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By H. E. Powell

The smelting of brass and bronze generates a dust composed primarily of zinc oxide, with lesser amounts of other metal oxides, such as copper, lead, and tin. The small quantity of this waste generated by individual smelters and the relatively low unit value of the contained metals, suggests the desirability of reclaiming the metals onsite or at some nearby point. The Bureau of Mines has developed a process that fits these requirements. The technique consists of (1) dissolving zinc and copper from the dust with sulfuric acid, (2) recovery of copper by cementation, (3) recovery of zinc as zinc sulfate crystals, and (4) recovery of lead and tin as a salable residue. Alternatively, zinc may be recovered by electrodeposition. Free acid is recycled and no major pollution problems are generated by the process.

Jan 1, 1972

By Jack E. Tress

The Bureau of Mines has been involved for several years in the development of processes for the recycling of solid wastes. As part of this program, a project was initiated to determine the feasibility of producing secondary pig iron from auto scrap. During the test period, 86,000 pounds of shredded auto scrap, along with petroleum coke and fluxing agents, was charged to a submerged-arc furnace of 1-ton nominal capacity. Eighty-eight thousand pounds of pig iron, with an average carbon content of 3.90 percent and an average copper content of 0.2 percent, was produced at an electrical consumption of 512 kW-hr per net ton. A cost estimate of the process showed that the pig, iron might be produced at a cost of $57 per ton.

Jan 1, 1973

During 1990-1999, a total of 458 fires occurred in all coal mining categories; 157 of those fires caused 164 injuries and 2 fatalities. The greatest number of fues and fire injuries occurred at surface mines, whch also had the highest risk rate values. A total of 66 fuefighting interventions were required. Of these, there were 25 mine rescue team interventions in underground mines, including 5 mobile equipment firefighting interventions, and 41 fire brigade and fire department interventions at all surface operations, including 19 mobile equipment interventions. In all, 50 fires destroyed or heavily damaged equipment (including 16 pieces of mobile equipment) because of failure of other firefighting methods, late fire detection, undetected fires, or fire size. A total of 1 14 fires were detected late by smoke, and 42 fires were not detected.

By Clarence O. Babcock

This Bureau of Mines publication presents guidelines for mining near surface and underground bodies of water. The guidelines were based on information developed under contract in three phases of study, as follows: (1) Collection and documentation of data from worldwide sources; (2) application of existing guidelines, foreign, Federal, and State, to case histories of previous inundations; and (3) development of recommended guidelines for underground coal mining near bodies of water aimed at maximum efficient utilization of underground coal resources consistent with minimizing inundation hazards. While the contract guidelines were for the mining of coal seams, they may also be used for mining any tabular sedimentary mineral deposit. Tables are given for the determination of the size of coal pillars needed; for other bedded deposits, similar tables could be determined based on their strength properties.

Jan 1, 1977

By R. O. Pynnonen

Tunnel-driving is recognized as a hazardous occupation; adequate support of roof and sides for preventing accidents from falling material is usually one of the most important safety problems. Where extraordinary conditions of sand and water are found, this problem becomes even more difficult. Tunneling at the Tioga No.2 mine was stopped when a 22-foot bed of water-saturated, fine gray sand was encountered. The tunnel, designed to house an ore-conveyor belt, was being driven from both ends. Driving was extremely difficult at both the upper and lower faces when the sand horizon was reached. A distance of 178 feet remained between the faces. Heavy pressures deformed the steel-supporting rings at the upper face, and there was an inrush of mud and sand at the lower face.

