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Flotation Circuit Optimisation - Towards More Sustainable Practice

Sep 13, 2010

A rotating disc geometry was used to provide a uniformly accessible surface for a kinetic study of copper cementation with zinc in sulphate solution. For copper concentrations of the order of 10 p.p.m., a porous, adherent deposit is formed on the zinc surface and this has a significant influence on the reaction rate. When the specific mass of deposit is less than about O· 35 mg/cm2 the surface may be considered as smooth and the rate is described by simple convective counter diffusion of zinc and copper ions through a laminar diffusion boundary layer to the deposit-solution interface. In the presence of additional deposit, the diffusional mass transfer rate is increased by increased surface roughness.The rate under these conditions is first order, with the degree of enhancement independent of further increases in the specific deposit mass. The enhancement in rateis, however, directly related to the initial mass flux and the species involved in the reaction.Preliminary work showed the same mechanism to apply to cementation from chloride solution, solutions of high zinc concentration, and cementation of copper with iron..

Jan 1, 1970

By Uusna S, Canning R. G, Goodheart B. A

The development of a process for removal of iron oxides from ilmenite is outlined whereby the Ti02 content of Western Australian ilmenites can be upgraded from 55 to approximately 90 per cent. In the first stage, the iron oxides are reduced with solid carbon (coal) to metallic iron. Experimental reductions were carried out in crucibles, a fluidized bed, and a small pilot plant rotary kiln. The reduced ilmenite was then agitated in aerated water, in the presenceof catalysts, so that the iron "rusted" away from the ilmenite grains and the precipitated iron oxide was easily separable by decantation.The influence of variables on the rates of reduction and oxidation are discussed. The oxidation rate was examined for both the physical oxygen transfer characteristics and electrochemically by reference to Pourbaix diagrams, in which redox potential is plotted against solution pH.The upgraded ilmenite is expected to be an attractive material for pigment manufacture, and the iron oxide has prospects of being a marketable by-product. The process may possibly be applied to other ores.INTRODUCTIONThere are extensive deposits of ilmenitic beach sands, Le. iron titanium oxides of the general formula FeTi03, 'occurring in the lower south-west portion of Western Australia, and although there has been considerable commercial development, local producers face keen competition on a freight-cost basis. Thus the removal of the unwanted iron oxide constituent would have the double advantage of reducing the freight differential and presenting a more attractivematerial to pigment manufacturers.

Jan 1, 1965

Polyacrylamide flocculating agent has been used in the Leaching Division 'of the Risdon Works of the Electrolytic Zinc Company of Australasia Limited since October, 1960. The number of thickeners in the continuous thickening stage was thereby reduced from eight to three. There has been an increase of 25 per cent in throughput and a reduction of solids in thickener over-flow from 3-4 g/l. solids to 0·5 g Ir. solids. Reagent addition has been at the rate of 0·25 lb Separan NP10 per ton solids.Additionally there has been a gain of 3 per cent in current efficiency as the direct result of the addition of Separan NP10 to purified cadmium sulphate solution priOl; to electrolysis for cadmium metal. A smoother deposit has resulted and it has been possible to increase deposition time between strippings from 47 to 71 hr. However, there has been a slight increase in the lead content of the cadmium metal produced.The use of Separan NP10 to settle copper bearing residue in a batch process stage has resulted in a five-fold increase in settlement rate and a reduction in purification cycle time.INTRODUCTIONThe Electrolytic Zinc Company of Australasia Limited, Risdon, Tasmania, produces zinc by electrolysis of purified zinc sulphate solution, the raw material being zinc sulphide concentrate. In the Risdon process (Van Arsdale, 1953; J ohnstone, 1953; Ross, 1949) the compound zinc ferrite (ZnO.Fe203) is formed during the concentrate roasting stage. When the roasted material is leached in dilute sulphuric acid the zinc ferrite is not attacked, and it remains as part of the insoluble leach residue, of which it may form as much as two-thirds of the whole. The remainder is mainly unroasted zinc sulphide, unleached zinc oxide, lead sulphate, gypsum, silver compounds etc. The zinc in the residue may be 10 per cent of that in the original concentrate.Continuous thickeners are used to recover the valuable residue from the impure zinc sulphate solution and the...

