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By R M. Hough, G Duclaux, M A. Pearce, M F. Gazley

"An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation. Microcharacterisation, such as that described in this paper, provides understanding of a mineral system at multiple scales, and understanding microscale variations is the key to understanding the large-scale variations in a mineral system. More than 50 high-grade lode samples from across Plutonic Gold Mine (Plutonic), Marymia Inlier, Western Australia were analysed by a variety of techniques, including micro X-ray fluorescence (µXRF) mapping, micro X-ray computed tomography (µCT), scanning electron microscopy (SEM), field emission gun SEM, electron back-scatter detector (EBSD), proton-induced X-ray emission microprobe and synchrotron XRF mapping. These data demonstrate that competency contrasts are the key to governing the location of Au mineralisation at Plutonic. Micro CT imaging of high-grade samples shows the Au filling in voids and pore-space in the rock, after having travelled along more permeable layers and already existing or reaction-induced pores formed during hydrothermal circulation. Using 3D visualisation, the Au is seen to form a connected network that appears undisturbed at the scale of the samples, and a high-grade Au deposition event was one of the last events to affect the rock. This interpretation is supported by SEM analyses on high-grade samples that reveal calc-silicate (epidote-clinozoisite) alteration that is not present in lower Au grade samples, which are typically dominated by potassic alteration, and that sulfides are typically less abundant close to the Au. The replacement of biotite by chlorite is an alteration associated with the high-grade Au-mineralising fluid. Gold is coarsest where Au particles are located on the margins of minerals, typically sulfide and quartz grains, suggesting the importance of rheological contrast at the microscale. Furthermore, EBSD data reveals that Au is undeformed and overprints peak metamorphic and retrograde minerals. Data confirm recent deposit-scale observations, suggesting that deposition of high-grade, visible Au was related to a hydrothermal fluid circulation event late in the geological history of Plutonic.CITATION:Gazley, M F, Duclaux, G, Fisher, L A, Hough, R M and Pearce, M A, 2015. High-resolution characterisation of gold mineralisation at Plutonic Gold Mine, Western Australia – evidence for the late-stage deposition of high-grade gold , in Proceedings PACRIM 2015 Congress, pp 51–58 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 18, 2015

This paper describes the principle of cut-and-break rock excavation, in which rock is first undercut, and the undercut material is subsequently broken free by a wedging action. The current work on cut-and-break using the large rock cutting test rig at the Centre for Mining Technology and Equipment (CMTE) is outlined, and suggestions are made as to the potential advantages of cut-and-break roadheading, particularly in excavating short tunnels in hard rock in an urban environment.

Jan 1, 1993

By Singh T, Singh D. P

India has limited resources of coking coal. Most of the coking coal seams are located in Jharia Coalfield. These seams were worked in the past by the bord and pillar system in a haphazard manner, which has resulted in honeycombs of old working. Most of such areas are under fire. In order to meet the demand of coking coal in the 21st century, it is essential that the coal locked due to old underground workings is recovered fully by conducting opencast mining to an ultimate depth of 500 m. The major problem envisaged in conducting opencast mining in such areas will be the stability of pit slopes over voids and the behaviour of subsided material in the pit slopes. An attempt has been made to simulate this complex situation from a specific section of the rockmass of a mine in an equivalent material (EM) model. The old workings existing in upper coal seam (V) were simulated by developing staggered bord and pillar workings in two sections and depillaring them. Opencast mining was conducted for recovery of coal locked due to irregular working in coal seam V. The slope instability caused by intersection of the slope with the void, during frontal working (by shovel-dumper combination) was observed in various situations. In this paper, the technique adopted for simulation of a 125 m thick section of rockmass in an EM model is outlined. Adverse effects of staggered workings and

