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By In-Kuk Bae, Kwang-suk You, Joobeom Seo, Kwanghyun Bea, Hyung-Seok Kim

Arsenic in base metal sulfide ores is highly penalized owing to high costs for its control in metallurgical processing. The arsenic element in the lead-zinc ore, which is target ore in this study, has been shown to be in the form of arsenopyrite. Experimental work in this study is about arsenic rejection flotation, using depressant suitable for the removal of arsenopyrite from the Pb concentrate. The arsenic rejection flotation also included the oxidation treatment of Pb concentrate with H2O2. In this study, the Pb concentrates containing 80.7% Pb and 0.25% as was obtained with the additions of aluminosulfate as arsenic depressant. And through IR measurement, it was also known that the addition of aluminosulfate during arsenic rejection flotation formed calcium aluminosulfate hydrates on the surface of arsenopyrite particle, resulting in rendering arsenopyrite hydrophilic.

Jan 1, 2014

By I. A. Makalin, V. N. Yakovlev, S. V. Imangulov, I. V. Zyryanov

"The presented studies aimed at solving the problem of recovery of low-luminescent diamonds, which are not recovered using X-ray luminescence method of processing of diamond-bearing ore. The purpose of the studies is the determination of possibility and feasibility of recovery of such crystals using dual-energy X-ray transmission separation technology. In preparation for studies methods were developed for testing technical and process parameters of XRT-400 Aliud GmbH (Germany) sorter, manufactured according to design specifications of Yakutniproalmaz Institute, and XRT/D TOMRA Sorting Solutions GmbH (Germany) sorter, designed for processing of -50+5 mm ore, as well as RGS-1M, RGS-2 X-ray sorters, developed by JSC NPP Bourevestnik (St. Petersburg) in cooperation with Yakutniproalmaz Institute, for material size of -6+3 mm. In 2018, in-process tests of RGS-OD-3 X-ray sorter prototype on material size of -3+1 mm are scheduled. Studies to determine the content of low-luminescent diamonds and feasibility of their recovery using XRT-400 and XRT/D sorters at the Processing Plant #3 of Mirny Mining and Processing Division (MPD) were carried out. The results of the studies confirmed presence of such diamonds and possibility of their recovery using the dual-energy X-ray transmission method. In-process tests of RGS-2 X-ray graphic sorter were carried out at the Processing Plant #16 of Nyurba MPD. According to the results of sampling of RGS-2 sorter separation products, the recovery of -6+3 mm sized diamonds from tailings of X-ray luminescence sorters was achieved at the level of 96%, while the diamonds recovery was 98.5% in value terms, the concentrate yield was 0.1%. In-process tests of RGS-1M sorters at final recovery of the grease separation concentrate at the Processing Plant #3 of Mirny Division were carried out. Recovery of low-luminescent -6+2 mm sized diamonds by RGS-1M sorter amounted to 92.4% for single operation, and with the double control operation reached 99%. As a result, -6+2 mm sized base product recovery increased by 0.2%."

Jan 1, 2018

By Lokesh K. Thakur, Peter Radziszewski

"For the cases tested (11 mills with 15 operating conditions), the Bond abrasion test steel media wear rate prediction gives an overall error of 73% and a standard deviation of 192.5%. However, total steel media wear in a given mill (ball or SAG) grinding process is a product of three recognised wear mechanisms -- impact, abrasion, and corrosion. A total media wear model can be defined on the assumption that the effect of each wear mechanism can be independently determined which allows for a total media wear model to be defined as the summation of the wear result of each mechanism (eqn. 1). It is assumed that impact and abrasive media wear is a function of the energy dissipated in impact and abrasion as estimated by a DEM charge motion simulation. Corrosive media wear is assumed to be a function of the media surface area present in a mill.The 3 initial tests developed (steel abrasion wheel, corrosion batch mill, impact chamber) coupled with the impact and abrasion energy spectra from a DEM charge motion simulation produced total steel wear rate results for the same cases as the Bond abrasion test giving an overall error of 0% and a standard deviation of 66.1%. However, if one were to consider the general observation that wear is proportional to energy and maintain the assumption that corrosion is proportional to media surface area then one would realize that the total media wear eqn. (1) can be reduced to eqn. (2). As this is a linear equation and one has, for the same mill, media wear and operating data for three different operating cases, one obtains three equations with three unknowns. This defines a simple matrix manipulation to determine the constants k1, k2 and k3. From the previous data set, we had 6 identical mills grinding the same ore but having different worn liner profiles and charge volume which provided the opportunity to average out the ki values over 20 combinations of 3 cases. With the determined ki values, it was possible to determine a second estimate of the contributions of impact, abrasion and corrosion to total media wear giving an overall error of 0% and a standard deviation of 56%."

