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By W. A. McKinney

Bureau of Mines Research has demonstrated that it is technically feasible to segregate oxidized copper ores by use of a direct-fired, refractory-lined rotary kiln. Previously, the segregation process had been effected only in much more complicated indirect-fired, stainless steel kilns, The method comprises heating crushed ore premixed with small quantities of salt and carbonaceous material, such as coke, to about 830° C to produce copper as fine flake and metallic films on the surface of the coke particles. After grinding of the cooled furnace calcines, the copper is recovered by conventional flotation. During direct-fired segregation it was necessary to closely control the air-gas mixture in the burner. Good copper recoveries were obtained only when adding air in the limited range of 1.15 to 1.2 times the theoretical amount required for combustion of the natural gas. Batch trials of the new technique on quartzite-, limestone-, sandstone-, and limonite-type oxidized copper ores containing from 1.4 to 6.2 percent copper yielded flotation concentrates containing from 3.7 to 45 percent copper, representing 84 to 95 percent recoveries. Analyses of the furnace gases showed that loss of copper by volatilization was negligible. The preliminary direct-firing segregation studies were complemented by continuous runs on the quartzite ore, containing 1.4 percent copper, in an integrated segregation-flotation pilot plant having a 60 pound-per-hour capacity. In a typical test, 84 percent of the copper was recovered in a cleaner flotation product containing 25 percent copper. The study will be continued to further delineate the conditions for good segregation as effective use of standard ceramic-lined kilns will render the process more attractive from a commercial standpoint.

Jan 1, 1963

By L. R. Burdick

The Smokescope is an instrument recently developed for determining the density of smoke by shade comparison. The instrument is designed so that the smoke is seen adjacent to two shades of gray corresponding to Nos. 2 and 3 on the Ringelmann chart. Data on smoke density are important in the smoke-abatement field. The method that is specified and accepted as standard for smoke-density determination by the majority of city smoke regulations involves comparing the smoke shade with the four shades on the Ringelmann chart as published by the Bureau of Mines.2/ This investigation was made to determine the accuracy and convenience of the Smokescope. It was conducted as a part of the Bureau I s air-pollution work, which includes the study of techniques that will promote smoke abatement. The accuracy of the Smokescope was arbitrarily defined as the difference between the Smokescope determinations and the determinations by the accepted, standard method and was expressed as Smokescope correction. Although the corrections obtained were strictly correct only for the two observers and the Smokescope of the investigation, they indicate what might be expected from any observer who uses a Smokescope with reference shades that duplicate those of the test instrument. The report is devoted largely to the data on Smokescope correction, which were taken from a single stack under controlled smoke conditions. Field work, which was done at various locations with different stacks, is mentioned briefly in connection with the comparison of the convenience of the two methods. The data for estimating Smokescope correction were taken for the three variables that were expected to affect the results, namely, the density of the smoke, the amount of light, and the color of the sky behind the smoke.

Jan 1, 1955

By T. J. Driscoll

In this Bureau of Mines investigation, the electrochemical polarization behavior of Fe and Fe-1BCr has been characterized in rigorously controlled 1[N] H2S04 solutions stirred with oxygen or an inert gas. Samples that under-went various levels of corrosion or passivation were examined using Auger electron spectroscopy (AES) and ion sputtering. Passivation of iron occurred at a potential of approximately 0.6 volt (1) in poorly stirred, oxygen-saturated solutions for forward polarization (scanning from cathodic to anodic potentials); (2) in pH-adjusted (increased), well-stirred, oxygen-saturated solutions for forward polarization; and (3) in well~ and poorly stirred, oxygen-and helium-saturated solutions for reverse polarization. Passivation of Fe-18Cr occurred at a potential of approximately -0.1 volt in helium-, nitrogen-, and oxygen-saturated solutions for all cases of forward polarization and most cases of reverse polarization. Elemental depth profiles obtained from AES sputtering measurements indicated that films or adsorbed species were present on iron samples in solution subjected to open-circuit, active, and transpassive corrosion, cathodic reduction, and passivation. This conclusion was reached by considering the distribution of the solution species, primarily sulfur, in the films, which were composed primarily of iron and oxygen. Sulfur was present throughout the films on actively corroding samples, in the outer regions of films of passive and transpassive samples, and on the film surfaces of open-circuit and cathodically reduced samples. For Fe-18Cr, sulfur was found on the surfaces of films on passive samples only, indicating that only the passive samples had films on their surfaces in solution. The films on electropolished and passive Fe-1BCr samples had the largest chromium concentrations, estimated to be approximately 45 at. pct, with less chromium in films of cathodically reduced, active, and open-circuit samples, in that order.

