduced.INTRODUCTION Engineer Bill Smith while working at Motorola in 1986 introduced a new concept in which a set of techniques and tools are used for process improvement by controlling variations (defects). These tools and techniques are explained by an acronym DMAIC. D DEFINE the problem M MEASURE the variables in the problem A ANALYSE the variables of the problem I IMPLEMENT and verify the solution to the problem C CONTROL the solution to sustain it Most times in six-sigma approach, variations in the process that results in defects and customers’ dissatisfaction are targeted at 3.4 defects per million opportunities. There are numerous methods six sigma application use to achieve quality results and innovative strategies. Improving the quality of process through these methods helps identify and reduce variations which paves way for organisational excellence. In this study, it is encouraged to use six sigma techniques to improve aluminium rolling operations and other aluminium processing activities, the benefits of such improvement concept include: • Satisfy the voice of the customer (VOC) • Minimise costs • Maximise Profits • Build Good Team • Implement Profitable Project"

Jan 1, 2018

By P. Homola, M. Karlík, M. Slámová

"Aluminum sheets (AA1199, AA8006, and AA5754) were processed by accumulative roll-bonding (ARB) in the temperature range from 20 to 350°C. The microstructure of the sheets was characterized by means of scanning and transmission electron microscopy and electron backscattered diffraction. Mechanical properties were monitored by hardness measurements and tensile tests. Increasing strain (number of ARB cycles) led to incremental development of lamellar microstructure with a decrease of the spacing between high-angle grain boundaries in the normal direction of sheets. ARB process produced an important increase of strength while maintaining thickness and relatively high ductility, without accenting of the anisotropy of mechanical properties of sheets. The level of hardening decreased with the processing temperature and at 300 and 350°C ARB caused even the softening of the material due to the recovery of the deformed microstructure or partial recrystallization during heating to ARB processing temperature.INTRODUCTION Accumulative Roll Bonding (ARB) is a technique of grain refinement by severe plastic deformation (SPD) proposed by Saito et al. (1999). One ARB cycle consists in sheet cutting, surface treatment, stacking of two pieces, heating (optional), and rolling with 50% reduction in thickness. Since the sheet thickness remains unchanged by this cycle, ARB processing can be repeated as many times as desired. The goal of ARB is to impose an extremely high plastic strain on the material, resulting in structural refinement and strength increase without changing specimen dimensions. After several cycles, ultra-fine grained (UFG) materials with high strength and relatively high ductility are produced. An advantage of this method is that it does not require any special equipment as other SPD methods such as equal channel angular pressing (ECAP) (Valiev & Langdon, 2006), high pressure torsion (HPT) (Valiev et al., 2000), or cyclic extrusion and compression (CEC) (Richert et al., 1999), but only a conventional rolling mill and so it is seen as an economically viable and industrially scalable processing route. ARB processing has been successfully applied to various kinds of metallic materials at room or elevated temperatures (Tsuji, 2005). Besides processing single metals and alloys, ARB has also been used for creating ultra-fine grained and nanograined metallic composites (Wu et al., 2010; Qu et al., 2014)."

