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By V. R. Miller

The Bureau of Mines conducted research on substitute brazing filler alloys with properties similar to those of silver filler alloys in an effort to conserve silver and reduce hazards from cadmium emissions. Experimental work was conducted first on the commercial silver brazing alloys BAg-I, BAg-la, BAg-2, and BAg-3 to establish criteria for evalu-ating the substitute alloys. Properties investigated included the wettability of copper, brass, and steel substrates, and the strength of joints made with the filler alloys. A series of experimental alloys containing 50 to 60 pct Cu, 20 to 28 pct Mn, and 17 to 30 pct Zn was prepared and evaluated, together with Cu-Mn-Zn alloys with 5 pct Pb or 2 pct Ni. Wetting properties and joint strengths were not as good as those for silver filler alloys, and the high application temperatures reduced the copper and brass base metal strengths. However, experimental alloys containing 70 pct Cu, 15 to 20 pct Mn, and 10 to 16 pct Sn had wetting and strength properties approaching those of the silver filler alloys. The application temperatures for these alloys were high-er than those for silver fillers, but not as high as those for the Cu-Mn-Zn alloys. With the Cu-Mn-Sn alloy fillers, copper alloy joint members are less deteriorated by recrystallization than when applying Cu-Mn-Zn alloys. The Cu-Mn-Sn system has potential for further devel-opment as a substitute brazing alloy system, particularly if the melting temperature can be reduced by the addition of other elements without decreasing the ductility and wetting.

Jan 1, 1983

By Alexander May

In this Bureau of Mines publication stability constants for complexes of diethylenetriamine, 2-aminoethyl sulfide, triethylenetetramine, and 1,8-diamino-3,6-dithiaoctane with copper, nickel, zinc, and cadmium were deter-mined. The amine complexes were found to be much more stable than the analogous thio complexes. The results are interpreted in terms of possible molecular structure of the complexes.

Jan 1, 1974

By B. J. Moore

This Bureau of Mines publication estimates that U.S. helium resources as of January 1977 were 710 billion cubic feet. These resources are broken down into four classifications, as follows: Helium in measured natural gas resources and in storage, 201 billion cubic feet; helium in indicated natural gas resources, 150 billion cubic feet; helium in hypothetical natural gas resources, 175 billion cubic feet; and helium in speculative natural gas resources, 184 billion cubic feet.2 Most of the helium in natural gas is presently dissipated as natural gas is consumed as fuel and for other purposes. Helium resources of the United States may also be divided into three other categories: (1) Depleting and undiscovered natural gas resources, 589 billion cubic feet; (2) nondepleting natural gas, 83 billion cubic feet; and (3) storage, 38 billion cubic feet, of which 37 billion cubic feet is federally owned and 1 billion cubic feet is privately owned. The United States does not have any significant leasehold rights in the depleting fuel gas resources. However, through the Department of the Interior, it does have leasehold rights to about 70 percent of the helium found in nondepleting natural gas, and it owns over 90 percent of the helium in storage.

Jan 1, 1979

By M. Karmis

Surface subsidence is an inevitable consequence of many underground mining operations and has been recognized as such since the fifteenth century. Damage resulting from this phenomenon ranges from simple land settlement to severe structural damage to buildings and has been witnessed in rural (Illinois, Colorado, West Virginia, Virginia, Pennsylvania) as well as in urban areas (Pennsylvania, West Virginia, Illinois, Wyoming). In fact, it is estimated that over 2 million acres of land across the United States have been affected by mining subsidence, of which 140,000 acres are in urban areas (Singh, 1978; Johnson and Miller, 1979). Further, it is estimated that during the next twenty years an additional 1.5 to 2.4 million acres of land will also be affected by mining. Subsidence prevention is not feasible, at least under the existing technologic and economic constraints of underground coal mining. Foreign experience has demonstrated, however, that subsidence can be successfully controlled if an accurate method of predicting ground movements is available. Such techniques have been developed in many coalfields, where it is currently accepted that subsidence can be predicted within ± 20 percent of the actual values. Furthermore, such movements can be translated into anticipated structural failures using established damage criteria, thus enabling appropriate precautionary measures to be implemented.