Jan 1, 1958

By R. W. Holliday

To determine the copper and nickel content of reported ore occurrences in the Chippewa mine near Rockmont, Douglas County, Wis., the Bureau of Mines reopened and sampled the old shaft and workings during the summer and fall of 1953. Occurrences of native copper near Rockmont and others near Gordon, also in Douglas County, Wis., are in lava flows, which extend from the Keweenaw Peninsula of Upper Michigan southwest across Wisconsin and into Minnesota. Sporadic attempts have been made to find additional economic copper deposits in these flows since profitable mines were developed in Upper Michigan nearly 100 years ago. The Rockmont and Gordon areas were explored extensively more than 50 years ago. More recently, from August 1944 to duly 1945, an occurrence near Gordon was investigated by the Bureau.2/

Jan 1, 1955

By A. E. Prokop, J. P. Rider

Previous research on continuous mining operations has shown that significant interactions exist between dust control parameter application and the resulting respirable dust levels, but simply increasing the level of the controls does not guarantee a reduction in respirable dust levels. Full-scale laboratory tests are being conducted to provide information to longwall operators which would assist them in selecting control parameters that would reduce dust levels for mine-specific conditions. The interactions between face air velocity, shearer water quantity, drum water spray pressure, external water spray pressure, and spray system design were evaluated in a simulated 2.13. m (7-ft) coal seam for two cutting directions. Locations around and downwind of the shearer were monitored to evaluate relative changes in respirable dust levels as a function of each control parameter.

By A. L. Engel

High extractions of lead, gold, and silver resulted from treatment of an oxidized, arsenical refractory ore by chloride volatilization. The ore was roasted in an oxidizing atmosphere at 1,000° C. for 1 hour. The chloridizing reagent was 300 pounds of CaC12?2H20 per ton of ore. Ninety-nine percent of the lead, 98 percent of the gold, and 96 percent of the silver, and only 6 percent of the arsenic, were volatilized. These results indicated that a satisfactory method could be developed for treating this type of ore. Recovery and separation of the volatilized values and developing metallurgical and operating data for this process require further investigation on a more extensive scale. Tests by gravity concentration, flotation, and cyanide leaching did not give satisfactory results.

Jan 1, 1958

By E. P. Youngman

The mining law of Chosen, which was made effective April 1, 1916, was promulgated as ordinance 8, December 24, 1915, in accordance with the provisions of articles 1 and 2 of law No. 30 of 1911. The new le repealed the mining law, Fo. 3 of 1906, and the placer mining law, No. of 1906, and in effect annulled all prior mining legislation. An amendment to the mining law of 1916 (by virtue of law No. 30 of 1911) vas. passed December 16, 1918, as ordinence o. 17. The detailed regulations, which were to supplement the law proper, and rich in all probability follow closely the regulations in force in the Empire, were not available. Unless otherwise indicated, references in this paper are to the mining law of 1916.

Mar 1, 1933

By Kenneth M. Earl

The purpose of this investigation was to obtain subsurface information on the John Burdette barite-fluorite deposit, Garrard County, Ky. The deposit was intersected in each of five inclined diamond-drill hales aggregating 1,163 feet. All holes were drilled from the hanging wall of the deposit; the inclinations varied from minus 41° to minus 75°. Disseminated metallic sulfides were noted in the drill cores from holes 1, 2, 4, and 5. The deepest drilling was hole 5, which intersected the deposit at approximately 490 feet down dip. Visual inspection of the cores did not indicate mineralization of economic importance; therefore, no chemical analyses were conducted. Condensed logs of diamond-drill cores are included in this report. All drill cores were shipped to the Bureau of Mines core library in Minneapolis, Minn., for future reference,

Jan 1, 1959

By R. V. Ramani, R. Stefanko, G. W. Luxbacher

1 11 THIS IS A DIGITAL COMPUTER SIMULATION OF THE VENTILATION SYSTEM OF A MINE LOCATED IN WASHINGTON COUNTY, PENNSYLVANIA. THE VENTILATION SURVEY ON WHICH THIS SIMULATION IS BASED WAS RUN FROM OCT. 27-30 AND ON NOV. 2, 1976 IN THE ACTIVE PORTION OF THE MINE INBY COMBS SHAFT AND THE INACTIVE PORTION AFCUND AND INBY DONAHOO SHAFT. FOLLOW-UP SURVEYS WERE THEN RUN ON FEB. 18 AND FROM MARCH 7-11, 1977 TO INCLUDE THE MAIN HAULAGE SYSTEM OUTBY THE ACTIVE AREAS OF THE MINE. ALL SURVEY DATA WAS NORMALIZED TO A STANDARD DENSITY OF 0.075 POUNDS/CU.FT. PRIOR TO THE CALCULATION OF INPUT PARAMETERS FOR THIS SIMULATION. IN THIS RUN, THE ORIGINAL VENTILATION NETWORK HAS BEEN MODIFIED TO INCLUDE NEW INTAKE AND RETURN AIRSHAFTS AT THE WEST MAINS.