Jan 1, 1979

By R. L. Grayson, S. S. Peng

"Abstract. Sampling of respirable dust and analyses of samples have been partially completed for a longwall panel. Physical and compositional properties which have been characterized include:l. Respirable mass concentration, 2. Mineral composition,3. Particle size distribution by mineral,4. Particle shape distribution by mineral,5. Particle angularity distribution by mineral, and6. Respirable size distribution.Analytical techniques used in the characterization of samples are described, and results are reported with emphasis placed on relationships between the various characteristics and worker locations. Details of existing mining conditions, equipment arrangements, dust control methods and operating system parameters are presented.INTRODUCTIONThrough the work of many researchers worldwide, the health of coal miners in modern societies is now protected from dangerous exposure to respirable coal mine dust. A vast amount of research culminated in the exposure-response model of Jacobsen, et al. (1971) whi3h has been used to establish the 2mg/m exposure limit in the United States. According to the model, exposure to respirable dust for 35 years at this level or less would prevent the occurrence of a clinically significant case of coal workers' pneumoconiosis (CWP). The exposure limit, of course, must be adjusted whenever greater than five percent free silica exists in the respirable dust.The Jacobsen model was built around a mass concentration exposure, which showed the highest correlation with incidence and progression of CWP. As Morgan; et al. (1973) noted, howev.er, the quantity of respirable dust inhaled is not the only significant factor. It is noted that although mass of respirable dust correlates highest with the incidence of CWP, it is not a causal factor. Indeed, the insidious processes causing the disease occur on the cell-particle scale, requiring microscopic investigation."

Mar 1, 1989

By A. J. Forney

Recent experiments used catalysts of plate assemblies in synthesizing high-Btu gas and gasoline indirectly from coal. A gas with a heating value of 925 to 943 Bt-: per cubic foot has been prod u la the hot-gas-recycle pilot plant from synthesis gas (3H2+100) with lathe turnings used as catalyst in the first reactor, and assemblies of parallel sprayed plats of nickel in the second. Solid plates made of Raney nickel, and steel and aluminum plates sprayed with Raney nickel or nickel oxide were tested. Those catalysts had very low resistance to gas flow; 90 percent lower than nickel granules used in previous experiments. In a single stage of synthesis thee nickel plates were only partially successful. Although the heating values of the product gas ranged from 856 to 941 Btu per cubic foot, the carbon monoxide content of he gas was above 0.1 percent. Both steel and wrought turnings were tested in single-stage synthesis, but the conversion of hydrogen and carbon monoxide was too low to attain the desired heating value of 900 Btu per cubic foot in the product gas. Assemblies of plates thermally sprayed with fusel iron were tried in an experiment to make gasoline. A gasoline yield of 52 percent (of the hydro¬carbons produced) was obtained using a 1H2-10O feed These sprayed assemblies were in service for 1,500 hours, the longest that this type of catalyst has been used. When a second reactor containing Raney nickel catalyst was added in series with the first reactor, complete utilization of the feed gas was obtained because in addition to the liquid product, a high-Btu gas with a heating value of 800 Btu per cubic foot was made.

Jan 1, 1965

By M. G. Zabetakis

The use of liquid hydrogen as a high-energy fuel introduces numerous hazards not ordinarily associated with the use of other more conventional fuels. These hazards are attributable to the unique properties of hydrogen in the liquid and gas states (table 1). Since little work has been conducted on explosion and related hazards of cryogenic fuels, a research program was undertaken to obtain basic data on such dangers for hydrogen and other combustibles under these conditions. These data were used to outline emergency procedures for protecting personnel and equipment when an accidental spillage of liquid hydrogen occurs and to establish a quantity-distance table for the storage of this fuel. The vaporization of liquid hydrogen from a surface is treated as a prob¬lem in heat transfer theory. Two extreme cases are briefly considered: (1) The transfer of heat occurs at constant temperature drop between, the boiling liquid and the hot surface, and (2) the transfer of heat is limited by the rate at which it can flow to the surface from a hot insulating medium. The available data indicate that the former case (1) is applicable when vaporizing from a conducting surface and, initially, when vaporizing from an insulating medium; the latter case (2) is applicable after initial flash vaporization has occurred from the insulating medium. The vaporization rate determines in part the rate at which flammable hydrogen vapor-air mixtures are formed above a spill area. However, the rates at which heat is transferred to the vapor, and air is brought in contact with it also are of importance. Accordingly, the distribution of flammable mixtures above a spill area was determined experimentally. In general, flammable mixtures were found to be both above and within the visible vapor cloud.

