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By K. H. Zhang, Y. P. Gao, J. Q. Zhao, Q. Li, J. C. Ma

Compared with sinusoidal oscillation, non-sinusoidal oscillation enhances the ability to control waveform and meets different oscillation requirements by adding an independent parameter, which is the key technology for high-efficiency continuous casting. A new waveform of mould non-sinusoidal oscillation is proposed in this paper, that is, a velocity waveform that is composed only of straight lines and parabolas, which not only has good dynamic characteristics, but also further enhances the feature of non-sinusoidal oscillation. Compared with sinusoidal oscillation, the negative strip time is reduced by 15.9%, the maximum negative strip velocity difference is increased by 38.3%, and the maximum positive strip velocity difference is decreased by 27.8%. The formulas of oscillation process parameters can be clearly deduced, and the isoplethic curves of oscillation process parameters when multi-parameter simultaneously changes are drawn. The negative strip time decreases as the modification ratio, frequency, and casting speed increase, but increases as stroke increases. In order to maintain the stability of negative strip time, an oscillation synchronous control model for optimising oscillation basic parameters was developed. Through practical application, the mean oscillation mark depths decreased by 10.1 μm and the flux consumption is increased from 0.37 kg/t to 0.45 kg/t in the non-sinusoidal oscillation model, which meets the requirements of normal production.

Oct 24, 2025

By A. Becker, R. Tait, S. L. George, A. Carlisle

Surface treatments like laser shock peening (LSP) induce residual stresses penetrating up to 1 mm deep, surpassing traditional methods, thus significantly increasing the potential impact on materials prevalent in the automotive and aerospace sectors. Through extensive fatigue testing and fractography investigations, it was determined that LSP resulted in a fatigue life increase of over five times for aluminium alloy AA7075-T6 and titanium Ti-6Al-4V. Increased fatigue life was also noted in AISI316 stainless steel, which showed increases in fatigue life of 1.7x. While fatigue life in all cases improved, the efficacy of LSP was shown to be material dependent.

Jul 23, 2025

By B. Kweto, W. Legodi, C. van Buuren, R. F. Sandenbergh

Biooxidation, and especially the BIOX® process, is a viable, economical and environmentally attractive process to liberate gold hosted in refractory sulfides by oxidatively leaching the sulfides as soluble sulfates. The moderate to high cyanide consumption during the subsequent cyanidiation of the washed biooxidation residue is probably caused by the retention on the solids of labile sulfur species formed during the multi-electron oxidation process of sulfide to sulfate. In this work the nature and mode of transport of the cyanicides in the products from the mesophile BIOX® process, as well as that of the combined mesophile and thermophile bioxidation process, were considered and strategies to reduce cyanide consumption evaluated. It was found that labile sulfur species were the major cyanide consumers in the mesophile biooxidation product, forming predominantly thiocyanate during cyanidation. The transfer of labile sulfur species was only marginally decreased by more intensive and thorough washing of the biooxidation products with warm and hot water, intense stirring and warm caustic leaching. A major reduction in cyanide consumption was however achieved by using a combined mesophile and thermophile biooxidation process. Keywords: Biooxidation, refractory sulfide gold ores, cyanide consumption

