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By Sarthak Kaushik

Zeta potential measurements show that the isoelectric point of crandallite, in aqueous solution of 10-2 N sodium chloride is at about pH 5.5. Measurements of turbidity confirm the point of zero charge or crandallite. Calcium ions specifically adsorbed on the surface and thus changed the zeta potential and turbidity. From the measured data, it is confirmed that starch acts as a flocculent for crandallite. Oleic acid, which is a collector used in phosphate ore processing is weakly adsorbed on the surface of crandallite. This results in hydrophobic coagulation of particles resulting in a lower turbidity.

Sep 1, 2012

By Milind Chikhale, Yogesh Reja, Keshav Tyagi

"Using computer models for process design is a well-established practice in the mineral industry. In recent years, there has been emphasis on modeling of processing plant as a whole. This paper covers development of a model for iron ore processing plant. Basic purpose of this model is to use simulation for efficient plant design and help in minimizing risk at the very initial stage of project. Feed to the plant is Hematite iron ore from a deposit located in Eastern India. Major processes in plant include multi-stage crushing, screening, grinding, classification, gravity and magnetic separation. Models for different process equipment were developed using METSIM and Bruno simulation software. Customized black box models and known mathematical models were used for predicting behaviour of processes. Data needed was identified based on the model type. The required data was arranged as per project requirement and processed for development and validation of model. Equipment models were developed and validated on the basis of process design basis, theoretical and empirical data from technical references, and bench scale and pilot scale testwork results. Validated process circuits were assembled to simulate and represent the entire plant process. The result shows expected variation in plant output as a result of variation in the feed. Study concludes by discussing potential applications of the model in plant design."

Jan 1, 2014

Pure camsellite samples were prepared through crushing, sorting and grinding the high-grade iron-containing camsellite ores from Fengcheng, Liaoning, China. The flotation behaviour of camsellite was studied via a systematic investigation of camsellite flotation re-covery changes as a function of choices and dosages of collectors and depressants at different slurry pH. The results showed that at pH 8.5 to 9.5, the recovery of camsellite reached the maximum at 90%~93.5% using dodecylamine as the collector, while under the same condition a recovery of 84%~86% could be achieved with sodium oleate. The adsorption of dodecylamine was not affected by the addition of sodium hexametaphosphate, but the adsorption of sodium oleate could be significantly depressed. This implied that sodium metahexaphosphate could be used as an effective depressant for the other associated minerals during the dodecylamine flotation of camsellite. When starch was used as the depressant, the flotation of camsellite by sodium oleate was almost completely depressed in the alkaline conditions. Significant depressions were also observed when calcium chloride was added in the camsellite-sodium oleate system. The higher the slurry pH is, the stronger the depression. Zeta potential measurements indicated that the flotation was mainly initiated by the electrostatic adsorption of the collector on camsellite. X-ray photoelectron spectrometer (XPS) analysis showed that the adsorption was originated from the electrostatic attraction between the N atom in dode-cylamine and B atom in camsellite. Dodecylamine had a higher coverage on the camsellite surface than sodium oleate.

Jan 1, 2014

By I. Gombköto

Mining and mineral processing operations are usually generating huge amount of tailings. These tailings often gives lots of maintenance work in order to protect environmental resources from heavy metals slowly leaching out of tailing are due to Acid Rock Drainage (ARD) process. Handling leakage could be active or passive such as using of Permeable Reactive Barriers (PRB). PRB?s are used worldwide treating underground contaminations, using different type of matrix materials. All generally used matrix material has its advantages and disadvantages such as selectivity, sensitivity of precipitation generation or not satisfying hydraulic conductivity. Nowadays cheap and effective matrix material which is ignorant to pore plugging caused by precipitation within the PRB could be one solution to the demands of the industry. The authors have been carried out an investigation at University of Miskolc on lignite as high humid acid containing material for determining the ability of heavy metal adsorption and pore plugging resistance. Moreover, using hydraulic and chemical simulation methods, complete PRB dimensioning protocol based on new lignite matrix had been introduced. Within the frame of this paper the results are going to be discussed.

