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Modelling of Synergistic Effect of Cyanex 302 and D2EHPA in Zinc Solvent Extraction A comprehensive model is presented to predict the synergistic effect of D2EHPA and Cyanex 302 on co-extraction of zinc and manganese. The experimental results indicated that pH, temperature and the extractants ratio have strong effects on the extraction process. Correlations were proposed to predict the distribution coefficient of zinc and manganese between two phases at different conditions by multiple linear regression. The correlations were simplified by eliminating less important terms by analysis of variance. Optimum conditions (ie pH, temperature, extractants ratio and aqueous to oil phase volumetric ratio) for obtaining maximum separation of zinc from manganese at different zinc concentrations and number of extraction stages were determined. For finding the optimum condition genetic algorithm was used. Comparison the model estimations and the experimental data show that the presented model has good ability to predict the behaviours of zinc extraction system over Cyanex 302 and D2EHPA.

Sep 13, 2010

By Urabe T

In June 1989 a diving cruise of the French submersible Nautile has been carried out on the North Fiji basin spreading ridge. The objective of the cruise was the geological and geochemical study of the active spreading axis and associated hydrothermalism processes. This operation was the third cruise of the French-Japanese STARMER project following two cruises of the R/V Kaiyo in 1987 and 1988.INTRODUCTIONAfter the Seapso III cruise (Auzende et al., 1986, 1988a and b) of the R/V Jean Charcot in 1985, the objective of the Kaiyo 87 and 88 cruises was the complementary Seabeam mapping of the North Fiji Basin spreading axis between WS and 22'S and a systematic sampling (water and rocks) and deep towing (TV and photos) at about every ten milles along the axis.

Jan 1, 1990

By Isokangas T. A

With some two-thirds of the production exported, coal mining prac- tices of the last few years in Australia have been much influenced by the decline in the price received. It became essential to improve efficiency and rationalise operations. Trends in underground practice vary. On the one hand many additional longwalls have been installed and most recently the results achieved by them have shown a significant up-turn; this may be correlated more with increases in equipment capacity than with utilisation which has altered little during the past six years. Varied constraints remain affecting cur- rent and future longwall operations. On the other hand a number of mines have been closed whilst others have sought to improve results by various installations including miniwalls, shortwalls, and use of continuous haulage and mobile breaker line sup- ports. All mines continue to review working practices.

Jan 1, 1988

By Hinkley JT, Smitham JB, Nicol SK

Historical investigations of mineral flotation have highlighted the many factors which affect flotation. Some of these are related to the mineral, its degree of liberation (however defined), solution chemistry and flotation reagents. The complexity of the interactions between these factors often leads to uncertainty over whether the final grade/recovery results obtained in either laboratory or pilot scale tests are in fact the maximum recovery at a specific grade. The reason for this is that there has not previously been a general technique for establishing the floatability of an ore. This study describes the further development of the 'tree' flotation technique for minerals other than coal, and in particular its application to iron ores. Oxides have been chosen as a system of intermediate complexity between the simple coal system and sulphide minerals to illustrate the principles and develop the concepts. The 'tree' flotation procedure consists of the progressive flotation to completion of successive froth products, followed by reflotation to remove entrained material. It therefore represents an 'equilibrium' approach to floatability rather than a kinetic approach. By ordering the various products and tails in order of increasing grade, a cumulative curve of grade and recovery can be constructed against which an isolated batch or plant result on the same ore can be compared. In this investigation, a Jaspilitic iron ore was tested at various grind sizes to determine the 'best' flotation grade-recovery that could be obtained with a given set of reagent conditions. The separation characteristics of a process are best measured on a system which contains particles which behave as 'middlings' with respect to the process in question. For this reason a natural ore was chosen in preference to model systems in order to relate more readily to plant situations.

