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By Gordon M. Pugh, David G. Rasmussen

INTRODUCTION This method is a variation of cut-and-fill mining where either the wall rock or the vein is too unconsolidated to permit safe mining by conventional cut-and-fill methods. Basic development consists of driving a 2.4 x 2.7-m (8 x 9-ft) haulage heading laterally in the footwall side of the vein. Crosscuts are driven over to the vein at 91-m (300-ft) intervals. Then the vein, at each inter¬section, is mined out to a distance of about 9 m (30 ft ) above the track level. After the installation of an ore chute, scrams or intermediate drifts are driven in both directions along the vein. Mining then starts imme¬diately below the level bounding the upper limit of the stope. A cut varying between 3 and 4.2 m (10 and 14 ft) in depth and mined for a distance of 45.7 m (150 ft )along the strike is taken from the orepass in each direction (Fig. 1). In this mined-out void, the floor of the cut is equipped with 203 x 203-mm (8 x 8-in.) caps hitched into the wall with steel saddle hitches installed on 1.5-m (5-ft) centers. Double wood stringers, 152.4 x 152.4 mm (6 x 6 in.), are then installed on 1.2-m (4-ft) centers longitudinally down the length of the stope. Reinforc¬ing wire mesh is also placed, overlying each mat of timber. Directly above the stringers, stulls are installed from hanging wall to footwall to hold the timber in place during the sand-filling operation. Then a cement¬sand mixture in a ratio of about 1:10 weight is poured to a depth of about 2.4 m (8 ft). The entire cycle is then repeated down to the scram drift. Another variation of timbering is illustrated in Fig. 2. There is a vein width of approximately 5.5 m (18 ft) with the same unconsolidated ground conditions. The primary difference between handling this situation and the previously described undercut-and-fill method is that standard timbered sets are installed in each excavated stoping void rather than stulls. Once again the basic method is to work down the ore block from an upper timbered drift to a lower timbered drift. Cuts are taken from a timbered raise with a chute on the stope side. Each piece of ground excavated is essentially two sets high, 5.5 m (18 ft), by two sets wide, 5.5 m (18 ft), by the length of the cut along the strike of the vein. The timbered sets are 2.4 x 2.4 x 2.4 m (8 x 8 x 8 ft). The net result is, therefore, two sets of timber on a top floor separated by doubled-up 76-mm (3-in.) lagging from

Jan 1, 1982

By Hung-Kei H. Lam

Rubidium and cesium were discovered by Bunsen and Kirchhoff about 100 years ago. These two elements are by no means as abundant as sodium or potassium. Their occurrence in minerals is widespread, but usually as minor constituents. There is no known specific ore containing rubidium, but rubidium is found replacing the. other alkali metals in .some minerals.. Perhaps the highest concentration of rubidium found in one mineral is in lepidolite, KLi(OH,F)2A12Si3010, which contains from 0 to 3.5%*Rb20. 0n the average, lepidolite contains about 0.5% Rb20. Other sources of rubidium are carnallite, KMgCl3?6H20; pollucite, H20.2Cs20.2AI203.9SiO2; rhodizite, R20.2A1203-3B203; biotite, H2K(Mg,Fe)3A1(Si04)3; sea water, rivers, marine and fresh water organisms, soils, and plants. Cesium, even though it is the least abundant. of the stable alkalies, has a specific ore. Pollucites a hydrous cesium aluminum silicate, may con¬tain as high as 42.5% Cs20, although again, the average Cs20 content is about 25% among the handful of known deposits. Other cesium-containing minerals are lepidolite and carnallite. Rubidium and cesium are very much like potassium in chemical properties, consequently, they are hard to separate. Because of the difficulty in obtaining pure cesium and rubidium compounds coupled with the scarcity-of supply, prices were high and the two elements enjoyed little industrial use. Just before the Second World War, the world. supply of rubidium and cesium, from Germany, was a matter of tens of kilograms per year and prices were about

Jan 1, 1959

By Douglas R. Malicoat, Christopher J. Pritchard

Tg Soda Ash operates an underground trona mine located In southwestern Wyoming, which utilizes continuous mining machinery to produce 2.OM tpy (2.2M stpy) by shortwall and room and pillar methods. As the mine developed, the Increasing distance from the shafts caused travel times to be a significant factor in planning for mine emergencies. It was decided to construct a barricade chamber, a modified refuge chamber, to Increase safety and to provide an additional escape option in the case of a mine emergency. Fortunately, there has been no need to use these facilities during the last 9 years, but mine emergency planning has been greatly improved.