Jan 1, 1983

By N. A. Gokcen

This Bureau of Mines report reviews and summarizes recent studies of the rates of chlorination of aluminous resources with CO and C12 mixtures with and without COC12. No reaction mechanism could be obtained from the existing results; however, diffusional barriers in the gas and solid layers probably control the chlorination rate in thermogravimetric experiments. Fluidized beds of particles smaller than 0.1 mm appeared to show very little solid layer diffusional barrier. For optimum chlorination the particle size should probably be less than 8 mm, the calcination temperature approximately 700° C, and the chlorination temperature from 650° to 750° C. Relatively rapid chlorination with COC12 in thermogravimetric experiments was attributed partly to the simultaneous supply of reductant and chlorinator by one gas to the sample reaction site. Comparable results for chlorination of fluidized beds with COC12 are not available. Equimolar mixtures of CO and C12 produced the optimum rate of reaction. Addition to the calcine of 10 to 20 wt-pct NaCl accelerated the rate of chlorination, and addition of SiC14 to the gas mixture decreased the rate of chlorination of SiO2 drastically, but at the expense of chlorination of significant fractions of Al2O3. Further research in various areas is suggested.

Jan 1, 1983

By Wallace W. Roepke

The Bureau of Mines determined coal-cutting forces and primary dust generation of four styles of radial gage bits as used on end rings of continuous mining machines. Direct comparisons for reference were made with two widely used conical plumb-bob types having 60' and 90' (nominal) included tip angles. The cutting forces for all of the gage bits were similar to those of the 60°-tip plumb-bob bit. All bits except the RAD-3 gage bit generated similar amounts of primary total dust at shallow cutting, but during deeper cutting, the amounts varied and the gage bits produced as much as 2-1/2 times the dust produced by the 60° bit. This seems atypical since past experience has always shown differences in dust generation at shallow cutting. The specific energy was more like that found previously with other bits, since the values were spread at shallow cutting but became nearly similar at deeper cuts. The 90° bit and the RAD-3 gage bit are not recommended for use except in extremely difficult cutting conditions where dust and forces are of secondary importance. The choice among the remaining four bits can be made on the basis of dust, energy, forces, or cost, as circumstances dictate.

Jan 1, 1983

By R. J. Fantel

The Bureau of Mines investigated the resource availability of titanium minerals from 63 mines and deposits in 12 market economy countries. These mines and deposits contain, at the demonstrated resource level, an estimated 438 million metric tons (mt) of titanium dioxide (TiO2) in the minerals rutile, ilmenite, leucoxene, and anatase. An additional 314 million mt of TiOz is available from inferred resources. If all titanium minerals and other recovered heavy minerals are sold at total costs at least equal to the January 1984 market prices, approximately 200 million mt of contained TiO2 could be recovered in total. In terms of mineral concentrates, this equals approximately 11 million mt of rutile concentrate, 187 million mt of ilmenite concentrate, 3 million mt of leucoxene concentrate, 13 million mt of synthetic rutile concentrate (in addition to the ilmenite), and 89 million mt of titanium slag. The study indicates that world resources of low-cost rutile are declining. In order to maintain future supply for high-grade titanium resources, alternate sources will need to be developed, which may include higher cost rutile mines, Brazilian anatase deposits, increased production from slag operations, or more synthetic rutile capacity from ilmenite resources, which are abundant.

Jan 1, 1986

By Gordon L. Kinney

Following a year of great uncertainty, the political situation in Bangladesh improved during 1976. The major problem for Bangladesh remained the high birth rate and crowded conditions. Bangladesh had the highest population density of any agrarian country--over 80 million people in a land area of 144,000 square kilometers, 65% of which is considered arable. The Government, with considerable foreign assistance, was actively encouraging voluntary family planning, and set a growth rate target of 2% per year or less. However, even if the growth rate was reduced to the target level immediately, the population of Bangladesh would nevertheless nearly double within 20 years.

