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By Gregg J. Hodges

The Stillwater pt-pd mine and flotation mill are located about 130 km (80 miles) southwest of Billings in Stillwater county, M6ntana~ The pt-pd ore zone stretches about 43 km (27 miles), but varies in thickness from 0 to 6 meters (0 to 20 feet, but generally 3-6 feet) and dips 55-90,degrees from horizontal. The ore is hosted in basic, layered igneous rocks containing about 1% sulfide minerals which include chalcopyrite, pentlandite, pyrrhotite, and minor pyrite. The pt-Pd minerals are intimately associated with these sulfide minerals and are found as precious metal sulfides, tellurides, bismuthnides, and arsenides as well as native Pt metal. Approximately 90 different precious metal minerals have been found, but about 80% of the pd is in solid solution in the pentlandite. The ore assays about 0.1% Cu, 0.1% Ni, 6.2 g Pt/tonne (0.18 Troy ounce Pt/short ton (opt)), 21.3 g Pd/tonne (0.62 opt Pd), 0.21 g Au/tonne (0.006 opt Au), and 0.21 g Rh/tonne (0.006 opt Rh). The ratio of pd to Pt in the Stillwater ore and concentrates is about 3.5.

Jan 1, 1988

By Brett P. Spigarelli

"To meet the growing need for CO2 capture and storage technology, Michigan Technological University is studying CO2 capture using alkali-based solvents. The objective of the present study was to find a way to increase the absorption rate of CO2 into an alkali solution without reducing the absorption capacity of the solution. One approach to increasing absorption rate is to use a surfactant to chemically alter the gas bubble size. The surfactant chosen for the study was a neutral-charge polypropylene glycol methyl ether (PPGME) with a molecular weight of 200. Experiments were conducted to study the absorption rate of CO2 at varying surfactant concentrations. Results showed that as the concentration of PPGME increased in solution, the absorption rate also increased. The CO2 absorption rate increased from 3.45 x 10-3 mol/min CO2 at 0g/L PPGME to 3.92 x 10-3 mol/min CO2 at 0.48 g/L PPGME. This amounted to a 14% increase in the CO2 absorption rate with no decrease in the absorption capacity of the solution. IntroductionChemical absorption using an amine solvent is currently the most mature carbon capture and storage technology available. Amines are advantageous in that they have a fast CO2 absorption rate, which leads to a high CO2 removal efficiency. However, amine absorption has some considerable drawbacks, such as high energy requirements, high equipment corrosion rates, amine degradation in the presence of oxygen, high waste generation and a large increase in plant footprint if new equipment is constructed (Herzog and Golomb, 2004; D’Alessandro et al., 2010). Due to these drawbacks, Michigan Technological University (MTU) is studying CO2 absorption using alkali-based solvents, which address the above disadvantages of amine solvents."

Jan 1, 2015

By Andrzej Wala, Tom Altman, Tom Hughes

The University of Kentucky Mine Ventilation Manager (UKMVM) is a system that contains Level Five knowledge bases and comprises an expert mine ventilation management system. The package uses production rule language (PRL) to interpret data monitored from sensors, e.g., for airflow, temperature, and concentration of gases, in an underground mining environment. Activated from the PRL knowledge bases are Pascal subprograms which (1) organize the monitored data to set up emergency consultations, (2) display graphic representations of a mine's ventilation network with the latest sensor readings, (3) provide interactive updating of mine ventilation parameters, e.g., resistance changes, revised flow requirements, and new regulator and fan settings. Also activated from these knowledge bases are programs which (1) monitor airflow, temperature and gas concentrations from a physical mine ventilation model and (2) adjust regulator openings and fan rpm's. Thus, as an expert system the UKMVM not only presents advisory consultations for underground environmental emergencies, but also serves as an interface between the monitoring and responsive control aspects in the continuous maintenance of normal mine ventilation.

Jan 1, 1989

By Sterling S. Cook

The U.S. Bureau of Mines is conducting core leaching experiments with sulfuric acid on oxide copper ores from the Cyprus Casa Grande and ASARCO Santa Cruz deposits in Arizona to further our understanding of the leaching process in supergene copper ores as it relates to in situ mining. Leach solutions from atacamite mineralization contained 5 to 30 g/l copper and few extraneous ions. Leachant from chrysocolla ores, with grades similar to the atacamite, contained 2 to 9 g/l copper and abundant extraneous ions. Quartz and K-feldspar had no impact on leach solution composition at any acid concentration (up to 40 g/l) while illite and sericite had minimal impact. Biotite, calcium-rich clay and limonite have a significant impact on solution chemistry when there is abundant free acid in solution. High acid concentrations increase acid consumption in ores with abundant biotite and limonite gangue. High acid concentrations can be used in ores with quartz, K-feldspar, and sericite gangues without increasing acid consumption per unit of copper removed.