Jan 1, 1963

By A B. Christie

Space-based synthetic aperture radar (SAR) data is becoming available over much of the world, includingNew Zealand. Radar imagery has a number of very advantageous features, including all-weather capability; it also has artifacts, such as layover, which require processing before these data may be used to best effect.   This paper gives an outline of SAR, details the image processing required, and discusses the use of the first New Zealand Japan Earth Resources-1 SAR data to aid geological mapping on the Coromandel Peninsula.

Jan 1, 1994

By P Rubie, B Morgan, J Russell, C Stewart

The relationship between efficient liner exchange, concentrator availability and concentrator profitability is well documented. Russell Mineral Equipment’s (RME) relationship with OZ Minerals’ Prominent Hill site personnel enabled sound collaboration between the two parties. Both parties worked together to identify the sources of productivity and efficiency loss and developed solutions to reverse them.This paper chronicles the identification of production inefficiencies and the resulting removal of mill relining from the critical path through the materialisation of mill relining optimisation strategies. Furthermore, this paper outlines other recent mill relining optimisation strategies developed by RME and tested at Prominent Hill, to demonstrate and achieve further productivity, efficiency and safety improvements.CITATION:Rubie, P, Russell, J, Morgan, B and Stewart, C, 2017. Mill relining optimisation – a story of collaboration, in Proceedings MetPlant 2017, pp 335–345 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 11, 2017

When a thin film of volatile matter is deposited under vacuum on a polished coal surface, and the coated surface is examined microscopically in plane-polarized reflected light, colour changes are observed which are characteristic of the various macerals present. The colour changes appear to be mainly due to interference between light reflected at the upper surface of the film and at the film!coal interface. A variety of source materials for the volatile matter required have been tested, including powdered bituminous coal, coal tars, boron oxide, and certain resins. Bituminous coal gave the best results.

Jan 1, 1970

Orebodies are defined in economic terms in that they must satisfy conditions determined by costs of mining, extraction and marketing before being so described. Despite this they have an essential chemical character as specialized products resulting from geochemical differentiation, and it is surprising that so little basic geochemical research has been carried out with respect to ore occurrence and that prospecting methods based on geochemical principles are not more widely applied.Many exploration geologists associate geochemistry with analytical techniques applied to the detection of dispersed traces of metals from actual orebodies. Geochemical research, applied to economic geology, goes far beyond this limited field and the purpose of this paper is to discuss aspects of such research and its use in formulating exploration principles.THE GEOCHEMICAL BACKGROUND TO MINERAL OCCURRENCE AND EXPLORATIONThe three aspects of economic mineral deposits to which geochemical research can be of use in determining ore guides are genesis, control of deposition and mode of dispersion from orebodies after emplacement. Prospecting for mineral deposits is primarily based on theories of ore occurrence which deal with the genetic and depositional influences controlling localization of ore. There are many such theories and they will not be discussed here as they have been adequately reviewed in geological publications. Some are based on differing argument concerning the same empirically observed associations of ore. In this respect it is perhaps fortunate that they are not always mutually exclusive as regards the...

Jan 1, 1960

Significance of Ion Interactions in Flotation in Saline and Brine Solutions

Sep 13, 2010

By Browner R, Lincoln F. J

The activity of silver in solid gold-silver alloys (electrum) has been measured with an electrochemical concentration cell based on the super ionic conductor silver-i3-alumina in the temperature range 200 to 80oaC.The measurements of the silver activity in the range 0.5 to 90.0 atom per eent silver were found to be highly reproducible although there is some disagreement with an earlier study which used a similar technique. At temperatures above 400° the silver activity exhibits both positive and negative deviations from ideality in the silver rich region.This method suggests a simple technique for the nondestructive determination of silver in electrum alloys.

