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By Edward Keller

In a paper, entitled A Uniform Method for the Assay of 'Copper Material for Gold and Silver,' A. R. Ledoux invited the assayers of this country to contribute to a symposium, in which the results of their assays of given samples of copper-matte and metallic copper would be made comparable. This symposiun 2 appeared about one year thereafter; and through it and its discussion, first became generally known the fact that the gold-yield by the all-fire method of assaying is usually higher than by the so-called combination (wet and dry) method, in which nitric acid is employed as a solvent for the copper. In the publication alluded to, the supposed cause of gold-losses in the latter method was declared to be the solvent action of copper nitrate, or of the reduction-products of the nitric acid, upon the gold. Up to a very recent date, gold has been held to be insoluble in pure nitric acid. (The solvent action of any chlorine present in the nitric acid must here properly be disregarded as belonging in the realm of carelessness.) Among later allusions to this topic, W. R. Van Liew3 ascribes the solution of the gold in the combination-assay entirely to the action of nitrous acid at the high reaction-temperature of copper and nitric acid; F. B. Flinn4 believes the low result in gold to be due exclusively to mechanical losses—finely-divided gold penetrating through the filter-paper—but presents no experimental data confirmative of this belief; and 0. Pufah]5 attributes the solubility of' the gold in some coppers to the presence of selenium—a view which appears to be shared by many as-

Jan 1, 1913

By James W. Burns

Thin, heavily doped n-type layers of GaSb have been grown on p-type GaSb substrates. Techniques have been developed for the growth of the n-type layers from a tellurium-doped gallium-rich solution. The solution used consists of 95 at. pct Ga and 5 at. pct Sb. The process consists of immersing the p-type wafer in the solution at a temperature slightly above the liquidus temperature, holding briefly to permit dissolution of the substrate surface, then decreasing the temperature to a value slightly below the liquidus to obtain 1 HE resistivity of n-type GaSb varies linearly with applied hydrostatic pressure, while the resistivity of p-type GaSb is insensitive to such pressure.1,2 The growth. Growth from a solution of GaSb in tin will also be described. In either case the substrate is clamped to a shelf at one end of a graphite boat, and immersion of the wafer and subsequent decanting of the solution is accomplished simply by tilting the furnace. The process is useful for the formation of p-n junctions in III-V compounds and has the advantage that the problems normally associated with diffusion of Group VI elements are not present. Layers up to 4.0 mils in thickness have been grown by the process. material therefore should be useful in a hydrostatic pressure-sensing device. A practical hydrostatic pressure sensor, however, requires the fabrication of GaSb sensing elements of several hundred ohms resistance. Attempts were made to prepare such elements by diffusion, taking advantage of the high sheet resistance of the thin diffused layers and depending upon the p-n junction to provide isolation from the base layer. Additionally, thin layers of conductivity type opposite from that of the base layer were pre-

Jan 1, 1969

By R. F. Domagala

SOME of the results of a program designed to study the kinetics of transformation and related mechanical properties of prototype Zr-X binary alloys systematically are presented here. The object of this program was to provide a sound basis for a scientific approach to the realization of optimum properties in binary zirconium alloys. Alloys of Zr-Mo (eutectoid), Zr-Sn (peritectoid), and Zr-Ti (a and ß isomorphous) were prepared and studied. The data herein are confined to a presentation of the results of studying the eutectoid prototype alloys. The Zr-Mo phase diagram has been determined.&apos; A definitive metallographic study of isothermaily annealed samples prepared from high purity elements served to position a sluggish eutectoid reaction, ß?a + ZrMo2, at 780°C. The compositions of the phases involved in this reaction are: ß, 7.5 ±1 pct Mo; a, <0.18 pct Mo; and ZrMo2, 67.8 pct Mo. Inasmuch as a lower purity sponge zirconium was used in this work boundary placements were rein-vestigated with the less pure alloys. Materials and Procedures Hafnium-free sponge zirconium was used to prepare all ingots. The arc melted hardness of a small button of this zirconium was found to be Vpn 168. Chemical analyses conducted at Armour Research Foucdation are shown in Table I, High purity molybdenum sheet was used as the alloy addition. A typical analysis is shown in Table I. Several 200-g Zr-50 pct Mo alloys were made by arc melting. Crushed granules of this material were used to ensure inqot homogeneity Ailoy ingots were prepared by double melting techniques. First, three 5-lb ingots of each alloy composition were are melted in 2 nonconsumable electrode arc furnace. After melting. the ingots were ground to remove surface defects. A subse-

