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By Wiraseranee. Chompunoot, Kazuki Morita, Toru H. Okabe

"Aiming at the development of more effective recycling processes, dissolution behavior of rhodium into molten slag was investigated. Using a pure rhodium crucible and Na2O-SiO2 slag system, equilibration experiments were carried out for 18 h at 1423-1623 K under various oxygen partial pressures of 0.005-1 atm with varied slag basicity. Rhodium solubility increased with increasing oxygen potential, slag basicity, and temperature. Rhodium dissolved into slag as rhodate ion ([RhO2]-) by the endothermic reaction: Rh(s) + 3/4O2(g) + 1/2O2-(in slag) = [RhO2]-(in slag). In the dissolution reaction, the “rhodate capacity” of slag is newly-defined. The correlation between rhodate capacity and optical basicity is reported.IntroductionDue to its high chemical resistance and outstanding catalytic properties, rhodium (Rh), one of the platinum group metals (PGMs), is utilized in various applications such as catalysts, molten glass vessels and containers, and electronic devices. Owing to the rarity of Rh resources in nature, recycled Rh from scraps such as spent automobile catalytic converters is currently considered as an important source of Rh supply [1]. According to the recycling practices, Rh is currently mainly recovered from scraps along with other PGMs such as platinum (Pt) and palladium (Pd) by a dry process (e.g., smelting), a wet process (e.g., leaching and subsequent separation of PGMs from aqueous solution), or a combination of both processes [2]-[4]. Among these processes, smelting is commonly applied because PGMs can be effectively separated from a relatively large amount of various impurities coexisting in scraps. In the smelting process, Rh and other PGMs are collected in the collector metal (e.g., iron and copper), and impurities in scraps are removed into slag [4]-[6]. The process may be carried out at a temperature range of 1573-1973 K, in either an oxidizing or reducing atmosphere. Due to the high oxidation resistance at high temperatures, Rh is expected to be collected efficiently in the metal collector rather than being oxidized and forming RhOx in a molten slag. However, Rh loss into slag does occur in this process [7]."

Jan 1, 2011

By C. H. P. Lupis, Henri Gaye

There are m -I conditions for the stability of a solution of m components with respect to infinitesinzal flucturations. However, in most cases, only one of these conditions has to be considered to determine the domain of instability and the existence of this more restrictive condition greatly simplifies the calculations. It may be used advantageously for the prediction of miscibility gaps and the method is illustrated in details for the case of the Ag-Pb-Zn system. THE thermodynamic conditions for the formation of a miscibility gap may be viewed as a necessary consequence of the conditions for spinodal decomposition. A previous article1 has examined in detail the form of these conditions for multicomponent systems. There is only one condition for the stability of a binary system (with respect to infinitesimal fluctuations), but there are two conditions for a ternary system, and m — 1 conditions for an m-component system. The probability of violating a stability condition, and thus forming a miscibility gap, obviously increases with the number of components, a result which is rather intuitive since the atoms of the solution have now many more ways of redistributing themselves and introducing complexities in the form of the free energy hy-persurface. It is of interest to take advantage of this possibility of precipitating new phases and to examine which stability condition is the likeliest to be violated, that is, which stability condition is thermodynamically the most restrictive. The finding of such a condition would greatly simplify the application of the stability criteria since only one condition could then be considered, instead of m - 1. In Ref. 1, coherency strain energy terms were neglected, thus restricting the applications of the treatment to solutions where they are negligible, such as liquid alloys. In the following study the same assumption will be made. To generalize the treatment to systems where the strain energy terms are sizable, the reader is referred to Cahn's classical article on spinodal decomposition.2 Let us designate by Gij the second derivative of the Gibbs free energy with respect to the number of moles ni and n j. There are several equivalent sets of m — 1 stability conditions.' The one considered here expresses that the successive diagonal determinants of order 1, 2, ... m — 1, associated with the symmetric Gij matrix (for 2 5 i, j 5 m) are positive.' For a binary solution 1-2, the condition for stability is: O(u=G22^0 [1] For a ternary system 1-2-3, the condition [I.] is re- tained (the value of G22 will differ, of course, according to the concentration of 3) and another condition is introduced: £>(21 = G22G33 - Gl3 ^ 0 [2] In a composition diagram, these two conditions define two domains of instability. Starting at a point where the solution is stable (for instance at a point where the solution is very dilute) we gradually change the composition until the condition [I] or [2] is violated. As already noted in the literature, e.g., in the work of Prigogine and Defay,3 it is the boundary of the domain (2) which is first crossed. For if we assume that the boundary of the domain (1) is reached first, at this point G22 = 0 and the second condition is necessarily violated (D(2) = -& 5 0), in contradiction with our original assumption. An exhaustive study of the ternary regular solution case may be found in the work of Meijering.4 Moreover if the boundaries of the two domains have a common point, they also have a common tangent. For if the two lines were to cross each other as is illustrated in Fig. 1(a) any point M in the line QP would be such that £> = 0 and 0"' > 0 which, as shown above, are incompatible results. Thus, the two lines must be tangent at their common point Q as illustrated in the example of Fig. l(b). The reasoning of Fig. l(a) implies that the point Q is not a "singular" point for either boundary line. This singularity may be of two types. First, the lines meet without crossing each other and without being tangent. Second, the tangent at Q for D"' or 0"' is not single-valued. Other types of singularity are unlikely because of the usual analytical forms of D"' and 0"'. The exception to the common tangent requirement due to the first type of singularity was pointed out by John Morral;5 it occurs when the common point, Q' or (3" in Fig. l(b), is located at a boundary of the composition diagram, e.g., at the line X3 = 0. It may also be noted that at the common nonsingular point Q of D(1) and D(2), Fig. 1(b), G23 is necessarily equal to zero, whereas at a point such as Q' or Q", this conclusion is no longer valid because the product G22G33 is now indefinite (of the form 0. a). The exception to the common tangent requirement due to the second type of singularity occurs when two branches of the same boundary line intersect, for example when D(1)or D(2) decomposes into a product of functions, at a point which belongs to the boundary of the other condition. It is possible to show by a simple analytical calculation that, in this case, if Q is a singular point of D(1), then it is necessarily a singular point of D(2), and that the reciprocal is true except if G33 = 0 at Q. For the present article, however, more elaboration on these singularities appears to be unwarranted. To generalize the previous results to an m -component system, we use the mathematical theorem stating that if the diagonal determinant D(r) = 0, then