Jan 1, 2018

By Richter, E. Charikinya

"Mineral processing unit models require information on particulate properties such as particle size, solids flowrate and mineralogical composition to model their operations. Process models that describe the separation process can be classified based on the level of information required from the ore, i.e. the feed stream to the separating unit. The most comprehensive level of mineral processing models is the particle-based modelling approach. Particle based modelling describes a modelling approach where mineral composition, mineral liberation and textural information of particles making up the process streams is used in modelling. The advantage of this approach is that all model streams carry particle level information (size, liberation, shape). This information is obtained by applying automated mineralogy techniques such as Quantitative Evaluation of Minerals by Scanning Electron Microscopy (QEMSCAN) analysis which provide accurate and detailed information on process stream particle properties. Currently the use of liberation information in modelling and simulation is rare, due to the limited number of separation models that liberation data as input. The objective of this study is to develop a particle based model for a dry magnetic separator, where mineralogical information is used directly to simulate a dry magnetic separator operation. Magnetic separation tests were carried out on high, medium and low grade magnetite ores using a laboratory magnetic separator. Streams from the separator were sampled and sized for chemical and liberation analyses. A sized mass and elemental balance around the magnetic separator was carried out. The elemental assays of each stream were converted to mineral quantities and a sized mineral balance was done. QEMSCAN measured liberation data was reconciled to the mineral balance based on mineral quantities obtained from chemical assays. This was followed by the development of a particle based model that calculates the trajectory of a single particle based on its mineral composition and textural properties. The model was tested on experimental data and was able to predict the effect of variation in process feed stream mineralogical attributes (liberation, grade, particle size) on magnetic separation performance. Results of this study highlight the benefits of the particle based modelling approach. INTRODUCTION The extraction of mineral values from ore requires liberation of the value minerals from the gangue followed by their separation. Liberation is achieved by size reduction operations (Desmond, 2008; Fuerstenau and Abouzeid, 2002). Separation of gangue material from value mineral takes place in various mineral upgrading stages such as classification, magnetic separation and flotation. In these concentration stages value minerals are separated from gangue minerals based on the physical properties of the ore particles making up the feed such as size, liberation, volume of magnetic material and density. The success of separation is related to the liberation of the feed particles, the performance of the separation technology applied, as well as the inherent characteristics of the feed material (Leißner et al., 2013)."

Jan 1, 2018

By S. A. Bogidaev, M. Yu. Tiunov

"The paper describes the results of the flotation tests with complex rare metal ores from deposits in the Trans-Baikal Territory. Correlations between the quality of produced wolframite, hubnerite and mica concentrates with or without the presence of various alkaline modifiers are determined. Commonly, rare metal ores contain minerals of comparable value to main elements recovered in processing plants using gravitational methods. The paper describes the results of flotation recovery of valuable minerals – main and associated – from gravity tailings of deposits in the Trans-Baikal Territory. It was found that gravity tailings from the first deposit contained fine-grained wolframite, mica (muscovite, lepidolite etc.), feldspar; hubnerite, scheelite, beryl, fluorite, rubidium-containing muscovite from the second deposit, correspondingly. This paper presents the results of the stage flotation tests with the production of tungsten (wolframite, hubnerite), fluorite and mica concentrates from gravity tailings. Figure 1 demonstrates the flowsheet of tungsten ore minerals and mica stage flotation from gravity tailings of the first deposit.Wolframite can be floated using oleic acid with the presence of soda ash, a complexing collector (IM-50), under slightly alkaline conditions in combination with a nonpolar collector [1, 2, 3, 4]. The study included wolframite flotation using the combination of two alkaline modifiers. Flotation of wolframite was performed after pulp desliming, using tall oil saponified with soda ash. The recovery of wolframite in the concentrate of rougher flotation reached 80-85%; the concentrate contained up to 1% of tungsten oxide that can be upgraded to a saleable product using gravitational methods. This procedure was tested during flotation of wolframite, tantalite-columbite and pyrochlore, and provided high performance regardless of a season, at pulp temperatures of 8-10°C, though fattyacid collectors are significantly inefficient at such low temperatures due to low solubility, dispersion and increased collector consumption, consequently. The introduction of two alkaline modifiers in pulp appears to improve these characteristics.The first stage of the tests was focused on increase of iron-bearing tungsten ore minerals recovery from gravity tailings and stabilization of the cold pulp flotation process."

Jan 1, 2018

By Frans van Grunsven, Cees van Rhee, Geert Keetels

One of the obstacles during the initial phases of project development is the assessment of the environmental impact. Mining residue, consisting of fine seafloor sediments, are to be discharged subsea to mitigate the impact of these suspended particles. In order to test the effectiveness of discharging in proximity of the seabed, a numerical model is developed within the open source software package OpenFoam. Dedicated laboratory experiments for numerical model validation are discussed within this paper. INTRODUCTION Siltation is considered one of the major pressures on the environment for a seabed mining operation. Siltation is defined as the pollution of water by a high concentration of suspended sediments like clay or silt. This can be caused by two main activities during the mining process: the spill loss during the excavation and the return flow of undesired seafloor sediment after ore filtration on the ship. In a concentrated cloud, these fine particles form a so-called turbidity plume. Prediction of the size of these plumes and the created layer thickness of deposited sediment is a crucial part of the environmental impact assessment. The challenge in predicting the behaviour of these plumes is found in the wide range of scales involved in the process. At the point of origin, the turbidity plumes spread mainly under the influence of turbulent whirls created by an initial momentum and a buoyancy difference due to the presence of the suspended sediment particles. If carried by ambientcurrents, these plumes can spread for several kilometres before blending in the background.