Jan 1, 2020

By A. F. Lee

Dr E. C. Hanekom (Visitor): Two years ago we used the bubble pick-up technique as developed at Anglo American Corporation for screening candidate flotation agents prepared in our laboratories. It was obviously necessary to know to what extent the technique gave reproducible results and a statistical evaluation of the test method was made using a mineral sample provided by Anglo American Corporation. A bubble of 2.0 mm diameter was used and the measuring graticule was divided into squares (units) with sides of 5.0 mm at 25 X magnification. The mineral granules had diameters from 53 to 74 mm. The bubble was loaded by depressing it against a layer of mineral grains to give an arbitrary but constant compression of 0.4-0.5 mm. It was rolled five times through 2 mm horizontal displacement. The bubble was then lifted, its load compacted by gently stirring and the projected area measured in squares (units) on the grid. Each substance was tested at 5 ppm concentration in distilled water at five points in the pH range 3-6. With these standardized conditions of operation the reproducibility of the test was studied. Four materials were tested and at each pH value the procedure of forming a bubble, picking up granules and counting the units was repeated ten times. From these results the standard deviation for a single count at any pH value was calculated for each material (Table 1. The coefficient of variation of approximately 3 per cent was relatively low and it was decided that further refinements in the counting procedure would be of doubtful benefit with the present apparatus. Similar experiments were carried out with 12 sample materials. In this case the bubble formation and pick-up were repeated four times at each pH value, the mean value was calculated for each set of four observations and final pick-up values for the materials were obtained by selecting the highest mean count. Each test was completely repeated a number of times as indicated in Table 2 and the standard deviation calculated. The results allowed the selection of the more promising materials and the rejection of poor performers at the 95 per cent confidence level. All tests were carried out by one operator. Some evidence was obtained that the method is sensitive to operator bias. In conclusion it can be said that from all the results analyzed it would appear that once operation conditions are fixed (viz operator, pH control) the precision of the method is adequate. The author wishes to thank Messrs African Explosives and Chemical Industries Limited for permission to publish these data. G. S. Stander and C. J. Kooij (Visitors): We must congratulate Mr Lee for this most interesting and useful development of the pick-up experimental method. It certainly provides research workers with an instrument which makes flotation more of a science and less of an art. We visited Mr Lee at his laboratory where he gave us a demonstration of the bubble pick-up instrument and technique as developed and improved by him.

Jan 12, 1969

By H. Vuthaluru, O. Kavianipour, C. -Z. Li, N. Suresh, D. Sahu

The paper describes a CFD model developed for 76mm Dense Medium Cyclone (DMC) using Ansys Fluent Software to gain insights into the separation of particles according to their size and density. The simulation used in this paper includes the Reynolds stress model to predict the turbulence inside the cyclone body. An Eulerian-Eulerian multiphase CFD model was applied to model a number of physical aspects such as the separation of coal particles and the segregation of magnetite media solids. The experimental results generated in a laboratory scale DMC were used for the validation purpose and the predicted results of CFD have been validated for the flow splits of water, magnetite and coal. The simulation results obtained from the Eulerian-Eulerian multiphase model revealed that the prediction agreed with experimental results, and matched reasonably well in terms of the mass flow rates of water, magnetite and coal. Furthermore, the partition curve of the DMC when mapped for the separation of - 3.0+0.50 mm size also showed to be in agreement with the experimentally obtained curves. The gravity of cut (SG50), also predicted by the Eulerian-Eulerain multiphase CFD model, was found to be in the vicinity of observed experimental value of SG50. Keywords: Dense medium cyclone, Eulerian-Eulerain multi-phase modelling, computational fluid dynamics, cut gravity (SG50)

Jan 1, 2020

By M. D. G. Salamon

If a transition from one equilibrium state to another occurs during the course of mining, energy transfer takes place in the rock mass, which is assumed to be an elastic continuum. The energy components are defined as follows: the work done by external and body forces, W; the increase in stored energy in the mass, Uc; the strain energy in the rock mined during the transition, Urn; the work done on mine support or backfill, Ws; and the released energy, Wr. The energy balance is defined as (W + Urn) - (Uc + Ws) = Wr> 0, where the first set of components in parentheses represents the sources of energy, while that of the second corresponds to the known modes of energy expenditure and the component on the right is the unaccounted-for energy surplus, which must be released and dissipated in some form. The inequality Wr ~ Urn> 0 applies. Expressions for the energy components are derived first for the general case and then for the 'slit' modal used to simulate tabular excavations. Through specific examples, the importance of the progressive nature of mining is emphasized. The size of the steps used to enlarge the excavations appears to play a significant role in the mode of energy transfer. This observation forms the basis of the second paper in this series of two papers.