Jan 1, 2003

By Vladimir Grujic, Milorad Grujic, Ivan Djurkovic, William Riggs

"In this paper, we have studied efficiency of different chemical structures of frothers on copper ore Majdanpek. The goal was to find out the best suitable chemical structure, which allows good bubble formation, size and interaction, forces on mineral surface. The particle size distribution was between 10 and 100 µm. Our research was oriented on three groups of frothers: alcohols, poly glycol ethers and poly glycols.We also used different collectors based on similar or less similar alcohol group in chemical structure as in frothers, expecting higher stability of air bubble in contact with copper minerals. Minimal potential energy was determinate in the hydrodynamic conditions for different particle sizes. It was founded that it is proportional to air bubble volume on 0.88° and contra proportional to the kinematics viscosity of pulp.Analyzing the results, we find out that poly glycols decreased surface tension the most. Also, it increased amount of coarser particles to the top of pulp. This group is less sensitive to pH value compared to the others too.From the class of frothers with higher efficiency in flotation process, we pointed OrePrep X-75 and X-133 as frothers with expressive frothing characteristic in the alkaline and low alkaline circuits. Special suitability of those frothers for floating copper minerals makes their hetero polar molecules with more than one hydrocarbon radicals connected to one polar group. However, those froters have no nether high or low solubility and are non-ionization. Those froters indicate some small collecting characteristics too. In dispersion systems, those two frothers make two types of bubbles: smaller di < 1.2 mm; V = 0.0008 cm3 and middle di < 16 mm; V = 2.2 cm3 (di – Bubble diameter, V – Bubble volume). Transportation speed of air bubbles it is possible to calculate based on equation: ?s = 27.5 * di 1.4 cm/s. Distribution of free surfaces for chalcopyrite is average 80% in the class –74µm +10µm and 20% in the class -10µm. If we get all class sizes, we find that recovery (R) depends from the time by equation:"

Jan 1, 2003

By B. Aydin, G. Erturk, G. Bulut

Coal is a complex material because of its structure consisting of carbon constituents and mineral matter. Flotation is readily carried out due to hydrophobic characteristic of coal. Therefore coal flotation is the most commonly used technique for fine coal beneficiation in order to acquire clean coal separating ash forming mineral matter from carbonaceous matter. In the coal flotation, floatability of coal both depends on characteristic of coal and used flotation reagent. Frothers as a flotation reagent are used to facilitate air dispersion into fine bubbles by prevention of bubble coalescence in the pulp phase, and stabilization of flotation froths. In this study, the effects of frother types and concentrations at different pH and particle size on the coal flotation were investigated. The representative sample was taken from Zonguldak, Turkey. It contains 9.1% ash and 7313 (kcal/kg) calorific value. Pine oil, Dowfroth 250, MIBC and Isooctanol were tested as frother types. It is determined that 1.92 ppm frother concentration is sufficient to float coal, except pine oil. In mixed frother tests, it is seen that Dowfroth 250 is more effective than others. No significant difference in coal recovery was observed for flotation tests at the different pH values. The best results are obtained in size of coal (-0.1 mm) with all frothers.

Jan 1, 2014

By S. Makni

Flotation is a complex process in which many mechanisms come into interaction. In this paper, an approach to model these mechanisms in order to predict size-by-size flotation performances is presented. The estimation of the collection efficiency of particles takes into account the serial sub-processes of particle-bubble collision, attachment and detachment. The model was applied to an industrial plant and yielded satisfactory results whereby the actual flotation performances could be correctly predicted. Furthermore, the flotation model allowed investigating the possibility of improving flotation performances by a split flotation feed in comparison to the actual single-stage process.