Jan 1, 1983

It is the purpose of this paper to produce some evidence on the accuracy to be expected from normal assay procedure using the usual first class equipment, and to examine the effect that many assaying inaccuracies have on reported metallurgical recoveries.Generally speaking, the evaluation of the gold content of a mineral ore sample by the fire assay method is a relatively simple process.A weighed quantity of finely ground ore is fused with suitable fiuxes including litharge and a reducing agent to give a button of lead and a quantity of slag. The shower of lead produced by the reduction of the added litharge collects the gold and silver present in the ore, concentrating the values into the lead button.The button of lead, after separation from the slag, is, on heating in an absorbent cupel in a current of air, reoxidised to litharge and absorbed into the cupel leaving a gold and silver bead in the cupel. This bead' is heated in a solution of nitric acid to dissolve the silver, leaving the gold undissolved to be dried and weighed. Knowing the original weight of the ore and the weight of the gold prill the value of the ore is easily calculated.Summarising1. Fusion Process.-Ore plus fiuxes give a slag plus lead button.2. Cupellation Process.-Lead button is re-oxidised to litharge leaving a gold and silver bead.

Jan 1, 1952

By Mills R, Shannon W. T, Finch J

As an extension to investigations into methods of upgrading the Iitania content of ilmenite concentrate from beach sands using 100 g/day, a small pilot plant treating 23 kg/ day of ilmenite was used.In the pilot plant the iron oxide in the ilmenite was reduced to iron at 1200°C using carbon (coal/char) without melting the material, using a tunnel kiln heating cycle, the charges contained in saggars, The iron was then separated from the titania fraction by ball milling, wet magnetic separation, and screening. The resulting magnetic product was high in iron (about 80 per cent Fe) and the non-magnetic product high intitania (about 70 per cent TiO2).From this trial sufficient data were obtained to enable the preparation of a flow sheet for a plant producing 62,300 tonnes/year total products, and an estimate of costs to be made. This has shown that for an estimatedcapital expenditure of nearly $6,000,000 and annual production costs of about $4,000,000, the cost per tonne of high titania product (76 per cent TiO2) would be nearly $70.

Jan 1, 1977

This paper describes certain analytical methods used at the Rosepery Mine and Treatment Plant of the Electrolytic Zinc Co. of Australasia Ltd., which are not generally in use and may therefore be of more interest than a description of the normal routine methods which are used in most of the mining assay laboratories of the Commonwealth, and which have been published previously.The ore mined and treated at Rosebery is of a complex nature and demands closer control in the concentrating plant than is necessary on some other similar mining fields.It is necessary for the mill shift supervisors to keep constant control on the grade of lead and zinc concentrates produced on their respective shifts, and further, it is essential to maintain an economic compromise between grade of concentrates and the recovery of the particular concent:t:ate. This necessitates a more frequent check on concentrate grade tp.an is provided by the daily assays carried, out by the assay office. Rather than employ trained ,assayers on shift work, "quick methods" of analysis, which could be carried out by the operators, 'were adopted.'In such methods, it is desirable that the necessary manipulation should be reduced to the following:-a. Taking the sample, drying and mixing.b. Weighing the necessary amount of sample-for assay.c. Adding the reagents for use in the assay without change of beakers.d. Titration and calculation.Such a contraction of, the normal technique would be impracticable for many determinations, but in the case of lead...