Jan 1, 1984

By Z. Hou

ABSTRACT: Short-term strength, damage and healing boundaries for rock salt are experimentally determined and integrated into the Hou/Lux-MDS damage-healing model. This model can be used to describe the mechanical behaviour of rock salt during a damaging process (under high stress to strength ratios) as well as during a healing process (under very low stress to strength ratios with high confining pressure). The development of the damage and the stress to strength ratio in the excavation damaged zone (EDZ) of a storage cavern under a minimum internal pressure as well as the development of the healing of damage and the stress to strength ratio under a subsequent maximum internal pressure are investigated project-related. The results of the investigation make it possible to shift the permissible minimum pressure boundary down, allowing the optimisation of decisive economic characteristics of storage caverns. RÉSUMÉ: Le comportement court terme, l’endommagement et les conditions de colmatage pour le sel gemme ont été étudiés expérimentalement et intégrés dans le model endommagement-colmatage Hou/Lux-MDS. Ce modèle permet de décrire le comportement mécanique de sel gemme pendant le processus d’endommagement (sous fort rapport contrainte-résistance) et le comportement du processus de colmatage sous très faible rapport contrainte-résistance avec forte pression de confinement. Le développement d’endommagement et le rapport de contrainte-résistance dans une zone d’endommagée (EDZ) d’une cavité de stockage avec un maximum de pression de soutènement ont été étudiés. Les résultats de cette étude permettent de conclure qu’il est possible de baisser la pression de soutènement, et par conséquent d’optimiser les caractéristiques économiques décisives des cavité de stockage. ZUSAMENFASSUNG: Für Steinsalz werden Festigkeits-, Schädigungs- und Verheilungsgrenze experimentell ermittelt und in das Schädigungs-Verheilungs-Modell Hou/Lux-MDS integriert. Damit kann das mechanische Verhalten von Steinsalz sowohl bei einem Schädigungsprozess (mit hohen Ausnutzungsgraden) wie auch bei einem Verheilungsprozess (mit niedrigen Ausnutzungsgraden) beschrieben werden. Projektbezogen werden die Schädigungs- und Ausnutzungsgradentwicklung in der Auflockerungszone einer Speicherkaverne unter einem minimalen Innendruck sowie die Verheilungs- und Ausnutzungsgradentwicklung unter einem anschließenden maximalen Innendruck untersucht. Die Untersuchungsergebnisse erlauben, die zulässige Minimaldruckgrenze nach unten zu verschieben, so dass entscheidende wirtschaftliche Kenngrößen von Speicherkavernen optimiert werden können.

Jan 1, 2003

By B. P. Watson

Uniaxial tests performed on core from instrumented sites at Amandelbult 1 shaft, Impala 10 shaft and Union Section Spud shaft showed a nonlinear elastic relationship between applied load and induced deformation. This nonlinear behaviour does not appear to be dependent on borehole orientation but in the case of the Amandelbult and Union sites appears to have been influenced by the stress condition of the rock mass at the time of drilling. Cores drilled at these two sites under destressed conditions, such as over a stope, showed a linear elastic response to the applied load whereas most of the cores drilled under relatively high radial stresses were nonlinear. The Impala 10 shaft tests, however, all showed strong nonlinear behaviour irrespective of the stress condition of the rock mass at the time of drilling, although high stress conditions may have influenced the severity of the nonlinearity. A comparison between underground stress change measurements and an elastic model indicated that the rock mass became nonlinear when the virgin stress condition was relaxed to about 10 MPa. The cores for laboratory testing were retrieved from vertical boreholes drilled up from the centre of a stope and from horizontal boreholes drilled over pillars and stopes at about 600 m, 1 100 m and 1 400 m below surface for the three sites respectively. The k-ratios under virgin conditions were estimated from sockets, modelling and stress measurements to be 1.0, 1.3, and 0.5 for the Amandelbult, Impala and Union sites respectively. Of the three sites, therefore, Impala 10 shaft appears to have had the highest virgin stress state. Tests performed on similar rocks from shallower depths at Impala Platinum essentially showed a linear relationship between stress and strain. From the small Impala Platinum rock test database available to the project, it appears that the nonlinear elastic behaviour initiates at this mine from about 1 000 m below surface and seems to become progressively more nonlinear below this depth. In addition, the nonlinear elastic rocks are weaker, have a lower Young?s modulus and a higher Poisson?s ratio than their linear elastic equivalents. Interestingly the tangential Poisson?s ratios of the nonlinear elastic materials are often greater than 0.5 at 50% of the failure stress, suggesting an early failure initiation. The paper describes the microscope and modelling work done to determine the causes of the nonlinear behaviour and discusses some implications of the behaviour for deep-level mining.