Jan 1, 1988

In South African gold mines, the types of material requiring transportation to the stoping areas include timber packs, explosives, hydraulic rock props, scrapers, scraper winches, pipes, pumps and backfill material (in areas where backfill is being used). Currently timber packs are broken down to their basic components (log and brick) and are transported into the stope by means of either monowinches or a combination of monowinch and scraper winch. Other materials, such as explosives, hydraulic rock props, scrapers, scraper winches, pipes, pumps and backfill material must be transported by other means, usually by hand or, in the case of heavier items, by chain blocks. With the drive to increase stope advance rates and the rise in the number of miners with HIV/AIDS, there is a need in the South African gold mining industry for an improved material handling system. To meet future requirements, material handling systems should assist miners to transport materials quickly and efficiently. Furthermore, it must be financially viable and economically competitive with current material handling systems. This paper looks at the in-stope material handling efficiency of current monowinch systems and provides solutions to improve efficiency. In addition, the use of in-stope monorails are reviewed and the possible scenarios that will substantiate the use of monorail systems are discussed.

Jan 1, 2003

By Smith CB, Boxer GL

The Argyle diamond deposits in the East Kimberley were found as a result of a long term exploration programme, begun in 1972 by the Kalumburu Joint Venture (KJV), to search for diamonds on the Kimberley craton. When CRA Exploration Pty. Limited joined the KJV in 1976, it was re-named the Ashton Joint Venture (AJV). The Kimberley craton was considered prospective by analogy with structural settings of diamondiferous kimberlites in Africa. Diamonds were found during regional drainage sampling in Smoke Creek in late 1979, which led directly to the discovery of the rich Argyle lamproite diatreme (AK1) and associated alluvial deposits of Smoke and Limestone Creeks. The diatreme intruded into quartzites, sandstones and shales of Adelaidean age, and consists predominantly of lapilli ash tuff, with minor coarse and fine ash tuffs, 'non-sandy tuff' and olivine lamproite dykes. Erosion of the diatreme has produced the alluvial deposits of Smoke Creek and Limestone Creek to the north and east. Argyle diamonds are of predominately industrial quality, and the typical diamond is a brown, irregularly shaped, frosted, heavily resorbed form with abundant graphite inclusions, well developed etch channels and prominent hexagonal surface depressions. The pre-feasibility evaluation of AK1 comprised diamond drilling, surface and underground sampling, metallurgical sampling, marketing studies and ore reserve estimation. The proven AK1 ore reserve is 61Mtonne at 6.8ct/tonne. Evaluation of the alluvial deposits gave results of Upper Smoke Creek, 580 000 tonne at 4.6ct/tonne and Limestone Creek, 1.7Mtonne at 3.5ct/tonne. Commercial production from the two alluvial deposits began in 1983 with production for the year reaching 6.2 Mct. Mining of the alluvial deposits at three to five Mct/year is proposed to continue until the start of mining of the AK1 deposit in late 1985 or early 1986 at which time a new processing plant and associated infra- structure will have been constructed adjacent to the AKl deposit in the Limestone Creek area. Production is planned at three Mtonne/year, producing 25Mct/year, which will make Western Australia the largest producer of natural diamond (by weight) in the world.

Jan 1, 1984

Water retention, water loss and delay in tailings storage rehabilitation are major challenges for many Coal Mines. Work by Stewart, Backer and Busch in the early 1980s suggested that there were improvements to be made in tailings dewatering and density by the addition of flocculant. This prompted ACARP, in cooperation with Bulga Coal Management (Xstrata), to initiate a research project investigating the impact of flocculant addition on tailings deposition density, water retention and the tendency for tailings to form surface crusts suitable for subsequent rehabilitation. A polyacrylamide-based flocculant (200 - 250 g/tds) was injected into the tailings line immediately prior to disposal into the impoundment area. The flocculated slurry rapidly released clear water and created a beach due to the immediate increase in deposition density. The deposition density increased from 35 per cent w/w to 61 per cent w/w solids within 24 hours and continued to increase to 75 per cent, seven days after treatment. The water capture at the tailings storage facility improved by more than 90 per cent; water which would otherwise be lost from the circuit through retention and evaporation. The impoundment capacity had nearly tripled due to the improvement in initial deposition density from 420 kg/m3 up to 1163 kg/m3. Four weeks after disposal surface crusts were forming on the storage facility, suggesting that there would be less delay between cessation and tailings storage rehabilitation.