Jan 1, 1961

By E. W. Dean

In the early winter of 1919 the Pittsburgh petroleum laboratory of the Bureau of Mines undertook the work of testing fuel oil samples representing purchases of the United State Shipping Board for ships sailing from the port of New York. fuel oil was, at this time, being bought on a contract which involved specifications issued by the United States Navy under dace of October 2, 1920 (See Bulletin 1, Oil Division, U. S. Fuel Administration.)The object of the Bureau of Mines in undertaking this inspection work was twofold. (1) The Bureau was in position to give, and the Shipping Board needed, reliable laboratory service for checking the quality of the fuel oil purchased, the value of which ran into millions of dollars for,year's supply. (2) It was believed, and later demonstrated, that the existing specifications did not insure the obtaining of a reliably satisfactory quality of oil.The objection to the specifications concerned the employment of a clause limiting the gravity of the oil. The inadequacy of gravity specifications for several types of petroleum products has long been recognized, and there was every reason to reason to believe that they were no more desirable for fuel oil than for gasoline, kerosene, or lubricating oil. A first and obvious objection was the fact that it is somewhat difficult to make accurate gravity tests on ""heavy"" residuum fuel oils. (The Bureau found it necessary to employ or such tests a rather tedious procedure involving the use of a picnometer and an accurate balance, as the simpler methods, employing hydrometer or displacement balance, proved unreliable in a large proportion of cases.) A second and more important objection was that gravity tests, even when accurately made, do not provide a reliable index of the actual quality of the oil.

Feb 1, 1921

By Richard J. Mainiero, Marcia L. Harris

The New York State Department of Transportation recently commenced highway widening and drainage improvement projects in Clarence and Amherst, NY. Drainage improvements including the installation of storm sewer lines required excavation to a depth of 2.5 m (8.2 ft). In September 2002, NYSDOT stopped further blasting when 800 ppm CO was detected in the basement of a house near the blasting site. At the insistence of NYSDOT, the general contractor developed a new blast plan with the assistance of an environmental consultant. The plan provided for the installation of multi-gas monitors in buildings of special concern and/or with basements and residential type CO monitors in all other buildings within 100m (330 ft) of the blast. The multi-gas monitors would be remotely monitored. The plan provided action levels which would ensure public safety. The blast design was also modified to allow for better venting of CO. Blasts were limited to 20 ft lengths. The overburden was to be removed from the rock and blasting mats put in place to prevent flyrock. Approximately twenty feet of trench adjacent to the blast was left open to allow ground movement and gas release. The use of CO monitors was effective to alert occupants of a building to the presence of CO. The most effective appeared to be the residential type CO alarms with digital readouts. They were simple and easy to use and allowed the public to participate in the process. False alarms were repeatedly received with the more sophisticated instrumentation. Residential type CO monitors are preferable to warn people near blast sites. More sophisticated instrumentation should be avoided unless personnel are experienced in its use. A general overview of the blasting and monitoring is presented and discussed. The use and effectiveness of residential type CO monitors and multi-gas monitors are discussed.

By R. V. Ramani, R. Stefanko, G. W. Luxbacher

Comprehensive ventilation surveys are made to review the adequacy of the mine system with regard to both statutory requirements and/or company policy, to evaluate improvements to the current ventilation system and to plan for £stun expansion. If computer simulation is to be used for these purposes, accurate quantity and pressure measurements become an absolute necessity since the validity of the computer generated output is heavily dependent on the accuracy of the input data. Consequently ventilation surveys that are run to generate input data for computer simu¬lation must use the best data collection procedures to guarantee as accurate results as are possible. These requirements have led to modifications in procedures that are used for routine ventilation surveying. McElroy and Kingery (1957) have recommended that pressures be measured independent of quantities since minor changes in mine conditions have a greater effect on absolute pressure measurements than on quantity measure¬ments. They estimate that, for large mines, a pressure survey may take only 1 to 3 days while the corresponding quantity survey would require 1 to 3 weeks. Although this procedure would undoubtedly lead to more ac¬curate pressure measurements, its use for the development of computer input data is not recommended for the following reasons. Atkinson's equation, H = RQ2, is used in computer oriented analysis to develop the airway resistance, R, based on quantity and pressure loss measure¬ments. It can easily be seen that since R a 1/Q2 and R a H, the effect of errors in quantity measurement is, in fact, more significant than those in pressure measurement. If the quantity and pressure measure¬ments are made at different times another problem results. Minor changes in quantity that may occur in the time between the pressure and quantity