Jan 1, 2009

By M. Saghaeian, R. Hejazi, V. Sheikhzadeha, A. H. Baladastian, A. Dehghani Ahmadabadi

This paper describes research done to remove apatite (phosphorus) from hematite ultrafine (70% finer than 25 micron) concentrate, recovered by electromagnetic separators at the FST Tailing Recovery Plant located in Chadormalu Iron Ore Complex through reverse froth flotation. As a result, iron and phosphorus content in magnetic concentrate (flotation feed) were 53.52% and 0.58%, respectively. Therefore, to increase the Fe content and decrease the P content of the sample, reverse flotation tests were applied. Chemical reagents used in this research consisted of sodium silicate as a depressant, sodium hydroxide and sodium carbonate as pH regulators, Alke & Dirol as fatty acid collectors and MIBC as frother. Process parameters including dosages of collectors, depressant and frother, preparation times of depressant and collectors, steps and time of frothing and pH range were selected. After doing flotation tests, in optimum condition, dosages of collectors were 1200 g/t, depressant 1200 g/t, pH in the range of 9.5 to 10, preparation time of collectors in the first step was eight minutes and at the other steps, four minutes; the number of frothing steps 4 and frothing time in each stage was three minutes. In this case, it was observed that the amount of phosphorus in the final concentrate was reduced to 0.05%, the Fe content increased from 53.52% to 61.66% and the Fe recovery achieved was 82.21%. Keywords: Iron ore, hematite ultrafine concentrate, iron and phosphorus content

Jan 1, 2020

By W. Bleloch

Published in the Journal, September 1970, and presented at a colloquium on 'Future of the Steel Industry', 17th March, 1971. Errata (a) The final sentence in the penultimate paragraph, left hand column p. 34 of the text should read: 'In the hot regions of the bosh and stack the C+CO2=2CO reaction proceeds to CO from coke carbon and carbon dioxide generated by reduction of iron oxides by CO (the so-called solution loss of carbon)'. The italicised words have been omitted in the text. (b) Temperature in Fig. 3 is K not C. (c) In Fig. 9, connection from top plate of column 10 to heat exchanger 9 has been omitted. DISCUSSION J. B. BEEDON AND C. J. JONKER* Dr Bleloch's paper has outlined the advantages of recycling stack-gas of low nitrogen content in the blast furnace. In the first instance it would appear to be extremely beneficial in controlling the hearth temperature and allowing a 100 per cent oxygen-blast to be used. On a second point however we have to disagree. It is claimed that heat is liberated in the combustion zones by the oxidation of CO to CO2 near the tuyeres and in the subsequent reduction of the CO2 by CO. The author has hypothesized as follows, and we quote: 'The C+CO2=2 CO reaction in the outer combustion zone at about 1 700°C is no longer endothermic due to loss of stability of CO2 and its consequent dissociation into CO and free oxygen.' This statement requires closer examination. If we consider the individual events occurring with the CO in the recycled topgas, with the oxygen in the blast and with the coke in the burden, as done by Dr Bleloch, the following heat considerations emerge. All heats of reaction are calculated from the enthalpy values of each reactant and product, as well as the temperature dependence of their molar heat capacities. (a) At the tuyeres: CO+1/2 O2-+CO2 . . . . . (1) CO, CO2 at 500°C; O2 at 25°C. ?H reaction = -65 000 cals/mole CO The reaction (1) is exothermic. (b) In the outer combustion zone: CO2+C?2 CO . . . . . . . . (2) C, CO at 1 700°C; CO2 at 500 0C. ?H reaction = -56 000 cals/mole CO Reaction (2) is endothermic. The overall heat gain of reactions (1) and (2) is ?H=+56 000 - 65 000= -9000 cals/mole CO i.e. the overall reaction is slightly exothermic, the amount of heat liberated is however smaller than suggested by Dr Bleloch. (c) The dissociation CO2+CO+1/2 O2 . . . . . (3) is a highly endothermic reaction at 1 700 0C, requiring 82 000 cals/mole CO2 to proceed to completion. Furthermore, this reaction (3) is energetically not favoured to proceed, as can be observed from the free energy-temperature relationship of figure (3), which favours the formation of CO2 at 1 700 0C. Hence direct dissociation of CO2 at 1 700 0C appears to be unlikely.* The concept of recycling topgas is however still intriguing from many other points of view. Apart from providing a very efficient method of hearth temperature control, it will create a much higher CO partial pressure in the stack. Whether the rate of indirect reduction in the stack will be proportional to this partial pressure or not is un-