Sep 1, 2012

By V. V. Trusova, Shiyrav Gandandorzh, K. V. Fedotov, V. A. Domracheva

"In Russia, 1.1 million tons of mercury-containing waste are stored. The amount of mercury in soils and heaps of industrial enterprises is estimated at 3000 tons; in dumps, concentration tailings, sludge dumps of the gold mining industry up to 6000 tons have been accumulated. Mining is one of the main sources of mercury emissions in the natural environment that poses a real threat to the natural environment. At present, the process of amalgamation is prohibited and not applied in gold extraction. The application of amalgam technology in gold mining led to the accumulation of highly toxic products in the form of gold-bearing amalgam and metallic mercury, with a mercury content of dozens and even hundreds of times greater than the maximum permissible concentration for soil (1). Therefore, mercury-containing tailings constitute an ecological hazard to the environment. According to published data, at waste storage sites of industrial enterprises, up to 50 tons of mercury enter soil annually, and up to 3.5 tons pollute the air. At the same time, mercury-containing waste due to the reduction of the country's mineral resources is an additional source of mercury. Therefore, it is necessary to recycle mercury-containing waste. INTRODUCTION Paperobjective: demercurization of technogenic raw materials (amalgamation tails, discharge outlets of tailing dumps) to be recycled. Under natural conditions, the mercury usually migrates in the form of three most common compounds: elementary mercury (Hg); mercuric mercury ion (Hg+2); methylmercuryion (Hg (CH3) +. Chemical compounds Hg (II) are found in natural conditions much more often than Hg (I).The authors propose to conduct demercurization of technogenic raw materials (mercurial tailings) in two stages. At the first stage, the mercury in the form of small balls, the finest particles (drip mercury) can be extracted by applying the gravitational method. We propose a method for centrifugal processing of crushed waste in the apparatus of Itomak company, Novosibirsk, as the basis of the technological process for mercury recycling. The extraction of metallic mercury out of mercury-containing waste into commercial products, according to the technological characteristics of the Itomak apparatus, reaches 86.0% (2, 3). At the second stage, the extraction of mercury out of technogenic raw materials is performed applying a sorption method and using carbon sorbents based on fossil coals. Hard coal of the Kuznetsk Basin has been already used for industrial production of active carbons (carbon sorbents) of the KAD-iodine type, which is one of the prerequisites that determine the choice to use it for the aims of this study."

Jan 1, 2018

By Zhu Yangge, Zheng Guibing, Hu Xiaoxing

"Because of the similar crystal structure and surface properties, it is very difficult to realize the efficient separation of magnesite and dolomite by flotation, which is the main reason restricting the utilization of magnesite resources with dolomite symbiotic. To deal with a magnesite resources with high content of calcium impurity in northwest China, a novel decalcification technology by combining flotation with leaching is proposed in this paper. In flotation process, a novel flotation collector with good efficiency and low temperature resistance was developed, and the depression effect of sodium hexametaphosphate was investigated. In leaching process, the leaching rate difference of calcium and magnesium was observed. By industrial test, from the magnesite ore with MgO content of 43.96%,the grade and recovery of obtained concentrate ( calculated by MgO) are 47.28% and 67.68% respectively, at the same time, CaO content decreases from 3.91% to 0.30%, which means that more than 95% of CaO impurity is removed.INTRODUCTIONMagnesite is one of the main raw materials for the production of refractory materials, and it is widely used in metallurgy, chemicals, ceramic, construction and other industries. China is the most important supplier of highquality magnesite resources, accounting for about 60-70% of the world's identified supply of magnesite products is provide by China (Jewell, 2014). In recent years, high-quality magnesite ores can be directly used are going to run out in China, and the utilization of magnesite resources with high impurity content have drawn more attention.The main purpose of purification for magnesite is to remove SiO2 and CaO impurities which affects the strength of the refractory material. Flotation is the commonly used method to remove impurities in magnesite ore. Reverse flotation with cationic collector is usually adopted to remove silicon containing impurities, and a great deal of literature has been reported (Santana A. N. and Peres A. E. C., 2001; Wang and Sun, 2008; Zhu et al, 2014; Wu et al, 2015; Ivan B. et al, 2017). But when the major gangue component is dolomite, it is very difficult to realize the efficient separation due to the similar crystal structure and surface properties between magnesite and dolomite. To solve this problem, researches have studied the surface properties of magnesite and dolomite, such as wettability, electrical property, solubility and solution chemistry (Nermin and Nurgul, 2006; Nermin 2006; Ozbek and Abali, 1999; Lacin et al, 2005; Bayrak et al, 2006; Bakan et al, 2006; Chen G. and Tao D., 2004), but the commonly studied direct flotation using oleic acid as collector is still hard to receive an ideal effect."