Jan 1, 1949

The 8 ft by 91/2 ft drive which joined No. 7 Shaft with Browne Shaft on the 1,480 ft level was extended from both ends and met at a point approximately 12,000 ft from No. 7 (2,000 ft from Browne).The surveying required for this 2 1/2 mile haulage drive called for greater accuracy than was obtainable from South Mine standard methods. Procedures and devices from published information were tried and modified as required to suit local conditions. Several new methods were applied and improved as the drive advanced. The control of angular, linear and level measurements was perhaps considerably in excess of the requirements, but this was offset by abnormally large discrepancies resulting from shaft plumbing. The accuracy of the final breakthrough, although not to the standard desired, was sufficient to complete the connection without inconvenience and added cost.INTRODUCTIONThe acquisition of the Browne Shaft leases in January 1962 presented the management of Broken Hill South Limited with the problem of transporting ore from these leases to its mill. It was eventually decided that diesel locomotivehaulage through a 2t mile drive on the 1,480 ft level between the two mines was the best solution. The drive was advanced from both ends after Browne Shaft was deepened by 80 ft to reach the 1,480 ft level horizon. Each end advancedabout 15 ft/day with the miners working three 7 hr shifts. Blasting was restricted to the end of the shift.The survey work involved five shaft plumbings and 78 theodolite stations in a traverse, underground and surface,of more than 5 miles. Because of the exceptional length of the drive, an unusually high degree of reliability was required.The aim was for a maximum error at breakthrough of 1 ft 1 in 30,000, and to secure this, precise methods of linear measurement were necessary. Shaft plumbing in particular posed special difficulties.

Jan 1, 1965

By F E. Grader

A linear motor properly wound can serve as a mechanism for separating paramagnetic sulphide minerals, like pyrrhotite, from other sulphides and associated gangue minerals. The effectiveness of separation depends on the energising current of the separator, the frequency of the ac cycle, and the particle size of the minerals. The speed of travel of the minerals over the surface of the separator is also a function of particle size, and appears to be constant. The movement of pyrrhotite, magnetite and iron filings of comparable size fraction (150 ¦m +74 ¦m) on the linear motor surface has been observed using a cine camera. An attempt, has been made to give a theoretical basis for the movement of the particles by calculating the minimum electrical energy required to move them. Further, the rate of decay of magnetic moment of the particles has been estimated for magnetite and it has been found that sufficient residual magnetism existed in the particles after they had been exposed to the first half of an ac cycle for them to have like polarity with the second half of the cycle. The particles are therefore repelled from the motor surface every second half of the cycle. This repulsion due to remanent magnetism is the probable cause of particle movement over the linear motor surface.

Jan 1, 1980

By E Hollinger, J L. Mauk

Gold-silver mineralised veins at Favona, represent a new low-sulfidation epithermal vein discovery that occurs less than 1 km southeast of the world-class Waihi deposit. The Favona vein is hosted in Late Miocene andesitic lava flows and local dacitic tuffs that are intensely altered to quartz, adularia, chlorite, illite or interstratified illite-smectite (with ten to 70 per cent smectite) and pyrite. Adularia is widespread and envelops the veins, whereas chlorite and illite are mostly restricted to the footwall, and illite-smectite is confined to the hanging wall of the Favona vein. At shallow levels, kaolinite, cristobalite and rare alunite overprint the above minerals. A polymict hydrothermal breccia also occurs above and in the hanging wall of the Favona vein and contains clasts of altered andesite and various quartz vein fragments. Fluid inclusions in quartz veins sampled over a 300 m vertical interval have a homogenisation temperature range of 175¦ to 266¦C and dilute apparent salinities of 220¦C and grading into illite-smectite and local smectite which formed at 2. In contrast, late kaolinite, cristobalite and alunite formed from descending steam-heated acid-sulfate waters. Overall, the Favona and Waihi deposits are interpreted to have formed at similar levels in a single low relief hydrothermal system, with each deposit representing a distinct zone of fluid upflow.