Jan 1, 1993

By S. Ilyas

Technical innovation in electrical and electronic equipment with new functions and design, stimulate consumer?s purchasing desire towards the latest equipments and this leads the rapid increase in the production of increased amount of waste materials Treason et al (2006) have reviewed the data on electronic waste generation in different parts of the world. Studies by Bertram et al (2002) have also affirmed that waste electrical and electronic components are the fastest growing waste category; this emphasizes the need for efficient recycling strategies. Recycling of electronic waste is an important subject not only from the point of waste treatment but also from the recovery aspect of valuable materials. However, recycling of electronic scrap is still quite limited due to the heterogeneity of the materials present in the products (Veit et al. 2005). A bioleaching based process offers a number of advantages compared to the conventional pyro or hydrometallurgical methods (Lee et al. 2007; Lee and Pandey, 2012). The advantages include simple, inexpensive (in some cases) and eco-friendly approach besides, generation of less active leach residue then other metallurgical processes. Though, biohydrometallurgical process has been successfully applied for the leaching of metals from ores (Olson et al. 2003; Rawling 2000), data pertaining to its application for the extraction of electronic scrap is still scanty. Recently, a few studies have been undertaken for extraction of metals from electronic scrap/printed circuit boards (Brandl et al. 2001; Faramarzi et al. 2004; Choi et al. 2004, Ilyas et al. 2007; Ilyas et al. 2010). These studies were conducted with mesophilic chemolithotrophic (Acidithiobacillus ferooxidans and Acidithiobacillus thiooxidans) or cyanogenic bacteria (Chromobacterium violaceum) or moderate thermophilic bacteria (Sulfobacillus thermosulfidooxidans). However, compared to bacterial leaching, fungal leaching has the following advantages: (i) ability to grow under higher pH, and thus is more suitable in bioleaching of alkaline solid waste (ii) a generally faster leaching process with shorter lag phase (iii) Chelation of excreted metabolites (e.g. organic acids) with metal ion, thus reduce its toxicity to the biomass (Burgstaller et al. 1993; Aung and Ting 2005). The specific objective of this work was to; ? Collection, isolation and enrichment of fungal strain ? Evaluate the abilities of Penicillium chrysogenum to leach metals from electronic scrap at various leaching modes (one-step bioleaching, two-step bioleaching, spent medium leaching, fresh medium leaching, leaching with deionised water and chemical leaching). ? Comparative study of all leaching modes

Feb 27, 2013

By Meng Li, Hao Nie, Weitian Ding, Mamdouh Omran, Ying Li, Yao Ge, Yaowei Yu, Abourehab Hammam, Lei Zan

This study examines the isothermal and non-isothermal reduction behaviors of iron ore compacts in a pure hydrogen atmosphere and compares the results obtained during the reduction process by CO. The different phases accompanying the reduction reactions were identified using X-ray diffraction (XRD) and its morphology was microscopically examined. In isothermal experiments, temperature plays a significant role in the reduction process. At any given temperature, the reduction rate during the initial stages is higher than that during the final stages. The reduction rate in H2 atmosphere was faster than in CO gas. The comparison of activation energy values suggested that reduction with H2 is more efficient thanwith CO. At the same temperature, the time required to achieve a certain degree of reduction was lower when using H2 gas than CO atmosphere. In non-isothermal tests, the heating rate has a significant effect on the reduction rate and reduction extent. At the same heating rate, the degree of reduction was higher in H2 atmosphere than in CO gas. Based on experimental data, the parameters of reaction kinetics were deduced by application of model-free and model-fitting methods. The reduction in H2 atmosphere was controlled by nucleation model (Avrami-Erofeev model), while the CO reduction reaction was controlled by gas diffusion.

