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By Aner W. Erickson

"Preliminary examination of tungsten deposits on the Mountain View property near Hyder, Alaska, was made by Neal M. Muir, an engineer of the Bureau of Mines daring the summer of 1942. Fifteen samples were cut, rough esti¬mates of ore reserves were made, and it was proposed to extend the drift on scheelite-bearing vein 300 feet in a northwesterly direction.From May 22 to October 24, 1944, an exploratory project was conducted on the property by the Bureau. In the course of this work, the camp buildings were rehabilitated; the dam, hydraulic line, and machinery were repaired; 226 feet of drift was driven; 80 groove samples aggregating 3.9 tons in weight were cut; a 6,000-foot surface and underground traverse was run; and the area was mapped in detail.In its program of exploration of mineral deposits, the Bureau of Mines has as its primary objective the more effective utilization of our mineral resources to the end that they make the greatest possible contribution to the national security and economy. It is the policy of the Bureau to publish the facts developed by each exploratory project as soon as practicable after its conclusion. The Mining Branch, Lowell B. Moon, chief, conducts preliminary examinations, performs the actual exploratory work, and prepares the final report. The Metallurgical Branch, R. G. Knickerbocker, chief, analyzes samples and performs beneficiation tests. Both these branches are under the supervision of Dr. R. S. Dean, assistant director.Special acknowledgment is doe Neal W. Muir, project engineer, and Robert S. Sanford, acting chief, Alaska Division, Mining Branch, for their supervision of the field work and revision of the report.Acknowledgment is also made to Silbak Premier, Ltd., for rendering valuable assistance in the repair of equipment and for extending various courtesies to Bureau of Mines personnel during the conduct of this project.The Mountain View property is located at latitude 55° 59' north, and longitude 130° 03' west in the Salmon River mining district of southeastern Alaska, about 5 miles in a northwesterly direction from the town of Hyder, which lies at the head of Portland Canal, as shown in figures 1 and 2. Vein outcrops and surface workings are at an elevation of 950 feet and occupy the west flank of a low ridge between Skookum and Fish Creeks, as shown in figure 3. The portal of the long adit exposing the vein at depth is on Skookum Creek about 550 feet north of the confluence of Skookum and Fish Creeks.Access to the property is over a 4-foot wide trail built and maintained by the United States Forest Service. This trail is suitable for pack animals and is adequate for transportation of supplies and material for exploratory work. During the periods of camp construction and past exploratory operations a 4,000-foot, single-cable, aerial tramway, now in disrepair, served for transportation of materials and all machinery from the Salmon River Highway to the property. The cost of such hauling was high, amounting to $12 a ton. Topography is suitable for construction of a ""cat road"" 2 miles in length, connecting the property with the Salmon River Highway. It is estimated that such a road could be built for $5,000 a mile, and supplies, machinery, and concentrates could be haled over it at a cost of less than $2.50 a ton."

Sep 1, 1946

By M. S. Seehra, V. S. Babu

"INTRODUCTION The accurate determination of the free silica index in coal mine dusts is an important requirement because severe health hazards are believed to be associated with the inhalation of respirable-sized silica particles.1-6 Free silica refers to the three polymorphs of silica (Si02)viz., quartz, cristobalite, and tridymite-although quartz is usually the dominant form in most mine dusts.6 The free silica index is the concentration in micrograms of free silica in air per m3 of air sampled corrected to standard conditions of 25°C and 760 mm/Hg, the present MSHA (Mine Safety and Health Administration) limit on time-averaged basis being 100 µ.g/m 3 for coal mines. A recent review7 has concluded that quartz, cristobalite, and tridymite particles impart nearly equal long-term hemolytic damage when compared on a per unit surface area basis.At present, two experimental methods-viz., transmission infrared spectroscopy (TIRS) and x-ray diffraction (XRD)-are commonly used for the determination of silica concentrations in mine dusts. In TIRS, which has been adopted by MSHA and is commonly called the P7 method, the silica absorption band near 800 cm - 1 is used for quantification. However the mineral kaolinite, which is commonly present in mine dusts, also has absorption band, albeit weaker, at 800 cm- 1• To correct for this interference, one uses the stronger 915-cm -1 band of kaolinite to determine the concentration of kaolinite, and the kaolinite contribution to the absorbance at 800 cm-1 is then determined from a calibration curve, leading to the determination of silica by subtraction. In the XRD technique, usually an internal standard such as CaF 2 is used to determine the concentration of silica from line intensity measurements. XRD has the added advantage that concentrations of quartz, cristobalite, and tridymite can be determined.8•9 In an exhaustive study on the precision of the techniques ofTIRS and XRD for monitoring worker exposure,9 the conclusion has been reached that both methods measure silica within 253 of the ""true"" value 953 of the time in a single laboratory."