Jan 9, 1970

By J. L. Gaigher

A simple mineralogical regression model is described, which was devised in order to help the flotation plant cope with rapidly changing headgrades and feed mineralogy. Minerals in the feed were determined by means of quantitative X-ray diffraction and compared with plant performance parameters and flotation reagent consumption rates, using regression analysis. A mineralogical regression model for predicting recovery served to motivate flotation plant personnel and also set standards whereby flotation performance could be measured. The reagent consumption model indicated in which direction any or all of five flotation consumption rates should be altered. All practically measurable parameters, even those showing poor or no correlation, were included in the model, provision being made for the continuous update of a batch of data of 30 lines. Compared with the method of multiple linear regressions, the r2 is poorer at 0,41 (versus 0,50), but the mean standard error of estimate for both methods is identical at ± 6,6 units. The regression model is simpler than the method of multiple linear regressions, and although the accuracy of prediction is not high (41%), the mineralogical regression model proved to be successful in practice. Flotation efficiency, as measured by the mean ratio of head to tails grade, for the 9 month period after the mineralogical regression model was implemented on an hourly basis, improved from 2,8 to 3,2, which is equivalent to an improvement in average flotation recovery of 5% relative.

Jan 1, 1987

By C. Hey

The cycloned gravitated tailings backfill system, also referred to as a soft or low density fill, has been implemented at Vaal Reefs. Inhibiting the success of the system was the problem of shrinkage after placement. The problem was overcome by a pressure fill technique which eliminated settlement, contained costs and allowed remote placement. The technique involves the preinstallation of disposable pipes which are filled cyclically until a residual pressure of 0,5 bar of active support is generated in the filled paddock.

Jan 1, 1988

By R. S. Sanders, J. Schaan

Syncrude Canada Ltd. produces synthetic crude oil from Canada?s vast oil sand reserves by mining the oil sand, then separating and upgrading the ultra-viscous crude oil, or bitumen (~ 106mPa s @ 10ºC). At Syncrude?s Aurora Mine, about 16 000 tonnes oil sand per hour are mined and then transported 5 km by slurry pipeline to the extraction plant. The waste tailings stream is then transported about10 km by pipeline to a settling/sand storage basin. Oil sand slurries are reasonably concentrated (> 35%solids by volume), typically have a sand particle diameter between 0.18 and 0.3 mm, and are transported at reasonably high velocities (3 to 5.5 m/s). As one would expect, pipeline wear is a significant problem in this industry, in terms of both unplanned production outages and maintenance costs. In order to develop strategies to extend pipe life and to focus more on condition-based maintenance scheduling (as opposed to preventative maintenance), Syncrude has implemented an ongoing pipe wear measurement programme. Regular measurements of pipe wall thickness are obtained at various circumferential positions at a number of axial locations along each pipeline, using an ultrasonic scanning technique. In this paper, we show how wear rates vary as a function of axial location and circumferential position for oil sand hydro transport and coarse particle tailings pipelines. The specific positions at which peak wear rates occur are explained by considering the characteristics of the coarse particle slurry flows to which the pipelines are exposed.

Jan 1, 2007

By E. Uslu

The kinetics of the reduction of chromite from the LG-6 layer of the Bushveld Complex in Fe-Cr-C alloys were studied in the temperature range 15OO°C to 1680°C under an inert argon atmosphere. The rotating cylinder technique was used, and the rotational speed of the chromite cylinder ranged from 0 to 1000 r/min. The melt consisted of 30 to 80 per cent chromium and 2 to 8 per cent carbon. The initial chromium-te-iron ratios of the melts varied between 0,42 and 4,95. The reduction of chromite spinel was analysed in terms of the decarburization of the metal. It was found that decarburization increased with an increase in the temperature, the carbon content of the bath, and the rotational speed of the cylinder up to 400 r/min, after which it remained almost constant. Decarburization also increased with an increase in the chromium content up to about 50 per cent chromium but, at higher chromium contents, it decreased. In the early stage of the reduction, up to about 30 minutes of reaction time, the liquid-state mass transfer of oxygen was found to be the most likely rate-determining step. The apparent activation energy was calculated to be 84,864 kJ per mole of oxygen. In the later stage, diffusion of iron and/or chromium in the solid state is the most likely rate-determining step. The apparent activation energy for the diffusion was calculated to be 471,18 kJ/mol.