Jan 1, 1993

By Churchill J

A suite of software programs has been written to provide the field engineer or geologist with the capability to collect and store data directly into small, portable handheld computers. This allows the engineer and geologist to collect data in a more efficient manner as the data is collected in sequence and is verified at the time. Typical applications for this software include geological and geophysical logging, trucking surveys, mine surveying, condition monitoring, ventilation surveys and maintenance systems. The software allows the user to construct his own electronic notebook by structuring data input to the computer in a similar manner as is now done on pre-printed forms. The user can store all valid entry codes or numeric ranges in a dictionary and all data inputs made are validated against this dictionary. Once constructed the user may call the electronic data sheet into the unit and collect data which will be stored into the unit which has the memory capacity to record data for up to periods of 60 hours. The data can then be automatically transferred to mini/microcomputers for immediate analysis and report generation. The software may be used on a variety of handheld computers.However the generally rugged environments found in the mining industry limit the choices. In particular the authors have selected a unit weighing a little over one kilogram, which is rugged enough to fall off an underground survey vehicle, and survive when accidentally immersed in water,without losing data. This paper describes the software developments in detail. The project development work to produce this system has been funded by a grant from the Australian Mineral Industries Research Association and is supported by a number of large Australian mining companies.

Jan 1, 1986

By Sun Y. L, Jiang J. J, Lu S. L

A distinguishing feature of tunnels in squeezing rocks is that a large deformation of the surrounding rocks takes place slowly and gradually, often called squeezing phenomenon. It is different from the rocksbursting phenomenon during which the deformation of tunnels occurs instantaneously when the resulting stresses exceed the strength of the surrounding rocks. The squeezing phenomenon has received great attention in the field of rock mechanics and tunnelling recently. The mechanism and various factors related to the large deformation and failure of tunnels in squeezing rocks are discussed in this paper on the basis of field investigations and laboratory model tests. The relationship between the deformation of surrounding rocks and support of the tunnels in squeezing rocks is presented in the form of numerical modelling.

Jan 1, 1995

On the face of it this is an easily answered question. Modern technology and life as we know it today would be impossible without industrial minerals and the responsible utilisation of mineral resources is essential for the economic wellbeing of the nation. The quarrying industry supplies a high percentage of the industrial minerals used in New Zealand and our role therefore, is to ensure a constant supply of high quality roading and concrete aggregates so that society and the community as a whole can develop. We must do this in a manner which causes the least possible disruption to members of the community, which efficiently utilises all the valuable resources, which causes as little pollution as possible and last but by no means least, creates realistic profit for the operator. It is only by achieving a reasonable profit that we are able to continue in business and therefore play our part in the development of the country. Unfortunately, quarries have a poor image and are not generally popular, as on the whole, they are noisy, dirty and dusty and attract large trucks which create traffic problems. Judging by the amount of restrictive legislation with which we have to comply today, not even government or the local authorities want quarries which presents the industry with some serious problems, some of which will be outlined in this paper.

Jan 1, 1978

Roasting of zinc concentrate at the Risdon Works of the Electrolytic Zinc Company of Australasia Limited, (E.Z.), is carried out in two fluid bed roasters capable of treating 450000 tonne/yr, or sufficient for the output of 220000 tonne of salable zinc. The furnaces were constructed by Lurgi, Australia, to the basic design developed by Vieille Montagne Company of Balen, Belgium. The advantages of fluid bed roasting include a higher metallurgical efficiency in sulphur oxidation from a feed which does not require any pre-grinding, mechanical reliabil- ity through the absence of any moving parts within the furnace and the capability of being scaled up to a large unit.

Jan 1, 1977

By Kim M

Mukuk gold mine in South Korea produces a pyrite concentrate containing gold associated with arsenopyrite as a gangue mineral. The effects of Portland cement as a depressant on the flotability of arsenopyrite were studied to improve the separation of arsenopyrite from pyrite concentrate containing gold. A series of the fundamental flotation tests were performed using Portland cement as a function of pH and concentration of the collector. Flotation recovery of pyrite and arsenopyrite in the fundamental tests with amyl xanthate showed that arsenopyrite was depressed by the addition of a moderate amount of Portland cement, but pyrite was not depressed by it. In the flotation tests of the artificial mixture samples with arsenopyrite and pyrite, following pH were adjusted to be 10.5 by Portland cement, different amount of amyl xanthate was added. The results from these studies showed that flotation recovery of pyrite was 100 per cent under the condition of some addition of amyl xanthate, but arsenopyrite was not floating at all. Portland cement shows remarkable depression of galena, but its effect on the flotability of chalcopyrite is not as clear. In the pulp under Portland cement addition, chalcopyrite can be easily activated by the addition of sodium bisulphite, whereas galena is depressed more effectively. From the batch flotation tests with the pyrite concentrate, the galena concentrate and the Cu-Pb bulk concentrate from the mines, it was confirmed that the results of the batch flotation tests agree with the results of the fundamental flotation tests. The effects of depression by Portland cement on pyrrhotite, marmatite and stibnite are also discussed briefly.