Nov 1, 1995

By G. L. Oldright

The data in this paper were collected at the Trail smelter of the Consolidated Mining & Smelting Co. of Canada, Limited, through the courtesy of S. G. Blaylock, vice president and general manager; James Buchanan, smelter superintendent; George Murray, assistant smelter superintendent; and the staff members given in Paper XI, Report of Investigations 3243. INTRODUCTION This paper is the thirteenth of the series on Smelting in the Lead Blast Furnace, and the third of the series on Handling Zinciferous Charges. Tyro other papers have been written on the Rate of Descent of the Stock Column, and Formation of Accretions. These are Reports of Investigations 2963 and 3094, for the Tooele plant and the Bunker Hill plant, respectively.

Jan 1, 1934

By David C. Byrne

PURPOSE: Evaluate practical technological advances in hearing protective devices for use in different mining environments. RESEARCH SUMMARY: Previous NIOSH research shows that miners develop hearing loss much more quickly than nonoccupationally noise-exposed individuals and that miners experience a greater severity of hearing loss than would be expected for nonoccupational noise-exposed persons of the same age and sex. As described in the National Occupation-al Research Agenda, problems created by occupational hearing loss include(1) reduced quality of life due to social isolation and unrelenting tinnitus,(2) impaired communication with family members, the public, and coworkers, (3) diminished ability to monitor the work environment (i.e., warning signals, equipment sounds, etc.), (4) lost productivity and increased accidents resulting from impaired communication and isolation, and (5) expenses for workers’ compensation and hearing aids. Although eliminating hazardous noise is the long-term solution to the noise problem, miners will likely need to rely on personal hearing protection in certain situations for quite some time. However, it is well known that noise attenuation provided by hearing protectors as they are worn during everyday use is usually quite different (i.e., worse) than when tested under lab conditions. In addition, workers may refuse to wear their hearing protection for any number of reasons. This project was initiated to evaluate practical technological advances in hearing protectors, with an emphasis on optimizing the balance between effectiveness, comfort, over protection, and communication ability. The recently completed auditory research facility is now under-going the accreditation process conducted by the National Institute of Standards and Technology under the National Voluntary Laboratory Accreditation Program. Experiments are planned to investigate the factors that affect a miner’s ability to hear hazard and warning sounds (e.g., roof working, alarm signals, spoken communications, etc.). A service contract has been initiated to record and digitally store samples of typical warning sounds heard in an underground coal mine. This information will be analyzed in the lab to develop recommendations that can be offered to the mining community regarding correct earplug/earmuff usage to maximize there cognition of hazard and warning sounds while adequately protecting the miners’ hearing.