Jan 1, 2018

By V. Panayotov, M. Panayotova

"Wastewater from ores processing is often polluted by molybdate and sulfate (SO42-) ions. Sorption is one of suitable methods for removing those pollutants when presenting in low concentrations. This work reports results on adsorption of sulfate and molybdate ions on metal modified (with barium - Ba and lead - Pb) and organic reagent modified (with Hexadecyl-trimethyl-ammonium bromide - HDTMA) clinoptilolite. Zeolite’s modification with Pb, Ba and HDTMA increases its uptake capacity with respect to Mo(VI) at pH 3, with the uptake capacity decreasing in the order CL-Pb > CL-HDTMA > CL-Ba. Lead-modified clinoptilolite shows high uptake with respect to Mo(VI) in acidic, neutral and slightly alkaline conditions. The presence of SO42- in concentrations twice higher than the amount of Mo(VI) do not interfere with the Mo(VI) removal by CL-Pb. Zeolite’s modification with Ba and Pb renders it able to immobilize SO42- from water in the pH range 3-9. Kinetics of the uptake process is best described by the pseudo-first order kinetic equation. Increasing the initial concentrations of Mo(VI) and SO42- increases the removed amount of pollutants. INTRODUCTION Wastewater from copper-molybdenum ores processing is often polluted by molybdate and sulfate ions. Molybdenum (Mo) migrates easily in water and consequently the Mo polluted areas could extend for hundreds and thousands of meters (Ryzhenko, 2010). Molybdate anion is the only Mo(VI) species in natural water, i.e. at pH > 6.0. Its median freshwater hazardous concentration affecting 5% of the species (HC 5.50%) is 38.2 mg Mo/L (De-Schamphelaere et al., 2010). The marine water chronic toxicity (HC 5.50%) is assessed at 5.74 mg Mo/L (Heijerick et al., 2012). The predicted no-effect concentrations (PNEC) are 12.7 mg Mo/L and 1.92 mg Mo/L correspondingly for freshwater and marine water (Heijerick et al., 2012a). When sulfates present in drinking water in excess of 250 mg/L they cause a cathartic action (especially in children) in the presence of sodium and magnesium, and when the concentration exceeds 600 mg/L, diarrhea. When sulfate-rich effluents are discharged into the environment, they may increase the acidity of water bodies and soils (Guimarães and Leão, 2014). Because of the adverse effects to human health and the environment, limits are set for SO42- concentrations in waters and wastewaters in the range of 250 / 500 mg/L."

Jan 1, 2018

By Prasad Kopparthi, Narasimha Mangadoddy, Balraju Vadlakonda, A. K. Mukhurjee

"Column flotation (CF) is widely using equipment in mineral processing since many years. ERT technique facilitates non-invasive and nonintrusive visualization of different parameters in a column flotation. The hydrodynamic investigation of two-phase and three-phase are studied using electrical resistance tomography (ERT) coupled with pressure transducers in laboratory column flotation. Bubble size distribution, bubble rise velocity and gas and solids hold-up hydrodynamic parameters are extensively used for column flotation design and performance evaluation. The effect of superficial gas velocity, feed flow rate and slurry height in the column on mean gas holdup and its radial distribution has been analyzed for both two-phase and three phase flows. Influence of solid particles on gas hold-up and its complete elucidation of dispersion in the column are assessed. Experimental results show ERT coupled with PT is suitable as an online monitoring tool to provide useful information on the hydrodynamic parameters of the column flotation. The tomography images, which were generated using a modified sensitivity back projection algorithm, were employed to explore the parameter study in two phase flow in column flotation.Furthermore, the results also indicate that ERT is a very powerful tool for diagnosing the `inside' flow behaviour of gas-liquid two-phase and gas–liquid–solid three-phase flow in columns operating for a wide range of flow regimes.INTRODUCTIONColumn flotation is being widely used in mineral processing industries in last few decades. There has been a lot of attention in understanding the various mechanisms that take place during operation. Due to many reasons column flotation has been found to yield better performance than conventional flotation cells, particularly with fine particles (Honaker and Mohanty, 1996). Due to complex flow behavior in nature, the performance of column flotation influenced by on flow characteristics of the process, (Jena et al., 2008). Previously basic research is carried out to evaluate the effect of the hydrodynamic parameters on the performance of column flotation (Finch and Dobby, 1991)."

