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By Kenneth G. Thomas

This paper reviews the alkaline and acid gold autoclaving experiences gained at Barrick Gold Corporation. Alkaline autoclaving was operational at Barrick Mercur, Utah, U.S.A., on carbonaceous/sulphide refractory ore for eight years commencing in 1988. Acid autoclaves have been operational at Barrick Goldstrike, Nevada, U.S.A., on sulphide refractory ore since 1990 and now process 17,500 stpd of ore through six large autoclaves. Information is presented on operating costs, materials of construction, reagent requirements and flow sheet developments that reduced capital and operating costs.

Jan 1, 2000

By A. Robles

The main goal of the present work is to propose a viable alternative for selective arsenic elimination from copper smelter flue dust without the need of a global leaching scheme for all the individual components of the flue dust. Using this alternative, the inherent copper recovery problems are avoided. Arsenic precipitation is also considered for regenerating the solution and completing the process cycle. The experimental results for arsenic extraction and precipitation are satisfactory. Concentration of NaOH used was relatively low. The main reason for succeeding in high arsenic extraction and low NaOH consumption is due to the previous water washing of the flue dust. Water washing dissolves much of the iron and copper that are present in certain percentage as sulphate.

Jan 1, 1999

By Kenneth E. Skiff

INTRODUCTION United Nuclear Corporation and Homestake Mining Company are partners in a major uranium mining and milling venture near Grants, New Mexico. The partnership was formerly called Homestake-Sapin Partners and was recently renamed United Nuclear-Homestake Partners (UN-HP). The mill, originally built in 1958, had a capacity of 1,650 tons per day. With subsequent improvements and the addition of the adjacent Homestake - New Mexico Partners mill, the UN-HP mill is currently rated at about 3,500 tons per day. An alkaline type leach process is utilized by the mill. Milling consists of five basic steps: A. Ore handling and preparation B. Extraction C. Solid-liquid separation D. Precipitation and purification E. Product preparation MILLING Ore Handling and Preparation The primary source of ore for the UN-HP mill is from its four

Jan 1, 1983

By Xiaolong Bi, Shaohua Luo, Longjiao Chang, Shiyuan Cao, Jianan Liu

iliary agent was proposed. The mineralogical transformation and silicon extraction kinetics of laterite nickel ore in alkaline hydrothermal treatment were studied. The effects of reaction temperature (175 ~ 250℃), molar ratios of sodium hydroxide to ore (1.05 ~ 1.2:1), and laterite nickel ore particle size (44 ~ 178 μm) on the extraction ratio of silica were investigated by using the shrinking core model. The results show that the extraction ratio of silica increases with the increase of reaction temperature, sodium hydroxide to ore molar ratio, reaction time, and the decrease of raw ore particle size. The kinetic analysis shows that the separation of silica in laterite ore can be described by internal diffusion model. The apparent activation energy (Ea) of the reaction was 8.87 kJ mol− 1, and the kinetic modeling was established.

Dec 2, 2021

US 4,133,866-Selective recovery of the bound sodium content of red mud obtained in the production of alumina by the Bayer process The red mud is mixed with aqueous ferric sulfate, the resulting suspension stirred intensively at a temperature of 15-85°C and adjusted to a pH value of from 4.4 to 4 6, and the solids are removed. The clarified solution of sodium sulfate can be used directly for the leaching of additional bauxite T Lakatos, M Miskei, J Szolnoki, F. Toth, and L Revesz, assigned to Aluminiumipan Tervezo es Kutato Intezet, Almasfuzitoi Timfoldgyar, and MTA Geokemiai Kutatolaboratorium. Jan. 9, 1979. 3 pp (423-208). Filed: 10¬28-77 (846,588) Priority: Hungary, 10-29-76 (AU 364). US 4,145,398-Continuous digestion of bauxite with aqueous sodium hydroxide, with higher throughput in existing plants or the construction of smaller plants with equivalent capacity The ore suspension at a solids concentration of 1-6% by weight and temperature of 200-300°C is flowed through a digestion tube or nest of tubes at a velocity of preferably from 2 to 5 m/s and under a pressure of from 10 to 200 atm Heat is supplied by a fluid heat carrier flowing in countercurrent in a concentric outer tube. Preferably, some of the red mud is recycled to the digestion operation. L. Plass, assigned to Vereinigte Aluminium-Werke A.G Mar 20, 1979. 5 pp. (423-121) Filed: 2-27-76 (754,749) Same: British 1,437,548, dated May 26, 1976 Same Canadian 1,008,253, dated Apr 12, 1977. US 4,146,573-An aqueous slurry of red mud, formed in the Bayer process production of alumina from bauxite, can be solidified by treating the red mud with a described quaternary ammonium salt, continuing mixing until the red mud has set up to a rigid mass, and recovering the solidified concentrated red mud J Kane, assigned to Nalco Chemical Co Mar 27, 1979 4 pp (423-82). Filed 8-2-78 (930,251).