Sep 1, 2012

By J. Kwon, D. Lee, H. Cho

"The use of the combined grinding and liberation model to predict liberation characteristics of iron ore comminuted by a ball mill was studied. Comminution characteristics were obtained using the one-size fraction method. The iron ore samples were crushed and separated into a number of narrow size fractions by screening. The size fractions were further divided by magnetic separation into three classes: concentrate, middling, and tailings. Subsequently, various size-grade classes were subjected to ball milling, and the results were analyzed in terms of the kinetic grinding model. The mineralogical textures of the grinding products were analyzed using mineral liberation analysis. The distribution of iron content within the size fractions was characterized by the beta distribution combined with the Andrew–Mica diagram. It was found that the grinding characteristics of the iron ore samples varied slightly with the iron content. However, the liberation characteristics were well described by the same set of liberation model parameters, regardless of composition. The variation in grinding kinetics with composition and the liberation model parameters was used in the combined comminution–liberation model to predict the evolution of the size-composition matrix as grinding proceeded. The predicted results agreed well with the experimental results. The developed model can be used to construct the yield–recovery graph and to calculate the liberation efficiency to determine the size reduction threshold for efficient separation. INTRODUCTION In mineral processing, comminution is usually the first step that ores undergo to liberate valuable minerals from gangue minerals. Generally, as the particle size decreases, higher liberation can be achieved. However, excessively small particles are unfavorable to subsequent processes, such as separation. Moreover, comminution is a highly energy-consuming process itself that accounts for approximately 60% of all energy used for processing. Therefore, there is a definite need to increase energy efficiency by applying adequate stress so that a high degree of liberation can be acquired at the coarsest size without overgrinding. To this end, it is essential to develop a model to predict the liberation of minerals as a function of size reduction."

Jan 1, 2018

By X. F. Cao

There was a large reserve of bauxite resources in China. And these resources were mainly the dias-pore-bauxite and contained plenty of aluminosilicate including kaolinite, illite and pyrophyllite. Reducing the contents of aluminosilicate would be significant to the using of Chinese bauxite resources. In this paper, from the single mineral flotation experiments, the surface properties and flotation beha-viours of aluminosilicate including kaolinite, illite and pyrophyllite, using dodecyl amine (DDA), N, N-dimethyl-dodecyl amine (DRN12) and N-dodecyl-1, 3-propane diamine (DN12) as collectors, had been investigated. The flotation results shown that the flotation behaviours of aluminosilicate had been influenced greatly by three amine collectors; and the effect was in the order of DN12>DRN12 >DDA. On the basis of FT-IR spectra and zeta potential measurements, the ionization of surface hydroxyl, as well as isomorphic exchange of surface ions, accounted for the mineral surface charges. And the mechanisms of interactions between the mineral surface and collectors mainly included two modes: electrostatic adsorption and hydrogen bonding; for the DDA and DRN>DDA. 12, the mechanism was mainly electrostatic adsorption; and for the DN12, the mechanisms of electrostatic adsorption and hydrogen bonding both existed. Results of quantum chemistry research shown that the collecting ability of amine collectors was greatly influenced by the electro-negativity of N in the amine molecules; and The |E(EHOMO| and ?E (HOMO-ELUMO) of N atom in DRN12 and DN12 were lower than that of DDA, and the positive charge of ?N group in DRN12 and DA12 were higher than that of DDA. All these calculation results could explain the collecting power of DN12>DRN12>DDA.

Jan 1, 2014

By P. Basarova

The attachment of bubbles onto a collecting surface is an ubiquitous natural phenomenon, playing a critical role in numerous practical processes. The goal of the project is to broaden the knowledge about hydrodynamic interactions between small bubbles and large solids that occur in nature and industrial processes. Focusing on collision processes between a single rising bubble (Db<1 mm) and a larger falling spherical particle in stagnant liquid, the theoretical model describing the bubble trajectory is given here. The model is based on analysis of forces acting on the bubble, and utilizes equation for the bubble motion. Mobile and immobile type of bubble surface mobility are considered. The calculated results are compared with the experimental data; here a high-speed video camera was used to capture the bubble motion and bubble-particle interaction. Very good agreement between experimental and calculated data was found. For both types of surface mobilities, the bubble deviation in the horizontal direction is nearly linear. The proportion constant is bigger for immobile bubble surface and increases with the bubble size. Furthermore, particular forces acting on bubble were studied. A similar course of relative bubble velocity and force impact was observed for identical bubble position. For cases when the bubble centre is close to the particle axis, only deflection in one direction is observed. When the bubble is reaching the maximum trajectory, the force ratio is changed. The bubble is firstly pushed away from the particle, but when it is within close distance from the particle, the bubble is pushed towards the particle.