Jan 1, 1958

By D. Coutsouradis, L. Habraken, P. Nicolaides

The TTT curves of 0.1 pct C, 13 pct Cr steels containing up to 12 pct Co have been determined in order to establish whether the effect of cobalt is similar to that observed m plain carbon steels. It is shown that cobalt increases the incubation time and decreases the transformation rate, though not in an uniform way. The bainitic transfornation is displaced to lower temperature and overlaps partially the martensitic zone. ThE effect of cobalt on the transformation of a plain carbon austenite has been studied by many investi-gators.&apos;-3 It was shown that cobalt displaces the TTT curves to shorter times and diminishes the harden-ability. The interpretations given for this effect of cobalt are conflicting. According to E. Houdremont,4 cobalt increases the transformation rate of austenite because it increases the diffusion of carbon as shown in the experiments of E. Houdremont and H.Schrader,&apos; R.Smoluchowski,5 and M. Blanter.6 On the other hand, M. Hawites and R. Mehl3 deny on the basis of their own experiments any effect of cobalt on the diffusion of carbon and they assume that an explanation should be found in an eventual effect of cobalt on the mechanism of nucleation and growth of pearlite. W. C. Hagel, G. M. Pound, and R. F. Mehl7 have shown by calorimetric measurements that cobalt increases the free energy of the austenite-pearlite transformation in an eutectoid steel and this result explains qualitatively the observed effect of cobalt on the rate of nucleation and growth of pearlite. The purpose of this research was to see by determination of TTT curves, if this same effect exists in 13 pct Cr steels. EXPERIMENTAL PROCEDURES The preparation of the alloys was carried out in an

Jan 1, 1960

By E. T. Dumble

The domes of the Texas coastal plain are structural features, consisting of bosses or stocks of salt, gypsum or anhydrite, or of combinations of these, intruding into and occurring in connection with broken and uplifted sedimentary beds of Cretaceous and Tertiary age. Some of these domes show on the surface as mounds of greater or less elevation, while others are only known from drilling records. They may be divided into two classes: interior domes and coastal domes. The interior domes include those which occur in a zone 40 to 50 miles in width lying immediately east of the Cretaceous-Tertiary contact, and extending from the Sabine to the Colorado. With a single exception, these domes, so far as now known, occur in approximate alignment with the contact, but at irregular intervals. East of the Brazos, the domes are entirely surrounded by Eocene sediments. The coastal domes are found nearer the Gulf, lying entirely within Neocene territory and stretching from the Rio Grande to the Sabine. They are much more numerous than the interior domes, and, apparently, are ranged along several lines having a general northeast-southwest direction. No domes are known in the Oligocene belt. INTERIOR DOMES The interior domes so far, identified are Butler&apos;s, in Leon county, Palestine and Keechi in Anderson county, Brooks and Steen in Smith county, and Grand Saline in Van Zandt. In connection with these interior domes we must also consider the Sabine Peninsula,. of Harris, which is, without question, genetically connected with them. The Palestine and Keechi domes have been described recently by 0. B. Hopkins,1 who gives a clear idea of their corn position and structure. Others have been described at different times, and an excellent resume of the literature is given by De Golyer.2 _

Jan 10, 1918

By M. P. Dalton

THE problem at the Morning mill is to separate the galena, which contains a great percentage of the silver, from the sphalerite, making each into a commercial product. The ore as received from the nine is dumped into hopper-bottomed bins of 1200 tons capacity. These are divided into five sections, the first section being the regularly used section and the re-mainder used as a reserve bin. The ore is first passed through a 9 by 15-in. Blake jaw-crusher with an opening of 4 in. This allows a ham-mer head to pass through without damage. The crusher discharges to a conveyor that delivers the ore into a two-section punched-plate trommel screen with 1 ½ and 2-in. openings. The undersize is carried by means of conveyors to the mill bins. The oversize passes over a shaking feeder and through a spray or high-pressure water to a picking-belt, where waste and crude ore is hand-sorted. About 4 per cent of the ore by weight is picked out as waste, assaying about 0.6 per cent lead, and this is discarded over the dump. About 4 per cent of the ore by weight is removed as crude ore, assaying 10 oz. silver, 30 per cent lead, and S per cent zinc, and is shipped direct to the smelter. The remainder of the oversize from the picking-belt is con-veyed to a 4-ft. Symons cone crusher with 1-in. opening, which is interesting as a new introduction in this dis-trict. The machine consumes approximately 40 hp. and the pinion shaft travels 555 r.p.m. The horsepower is rather high, but the machine has an extraordinarily large capacity, and, due to the unique construction, there is no danger of tramp steel causing any damage, as in that case the discharge "opening" is automatically