Jan 12, 2001

By Earl L. Fosse

"Preliminary examination of the Khayyam mine indicated that greater reserves of copper might be found by trenching, sampling, detailed geological and topographical mapping, and diamond drilling. The deposit seemed to be a potential source of sulfur, also, for use in the manufacture of paper pulp.Formal examination of the Khayyam mine by the Bureau of Mines was a follow-up of a preliminary examination made by W.S. Wright and the author on October 19-21, 1944. John Reed and W. S. Twanhofel, of the Geological Survey, visited the property during the summer of 1943 and suggested that the prospect be examined further.Preliminary examination of the Stumble-On claim was made July 1-3, 1945, concomitant with the formal examination of the Khayyam mine 11/2 miles to the west.In its program of exploration of mineral deposits, the Bureau of lanes has as its primary objective the more effective utilization of our mineral resources to the end that they make the greatest possible contribution to national security and economy, It is the policy of the Bureau to publish the facts developed by each exploratory project as soon as practicable after its conclusion. The Mining Branch, Lowell B. Moon, chief, conducts pre¬liminary examinations, performs the actual exploratory work, and prepares the final report, The Metallurgical Branch, R. G. Knickerbocker, chief, analyzes samples and performs beneficiation tests. Both these branches arc under the supervision of Dr. R, S. Dean, assistant director.Special acknowledgment is due Robert S. Sanford, acting chief, Alaska Division, Mining Branch, for his help in the preparation of this report and during the project work.The Khayyam property is situated at 550 18’ north latitude and 1320 24’ west longitude on Prince of Wales Island in Southeastern Alaska. (see fig. 1.) The mine adit is 2,350 feet above sea level, near the summit of a mountain ridge, and 2.8 miles in an airline southwest of the head of McKenzie Inlet, a southern branch of Skown Arm. Skowl arm is navigable by ocean-going vessels .to the mouth of McKenzie Inlet, where reefs and rocky islands limit the channel width to 50 yards. Beyond this point the inlet widens to nearly half a mile. Coast and Geodetic Survey chart 8142 indicates from 12 fathoms of water at this narrow neck to more than 30 fathoms throughout the remainder of McKenzie Inlet, The old ore bunker and dock at the head. of the inlet are beyond repair. A new ore bunker and dock would have to be built if a large-scale mining operation were established.The mine can be reached by trail along the western ridge that lies on the west bank of Omar Creek. The trail is approximately 4 miles in length. The grade is rather steep to an elevation of 1,500 feet, but the last 21 miles can be traveled over gentle slopes along the crest of the ridge.Ketchikan is 30 miles by air and 42 miles by water from the head of McKenzie Inlet. Feed, hardware, fuel oil, lumber, and explosives can be purchased at Ketchikan and delivered by boat to McKenzie Inlet. By using an airplane, all small equipment and camp supplies could be using an airplane, all small equipment and camp supplies could be dropped with cargo parachutes near the mine."

Sep 1, 1946

"A coordinated, integrated research effort aimed at studying the scientific, engineering and medical aspects of the respirable dust problem is underway in the areas of dust generation, dust dispersion and dilution, dust characterization, interaction of dust and lungs, and relationship of seam characteristics to dust generation and mobility. (FIGURE 24) The Center's research program explores these concerns with the objective of refining existing strategies and developing new respirable dust control techniques that are consistent with the dust-lung interaction processes that lead to mine worker disability. The fundamental aspects of this work are applicable to the control of respirable dust problems in both hard rock mines and coal mines and to other dusts such as diesel-generated.Research projects in the Generic Mineral Technology Center for Respirable Dust have effected several improved methods for the preparation and characterization of the dusts needed by these projects. Superior procedures for generating ""standard"" dust samples have been developed and are in regular use in the laboratory. Questions raised during the course of some projects regarding ""stale"" versus ""fresh"" dust have led to the development of sampling techniques where the dust is directly collected in a surfactant. MSHA and CANMET have requested and received information on Center generated software. An equipment manufacturer, TSI, Inc., requesting input on modifying the inlet of an aerosol sampler has been assisted as a result of research that was conducted at the University of Minnesota.The objectives, scope and progress of all the research projects in the Center, in the form of abstracts and reports, have been detailed in Volume 1 of this series. Research papers written by the principle investigators and resulting from the findings of projects (FIGURE 25) and which are funded by U.S. Bureau of Mines grant number G1135142 have been published in Volumes 3 through 6 and Volume 8 of this series. Volume 2 relates the cooperation and interaction of the U.S. Bureau of Mines and the Generic Mineral Technology Center for Respirable Dust in research on the problem of respirable dust in the mineral industries."

Aug 31, 1989

By R. B. Stotelmeyer

Mineral resources, or a potential for their discovery, occur at 34 localities in the Glacier Peak Wilderness and adjacent areas of the north Cascade Range of Washington (see plate). Eighteen of the mineral deposits are in the established Wilderness, four are in or partly in contiguous RARE II (Roadless Area Review and Evaluation) lands recommended by the Forest Service for addition to the Wilderness (A, D and G6031.), three are in adjacent RARE II lands excluded from wilderness consideration, and nine are in nearby roaded areas excluded from the RARE II inventory. Mineral commodities that might be produced from the Wilderness and recommended additions are gold, silver, copper, lead, zinc, molybdenum, arsenic, cadmium, tungsten, cobalt, limestone (marble), pumice, and volcanic cinders. Mineral production from adjacent lands might include most of these commodities, plus antimony, decorative stone, pyrite, silica, and garnet.