Jan 1, 1970

By R. von Bonsdorff

Electrochemical and quartz crystal microbalance (QCM) methods were used to investigate the dissolution rate of gold in a solution similar to those utilized by the Outokumpu HydroCopper® process. The measurements were conducted in an electrolyte solution where [NaCl] = 2.8-280 g/L, pH = 1-2.5, [Cu2+] = 0-30 g/L and T = 70-95°C. According to these measurements, the solution flow has the greatest impact on the dissolution rate of gold in the HydroCopper® process. Under adequately acidic conditions (pH < 3), the dissolution rate of gold increases with increasing cupric concentration, increasing chloride concentration and increasing temperature. The results and trends observed compared well with the literature.

Jan 1, 2007

By Shize Jin

Effect of four polyols, namely ethylene glycol (EGL), glycerol (GCL), propanediol (PDL), butanediol (BDL) and three organic acids, namely oxalic acid (OA), malonic acid (MA) and succinic acid (SA) on the current efficiency (CE) and the cell voltage during zinc electrowinning was studied. Galvanostatic polarization was conducted in a supporting electrolyte (SE) containing 180 g dm-³ H2SO4, 60 g dm-³ Zn2+ and 8 g dm-³ Mn2+ at 38°C with magnetic stirring. The imposed current density was 50 mA cm-². The anodes were made of a Pb-Ag alloy and the cathodes were made of an aluminum alloy. The results showed that all the polyols tested in this study decreased the current efficiency and the cell voltage, but the decrease of the cell voltage was not important. Oxalic and succinic acids decreased the current efficiency to a less extent than the polyols, but did not decrease the cell voltage much. The only compound that increased the current efficiency was malonic acid, and its capacity of decreasing the cell voltage was the highest within the seven tested organic compounds.