Jan 1, 2008

The exploration and mining risks are investigated and compared to the risks of smelting, secondary processing and other normal industrial activities. This study concentrates on the risk before, or at the investment decision. Internal and external risks are distinguished. Internal risks are the risks inherent in every engineering design and common to all projects. The main external risks are the financial risk, changes in prices, location problems and geological factors. Financial risks concern every capital-intensive and export-oriented project and cannot be considered as typical mining risks. Changes in prices, i.e. the market risk, concern every industry using raw materials, but the market risk is especially accentuated in the mining industry. Problems of location and infrastructure are normally more significant in mining than in other projects, and geological risks are unique to mining. All these risks associated with mining projects combine to form a risk at least twice as high as that for other normal industrial activities. Within the range of profitability of mines, which on average is the same as in the manufacturing industry, only a few highly profitable mines exist. These few mines are the sole reward for the high risks taken.

Jan 1, 1986

By D Thomas, B Gallagher

Valuable data for geotechnical interpretation and integration into effective Australian underground mine planning may often be available, yet is not always fully appreciated or utilised, particularly in the early stages of mine planning or in due diligence studies. There may be considerable benefits associated with early prioritisation of geotechnical evaluation and impact on mine planning. Unidentified, misinterpreted, or ill-defined adverse geological and related geotechnical resource characteristics can pose significant business risk to underground coal projects and operations. Preliminary resource definition in the early conceptual mine planning stages attributes significant focus (entirely warranted) on resource quality and structural geology constraints. Yet detailed geotechnical data analysis and interpretation, which may have a substantial down stream impact and sensitivity with respect to future mine planning strategies, at times is given lower priority, or scoped and resourced in the later stages of a bankable feasibility study. Through extensive mine planning experience and observation of downstream process impacts, it has been found there is often data available for geotechnical analysis that does not readily stand out or is not adequately understood or utilised, available at the early (conceptual) stages of mine planning. Part of the issue may be that exploration geologists are not necessarily experienced geotechnical engineers and do not necessarily recognise or understand all important parameters. Subject to appropriate application of experienced professionals data can be manipulated to provide key geotechnical hazard assessment at minimal cost, and provide a framework for understanding and optimising the mine planning process. Although there is no single prescribed strategy for resource evaluation from a geotechnical perspective, potential business risks and mitigation approaches can and should be adopted at the conceptual mine planning stage. There has been a recent focus in the metals industry to provide a reporting framework for geotechnical classification of mining projects. This paper outlines the strategies and gives examples of key analyses adopted in mine planning and discusses the relative merits of adopting a reporting framework as a tool for geotechnical classification in mine planning.

Jan 1, 2005

By M DellÆAmico, K Vining

The iron blast furnace is the most widely used and efficient producer of liquid iron; however, emissions from sintering and coking cause environmental pressure for the integrated steel works. The combustion of coke fines (breeze) during sintering contributes to greenhouse gases (GHG) (eg carbon dioxide) and is a source of SOx and NOx emissions. Coking capacity is also constrained by environmental concerns and economic factors, such as increased coke consumption, and short supply is leading to high prices. Improved coking practices, which result in reduced production of fines, are also contributing to the tight availability of breeze for sintering. This combination of factors presents an opportunity to consider alternatives to coke as a fuel for sintering. CSIRO Minerals has been investigating the use of wood biomass/char as a substitute for coke during sintering. Wood biomass, or char produced from it, is an attractive carbon source as carbon dioxide liberated during combustion can be sequestered back into growing biomass. It has great potential to reduce the emissions from integrated steelworks and improve their environmental acceptability. Harvested biomass/char is also a renewable and sustainable resource and can be integrated with good land management practices such as remediation of salinity affected land. Weeds, especially woody weeds, can also be used as a source of biomass for charcoal, and integrating char production with weed management can help address a pressing environmental issue in Australia. Previous reported preliminary testwork indicated that the use of Red Gum char as a replacement for coke resulted in a product sinter of comparable quality, improvements in productivity and significant reductions in SOx and NOx emissions. In the latest testwork, CSIRO has examined the properties of a range of potential charcoals, and has conducted a further series of granulation and small-scale sintering trials with them in simulated Japanese Steel Mill iron ore blends. Sinter fuels characterised and evaluated include industry sourced coke breeze, commercially available wood char and a charcoal from prickly acacia (acacia nilotica). Prickly acacia has been declared a noxious weed, is widespread in Australia, and is classified as a æWeed of National SignificanceÆ. The results presented in this paper support the notion that charcoal outperforms coke in many aspects of iron ore sintering and factoring in environmental considerations makes the switch to charcoal even more favourable.