Jan 1, 2018

By Saveliy F. Kaplan, Valeriy N. Tsyplakov, Vasily N. Kovalev, Igor A. Agapov, Nikolai V. Vorob’ev-Desyatovskii

"Based on the experiments, a possibility of successful processing of double-refractory gold sulphide concentrates with a high content of natural organic carbon, which has a high sorption capacity toward gold chloride complexes, has been demonstrated. The proposed approach involves deep burnout of sorption-active organic carbon in an autoclave at a higher temperature and a longer retention time. INTRODUCTION It is known that one of the reasons why gold-bearing ores and concentrates are refractory is the occurrence of fine gold in sulphides (usually in pyrite and arsenopyrite) in ores and concentrates. In addition, refractory gold-bearing ores and concentrates also contain an organic carbonaceous material, which has a sorption capacity towards gold chloride complex, making the ore or concentrate even more refractory. In pressure oxidation, metallic gold is oxidized by Fe (III) aqua-ions and complex Au(Cl)4- ions are formed at temperatures over 180°C, in the presence of chlorides contained in ores. Complex gold anion is adsorbed on the organic carbon surface and then reduced to Au0; the chloride ion is regenerated and gold, adsorbed on organic carbon microparticles, is ultimately transferred to tailings (preg-robbing). Currently, there are several suggestions how to suppress preg-robbing (Simmons, 1998, Pyke, 1999, Rees, van Deventer, 2000, Zhao Jun-wei, 2008). It can be done by reducing the organic carbon content by processing (flotation, etc.),reducing chloride ion concentration by preliminary washing of concentrates in thickeners, reducing the adsorption capacity of organic carbonaceous material by introducing some organic substances that are strongly adsorbed on its surface (blanking agents), and reducing the redox potential of the slurry liquids by introducing neutralizing agents (limestone)."

Jan 1, 2018

By Toru Yamasaki

A concept of plate-tectonic controls for the formation of seafloor massive sulfide (SMS) deposits in back-arc settings was established by Franklin et al. (2005). According to Franklin et al. (2005), a consequence of extension and rifting is subsidence, thinning of the crust, and the rise of hot, athenospheric mantle into the base of the crust. Underplating of the crust by mafic magmas results in low-pressure partial melting of the hydrated crust at a <15-km depth, and the generation of felsic anhydrous melts. The rapid ascent of hot felsic melts, along with mantle-derived mafic melts, results in bimodal volcanism that characterizes rift and volcanogenic massive sulfide deposits (VMS) environments. The rapid and focused advection of the magmatic heat within the rift to the near-surface environment which are required to sustain vigorous long-lived VMS hydrothermal systems. Faults within rift environments may also allow seawater to penetrate into subvolcanic intrusions and mix with magmatically generated metalliferous fluid or allow a direct magmatic contribution from shallow crustal level (3–12 km) magma chambers (Franklin et al., 2005, and references therein). In addition, the caldera-forming processes are favorable for the formation of VMS deposits and the focused high heat flow and cross- stratal structural permeability that is restricted in time and space to caldera development provides an explanation for the clustering of VMS deposits and their restriction to specific time-stratigraphic intervals and structures in the evolution of submarine central volcanic complexes (Franklin et al., 2005, and references therein). The concept is persuasive, although it is based on a series of logically constructed reviews mainly focused on ancient on-land deposits.