Jan 1, 1991

By I. Ince, S. Kahraman, M. Rostami, B. Dibavar

The density, porosity, and strength of rocks are fundamental in the design of geo-engineering projects. Determining these properties requires the preparation of smooth core samples, which is usually impossible for soft rocks. Besides, only fragmented samples may be available in some projects. A method for predicting rock properties from rock particles such as drilling debris would therefore be useful. This study was undertaken to develop prediction equations for compressive strength (UCS), tensile strength (BTS), density, and porosity values from the crushability index (CI) obtained from rock fragments. The results showed that UCS, BTS, density, and porosity were strongly correlated with the CI. The physical characteristics and strength of rocks may be predicted with the help of the derived equations. The CI test is a valuable tool for estimating rock properties in drilling projects and in situations where core specimens are not available.

Mar 14, 2024

By C. Musingwini, A. S. Nhleko, M. J. Mahase

"In an environment like the mining industry, which is characterized by different stakeholders with multiple objectives, multi-criteria decision analysis (MCDA) is a useful approach for optimal decision-making. The application of MCDA techniques in the mining industry has predominantly been in mine planning and related problems, although no comprehensive survey has previously been undertaken to establish the application trends. A survey of the use of MCDA techniques was therefore conducted using case studies from the literature. It was noted that often two or more methods are applied to the same problem in order to increase confidence in the solution derived. As the number of criteria and alternatives increases, some methods become inefficient. A combination of the analytic hierarchy process (AHP) method with other MCDA techniques was the most frequently used approach, indicating the efficiency of the AHP method, especially when evaluating problems with more criteria and fewer alternatives. A combination of fuzzy theory with AHP or other methods incorporates uncertainty. The findings from the survey will benefit users applying MCDA techniques to solve mine planning and related problems.IntroductionA country’s natural resources serve the needs of different groups of people within the country. These different groups are collectively known as stakeholders (Herath and Prato, 2006). Stakeholders have different needs, preferences, and expectations, which describe and define the criteria to be considered in decision-making. The options available as solutions describe the alternatives in decisionmaking theory. The criteria and alternatives have to be evaluated simultaneously when making decisions, and this is when multicriteria decision analysis (MCDA) techniques become invaluable (Herath and Prato, 2006) because the human mind is considered to be limited when solving complex and intangible problems with several criteria and alternatives (Saaty, 2007). MCDA techniques belong to a broad group of techniques called multi-criteria decision-making (MCDM) techniques. The other group of techniques within MCDM comprises the multi-objective decision-making (MODM) techniques. MODM techniques are generally used to solve problems with an infinite number of alternatives, while MCDA techniques are generally used to solve problems with a finite number of alternatives (Musingwini, 2010)."

Jan 1, 2016

By P. J. van der Walt, P. J. F. Fourie, L. M. Falcon

Various methods for the beneficiation of minus 0,5 mm coal are examined briefly, and tests are described on a cyclone of 150 mm diameter operating with magnetite as the medium. It was found that, for sharp separations, at least 50 per cent of the magnetite should be finer than 1Oµm. At that size, the ash content of the product was about 7 per cent at yields of 59 to 64 per cent, and the loss of medium was reasonable (about I kg per ton of fines treated).

Jan 1, 1980

By L. W. Helle

This paper summarizes the investigations carried out into a defect involving the corners of billets rolled from continuously cast blooms, which broke open during the rolling process. As it was believed that the defect must be connected with the formation of subcutaneous blowholes in the bloom, the investigations were directed towards an understanding of the roles of the three gases involved in the process. In an extensive trial programme, samples were taken from the heat at all stages of processing, as well as from all the raw materials and alloys. The main sources of nitrogen were found to be re blows, pick-up from the alloys added to the ladle (especially graphite), and open-stream casting. The major source of hydrogen was moisture in the alloys, especially high-carbon ferromanganese and silicomanganese. Further, it was established that the moisture content of the alloys is closely related to the appearance of the defect in steels with a carbon content of less than 0,20 per cent; 72 per cent of all the defects were present in this type of steel. Most of the remaining defects were found in steels with a carbon content of more than 0,60 per cent, where the nitrogen content was substantially higher than in the lower-carbon steels. It is suggested that the defect arises from the combined effect of oxygen. nitrogen, and hydrogen. Its occurrence in low- and high-carbon steels is triggered by the formation of subcutaneous blowholes when the critical oxygen level for carbon monoxide blowholes is lowered by the presence of excessive amounts of hydrogen and nitrogen respectively.