Jan 1, 2003

The drill steel&apos; sharpening shop, which stands adjacent to the Chaffers shaft, is built to the dimensions of 110 ft. 9 in. by 58 ft. wide, and is air conditioned in order to maintain reasonable working conditions during the summer months.Figure 1 is a plan of the shop, showing the disposition of the machines and equipment.LIST OF STEEL SHOP EQUIPMENTAir Conditioning Plant comprising:-1 Spray and Eliminator Type Air Cooler, 6&apos; ft. x 7 ft. x 6 ft. with 80 fine sprays.1 No. 36 Keith type ER. Ball Bearing upcast multivane centrifugal fan.20,000 cfm. a in. WG. at 450 r.p.m.Fan motor, A.G.E. S.C. 10 h.p. 1,160 r.p.m.1 Water Pump. 2?!-3-in. Thompson Class G. Single Stage Centrifugal Pump.1 Pump Motor, A.G.E. S.C. 70 h.p. 1,160 r.p.m.Drill Steel Sharpening Equipment:-2 Holman Sharpening Machines, No. 11.1 Ingersoll Rand Sharpening Machine, No. 54.5 Ingersoll Rand Sharpening Machines, No. 50.2 Holman Hot Millers, Type DM. Double Spindle Machines.2 Morgan Hot Millers, Type 1.6 Reamers consisting of motors with Ingersoll Rand Chuck fitted to the shaft and carrying a reamer of i-in. square Ultra Capital Steel Motors, A.G.E. S.C. 1 h.p. 1,160 r.p.m.4 Double-sided Drill Sharpening Furnaces, oil fired with L.P. &quot;Major&quot; 2-in. non-rotary whirl type burners.Combustion Chamber, 2 ft. 4 in. x 6 in. x 12 in. Oil consumption, 3&#183;3 to 3&#183;8 gallons per hour.Furnace Lining, Standard Kyanite.Firebricks, 9 in. x 3 in. x 4 in.2 Moving Frame type double-sided tip hardening furnaces, oil fired using High Pressure Air reduced to 3 lb. per square inch.Combustion Chamber, 3 ft. 5 in. x 5 in. x 16 in.Burners, &quot;Major&quot; L.P. 2-in. non-rotary whirl type.Oil consumption, 3&#183;3 to 3&apos;8 gallons per hour.Furnace lining-bottom and sides, 60 only 9 in. x 3 in. x 4 in. Kyanite bricks.

Jan 1, 1941

By Cyro Takano

This paper is a contribution to fundamentals data on the equilibrium metal/slag for refining silicon in relation to Ca and Al as impurities. Silicon containing 0.1% Al and no Ca was placed in contact with a slag of various contents of CaO, SiO2 and Al2O3. Slag Al2O3 contents were 11.4%, 25.1% and 29.6%, keeping the ratio %CaO/%SiO2 constant and equal to ~0.53. The experiments were conducted at 1550oC, in a graphite crucible with argon atmosphere. The equilibrium was observed with low and medium content of Al2O3. The derived activities coefficients of Ca and Al in dilute solution of Si presented good correlation with those of the literature. Parallel reactions with formations of SiO(g) and CO (g) were also observed.

Jan 1, 2006

By Madgwick J. C

Microaerobic biodegradation oflow-grade manganese dioxide slurry tailings was demonstrated in enrichment cultures treated with dilute molasses at 30&#176;C and pH 5&#183;8. Supplementary nitrogenous nutrients, yeast extract addition and pH adjustment were not required.Continuously stirred, air-limited reactors were superior to still intermittently agitated cultures, in that, at 5 per cent (w/v) MnOz tailings and 5 per cent (w/v) molasses, the yield of 0.12 g Mn++/g molasses, the rate ofleaching of 1&#183;06 g Mn++/l/d and a recovery of Mn++ of 58 percent from MnOz were 2&#183;8 times, 1&#183;7 times and 1&#183;9 times greater, respectively. The best compromise in yield (0&#183;45 g Mn++/g molasses) and rate ofdissolution (0&#183;73 gMn++/l/d) was at 1 per cent (w/v) molasses in a stirred reactor.Where leaching organisms were separated from sterile ore by a bacteria impermeable membrane leaching was shown to be some 20 per cent due to diffusible metabolites and 80 per cent due to a direct contact between the bacteria and the ore particle&apos;s surfaces.