Jan 1, 2018

By E. Emelyanenko, P. Solozhenkin, J. Yagudina, O. Ibragimova

"To recover tetrahedrite-tennantite series minerals from porphyry copper-pyrite ores by the froth flotation method, further research on thiol collectors is launched to promote the utilization efficiency of copper ores. In the present paper the adsorption mechanism of the collectors on tennantite surface has been investigated by computational modeling and FTIR-spectroscopic analysis, which have revealed that the decrease in prognosis of collector activity evaluation (PCAE) for tennantite is in the following order: BX (-0.34318), AEROPHINE 3418A (- 0.61756), AERO 5100 (-14.18857). The lower PCAE the stronger the ability of the collector to interact with the mineral surface of tennantite and form the stable complex. More kinetic reliable conditions to form suitable adsorption layer and rupture of the liquid interlayer with AERO 5100 have been observed by FTIR spectra due to decrease of the intensity and stretching and bending vibrations of water (less than 20 and 65%, respectively). In order to verify the feasibility of AERO 5100 as a collector the industrial flotation tests have been conducted. Flotation performance has improved significantly with the stadially grinding and preflotation of tennantite in intercycle copper flotation that allows to avoid desliming of the fragile mineral and minimize loss of Cu and As in tailings. The recovery of copper in copper concentrate increases by 3.9% with the grade maintained.INTRODUCTIONCopper is one of the first metals extracted and the main material of choice for different high-technology applications today. Currently 80% of the world's copper comes from copper sulfide ores. However, due to the depletion of high-grade copper ores in the world and constantly growing demand for copper, the need to develop processes and technologies to treat copper resources from additional sources such as mine tailings, low grade deposits, industrial wastes and deposits with high impurity levels such as As and Sb will continue to increase (Miller and Craig, 1983). The beneficiation processes of copper-pyrite ores consisting of tennantite-tetrahedrite series minerals are generally complex. Tetrahedrite-tennantite minerals occur as fine anhedral grains intermixed with grains of galena, sphalerite, chalcopyrite, pyrite and other sulfides (Saharova, 1966). The mineralized zones of Southern Urals, Russia deposits correspond with these ore types but tennantite-tetrahedrite series are more abundant in ores at the Uzelginskoye deposit, some samples of which contain 70% of copper in tennantite form (Seravkin et al., 1994). This deposit differs from other similar copper-pyrite ores by thin mutual ""germinating"" minerals and higher content of arsenic (up to 0.8-1 %) which create additional considerable problems in enrichment (Solozhenkin et al., 2016)."

Jan 1, 2018

By Alexander V. Epiforov, Stanislav V. Balikov

This paper describes of processing tests of 8 flotation concentrates containing precious and base metals by pressure oxidation (POX) method. Concentrates 1 and 2 were gold-copper concentrates. Zinc and silver were by-products in these concentrates. These concentrates were processed by POX with following cyanidation of POX solid residues, copper solvent extraction and zinc carbonate precipitation. The recoveries of gold, copper, silver and zinc from these concentrate were 98, 99, 30 and 99%, respectively. Concentrates 3 and 4 were lead-zinc concentrates. Silver was by-product in concentrate 3. Gold, silver and copper were by-products in concentrate 4. Concentrate 3 was processed by POX with following reduction smelting of POX cakes for primary lead recovery and zinc carbonate precipitation from POX solution. The recoveries of lead and silver into ingot were 96 and 98%, respectively. The recovery of zinc was 99%. Concentrate 4 was processed by POX with following zinc carbonate precipitation and reduction smelting of POX cakes. Copper was precipitated from the POX solution using sodium sulphide prior zinc precipitation. The recovery of zinc into carbonate concentrate was 99%. The recoveries of lead, gold and silver into lead bullion were 95, 99 and 98% respectively. The recovery of copper into sulphide concentrate was 99%. Concentrate 5 was gold-pyrite concentrate, and concentrates 6-8 were double refractory gold-arsenopyrite concentrates. Silver was by-product in these concentrates. These concentrates processed by POX and CIL. The recovery of gold from concentrate 5 was 98%, and from concentrates 6-8 was 85-90. Low gold recovery from concentrates 6-8 was associated with preg-robbing factor. The recovery of silver from gold-sulphide concentrates did not exceed 10-20%. The low silver recovery was associated with argentojarosite formation that is resistant to cyanidation. The flowsheets for complex processing of precious and base metals sulphide flotation concentrates based on this test work results were proposed.

Jan 1, 2018