Jan 1, 2005

The Permian rocks at Gympie were first studied as far back as 1868 in conjunction with the discovery of gold. The relationship of the Gympie Group to other sequences in the Gympie Composite Terrane is an important subject of investigations in a new mapping project of the Geological Survey Program of the Department of Resource Industries.In two areas the Gympie Group has been divided into four defined formations. They are the Highbury Volcanics (base), Ram mutt Formation, South Curra Limestone and Tamaree Formation (top) in the Gympie area, and the Mant basalt (base), Kolbar Formation, Gigoomgan Limestone and Teebar Formation (top) in the Gigoomgan area. Geochemical and lithological evidence from the basal volcanics of the Gympie Group (Highbury Volcanics, Mant basalt) indicate that they developed in an intraoceanic island arc setting. The overlying volcaniclastic sediments (Rammutt Formation, Kolbar Formation), which contain some continentally-derived material, are mainly of local derivation and shallow-water marine. A hiatus is present at the top of the Early Permian Rammutt Formation and Kolbar Formation. Following the hiatus, limestone sedimentation characteristic of a basin of restricted circulation developed in the Late Permian. There is some evidence of a hiatus between the limestone deposition of the Gigoomgan and South Curra Limestones and the overlying probable turbidite deposits of the Teebar and Tamaree Pnrmatinnc

Jan 1, 1990

By T Roache, K Yang, M Quigley, C Young

In late 2004 a large-scale evaluation of a new suite of tools for semi-automated core logging was carried out in the Eastern Goldfields of Western Australia. Known as HyLoggingÖ Systems, these combine rapid hyperspectral mapping of mineralogy and very high resolution digital imaging of cores and chips in their original containers. The resulting data is very information-rich and provides information about host rock, alteration and regolith mineralogy. This, in turn, can be used to test geological models about fluid/rock interactions, ore system architecture, ore feed characterisation and generally improve the objectivity of the normally manual and variable logging process. Results were obtained from the Kanowna Belle and St Ives gold deposits in the Kalgoorlie region, as well as numerous holes from across Western Australia stored in the Kalgoorlie Core Library. At the Kanowna Belle gold deposit critical spatial trends in the proportions of white mica, the chemistry and species of those micas, the presence of selected carbonate species and the absence of chlorite proximal to ore zones have all contributed to improved ore deposit understanding. Significantly many of these trends are not discernible to the naked eye, nor easily quantified, previously, across many thousands of metres of core from separate drill holes. At St Ives, the HyLoggerÖ was able to show that low-Al (phengite) and high-Al (paragonite to muscovite) white micas are spatially associated with D3 foliation zones that are proximal and distal to Au mineralisation, respectively. D3 foliation zones are also associated with the depletion of metamorphic chlorite and amphibole, and their replacement with biotite, relative to unaltered mafic host-rocks. The HyLogged GSWA drill holes yielded mineralogical characterisation of classic deposits, including Kambalda (Ni), Fimiston (Au), Teutonic Bore (Cu, Zn, Ag), Black Swan (Ni) and Hannans (Au), illustrating a wide variety of mineralogical trends due to both host lithologies, previously unrecorded lithological subdivisions, and alteration patterns. During 2005 a unique thermal infrared HyLogger was developed to map the important remaining silicates, such as feldspars, quartz, olivines, pyroxenes and garnets. This was successfully tested on a 9000 m subset of the same cores as the earlier study. Interpretation has focused, in particular, on silicification, albitisation, and the mineralogy of several high-grade, less hydrous deposits.