Jan 7, 1927

By Dwain K. Butler

INTRODUCTION Characterization of a site for the prediction and simulation of dynamic events requires the determination of mechanical properties of the rock at stress/strain levels and rates and at a scale appropriate for the events and critical structures involved. The structures of interest can be on the surface, underground, or designed to impact and penetrate into the site (projectiles). Dynamic events of interest are equally diverse: seismic waves from distance earthquakes or explosions; close-in phenomena associated with earthquakes and explosions; vibrations associated with heavy equipment or machinery; and stress transients associated with impact and penetration. The complexity of site characterization depends on two factors not specifically related to the nature of the site itself: the stress levels generated by the dynamic event and the sophistication of the prediction and simulation techniques. For very high stress levels, such as occur near a nuclear detonation, and for low stress levels, such as occur during seismic wave propagation, site characterization is simplified, and often certain details of the site are not particularly important, such as shear strength variations in the case of very high stress levels. In the intermediate stress range, however, all descriptive relations are non- linear, a complete finite strain constitutive model is required, and all details of the site, such as lithology and fracture distribution, become important. The site characterization must be complete enough to support the most sophisticated prediction and simulation technique that will be applied to the analysis of the dynamic event. The procedures of site characterization are illustrated in this paper by a specific dynamic event, projectile impact and penetration, and a specific site, an outcrop of Dakota Sandstone near San Ysidro, New Mexico. The structure of interest was the projectile itself: nominally, 1.5 m in length, 0.165 m in diameter, 180 kg

Jan 1, 1984

By R. W. Jenkins

RACKLESS equipment is being used by the T Coplay Cement Manufacturing Co. to develop a folded limestone deposit economically and safely with inexperienced men. Cost and quality of development stone results in a saving when it is used instead of outside sources of limestone. This favorable cost has been attained by following a methods development and training program described in this paper. It is expected that further savings in favor of the mined stone will be made when stopes now being prepared are in production. The present equipment will be used for loading from stope draw points. The limestone is blended with quarried cement rock to serve as raw material for Portland cement, first produced in this country by Coplay Cement Manufacturing Co. from a process developed by its president, David 0. Saylor, in 1873. For many years the cement rock alone or with a small amount of added limestone was used for raw materials. Later as specifications were raised and the richer portions of quarries were depleted, limestone from outside sources was required in increasing amounts. In 1925 D. J. Uhle, the general manager, began to prospect company property for limestone. It was known that the argillaceous cement rock was underlain by crystalline high calcium limestone. After an extensive drilling program it was found that there were large reserves of limestone underlying a recumbent syncline exposed in the south wall of the company&apos;s No. 3 cement rock quarry. A quarry was started on the vertical limb of this fold in 1927, and by 1930 the full requirement of the plant was met. After 1945 production diminished because of the occurrence of dolomite beds in the south wall. The quarry floor was then 135 ft below the cement rock level and 285 ft below surface. In 1949 Gerald I?.

Jan 1, 1955

H. G. DAVIS, * Wilkes-Barre, Pa. (written discussion ? ).-The only practical method of testing mine air for gas, until recent years, was by the effect of the gas on the flame of the ordinary Davey Lamp, and it is quite surprising how nearly the correct percentage of gas can be deter-mined by many men by observing the behavior of the safety-lamp flame in the different mixtures. Mine foremen frequently guess the percentage of gas to within 0.1 per cent., making certain allowances to cover the dust-laden atmosphere, in which the test was made. It is not meant by this that anthracite dust is explosive, but that its properties increase the length of a fuel cap on an ordinary oil-burning lamp, which, as Prof. -Young contends, increases in height with the proportion of gas and in-creased temperature. Naphtha or benzine-burning lamps have a hotter flame, and, there-fore, are more sensitive so that a smaller percentage of gas can be detected. Some of the fire bosses in this region some years ago preferred the Koehler lamp, while others did not care to use it in their morning examinations. In 1911, when the experimental mine of the Bureau of Mines at Bruce-ton, Pa., was being prepared to be exploded, a large number of mining men went through it to examine the entries, which were lighted by electricity. While so doing, they saw in the face-return-airway a Koehler or Wolfe lamp, that seemed to he burning with difficulty. An investigation showed that the lamp had been filled to overflowing with naphtha and was generating this surplus gas. This shows how easily we can be