Jan 1, 1993

Over the last thirty years production of heavy minerals from Australian deposits has dominated the world market. The main incentive has been to suoply the raw material for titanium dioxide based pigments. These ~ninerals include ilmenite, rutile, leticoxene and more recently, synthetic rutile. Inevitably the viabilit/ of developing placer type deposits has seen influenced by other heavy minerals present, such as zircon and monazite, but these have been of secondary importance. For most of the sixties and seventies, Australia supplied the 'najority of free world rutile and zircon, and a large proportion of the ilmenite. With the run-down of rutile- rich reserves in eastern Australia, the emphasis has s:iifted in several countries, including Australia, to fill }the gap with i l Wen i to and its derivatives, leucoxene, synthetic rutile and titanium rich slag. over the next 15 - 20 years, as high grade beach placers in Western Australia are mined out, less traditional sources for mineral sands products will be opened up. Low grade placers (particularly those dominated by ilmenite) will be reassessed in Australia, U.S.A., Africa and Asia, and exploration will shift from beach and dune environment, to heavy mineral concentrations in alluvials, lake deposits and continental shelf deposits. At the same time, production of anatase and bastnaesite will be expanded, as required, from the huge resources contained in carbonatites in 3razil, U.S.A. and China.

Jan 1, 1986

By R Farana

The future challenges in mining instrumentation, mainly on future intelligent mines, are to continue providing instruments with the highest level of reliability at the lowest possible cost, and also to take advantage of technology existing in other industries and to adapt it to the mining context. New wireless instruments (smart sensors, smart actuators, smart controllers) would also be very useful, as well as instruments fully adapted to the monitoring of large movements that are observed, in both underground and open pit mines. Mining instrumentation is found to various degrees in most mines, both open pit and underground. Smart mining instruments present a certain number of aspects specific to the environment in which the instruments are installed. Namely, the instruments can be installed either for short-term or long-term purposes. The mining industry is always looking for useful instruments that can provide relevant information on ground behaviour adjacent to mining stopes or permanent infrastructure. The instruments must meet the various criteria, and must also evolve with the new mining technologies that are continuously being implemented. A strong collaboration between the mining industry, research organisations, and instrument manufacturers is the key to meeting these objectives. This contribution describes the current trends on smart sensors and smart instrumentation with Wireless LAN support.

Jan 1, 2003

By J L. Edwards

High resolution, acoustic scanning technology has emerged in recent years as a powerful wireline tool for identifying the occurrence and orientation of structures and borehole breakout û the latter being a strong indicator of horizontal stress directions. While other wireline techniques such as dip metre and calliper logging can provide some of these data in a fairly rudimentary way, the quality and ease of interpretation of acoustic scanner logs provides a level of detail that significantly enhances the risk profile of the analysis which more than compensates for their additional upfront cost (MacGregor, 2002). As is often the case with such technology it is one thing to generate a data set that describes the attributes of the various features apparent in a log, and another to be able to analyse those data in such a way that their individual and collective impact on mine planning issues can be readily assessed (MacGregor, 2003). This paper describes a process for the interactive manipulation and visualisation of joint and breakout data to enable them to be effectively included in the mine design process.

Jan 1, 2009

Silver and gold bearing ore from the Palmarejo mine, located within the Mexican state of Chihuahua, contains a complex mix of electrum, native silver, silver sulfides and silver chlorides. This paper presents a case study that describes the selection, development and engineering of a tailored process plant for the recovery of silver and gold from this ore. Process circuit feasibility study modelling, metallurgical test work and engineering studies are outlined. Options considered to optimise the recovery of the contained silver and gold are compared, based upon cost, operability, recovery and engineering aspects. Concentration by flotation was found to be the preferred primary recovery route. Intensive leaching of the flotation concentrate resulted in solution grades sufficient to allow direct electrowinning to be evaluated against the more traditional Merrill Crowe process. The flotation tailings stream is processed through a separate leaching stage as there is sufficient economic metal extractable from this stream. The processing flow sheet, which is designed to maximise the recovery from both the flotation concentrate and tailings, and to utilise a common metal production facility, is presented.