Jan 1, 1988

By Naeimeh Shabani, Hamid Mirzaie, Javid Sadeghi, Hoda Jafarizadeh-Malmiri, Afshin Javadi

Iron oxide nanoparticles (Fe3O4 NPs), despite their small size, are stable and have a large surface area that allows for absorption and removal of ions as well as turbidity in a short period of time. Thus, the present study addressed the synthesis and characterization of Fe3O4 NPs synthesized using the co-precipitation method and evaluated their effect on the coagulation process in water treatment. The Fe3O4 NPs characteristics were evaluated as follows: magnetic properties were measured using a vibrating sample magnetometer (VSM), surface area using Brunauer–Emmett–Teller (BET), crystal phase using X-ray diffraction (XRD), and morphology using field emission scanning electron microscopy (FESEM). In addition, the effects of the synthetic Fe3O4 NPs on the turbidity reduction of water in various pH levels were evaluated. The synthesized Fe3O4 NPs were without any impurity in the sizes of 22–32 nm, surface area of 99.6 m2/g, pores’ mean diameter size of approximately 10.6 nm, and maximum magnetic saturation of 66.21 emu/gram (emu/g). Using 0.2 g of synthetic Fe3O4 NPs with an initial turbidity of 17 NTU and pH of 6 could reduce all water turbidity (100%). Considering the cheap and facile production and separation, as well as the possibility to reuse them and reduce the sludge water content, iron oxide Fe3O4 NPs can be effectively used for turbidity reduction in the water treatment process.

Oct 26, 2020

By K. A. Lapakko, D. A. Antonson

Fourteen samples of pyrite-bearing Archean greenstone rock (d < 6.35 mm, 0.04% < St < 1.22%) were characterized (particle size, chemistry, mineralogy) and subjected to laboratory dissolution testing. The only sulfide and carbonate minerals identified were pyrite and siderite, respectively. Quartz, chlorite and sericite typically comprised 90 to 98 percent of the mineral content. For the first 60 weeks, seven samples with sulfur contents less than or equal to 0.16% produced drainage pH values exceeding 6.0. Over this period, six of the seven samples with sulfur contents greater than or equal to 0.20% produced drainage pH below 6.0, with minimum values ranging from 3.2 to 4.7. The seventh sample (0.72% S) had a siderite content of 18%. Small amounts of magnesium and, to a lesser degree, calcium carbonates present in the siderite apparently dissolved to neutralize acid and maintain drainage pH above 6.0. Sulfate release rates generally increased as sulfur content increased, and the rates of pyrite oxidation estimated for individual samples were roughly half to five times that reported in the literature for the abiotic oxidation of pyrite by oxygen. Observed neutralization potentials ranged from 0.2 to 2.0 g CaCO3/g rock.

Jan 1, 2002

By R. W. M. Lai

The study of flotation kinetics was first reported by Garcia-Zuniga1 in 1935. Since then, literature on the subject has grown with the time. 2-19 Although there is an abundance of flotation kinet¬ics models available in the literature to describe flo¬tation systems, they are mostly of academic interest and are seldom applicable for use in the industrial environment. Several reasons contribute to the wide gap in the industrial -application of the academic models. These include: 1) the lack of generality in the model, e.g., the model is limited to certain size ranges; 14 2) the academic models involve complicated mathematics; 5,6,10,11 3) confusion about the order of the flo¬tation rate, e.g., several authors proposed a first order rate model, 1,15,16 whereas the others propagated a second order rate model: 2,17,18,194) the use of an unrealistic rigid value, such as the use of a maximum recovery of 100%, 5,8,19 which is unrealistic in industrial operations; and 5) the use of graphs that confuse the reader rather than interpret information. 2,3,10 This paper intends to introduce a simple and easy to understand empirical flotation kinetics model along with a way of presenting the model in an informative graphical form, which should stimulate the interest of other practical engineers to become concerned with practical application within the mineral industry.