Jan 1, 1980

US 4,190,436 - In the cyanide leaching of gold ore in tailing or ore dump piles, or gold ore in vats or on pads, the ore is agitated and oxygenated by introducing timed bursts of air, along with cyanide in a cyclic or regulated manner. The leach liquor is drained from the material by providing a continuous flow of air. Fines are homogenously mixed, thereby reducing channelling In the ore bed. Yield is improved and cyanide consumption lessened. R M. Hughes Feb. 26, 1980. 7 pp. (75-105). Filed. 12-20-77 (862,335).

Jan 1, 1982

US 4,201,749-In the Bayer process production of alumina wherein aluminum hydroxide is precipitated from a sodium aluminate solution for use as seed, sodium oxalate and caustic components are removed from the precipitate by washing it first with a washing liquor which is saturated with sodium oxalate but has little content of caustic, and secondly with hot water. Substantially no sodium oxalate is recycled, yet loss of sodium aluminate is minimal. K. Yamada, T Harato, and H Kato, assigned to Sumitomo Aluminum Smelting Co Ltd May 6, 1980 8 pp. (423-127). Filed. 5-8-79 (37,145) Priority. Japan, 5-8-78 (53/54,803). Same¬British 2,020,642, dated Nov. 21, 1979.

Jan 1, 1982

By S. N. Rossovsky

"A new method for the hydrometalfurgical treatment of refractory gold arsenosulphide concentrates is presented. Themethod involves a combination of' finegrinding, intensive agitation, flotation, and cyanidation, and consists of leaching of -10u pyrite and arsenopyrite particles in alkaline solution under intensive agitation without the application of costly high-pressure and roasting techniques. Consistent extractions of gold, in excess of 96%, are achieved.IntroductionConventional methods of alkaline leaching of gold arsenosulphide concentrates in an autoclave» and under electrochemical oxidation( 2) require expensive equipment as well as high-cost energy and reagents. In other cases, processing of gold concentrates inelude: ultra-fme grinding, calcination at 200°C to 250°C with the addition of an oxidant (NH4NOJ followed by alkaline leaching of the resulting calcine with hydrogen peroxide, the latter being a complicated method yielding poor extractions of gold (89% to 90%). In this paper, a hydrometallurgical method is described for processing refractory gold arsenosulphide concentrates in which alkaline leaching is followed by cyanidation of the residue."

Jan 1, 1993

By Spencer PA, Winborne DA

The Porgera mineral deposit in Papua-New Guinea contains gold as finely divided, probably submicroscopic (1 um) particles dispersed in a pyrite sulphide matrix. Only 25-30% of the gold in pyrite can be extracted by direct cyanide leaching and fine grinding the pyrite does not increase gold extraction significantly. This work is concerned with the application of alkaline leaching at atmospheric pressure to oxidise the pyrite prior to gold recovery by cyanidation. The paper presents and discusses results of a comprehensive set of testwork using sodium carbonate, sodium hydroxide and calcium hydroxide alkaline media. Best results, at 60-70% gold extraction, were obtained with sodium hydroxide systems.

Jan 1, 1984

By P. N. H. Bhakta, X. P. V. Lei

The U.S. Bureau of Mines developed an alkaline oxidative pretreatment to increase the recovery of gold from refractory sulfide ores containing arsenopyrite (FeAsS) and/or pyrite (FeS2). Pretreatment of a low grade ore containing 0.4% FeAsS, 3.5% FeS2, and 2.74g/mt Au with 1.2m NaOH, 40 psig o2, 100° C, and 4 hr in a 2-L autoclave resulted in 94 to 96% sulfide oxidation. cyanidation of the pretreated residue resulted in 88% Au extraction compared to <20% Au extraction for untreated ore. Cyanide consumption was 0.25 kg NaCN per metric ton of ore. A flowsheet for treating sulfidic low-grade gold ore is proposed.