Jan 1, 2018

By Y. D. Gao

A new technique has been developed for comprehensively recovering tantalum niobium tungsten ore by adoption of stage grinding, stage separation, combination of flotation and gravity separation, gravity separation for coarse particles, flotation for fine ones, combination of ore-dressing and hydrometallurgy. The new type and high efficiency combinative collector mainly composed of benzyl hydroxamic acid is firstly used to treat tantalum niobium and tungsten slime, besides the new type equipment for gravitational separation ?YTF-C shaking table for fine particles is adopted to treat flotation rough concentrate, hence having notably enhanced both recovery and concentrate grade of fine tantalum niobium and tungsten minerals. The commercial test obtains the tantalum concentrate assaying Ta2O5 31.98% with recovery 43.44% and tungsten product assaying WO3 89.40% with recovery 76.02%. The developed technique provides a reliable approach and an effective way for comprehensive utilization of lean fine complex refractory tantalum niobium tungsten ore resource.

Jan 1, 2014

By L. Y. Feng

The percentage of leached zinc in massive zinc oxide ores (11.7% Zn, >2 mm) is up to 73.3 % in 120 days. Alternatively, crushed to -0.154 mm, mixed with cement 5% (wt), pelletized and solidified. The diameters of the pellets obtained are between 5 mm to 8 mm. When the pellet solidification periods are 3 days, 10 days and 45 days respectively, the alkaline leaching rates of zinc in the pellets are up to 95.8%, 89.1% and 76.4% respectively. Decreasing the solidification time can re-duce reaction time, increase dissolution of zinc in pellets and lower the effect of initial zinc concentration on leaching rate. The experiment results show that the minimum solidification time is three days, and the kinetic study indicates that alkaline leaching of the low grade zinc oxide pellets is controlled by the diffusion of the leach liquor through the gangue layer in the whole leach process, and the apparent rate constants are 3.33×10-2 day-1, 9.18×10-3 day-1, 5.82×10-3 day-1 respectively.

Jan 1, 2014

By Jan Svoboda, Atsushi Shibayama, Toyohisa Fujita, Toshio Miyazaki, Kenji Murata

"The electrical disintegration (ED) method and disintegration by underwater explosion were investigated as new fragmentation techniques for the kimberlite ore and tungsten scrap of superalloy (carbide bit). The results of various breakage tests demonstrated that both fragmentation methods as new disintegration techniques for recycling were able to liberate various components of materials of different resistivity and elastic impedance.SUMMARYThe breakage of the kimberlite ore from South Africa (sample size: 15 mm x 15 mm x 6 mm) was achieved by the ED method. A relationship between the sample size, voltage, the electrical current and the energy needed for the disintegration was found from the experimental results. Kimberlite exhibited a high degree of breakage, when the high voltage of 60 kV and the pulse current of approximately 5000 A were applied to the sample by the generator during 0.2 microseconds (Fig. 1)."

Jan 1, 2003

By A. Lane

Africa is ripe with opportunity for the mining industry. The continent has large, and relatively unexplored mineral deposits, and recent high economic growth rates have meaningfully improved the political, economic, and infrastructural environments. However, these opportunities are accompanied by significant risks, including resource nationalism, uncertain regulation, corruption, and continuing political instability (up to and including war). Forward-looking companies actively manage these risks by creating a sense of shared purpose with the countries and communities that own the resources, using tools such as stakeholder analysis, local narratives, scenario planning, and constituency engagement. They also measure socio-economic impact to insure the creation and demonstration of shared value.

Sep 1, 2012

By Ana Elisa Casas Botero

The Rhodococcus opacus microorganism was evaluated as a biocollector for flotation of barite. The electrophoretic behaviour of the mineral, before and after R. opacus interaction, was evaluated and showed that the cells adhesion shifted the mineral zeta potential curves. Adhesion tests were suggested a high affinity of the bacteria for barite. The experiments of the adsorption rate of the R. opacus on the mineral surface showed fast kinetics, achieving a maxim of cell adsorption after 5 minutes. Adsorption isotherm curves for barite could be categorized as Langmurian (L) type II. The best bioflotability results for barite achieved values around 75% for a R. opacus concentration of a R. opacus concentration of 250 ppm in the pH around 5.0. The studies were compared with the flotation of barite using a traditional collector. The bioflotation experiments were discussed considering the obtained adhesion tests. The results were supported by the Thermodynamic approach for selected pH values. The fundamental flotation studies showed the paramount potential that R. opacus presents as a biocollector and its possible application in the mineral flotation industry.