Jan 1, 1980

By Donald J. Barnes

The Glacier View RARE Ii further planning area contains no identified mineral deposits, other than stone, which cannot compete favorably with similar deposits closer to major markets. Pierce County mining claim records show six coal claims were located in the study area between 190b and 1907; however, no coal was found at the described locations. Two coal prospects, the H.O. Lamming and Floyd Rice, are within 0.5 mi (0.8 km) of the area's west boundary (fig. 1). At these prospects, impure bituminous coal beds strike approximately north and dip east toward the study area. Analyses of samples 1/ indicated an average heating value of 2,767 BTU 2/ per pound (6,436 joules per kg). Because of the low heat value, this coal is subeconomic. Intense folding and faulting which disrupted the beds would limit the use of conventional coal mining equipment, making future economic development even less likely. Trinity Resources of Houston, Texas has leased approximately 1,404 acres (568 ha) inside the study area and an additional 1,020 acres (413 ha) adjacent to the study area for oil and gas exploration. However, no oil or gas wells are known to have been drilled in or around the study area.

Jan 1, 1983

By C. M. Frost

Crude shale oil produced during in situ retorting by the Bureau of Mines at Rock Springs, Wyo., was refined by three schemes. In the first, the crude oil was fractionated to raw naphtha and 400° F+ residuum. The residuum was hydrogenated over cobalt molybdate catalyst at 815° F and 1,100 psig. The blended raw and 160°-400° F hydrogenated naphthas were hydrodenitrified and then catalytically reformed. The 400° F+ hydrogenated oil was catalytically cracked. In the second scheme, the crude was hydrogenated over nickel-tungsten catalyst at 800° F and 1,500 psig. The hydrogenated fractions were processed by methods used in the first scheme. The third scheme resembled the second but, prior to hydrogenation, the crude was "hydrostabilized" over cobalt molybdate at 500° F and 500 psig. Yields of reformate and cat-cracked gasoline as volume-percents of the crude, and research-method octane numbers (with 3 ml TEL) for the three methods were as follows: First method, 32 pet reformate, 90 octane; 19.5 pct cracked gasoline, 99.2 octane. Second method, 29 pet reformate, 81.1 octane; 21.3 pct cracked gasoline, 99.6 octane. Third method, 28.2 pet reformate, 86 octane; 28.7 pct cracked gasoline, 95.9 octane.

Jan 1, 1974

By Joseph Coffman

There are 14 operations that supply 97% of the Market Economy Country (MEC) manganese and contain nearly all of its resources. Six mines account for about 70% of the production and 85% of the resources; there are no known resources that are economically close to those that are currently being mined. Costs (January 1989 dollars) of producing manganese concentrates from the operations evaluated are estimated to range from $ 0.96 to $ 1.86 per long ton unit (ltu or 22.4 lb) of contained manganese. Total MEC demonstrated resources evaluated amount to about 1.2 billion tons of in situ ore containing 474 million tons of manganese. Identified resources amount to about 1.8 billion tons of in situ material. Key results of the study indicate the following: 1. The MEC supply of manganese will be from the currently mined resources well into the next century. 2. Centrally Planned Economy Countries (CPEC's) will be increasingly dependent on MEC manganese ore and concentrate in the future. 3. At the 1976 to 1987 demand increase rate, total MEC resource needed through the year 2000 would be about 282 million tons of in situ material. 4. Transportation and infrastructure support will continue to be major elements of production costs.

Jan 1, 1992

By Donald A. Wilson

As part of a continuing effort to maximize metal recovery from domestic secondary resources, the Bureau of Mines investigated a process for recovering the metallic portion of scrap alkaline batteries. A pyrometallurgical method for recovering nickel and cadmium from Ni-Cd scrap batteries previously developed on a laboratory scale, was scaled up to 25-and 43-pound charges. The method employed reduction and/or decomposition in a retort using a minimum of 2.5 percent carbon as a reductant. Metallic cadmium was distilled at atmospheric pressure and a minimum of 900° C. Purity of the recovered cadmium was 99.8 percent minimum and the nickel-iron residue contained less than 0.02 percent cadmium.