Sep 29, 2020

By David M. Sullivan

Jim Walter Resources, Inc., (JWR) a division of Jim Walter Corporation, has 5 underground coal mines in Central Alabama varying in depths from 400-2500 feet. Gas Chromatography plays a vital role in safety and production at each mine. Chromatographic data is used to monitor working areas for safety and proper ventilation and to control the quality of extracted methane for sales purposes. Instruments have a1 so been employed during mine rescue operations. JWR's first Gas Chromatograph (GC) was installed in April 1984 to monitor gob gas taken from longwall gob areas and sold based upon BTU value. The GC allows maximum extraction rate of the gas within the quality guidelines. By late 1985, another system was purchased and both units were upgraded to perform an analysis of indicator gases which may appear during mine emergencies. Each unit has the ability to detect and measure the following gases at almost any level ; Oxygen (021, Nitrogen (N2), Methane (CH4), Carbon Dioxide (C02), Hydrogen (HZ), Carbon Monoxide (CO) , Ethylene (C2H4), Ethane (C2H61, Acetylene (C2H2) and a composite of hydrocarbon threes and above (C3+). The analytical run is accomplished in less than ten minutes and is completely automated. This report will introduce Gas Chromatography as applied by Jim Walter Resources for the analysis of underground mine air.

Jan 1, 1987

The Mining Foundation of the Southwest (MFSW), located in Tucson, AZ, will hold its 16th annual American Mining Hall of Fame Awards Banquet Saturday, Dec. 5,1998. The Hall of Fame recognizes outstanding contributions to the mining industry by selected individuals and industry partners. Each year, one living award recipient and up to two mining history honorees are chosen by the , Hall of Fame Committee and the Board of Governors of the Mining Foundation. In 1989, the Mining Foundation initiated a Medal of Merit to recognize outstanding individual, technical and professional contributions to the mineral industry. In 1995, an award was created to recognize contributions made by companies and organizations in partnership with the mining industry. This year's inductee, guest of honor and featured speaker will be Charles G. Preble, president and chief executive officer of Southern Peru Copper Corp. He is being recognized for outstanding performance as an executive of an American company operating under difficult circumstances in a foreign country. The Hall of Fame will induct H. Myles Jacob, former chairman and CEO of Inspiration Copper Co., for innovation and farsightedness in matters pivotal to the cop- per industry of his time. In addition, John Cromwell Lincoln, former president and chairman of Bagdad Mining Co., will be inducted for his outstanding contributions to the American mining industry. These contributions include metallurgical research and development of the Bagdad Mine as well as pioneering innovation in the electrical industry. Medals of Merit will be awarded to David N. Skillings, editor and publisher of Skillings Mining Re- view, for his dedication and support of mining interests. J. Ruben Velasco Rodriguez will also receive a Medal of Merit. He is economic geologist, professor and former secretary of the board of directors and secretary general of Compania Minera de Cananea. His medal is for fostering excellent relations between Mexico and the , United States in mining geology and management and for advancing the professional development of others in the field of earth science. An Industry Partnership Award will be presented to Stephen Bechtel and the Bechtel Corp. in recognition of Bechtel's 100th anniversary and the company's outstanding service to the mining industry. The banquet will be held at the The Westin LaPaloma in Tucson beginning with cocktails at 6:30 p.m. Tickets are available from Clare A. Roscoe, manager, Mining Foundation of the Southwest 520-577-7519, fax 520-577-7073.

Jan 1, 1998

By F. M. Doyle

Metal removal kinetics and metal ion selectivity in ion flotation were studied from a thermodynamic perspective. Surface tension data could be used with the Gibbs adsorption equation to quantitatively predict the metal ion removal kinetics in alkylsulfate-Cu systems. However, surface tensions predicted cation selectivity coefficients in the sodium dodecyl-sulfate (SDS)-Cu-Ca and SDS-Cu-Pb systems rather poorly, although the predicted order of the selectivity (Cu2+<Ca2+<Pb2+) was correct. Another thermodynamic selectivity model, which used the Grahame adsorption equation and a geometrical analysis, predicted cation selectivity coefficients that agreed very well with experimentally measured values.