Jan 1, 2009

By Yokozawa K, Yamamoto T, Kameoka Y

Japan Construction Method and Machinery Research Institute has been conducting various field surveys of tunnel works and other excavation works, and the cost and efficiency of these two excavation methods have been studied. Based on these data, the costs of blasting excavation and mechanical excavation represented by roadheaders were calculated. The costs were calculated and compared for rocks of various hardness. When the total construction cost is considered, the degree of overbreak becomes one of the most influencial factors, because the overbreak area must be filled up with expensive shotcrete in NATM. So, in the next step, the relation between the excavation costs considering overbreak and the rock hardness was studied using the data on overbreak obtained by the field survey.

Jan 1, 1987

Accidents in open pit mining have a high cost in lost time of person- nel, damage to equipment and installations, and lost production. The realities of export competition require that Mine Management sig- nificantly reduce the costs associated with accidents and workplace ill-health. Newer management approaches are proving effective in reducing the Total Cost of Risk through a strucured Occupational Health and Safety Programme exhibiting the following features: ò Formal Company Policy ò Accountability for OH&S performance clearly designated to each level of management and supervision ò Effective utilisation of a Mine Occupational Health and Safety Co- Ordinator and a Mine Occupational Health and Safety Adviser ò Development of realistic OH&S Objectives ò Training of Management, Supervision and Workforce in Occupa- tional Health and Safety ò Development and adoption of Safe Work Practices and Procedures ò Effective employee selection procedures, control of Contractors ò Monitoring of the health of the workforce ò Collection, recording and distributing information on all Mine inci- dents, accidents, injuries and damage ò Ensuring that the Mine environment is healthy and safe ò Effective Emergency Procedures to deal with injury, fire, rescue and other situations of risk ò Controlling those Mine hazards which cannot be removed ò Adopting a high standard of Occupational Rehabilitation ò On-going visible Management participation in the programme to ensure that momentum is developed and maintained. This approach requires that Occupational Health and Safety be given equal status with product quality, maintenance of plant and output per- formance; its implementation is rewarded with improved morale and major cost reductions.

Jan 1, 1989

By S Holmes

Solid Energy New Zealand operates the Stockton Opencast Coal Mine, a unique deposit consisting of high quality hard coking and thermal coals. Stockton's uniqueness includes high variability of the shipment specifications, strict quality constraints, minimal stockpiling capacity in the coal transport chain and the variability of coal quality both vertically within the seam and laterally across the deposit. The process of resource proving and modelling results in a high level of understanding of the deposit to allow detailed planning to be undertaken. The use of computer aided mine planning tools is an important component of the mine planning at Stockton. Detailed planning is implemented in the field through selective mining practices and monitoring to minimise dilution and maximise recovery of the coal resource. The quality variability in the coal, the æjust in timeÆ approach of the coal transport chain and markedly varying quality specifications from shipment to shipment requires a large coal inventory and the mine to be driven by quality constraints rather than material movement capacities.

Jan 1, 2003

Every estimate of ore reserves necessarily contains an assumption in regard to the specific gravity of the ore. This assumed figure may be based on experimental data, on textbook data, or on a reconciliation of past tonnage estimates and production figures. Not infrequently it is simply a guess - shrewd or otherwise.Errors in the density factor are not likely to be serious in gold-quartz mines-or, at least, not so serious as in base metal mines. It is to the closer determination of ore density in the latter that this paper is devoted. Moreover, the remarks apply to ores which show no appreciable pore space.Not many ore bodies are sufficiently homogeneous to allow of a truly representative factor being obtained by the simple testing of a few specimens of ore, or by the weighing, after breaking, of a carefully measured block. The empirical figure derived from a comparison of past ore reserves and actual production can never truly describe conditions other than those now past; no real link with ore as yet unmined is provided. The dilution of heavy ore by waste is not exposed by this method, but is effectively cloaked. Anyerrors in past estimations of ore reserves are transmitted, by way of the density factor, as a source of error in all future estimates.ObjectIons may be raised to the practice of weighing measured blocks of ore in the case of any but a very homogeneous ore body. Even then, the exact composition of the block weighed, and an indication of whether its moisture content is representative of the whole, are difficult to determine.

