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By Sheng Dai, Yuan Lee, Haiming Xiao, J. P. Young

"There are numerous analytical applications of scatter-emission and/or absorption spectroscopy applied to liquids and solids in the temperature range of 0 to 350°C. In this paper an all-silica fiberoptic probe is described which is useful for spectral analyses from 0 to 1600 K and can be used in harsh chemical environments. The probe has been used for Raman spectral analyses of many molten salt and solid material systems to 1000°C. It has applications for such studies at higher temperature ranges. The instrumentation required along with the demonstrated and proposed applications of the all-silica probe are presented and discussed.IntroductionThere are many kinds of scatter-emission spectroscopies that are of value for analytical measurements. Fluorescence, reflectance, arc or spark emission are descriptors for some of these. Raman scatter spectroscopy is also quite a useful technique for analytical measurements.In Figure 1, we give a simplified explanation of the Raman effect. If one shines monochromatic light into a sample, light may be absorbed, exciting the sample to some virtual state. We know from experience that almost all of the light is re-emitted in the same wavelength range. This is called Rayleigh or Mei scattering and is designated in the figure by the arrows in both examples that point up and down from the same lower energy state. A very small percentage (the order of 10-4%) of the monochromatic light is re-emitted leaving the sample at a vibrationally-excited state. Thus, this light is at a distinctly lower energy compared to the exciting radiation. This is called a Stokes shift and is represented in the left-hand example by an arrow descending to a more energetic vibrational state. If the sample is not at a temperature of absolute zero, some of this vibrationally excited state will be thermally populated. That portion of the sample still absorbs and re-emits exciting radiation as Rayleigh scattered light, but a small percentage of the exciting light is re-emitted as the sample relaxes to the lower vibrational state. The energy of this light is of higher energy and is called an anti-Stokes shift, depicted in the example to the right. Notice that the energy separation of the Stokes or anti-Stokes shifted emission from that of the exciting radiation is the same, and expressed in ~cm-I. The intensity of either shifted emission is a function of the population of the vibrational energy states; therefore, the ratio of the intensity of Stokes to anti-Stokes signal varies with absolute temperature. We will come back to this point later."

Jan 1, 1997

By Yongzhong Xiao, Tiejun Chun, Jian Pan, Deqing Zhu

"An innovative process of reverse floatation-direct reduction-low intensity magnetic separation was developed to effectively beneficiate the superfine run-of-mine (ROM) ore mined from Hunan Province, China. Mineralogy was measured that the ROM ore is of superfine low grade hematite ore type, assaying 27.2wt%Fetotal and with main valuable minerals of hematite occurring at size between 3 to 5µm. The upgrading results show that the final iron concentrate, assaying 88.3wt%Fe total and 94.5% metallization degree was obtained at an overall iron recovery of 69.9% under the following conditions: rough concentration by grinding of ROM up to 88.7% passing 0.074 mm and reverse flotation at pH=9.4, 100 g/t starch and 200 g/t dodecylamine (DDA), and coal reducing the rough concentrate pellets containing 12% calcium containing complex additive at 1200 oC for 120 min, and finally magnetic separation of the reduced pellets by grinding up to 89.2% passing 0.043 mm at 0.08 T field intensity.IntroductionWith the rapid development of iron and steel industry in China, there has been a soaring demand for iron ores in the past decade. The imports of iron ores have increased from 148 million ton in 2003 to 628 million ton in 2009 [1]. Iron making industries increasingly demand for high grade raw materials to improve product quality and reduce operation cost. However, availability of high grade natural ores is limited and enrichment of lower grade ores is necessary to meet the demand. Therefore, large quantities of superfine low grade iron resources are necessary to utilize in China at the moment."

Jan 1, 2011

By T. Mutoh

Tellurium in raw slime has recently been recovered as copper telluride in Onahama Smelter & Refinery. The slime is decopperized with sulfuric acid solution in conventional leaching tanks. The pregnant leach solution containing 45 g/l of copper and 1 g/l of tellurium is introduced to a copper telluride recovering reactor. The tail solution from the reactor containing less than 20 mg/l of tellurium is recycled directly to circulation tanks of copper electrolysis. The impurities of the product copper telluride is kept below 1% without any purification.