Jan 1, 1977

By J. W. Griflith, P. A. Mack, C. M. Lang, S. Riling

"N-acetyl-beta(B)-D-glucosaminidase is a N-acetyl-beta((B)-D-glucosaminidase enzyme se¬creted by alveolar macrophages in response to phagocytosis of particulate material. Alveolar macrophages participate in the degradation and fibrosis of pulmonary tissue that results in pneumoconiosis. Known quantities of four characterized respirable dusts were bronchoscopically placed into the right caudal lung lobe of macaque monkeys. Bronchoalveolar lavage (BAL) samples were collected from dust-exposed right lung and unexposed left lung of the same individuals at 2-week intervals for 12 weeks after dust instillation. The samples were tested for N-acetyl-B-D-glucosaminidase activity to determine if the enzyme levels could serve as an indicator of pulmonary injury induced by generic coal dusts when compared to known fibrogenic and nuisance dusts. Installation of generic quartz, anthracite, or TiO2 dusts produced significant elevations of enzyme activity and increased numbers of macrophages in the dust-exposed lobes. Elevations in enzymatic activity and macrophage numbers were greatest in response to generic quartz dust. These results suggest that quantitative levels of N-acetyl-B-D-glucosaminidase activity may be a useful indicator of acute and chronic lung injury following exposure to fibrogenic and nonfibrogenic dusts.IntroductionCoal workers pneumoconiosis (CWP) is an occupational pulmonary disease associated with the inhalation of coal mine dust. An important external factor in the development of CWP is the composition of the respirable coal mine dust. A cause-and-effect relationship exists between coal mine dust and CWP, but it has not been shown that exposure to generic coal dusts will cause CWP [12]. Numerous immunological, biochemical, and cellular changes occur in CWP; however, in this study, only N-acetyl-beta(B)-D-glucosaminidase (NAGase), protein, and alveolar macrophages (AM) will be examined [7, 32, 33]."

Dec 1, 1996

By Terry J. Close

At the request of the Idaho Congressional Delegation, the U.S. Bureau of Mines Western Field Operations Center investigated the mineral resources of the 140,000-acre Red Mountain roadless area, located northeast of Lowman, in central Idaho. The area includes U.S. Forest Service Red Mountain RARE II area (4-063). The highly mineralized road less area is underlain mainly by granitic rocks which are transected by a northeast-trending fault system. Associated with the granitic rocks and fault system are gold and black sand mineral resources. At least 1,395 ounces of gold and 858 ounces of silver have been recovered from six lode and placer mines within the roadless area. A total of 525 tons of columbium-tantalum, 2,049 tons of euxenite, 83.5 tons of columbite, and 54,862 tons of ilmenite concentrates have been produced from a nearby black sand mineral placer. Mine workings and facilities in the roadless area consist of two dismantled mills, 15 open and caved underground excavations totaling about 2,900 ft of workings, seven large pits and quarries, over 166 smaller dozer-and hand-dug prospect pits and trenches, and in excess of 66 drill holes. The mineralized sites in the roadless area are covered by about 690 current (1992) mining claims. About 130 individuals are holding the claims. Also within the roadless area are four patented lode mining claims. Twenty-five of the 54 mineralized sites identified during the study of the roadless area have, or likely have, mineral resources. One has gold and three have black sand mineral resources that are marginal or subeconomic. There also are two hot springs with thermal water resources, some veins that could be sources of decorative quartz, and dimension stone which was quarried in the past and could be again.