Sep 1, 2012

By M. Minagawa, G. Granata, C. Tokoro, T. Kato

"In this work, we studied the mechanochemical activation of chalcopyrite by vertically stirred ball milling (VSBM) to enhance the dissolution of copper. By using x-ray diffraction (XRD) and laser diffraction particle size analysis, we investigated the effect of milling and milling conditions on particle size and phase composition of the chalcopyrite concentrate. To elucidate the efficiency of VSBM towards the mechanochemical activation of chalcopyrite, we also conducted leaching experiments in sulfuric acid-ferric sulfate media. Under all investigated milling conditions, the VSBM determined a dramatic decrease of particle size from over 100 µm of P80% up to about 13 µm. Furthermore, the XRD of the ground chalcopyrite specimens highlighted a partial oxidation of the mineral. In leaching, upon grinding by VSBM, the increase of copper extraction ranged from a minimum of +10% to a maximum of +40%, depending on the grinding conditions. In order to elucidate whether the dissolution enhancement was a consequence of the decreased particle size or of an induced mechanochemical reaction, we performed leaching experiments on activated and non-activated chalcopyrite sample having the same particle size. In addition, we determined the activation energy of leaching before and after vertically stirred ball milling. The leaching results on samples with the same particle size highlighted a greater copper extraction and higher dissolution rates upon mechanochemical activation. Whether performing grinding by VSBM or not, the leaching kinetics was found to be controlled by the chemical reaction on the surface of the chalcopyrite particle. By grinding the chalcopyrite concentrate by VSBM, the activation energy of leaching slightly decreased from 66 to 58 kJ/mol. INTRODUCTION Due to the increasing demand of copper, low grade ores and refractory minerals like chalcopyrite are expected to become the main copper source in the next years (Klauber, 2008). As a low-grade sulfide, chalcopyrite shall be processed hydrometallurgically. However, due to the formation of a protective layer of elemental sulfur during the oxidizing leaching, the dissolution of copper is slow and/or incomplete (De Bernardi and Carlesi, 2013). Therefore, the development of new technologies to enhance the extraction of copper from chalcopyrite is highly required."

Jan 1, 2018

By Masakazu Niinae, Kenji Aoki

"Electrokinetic soil remediation by electroosmosis and ionic migration is restricted to soluble substances. At a higher pH, the soil particles sorb more heavy metals than at a lower pH and the precipitation of heavy metals are promoted. Both mechanisms make heavy metals immobile, rendering cleanup more difficult and electrokinetic extraction inefficient.In this study, the effectiveness of introducing a complexing agent to enhance the removal of cadmium from kaolinite in the region of neutral pH by ionic migration is examined. The complexing agent selected was ethylenediaminetetraacetic acid (EDTA). The investigation was carried out in a laboratory-scale column containing kaolinite contaminated with cadmium. As the results of the study, cadmium migrates toward the anode without accumulation of cadmium and is successfully removed at the anode reservoir."