Jan 1, 1977

By Lambert Dolphin, George Oetzel, Robert Bollen

An electromagnetic sounder developed for an archaeological application in Egypt has been successfully tested in a California dolomite mine. Chambers in the mine 100 to 130 feet from the surface gave intense, well-defined echoes consistent with an average attenuation coefficient of 0.6dB/m and a relative dielectric constant of 11. By moving the transmitter and receiver units on the hillside above the underground chambers, various characteristics of the propagation could be observed such as dispersion, chamber aspect sensitivity and cross section. The transmitted pulse was one to one-and-a-half radio-frequency cycles long at a peak power of 0.2 MW. Frequencies employed were 16 to 50 MHz. The light weight, highly portable, battery-powered equipment is potentially suited to other underground sounding applications.

Jan 1, 1973

By W. G. Payne, A. C. Richardson, B. L. Gandrud

"INTRODUCTION The Connellsville mine of the Yolande Coal & Coke Co. is in the southwestern part of Jefferson County, Ala., about 30 miles southwest of Birmingham. The mine is on the Blue Creek bed, which is about 6 feet thick and dips at a angle of 18º. The bed is worked by the room-and-pillar method and is mined by both machine and hand methods. The Blue Creek bed at this point yields a high ash, low-volatile coal with excellent coking properties. Because of its exceptionally low volatile content and high coking strength, this coal is excellent for blending with Alabama coals of higher volatile content and weaker coking properties to form blends suitable for production of metallurgical coke.A sample of washed coal taken during this investigation gave the following analysis on an as received"" basis: Moisture, 8.3 per cent; volatile matter-, 20.2 per cent; ash, 8.0 per cent; fixed carbon, 63.5 per cent. The high ash content of this coal limits the quantity which can be utilized when low-ash coke is required. In the Birmingham district it is usually difficult to sell as coking coal a product that contains more than 8.0 per cent ash. To produce a. coal with this ash content at Connellsville presents a somewhat difficult washing problem. This paper gives the results of an investigation that was conducted by the Southern Experiment Station of the U. S. Bureau of Mines in cooperation with the University of Alabama and the Yolane Coal & Coke Co. for the purpose of determining the washing characteristics of the coal and the possibility of reducing its ash content on coal-washing tables.The practice at the Connellsville washery at the time of beginning this investigation was to crush the run-of-mine coal to pass a 1 1/2-inch round-hole screen and to treat the satire output on two primary, 3-compartment jigs. A. middling product was recovered from the primary jigs which was re-treated on a single-compartment rougher jig. This system yields a product of acceptable ash content, but the yield is low and the loss of good coal in the refuse is high."