Jan 1, 1993

By S. R. B. Cooke, J. Bruce Clemmer, F. P. Diener

"The limestone deposit utilized by one of the plants of the Universal Atlas Cement Co. is covered in part by a stratum of cherty limestone. If this overlying deposit could be utilized by removing the excess of chert economically, quarry costs could be reduced and the amount of rock economically available would be increased greatly. On account of the distribution of flint and limestone, a product fairly free of flint can be obtained until the quarry face is about 50 or 55 feet high. As the face is worked farther back into the hill, the comparatively clean stone is overlain with a constantly increasing amount of high-flint limestone. If this flint remained with the limestone, there would be a prohititively high silica ratio in the finished cement; if the flinty layer were removed as overburden a very large tonnage would be handled and much good stone lost. Consequently it was felt that means should be devised for separating the flint from the limestone after it reaches the plant.The investigation was undertaken by the Mississippi Valley Experiment Station of the United States Bureau of Mines in cooperation with the Universal Atlas Cement Co. and the Missouri School of Mines and Metallurgy, Rolla, Mo.CONSIDERATION OF PROCESSESMany schemes for the separation of Minerals are based on differences in the specific gravities of the minerals to be separated. In this case the flint has a specific gravity of approximately 2.62 while the limestone averages about 2.70. This differential is not large enough to permit separation by any method based on specific gravity. Furthermore, all the limestone particles in any given sample are not alike; usually about 10 percent of them have a specific gravity the same as, or lower than, the flint."

Mar 1, 1935

By B. R. Mohal, S. Chander

"The adsorption and wetting behavior of freshly ground and aged coals has been determined in the presence of a nonionic surfactant. The amount of surfactant adsorption changes with the concentration and ""age"" of the coal. The freshly ground coal has smaller amounts of adsorption at lower surfactant concentrations than the ""aged"" coal whereas at large surfactant concentrations, the order is reversed . In the latter case, more surfactant is adsorbed on fresh coal than on the ""aged"" coal . . It is proposed that at low concentrations, the surfactant adsorbs through both hydrophobic and hydrophilic interactions with the molecule lying parallel to the· surface, whereas at higher concentrations surface micelles form at the hydrophobic sites. The wetting behavior correlates well with the adsorption behavior.INTRODUCTIONNonionic surfactants have many applications in the coal and mineral processing industry. They can be used as dispersing agents to modulate flotation, flocculation and filtration of particulates (1). They can also be used to increase the wettability of hydrophobic solids such as coal and can hence be used as dust suppressants (2,3). Although the adsorption of representative nonionic surfactants such as Triton N-101 (an ethoxylated nonylphenol with 9.5 moles of ~thylene oxide and HLB equal to 13.4) have been studied extensively on substrates such as calcium carbonate (4), silica (5) carbon black (6) and graphite (7), very few studies are available for coals. Coals differ from other substrates with respect to two important characteristics: 1) coal are porous and 2) coals consist of a patchwork of hydrophobic and hydrophilic sites (8). Since the adsorption characteristics of a surfactant are influenced significantly by the nature of the substrate the characteristics of the coals must be taken into consideration."

Jan 1, 1989

By Roy H. Grau, John C. LaScola

"This Bureau of Mines report contains a tabulation of methane emissions during 1980 for all coal mines located in the United States with emissions greater than 0.1 MMcfd. Listed for each mine are methane emission quantity, location, and coalbed. The report also compares records of 1975 and 1980 and describes relationships between emissions in 1980 and the Bureau's coalbed gas content data on 11 mines.INTRODUCTIONMethane gas is a threat to safety in underground coal mines. Research by Government and industry has led to great gains in reducing methane gas ignitions and explosions. The development of advanced methane control techniques is necessary for the safe operation of more gassy mines and the implementation of rapid mining techniques.As part of this research, the Bureau of Mines has surveyed total methane emission data from underground bituminous coal mines in the United States and tabulated emissions from mines producing over 0.1 MMcfd of methane. This report is an update of similar studies previously described in Information Circulars 8733, 8659, and 8558 (2-4).3The data from 1980 were compiled from Mine Safety and Health Administration (MSHA) records of air quality-quantity inspections made quarterly at each mine. The inspections involve measuring airflow and collecting air samples in the main returns. From these data, an average methane emission is calculated and used to represent the daily mine emission for each quarter. The methane emissions given in this report are the averages of the four 1980 quarters and do not include mine emissions from other sources such as degasification projects. Since a previous Bureau study showed that emissions from mines emitting less than 0.1 MMcfd represented only 2 pct of all emissions, 0.1 MMcfd was chosen as a lower limit for data collection (4)."