Jan 1, 2003

By A. Morrison, P. Brito-Parada

"The separation of valuable and gangue minerals according to their surface hydrophobicity in a froth flotation tank occurs in both its pulp and froth phases. In the pulp phase, hydrophobic particles must be brought into contact with rising bubbles introduced at or near the bottom of the tank. In a mechanical froth flotation tank, this is primarily achieved through the agitation of the pulp by an impeller or by a rotor-stator system. However, the turbulent and mixing effects of such an impeller or rotor-stator system, necessary to promote bubble-particle interactions in the pulp, are not confined to the pulp zone, but are transmitted into the froth zone at the pulp-froth interface. This impeller-induced turbulence at the pulp-froth interface is compounded by the impulse of buoyant bubbles entering the base of the froth phase, reducing the stability, and thus separation performance, of the resulting froth. Hence, turbulence improves separation performance if it occurs deep in the pulp phase, but diminishes it if it occurs close to the pulp-froth interface. For this work, a performance-enhancing pulp phase insert was designed to isolate the impeller-induced turbulence from the pulp-froth interface in a laboratory-scale, continuously-operated froth flotation tank. The result was a shifted grade-recovery curve that allows the insert to be designed to maximize the recovery from the system without sacrificing the grade of the concentrate, or vice versa, along a spectrum of improved performance. This paper will present the insert design and development process that resulted in this improved grade-recovery curve, as well as a set of heuristics that could be used to design a similar insert for pilotand industrial-scale validation and deployment.INTRODUCTIONAn almost ubiquitous design feature of commercial flotation tanks is the enclosure of the impeller to create a concentrated turbulent zone (Mavros, 1992). These turbulent zone enclosures are varied-- from the rotor-stator design of, for instance, Outotec cells, to the air disperser design of Wemco cells-- but all share the same rationale: that turbulence is desirable to promote bubble-particle interactions (Ralston, 1999), and to produce smaller bubbles (Wills, 2006), but also undesirable because it promotes the detachment of valuable mineral particles from bubbles, and exacerbates entrainment-inducing mixing at the pulp-froth interface (Jameson, 2010)."

Jan 1, 2018

By Igor Kuzymin, Isaak Maximov, Iuriy Akkerman, Galina Aksenova, Valentina Sentemova, Nataliya Trubechkova

"The Russian Federation possesses large reserves of oxidized ferruginous quartzites. These ores are currently mined together with magnetite ores and are stockpiled on account of unavailability of an efficient processing technology. This paper presents the results of investigations performed on the ores from the largest oxidized ferruginous quartzite deposit located in the Kursk Region iron-ore basin of Russia. The objective is to produce concentrate with iron content at least 66% and silica content within 5%. A processing technology was, developed under laboratory conditions, which included ore preparation, wet magnetic separation in weak and strong fields and reverse cationic flotation with addition of caustic soda, dextrin and Lilaflot 811M (alkoxy propylamine) collector from Akzo Nobel. The developed technology produced iron recovery concentrate with iron content of nearly 67%, and that of silica - 4.1%, iron recovery into concentrate being 72.6%."

Jan 1, 2014

By Eduard Stefanescu, James M. Mwase, Egon Sehner, Stoyan Gaydardzhiev

"The study is focused on investigating the production of synthetic rutile of 95% purity or higher from a Norwegian ilmenite ore concentrate. This was to be achieved using a sequential process involving oxidative-reductive roasting at 975°C, followed by magnetic separation to further concentrate the sample and finally leaching with 20% HCl to remove mostly Fe-based impurities leaving behind synthetic rutile. The key process parameters considered were roasting time (1 and 2 hrs), leaching temperature (100, 125 and 145°C), pulp density (15 and 25wt%) and leaching time (3 and 6 hrs). The option of directly leaching the concentrate without pre-treatment was also evaluated. Test work was conducted using samples screened to a size fraction of 105-212 µm. Samples were leached in a 1 L glass autoclave. The reactor was hermetically sealed and thus the resulting pressure was not controlled but was dependent on the process temperature. The product from leaching was calcined and analysed via XRD and SEM to determine the purity of the product. The magnetic separation step was found to be ineffective and discontinued early in the study. Thus far a product with 97% synthetic rutile purity as analysed by SEM has been produced by directly leaching the concentrate at a temperature of 145°C, pulp density of 25wt% and leaching time of 6 hrs.INTRODUCTION The study investigates the use of a process route comprising oxidative-reductive roasting, followed by magnetic separation and then hydrochloric acid leaching and calcination to produce synthetic rutile from ilmenite concentrate. The grade of synthetic rutile produced should be suitable for chlorination to produce pigment grade TiO2. Hence the proposed process should produce a product consisting of no less than 95% synthetic rutile. Additionally, the product should have no more than 1.5wt% combined content of CaO and MgO (Zhang et al., 2011) as they tend to form high-boiling-point chloride leading to the malfunctioning of fluidized bed chlorinator (Cardarelli, 2008). Finally the product should have no more than 2.1wt% of Fe2O3."