Jan 1, 1982

By L. R. Willmott

An ethanolamine purification unit for removing carbon dioxide and hydrogen sulfide from Firscher-Tropsch synthesis gas was installed at the Bureau of Mines synthetic liquid fuels demonstration plant at Louisiana, Mo. The unit was a surplus Radford Girbotol unit from the Missouri Ordnance Works modified for a capacity of 90,000 std. cu. ft per hour of synthesis gas at 450 p.s.i.g., operating pressure. The hydrogen sulfide loading of the feed gas was specified at 500 grains per 100 cu. Ft. The unit was designed by the Girdler Corp. and installed by the Koppers Co. Initial operations were conducted far 11 days in May 1951. Thereafter 7 additional runs were made, varying lo duration from 8 to 54 days. The last run was terminated on May 29, 1953, the total time the Plant wars in operation being 219 days.

Jan 1, 1956

By David C. Byrne

PURPOSE: Evaluate practical technological advances in hearing protective devices for use in different mining environments. RESEARCH SUMMARY: Previous NIOSH research shows that miners develop hearing loss much more quickly than nonoccupationally noise-exposed individuals. Also, miners experience a greater severity of hearing loss than would be expected for nonoccupational noise-exposed persons of the same age and sex. As described in the National Occupational Research Agenda, problems created by occupational hearing loss include (1) the reduced quality of life due to social isolation and unrelenting tinnitus, (2) impaired communication with family members, the public, and coworkers,(3) a diminished ability to monitor the work environment (e.g., warning signals, equipment sounds, etc.), (4) lost productivity and increased accidents resulting from impaired communication and isolation, and (5) expenses for workers’ compensation and hearing aids. Although the elimination of hazardous noise is the ideal long-term solution to the noise problem, miners will likely need to rely on personal hearing protection in certain situations for quite some time. However, it is well known that noise attenuation provided by hearing protectors as they are worn during everyday use in the workplace is usually worse than when tested under laboratory conditions. Additionally, workers may refuse to wear their hearing protection for any number of reasons. Therefore, this project was initiated to evaluate practical technological advances in hearing protectors, with an emphasis toward optimizing the balance between effectiveness, comfort, overprotection, and communication ability. Currently, the necessary in-house laboratory facilities and research techniques are being finalized. Individual experiments are planned that involve analysis of new hearing protector technology under both laboratory and field conditions. The laboratory components are to consist of con-trolled studies using human subjects and/or an anthropometrically correct artificial test fixture to evaluate the adequacy/effectiveness of various hearing protective devices. Field studies are planned to determine the actual usefulness and practicality of the hearing protectors as used in diferent mining environments. Recommendations can then be offered to the mining community regarding correct earplug/earmuff usage that maximizes recognition of hazard/warning sounds while adequately protecting the miners’ hearing.

Jan 12, 2000

By Thomas E. Finch

This report is a continuation and expansion of a previous USBM grant (No. G0254004) which examined alternative methods of handling the parting between two coal seams in a surface mining operation. The alternative methods consist of equipment implementation in either a stowing or haulback technique. Following a typical strip mine conformation, the parting is directly stowed or hauled back and placed in the pit bottom after second seam removal. The objectives are to produce an environmentally sound material placement technique and to increase prime stripping machine utilization. This report contains the engineering philosophy behind two computer programs created to evaluate parting handling methods over d wide range of coal and parting thickness ratios. The nature of the computer approach allows cost sensitivity analysis and quick updating of costs. The two programs are clearly presented with documentation and examples such that consumers may apply then to their own operations.