Jan 1, 1990

"In conjunction with Banick Mercur , Wright Engineers Limited designed the first multi-stage aqueous pressure oxidation system in an alkaline environment in North America. A three-stage slurry heating and slurry pressure let-down with heat recovery was an innovative approach to the problem of high energy cost with the low sulphur content of the ore. The design of this system required solving a number of problems associated with heating and pumping of slurries at pressures up to 3230 kPa and temperatures in excess of 220°C. Wright received an Award of Merit in October 1989, from the Canadian Consulting Engineering Awards Committee in the Process Category for its design of the Mercur pressure oxidation system.The Mercur Mine is located at the south end of the Oquirrh Mountains in Tooele County about 65 miles by road from Salt Lake City, Utah, U.S.A. The original mill was designed to process 5000 tpd of oxidized gold ore in a carbon-in-leach (CIL) circuit. A new ore treatment system was required to treat the substantial quantities of refractory ore reserves which could not be treated economically in the existing mill. The new pressure oxidation circuit makes the refractory ore amenable to gold recovery by oxidation of the sulphides contained in the ore .Wright Engineers Limited was commissioned by Barrick Mercur Gold Mine Ltd ., a wholly-owned subsidiary of American Barrick Resources, to design the pressure oxidation facility. This followed completion of a feasibility study by Wright which showed that the project was technically and economically viable.Work on the feasibility study began in 1986, detail design commenced in February 1987, and was completed in December 1987. Mechanical installation was completed in January 1988, and slurry feed began in February 1988. The plant has operated since June 1988 without major interruption . Wright was responsible for engineering, procurement and construction management for the addition of the 750 tpd pressure oxidation circuit to the existing mill and also had commissioning responsibility.Major unit processes involved in the pressure oxidation facility are ore thickening, three-stage slurry preheating, pressure oxidation and three-stage slurry cooling with heat recovery, stearn generation, propane and oxygen storage and a video graphic display process control system were included in the scope as process anciliaries.The pressure oxidation increases gold recovery from the refractory ore by conventional CIL from as low as 35% to more than 86070. A patent has been granted for the process."

Jan 1, 1989

By P. T. O'Kane

"INTRODUCTION Wright Engineers Limited is active and has extensive experience in the design of pressure oxidation plants for the treatment of refractory gold ore and concentrate. In addition to the Mercur oxidation facility, similar projects undertaken during the last few years include the 3000 ton per day acid oxidation plant for the Getchell Mine, Nevada, a concentrate treatment autoclave for Asamera in 1984 and a feasibility study of a 50-tons per day autoclave plant for Consolidated Professor's Duport property in Ontario. The Equity Silver antimony and arsenic precipitation autoclaves, and the low pressure autoclaves at Key Lake Uranium in Northern Saskatchewan were also engineered by Wright in recent years.In August 1986, Wright was retained by Barrick Resources (U.S.A.) Inc. to add a 750 tpd pressure oxidation circuit to the existing mill at their Mercur Gold Mine, Utah. This paper describes this facility and outlines the start up in the spring of 1988 and subsequent successful operation. MERCUR OPERATION The Barrick Mercur Gold Mine is located at the south end of the Oquirrh Mountains in Tooele County, Utah. The carbon-in-leach (CIL) process plant camnenced operation in 1983 with a design throughput of 3000 tpd and has since been expanded to handle rrore than 5000 tpd. 'IWo ore types are mined, an oxide ore and a refractory ore, which is by Barrick's definition ""an ore from which less than 60% gold extraction is achieved by a standard CIL amenability test."" Typical of many sulphidic/carbonaceous ores, the refractory gold does not respond well to the cyanidation process. As a result, refractory ore has been stockpiled since the start of mining. As of June 1987, Mercur had about 570,000 tons of refractory ore stockpiled and 5.7 million tons of proven and probable reserves, grading 0.06 oz/t including approximately 3.5 million tons of tailings from the previous operation grading 0.55 oz/t. In 1986, Barrick decided to build a 750 ton per day pressure oxidation plant to process these ores. The process, for which a patent was granted, comprises pressure oxidation of the sulphides in an alkaline environment. It was developed in 1981 but was set aside in preference of a CIL plant treating only oxide ores by the previous owner of the property, Getty Oil. This process is capable of increasing gold recovery from the refractory ore from as low as 35% by conventional CIL processing to more than 85%. In 1986 Wright Engineers was engaged to undertake a feasibility study based on batch testing. This lead to a decision by Barrick Mercur later that year to build the commercial pressure oxidation plant. Wright was awarded the contract for engineering, procurement, construction managernent and commissioning in March 1987. The plant was mechanically complete in January 28, 1988, and was in operation by February 1988."