Jan 1, 2006

By S Bouzalakos, W Timms, H Malli

Combining ultramafic mine tailings and acidic mine drainage via mineral carbonation to sequester carbon dioxide, presents an opportunity to minimise waste on mine sites. Low pH mine water with trace element concentrations can be effectively treated by high magnesium mine tailings, a useful source of finely ground reactive matrix. By using milled tailings for mineral carbonation, there are negligible energy requirements for communition of ore rocks to reduce particle size. This study aimed to assess the technical applicability of reacting ultramafic tailings and acidic mine water through mineral carbonation technology in the mining industry. Dissolution has been identified as the rate limiting stage in mineral carbonation; hence the study focused on identifying optimal dissolution conditions. Ultramafic tailings (particle size <100 µm) derived from serpentinite ore, were reacted with a typical mine water that was synthesised in the laboratory. Through variances in the solid to liquid ratios and temperature of dissolution, a maximum five per cent magnesium dissolution efficiency was reached at 50 g/L and 100°C. The acidic mine water was neutralised (from pH <2 to pH ~6) and iron, copper and zinc ion concentrations reduced significantly during the formation of solid precipitates. Carbonation was undertaken by injecting carbon dioxide into the magnesium-rich solution to form stable carbonates. The experimental work demonstrated proof of concept; however, dissolution efficiency and carbon dioxide sequestration was low, indicating that further research would be required before larger scale implementation.CITATION:Malli, H, Bouzalakos, S and Timms, W, 2015. Ultramafic mine tailings to treat acidic mine water and lock away carbon through mineral carbonation, in Proceedings Tailings and Mine Waste Management for the 21st Century , pp 133–136 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 27, 2015

By R O. James

The usual focus of papers on fatty acid collector action in non-sulfide flotation is on the adsorption of the carboxylate and/or neutral molecule species at the mineral-solution interface. Little attention is paid as to whether or not the solution conditions correspond to true solutions, micellar and other self-assembly objects or precipitates. Our examination of the solution chemistry of the important fatty acid collector, oleic acid, has revealed that many, if not most investigators set their experimental conditions to be in micellar or precipitate domains while arguing, often by implication, that they have only solute species present. We have investigated the equilibrium solution domains usually encountered in studies of oleic acid flotation of such minerals as barite, calcite and fluorite. The alkaline earth-fatty acid and liquid oleic acid precipitate phases exert a strong influence on the solution chemistry, a fact not often appreciated in many studies.

Jan 1, 2005

By T Higuchi, T Yamamoto, K Takehara

Iron ore fines are used as raw materials for sintered ore for blast furnaces in the world. Since the production and quality of sintered ore have a great influence on the stable operation of a blast furnace, many technologies were developed for controlling the heat profile in the sintering machine, which largely affect the sintered ore properties. In particular, the influence of oxygen in the suction gas, which plays an important role in combustion, was investigated over the years. It is known that increasing the oxygen ratio by about 30 per cent not only significantly improves the combustion rate, but it also increases the strength and yield of sintered ore. However, the details of the mechanism for improving these qualities are unknown. In this study, we investigated the influence of oxygen enrichment at higher ratios (O2: 21–40 per cent) and tried to understand the sintering behaviour enhanced by oxygen. The effect of oxygen enrichment on sintered ore quality and the heat profile were evaluated by sintering tests using a quartz glass pot. From the results, sintered ore yield had a maximum value for O2 = 30 per cent, but strength was increased for O2 = 40 per cent. From heat pattern analysis, it is clear that the high temperature holding time also reached a maximum at O2 = 30 per cent. Furthermore, we found that with increased oxygen ratio, the combustion speed (flame front speed) was increased, but the area of combustion was enlarged. It is considered that there could be a maximum oxygen ratio value for the yield from the balance of these positive and negative effects on high temperature holding time. To clarify the reason for strength improvement, thermodynamic calculations were performed and it was found that melting behaviour could be improved by changing the oxygen ratio.