Jan 1, 1977

By D. J. MacDonald

The Bureau of Mines investigated two alternative methods for treating a zirconium-bearing chloride-sulfate strip liquor to obtain reactor-grade Zr02. One method involves neutralization with NH3 and the other hydrothermal precipitation. The strip liquor was derived from zircon sand by a Bureau of Mines method for separating zirconium and hafnium via solvent extraction with a tertiary amine. Neutralization with NH3 to precipitate hydrous zirconium oxide required 0.9 to 1.1 g NH3 per gram of zirconium. The NH3 can be recovered for recycle. Zr02 that met reactor-grade specifications was produced by precipitation with NH3? Hydrothermal precipitation of Zr02 from strip liquor required that the solution be maintained at 2600 C and 680 psi for 10 min and in a non-corrodible pressure vessel. In bench-scale experiments both methods gave-zirconium recoveries greater than 99 pct.

Jan 1, 1984

By Alexander May

The Bureau of Mines conducted studies to determine if phosphogypsum, a waste material from the processing of phosphate rock, contains hazardous toxic materials as defined by the Environmental Protection Agency (EPA) and whether leaching of these toxic materials and radium may occur. Samples of the phosphogypsum stockpiled material were evaluated using the EPA extraction procedure, atomic absorption, neutron activation, x-ray diffraction, and chemical and physical means. Radiological tests performed used both the germanium-lithium and emanation methods. The data show that the phosphogypsum stockpiles are not hazardous toxic waste as defined by EPA criteria. Trace elements and radium are not leached from the phosphogypsum stockpiles. Absorption of trace elements and radium by phosphogypsum is the major reason for their not being leached. The standard error of measurement of radium concentrations was 4.7 pCi/g.

Jan 1, 1983

Minimize failures or inefficiency in the operation of in situ mining wells. Approach The proper design, construction and development of wells are important to any in situ leaching operation. To permit cost-effective production from an underground ore body by leaching it in place, many wells are normally installed. Construction and maintenance costs increase with the number of wells, and poor construction and maintenance procedures result in production losses and negative environmental impacts, To minimize these losses and impacts, the Bureau of Mines conducted an investigation to determine the optimum in situ well construction and operating procedures for the minerals industry. Factors considered during the investigation included drilling equipment and procedures; types of well casing and grouting; completion methods, e.g, screening or perforation; and system maintenance. The data collected were used to prepare a manual that offers guidelines

Jan 1, 1984

By John C. Edwards

Chapman-Jouguet detonation calculations were carried out for pentaerythri-tol tetranitrate (PETN), TNT, and ammonium nitrate-fuel oil (AN-FO) explosives using the compressibility form of an equation of state of hard spheres based upon Percus-Yevick (PY) theory, and a chemical equilibrium detonation code called TIGER. Similar calculations were also carried out with the Becker-Kistiakowsky-Wilson (BKW) equation of state. For PETN, the BKW equation gives somewhat better agreement with experimental values of detonation velocity and pressure. However, in terms of experimental temperatures and concentrations of the minor product species (NO), the predictions of the PY equation are shown to be more satisfactory. Similar comparisons of experimental and theoretical results for TNT and AN-FO indicate that the PY equation has general utility in predicting the detonation properties of condensed explosives at moderate loading densities (Po < 1.3 g/cm3).

Jan 1, 1974

By George S. Rice

"Soon after the armistice, an investigation was conducted by the writer on the use of liquid oxygen for explosive purposes in Germany, so far as the conditions of such investigation wore permitted at the time. The results of this inquiry were published in Technical Paper 243, entitled ""Development of Liquid Oxygen Explosives during the War.""Recently, through the courtesy of Dr. C. L. Parsons, former chief chemist of the Bureau, who was visiting Germany, and Mr. Chester L. Benson, of the American Expeditionary Forces in Germany, data was obtained from the Deutsche Oxhydric A. G., Surth near Cologne, (one of the principal manufacturers of liquid oxygen installation) concerning the number of plants which bad been installed in Germany during the period following the armistice. An analysis of the figures obtained shows the following installations in different kinds of mining operations:"

Sep 1, 1920

By W. M. Merritts

A joint investigation by the Bureau of Mines and the Christopher Coal Co. at the Humphrey No. 7 mine, operating in the Pittsburgh coalbed in northern West Virginia, was undertaken to gain more insight concerning the hazardous emission of methane gas in mining, This report describes the equipment, procedure, and results. Horizontal bleeder holes drilled in the faces drained large quantities of methane, eliminating downtime of mining equipment. Also, larger quantities of methane were removed by forcing 14 to 25 g.p.m. water at 25 to 200 p.s.i. 5 pressure into the bleeder holes, In one infusion test a fluorescein dye was added to the infusion water; in later mining operations, the infusion water was traced for a distance of 1,500 feet. With vacuum pump applied to the horizontal hole the gas-flow rate increased, and the methane content decreased.