Jan 1, 1986

Mirador - Overview ? Located in Andean foothills of SE Ecuador ? Copper-gold porphyry hosted by calc-alkaline Late Jurassic granitic and porphyritic rocks ? 438 MT of 0.61% Cu and 0.19 g/t Au measured and indicated resources (at 0.4% Cu cut-off) ? Additional inferred resources of 235 MT of 0.52% Cu and 0.17 g/t Au ? Initial 25,000 tonnes/day production, expanding to 50,000 in year 6 320 MT of 0.62% Cu, 0.2 g/t Au ore mined at an average 1.4:1 strip ratio over a 21 year mine-life

May 1, 2006

By Carvalho A. Felipe de

The search for environmentally friendly and cost-effective methods for gold extraction has been undertaken in order to provide alternatives to the use of cyanide leaching in the gold industry. Among such alternative reagents is the combination of chloride and hypochlorite ions due to their oxidation of metallic gold and its complexation. Therefore, the current work aims at investigating gold leaching from an oxidized material by means of a solution comprising calcium hypochlorite and sodium chlorite. The sample used in the current research contained 66.1% Fe2O3, 20.4%SiO2, and 35.7 g/t of Au. In addition, XRD and SEM-EDS analysis revealed iron oxide, quartz and muscovite as the main crystalline phases in the sample. For comparison purposes, cyanidation of the oxidized material resulted in 90% gold extraction in 24 h. The reference conditions for the leaching tests with the chlorite-hypochlorite system were: particle size −37 μm, solid/liquid ratio of 10% (w/v), 10 g/L NaCl, 10 g/L Ca (OCl)2, pH 5–6, 3 h of leaching. The effects of the: (i) Ca(OCl)2 concentration, (ii) NaCl concentration, (iii) pHrange and (iv) the effect of pulp density in the extraction of gold were assessed. In addition, the stability of the hypochlorite solutions (OCl−) was investigated. The ideal concentrations of Ca(OCl)2 and NaCl were determined as 25 g/L and 15 g/L, respectively, whereas the optimal pH range was 4–6. Under these conditions, the final gold extraction reached approximately 84%. By varying the solids content of the pulp (10%, 20% and 30%), it was observed that the lower solids value resulted in greater gold extraction (84%). The degradation of the hypochlorite solution and the possible catalytic effect of the presence of the solid were evidenced. To sumup, in the experiment, high gold extractions were achieved in shorter periods of time (3 h), as compared to the cyanidation of the same sample. On the other hand, itwas necessary to use significant amounts of the reagent due to hypochlorite instability at the pH conditions recommended for high gold extractions.

By Bulters J, Sheppard I

Two blasthole density logging programmes have been conducted on the Mt Whaleback iron ore mine to evaluate the use of this type of logging as an aid to blast pattern design. The first programme also involved the setting up of a Density Test facility with which to calibrate the density probe. The programmes indicated that about 22-23 blastholes can be consistently logged per day at a cost of $1.30 per metre. Even though this is only half the rate required to log the average number of blastholes drilled daily on Mt Whaleback, testwork indicated that no significant loss of accuracy results if only half the holes in a pattern are logged. The major results of the programmes were: 1. The density range for black pyritic Shale is 2.2-2,9 g/cc. 2. The density range for soft to medium hard BIF is 2.1-3.0 g/cc. 3. The density range for hard BIF is 3.0-3.6 g/cc. 4. The front row blastholes show consistently lower densities than the main body holes due to blast damage. 5. A low density zone extending to a maximum depth of 6 m occurs at the top of most blastholes and results from blast damage from the bench above. These density results have been used to implement savings in drilling and blasting via pattern expansion and charge optimisation of blastholes. Eight ore

Jan 1, 1986

By Eric Barnard, Andreas Nashitati, John Tero, Guy Deschênes, Setta Mbalamba, John Rajala