Feb 1, 1933

By Frank E. Chase, Deno M. Pappas, Christopher Mark

Multiple seam interactions are a major ground control hazard in many U.S. underground coal mines. The two most common types are: • Undermining, where stress concentrations caused by previous full extraction in an overlying seam is the primary concern, and; • Overmining, where previous full extraction in an underlying seam can result in stress concentrations and rock damage from subsidence. The National Institute for Occupational Safety and Health (NIOSH) has completed a major study aimed at helping to identify the location and likely severity of these interactions. In the course of field visits to mines throughout the U.S., more than 300 multiple seam case histories were assembled into the largest data base of multiple seam case histories ever collected. These data were analyzed with the multivariate statistical technique of logistic regression. The study also employed LaM2D to estimate the multiple seam stresses, ALPS and ARMPS to determine pillar stability factors, and the CMRR to measure roof quality. The study resulted in the development of a computer program, called Analysis of Multiple Seam Stability (AMSS), which can help mine planners to evaluate each potential interaction and take steps to reduce the risk of ground control failure. AMSS first evaluates pillar design by calculating the single seam Stability Factor (SFSS) using ALPS or ARMPS. It also automatically generates a LaM2D analysis that provides the additional multiple seam stress so that the final, multiple seam SFMS can be determined. The second part of the AMSS procedure builds upon the statistical findings that overmining is much more difficult than undermining, isolated remnant pillars cause more problems than gob-solid boundaries, and weaker roof significantly increases the risk of multiple seam interactions. AMSS quantifies these effects and predicts the outcome in terms of three levels of risk: GREEN (where a major multiple seam interaction is considered unlikely), YELLOW (where adding a pattern of cable bolts or other equivalent supplemental support could greatly reduce the probability of a major interaction.), or RED (a major interaction should be considered likely, and it may be desirable to avoid the area entirely).

By Christopher C. Jobes, Alan G. Mayton, Timothy J. Matty, Joseph P. DuCarme

Mining injury statistics show that a significant number of back, neck, and head injuries are linked to exposure from vehicle vibration. Use of a suspension seat is a common way to isolate the vehicle operator from the adverse effects of vibration exposure. Thus, researchers at the National Institute for Occupational Safety and Health1 – Pittsburgh Research Laboratory (NIOSH – PRL) performed laboratory studies on four passive and two semi-active seat suspension designs. These are typical of seat suspensions commonly found on large off-road heavy surface mining, construction and agricultural vehicles as either replacement or original equipment manufacturer (OEM) systems. One included a pneumatic (air bladder) spring mechanism. The fifth and sixth suspensions were a NIOSH magnetorheological (MR) semi-active damper design based on the pneumatic (air bladder) and one of the coil spring suspensions above. These suspensions were modified with a commercially available MR damper substituted for the OEM damper. These six seat suspension systems were tested and analyzed, for vertical vibration only, using the ISO 5007 Standard [1]. This paper describes the laboratory vibration tests using a MTS® shaker table and discusses the results obtained for the different suspension designs and highlights the rheonetic technology studied. Implications of the seat suspension designs relative to their capabilities for isolating vehicle operators from vibration exposure are discussed. Results for suspensions 1 through 3 showed frequencies of isolation from 2.1 to 3.0 Hz using the 40-kg (88-lb) mass and from 1.65 Hz to 1.8 Hz using the 80-kg (176-lb) mass. Suspension #4, in tests with only the 80-kg (176-lb) mass, showed an isolation frequency of 3.7 Hz. With the MR damper added to seat suspension #4, the peak transmissibility was lowered from 1.3 to 0.95 and showed a corresponding downward shift in frequency from 2.25 Hz to 1.4 Hz. In fact, the results for suspension #5 (the MR damper added to seat suspension #4), using test #3 conditions of the programmed control algorithm, showed isolation (attenuation of transmitted vibration) throughout the test frequency range from 1.0 to 6.0 Hz.

By P. -E. Boileau, P. Marcotte, Y. Aldien, S. Rakheja

A number of biodynamic models of the hand-arm system have evolved on the basis of measured driving-point mechanical impedance (DPMI) responses to facilitate analyses of the coupled hand-tool system [1]. The parameter identifications in such models are based upon minimization of an error function of the model and the target impedance data, which may not yield a unique solution. Consequently, a number of model structures and parameter sets could be realized that would equally satisfy the target curve. Moreover, the vast majority of the reported models exhibit acute deficiencies due to excessive static deflections of model masses, presence of a low frequency mode and very light masses in the order of 1.2- 4.8 grams. The models also do not characterize the dependency of the biodynamic responses on many factors, namely the hand forces, hand-arm posture and vibration intensity. This study aims at development of a hand-arm biodynamic model with considerations of the hand forces, and both the DPMI and power absorption measures, to enhance the uniqueness of the model. Methods Two different model structures are chosen for identifying the model parameters on the basis of measured DPMI and absorbed power characteristics of the hand-arm system under zh-axis vibration over a range of hand-grip and push forces. Owing to the strong influence of the hand-handle coupling forces, the models were initially derived for fixed hand forces, namely 30 N grip and 50 N push forces, as suggested in the ISO 10068 standard [2]. The equations of motion for the model are formulated and solved to compute both the DPMI and absorbed power responses. A constrained minimization function comprising weighted errors of both the DPMI and absorbed power is formulated and solved to identify the parameters. Alternate functions corresponding to different combinations of hand forces are then applied to identify hand-force dependent model parameters. Variations in the model parameters are investigated as functions of the grip, push and coupling forces through linear regression analysis. Regression-based models are formulated for deriving the hand-handle forces dependent model parameters. The validity of the model is also examined under selected combinations of hand forces. [ ]