Jan 1, 2002

The Acid Leaching Process for the Synthesis of Zeolitic Material from Paper Sludge Ash

Sep 13, 2010

By P M. Ashley, M Muller

Massive sulphide ZnPbCuAg deposits in the Halls Peak district of north-eastern NSW are of the submarine volcanogenic type. They occur as a number of small lenses enclosed in shale and epiclastic rocks, in association with felsic volcanics of early Permian age. The deposits crop out in steep terrain near the eastern edge of the New England plateau. Local relief of 700 m and slopes up to 50¦, coupled with an average annual rainfall of about 1000 mm has led to local severe land sliding in previously mined areas. Mining from the 1890s to the 1960s has also resulted in unconstrained drainage of heavy metal-bearing acid waters and physical dispersion of finer grained metalliferous sediments into the Chandler River. Waters emanating from the main landslide area, from underground workings and draining scattered unconfined stockpiles of massive sulphide ore have pH values of 3 to 4 and contain elevated contents of Zn, Cu, Pb, Cd and Fe. Chemical mobility of heavy metals into streams occurs under low pH conditions with Zn exhibiting the greatest dispersion. Increasing pH conditions downstream cause precipitation of Fe phases and coprecipitation of heavy metals. Physical dispersion of secondary metal-bearing minerals into the surrounding creeks results in wt% levels of Cu, Pb and Zn in the stream sediments thereby exceeding the regional background values by one to three orders of magnitude. Areas disturbed by mining are characterised by lack of vegetation, biomagnification of heavy metals into algae and lower plants, and partial recolonisation by metal-tolerant grass species (Snow Grass, Poa sieberana; Blady Grass, Lomandra longifolia). Rehabilitation measures will have to include landslide stabilisation, impervious sealing or removal of sulphidic materials, import of topsoil and revegetation by metal-tolerant, slow-growing native grass and shrub species.

Jan 1, 1995

This paper summarizes the progress of geological exploration at North Broken Hill Ltd.The North Mine orebodies occur in knots of minor folds on a simple limb structure which is itself highly folded, giving rise to two distinct orebodies pitching N. at av. 42° down to 2,920-ft. level, where the pitch steepens to near vertical as a result of complementary shear movement on the Globe-Vauxhall Crush Zone.The lack of adequate marker beds and top and bottom relations makes the resolving of the complex structural environment of the orebodies most difficult.To test the deeper ground of each side of the De Bavay Fault on the 2,600-ft. level the footwall drive was extended 3,556 feet and over 20,000 ft. of drilling completed from three transverse fans, only one of which intersected the orebodies due to steepening of pitch.The problem of locating the North Mine orebodies N. of the DeBavay Fault remains speculative because the exact position of them S. of the fault is still unknown. Exploration beyond the fault in the search for ore had two lines of mineralization to consider, an eastern one through Cosgroves-Round Hill, long regarded as the continuation of the main lode, and a western one passing through Silver Hill Silver Peak.From surface 45,000 ft. of drilling was completed in five sections, establishing that the structure was dominantly synclinal with a flatdipping E. limb, the W. limb and adjoining structures being involved in the Globe-Vauxhall Crush Zone. Mineralization, though weak, was remarkably persistent but the economic mineralization exposed at surface has not persisted with any continuity.Deep exploratory drilling below the bottom level (3,370 ft.) has established high-grade ore to a depth of 4,095 ft. and also has proved its existence within the Globe-Vauxhall Crush Zone.INTRODUCTIONThis paper summarizes the progress of geological exploration at North Broken Hill Limited from the inception of the Geological Department in 1941 until the end of 1955. The writer has drawn freely on departmental records for the period prior to 1947.

Jan 1, 1956

The sulphide ores of the principal lodes of the Boulder Mines are mainly composed of a schistose guess with a varying proportion of silica and lime, containing tellurides of gold, silver and mercury, associated with iron pyrites. It is a great difficultyto obtain pure and homogeneous samples of the tellurides for analysis, and from a number of tests made with excellent specimens it was found hardly possible to procure two to agree in analysis, the precious metals being found to be combinedwith tellurium in most varying proportions indeed, a close inspection of a partially crushed specimen will reveal, even to the naked eye, the various shades of colour characteristic...

Jan 1, 1901