The Otjikoto Mine, owned at 90% by B2Gold Corporation, is located 300 km north of Namibia’s capital city of Windhoek. The reserves from the open pit mine, estimated at 25.9 million tons with an average grade of 1.28 g/t Au, contain gangue minerals, pyrite and pyrrhotite, and have an estimated 10 year mine life. The feasibility study included an optimisation of gold leaching using CSTR for the original design. The results of the test work were used to establish the design criteria. Gravity tails from three composites (drill cores), representing the major ore types, were used. The XR3 sample (gravity tails) contained 0.32 g/t Au, while the XR2 and XR1 gravity tails samples (used for variability) contained, respectively, 0.30 g/t Au, and 0.47 g/t Au. The optimum leaching conditions were: a pre-treatment of 7 h at pH 10.5 with 100 g/t lead nitrate, DO > 5 ppm followed by cyanidation at 300 ppm NaCN, pH 10.0, DO > 5 ppm for 48 h. The gold extraction was 91.5% (97.2% overall extraction gravity/leach) and the cyanide addition was 0.57 kg/t NaCN. Increasing the DO to 16 ppm did not show any economic benefits. No pre-treatment or a 4-h pre-treatment reduced the gold leaching kinetics. The XR2 and XR1 gravity tails samples had gold extractions of 92.9% and 92.3%, respectively. At the plant scale, an 11 h pre-treatment is used followed by 42 h cyanidation with 250 ppm NaCN and an average DO of 8 ppm and 230 g/t lead nitrate in 2016. The cyanide addition was 0.49 kg/t NaCN. The commercial operation started on February 28th, 2015. The overall gold recovery and production were 98.4% and 145,696 ounces for 2015 and 98.1% and 166,286 ounces for 2016. It was found that retention times, gold content of leach residues and cyanide addition are comparable for the lab and the plant. Details of the Otjikoto process flowsheet are discussed in this paper along with the results of the lab leach optimisation test program and the plant leach circuit performance and improvements.

Jan 1, 2017

By Y. Lin

It is difficult to remove arsenic and bismuth from antimony in the process of crude electro refining. The electro refining of antimony has been studied using ammonium fluoride-antimony sulphate electrolyte system. The Influence of temperature, current density and additives on arsenic and bismuth removal from crude antimony has been investigated in this paper. Optimum process parameters, namely, temperature of 25?, current density of 400A/m2, distance between anode and cathode of 50mm, electrolytic period of 24 hours, oxalic acid dosage of 10g/L and complexon III dosage of 0.2 g/L have been ascertained.

Jan 1, 2014

By F Gervilla, J Laukkanen

The Kevitsa Ni-Cu-PGE deposit in northern Finland contains disseminated Ni-Cu-Fe sulfides, and platinum-group minerals (PGM). The 2.05 Ga-old ultramafic-mafic, funnel-shaped intrusion is intruded into a volcanosedimentary sequence. The major ore minerals are pentlandite, hexagonal pyrrhotite and troilite, chalcopyrite, cubanite and magnetite. Pyrrhotite and pentlandite are replaced by pyrite, millerite and heazelwoodite near the surface. Nickeline, maucherite and gersdorffite are locally abundant. A pilot feed sample of 575 t of the main orebody at Kevitsa had average grades 0.45 per cent Cu, 0.36 per cent Ni, 1.85 per cent S, 0.33 g/t Pt, 0.34 g/t Pd and 0.19 g/t Au, with 0.06 per cent Ni contained in silicates. Higher PGE contents (2 - 27 ppm) occur in a vertical N-S bearing fault zone. The PGM (n = 6022) mapped in specimens of four drill holes, consist of sperrylite 34.7 vol per cent, braggite and cooperite 18.5 vol per cent, geversite 17.2 vol per cent, moncheite 14.7 vol per cent, merenskyite 6.7 vol per cent, stibiopalladinite 4.3 vol per cent, sobolevskite 1.9 vol per cent, kotulskite 0.7 vol per cent, michenerite 0.6 vol per cent, keithconnite 0.3 vol per cent, rustenburgite 0.1 vol per cent, melonite, froodite, laurite together 0.1 vol per cent and only a few grains of sudburyite, irarsite, vysotskite, erlichmanite, hongishiite, Pt-Cu-alloys, three undefined Pd and Pt bismuthinides and antimonides and a Pd-Cu-bearing Pt-Ni-Fe sulfide. Most of the PGM, 62 per cent, are enclosed in silicates, 29 per cent are intergrown with sulfides, nine per cent are within sulfides. A portion of the PGE occurs in solid solution in sulfides and arsenides. Ni flotation yielded smelter-grade concentrates averaging 12.2 per cent nickel. The average sulfide Ni recovery is 78.8 per cent and total Ni recovery is 65.3 per cent. The average Pt is 10 g/t at 55 per cent recovery, Pd 7.7 g/t at 38 per cent recovery and Au 1.6 g/t at ten per cent recovery. Cu concentrates averaged 28.6 per cent Cu with an average recovery of 78 per cent and further 11 per cent in the nickel concentrate. The copper concentrate contains 4 g/t Au at 24 per cent recovery. The average Fe to MgO ratio 17.9 is well above the targeted minimum of 4.5. The pilot results show that the previously used TETA (triethylene tetramine) can be avoided and good quality, smelter-grade concentrates can be produced from the Kevitsa ore at economical levels of recovery by conventional flotation methods.