Jan 1, 2018

By John Ralston, Stephen Grano, Yongjun Peng, Daniel Fornasiero

"A specially designed mill which allowed the control of pH throughout grinding was used to study the effect of grinding conditions on galena flotation and galena separation from pyrite. The changes occurring on the mineral surface during grinding were investigated by EDTA extraction and ToF-SIMS measurements.Galena flotation and galena separation from pyrite were strongly dependent on the type and amount of oxidation species produced on galena and pyrite surfaces under different grinding conditions. Iron oxidation species depressed both galena and pyrite flotation, whilst lead oxidation species activated pyrite flotation but had little effect on galena flotation. Optimum galena flotation and galena selectivity against pyrite were achieved by selecting grinding conditions that enabled lead and iron oxidation production to be controlled.Grinding conditions had a large effect on the flotation of the galena particles of different sizes. Flotation of fine galena particles (-10 µm) was depressed by iron oxidation species derived from the grinding media. Chromium grinding medium decreased the production of iron oxidation species and therefore increased the flotation of fine galena particles."

Jan 1, 2003

By Peter N. Holtham, Geoffrey J. Lyman, Matthew S. Brennan, Vijay Subramanian, Rui X. Rong, Tim Napier-Munn

Studies of the dense medium and classifying cyclone have been conducted using the Fluent computational fluid dynamics code. Experimental measurements of the segregation of medium in a DM cyclone by gamma-ray tomography and the performance of a novel classifying cyclone design have been used to test and interpret the 3D CFD predictions. The predictions of the CFD models were generally plausible, though more work is required to incorporate turbulent mixing of the slurry in the cyclone. The benefits of the novel cyclone design were explained by the model in terms of conditions favouring reduction of short-circuiting at the vortex finder, and the removal of the air core from the wall at the apex. Work is continuing.

Jan 1, 2003

By M. Naymanbayev

The characteristics of the mineral composition of ores and valuable set of components: the technology of processing depending on the type of mineralization, the nature of the impregnation of ore minerals and their composition have been considered. There have been given technological schemes for processing concrete objects. The analysis of fitness fields for industrial development (degree of scrutiny, the effectiveness of developed enrichment and hydrometallurgy technology) has been provided.

Sep 1, 2012

By Masakazu Niinae, Tasuma Suzuki, Mai Moribe, Yohhei Okabe

Bench-scale electrokinetic experiments were performed to elucidate the electrokinetic remediation mechanisms of arsenate from artificially contaminated kaolinite. The electrokinetic experiments in which a constant voltage was applied demonstrated that high soil pH favored arsenate remediation with respect to both the remediation time and electricity consumption. It was also demonstrated that applying a pulse voltage (1 hour ON, 1 hour OFF) significantly improved the electricity consumption efficiency when the soil pH was maintained at the initial value during the experiments; this trend was not observed when the soil pH was gradually increased from the cathode side. These electrokinetic experimental results indicate that the remediation rate-limiting step varied with soil pH. When the soil pH was maintained at the initial value of 7.2 during the experiments, arsenate desorption was the remediation rate-limiting step rather than the migration of dissolved arsenate toward the anode. Conversely, when the cathode pH was not controlled and the soil pH was correspondingly increased gradually from the cathode side, the migration of hydroxyl and desorbed arsenate ions toward the anode played a more important role in the control of the overall remediation efficiency.

Jan 1, 2014

"This research aims at improving the beneficiation of coals and minerals in fine and ultrafine size fractions. A widely used method for upgrading fine and ultrafine particles is froth flotation, which is generally classified into mechanical flotation and column flotation. The present work is focussed on column flotation. A flotation column equipped with a conventional bubble diffuser/sparger was used with oscillatory air supply generated using a fast-switching solenoid valve. The flotation tests were carried out for coal particles and mineral particles, respectively, and a comparison in flotation performance was made between oscillatory air supply and steady air supply. It was found that use of oscillatory air supply with a proper valve switching frequency and on/off time ratio to replace steady air supply could lead to increased recovery of coals or minerals by more than 14 percentage points and substantial reagent cost savings. The improved flotation performance was attributed to enhanced gas dispersion and flow conditions. This research offers a simple new approach to improving the beneficiation of fine coals and minerals with using flotation columns.INTRODUCTIONFroth flotation has been widely used for the separation and concentration of fine coals and minerals by exploiting the difference in their affinity to air bubbles in aqueous medium. Froth flotation is an effective method for beneficiation of coal and mineral particles in a certain size range. It remains difficult to upgrade ultrafine mineral particles. One of the reasons for the ineffective flotation of fine particles is the low probability of bubble-particle collision in the collection zone (i.e., the pulp zone). According to Reay and Ratcliff (1973) and Yoon and Luttrell (1989), the probability of collision is significantly affected by bubble size and particle size, and the collection zone recovery can be increased by decreasing the bubble size."