Jan 1, 1990

By Wei-Tong Du, Yu Wang, Gang Wen

Carbon dioxide (CO2), a major component of the greenhouse gases, could be comprehensive utilized as a valuable resource to oxidize vanadium during the converter vanadium extraction process. The thermodynamic software, FactSage, was utilized to study the oxidation ability and theoretical cooling ability of using weak oxidant CO2 as coolant in vanadium-containing hot metal. Besides, experimental research on vanadium extraction in CO2 and O2 mixed blowing extracting process had been undertaken. The results indicated that the elements C, Si, V, Mn etc. could be oxidized by weak oxidant CO2, and the content of V2O3 in slag was approached to pure O2 blowing. Furthermore, CO2 had a remarkable cooling ability and the molten bath temperature kept on decreasing as CO2 blowing rate increases. This research has proved that CO2 and O2 mixed blowing in vanadium extraction process are effective.

Jan 1, 2015

By Tom Lewis

This report discusses the evaluation of the ENVIRO-CLEAN PROCESS, a technology developed by Lewis Environmental Services, Inc. for the recovery of metals such as chromium, mercury, copper, cadmium, lead, and zinc from surface and groundwater streams. This new heavy metal removal process (patent-pending) utilizes granular activated carbon with a proprietary conditioning pretreatment to enhance heavy metal adsorption combined with electrolytic metal recovery to produce a saleable metallic product. The process generates no sludge or hazardous waste and the effluent meets EPA limits. A 50 gpm system was installed for recovering hexavalent chromium from a ground water stream at a site located in Fresno, California. The effluent from the activated carbon system was reinjected into the ground water table with the hexavalent chromium concentration < 10 ppb. The system simultaniously removed trichloroethylene (TCE) to concentrations levels < 0.5 ppb. The activated carbon is regenerated off-site and the chromium electrolytically recovered. The full scale system has treated over 5 million gallons of ground water since installation.

Jan 1, 1996

By Xiaobing Yang, Abhishek Lahiri, Animesh Jha

"In the FFC-Cambridge process, the cathodic dissociation of oxide and CO/CO2 production on carbon anode is the basis for metal production in a CaCl2 bath. By using an inert intermetallic anode, the CO2 evolution can be eliminated altogether with acceleration in the electro-reduction kinetics. At present the process suffers from slow reduction kinetics of TiO2 to Ti metal, which can be enhanced significantly by the incorporation of alkali species in the TiO2 pellet at the cathode and in the CaCl2 bath in the presence of an intermetallic inert anode. Nearly full metallization with greater than 99% of Ti metal containing 1500 ppm of oxygen is possible to achieve in less than 16 hours of electro-reduction. Analyses of phase composition and the microstructures morphology in fully metallized pellets revealed the presence of localized solidified Ti layer, indicating that fast reduction process also involved formation of liquid phase as middle stage reaction. In addition, in situ creation of porosity and maintain higher current level during electrolysis process were two key factors to fully reduction of TiO2.IntroductionDuring cathodic dissociation of TiO2 in a CaCl2 bath and anodic evolution of CO2 on a carbon anode, which is the basis for the FFC Cambridge process [1], the rate of metallization slows down due to the formation of CaTiO3 at the reaction interface. Calcium and alkaline earth perovskites are known for their poor electrical conductivity which adversely affects the overall electro-reduction. One of the ways to increase the porosity is via the addition of polyethylene precursors in the pellet or by directly starting from perovskite [2, 3]. The experimental evidences shown in the literature confirm although the speed of reaction increases, but a complete or near complete metallization is not possible by enhancing the in-situ porosity alone, as the insulating perovskite is very slow to decompose under the equilibrium that prevails in the cell. Plethoric evidences on carbon anode show with the current decrease gradually, and finally stabilize at a very low value between 0.2 and 0.4 A, which is a testimony of the presence of perovskite insulating barrier in the current path. Our aim in this paper is to demonstrate the mechanism of enhanced electro-reduction when alkali ions are present in the oxide pellet at cathode and in the bath. We also show for the first time the use of an intermetallic anode for Ti-metal production using the FFC Cambridge process."