Jan 1, 1989

By Peng Qian, Xiao Li, Guoyan Fu, Peiwei Han, Yongliang Wang, Shufeng Ye

"Arsenic removal from high arsenic gold concentrate is conducive to increase the mineral value and realize the mineral comprehensive utilization. This study investigated the alkaline pressure oxidation leaching (APOL) of an arsenical gold concentrate in lower temperature to separate the arsenic into filtrate. The effects of temperature, NaOH concentration, solid-liquid ratio, reaction pressure and stirring speed on the leaching efficiency were investigated, and the characteristics of the gold concentrate and leaching residues were evaluated using XRD and SEM analysis methods. The obtained results showed that by using lower temperature (<60?) it is possible to avoid the production of elemental sulfur during the leaching process, which is benefit for the oxidation of arsenopyrite; When the reaction was carried out under appropriate conditions, more than 98% of the arsenic will be extracted into the filtrate as the form of arsenate or thioarsenate. INTRODUCTION In recent years, there has been considerable interest in the recovery of gold from refractory arsenical gold ore. The arsenic in this kind of ore usually exists as the form of arsenopyrite, and the gold surrounded by arsenopyrite exists as the form of fine particles, which will give many difficulties to metallurgical work. When the content of arsenic in the gold ore is more than 0.5%, it will seriously penalize the smelting efficiency (Ruiz et al., 2014). So pretreatment of the refractory gold ore is necessary to obtain the largest economic value and environmental benefits (Balaz et al., 2000). The oxidation pretreatment processes mainly include roasting oxidation, pressure oxidation, chemical treatment and biological treatment (Ann et al., 1992; Kou and Chen, 2012; Tongamp et al., 2010; Fernandez et al., 1995; Lin and Zheng, 1996). Among them, the roasting oxidation and pressure oxidation are the more ordinary processes in industry. The roasting oxidation process is the mature and adaptable technology, but the production of waste gas containing sulfur and arsenic will pollute the environment. The pressure oxidation method possesses certain metallurgical and environmental advantages, and can efficiently decompose the mineral. According to the different solution media, the pretreatment can be divided into alkaline and acidic pressure leaching pretreatments (Papangelakis and Demopoulos, 1990; Hiskey and Sanchez, 1995). The acidic pressure oxidation method has been used in most smelting plants for high arsenic gold ore pretreatment, while the alkaline pressure oxidation is still not widely applied. Compared with the acidic pressure oxidation, the alkaline pressure oxidation can be realized under lower temperatures."

Jan 1, 2018

By V. G. Papangelakis, A. Dani

"Alkaline pressure oxidation, particularly in the presence of trona as additive, can be used to oxidize high carbonate refractory gold ores as it prevents the formation of CO2 in the autoclave. However, the presence of silica in the ore can lead to the encapsulation of pyrite due to the solubility of silica in alkaline solutions and its subsequent reprecipitation on the reacting pyrite surface, leading to the formation of a passive layer. This fundamental study investigates the chemical composition and thickness of the passive layer on a rotating pyrite disk using XPS and SEM, as a function of process conditions at 230°C, in an aqueous slurry containing silica sand, sodium carbonate and calcium carbonate under 100 psi of oxygen overpressure.INTRODUCTIONAlkaline pressure oxidation (POX) has been used successfully to treat high carbonate refractory gold ores, which contain carbonates in addition to sulphides, most notably at Mercur and Goldstrike mines operated by Barrick Gold. There are several advantages to using alkaline POX over its acid counterpart, especially due to high carbonate content. First, it eliminates the production of CO2 in the autoclave without resorting to pre-acidification, which allows for high oxygen utilization. Second, alkaline POX suppresses the formation of elemental sulphur and intermediate sulphur oxyanions (such as thiosulphates and dithionates), which reduce gold recovery. Third, the use of sodium hydroxide or salts prevents the formation of anhydrite scale by forming soluble sodium sulphate. Other advantages are the use of cheaper materials of construction and the formation of non-acidic residue that do not require further treatment prior to cyanidation (Thomas, 2005).Sodium carbonate in particular is a promising reagent for alkaline POX because it was shown to significantly accelerate the kinetics of pyrite oxidation by molecular oxygen, when compared to other reagents such as sodium hydroxide, sodium borate and calcium hydroxide. This has been attributed to the following factors: a) the faster oxidation kinetics of Fe2+-CO3 complexes compared to Fe2+ oxidation, b) the buffering effect of carbonate ions on the acidic pyrite surface, and c) the increased solubility of oxidizing Fe(III) species due to carbonate complexation (Caldeira, 2010)."