Jan 11, 1919

By F. Weinberg

INTEREST is currently being directed toward grain boundary morphologies in zinc in terms of grain boundary facetingl and grain boundary energies.&apos; Some years ago the present author attempted to measure grain boundary energies in 99.999 pct purity Zn as a function of boundary angle, using the standard procedure of measuring equilibrium angles of the boundary traces at triple points. This followed an investigation he carried out on preferential melting of |H (112) Fig. 1—Electron transmission micrograph of a stacking fault, grain boundary intersection in copper. GRAIN BOUNDARY STACKING FAULT Fig. 2—Schematic representation of the intersection of Fig. 1, indicating inclination angles 0 and trace angles $. specimens were prepared by the Bollman technique in an electrolyte of 70 pct methanol, 30 pct HNO3 main-tained at -30°C. The interfacial free energy of the high angle grain boundary and of the stacking fault is assumed to be thermodynamically equivalent to the corresponding in-terfacial tensions. In terms of the true dihedral angles & between the intersecting interfaces, the equilibrium of interfacial tensions in the direction parallel to the stacking fault yields: ysF = -ygb(cos F1+ cos ±cosF2) Here, ysF is the stacking fault free energy and ygb is the grain boundary free energy, assumed equal on both sides of the intersection. Forces acting normal to the grain boundary, of the form ??gb/?F,l are assumed negligible as the grain boundary remains straight for a considerable distance on either side of the intersection. The micrograph of Fig. 1 may actually consist of several closely spaced stacking faults on the same slip plane. The actual point of intersection between the grain boundary and the first stacking fault, and the equilibrium configuration of the intersection, should not be affected by the presence of the other faults, as

Jan 1, 1970

By L. P. Teas

The year 1931 has been one of unusual interest in Gulf Coast petroleum development, not so much because of the number of new prospects discovered, for apparently none of any present distinction have been found, but because of the discovery of so many new oil fields and the proving of so many old prospects. During the year 10 new oil fields have been found on the Coast; five in Louisiana and five in Texas. Two suspected salt domes were proven by the drill. Production dropped from a daily average of 192,000 to 162,670 bbl., or an average of 58 bbl. for each producing well, and active operations from 189 to 119. During 1931 the Coast produced approximately 48,600,000 bbl., or 44 per cent less than in 1930, when 86,500,000 bbl. were produced. The daily return at the beginning of the year was $192,000 and at the end only $126,780, the price having dropped from $1 for A grade and a range of $0.75 to $1.22 for B grade to a price range of 70 to 86c, or an average of 78c $ per barrel at the end of 1931. The average Coastal well produced 17,400 bbl. of oil during 1931. During the year development in the old fields has continued active at Barber&apos;s Hill only, although some work is in progress at Humble, Pierce Junction, Refugio and Pettus. Clear Lake is active but the large ownerships will prevent the "boom" type of field. Production is being held fairly steady at Barber&apos;s Hill and Pierce Junction, but has declined rapidly during the year at Refugio, Humble, and to a lesser degree at Pettus. The 6000-ft. production at Barber&apos;s Hill has shown a decided drop during the year and has not measured up to expectations.