Jan 1, 1982

By W. L. O?Connell

[Patent Issue No. Date Issued To Subject 386,504 July 24, G. Sweanor The separation of quartz from a 1588 metal with a liquid such as CS2 or CHC13 under water by introducing mixture into water layer. Quartz will stay in water layer while metal sinks through organic.]

Jan 1, 1963

By S. D. F. Rocha

The influence of surfactants on the crystallization of calcium sulfate was investigated in both hatch and continuous systems. The investigation was per formed at the following conditions. 343 °K, 28% P205 and with a sulfate level of 2.0%. At concentrations of 5 and 200 µgig, respectively, dodecylbenzene sulfonic acid (DBSH) and sodium diisooctil sulosuccinate (SSNa) promoted both an increase in the size and a reduction in the length/width (L/W) ratio of the calcium sulfate hydrates produced in the hatch and continuous crystallizers. Unique effects were observed in the batch system at higher DBSH concentrations. At 10 µg/g, the precipitation of hemihydrate crystals with a distinct morphology and texture occurred under conditions where dihydrate precipitation was expected. Above 50 µg/g, the precipitation of calcium sulfate hydrates was completely inhibited.

Jan 1, 1996

When a company like Lonmin, the third largest platinum producer in the world, is mining one of the most precious metals in the world, time is money. Every piece of equipment is expected to be in top shape because every minute of downtime can add up to lost profit. Two different types of platinum ore are mined and processed by Lonmin, namely Merensky and UG2. Merensky has a grade of 3.5 g/t (0.1 oz/st) and UG2 has a grade of 4.5 g/t (0.13 oz/st). The mine also produces platinum group metals (PGM), which consist of platinum, osmium, palladium, rhodium, iridium and ruthenium. Although South Africa has more than 80 percent of the world?s PGM reserves, these minerals are very scarce. Lonmin is considered a low-cost producer of these minerals, generating 21.5 t (694,000 oz) of platinum and 18.6 t (600,000 oz) of PGMs in 2012. So when the company?s Karee K3 concentrator plant in Rustenburg, North West Province, South Africa, was experiencing high operating costs on the transfer points, a solution was needed.

Jan 1, 2012

By P. N. H. Bhakta, X. P. V. Lei

The U.S. Bureau of Mines developed an alkaline oxidative pretreatment to increase the recovery of gold from refractory sulfide ores containing arsenopyrite (FeAsS) and/or pyrite (FeS2). Pretreatment of a low grade ore containing 0.4% FeAsS, 3.5% FeS2, and 2.74g/mt Au with 1.2m NaOH, 40 psig o2, 100° C, and 4 hr in a 2-L autoclave resulted in 94 to 96% sulfide oxidation. cyanidation of the pretreated residue resulted in 88% Au extraction compared to <20% Au extraction for untreated ore. Cyanide consumption was 0.25 kg NaCN per metric ton of ore. A flowsheet for treating sulfidic low-grade gold ore is proposed.

Jan 1, 1990

By C. E. Ekburg

Gold Quarry is a sediment-hosted, epithermal disseminated gold deposit located along the Carlin Trend. Gold, hosted by allochthonous Ordovician siltstones and cherts, is localized at the intersection of structures sympathetic to the major Good Hope and Gold Quarry faults. The magnitude of Gold Quarry was discovered in 1979 by surface exploration and by percussion holes drilled near the Maggie Creek orebody. Four years of development drilling delineated an open pit mineable gold deposit that contains 130 Mt (144 million st) of ore at an average 1.68 g/t (0.049 oz per st) of gold and includes a high-grade core of 46 Mt (51 million st) that average 2.64 g/t (0.077 oz per st) gold. Milling of the higher-grade portion began in 1985.

Jan 1, 1987

By S. S. Cook, S. E. Paulson

The US Bureau of Mines is conducting core leaching experiments with sulfuric acid on oxide copper ores from the Cyprus Casa Grande and Asarco/Freeport Santa Cruz deposit in Arizona to further the understanding of the leaching process in supergene copper ores as it relates to in situ mining. Leach solutions from atacamite mineralization contained 5 to 30 g/L (0.05 to 0.28 oz/gal) copper and few extraneous ions. Leachant from chrysocolla ores, with grades similar to the atacamite, contained 2 to 9 g/L (0.02 to 0.08 oz/ gal) copper and abundant extraneous ions. Quartz and K-feldspar had no impact on leach solution composition at any acid concentration up to 40 g/L - (0.39 oz/gal) while illite and sericite had minimal impact. Biotite, calcium-rich clay, and limonite have a significant impact on solution chemistry when there is abundant free acid in solution. High acid concentra¬tions increase acid consumption in ores with abundant biotite and limonite gangue. High acid concentrations can be used in ores with quartz, K feldspar, and sericite gangues without increasing acid consumption per unit of copper removed.