Jan 1, 1982

By G. Nuñez, M. A. Pathak, C. F. Stanley

"A 1986 report by the U.S. National Committee on Blomechanlcs (1) describes lung disease as a major national health problem. The report cites three areas that would benefit from a better understanding of the vibratory patterns of the lung. These areas are outlined below.1. In cases of respiratory distress, pressure driven artificial respirators are used. A new technique using high frequency respiration is quite promising, but the pressure distribution in the lung as a function of frequency is not yet known. At these frequencies of 1 to 60 Hz, the lung expands asynchronously (2) and a better understanding of these expansion nonunlformltles could provide valuable Information about the mechanics of high frequency ventilation.2. Listening to the sounds In the lung can yield valuable Information about the state of the lung. To improve the technique, a better understanding of how acoustic waves propagate through the lung is needed.3. The response of the lung as It Is subjected to acoustic excitation, dynamic loading or shock waves is not well understood. A better knowledge of these responees can lead to improved treatment for patients subjected to either explosive pressure waves or car crashes.4. Researchers are measuring the acoustic Impedance of the Iung to detect early states of dysfunction. Sneckenberger and Whitmoyer (3) have reported Impedances obtained at acoustic frequencies up to about 6000 Hz. However, It la not certain which parts of the lung are responding to the acoustic excitation.To Investigate the vibratory characteristics of the lung, excised rat lungs were excited via the trachea with acoustic waves at frequencies up to 6000 Hz. Thie paper describes an Instrumentation system, utlllzlng time-averaged holographic Interferometry, to detect and quantify the response of the lung surface to the acoustic excitation."

Jan 1, 1989

By T. F. Dumm, L. G. Austin

"INTRODUCTIONGomez and Austin (1,2) have recently described calibration procedures for quantitative chemical analysis of particles by energy dispersive spectroscopy using particles mounted and polished in a resin matrix and scanned by an SEM under computer control. Their software is specifically designed for the analysis of Si, Al, Ca, Na, K, Fe and S in coal particles, and in this case the resin is loaded with iodine (3) to enable the exposed cross-section of an embedded coal particle to be differentiated from the matrix. However, the basic ideas of their procedures could be extended to any system of particles where it is desired to measure inorganic species in particles containing light elements such 0, C, H and N which are not directly detected. In these circumstances it is necessary to perform a quantitative determination of the measured components, so that the equivalent volume of light elements in the excited sample volume can be estimated by difference using ZAF and other corrections applied to the raw count intensities.Part of their procedure involves a new technique (2) for estimating background spectrum intensities; the intensity for a particular energy window is then subtracted from the total measured intensity for that window to enable the concentration of the corresponding element to be calculated. In addition, corrections for overlap of peak spectrums are applied. For example, Figure 1 shows some typical spectrums for known materials for the system they used, demonstrating a wide Gaussian spread about the theoretical peak energy. Since background spectrum and peak overlap corrections require a knowledge of the composition of the material, as does the application of the ZAF corrections, it is necessary to have an iterative solution of the equation sets, starting with estimates of the composition based on initial count rate corrected solely for dead time and detector efficiency."

Jan 1, 1989

By H. H. Schrenk

[A colorimetric method5/ for the determination of benzene in amounts as low as 0.001 mg has been developed recently at the U.S. Bureau of Mines Pittsburgh Experiment Station by the authors, with the assistance of chemical personnel fro a the Allegheny County (Pa.) Relief Works Division. The method is based on the direct nitration of either liquid - or gas - phase benzene, followed by neutralization, extraction with butanone, and final treatment with sodium hydroxide which produces a violet color. The color is matched with color standards of known values. Although the method is adaptable to many conditions the primary objective was a procedure that would be suitable for hygienic investigations. The development worth included a study of possible interference by chemicals that be present in those situations in which the method. would be employed. In this study it was found that a specimen of hexane prepared by the Gulf Research Laboratory, Pittsburgh, by fractionation of West Virginia natural gas gave positive result for benzene, whereas a specimen of pentane prepared in the same manner showed only a trace, and specimens of n -heptane and octane (2,2,4 trimethylpentane) supplied by Eastman Kodak Co. save a negative result. According to information obtained from the Eastman Kodak Co. the latter two compounds were highly purified, the n-heptene being prepared from line and the octane synthesized in the laboratory. On nitration of a larger amount of tae natural hexane a visible quantity, of needlelike crystals which resembled those of m-dinitrobenzene was obtained. The hexane from this nitration was recovered by distillation and again nitrated, but no crystals or colorimetric indication of benzene was obtained. This imitated that the specimen of natural hexane contained a substance which at least had the chemical behavior of benzene.]