Sep 18, 2023

By M D. Basuki Dwi Priyono

The Toguraci low sulfidation epithermal gold vein deposits are located 2 km WSW from the Gosowong mine and form part of the Gosowong Goldfield. The goldfield lies within a Neogene magmatic arc on Halmahera Island, North Maluku Province, East Indonesia. The terrain is moderate to steep, rainforested, and poorly outcropping. Exploration and mining operations are being carried out within the PT Nusa Halmahera Minerals Contract of Work (exploration tenement) jointly owned by Newcrest Mining Ltd (82.5 per cent, operator) and PT Aneka Tambang Tbk. (17.5 per cent). First pass exploration of the Gosowong area began late 1992 resulting in the discovery of weakly developed porphyry copper mineralisation (named Bora) at Toguraci in 1993. Early in the evaluation of this porphyry an overprinting epithermal Au/Ag mineralisation event was recognised, however exploration focus remained on the Bora porphyry deposit for some time. The discovery of the nearby Gosowong epithermal gold deposit and the exploration of other prospects in the area further diverted attention and funds from Toguraci. It was not until year 2000 that Toguraci was seriously reevaluated as part of a detailed appraisal of the epithermal gold potential within a 5 km radius of the Gosowong gold mine. A fly-camp based drilling campaign using man-portable rigs was undertaken between August 2000 and March 2002. All exploration at Toguraci was then stopped pending government approvals to mine. These were finally issued in May 2003 and immediately drilling restarted and pre-mine approvals (eg the environmental impact study) were sought and granted. The first Toguraci gold bar was poured in February 2004. Exploration at Toguraci and elsewhere in the Gosowong Goldfield continues today.

Jan 1, 2004

By N Steenkamp, L Furstenberg, W Cele, M Richter

Managing productivity and improving efficiency for a healthy return on capital employed have become key mining industry strategies under prevailing tough global market conditions. However, achieving this in a multisystem environment such as a mining operation can be daunting. The field of discrete event simulation offers some relief, giving engineering teams insight into multivariable systems and stochastic processes. It allows for integrated system thinking and domain expertise to be woven into project thinking fibre. Directed system optimisation and therefore improved efficiency becomes possible. Furthermore, capital discipline accrues from optimal upgrade investments. This paper illustrates the practical application of this approach by reviewing a typical case study for a direct shipping iron ore operation. Dynamic simulation was used to establish maximum processing plant capacity under varying material characteristics and identify capital-efficient upgrades for increasing production.The study started with descriptive statistical analysis of existing data. Discrete equipment and system capacities were defined, followed by static plant mass balance calculations to establish bottlenecks and overall static capacity. Equipment ‘uptime’ and ‘downtime’ analyses established system and overall plant availability and utilisation. From this information, a dynamic simulation model could then be developed and initially calibrated against actual plant performance to verify its robustness. Once confirmed to accurately represent existing plant dynamics, system capacity response to variable changes could be tested to ultimately determine maximum plant capacity. Additionally, plant optimisation was incorporated to arrive at optimal upgrade points. Maximum capacity and necessary upgrades were established as a function primarily of feed size distribution. Additionally, the interfacing effects of rehandling feed material to the final product grade and potentially to life-of-mine were established as important outcomes. The results of the study illustrate the value of using dynamic simulation models to realistically and cost-effectively increase throughput.CITATION:Cele, W, Furstenberg, L, Richter, M and Steenkamp, N, 2015. Capacity evaluation of iron ore processing facilities utilising dynamic simulations, in Proceedings Iron Ore 2015, pp 597–604 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015

By N Barnett, M Dello-lacovo, J Oh, S Saydam, T Pelech

In-Situ Resource Utilisation and Off-Earth mining require the application of horizontal drilling. The stability of such openings is challenging when excavating in the lunar regolith. Excavations on the Moon will encounter unconventional operational conditions such as different material properties, low gravity, and a moonquake. Micro-tunnelling or drilling to support lunar exploration and development of infrastructure on the Moon requires stability analysis to ensure its desired performance. The discrete element method (DEM) modelling technique has been utilised to investigate the optimum opening sizes on the lunar soil. From the literature, the mechanical properties of the lunar regolith have been reviewed and used for numerical model development. The model has been calibrated by simulating numerical triaxial tests with the Mohr–Coulomb failure criterion. Then, detailed parametric studies have been performed to investigate the influence of confinement, opening dimensions and moonquakes on the stability of openings. The findings have led to the development of a simple stability chart of the relationship between unsupported opening sizes and lunar regolith properties at different depths.