Jan 6, 2006

By K. K. Kelley

The entropy values at 298.1° K. for the elements and inorganic compounds, on which sufficient data were available for calculation in 1931, were discussed in a previous publication (96).3 Since that time the specific beats at low' temperatures of many more inorganic substances have been determined, and considerable advances have been made in the realms of spectroscopy applicable to the determination of thermodynamic properties. Moreover, a critical study of the existing vapor-pressure data made by the author (98) furnishes entropy of vaporization results suitable for obtaining approximate values of the entropies of a number of gases from the entropies of the solids or liquids. Consequently, it appears worth while at the present time to supplement the former publication, giving the new values now obtainable and making such revision in the older values as the data warrant. The methods of calculating entropies were discussed in previous publications (96, 98) and will not be repeated here. ENTROPIES AT 298.1° K. FOR INORGANIC SUBSTANCES In the following pages, the same arrangement is followed as in the previous publication (96). All entropy values are expressed in 15° gram-calories per degree Kelvin per gram-formula mass of substance. The figures given for gases do not include the effect of nuclear spin, as is nearly universally customary at present. The estimates of accuracy in the case of the values obtained from heat-capacity data apply only to the existing measurements and to the necessary extrapolations as they are made. It is assumed usually that the substances are in such an energy condition at the lowest temperatures reached in the specific-heat measurements that the usual normal type of extrapolation may be made. No allowance is made for error in this assumption. The recent work on Gd2SO4. 8H2O and FeC13 illustrates the difficulties that may arise in obtaining the entropies of some paramagnetic substances. Also the data and calculations for such substances as CO, H20, and N20 show that the correct entropy is not obtained in all cases by indiscriminate application of the usual

Jan 1, 1936

By G. R. Hopkins, E. M. SEELEY

According to reports received by the Bureau of Mines, Department of Commerce, as of Jamary 1, 1930, there were 1,035 natural-gasoline plants in the United States, with a total daily capacity of 10,516,000 gallons. (These data do not include one small plant in Alaska.) The last similar survey, that of Jamary 1, 1928, showed a total of 1,155 plants of 8,048,000 gallons daily capa- city. This in two years time the number of plants has decreased by 120, but the total capacity has increased 2,468,000 gallons or 31 per cent. This is roughly equivalent to the gain in production over the same periodi Over half of the increase in total capacity was registered in California, where the development of flush oil production having a comparatively high gas-oil ratio in such fields as Santa Fe Springs led to construction of some new plants and material enlargement of others. Of the total plants, 999 were operating on Jamary 1, 1930, and 36 were shut down. This compares with 1,060 operating and 95 shut down two years ago, which indicates a tendency to dismantle plants as soon as they become obsolete or umrofitable. The total daily capacity of the plants operating on Jamiary 1, 1930, amounted to 10,278,000 gallons, or 98 per cent of the total, leaving only 238,000 gallons, or 2 per cent, for the shut-down plants. This contrasts with the refining industry, which usually has 5 per cent of its total capacity idle; the difference is due to the relative ease with which a refiner can secure a crude supply as against the difficulty the natural gasoline manufacturer has in reestablishing his gas connections. During 1929 the average total daily capacity of the operating plants was 9,899,000 gallons, while the average daily production amounted to 6,015,000 gallons. This indicates that the plants operated during 1929 at 61 per cent of their capacity. Although over 60 plants were dismantled in Oklahoma during 1929 the State continued to rank first in total mumber. California was second in mumber of plants with 165, and was one of the few States that showed a gain since the