Jan 1, 2009

By Xuefeng She, Qingguo Xue, Jingsong Wang, Guang Wang

Iron nugget could be got at high temperature using carbon composite pellet, which were made by the mixture of ludwigite and reducing agent. In order to reduce sulfur content in the nugget, effects of additives on the desulfurization was investigated. The sulfur content could be dramatically reduced if the CaO was introduced into the pellet and the sulfur content was as low as 0.046wt.% when the addition amount of CaO was 5wt.%. However, the melting separation of pellet became increasingly difficult and the yield of iron decreased when CaO content in the pellet gradually increased. Na2CO3 could also reduce the sulfur content in the iron nugget and made the iron and slag separate difficultly as well. When 6wt.% Na2CO3 was added into the pellet, the pellet was too difficult to melt separation and the sulfur content in the nugget was 0.084wt.%, which didn’t meet the need of steel making.

Jan 1, 2015

By Marcio Toshio Tanaka, Marcelo Breda Mourao, Cyro Takano, Cesar Yuji Narita

"The concerns in questions related to the environmental impact in the steelmaking industries caused mainly on the gas emissions such as the dioxide carbon are due to its raw material such as the coal, a fossil and non renewable resource. The purpose of this paper is to replace from 10% to 50% of the coal used in cokemaking by mixing it with a renewable source (wood charcoal). The powder (- 325 mesh) from both raw materials (coal and wood charcoal) were mixed in order to obtain a briquette that was then heat treated at 1100°C to obtain the biocoke. Results of usual analysis (coke reactivity index, coke strength after reaction and cold crushing strength test) were employed to compare to regular coke briquettes. It was found that biocoke with different amounts of wood charcoal present features enabling it to be used in some ore reductionprocesses.1. IntroductionThe iron and steelmaking industry is a heavy emitter of carbon dioxide; according to the World Steel Association, 6.5% of global emissions of this greenhouse gas is due to the production of ferrous materials [ 1]. This is due to the fact that the fuel and reductant employed in the blast furnace is metallurgical coke, obtained from fossil coal. There are some projects aiming to reduce or even eliminate the emission of fossil GHG in the iron and steelmaking process [2]. Most of them propose the capture and storage of the gas (CCS) [3], a technology not yet proven. Other studies point out that the coke consumption in the blast furnace could be reduced by using high reactivity coke; this could lead to lower temperatures in the thermal reserve zone of the blast furnace and consequently less fuel rate in the furnace.The use of biomass in the iron ore reduction process is known as an environmentally accepted solution, as biomass does not release already fossilized carbon."

Jan 1, 2013

By Alwin Frei, Aldo Steinfeld, Peter G. Loutzenhiser, Enrico Guglielmini

"Using concentrated solar radiation as the energy source of high-temperature process heat, the carbothermal reductions of Al2O3 to Al and SiO2 to Si were examined thermodynamically and demonstrated experimentally at vacuum pressures. Reducing the system pressure favors Al(g) and Si(g) formation, enabling their vacuum distillation and avoiding contamination by carbides and/or oxycarbides. Exploratory experimentation in a solar reactor was performed with mixtures of charcoal with alumina and silica in the ranges of 1300-2000 K and 1997–2263 K, respectively, at 10-3 bar by direct exposure to concentrated thermal radiation. Distilled samples contained up to 19 wt% of Al in Al-Al2O3 mixtures and 79 wt% of Si in Si-SiO2 mixtures. When the reducing agent is derived from a biomass source, the solar-driven carbothermal processes are CO2 neutral.IntroductionMetallurgical extractive processes for producing Al1-2 from Al2O3 and Si3-6 from SiO2 are characterized by their high specific energy consumption and concomitant emissions. Alternatively, concentrated solar energy can be used as a high-temperature heat source to drive the carbothermal reductions and, thus, avoid greenhouse gas emissions and other pollutants derived from fossil-fuel-based processes7-12. When the reducing agent is biomass charcoal, the solar-driven carbothermal reduction is CO2 neutral. The carbothermal reductions of Al2O3 and SiO2 are represented by the simplified overall stoichiometric reactions:"

Jan 1, 2011

By Anne Kvithydl

Printed circuited boards contain considerable quantities of valuable metal, while also containing many environmental pollutants making them unsuitable for landfill. In this study the decomposition of common plastics used in printed circuit boards were studied. Polytetrafluoroethylene (PTFE), polyvinyl chloride (PVC) and polyethylene (PE) were heated in both CO, and argon atmospheres using a thermo-gravimetric furnace (TG) coupled to a mass spectrometer (MS). Soda ash Na,C03 and baking soda NaHC03 were used as reactants. The degradation temperatures and evolved gases are presented for single plastics and mixtures. Mixed plastics are shown to behave as a sum of the individual plastics. The mass loss temperature is the same in CO, and argon. However, less residue is formed when heated in CO,.