Jan 1, 1932

By E. G. Banks

This paper is presented in the belief that metallurgists and chemists will be interested in the practice of grinding in tube-mills in connection with stamps, especially since the records of working here given extend over a lengthy period of time (since May, 1905). The ore from the Waihi mine—more especially that produced in the upper levels—contains a large proportion of hard, chalce-donic quartz, and the gold exists in an exceedingly fine state, conditions which necessitate very fine crushing in order to obtain a high extraction of the precious metal. Before the introduction of tube-mills at the 90-stamp Waihi mill, it was found necessary to stamp through 40-mesh (1,600 holes per sq. in.) woven wire-screens, having a fairly high discharge. The pulp then graded : Per Cent. Per Cent. On 50-mes11, .- 0.1 On l20-mesh ..8.77 On 60-mesh, . 8-74 On 150-mesh,.... 7.48 On 80-mesh,... 16.06 Passed 150-mesh,... 55.19 On 100-mesh,.... 3.66 The stamp-dnty was 2.89 short tons per stamp per day, or a total of 260 tons daily. Although the extraction on this pulp was: gold, from 88 to 90 per cent., and silver, from 74 to 78 per cent., it was recognized that finer grinding of the sands would prove beneficial, provided a machine could be found to do this work economically. Various grinding-mills and pans were tried, but without satisfactory results, the particles of sand being so hard that the capacity of any of the machines was too small to be economical. The results of grinding in tube-mills in other countries were so satisfactory that three tube-mills mere erected at the Waihi

Jan 1, 1908

By D. Turnbull, A. M. Turkalo

It is well known that if copper that has been severely cold-worked by rolling (70-98 pct) is heated to high temperatures a small number of large grains are formed at the expense of the fine grained structure that appears upon primary recrystallization. Dahl and Pawlek,&apos; Cook and Mac-Quarie,2 Ward,3 and Boas and Bowles4 have studied this phenomenon in copper. It has been reported as taking place with measurable velocities in the temperature range 700-1080". Boas and Bowles have reported that the time necessary for the transformation is of the order of days at 700°C. According to Ward3 the number of secondary grains which appear in OFHC copper decrease with increasing perfection of cubical alignment after primary recrystallization; also the perfection of cubical alignment increases with decreasing grain size prior to the final reduction. In this investigation two heats, A and B, of especially high purity copper (99.999 pct) supplied by the American Smelting and Refining Co., were used. The behavior of samples prepared from the two heats was qualitatively very similar providing that the grain sizes established prior to the final reduction were about the same. We observed that in specimens prepared from bars which were relatively coarse grained prior to final reduction secondary recrystallization took place at a rapid rate at temperatures as low as 500°C. This is about 200-300°C lower than the temperature necessary to obtain fairly rapid transformation in OFHC copper. A 0.22 in. thick rectangular bar of lot B was cold-reduced 60 pct by straight rolling and given a penultimate annealing treatment at 250°C. Following this it was cold-reduced 90 pct and heated to various temperatures in the range 450-1040°C. The specimens were about 8 mils thick

Jan 1, 1950

By C. E. Cannon, R. C. Craze

This paper discusses the results of a study of reservoir pressures in the Gulf Coast area of Texas and Louisiana, showing the general relation of the reservoir pressure to its subsea depth, as well as excessive reservoir pressures that have been encountered. The latter are particularly important in mud-control work, and the data show why it is necessary to use muds having a relatively high density in many of the deeper wells drilled in this area. Only a comparatively few of the wells drilled in the Gulf Coast that have encountered excessive pressures are discussed, but as far as is known those omitted fall within the range of pressure observed by the writers. Measurement of Pressures The following methods were used to determine the values of the original pressures: 1. Estimation of original pressure from subsequent pressure behavior of fields. This method is not precise, and was used only in a few of the older fields in which better methods of obtaining original pressures were not available. Only normal pressures were determined by this method. 2. Measurement of shut-in pressures soon after completion of the first producing well. With one exception, all pressures measured by this method were normal, this well having a pressure slightly higher than normal. 3. Measurements of pressure in connection with drill-stem tests. 4. Estimates from the maximum hydrostatic head of mud that failed to prevent flow from the high-pressure formations into the hole. This method is not exact, tending generally to indicate low pressures. Normal Pressures All pressure measurements available are plotted in Fig. 1, with original pressure at the water-oil contact as abscissa and subsea depth as ordinate. All producing fields fall close to the solid line, which passes through the origin and has a slope of 0.465 lb. per sq. in. per ft. By way of compari-