Jul 1, 1930

By M. Mahan, D. D. Blue, O. C. Garst, F. Fraas, L. Fink

"Early in World War II it became apparent that the known bauxite re- serves might not be adequate to supply the demands of the American aluminum-producing industry, as the transportation of bauxite from abroad to this country might easily be interfered with by hostile action. Consequently, the Bureau of Mines set up an intensive, well-integrated program for the production of cell-grade alumina from low-grade domestic ores. This pro-gram of investigation covered the production of alumina from clay, alumite, red mud, and other low- and marginal-grade ores. In line with the Bureau's usual policy of conservation of natural resources, it was decided that the investigation should be extended to cover the production of alumina and other valuable byproducts from aluminum dross.Statistical information showed that during the year 1943-44, an average of 2,900 tons of aluminum dross was generated monthly. This dross, after partial removal of free metal, had an average metallic aluminum content of approximately 9 percent. Some of this dross was produced by the melting of alloyed aluminum; but a large proportion 1,700 out of 2,900 tons - was generated by two producers of primary aluminum, and the dross did not contain an great proportion of alloying metals. Compared with dross from other sources, this 60 percent of the country's capacity can be assumed to have relatively uniform composition. Moreovcr, the problem of collection and distribution can be minimized because of the relatively small number of plants included in the organization of these two producers of virgin metal.Except for large pieces of metallic aluminum that easily can be mechanically separated for remelting, this dross has been discarded and scrapped. Inasmuch as chemical analyses show that the alumina content of dross is far higher-than ordinary ores - 111 percent alumina equivalent in dross compared to 57 percent alumina in bauxite - aluminum dross is a far richer source of aluminum than any known naturally occurring ores. The discard, of this waste material during the war and reconversion periods would be unsound economically. The work reported herein describes tests at the College Park Station of the Bureau of Mines on the recovery of metal, alumina, ammonia, methane, and abrasive-grade corundum from dross."

May 1, 1946

By Lester G. Morrell

THE WORLDWIDE economic expansion that has characterized the first 3 years of the 1960's continued through 1964 and was reflected in North America by strength in the industrial economy of the United States, which again was dominant. Advances in production were recorded in virtually all industries, including the mineral industry; 1964 mineral production established a new high, 5.4 percent above the previous peak recorded in 1963. However, the percentage increase in value of North American mineral production was slightly below overall economic growth. For industry in general, consumer demand held firm throughout the year and overall commodity prices averaged 2 percent higher than in 1963. Wages and salary payments also were up. With the single exception of the dock strike in the United States, the year was free of serious labor troubles and unemployment in both Canada and the States was at a low level. Despite the Viet-Nam situation, relatively tranquil international relations contributed to the forward movement of North American business. Total gross national product (GNP) for Canada and United States, in current dollars, was estimated at US$672.2 billion; 6.8 percent above the previous year's figure. Combined national income in 1964 amounted to US$546.9 billion, which was nearly 7.0 percent more than in 1963. In 1964, gains were recorded in each of more than 50 metals, nonmetals, and fuels commodities that comprise the North American output. The greatest category increase was 13 percent in metals, which was in part attributable to the 14 percent rise to a new record in value of iron and steel in United States, a 29 percent higher value of Canadian iron ore and a 57 percent rise in Canadian zinc. Despite a moderate decline in prices of iron ore and iron and steel products, generally favorable markets and rising prices for metallic ores and metals were a stimulant to the metals industry. Nonmetallic materials, with a total value in excess of US$5.25 billion were 7.3 percent higher than in 1963. High levels of highway and building construction and expanding demand for fertilizers and chemicals continued throughout the year. Noteworthy output increases were recorded for lime,

Jan 1, 1966