Jan 1, 1940

Mining of the silver-lead-zinc orebodies at the George Fisher Mine officially started in 2000. A review of mining performance to date shows that many of the extracted primary stopes have experienced some degree of hangingwall dilution. The degree of hangingwall failure in the stopes became progressively more extensive throughout mining of the orebodies in 2001 and 2002, culminating in the unplanned catastrophic failure of the 744D stope in which the ore between 13C (2683RL) and 12L (2714RL) sublevels caved into the previously mined cavity between 13L (2654RL) and 13C sublevels. This was followed several months later by another unplanned caving event in a nearby stope, 740D. As a direct result of these unplanned failures it was decided to mine the stopes with a smaller span than had been previously planned and in a primary-secondary pyramidal stoping sequence. To limit the exposure of the stope hangingwall, a hangingwall drive is no longer developed and therefore geologists no longer have access to the detailed geological information that this provided. Geologists at George Fisher Mine have had to be adaptable and flexible in response to these proposed changes and rely more on data from drilling than mapping for their geological interpretation. The result is that the drilling cycle has become much more critical in the planning process.

Jan 1, 2003

By Willis G. M

Preliminary experiments have shown that, when used in a fusedchloride electrolyte, titanium carbide anodes dissolve yielding lower titanium chlorides which nlay be electrolysed in situ to produce a cathode deposit of pure titanium metal. The anode residues are easily withdrawn from the cell. Further experiments have established the operating conditions for maximum efficiency in the process.The process is essentially two-stage, viz.: (1) titanium carbide production, (2) electrolysis producing metal. Power requirements appear to be moderate and this fact, combine·d with the simplicity of the process make it attractive as a possible method for the production of titanium.INTRODUCTIONDue to the high reactivity of titanium and its, affinity for oxygen and nitrogen, the extraction of this metal generally involves the use of halide. compounds as intermediates. For instance, magnesium reduction of titanium tetrachloride is the basis of the well established Kroll process and electrolysis of the lower chlorides in a molten salt bath has been proposed by Cordner and Worner (1951, p. 358) and others (Brenner and Senderoff, 1952, 223C; The TitaI Company (Inc.), 1952) as means of production of the metal. Thedifficulty of preparation of these compounds prompted a search for an alternative extraction process. The fact that aluminium, an equally reactive metal, has been prepared by electrolysis using aluminium alloy anodes suggested the possibility of a similar process for titanium production.The Titan Company (Inc.) (1952) has patented the use of crude titanium metal anode, but it was thought possible that a metallic compound, such as the carbide, could be used for this purpose. Although Lorenz and Kaufler (1909) suggested the use of carbide anodes for metal production, no...

Jan 1, 1956

By J J. Cilliers, K Hadler

Froth structure and stability are known to play important roles in determining mineral flotation recovery and selectivity. However, measuring froth stability in a consistent manner remains a significant challenge, especially at an industrial scale. Following preliminary tests on a copper concentration plant, a quantitative dynamic stability measure is investigated in this study in order to extend the results over a wider range of conditions and on a different orebody. The technique is based on the Bikerman foam test and uses a non-overflowing froth column to quantify froth stability. Experiments were carried out using an automated version of the froth stability column under different operating conditions. Air flowrate was the key operating variable. Tests were reproduced on a single flotation cell of a Platinum Group Metals concentrator. The froth stability factor, , was measured for each operating condition, and compared with the air recovery in the cell, , which was measured using image analysis. The froth stability column results gave the same trends as image analysis. In particular the froth stability factor was found to be linearly related to the actual fraction of air overflowing the cell. The metallurgical results clearly indicated that changes in air flowrate result in variations in flotation performance that can be attributed to changes in froth stability. The results showed that high froth stability conditions occur at intermediate air flowrates, and result in improved flotation performance. It is found that the froth stability column is a simple, cost-effective and reliable method for quantifying froth stability, and for indicating changes in flotation performance.

Jan 1, 2005