Jan 1, 1990

By Kristin K. Mueller, Lucie Coudert, Thi Yen Chau Nguyen, Lan Huong Tran, Jean‑François Blais, Guy Mercier

Fluorite (calcium fluoride—CaF2), also known as fluorspar, is an industrial mineral used in metallurgy, hydrofluoric acid production, and ceramics manufacturing. Based on the results from a previous study, a low-grade fluorspar by-product (20.0% CaF2) originating from the exploitation of a rare earth carbonatite deposit can be improved to 75.4% by combining magnetic separation and acid leaching. The present research aimed to develop and optimize a column flotation process to increase the purity of this fluorspar by-product by removing residual silicate minerals and meeting the requirements for ceramic manufacturing (> 85% CaF2). The optimal flotation conditions required for maximizing the recovery and improving the grade of a fluorspar by-product were identified using a conventional approach combined with a response surface methodology (Box-Behnken design). Optimal fluorspar flotation was achieved under the following conditions: 3.6 g/kg of sodium oleate as the collector, 2 g/kg of sodium silicate as the pH modifier and depressant, a conditioning time of 35 min, a flotation time of 7 min, and a solid-to-liquid ratio (S/L) of the pulp of 5%. Under these conditions, 86.8% fluorspar recovery was achieved, and the grade increased from 76.5% in the feed (metallurgical grade) to 88.6% (ceramic grade) in the final concentrate. The silicon content decreased from 5.66% in the feed to 1.12% in the fluorspar concentrate. Using magnetic separation before the flotation improves the final content of fluorspar in the concentrate with the final grade of 94.4%.

Sep 9, 2022

By L. W. Teal

The Paupers Dream Property is located in the northern Boulder Mountains, southwestern Montana, 30 km southwest of Helena. The property is situated in the central portion of the Butte-Helena gold belt, a NE trending lineament marking a zone of recurrent, late-Cretaceous to mid-Tertiary volcanic activity. Geology consists of a plutonic basement of late-Cretaceous quartz monzonite overlain by a pre-volcanic basal conglomerate and a complex sequence of Oligocene rhyolitic volcanics. Gold mineralization occurs in fracture-controlled quartz veins, silicified stockwork, and brecciated shear zones as auriferous pyrite, arsenopyrite, and disseminated free gold. An estimated 60,000 tonnes averaging 2.5 g/t was produced from the Porphyry Dike, Venus, and Paupers Dream Mines on the property. Current drill indicated reserves (May, 19861 are placed at 6,946,000 tonnes averaging 1.45 g/t gold.

Jan 1, 1987

By G. Myers, C. J. Wendt, W. H. Wilkinson, M. D. Dennis

Precious metal mineralization at Mt. Hamilton, NV is associated with a polymetallic, garnet-pyroxene skarn system developed in middle to upper Cambrian calcareous shale, limestone, and dolomite. The skarn is developed around the Cretaceous Seligman and Monte Cristo calc-alkaline stocks. Gold is associated with intense retrograde alteration. Later epithermal quartz veins contain gold, silver, base-metal sulfides, and sulfosalts cross-cut skarn alteration. Westmont Mining Inc. is currently developing two mineralized zones containing a geologic resource of about 7 Mt (7.7 million st) that averages 1.7 g/t (0.05 oz per st) gold and 17.2 g/t (0.5 oz per st) silver. The project will have an estimated mine life of seven years, with a planned annual production rate of I t (35,000 oz) of gold and 9.3 t (300,000 oz) of silver.

Jan 1, 1990

By W. Joseph Schlitt

Aqueous SO2 (sulfurous acid) is an interesting chemical compound. It functions as a reagent in various hydrometallurgical systems, but also represents an undesirable constituent in pyro- and hydrometallurgical effluent solutions. When present in such streams, SO2 can be oxidized to the more stable sulfate form to avoid exsolution of SO2 as a source of fugitive emissions and to simplify standard water treatment plant operation. This study provides information on the stoichiometry, kinetics and mechanism of SO2 oxidation using oxygen and an iron salt catalyst with solutions containing 0.05 to 20.0 g/l S02. Other test variables include iron salt concentration, oxygen pressure, temperature, degree of agitation and pH.