Jan 1, 2012

By G. X. Wang, R. E. Siemens, M. C. Fuerstenau, D. Chandra

Soda roasting of concentrates from Mouat, Montana, was performed in a temperature range of 450 to 650 degrees C and chromium was solubilised by water leaching at room temperature. It was found that high extraction yields of chromium were primarily dependent on the conversion of Cr3+ to Cr6+ during the roasting step, and this was enhanced significantly by simple attrition of chromite particles during this step. Gangue impurities (mainly Si) were more detrimental to Cr extraction than lattice impurities such as Al or Mg. It appears that oxidation proceeds into grains along a preferred crystallographic plane in the cubic lattice of the chromite. The effects of roasting time, temperature, soda to chromite ratio and particle size on the extraction of chromium are presented

Jun 18, 1905

By C. G. Anderson

Alkaline sulfide leaching technology (i.e. ASL) has been studied, presented and published throughout the literature and utilized in some current engineering studies. Yet, the actual industrial applications are very few and the knowledge about these is very limited. Hence, a large gap between the laboratory, publications, engineering studies, and the actual industrial plant exists. Recent studies of ASL applied to copper enargite concentrates definitively bear out this dichotomy. Hence, this paper will seek to dispel the common misperceptions that continue to surround the selective industrial ASL hydrometallurgical technology. For edification of the reader, a listing of ten common misconceptions and myths is listed. As well, ASL history, fundamental aspects and a new flowsheet application for simultaneous gold and high purity antimony oxide production from low grade materials is included. The associated estimated economic considerations are also included to heighten enlightenment about the application of this industrially proven technology.

Jan 1, 2014

By Corby G. Anderson

Over the past 15 years, numerous pressure oxidation plants for pretreatment of gold ores and concentrates have been installed throughout the world. While this technology is now established, it suffers in terms of the complex engineering and operational characteristics inherent in utilization of high temperatures (i.e. up to 225oC) and high pressures (i.e. > 3000 kPag). This paper outlines the application of an industrially proven pressure leaching methodology utilizing nitrogen species catalyzed pressure leaching and alkaline sulfide gold leaching. As such, it stands as an economic and engineering advancement in pressure leaching and non-cyanide treatment of gold ores and concentrates. In particular, the technology offers significant technical and economic advantages over traditional pressure oxidation and cyanide gold recovery in the treatment of gold bearing chalcopyrite ores and concentrates. An example of this will application will be delineated in this paper.

Jan 1, 2003

By Suzzann Nordwick

The metallurgical treatment of mercury-containing materials for precious or base metals recovery imposes many processing and environmental challenges. Mercury is usually present as elemental or cinnabar. Historically, mercury has been removed from mined ores pyrometallurgically by roasting, but hydrometallurgical methods have also been employed. For example, alkaline sodium sulfide solution acts as an universal solvent for most mercury compounds. While, most other metals are highly insoluble in this solution. This allows for a high degree of selective separation of mercury from other metals with the exception of tin, antimony and arsenic. Mercury leached with a solution of sodium hydroxide and sodium sulfide or sulfur can be re-covered by cementation or stabilized through sulfide precipitation. Hydrometallurgical technology for the pretreatment of mercury removal from gold, silver, and base metal ores using alkaline sulfide leaching will be discussed with a focus on alkaline sulfide leaching of mercury sulfide-containing materials.

Jan 1, 2003

By J. Gogal

Cameco's Cigar Lake Operation (CLO) started commercial uranium ore production in 2015. Initial mining was focused in areas of the ore body with relatively low concentrations of elements of concern (EOCs). As mining progressed into areas of the ore body that were richer in EOCs, some statistically significant behavior of certain analytes was noted in the water treatment circuits. It was ultimately found that the CLO ore body natively hosts numerous alkyl arsine compounds in addition to inorganic arsenide minerals. The alkyl arsines were found to be recalcitrant to typical adsorption on ferrihydrite, with the degree of recalcitrance associated with the degree of alkylation. A number of changes to the process circuits and water balance were performed and planned in order to inhibit the transport of alkyl arsines from the ore stream into the process water stream, and to optimize the overall site water usage. In some instances, the interactions of equipment in conjoined circuits of the process had controlling effects on the behavior of the overall circuit. Work continues to iterate upon the capital design features in order to further tighten the water balance, and to optimize water usage and operating costs.

Jan 1, 2020

By R. Chowdhury

Axis House manufactures and supplies alkylhydroxamate reagent of various carbon chain lengths for application in flotation of oxide copper and other minerals. As part of reagent performance improvement the structural factors of hydroxamate are examined by various analytical tools in particular with X-ray diffraction of single crystals. In a recent publication, the structure of n-octylhydroxamic acid and its corresponding potassium salt are presented with findings of hydroxamic functional group geometric preference, H-bonding, keto-enol tautomerisation, acid-salt aggregation and alignment of carbon chain. In this paper an example of branched alkylhydroxamate 3, 5, 5-trimethylhexylhydroxamate will be presented and compared with the result of linear alkylhydroxamate.

Sep 1, 2012