Jan 1, 1984

By C. A. Snyders

The research presented in this paper investigated the practical aspects of the recovery of platinum group metals (PGMs) from a dilute cyanide leach solution containing base metals, in a manner similar to that used for gold extraction in a typical CIP process, and focuses on both the adsorption and elution stages. The carrier-phase extraction of precious metals using activated carbon offers significant advantages over other processes in terms of simplicity, the high pre-concentration factor, rapid phase separation, and relatively low capital and operating costs. As a sorbent, activated carbon is still by far the most important material because of its large surface area, high adsorption capacity, porous structure, negligible environmental toxicity, low cost, and high purity standards. Adsorption tests were conducted on a pregnant alkaline leach solution (0.15 ppm Pt, 0.38 ppm Pd, 0.1 ppm Au) resulting from cyanide extraction performed in column leach tests. The initial adsorption rates of Pt, Pd, and Au were very fast and recoveries of these three metals were approximately 90 per cent after 2 hours, and 100 per cent for Pt, 97.4 per cent for Pd, and 99.9 per cent for Au after 72 hours. The parameters that influence the extraction of PGMs and Au were examined to assess their relative importance during the adsorption process in order to provide the basis for process optimization. The concentration of thiocyanate was not identified as significant factor for PGMs adsorption, while Ni concentration was the most significant extraction process parameter. Base metal cyanide complexes adsorb and compete with the PGM complexes for sites on activated carbon, and while copper adsorption can be minimized by adjusting the residence time, Ni adsorbs at approximately the same rate as the PGMs, influencing the loading capacity and adsorption kinetics of the PGMs. The feasibility of eluting platinum and palladium cyanide complexes from activated carbon using an analogue of the AARL process was investigated. Platinum and palladium elute from activated carbon almost to completion in 4 to 5 bed volumes at 80°C, while the elution of gold at this temperature is slow, with a significant amount of gold still to be eluted after 16 bed volumes. The equilibrium loading of gold is exothermic in nature (Fleming and Nicol, 1984) which will result in an increase in gold elution kinetics with an increase in temperature at similar pre-treatment conditions. A similar result was found for the elution of Pt and Pd. Cyanide pre-treatment was found to have a significant influence on PGM elution. Higher cyanide concentration in the pre-treatment step results in more efficient elution up to a point, and results suggest the possibility of an optimum cyanide concentration, beyond which elution efficiency starts decreasing due to increased ionic strength.

Jan 1, 2013

[Consider the situation where we wish to estimate the value of a block of ore W from the values of n samples wt (i = 1, 2.... n). The samples can be located anywhere inside or outside W. The blocks and the samples can have any size or shape (Fig. 8.1). We define ws as the set of all the samples wi: WS = Iw1; W2; W3.. . wn and we wish to estimate the block W using the samples ws. Let xi be the value of the ith sample and µw the unknown average value of the block. We can estimate µw from the average value of all the samples. Let µw be the estimator of µw. As the samples need not be of equal size, the sample average is: µw = wi xi/~ wi. (8.1) The mean squared error made when estimating µw by µw is known as the variance of estimation of W by ws. It is the error made when giving the value of the sample set ws to the block W and is written o2E (WS to W). By definition: o2E (ws to W) = E [(µw - µw)2]. (8.2) If n = 1, this error is known as the extension variance. Since the sum of the weights given to the sample values is equal to 1,0, the estimator µw is unbiased (the question of the absence of bias is studied in more detail in Chapter 9): E [( µw - µw)1 = 0. (8.3) The error (µw - µw) has zero mean and a variance o2E = E (W8 to W). If we assume that this error is normally distributed, we can define confidence limits for µw. Let tP be the value of the standardized normal variance t such that the probability that t is less than tP is p: (t,) = .\/27T f exp (- t2/2) dt = p (8.4) The probability that µw is larger than µw + t1-P oE is p. The probability that µw is smaller than µw- t1-P oE is p. The following approximation formulae are often used to calculate 2p central confidence limits for the block value: 68% central confidence limits (p = 16%): µw - o2E, and µw + o2E. 95 % central confidence limits (p = 2,5 %): µw - 2 oE, and µw + 2 oE. Tables of the function 0 can be found in any textbook on statistics (for example, Fraser, 1958, p. 388) (see Table 7.2). [ ] The last line of Table 2.2, corresponding to f = 00, also contains the value of tP for p = 80, 90, 95 and 97,5 %.]

Jan 1, 1978