Jan 1, 2014

By T. Laxmi

This paper details the optimization of rougher Wet High Intensity Magnetic Separator (WHIMS) using response surface methodology. The optimization is in parametric form and takes account of the major operating variables in WHIMS operation such as current in ampere and grid gap, in inch. The objective is to recover ilmenite mineral from red sediment deposits of Srikakulam, India by optimizing the rougher WHIMS. We predict mineral recoveries as a function of current and grid gap. Combination of these predictions with assay data provides predictions of mineral grades and recoveries. The optimized response was validated against data derived from laboratory-scale rougher WHIMS test work, comprising (i) mineral grade, (ii) mineral recovery, and (iii) separation efficiency of the process. We observed close match between the experimental and the predicted data over most of the operational range. This paper describes how the optimization was carried out using the response surface methodology along with MATLAB. The response surface was used to closely investigate the separation of ilmenite mineral by varying ampere and grid gap. The results show that under optimum conditions, such as 3.5 amp current (0.53 Tesla) and 2 inch grid gap, the mineral grade could reach, as high as 87.9% in the concentrate with 74.3 % recovery and 74.4% yield. Keywords: red sediment, wet high intensity magnetic separator, optimization, ilmenite, placer heavy minerals

Sep 1, 2012

By Y. S. Sun, P. Gao, Y. F. Li, J. W. Yu

"Oolitic hematite ore is one of the most refractory iron ores in the world. It is not feasible to separate iron minerals from raw ore by conventional mineral processing methods. In recent years, a new technology called coal-based reduction followed by magnetic separation has been employed to produce metallic iron powder from oolitic hematite ore effectively. In order to find the nucleation mechanism, a thermodynamic analysis of the carbothermic reduction of oolitic hematite ore was conducted by the HSC 6.0 thermochemical software. The phase transition and microstructure changes during the coal-based reduction were also investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS). The results showed that the iron oxides in the oolitic ore were reduced to metallic iron following the route of Fe2O3–Fe3O4–FeO–Fe in reduction process. The reduction reactions preferentially occur in the high activity regions to form a higher concentration of Fe elements, and then more supersaturated Fe separated out to form new phase nuclei. Under the action of homo-aggregation and principle of minimum free energy, the iron cores continuously absorbed migratory Fe around and grew into quasi-spherical iron particles embedded in slag phase. INTRODUCTION With the rapid increase of steel industry, premium grade iron ore in China has been gradually exhausted, and its supply has become bottleneck for the development of iron and steel industry (Guo et al., 2015). Therefore, it is urgent to exploit the refractory iron ores, such as oolitic hematite ore. Oolitic hematite ore is widely distributes in France, Germany, America, Canada, Pakistan, China, and among other countries (Maynard and Van Houten, 2004; Li et al., 2011). In China, the explored reserve of oolitic hematite ore is 3.72 billion tons, which accounts for approximately 1/9 of total iron ore resources of China (Gao et al, 2016). Oolitic hematite ore possesses complex composition,"