Jan 1, 2008

PolyMet Mining is developing the NorthMet property near Duluth, MN. Laboratory investigations have led to the development of the Platsol process to dissolve in one step the base metals (copper and nickel) as well as the gold and platinum group metals (PGM). To complete the prefeasibility study, a fully integrated, 10-day pilot plant trial was undertaken. The trial consisted of high-temperature (>220ºC or >428ºF) pressure oxidation in the presence of 5 to 10 g/L chloride (the Platsol process). This was followed by solid/liquid separation, gold plus PGM recovery from solution, conventional copper solvent extractions/electrowinning (SX/EW) and recycling of the copper raffinate to the autoclave. The concentrate tested during the trial period was a NorthMet bulk flotation concentrate. It assayed 14.7% Cu, 3.05% Ni, 0.14% Co, 26.7% S, 1.4 g/t (0.041 oz/st) Au, 2.2 g/t (0.064 oz/st) Pt and 9.9 g/t (0.289 oz/st) Pd Laboratory results were confirmed and, with minor adjustments of the laboratory Platsol conditions, the following leach extractions were obtained during the pilot plant trial: 99.6% Cu, 98.9% Ni, 96% Co, 94.6% Pd, 96 % Pt and 89.4 % Au.

Jan 1, 2003

By T. G. Carnahan

The Bureau of Mines conducted laboratory-scale weathering research on a leach residue containing elemental sulfur and mixed metal sulfides. Experiments were performed to determine pH and impurity element concentrations in the effluents as functions of time and to determine the effects on effluent concentrations of mixing the residue with dolomite tailing material. Four 800-day tests were conducted simultaneously. Soluble metal concentrations, especially zinc and copper, were excessive in the effluents from washed and unwashed samples of the residue. Concentrations of up to 20 g/l of Zn and 12 g/l of Cu were obtained. The pH values of the unwashed and washed residue effluents at the completion of the experiments were 2.8 and 1.9, respectively. Sulfuric acid from oxidation of pyrite caused the pH decrease. Mixing unwashed residue with dolomite tailing to maintain a near-neutral pH minimized the heavy metals content in the effluents. The pH in the dolomite tests increased slowly after the first 360 days and attained values of 7.8 and 8.2, respectively, for tailing containing 1 pct leach residue and for tailing devoid of leach residue. Dissolved zinc and copper did not exceed 0.10 g/l of Zn and 0.001 g/l of Cu.

Jan 1, 1982

By George Owusu

A study has been carried out on the use of solvent extraction, instead of the traditional zinc dust cementation process, to remove copper from concentrated zinc sulphate leach solutions. In a series of experiments using plant solution containing 1.9 g/L Cu, 2 g/L Fe, 173 g/L Zn, 7.9 g/L H,SO,, 0.25 g/L Cd, 15 mg/L Co etc. and LIX 622 in SX-1, up to about 97-98 % of copper present in the zinc sulphate leach solution was extracted with negligible co-extractions of zinc, iron, cadmium, cobalt, etc. pH modification was not required for this reagent. The copper loaded organic was almost completely stripped using 150 g/L sulphuric acid. Investigations into the effect of any possible organiclextractant contamination on zinc electrowinning showed (if any) little effect on current efficiency if the organic contamination is less than 45 ppm; current efficiencies of 95-97 % were obtained. At organic contaminations higher than 45 ppm, the current efficiency dropped to about 92- 94 %. Visually, the organic-contaminated cathode sheets had rough surface morphology, becoming more intense with increasing organic concentration, compared to the non-contaminated cathode sheets.