Jan 1, 2008

By Cheng Pan, Qiugang Yuan, Xuewei Lv, Mei Liu, Enguang Guo

Land-based nickel resources include nickel sulfide and nickel laterite. With the consumption of high grade nickel sulfide, use of nickel laterite has received more and more attention. The mineralogy and sintering behavior of limonitic nickel laterite with high iron and low nickel and silica was studied to offer technical support for producing ferronickel through sintering–blast furnace route. The mineralogy results showed that the main phases in this kind of nickel laterite are goethite (FeO(OH)), gibbsite (Al(OH)3) and NiFe2O4. The TGA (Thermogravimetric Analysis) and DSC (Differential Scanning Calorimetry) revealed hydroxide minerals in addition to absorbed water. After the sintering experiments the chemical composition, phases present (XRD analysis) and physical properties of the sinter were studied. The content of FeO in the sinter increased with increasing basicity up to 1.3, and then decreased with further increase in basicity. The yield of sinter increased (from 73% to 80%) with increase in the basicity from 1.1 to 1.7, and then the yield decreased with the further increase in basicity. Mg(Ni)(Fe,Al)2O4 is the main phase in the sinter while MgCaSiO4 and Fe2SiO4 is the main binder phase when the basicity is 1.1~1.5, and MgCaSiO4, Fe2SiO4 and SFCA is the main binder phase when the basicity is 1.7~2.1.

Jan 1, 2014

By Peter V. Barr

Despite the advent of modem firing control systems reheating furnace operations frequently allow significant thermal excursions in the discharged slabs or billets after furnace delays. Although HSM furnaces are not immune to this and other related problems, mini-mill operations are most vulnerable due to their more frequent delays and (often) less sophisticated control systems. In order to reduce these problems control systems will commonly include a thermal model, operating either on-line (interacting directly with the controller logic) or in an advisory, off-line mode. Using a new &apos;fast&apos; thermal model, the paper examines the thermal response of a typical mini-mill furnace during both delays and the subsequent recovery period. A variety of firing strategies are explored and compared on the basis of maintaining thermal excursions within allowable limits for rolling. Other factors, such as the potential for overheating of billets within the furnace during delays and the overall thermal state of the furnace, are also considered in some detail. Although common practice, the use of conventional thermocouple zone temperatures for furnace control during and after delays is shown to be a dubious proposition. Keywords: Reheat Furnace, Modeling, Process Control

Jan 1, 2003

Studies of electric pulse (EP) disintegration were conducted on ores of disseminated precious minerals, &apos;on platinum-bearing chromitites of the Konder Complex, Russia, on diamond-bearing impactites of the Popigai meteoritic crater, Russia, and on and diamond-bearing metamorphic rocks of Northern Kazakhstan. It was shown that EP disintegration ~s a technology that achieves ideal liberation of disseminated minerals, and is a new efficient method to study accessory minerals.

Jan 1, 1991

By H. Castillo

This paper describes the computer simulation of thermal stress fields generated in the quenching of the ns 415 H Steel automotive parts (Valve Lifters), running the ANSYS Multiphysics software of finite element (FEM). Simulation was performed introducing residual stress measurements on specific values areas, like internal pressure condition in the material. The stress condition effect in the material and the properties as temperature function data, were introduced to the FEM software. The thermal stress simulation was made on the 2D system. The parts were austenized to 850 900 °C and then oil quenched, tempered at 150 -200°C, and air cooled. The X-Ray diffraction technique was made to take measurements from residual stresses on valve lifters surfaces. The results analysis showed the ideal stress condition necessary in raw material to reduce the scrap percent in grind operations after hardening heat treating process. Keywords: Thermal Stresses, Temperature profile, Computer Simulation, Finite element analysis, Quenching of steel, Residual Stresses

Jan 1, 2003

By Gordon Irons, Kevin Graham, Krishnakumar Krishnapisharody

Ladle or secondary metallurgy in steelmaking is an essential process step for the production of high-quality steel. Professor David Robertson was a pioneer in the modeling of these processes, in particular gas-metal fluid dynamic interactions and the rates of slag-metal reactions. This is now a highly active area of research, and some of the recent developments in this area will be reviewed.