Jan 1, 1962

By J. M. Mutmansky, L. Xu

"IntroductionSince the establishment of the star,just concentration of 2 mg/m3, a strong effort has made by mining engineers and researchers to provide better dust control equipment and procedures for underground coal mines.Particular areas of success have been implementation of better coal-cutting strategy to control dust generation, better design of water sprays for dust suppression and air movement, use of scrubbers, and improved design of face ventilation systems. A drastic improvement occurred over time such that the average dust concentrations for continuous miner operators dropped from 6.5 mg/m3 in 1968 to 1.3 mg/m3 in 1980 and for auger, cutter, longwall, and roof bolter occupations from 2.7 mg/m3 in 1973 to 1.6 mg/m3 in 1980 (Niewiadomski, 1983).While dust concentrations in mining sections have been dropping considerably, one problem area has been mining sections where quartz is a considerable portion of the airborne dust. The federal regulations require that quartz content must be held below 0.1 mg/m3 in the air regardless of the concentration of the total dust. This legislation limits the allowable dust concentration to a ""reduced standard"" of 10/ (% quartz) when the quartz content of respirable dust in the mine atmosphere is more than 5%. Today, approximately one-third of underground coal mining operations have designated areas with more stringent dust standards in place, and many mines experience considerable difficulty in meeting these standards (Jankowski, and Babbitt, 1989).It is well known that metal miners subjected to respirable dusts high in quartz have a higher incidence of silicosis than those exposed to dust low in quartz. However, the role of quartz in the development of coal workers' pneumoconiosis is still a highly controversial question, in spite of the large number of research projects devoted to this subject over the last 20 years. Because coal seams contain less quartz than metal ores and quartz often comes from sources outside the coal seam (e.g., roof and floor), it is difficult to relate studies that deal with the quartz content in coal seams and the incidence of coal workers' pneumoconiosis. Hamilton, Ogden, and Vincent (1983) have provided a plausible explanation for the incidence of the disease by hypothesizing that the quartz content does not affect the probability of developing pneumoconiosis until some threshold value (generally thought to be about 10%) is exceeded.The objective of the research studies summarized here was to obtain a better understanding of quartz occurrences in airborne coal mine dust by studying the variations of the quartz levels in different dust sizes and the relationship between the quartz content in airborne coal mine dust and the quartz content in the mined material. The implications of the results to control of dust in high-quartz sections will also be discussed."

Mar 1, 1992

By N. Malakondaiah

Several growth chamber and laboratory experiments were conducted to study the germination behavior of plant species on mine spoils and plant growth responses to nutrients on spoils and topsoils. Experiments were conducted to study the germination potential of some native and introduced species under various conditions. The seeds of green needlegrass, side oats grama, thickspike wheatgrass, crested wheatgrass, birdsfoot trefoil and emerald crownvetch were less tolerant, whereas those of alkali sacaton. durar hard fescue, slender wheatgrass, yellow sweetclover and alfalfa were most tolerant to the sodic mine spoil conditions. Addition of leonardite improved the germination potential of some of the poor genninators. Slender wheatgrass and yellow sweetclover were used as test plants to study the fertility status and productivity potential of stockpiled topsoils and spoils collected from Center. Glenharold and South Beulah of North Dakota. The topsoils were neither saline nor sodic but low in N and P. The spoils were neutral to alkaline with SAIL of 12-32, EC of 1.8-5.5 mmhos/cm, Olsen&apos;s P< µ4g/g, and total N <0.07%. Application of N and P together to the topsoils increased the yield of wheatgrass and sweetclover by 88% and 70% of their respective maximum yields, whereas near maximum yields were obtained for both the species by the same treatments to the spoils. The average yields on topsoils were higher than the yields on spoils. The concentrations of major nutrients were higher in plants grown on topsoil, whereas the opposite was true with the concentrations of Mn, Zn, and Cu. Growth chamber experiments were also conducted to study the growth responses of alfalfa, oats and slender wheat grass by the application of Mn and Zn to a sodic coal mine spoil which was previously used for pot culture experiments. Significant growth responses to Mn and Zn were observed in alfalfa but not in oats or slender wheatgrass. Fertilizing the spoil with Mn along with NPK increased the yield of alfalfa to 85% and with Mn + Zn to 99%. Growth responses and plant composition results of this study confirm that the application of major nutrients to spoils can accentuate Zn and Mn deficiencies in some plants.