Jan 1, 1981

By Catherine C. Kilgore

The Bureau of Mines investigated the availability of fluorspar (CaF2) from 36 U.S. and 50 foreign mires and deposits in 13 countries. Only 6 U.S. properties are considered to be economic, as 29 domestic deposits were found to have an average total cost of production that was uneconomical at a breakeven (0-pct) discounted-cash-flow rate of return (DCFROR). The 50 foreign properties evaluated represent at least 55 pot of demonstrated fluorspar resources located in market economy countries and China. Al I evaluated foreign operations were found to be economic to marginally economic in January 1984 dollars when compared against published prices for each country. Reserves for 56 properties totaled 97 million metric tons (mt) (recoverable Ca F,) from demonstrated ore resources of 344 million mt that contained 123 million mt CaF2. The average total cost needed to cover all costs over the life of each operation was determined for all recoverable fluorspar products. Comparisons of ruining, beneficiation, and transportation costs per metric ton of fluorspar concentrate illustrate advantages between countries. Of the three countries with the greatest fluorspar production, China, with its high-grade, low-cost operations had the lowest weighted-average total cost of production ($38/mt concentrate), Mexico was next, at $54/mt concentrate, and benefited in U. S. dollar terms from the devaluation of the peso. The Republic of South Africa needed an average of $90/mt of concentrate to cover all costs of production at its large low-grade deposits.

Jan 1, 1985

By S. H. Lorain

Tin mining on Seward Peninsula, Alaska, has been intermittently active since the early 1900's. Most of the recorded production (over 2,200 short tons of metallic tin) has been obtained from placer deposits, but recent production also has resulted from development of lode deposits associated with intrusive rocks occurring in the western part of the peninsula. Generally, the lode deposits containing tin minerals (principally cassiterite) are found in dikes, in granite masses, and in silicate zones in limestone overlying the granite. Both the placer and lode deposits have been of considerable strategic interest to the Government because of the almost total absence of a domestic supply of tin. The most important tin-lode deposit discovered to date is in the Cassiterite dike at the Lost River mine, on Cassiterite Creek about 85 miles northwest of Nome. This highly altered, rhyolite porphyry dike averages 12 feet in thickness, strikes N. 75° to 85° E., and dips steeply to the south; it can be traced on the surface for about 8,000 feet. Throughout its explored length of about 2,200 feet the dike everywhere contains some tin and tungsten in veinlets and disseminations; economic concentration of the are minerals, however, is confined to definite shoots. The ore minerals include cassiterite, stannite, hulsite, paigeite, wolframite, scheelite, and base-metal sulfides; gangue minerals include fluorite, boron silicates, and lithium-bearing minerals. Some ore minerals also occur in the numerous other dikes and in the granite and intruded limestone in and adjacent to the mine.

Jan 1, 1958

By James H. Aase

Selected glacial lake clay deposits in Minnesota were sampled, tested, and evaluated to determine their suitability for use as a bonding agent in iron ore pellet manufacturing. Preliminary tests conducted on clay samples obtained from five ancient glacial lake basins identified the clays in the Lake Agassiz glacial lake basin near Cook, Minn., as having the greatest bonding potential. An auger drilling program was conducted to obtain substantial quantities of representative material for detailed testing. The drilling indicated the presence of large clay reserves in excess of 500 million tons within the 12-square-mile area investigated. Bench scale tests indicated that the bonding properties of Cook area clays, when activated with relatively small quantities of sodium carbonate monohydrate (Na2C03?H2O), imparted excellent strength characteristics to iron ore pellets. Larger scale continuous pelletizing tests were made to confirm the bench scale results. These tests indicated that use of 1 percent activated clay alone as binder gave the iron ore pellets an overall strength slightly lower than with 0.75 percent bentonite, considered the industry standard. Use of 0.5 percent activated clay plus 0.5 percent bentonite produced better pellet strength qualities than use of 0.75 percent bentonite alone, without increasing the silica plus alumina content. The data from both bench scale and larger scale continuous tests suggest that the Cook, Minn., clays can be utilized after activation either alone or in combination with bentonite at an economic advantage over present pelletizing practice with bentonite.