Nov 29, 2022

By J Chen

Research conducted into backfill drainage at Mount Isa Mines since 1992 is described. Piping in draining backfilled stopes has been the primary cause of bulkhead failures and emphasis is placed on research into the piping mechanism. Laboratory and in situ tests aimed at understanding the piping mechanism have been conducted and the results are presented. A case history of piping in a draining bench stope fill mass is described and a technique for reducing the potential for bulkhead failures in bench stopes is presented. Hydraulic fill is produced by standard cycloning of tailings and the overflow (reject material) is sent to thickeners prior to placement in the tailings dams. Research into the partial introduction of thickener underflow into the backfill system and its influence on backfill drainage is also described.

Jan 1, 1998

By S H. Li, H Z. Gu, A Huang

High aluminium steel is a promising advanced steel known for its exception properties and holds significant economic and strategic importance. However, the CaO-Al2O3-SiO2 based slag with high alumina content reacts vigorously with alumina refractories during the smelting process at high temperature, seriously affecting the safe and efficient production of furnaces and resulting in the formation of Al2O3-MgO non-metallic inclusions within the molten steel. This is a bottleneck problem for high-quality steel refining, and the key reaction path during the corrosion remains unclear. The dissolution reaction mechanism of alumina refractories in high alumina CaO-Al2O3-SiO2 slags under a weak static magnetic field was investigated in this work, using high temperature laser confocal microscopy and in situ radiation spectroscopy techniques. The results indicate that the interaction between the high alumina slags and the alumina refractories is governed by free radical reactions. The dissolution of alumina forms AlO and AlO2 radicals. The reaction rate increases with the C/S ratio of the slag due to its low polymerisation. The reaction between non-bridging oxygen and AlO2 free radicals accelerates the generation of AlO and O2ꞏ- radicals. The reaction layer composed of calcium aluminate is formed through the recombination of AlO, Caꞏ+ and O2ꞏ- radicals. The weak static magnetic field induces the Zeeman splitting of free radical pairs and intersystem crossing occurs, promoting the formation of triplet free radical pairs through the hyper-fine coupling effect. The reaction can be significantly inhibited as the triplet free radical pair does not meet Pauli’s incompatibility principle. This discovery perfects the structure theory of molten slags with radicals and provides supplement to the design of the highly slag-resistant refractories, and provides the theoretical basis for the development of external field protection technologies for high-quality steel refining.

Jun 19, 2024

By H Aoki, A Nakayama, K Morita, S Yamada

The thermal conductivity of mold flux is crucial for optimising the productivity and quality of steels. This study investigates the thermal conductivity of molten oxides, including CaO-BO1.5-AlO1.5 (CBA), CaO-BO1.5-AlO1.5-SiO2 (CBAS), and CaO-MgO-BO1.5-AlO1.5 (CMBA) melts, using a hot wire method. Additionally, their structure is examined using Raman spectrometry and magic angle spinning nuclear magnetic resonance (MAS-NMR) to explore their relationship. Furthermore, first-principles calculations are employed to assess the covalency of each bond in the melts for a more quantitative analysis of their relationship. The study confirms that an increase in the CaO concentration of the CaO-BO1.5-AlO1.5 melts reduces the amount of bridging oxygen and consequently decreases thermal conductivity. The covalency of the B[4]-O bond is highest, especially when the second-nearestneighbour Al atoms transition from Al[6] to Al[4], forming the AlB3O7 structure with B[4]. The relationship between thermal conductivity and the structure of CaO-BO1.5-AlO1.5-SiO2 melts can be quantitatively assessed using the degree of polymerisation of the network structure and the variation of covalency as indicators. Furthermore, replacing CaO with MgO in the CaO-MgO-BO1.5-AlO1.5 melts reveals a mixed alkaline earth effect on thermal conductivity.

Aug 21, 2024