Jan 1, 1982

In this study, the flotation performances of ethoxycarbonyl thionocarbamate (ECTC), dialkyl thionocarbamate (DATC) and xanthate copper sulfide collectors are compared by the structure-reactivity relationship using generalized perturbation theory and density functional calculation at the B3PW91/6-31G(D) level. The electron-donating power of xanthates is strong and, therefore, xanthates can strongly react with metal cation on the surfaces of copper and iron sulfide minerals through the formation of normal covalent bonds. This explains the poor selectivity of xanthates and also the high pH levels (above 13) required for the flotation separation of copper/iron sulfide minerals. DATCs are more selective for copper sulfide flotation, particularly against gangue iron sulfides. Although less powerful than xanthates, DATCs can perform copper/iron flotation separation at lower operating pH (commonly at pH levels below 11.5). ECTCs use an ethoxycarbonyl replacing an alkyl N-substituent in DATCs. The presence of the ethoxycarbonyl group effectively changes the functional group of collector from -C(=S)NH- to -C(=S)NHC(=O)-. The strong electron-withdrawing ethoxycarbonyl group adjacent to the C=S group decreases the electron density of the sulfur atom, which improves ECTC?s selectivity against iron sulfide minerals at slightly alkaline conditions. The lowest unoccupied molecular orbit (LUMO) of ECTC, which is constituted by the pz-orbit of every atoms in the conjugate -O-C(=O)-N-C(=S)-O- group and which is pleased with accepting richly d-orbital electrons (feedback electrons) from the (t2g)6(eg)3Cu(II) or t6e4Cu(I) configuration of copper cation on the surfaces of copper sulfide minerals, resulted in the formation of dative p-bond. The iron atom, which has a (t2g)6Fe(II) or (t2ga)3(ega)2 Fe(III) configuration on the surfaces of iron sulfide minerals (Fe(III) is the predominant composition at alkaline conditions), has difficulty in offering its d-orbital electrons (feedback electrons) to ECTC?s LUMO. ECTC collectors are powerful for copper sulfide minerals and very selective against iron sulfides, which has been further confirmed by UV spectra and bench-scale and industrial-scale flotation tests.

Jan 1, 2008

By Stephen L. Chryssoulis

The detection and quantification of invisible gold by microbeam techniques is discussed. Ion probe microanalysis is used to quantify the gold content of individual sulphide, sulpharsenide and oxide particles with a detection limit of 0.2 ppmw (g/t). The proton microprobe is used to determine the gold concentration of gangue minerals with a detection limit of 2 - 4 ppm. Using these techniques complete mineralogical balances for gold are obtained to assist in the process selection and optimization. A total of twenty gold and gold-bearing ores have been examined. Selected examples are presented.

Jan 1, 1990

By James A. Clum

The shift to lower grade iron ores, e.g., magnetic taconites, resulted in a shift towards agglomeration practices which could effectively deal with the fine particle sizes generated in the liberation and concentration processes. If the iron bearing particles are not extremely fine, e.g., -1/2 in + 100 mesh, sintering is an adequate means of agglomeration.(1) For the more dispersed ores which result in fine concentrates (more than 80%,-325 mesh), the fine particles must be agglomerated by mechanical means before final hardening, e.g., pelletizing.(1) In the pelletizing process, the essentially mechanical step of balling is extremely critical since the strength of the pre-fired pellet determines the firing conditions. The ability of the proper amount of moisture to hold together a ball of the very fine ore concentrate particles has long been recognized. It is a charac¬teristic of the reaction at the interface between the ionic solid of the ore concentrate and the polar water phase which overlays the solids. The strength in such moisture laden balls, the green strength, is a strong function of the water content (Figure 1) and thus deteriorates rapidly for either a small excess or a small deficiency of moisture. For purposes of commercial practice, the control of green ball handling properties by accurate control of ball moisture is too demanding. Moreover, as the ball is heated towards its hardening tempera¬ture, e.g., 1300&apos;C, there is a substantial drying reaction which would lead to such a low dry strength of the ball that it would not support its own weight much less the weight of other balls in a firing furnace.

Jan 1, 1976