Jan 1, 2014

By Li Kaihua, Li Liang, Miao Qingdong, Wang Cong

The current process of production of titanium sponge involves the use of TiCl4 as a feed material and a huge amount of heat is generated during the magnesiothermic reduction process. For this reason, it is possible to agglomerate into a titanium lump with the partial high temperature. And, it is difficult to obtain soft titanium sponge with low content of impurities. In order to solve the current problems in the titanium sponge production process, process optimization experiments study of TiCl4 feeding speed, vacuum distillation temperature, system pressure and time control had been conducted for obtain high quality titanium sponge. Experimental results show that lower feeding speed can improve the output capacity of titanium sponge and softer products can be obtained. The product grade rate of titanium sponge improved significantly.

Jan 1, 2015

By Raymond M. Coveney

Bedded sulfide ores in Cambrian Chinese black shales typically contains at least 2% Ni, 4.5% Mo, 1% As and 0.2% Se. Thin laminae and replaced on colites from the ore contain intimate mixtures of fine-grained Ni-rich sulfides and jordisite complicating ore treatment. The ores contain abundant jordisite, vaesite, nickelian pyrite, and barite and lesser amounts of sphalerite, gersdorffite, millerite, tennantite, fluorite, chalcopyrite, and HgSe (probably tiemannite). At present only ores that are sufficiently rich (>4.5% Mo) for direct roasting are mined and treated to produce, ammonium molybdate. The ores contain Pt, Pd, and Au in amounts totaling up to -2.5 ppm, but these are not recovered.

Jan 1, 1993

By Rubén J. Sánchez Rodriguez, Carlos M. Fontes Vieira, Carlos E. Gomes Ribeiro

Ornamental compound stone are produced by industry for decades, however, few published studies describe these materials. Brazil has many deposits of stone wastes and a big potential to produce these materials. This work aims to evaluate the chemical resistance of ornamental compound stones produced with marble waste and unsaturated polyester. An adaptation of Annex H of ABNT NBR 13818:97 standard, with reagents commonly used in household products, was used. The results were compared with those obtained for natural stone used in composite production.

Jan 1, 2015

By Susumu Okabe

Injection metallurgy is widely adopted in various fields of metallurgical operations to achieve high productivity. The Mitsubishi Continuous Copper Smelting and Converting Process employs the top blown lance technique for the continuous supply of solid charges and reaction gases into the molten bath, where the agitated bath contributes to enhance the heat and mass transfer and the increased gas/liquid interface area accelerates the reaction. However, excessive splashing of the molten materials accompanied by the injection may cause an unexpected wear of the furnace lining. In order to estimate the splashing rate quantitatively, and to optimize the furnace design and the blowing condition, a physical model study of the top blown gas injection onto the liquid bath was carried out. An equation of the splashing rate was obtained as the function of cavity size, gas velocity and bath properties.

Jan 1, 1995

By A. Rojo, N. J. Ramirez, J. E. Salgado

"This work aims to characterize the plastics used in a handgrip located in the car interior body in order to improve its design process and be able to predict its behavior when the part is subjected to impact test involving human casualties.Through stress analyses at high speeds and a video camera set up (front and side view), the reduction of area of specimen was obtained from image analysis, allowing to get the stress-strain real curve of the material.Continuing the characterization process a set of impact test was developed, where standard lzod configurations were used in unnotched specimens. From these tests were gotten displacement curves and absorption energy estimations.The proposed testing procedure allowed the acquisition of force and displacement data through time at various strain rates which are indispensable for the characterization of dynamic events. Using a specimen with a special configuration has shown a more detailed dynamic behavior resulting into more accurate numerical analyses within the design process.IntroductionIn the design process, one of the many analyses which take place is the impact test of the designed part. Nowadays there are many software capable to do these kind of analysis and each industry use the one they think it is convenient for them, but also the selected software has mathematic models that help to find the solution and the simulation of the case of analysis. These are not the only considerations that a company has to take into account, other one is the type of information and data necessary to feed the software. For this study we are going to focus on the acquisition of these data.The mail reason of this work is that generally the supplier gives the card of the material with all the characteristics and information requested by the buyer, but all of that information is acquired by standard methods, but it is inconvenient when the materials are polymers."

Jan 1, 2011