Jan 1, 1968

By A. T. Coumbe

During 1953-55, 31,105 miles of pipe for transporting crude petroleum and refined products was laid in the United States, a total slightly below that of the prior 3-year period, according to data compiled by the Bureau of Mines, United States Department of the Interior. The added mileage consisted of 22,571 miles of new pipe, representing about 2,163,807 tons of steel, plus 8,534 miles of secondhand pipe, equivalent to about 419,849 additional tons of steel. During the 3-year period, 13,069 miles of pipe was taken up. By January 1, 1956, the Nation had 188,540 miles of pipeline, an 11-percent gain over the 1952 total of 170,504 miles. The greater use of larger diameter pipelines indicated in recent surveys has continued, as the mileage for sizes 12 inches and over increased from 13 percent of the total mileage at the close of 1952 to 16 percent 3 years later. Crude-oil trunklines 12 inches and over in diameter gained 24 percent during 1953-55, and these larger lines represented 30 percent of the total mileage compared with 25 percent at the close of 1952. Furthermore, the mileage for crude-oil lines less than 12 inches in diameter declined 2 percent and made up only 70 percent of the 1955 total against 75 percent n the previous survey. Product Lines 8 inches and over increased 43 percent from 1952 through 1955 and composed 70 percent of the total mileage compared with 66 percent in 1952.

Jan 1, 1956

By Eric G. Zahl, John P. Dunford, Hamid Maleki

Coal bumps are influenced by geologic conditions, the geometric design of coal mine excavations, and the sequence and rate of extraction. Researchers from private industry and government agencies around the world have studied mechanisms of violent failure and have identified individual factors that contribute to coal bumps. To develop predictive tools for assessing coal bump potential, the authors initiated a comprehensive study using information from 25 case studies undertaken in U.S. mines. Multiple linear regression and numerical modeling analyses of geological and mining conditions were used to identify the most significant factors contributing to stress bumps in coal mines. Twenty-five factors were considered initially, including mechanical properties of strata, stress fields, face and pillar factors of safety, joint spacings, mining methods, and stress gradients. In situ strength was estimated in 12 coal seams where uniaxial compressive strength exceeded 2,000 psi. Allowances were made for favorable local yielding characteristics of mine roof and floor in reducing damage severity. Pillar and face factors of safety were calculated using displacement-discontinuity methods for specific geometries. This work identified the most important variables contributing to coal bumps. These are (1) mechanical properties of strata, including local yield characteristics of a mine roof and floor, (2) gate pillar factors of safety, (3) roof beam thickness, joint spacing, and stiffness characteristics, which influence released energy,(4) stress gradients associated with the approach of mining to areas of higher stress concentrations, and (5) the mining method. By combining the strength of both analytical and statistical methods, new capabilities were developed for predicting coal bump potential and for building confidence intervals on expected damage.

Jan 5, 1999

By David Hoadley, Kenneth R. Maser, Ashok B. Boghani, James E. Billar, D. Randolph Berry, Mackenzie Burnett, Robert H. Trent

A.5 Conclusions and Recommendations The illustrative simulations in the previous section have demonstrated 1. Flexibility of the program to simulate a wide variety of configurations and cases. 2. Ability of the program to predict evacuation time within a small margin of error (5 percent -.n a case considered). 3. Usefulness of the program in making some of the evacuation decisions. The above leads to a conclusion that the computer program can provide a useful tool in evaluating mine evacuation in the event of a fire. At present the program can be used to make decisions regarding evacuation scheme improvement, while the scheme is being studied. However, significant software and hardware developments are

Jan 1, 1976

By R. V. Ramani

This volume is the first of a four-volume final report on research carried out under a contract from the U.S. Bureau of Mines on the development of a computer simulation model for surface mine reclamation planning. The other volumes are titled as follows: Volume II: Dragline Model, Volume III: Mine Coordinate Generator System, and Volume IV: User's Manual for OPMHS/2. This report deals with the development of a geological model for surface mine planning. The most common orebody modeling techniques are described. A brief review of geostatistical theory and concepts is presented. A geostatistical option for orebody modeling is developed and validated. Computer programs and sample outputs are appended.

Jan 1, 1985

By Arnold P. Pipilen

In a study of the principal factors affecting the transport of coal-water mixtures through a centrifugal pump and a pipeline, the interrelation between solids concentration, velocity, and pressure drop was established for a bituminous lump coal (minus 2 inch) in concentrations up to 48 weight-percent. An optimum concentration was found to exist for maximum capacity of a given pipe-line, and for minimum energy requirements per ton of coal. Coal size degradation by particle fracture took place in the pump; abrasion and attrition to form fines took place in both pump and line. A novel system of studying flow of solid-liquid mixtures in pipelines by the determination of relative sound intensities was developed.

Jan 1, 1966