Jan 1, 1998

By Amilton Feliciano Castro

In this work, activated carbons (ACs) were prepared using Sewage sludge as starting material. The ACs were pyrolyzed in an inert atmosphere at 550 °C after independent chemical treatment with ZnCl2 or KOH with ratio of 1:1. The materials were used as adsorbents for removal of Cu(II) from aqueous solutions. The adsorbents were characterized using adsorption/desorption nitrogen isotherm, SEM (scanning electron microscopy). The results showed that copper removal could be linked to surface pH and compounds present on the surface of adsorbent. KOH-treated adsorbent has smaller surface area (186 m2 g-1) than ZnCl2-treated adsorbent (192 m2 g-1), however, KOH-treated adsorbent exhibited higher removal of Cu(II). The performance of KOH-treated adsorbent could be attributed to the presence of basic groups on the adsorbent surface. Liu isotherm model gave the best description of the equilibrium data. From the Liu isotherm, the maximum adsorption capacities at 298 K for KOH-treated, ZnCl2-treated and sewage sludge (without inorganic activation) adsorbents are 31.85, 19.79 and 3.513 mg g-1, respectively. The best desorption experiment was obtained using 1.50 mol L-1 of HNO3 as eluent. Recoveries of Cu(II) from Cu(II)-loaded adsorbents are 98.9% (ZnCl2-treated) and 95.5% (KOH-treated.

Aug 17, 2017

By C. Norman Cochran, James L. Brandt

ALTHOUGH gas in aluminum and its effect on aluminum products have been the subject of a number of papers, not many quantitative determinations of the hydrogen content of solid aluminum and its alloys have been recorded in the literature. For solid aluminum samples, four investigators have reported hydrogen contents which appear reasonable compared with the hydrogen solubility of 0.7 ml per 100 g, STP, in molten aluminum at 660°C established by Ransley and Neufeld&apos; and verified by Opie and Grant&apos; and Ransley and Talbot. Sloman," who used a vacuum fusion procedure, reported the hydrogen content of some high purity aluminum as 0.66 ml per 100 g, STP. Griffith and Mallett, employing the tin fusion method, reported the internal hydrogen content of six different aluminum alloys as ranging from less than 0.1 ml per 100 g, STP, for 1100 alloy to 0.7 ml per 100 g, STP, for 4043 alloy (previously 43S, a 5 pct Si alloy). Eborall and Ransley," using a solid extraction of the gases at 600°C, reported hydrogen contents ranging from 0.1 ml per 100 g, STP, to 1 ml per 100 g, STP. Ransley and Talbot reported that several thousand analyses on 99.2 pct and higher purity aluminum as well as Duralumin type alloys indicated hydrogen contents ranging from 0.1 ml per 100 g, STP, to 0.5 ml per 100 g, STP.

Jan 1, 1957

By T. Tamagawa

Vaporization of zinc and mixing of zinc vapor with CO-CO2 mixtures were studied experimentally to prepare Zn(g)-CO-CO2-Ar mixtures with desired composition for investigating the condensation behavior and efficiency of zinc vapor. The vaporization rate of zinc was generally constant under given conditions, and could be increased by raising the flow rate of the carrier gas, temperature and vaporization area. The Zn(g)-CO-CO,,-Ar mixtures were quenched by a water-cooling sampling tube for measuring the actual composition of the mixtures in the reactor. The oxidation extent of the zinc vapor in the CO-CO2 mixtures had relation to the CO2/CO ratios and the temperatures. Under current conditions, it was necessary to employ the CO2/CO ratio below 0.125 for mixing the zinc vapor with CO-CO2 mixtures without oxidation. In addition, the appearances and zinc contents of the condensed zinc on the sampling tube were also examined.

Jan 1, 2001

By Guo Chen, Xuefeng Liao, Tu Hu, Shengzhou Zhang, Hongying Xia, Jinhui Peng, Libo Zhang

Pine nut shell is as raw material for preparation of high surface area activated carbon (HSAAC) by microwave induced KOH activation. The effects of microwave power, activation duration and KOH/C mass rate (R) on the iodine adsorption capability and activated carbon yield were investigated. Additionally the surface characteristics of HSAAC were characterized by nitrogen adsorption isotherms and SEM. The operating variables were optimized utilizing the response surface methodology and were identified microwave power 738W, activation duration 17 min, and R 4, corresponding to a yield of 46.28 % and an iodine number of 2154 mg/g. The key pore structure parameters of HSAAC such as the Brunauer–Emmett–Teller (BET) surface area and total pore volume were estimated to be 3819 m2/g and 2.09 mL/g, respectively. The findings strongly support the feasibility of microwave heating for preparation of HSAAC from spent pine nut shell by microwave induced KOH activation.

Jan 1, 2016