Jan 1, 1982

By L. E. Schultze

Experiments were conducted by the U.S. Bureau of Mines to verify enhancements due to chloride and surfactant additions in the leaching system of chalcopyrite with ferric sulfate and sulfuric acid. A statistical experimental design was used and equipment was designed to eliminate contributions from changes in solution electrochemical potential during the course of the measurements. Results confirmed that chloride additions increased chalcopyrite leaching by as much as 94 pct over the electrochemical potential versus hydrogen electrode range of 630 to 750 mV at pH 1.7 and 50°C. Total iron concentration had no effect over the range of 1 to 5 g/L. The effect of surfactant addition was less well defined. While additions of LA 790 (a polyoxyethylene lauryl ether) resulted in increased copper leaching in several of the tests, the differences were too small to be statistically significant. No interaction effect could be verified.

Jan 1, 2010

By Fred N. Kissell, Jay F. Colinet

The two major lung diseases of miners are "blacklung" and silicosis. Blacklung, or pneumoconiosis, was first recognized as a disease of British coal miners in the 1600s. However, investigations into the cause of blacklung disease did not begin until the 1900s. The causative agent of pneumoconiosis in coal miners was thought to be silica until studies in the United Kingdom provided evidence that expo- sure to coal dust containing minimal silica could also cause pneumoconiosis. In the Federal Coal Mine Health and Safety Act of 1969, coal workers pneumoconiosis (CWP) was defined as "a chronic dust disease of the lung arising out of employment in an underground coal mine." Diagnosis of CWP is generally based on chest x-ray findings and a patient&apos;s history of working in coal mines, usually for 10 or more years. In its early stages, CWP is called "simple CWP." Miners with simple CWP are at increased risk of developing an advanced stage of the disease, called "progressive massive fibrosis" pMF) or "complicated CWP." PMF (complicated CWP) is associated with significant decreases in lung function and oxygen- diffusing capacity. PMF is also associated with breathlessness, chronic bronchitis, recurrent chest illness, and episodes of heart failure. Coal miners with silicotic lesions or PMF have an increased risk of tuberculosis and other mycobacterial infections. PMF may progress even in the absence of further dust exposure. This disease is also associated with increased mortality (National Institute of Occupational Safety and Health [NIOSH] 1995). The most recent study to determine the prevalence of CWP in coal workers was in the mid- 1990s. The average prevalence of CWP was 2.8%, but for those with 30 or more years in the industry it was 14%. For the 10-year period from 1987 to 1996, 18,245 deaths were attributed to CWP. The most frequently recorded occupation on the death certificate (70%) was mining machine operator (NIOSH 1999). Silicosis may develop when inhaled respirable crystalline silica (quartz) is deposited in the lungs. The clinical diagnosis of silicosis is based on (1) recognition by the physician that the level of silica exposure is adequate to cause the disease, (2) the presence of chest radiographic abnormalities consistent with silicosis, and (3) the absence of other illnesses (e.g., tuberculosis or pulmonary fungal infection) that may mimic silicosis. The radiographic patterns are often the same for CWP and silicosis; thus, these diseases are sometimes distinguishable only by work history or pathological examination. Chronic silicosis commonly involves 15 or more years of exposure to silica. The characteristic microscopic feature is the silicotic nodule. Chronic silicosis is often asymptomatic and may manifest itself as a radiographic abnormality with small, rounded opacities of less than 10 mm in diameter, predominantly in the upper lobes. Lung function may be normal or show mild restriction. Chronic silicosis is also associated with a predisposition to tuberculosis and other mycobacterial infections and with progression to complicated silicosis.