Jan 1, 1938

By H. P. Leighly

WORNER1 briefly studied the embrittlement of titanium by mercury. He found that mercury will wet the titanium surface at 400°C in vacuo, if the specimen had been heated previously to 700°C to dissolve the oxide coating. Subsequent exposure to the atmosphere causes the mercury film to recede rapidly. Bending of the titanium specimen even after the mercury film has receded results in a brittle fracture. For the study of the embrittling effect of mercury on titanium, specimens 2 by 12 by 0.051 in. were cut from RC-130-A sheet, an alloy having a nominal 8 pct Mn content and a mixed a-ß structure. The specimens were stressed horizontally at a predetermined value after which a plastic ring having a cavity 1/2 in. diam by 1/2 in. deep was placed on the specimen. The cavity was filled with mercury and a hole was drilled in the specimen through the pool of mercury. If the stress level was high enough, fracture occurred instantaneously with the drilling. By repeating the test at different stress levels, the threshold stress can be determined. Mercury embrittlement causes a drastic reduction in the ultimate tensile strength of this alloy from 132,000 psi to about 15,700 psi. The drilling of the hole, in the absence of mercury, does not change the tensile properties. Fig. 1 shows the typical fractures observed as a result of the embrittlement of this alloy by mercury. The central portion of the fracture was brittle represented by the jagged region which appears to have occurred on the shear planes at about 45 deg to the stress axis. Ductile fracture, which is perpendicular to the stress axis, occurred near the specimen edges accompanied by a reduction of the specimen thickness. Examination of the fracture reveals that only in the brittle region does mercury wet the

Jan 1, 1962

By Robert F. Love

Deep under the hills of southwestern Wyoming lies a nonmetallic mineral deposit of incredible dimensions and value. This nearly pure, horizontal bed of the mineral trona, a sodium sesquicarbonate (Na2HC0,.NaHC08.H20), is found in the Green River formation some 1500 ft below surface. It is believed that evaporation of an ancient saline lake left this sodium carbonate as the evaporite and mysteriously left practically no sodium chloride, which is the common constituent of an evaporated saline lake. The trona bed averages 10 ft in thickness and extends over an area of several hundred square miles. In 1938 a geologist with the U. S. Geological Survey identified the trona in the core from a former oil exploration drillhole. By so doing, he initiated the developments of a chemical industry of impressive growth in the area, an industry on the threshold of further and much more spectacular growth. A drilling program by the Union Pacific Rd. and Intermountain Chemical Co. in the early 1940&apos;s succeeded in blocking out mineable reserves of several hundred million tons. Development of the deposit started in 1946 with the sinking of a 12-ft diam, concrete-lined shaft 1500 ft deep-followed by construction of a small pilot calcining plant. Actual mining of the trona started in 1947 and continued on a limited scale until 1953, when the $15 million surface facilities were completed, along with the second shaft and other expanded underground facilities. Since April 1953 the mine has been producing more than half a million tons per year, from which the refining plant has produced more than 300,000 tons per year of high quality soda ash.

Dec 1, 1956

By Alfred F. Brainerd

Some fifty years ago, iron-ore was discovered near the town of Sheldon, Franklin County, Vermont, in a vein out-cropping on a knoll near Black Creek, which empties into the Missisquoi River a couple of miles away. A short time after this discovery, the owners, Mr. TV. 0. Gadcomb and Hon. Lawrence Brainerd, both of St. Albans, commenced mining (mostly by open cut), and also erected a Catalan forge, from which iron blooms were produced, most of which were worked into bar-iron and used in the neighborhood of the forge, while some were shipped by Lake Champlain to Troy, Albany and New York. But by reason of the lack of any railroad connections, and an insufficient demand for the blooms, this forge was subsequently abandoned, and the material used in its construction removed to other places. Mr. Keith, of Sheldon, used for many years a mixture of this ore with bog-ore from Swanton, in a charcoal blast-furnace, the product of which he consumed partly in his own foundry, shipping, however, a considerable amount to Troy and New York. Accurate data as to this enterprise are not at hand. The same vein has since been traced for some 20 miles, and some prospecting has been done 011 its outcrops at Berkshire, Enosburg and a few miles east of St. Albans; but the vein being small, only a few car-loads of ore were taken out from these places. The commencement of the St. Albans Iron and Steel Works in 1872, and the erection in 1877 of a ten-ton Siemens open-hearth furnace for the manufacture of steel rails, opened a new use for this ore. The furnace-charge consisted of pig-iron, old mils, steel scrap, and magnetic iron ore, added towards the close of the heat. The ore