Jan 1, 2018

By M. Kadiyski, V. Stoyanova, E. Visariev, V. Stoilov

"The present study deals with copper losses in slag from copper smelting. Copper slag cooling at Aurubis Bulgaria is traditionally done in pits. A new type of slag-cooling is introduced in the site, involving cooling ladles. In a previous study, the ladle cooling process was studied in detail, showing an improvement in the recovery of copper in the slag after flotation. The main reason for better recovery of copper is the increased cooling time, which allows for the accumulation and aggregation of copper droplets. The effects of the newly introduced slag cooling process are studied using optical microscopy and scanning electron microscopy. Cooling in pits and in ladles is compared, based on copper droplet size, distribution and content. Specialized image processing software is employed on images taken with an optical microscope. The results are then compared with a similar technique, available in SEM software. The availability of phase-analysing image software in combination with electron dispersive X-ray spectroscopy makes it possible to study the morphological properties, distribution and chemical composition of the copper droplets. The obtained results confirm the initial conclusions about size, distribution and composition of the copper-bearing particles. A large amount of copper particles is examined showing an obvious increase in their size from pit- to ladle cooling. The results show an increase in the average size of the droplets, which doubles from pit-cooling to ladle-cooling. There is a well-pronounced tendency of decrease of the percentage of droplets in the smallest fraction (<5 µm) in the ladle-cooled slag. In addition, the number of droplets in the larger fractions increases, compared to the ones in the pit-cooled slags. It is believed, that the developed methodology for analysis provides a relatively quick and reliable solution for comparison of the cooling rates in the slag. INTRODUCTION In the process of copper smelting and converting, iron-silicate slags are produced that contain various amounts of dissolved and entrained copper. Different physical and chemical techniques are employed for the valorisation of the remaining metals in the slag – magnetic separation, leaching, roasting, flotation, etc. According to Gorai et al (2003), about 2.2 tons of slag is produced per ton of metal. In 2016, about 20 million tons of copper have been produced globally (www.icsg.org). At an average of 0.5 percent copper content after treatment, these slags contain more than two hundred thousand tons of copper which is lost due to inefficient processing."

Jan 1, 2018

By Mingfei He, Yude Gao

"The leaching kinetics was studied during leaching of indium-bearing zinc oxide to recover indium. The effects of temperature, sulfuric acidity, particle size, stirring rate on dissolution rate of indium were investigated. Results showed that the leaching process was controlled by chemical reaction at the condition of low sulfuric acid concentration. While the acidity increased to 1.8 mol/L, the leaching process was transformed into an internal diffusion controlling model . The corresponding value of reaction orders under low acidity and high acidity were 1.194, 0.156, respectively. Further calculation results indicated that the leaching reaction activation energy was only 10.97kJ/mol under the condition of high acid. The leaching rate constant was inversely proportional to the square of particle size, while the effect of stirring rate on leaching process was insignificant. The leaching process can be enhanced by increasing the temperature and acid concentration, as well as the decrease of particle size. And a final kinetics eqution was proposed. KEYWORDS Indium, extration, leaching kinetics, zinc oxide INTRODUCTION Indium[1,2] plays an important role in many aspects of living and industrial production owning to its special physical and chemical properties. The reserve of indium is rare on the earth, and most of indium is distributed in some other minerals[3]. Some researchers [4,5] have proposed that indium mainly substitutes for the lattice of other minerals by isomorphous. Therefore, the extraction of indium should take into account of the production technologies of those minerals to comprehensively recover the valuable metals."

Jan 1, 2018

Three high-grade limestone ores (CaO content over than 53 %) with different geological origin have been characterized for the synthesis of aragonite precipitated calcium carbonate. Limestone ores examined in this study showed different crystal particle size that cause difference in disintegration degree and surface area of the synthesized slaked limes. The limestone ore with smaller crystal particle size showed higher disintegration degree and also yielded slaked lime with smaller surface area, which is good for the synthesis of aragonite precipitated calcium carbonate. The synthesis of aragonite PCC using the limestone with a small crystal particle size was yielded needle-shaped aragonite with the aspect ratio of about 14. Keywords: limestone, lime, slaked lime, precipitated calcium carbonate, aragonite, accelerated carbonation

Sep 1, 2012

By Shailin Lalloo, Allan B. Nesbitt

A fluidised bed was exposed to high gravities by placing it in a centrifuge. The bed expansions were measured and compared with the bed expansions predicted by the Richardson-Zaki model (1954). The Richardson-Zaki model was found to predict effectively the fluidisation behaviour of defined particles in this increased gravity environment.

Jan 1, 2003

By C. R. Mambote

One of the processes developed for vanadium recovery from the fly ash of crude oil is through acid leaching. In the process, iron is one of the impurities that should be removed before vanadium precipitation, due to the fact that iron tends to co-precipitate with vanadium. The mechanism of iron precipitation is understood in terms of ferric hydrolysis, followed by the dimerization and subsequent polymerization of the crystalline iron compound. In order to develop a new approach for the fly ash processing, in the present paper the precipitation of iron from the liquor after the leaching process was studied with addition of NaOH or NH4OH in the presence of H2O2 or Na2C2O4 at 80°C. The objective was to investigate the feasibility of the selective precipitation which could be applied to vanadium and nickel recovery from the fly ash. The experimental results show the difficulties of removing iron by precipitation without co-precipitating nickel and vanadium.

Jan 1, 2014