Jan 1, 1935

By R. L. Grayson, T. Simonyi, R. A. Andrel

"The purpose or this paper is to disclose analytical, statistical, and observational results relating to mineralogy and trace elements in respirable dust samples collected from two different mines in West Virginia. Samples were taken from longwall panels, and the panels operated in different coal seams, one located in the northern part or the state and the other in the southern region. Mining conditions and equipment arrangements on the panels will be described along with dust control techniques used. Results from sample analyses are summarized with emphasis on relationships between mineralogy, trace elements and mineral particle size to worker locations. Correlations are made between micro x-ray diffraction and energy dispersive x-ray analyses for sample mineralogy.IntroductionThrough the work of many researchers worldwide, the health of coal miners in modern societies is now protected from harmful exposure to respirable coal mine dust. A vast amount of research culminated in the exposure-response model of Jacobsen, et al, (l) which has been used to establish the 2 mg/m3 exposure limit in the United States. According to the model exposure to respirable dust for 35 years at this level or less could prevent the occurrence of a clinically significant case of coal workers' pneumoconiosis (CWP) in a miner. The exposure limit, of course, must be adjusted whenever greather than five percent free silica exists in the respirable dust.The Jacobsen model was built around a mean mass concentration exposure, which generally showed the highest correlation with both incidence and progression of CWP. As Morgan, et al noted, however, the quantity of respirable dust inhaled is not the only significant factor. 2) They noted that although mass of respirable dust correlates highe.st with the incidence of CWP, it is not a causal factor. Admittedly, the insidious processes causing the disease occur at the lund cell-dust particle level."

Mar 1, 1989

By J. W. Thompson

That the governor is hereby authorized to appoint a commission of seven persons, to be known as the industrial accidents commission-two of whom shall be employers of labor, two of whom shall be employees in either mines or industrial establishments of this Commonwealth, or duly accredited representatives thereof, two of whom shall be learned in the law, and one of whom shall be a person skilled and experienced in making investigations-to inquire into the causes and results of industrial accidents in the mines, mills, factories, stores, and upon the railroads, street railways, ships, wharves, and in all industrial establishments, and in all other places where men, women, and children are employed in manual labor in this Commonwealth; to study the most advanced methods for safe-guarding against these accidents; to inquire into the subject of fair compensation for those who are injured in these accidents, and for the families of those who shall be killed as a result thereof; and to study the operation and effect of the Workmen's Compensation Law of 1913. SEC. 2. The chairman of said co~mission shall be designated by the governor, and the person named on said commission as a skilled and experienced investigator shall be the secretary of the commission, The commission shall have power to employ such legal counsel and other officers and employees as it may deem necessary to properly perform its duties. SEC. 3. The secretary of said commission shall receive an annual salary of $2,400 and his actual necessary expenses; and the other members of the commission shall receive no compensation for their services, but shall be allowed their actual traveling and other necessary expenses. The salaries of any other persons employed by the commission shall be fixed by it.

Jan 1, 1920

Provide a machine for economically drilling probe holes in coal mines (required where there's a possibility of unmapped, abandoned workings) to check for possible water flood or gas hazards ahead of the face. Approach A lightweight air-powered drill, that mounts on a light-weight frame anchored to the face with an expandable packer, is used to drill one or more probe holes. The anchor installs quickly and will lock the drill in any desired position. How It Works The drill is portable and can be broken down to small components for ease of transportation. One man can carry these sections through restricted access routes to the working place. Components that are separable are the anchor assembly, drill frame assembly, and drill motor assembly. The drilling sequence is as follows: A 2-inch-diameter anchor hole is drilled 2 feet deep. The fixed anchor tube is rubber packer is expanded. A second anchor hole is drilled through a bushing in the anchor frame. The removable anchor tube is inserted and its rubber packer expanded. (This anchoring system withstood pulls of up to 14,000 pounds.) Next, the frame is attached to the anchor with two screw knobs, and the motor is attached to inserted in the hole and the rubber packer is expanded. A second anchor hole is drilled through a bushing in the anchor frame. The removable anchor tube is inserted and its rubber packer expanded. (This anchoring system withstood pulls of up to 14,000 pounds.) Next, the frame is attached to the anchor with two screw knobs, and the motor is attached to the frame with a single locking pin. Installing the anchor and drill takes less than 12 minutes.

Jan 1, 1981