Jan 1, 2000

By Victor Despointes, Stephane Polycarpe, Kathryn Kelly, Chris Feeney, Brian Hann, Vojtech Ernst Gall

The Pawtucket Tunnel is a 2.2-mi, 30.2-ft diameter CSO storage tunnel in Rhode Island. The primary tunnel is built using a dual-mode open-EPB TBM capable of sealing the face within 120 seconds to manage poor ground and water ingress which is launched from within a SEM starter tunnel. The main tunnel connects to four adits along its alignment, three of which are SEM tunnels and one being a MTBM tunnel. This contribution describes the selection process, potential risks, and requirements for the TBM, as well as the design of the main tunnel, the adits, and the adit-bored tunnel connections.

Jun 13, 2023

By Richard R. Radel, Jack Barry

Contract required excavating 2,000 If of 14&apos; horseshoe tunnel in rock, a 95&apos; deep work shaft on shore, and a 50&apos; deep intake shaft located in the middle of the Niagara River just above Niagara Falls. Large quantities of H2S were encountered in the range of 20 PPM with ventilation. Peak levels of 40 PPM were recorded. The original designed ventilation system required only a volume of 10,000 CFM to meet OSHA requirements. The volume of air was increased to 50,000 CFM to dilute the H2S to al- low workmen to work and comply with OSHA H2S action levels. The second phase of the tunnel consisted of placing 72" ID X 20 foot long concrete reinforced pipe in the tunnel. When the tunnel was holed through and both shafts were open, a substantial amount of work was required to take place in the shafts which eliminated the possibility of placing a bulkhead to secure proper ventilation. The ventilation team designed a jet system airlock. The design of this system was to bring fresh air down the work shaft in two duct systems; one 30" diameter and one 24" diameter. Following the excellent work of Jan Wolski (7th Mine Ventilation Symposium chapter 58) our design incorporated nozzles located approximately 100&apos; in by the work shaft. The velocity of the 24" diameter duct was 6,365 FPMD2.2 MPH. The velocity of the 30" diameter duct was 6,117 FPMl69.5 MPH. Both systems were on blow and being that air expands at 3112 degrees per side this high velocity of air expanded and created an air bulk head through which men and the large sections of concrete pipe could be passed without any delay or additional cost to the project.

Jan 1, 1997

By Walid M. Abdellah, Soliman Abu Elatta A. Mahmoud, Hanaa A. Abu Khoziem

The high-grade Th-U-Y zone is one of the numerous mineralized zones found in the El Garra El Hamra hydrothermally altered syenites in southwestern Egypt. It is characterized by the thorium minerals thorite and thorogummite, which are closely associated with xenotime-(Y). This zone of mineralization is localized in the eastern part of the El Garra El Hamra hydrothermally altered syenites. This zone does not relate to the first phase of syenites that appeared on the surface but is linked to the other, hidden phase of the syenitic body. Additionally, the fluids responsible for the mineralization of this zone belong to the late-stage hydrothermal event as well as the fault action due to the fact that it had continued reactivations for a long period of time. The studied mineralized zone also contains ceriopyrochlore-(Ce),(Ce,Ca,)2 (Nb,Ta)2O6 (OH), fluorite (CaF2) and barite (BaSO4), which are found in considerable amounts, whereas apatite (Ca5(PO4)3F) and chromite (FeCr2O4) are rarely found together with Fe-oxi-hydroxides (hematite and goethite) with a minor amount of jarosite (KFe33+(OH)6(SO4)2). Finally, the main constituent mineral in the zone is the pseudomorph perthite in addition to quartz, which is found as deformed crystals. A technological sample was collected from this zone and was found to assay 4.62 weight percent thorium (Th), 0.37 weight percent uranium (U) and 3.12 weight percent rare earth elements (REEs). From the chemical and mineralogical composition of the studied technological sample, the leachabilities of Th, U and REEs were investigated using sulfuric acid (H2SO4) agitation leaching and pug leaching methods. The latter was found to be preferred under the conditions of 0.54 ton H2SO4 per ton of altered syenite at 110 °C for two hours.

By F. M. Doyle

Metal removal kinetics and metal ion selectivity in ion flotation were studied from a thermodynamic perspective. Surface tension data could be used with the Gibbs adsorption equation to quantitatively predict the metal-ion removal kinetics in alkylsulfate-Cu systems. However, surface tensions predicted cation selectivity coefficients in the sodium dodecylsulfate (SDS)-Cu-Ca and SDS-Cu-Pb systems rather poorly, although the predicted order of the selectivity (Cu2+ < Ca2+ < Pb2+) was correct. Another thermodynamic selectivity model, which used the Grahame adsorption equation and a geometrical analysis, predicted cation selectivity coefficients that agreed very well with experimentally measured values.