Jan 1, 2018

By Markus A. Reuter, Albert Scholte, Ewoud V. Verhoef, Gerard P. J. Dijkema

A dynamic, interactive map has been developed of the life cycle of a number of metals, from mining through to minerals processing, metal production, product manufacturing, recovery and waste management. Whilst the existing metal process network and waste management infrastructure provide substantial scope for (product) design, these also limit change due to the complex interdependence of metals, both in production and recovery, and the strong path dependency of industry and infrastructure development. Therefore, models for dynamic simulation were constructed that allow the specification and evaluation of the metal process network and waste management infrastructure ‘products’ over a longer time span. The model has been constructed using a bottom-up approach, to enable assessment of the environmental aspects of metallurgy and to simulate changes in the system structure and technology, i.e. from reactor or individual process step up to integrated material cycles. The model comprises hierarchical mass balances and linear models of individual processes and sub-processes. Thus, at lower system aggregate levels an increasing level of technical detail is represented. Data reconciliation has been used literature data on process feed, products and residue composition to calculate representative and reliable split factors around each (sub-)process. World production figures on process capacity and recovery rates are be used to calculate the relative contribution of processes. The dynamic map is illustrated with a case on the introduction of lead-free solder.

Jan 1, 2003

By Narasimha Mangadoddy

The complex nature of multi-phase flow in dense medium cyclones has restricted plant operators and designers to rely on empirical equations for predicting the performance. A number of empirical cyclone models have been developed in the past (Wood, 1990; Dunglison, 2002). In recent years, this subject has been broached with computational fluid dynamics (CFD). Most of the CFD models have not considered the correct rheological behavior of magnetite medium while simulating the medium segregation inside the cyclone. These models mostly predict excessive underflow volumetric flow rates. In this paper simulations of magnetite medium in a dense medium cyclone, were conducted in FLUENT where the particle phases were simulated using the modified Mixture model. The turbulence was resolved using Large Eddy Simulation (LES) model. The rheological behavior of medium was considered in the form of Granular viscosity, Newtonian and Non-Newtonian models corrected with particle loadings and fraction of ultrafines. Multi-phase simulations using granular viscosity option although predict the overall split product medium densities reasonably close to experiments, the mixture viscosity values are restricted to substantially lower values, similar to water viscosity. Simulations using Newtonian viscosity model corrected with particle loading, and fine fraction below 53µm size is predicting overall mixture viscosity levels well over water viscosity levels, but under predicting the under flow the underflow medium density. Multi-phase simulations using Non-Newtonian Herschel-Buckley model, calibrated for superfine magnetite medium measured viscosities, is closely predicting the medium segregation with gamma ray tomography data. Overall predicted product medium densities, underflow volume split are close to the experimental data. This model is can be further used to simulate coal portioning and hence in developing new designs.

Sep 1, 2012

By Charlene Gokhale

Geopolymerisation has emerged during the last few years as an industrial and ecological approach to construction and waste management. By utilizing waste materials and their reactive properties, it is now possible to create geopolymers systems that not only mechanically durable enough to be used as construction materials but are also potential stable immobilisation systems for toxic waste. Previous studies by Van Jaarsveld et al. (1997) and Van Jaarsveld et al. (1998) have reported on the numerous applications of geopolymers in the immobilisation of toxic metals. Research into the possible utilisation of geopolymers as an encapsulation media for organic waste has however been rare. This paper therefore provides an insight into the possible utilisation of geopolymers as a binder for hazardous organic materials.

Jan 1, 2003