Jan 1, 1885

R. 8. MACPHERRAN, Milwaukee, Wis. (communication to the Secretary): The importance of carbon in pig-iron, as well as the desirability of buying, for some purposes, irons which are high in carbon, has always been recognized. Mr. Summers, I think, has given undue weight to the carbon-determinations. The combined carbon often decreases materially as the center of the pig is approached, with a corresponding increase in the graphite. Even the determination of total carbon, to be of service, must he supplemented by that of other elements. By it alone, the softness of a foundry-iron cannot be determined. Car-wheels and No. 5 iron, for instance, frequently contain 3.75 per cent. of carbon. This is the percentage specified by Mr. Summers for his No. 1 iron, " with the silicon about anywhere the furnace-man wants it." It is true that, other things being equal, the higher the carbon the softer the iron for foundry-use. But to introduce any given percentages of graphitic and total carbon into a pig-iron specification would but make the specification more complicated, without increasing its value in a commensurate degree. Mr. Summers does not believe in the governing of mixtures by the silicon, and, in support of his views, gives several tables. It seems to me that both his conclusions and his tables are somewhat unsatisfactory. He comments on the irregularity in carbon, but fails to note the significance of the irregularity in silicon..The variation of 0.7 per cent. in silicon, for example, is too great to be accounted for by difference in blast. It might better be attributed to bad grading at the furnace, unsystematic sampling, or irregular charging. Deductions drawn under such conditions are of little value. In ordinary work the castings from the same mixture should

Jan 1, 1899

By Alexander N. Mitinsky

UP to a certain limit, the increase of pressure on the diamond-drill increases the rate of progress in drilling. That limit is set by the resistance of the diamonds to compression; and beyond it, the destruction of the stones will involve an. economic loss, both in time and in money. It is, therefore, important to all diamond-drillers to know what is the resistance mentioned. In Europe, operators usually follow an empirical rule, which directs the maintenance of a pressure, on the area-of the bottom of the drilling-tool, of 12 kg. per sq. 4m. For the tools in ordinary use, this is equivalent to 1 kg. per sq. mm. of the diamonds set in the tool So far as I know, American drillers are using pressures as high as 50 to 60 kg. per sq. cm. of the total area of the drill, and the consumption of diamonds (on Denny&apos;s authority, 0.2 carats per meter bored) is greater in America than in Europe. But the reason for this difference may be the comparatively larger size of the diamonds commonly used by American drillers. With the assistance of my friend, the late S. Woisslaw, who was the pioneer of diamond-drilling in Russia, I selected from his stock a number of black diamonds, which I subjected in my laboratory to compression-tests. To prepare regular cubes for such tests, as is generally done with other stones, would have been not only costly, but, what is more important, practically useless. I therefore determined, in order to assimilate as nearly as possible the conditions of actual use, to place each sample between a hard plate (corresponding to the rock) and a softer plate (corresponding to the bottom of the tool), into which it would be pressed during the test.

Jan 1, 1906

By William Wraith

1. INTRODUCTION. AT the Washoe smelter,. Anaconda, Mont., the blister-copper from the converters is transferred, by means of a crane, to a refining-furnace,, in which it is brought to proper pitch by means of air and poles. From this furnace the refined copper, containing gold and silver, is poured into cast-iron molds placed on a platform-conveyor, giving an anode 36.75 in. long, 28 in. wide, and 21 in. thick. By reason of a disagreement between the smelter and the refinery, in reference to the silver-content of the anodes, it became necessary to investigate the methods of sampling used. II. SMELTER METHOD OF SAMPLING. At the smelter the sampling is done by " spotting " into water a small portion of the molten stream of copper as it flows from the furnace, by batting" the stream with a wooden paddle. The first sample is taken 30, min. after the pouring is started, three. other samples being taken at 1-hr. intervals, each sample weighing from 4 to 6 oz. The samples are dried, examined for particle&apos;s of burnt wood, screened on a 10-mesh screen of No. 8 wire to remove the fines, the oversize then screened on a 4-mesh screen of No. 20 wire to remove the coarse, the undersize of this screen being taken as the sample. Teh four portions thus obtained are thoroughly mixed and spli in half by passing over a 16-slot splitting-device, slots being 0.5 in. wide. One-half of the sample is sent to the laboratory for analysis and one-half kept as a duplicate. III. REFINERY METHOD OF SAMPLING. The method used at the refinery and also used in this investigation is the one developed by Dr. Edward Seller, of

Mar 1, 1910