Jan 1, 2002

By Arpad E. Torma

The electrochemical behavior of a zinc sulfide concentrate during the microbiological leaching was investigated using ZnS-carbon paste electrodes and a cyclic voltametric technique. The effects of Zn2 [ ] , Fe2+, Fe3+ and Cu2+ on the cathodic and anodic currents associated with zinc sulfide leaching in presence and absence of microorganisms, were assessed. The semiconductor nature of zinc sulfide was discussed in terms of ability of microorganisms to obtain their metabolic energy (through removal of electrons) from this high energy gap substrate. The intermediate electrochemical reactions involved in the ZnS leaching were described.

Jan 1, 1989

By Edita Vircíková, J. B. Hiskey, Ludovít Molnár, Peter Lech, B. J. Scheiner

This paper describes the results of a study of hydrometallurgical methods of producing sodium arsenate for the glass industry from arsenic oxide wastes occurring in carbon dioxide washing. This paper addresses the following aspects: theoretical assumptions for leaching arsenic and its oxides, experimental results of As(III) oxidation to As(V) in aqueous solutions, sodium arsenate crystallization (the system As2O5-Na2O-H2O), characteristics of the crystalline product, and pilot-plant tests using sodium arsenate in the glass industry.

Jan 1, 1993

By S. S. SHINDE, P. C. JIKAR, N. B. DHOKEY

Mill scale is an oxide waste product of the steel mills, which contains around 70% iron and other allied impurities. In the present context, a dynamic prototype counter current reactor (CCR) has been used for experimentation and simulation of particle bed by using discrete element method (DEM). Mill scale was pulverized to ASTM mesh range 140 (106 μm)/ + 270 (53 μm), and then it was oxidized in CCR to make single oxide Fe2O3 phase by maintaining required thermodynamic conditions such as pure oxygen at 1100 °C. Then this oxidized powder was subjected to reduction reaction in CCR having gas mixture ( H2:N2) ratio of 1:4 at 875 ± 5 °C for filling degree (fd) and reactor revolution (ω) ranging from 5.38 to 16.14% and 2 to 5 rpm, respectively. A creeping fluid flow condition (Re ˂ 1) and natural heat convection (Gr/Re2 ˃˃ 1) has been maintained while undergoing solid–gas reaction. Besides particle bed behavior has been quantified by Froude number (Fr) for the optimum operating window. The simulation was validated by the experimental results of reactor reaction product by X-ray diffraction (XRD) and scanning electron microscope (SEM) images. Prevailing heat transfer mechanism and reduction reaction mechanism has been established for solid–gas counter current conditions.

Nov 22, 2021

By Charles H. Greene

This paper will describe briefly the steps taken in the development of a Central Florida phosphate ore deposit from acquisition to mining. Further, the design and early operation of the mining and beneficiation facilities will be depicted. During the 1950&apos;s, with confidence in the continually increasing requirement for phosphate fertilizer materials essential for producing food, I&apos;. R. Grace & Cc acquired the Hookers Prairie tract containing approximately 45 million metric tons o. (50 million short ton~ of potential phosphate rock product. In 1973, at a point when the Grace captive need for rock was being greatly enlarged by a planned doubling of its Bartow phosphate chemicals plant capacity, the decision was made to expand existing phosphate rock production by building a new mine and plant. The initial annual capacity was to be 2.3 million tons (2.5 million st); however, subsequent investigation pointed to a higher than estimated dragline operating factor &apos;and the forecast of annual capacity was set at 2.5 million tons (2.8 million st).

Jan 1, 1977

By Rajiv Hadkar, M. D. McKinley, J. B. Hiskey, B. J. Scheiner, G. W. Warren

Flyash from municipal solid waste incinerators containing roughly 13 to 15% Zn, 2% Pb and 0.2% Cd is an attractive material for simultaneous metal recovery and detoxification. Results have shown that Pb in flyash is present as PbSO4 and PbC12 and that about 70% of the Zn is present in the form of soluble amorphous compounds. Leaching results in a number of acid and basic lixiviants show that acid leaching is clearly more effective than basic leaching which is limited by low solubility of Cd and Zn. Cementation in acid solution with pH < 1 promotes redissolution of the precipitated metal. Successful zinc electrowinning from chloride leaching solutions has also been demonstrated, although Pb2+ and Na+ can be potentially detrimental. The presence of Pb2+ can prevent deposition of metallic Zn, forming zinc oxychloride, ZnC12.4Zn(OH)2, instead. High concentrations of Na+ can also result in precipitation of NaCl. This investigation has shown that hydrometallurgical treatment of MSW flyash through leaching, cementation and electrowinning is a potentially feasible method for simultaneous detoxification and recovery of metal values. Several issues have also been identified which would require further investigation for final process development.

Jan 1, 1993

By C. D. Anderson

"IntroductionTungsten carbide is a valuable material used in a variety of different applications, including the manufacturing of cutting tools, bearings and as a cost-efficient alternative to industrial diamonds. Both the high hardness value (Mohs 9) and scratch resistance of this material make it a valuable commodity for use in the mining industry.Usually, the production of tungsten carbide is a multistep process involving one or more of the following unit operations: hydrometallurgical digestion, solution purification, crystallization (as ammonium paratungstate), calcination, hydrogen reduction and carbon synthesis. The proposed three-step process eliminates three of these steps (crystallization, calcination and hydrogen reduction) by implementing a combination of hydro/pyrometallurgical techniques. These include alkaline pressure leaching, carbon adsorption and carburization roasting. By eliminating some of the intermediate processing steps, there is potential to reduce energy consumption and decrease overall operating costs.Methods and resultsInitially, alkaline pressure leaching with sodium carbonate (Na2CO3) was employed to selectively leach tungsten, as tungstate (WO4 2-), from an industrial Scheelite (CaWO4) flotation concentrate. Experimental variables included lixiviant (Na2CO3) concentration, temperature and residence time. Experimental constants, based on previous work, were percent solids at 13 wt% and agitation at 400 rpm (Queneau and Strathmore, 1969). Leaching results showed it was possible to extract 97% of the tungsten present. The most favorable conditions for leaching were determined: 2M Na2CO3, temperature of 180° C and a residence time of 30 minutes."

Jan 1, 2015

By Sumit Kumar Hota, Asadi Srinivasa Reddy, Ashok Kumar, Ashish Agrawal, Surajit Sinha, Chandra Sekhar, Tanay Ray

In the current operational facility, due to the absence of pellet pot facility, a novel technique is developed wherein the pellets with different chemistries prepared in the laboratory are fired in an induration machine by placing them inside the Inconel baskets. In the present work, an attempt is made to optimize the pellet chemistry by developing 2 different flux pellets, viz., low basicity (B2: CaO/ SiO2 = 0.3) pellets and high basicity (B2 = 0.9) pellets, and further the effects of basicity on pellet properties, viz., cold compressive strength, porosity, swelling index, reducibility index, and softening and melting temperature, are studied. It has been found through the multiple operational trials that increasing the basicity of pellets from 0.3 to 0.9 results into improving the pellet strength, reducibility and softening and melting characteristics. Moreover, it is observed that the swelling index of pellets is reduced by adding 2% MgO to both low and high basicity pellets that could be attributed to the formation of high melting point slag in pellets. The operational trial has resulted into producing pellets that exhibit a combination of desired mechanical strength, improved swelling, and reducibility index and possess better softening–melting behavior among all the chemistries studied.

May 24, 2022

By B. M. Ghadiali, J. B. Putnam, T. P. Smirnoff, M. A. Elioff, P. F. Ryan

Geotechnical investigations for the Mid-City Extension of the Los Angeles Metro revealed high concentrations of toxic hydrogen sulfide (H2S) gas as well as methane. Testing techniques employed to determine the extent of gasses, and to identify potential treatment measures, included gas sampling with cone penetrometers and soil-gas extraction with air injection testing. A gas reservoir model was developed to predict inflows into excavations. Other studies included a hazard evaluation and a general data search for other H2S occurrences and geologic conditions that could facilitate the accumulation of H2S. The paper describes the investigations and proposed design and construction alternatives.

Jan 1, 1995